JP2019165664A - Method for suppressing stickiness of food - Google Patents

Method for suppressing stickiness of food Download PDF

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JP2019165664A
JP2019165664A JP2018055585A JP2018055585A JP2019165664A JP 2019165664 A JP2019165664 A JP 2019165664A JP 2018055585 A JP2018055585 A JP 2018055585A JP 2018055585 A JP2018055585 A JP 2018055585A JP 2019165664 A JP2019165664 A JP 2019165664A
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stickiness
food
water
soluble soybean
sugar
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貴晴 井上
Takaharu Inoue
貴晴 井上
悠悟 島
Yugo Shima
悠悟 島
馬場 俊充
Toshimitsu Baba
俊充 馬場
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Fuji Oil Co Ltd
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Fuji Oil Co Ltd
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Abstract

To provide a method for suppressing stickiness of food coated with a carbohydrate solution.SOLUTION: The present invention provides a method for suppressing stickiness of food caused by carbohydrate, by adding water-soluble soybean polysaccharides in a powder form to the food. The water-soluble soybean polysaccharides are added to the food by 0.01-5 wt.%.SELECTED DRAWING: None

Description

本発明は水溶性大豆多糖類を用いた食品のべたつき抑制方法に関する。   The present invention relates to a method for suppressing stickiness of food using a water-soluble soybean polysaccharide.

佃煮や調味液を含浸した菓子類のような、表面に糖質を含む液が付着している加工食品は、コンビニエンスストアやスーパーマーケット等で販売され、多くの消費者に食されている。
これらの食品において、糖質に由来するべたつきによって、喫食時に手や口の周りがべたつくという問題がある。
Processed foods, such as boiled simmered or confectionery impregnated with seasoning liquid, with a liquid containing sugar on the surface are sold at convenience stores and supermarkets and are eaten by many consumers.
In these foods, there is a problem that the hands and mouth are sticky during eating due to stickiness derived from sugar.

食品のべたつきを防止する従来の方法としては、剥き栗にアラビアガム等の水溶性多糖類を水溶液化してコーティングする方法がある(特許文献1)。また、果実含有ハードキャンディにセルロース誘導体やプルラン、ペクチンを添加する方法も開示されている(引用文献2)。   As a conventional method for preventing the stickiness of food, there is a method of coating peeled chestnuts with a water-soluble polysaccharide such as gum arabic as an aqueous solution (Patent Document 1). A method of adding a cellulose derivative, pullulan, or pectin to a fruit-containing hard candy is also disclosed (Cited document 2).

特開2003−203号公報JP 2003-203 A 特開2010−273954号公報JP 2010-273594 A

引用文献1の技術では対象が限定的であるし、効果も十分といえずさらに改善する余地があった。また、引用文献2の技術ではゲル化剤とセルロース誘導体を用いなければならず、工程が煩雑である。また、効果も十分とはいえず、さらに改善する余地がある。
そこで、本発明は糖液がからまれた食品のべたつきを抑制する優れた方法を提供することを目的とする。
The technique of the cited document 1 has a limited object, and the effect is not sufficient, and there is room for further improvement. Moreover, in the technique of the cited document 2, a gelatinizer and a cellulose derivative must be used, and the process is complicated. Moreover, the effect is not sufficient and there is room for further improvement.
Then, an object of this invention is to provide the outstanding method which suppresses the stickiness of the foodstuff in which the sugar liquid was entangled.

そこで上記課題を解決すべく本発明者らが鋭意研究を行った。その結果、Brix60%以上の糖液で被覆された食品に対して、水溶性大豆多糖類を粉末形態で添加することによって、糖質由来のべたつきを抑制し上記の問題を解決できることを見出し、また、水溶性大豆多糖類を水溶液の状態で添加するとかえってべたつきが増強されることがわかり、本発明を完成するに至った。   Therefore, the present inventors have intensively studied to solve the above problems. As a result, it was found that by adding a water-soluble soybean polysaccharide in a powder form to food coated with a sugar solution of Brix 60% or more, stickiness derived from carbohydrates can be suppressed and the above problems can be solved. The addition of water-soluble soybean polysaccharide in the form of an aqueous solution reveals that stickiness is enhanced, and the present invention has been completed.

すなわち本発明は、
(1)Brix 60%以上の糖液で被覆された食品に対して、水溶性大豆多糖類を粉末形態で添加することを特徴とする、食品のべたつき抑制方法、
(2)糖液のBrixが70%以上である、(1)記載の食品のべたつき抑制方法、
(3)水溶性大豆多糖類を食品重量に対して、0.01〜5重量%添加する、(1)または(2)記載の食品のべたつき抑制方法、
(4)Brix 60%以上の糖液で被覆された食品用の、水溶性大豆多糖類を主体とする、食品のべたつき抑制剤、
である。
That is, the present invention
(1) A method for suppressing stickiness of food, characterized in that water-soluble soybean polysaccharide is added in powder form to food coated with a sugar solution of Brix 60% or more,
(2) The method for suppressing stickiness of food according to (1), wherein the Brix of the sugar solution is 70% or more,
(3) The method for suppressing stickiness of food according to (1) or (2), wherein the water-soluble soybean polysaccharide is added in an amount of 0.01 to 5% by weight based on the weight of the food.
(4) Food stickiness inhibitor mainly composed of water-soluble soybean polysaccharide for food coated with a sugar solution of Brix 60% or more,
It is.

本発明により、Brix60%以上の糖液で被覆された食品においてべたつきを抑制することができ、喫食時の手や口の周りのべたつきが抑制される。   According to the present invention, stickiness can be suppressed in foods coated with a sugar solution of Brix 60% or more, and stickiness around hands and mouths during eating is suppressed.

(Brix 60%以上の糖液で被覆された食品)
本発明のBrix 60%以上の糖液で被覆された食品は、糖液に起因してべたつきを有するものである。本発明におけるべたつきとは、指で触れた際に粘りや糸引きを生じることをいう。本発明の方法により、このようなべたつきを有する食品のべたつきを抑制することができる。
本発明の検討において、Brixの糖度を変えて、べたつきとの関係について調べたところ、糖液のBrixが60%以上でべたつきを生じることが確認されている。
また、糖液Brixの値が60%よりも上がると、べたつきの度合いがより強くなるが、その場合にも本発明の方法により、べたつきを抑制することができる。べたつきの度合いがより顕著な食品に対しても有効に本発明の効果が発揮されることから、糖液のBrixは70%以上が好ましい。
また、本発明において「被覆された」とは、食材に糖液が完全に被覆されていなくても、食材に絡められ糖液の影響で食材を触ったときにべたつきを感じる程度の範囲で被覆されたものも含み、完全に糖液で被覆されたもののみに限定されるものではない。
(Food covered with Brix 60% or more sugar solution)
Foods coated with a sugar solution of Brix 60% or more of the present invention have stickiness due to the sugar solution. Stickiness in the present invention means that stickiness or stringing occurs when touched with a finger. By the method of the present invention, the stickiness of food having such a stickiness can be suppressed.
In the examination of the present invention, when the sugar content of Brix was changed and the relationship with stickiness was examined, it was confirmed that stickiness was produced when Brix of the sugar solution was 60% or more.
Further, when the value of the sugar solution Brix is higher than 60%, the degree of stickiness becomes stronger, but even in that case, stickiness can be suppressed by the method of the present invention. Since the effect of the present invention is effectively exhibited even for foods with a more noticeable stickiness, the Brix of the sugar solution is preferably 70% or more.
Further, in the present invention, “coated” means that the food material is not covered completely with the sugar solution, but is covered in a range where the food material is tangled by the influence of the sugar solution and feels sticky when touched. It is not limited to the one completely covered with the sugar solution.

本発明の対象となる食品として、(1)糖を主体とする溶液に食材を投入し、加熱し煮詰めた食品、(2)糖を主体とする溶液を食材に絡めた食品、(3)果物などの糖を多く含む食材を乾燥させた食品などが挙げられる。これらの食品の具体的な例として、佃煮、みりん干し、かりんとう、大学芋、ドライフルーツ等の他、大豆たん白素材などの食材に糖液をからめたような食品等が挙げられる。   Foods subject to the present invention include: (1) foods that are prepared by putting food into a solution mainly composed of sugar, heated and boiled; (2) foods that are entangled with a solution mainly composed of sugar; (3) fruits Examples include foods obtained by drying foods rich in sugar such as Specific examples of these foods include foods such as boiled boiled fish, mirin-boshi, karinto, university koji, dried fruit, etc., as well as foods in which sugar liquid is entangled in ingredients such as soybean protein materials.

糖液の原料となる糖類は特に限定されない。例えば、ショ糖、上白糖、グラニュー糖、ブドウ糖、果糖、異性化糖、トレハロース、乳糖、麦芽糖、オリゴ糖、糖アルコール(ソルビトール、マルチトール、キシリトール、ラクチトール、エリスリトール、マンニトール等)、水あめ等が挙げられる。これらの糖類は1種、または2種以上が組み合わされていても良い。   The saccharide used as the raw material for the sugar liquid is not particularly limited. For example, sucrose, sucrose, granulated sugar, glucose, fructose, isomerized sugar, trehalose, lactose, maltose, oligosaccharide, sugar alcohol (sorbitol, maltitol, xylitol, lactitol, erythritol, mannitol, etc.), starch syrup, etc. It is done. These saccharides may be used alone or in combination of two or more.

(水溶性大豆多糖類)
本発明における水溶性大豆多糖類とは、大豆原料から抽出し、固液分離することにより得られる水溶性の多糖類である。水溶性大豆多糖類の大豆原料として、子葉由来のものが好ましく、豆腐や分離大豆蛋白などを生産する場合に副産物として生じるオカラを利用することが好ましい。油分を含むオカラを使用する場合には、オカラの加熱によって油分が酸化し、オカラから抽出した水溶性大豆多糖類の風味が悪くなる場合がある。そのため、脱脂大豆から得られたオカラを使用するのが好ましく、分離大豆蛋白を製造する工程で副産物として生じるオカラを使用することが最も好ましい。
水溶性大豆多糖類は、例えば、分離大豆蛋白を製造する工程で得られたオカラを原料として、アルカリ性域乃至弱酸性域、好ましくはpH3〜7の条件下で、100℃を超える温度、好ましくは100℃を超え190℃以下、より好ましくは100℃を超え130℃以下で加熱抽出し、スラリーを得る。その後、スラリーを固液分離し、上清液を必要に応じて精製処理、殺菌をした後、噴霧乾燥等で乾燥することにより得られる。
(Water-soluble soybean polysaccharide)
The water-soluble soybean polysaccharide in the present invention is a water-soluble polysaccharide obtained by extraction from soybean raw material and solid-liquid separation. As the soybean raw material of the water-soluble soybean polysaccharide, those derived from cotyledons are preferable, and it is preferable to use okara produced as a by-product when producing tofu or separated soybean protein. When using okara containing oil, the oil is oxidized by heating the okara, and the flavor of the water-soluble soybean polysaccharide extracted from okara may deteriorate. Therefore, it is preferable to use okara obtained from defatted soybean, and it is most preferable to use okara produced as a by-product in the process of producing separated soybean protein.
The water-soluble soybean polysaccharide is, for example, an okara obtained in the process of producing isolated soybean protein as a raw material, in an alkaline range to a weakly acidic range, preferably at a pH of 3 to 7, preferably at a temperature exceeding 100 ° C, preferably Heat extraction is performed at a temperature exceeding 100 ° C. and not exceeding 190 ° C., more preferably exceeding 100 ° C. and not exceeding 130 ° C. to obtain a slurry. Thereafter, the slurry is solid-liquid separated, and the supernatant is purified and sterilized as necessary, and then dried by spray drying or the like.

(添加量)
水溶性大豆多糖類の添加量は、食品重量に対して、好ましくは0.01〜5重量%、より好ましくは0.25〜1.5重量%となるように添加する。添加量が少なすぎると本発明の効果が得られない場合がある。また、添加量が多すぎると、水溶性大豆多糖類粉末が食品表面に析出したり、水溶性大豆多糖類に由来するぬめりが生じたりする場合がある。
(Addition amount)
The addition amount of the water-soluble soybean polysaccharide is preferably 0.01 to 5% by weight, more preferably 0.25 to 1.5% by weight, based on the weight of the food. If the amount added is too small, the effects of the present invention may not be obtained. Moreover, when there is too much addition amount, water-soluble soybean polysaccharide powder may precipitate on the food surface, or the slime derived from water-soluble soybean polysaccharide may arise.

(添加方法)
水溶性大豆多糖類の添加方法は、例えば、食品に糖液を絡めた後、水溶性大豆多糖類の粉末を添加する方法が挙げられる。
(Addition method)
The method for adding the water-soluble soybean polysaccharide includes, for example, a method of adding a water-soluble soybean polysaccharide powder after entanglement of a sugar solution with food.

以下、実施例を挙げて本発明をさらに説明する。なお、例中の%はいずれも重量基準を意味する。   Hereinafter, the present invention will be further described with reference to examples. In the examples,% means a weight basis.

以下に示す実施例において、水溶性大豆多糖類として不二製油株式会社製の「ソヤファイブ-S-LA200」を使用した。   In the following examples, “Soya Five-S-LA200” manufactured by Fuji Oil Co., Ltd. was used as the water-soluble soybean polysaccharide.

(各種多糖類の検討)(実施例1、比較例1〜9)
すき焼きのタレ300g(ヤマサ すき焼き専科、ヤマサ醤油株式会社製)とグラニュー糖300gを鍋に入れて加熱し、グラニュー糖が溶解したのを確認した後、粒状大豆蛋白素材(ベジプラス2900、不二製油株式会社製)300gを混合した。さらに加熱を続け、糖液を煮詰めていき、糖液のBrixが80%となったところで加熱を止めた。次に、上記の糖液で被覆された粒状大豆たん白素材100gに対して、水溶性大豆多糖類の粉末0.5gを添加して均一に混合し、糖液をからめた食品を得た(実施例1)。
(Examination of various polysaccharides) (Example 1, Comparative Examples 1 to 9)
Put 300g of sukiyaki sauce (Yamasa Sukiyaki Senka, Yamasa Soy Sauce Co., Ltd.) and 300g of granulated sugar in a pan, heat and confirm that the granulated sugar is dissolved. 300 g) was mixed. The heating was further continued, and the sugar solution was boiled. When the Brix of the sugar solution reached 80%, the heating was stopped. Next, 100 g of the granular soybean protein material coated with the above-mentioned sugar solution was mixed with 0.5 g of water-soluble soybean polysaccharide powder and mixed uniformly to obtain a food product entangled with the sugar solution (Implementation) Example 1).

また、他の多糖類として、プルラン(株式会社林原「プルラン」)、ローカストビーンガム(三栄源エフ・エフ・アイ株式会社「ビストップD-2050」)、キサンタンガム(三栄源エフ・エフ・アイ株式会社「サンエース」)、α化でんぷん(株式会社カーギルジャパン「HiForm 72348」)、難消化性でんぷん(株式会社カーギルジャパン「ActiStar 75330」)、デキストリン(松谷化学工業株式会社「TK-16」)、不溶性食物繊維(レッテンマイヤー株式会社「VITACEL AF400」)、結晶セルロース製剤(旭化成株式会社「セオラス DX-2」)の各粉末を用いて実施例1と同様にして食品を得た(比較例2〜9)。なお、多糖類無添加のものを比較例1とした。   Other polysaccharides include pullulan (Hayashibara “Pullan”), locust bean gum (Saneigen FFI Co., Ltd. “Bistop D-2050”), xanthan gum (Saneigen FFI Co., Ltd.) Company "San Ace"), pregelatinized starch (Cargill Japan "HiForm 72348"), indigestible starch (Cargill Japan "ActiStar 75330"), dextrin (Matsuya Chemical Industry "TK-16"), insoluble Foods were obtained in the same manner as in Example 1 using each powder of dietary fiber (Rettenmeier "VITACEL AF400") and crystalline cellulose preparation (Asahi Kasei "Theolas DX-2") (Comparative Examples 2-9) ). In addition, the thing without a polysaccharide was set as the comparative example 1.

得られた食品を袋に充填、密閉し、この状態で1日間、常温(22℃)で保存後のべたつきを、パネラー4名で評価した。パネラーは糖液をからめた食品に指で触れて、そのべたつき度合いを評価した。各パネラーは1〜10点で評価し、合議にて点数の決定を行った。点数は、多糖類無添加のものを5点とし、これを基準に指で触れた際に粘りや糸引きが低減され、べたつきが抑制できているものは4点以下(べたつきが全くない場合は1点)、指で触れた際に粘りや糸引きが強くなり、べたつきが増強されているものは6点以上(べたつきが極めて強いものは10点)と判断した。
評価点が4点以下の場合、合格と判断した。
The obtained food was filled in a bag and sealed, and the stickiness after storage at room temperature (22 ° C.) for 1 day in this state was evaluated by 4 panelists. The panelists touched the food with sugar solution with their fingers and evaluated the stickiness. Each panelist evaluated with a score of 1-10, and the score was decided by discussion. The score is 5 points with no added polysaccharides, and stickiness and stringing are reduced when touched with a finger based on this, and stickiness is suppressed by 4 points or less (if there is no stickiness) (1 point), the stickiness and stringiness became strong when touched with a finger, and the stickiness was increased to 6 points or more (10 points were extremely sticky).
When the evaluation score was 4 points or less, it was judged as passing.

(表1)水溶性大豆多糖類と他の多糖類との比較結果

Figure 2019165664
(Table 1) Comparison results of water-soluble soybean polysaccharide and other polysaccharides
Figure 2019165664

表1の結果のように、他の多糖類と比較して、水溶性大豆多糖類は食品のべたつき抑制に優れた効果を示した。   As the result of Table 1, compared with other polysaccharides, water-soluble soybean polysaccharide showed the effect excellent in stickiness control of foodstuffs.

(水溶性大豆多糖類の粉末添加と水溶液添加による比較)(実施例1、比較例10〜11)
水溶性大豆多糖類を粉末形態にて添加した場合と、水溶液化した後に添加した場合とで効果を比較した。
実施例1と同様にしてBrixが80%の糖液をからめた食品を得た。その後、水溶性大豆多糖類の20%水溶液を、糖液をからめた粒状大豆蛋白素材(ベジプラス2900、不二製油株式会社製)100gに対して、水溶性大豆多糖類の量として2.5gとなるように添加(比較例10)、あるいは水を粒状大豆蛋白素材(ベジプラス2900、不二製油株式会社製)100gに対して、2g添加(比較例11)し、パネラー4名にて評価を行った。評価は段落0019に記載の手法にて行った。結果を表2に示した。
(Comparison by adding water-soluble soybean polysaccharide powder and aqueous solution) (Example 1, Comparative Examples 10-11)
The effect was compared between the case where the water-soluble soybean polysaccharide was added in the form of a powder and the case where the water-soluble soybean polysaccharide was added after the aqueous solution.
In the same manner as in Example 1, a food product in which a sugar solution containing 80% Brix was entangled was obtained. Then, 20% aqueous solution of water-soluble soybean polysaccharide is 2.5g as the amount of water-soluble soybean polysaccharide to 100g of granular soybean protein material (Veggie Plus 2900, Fuji Oil Co., Ltd.) entangled with sugar solution. As described above (Comparative Example 10), or 2 g of water was added (Comparative Example 11) to 100 g of granular soybean protein material (Veggie Plus 2900, manufactured by Fuji Oil Co., Ltd.) and evaluated by 4 panelists. . The evaluation was performed by the method described in paragraph 0019. The results are shown in Table 2.

(表2)水溶性大豆多糖類の粉末添加と水溶液添加との比較結果

Figure 2019165664
(Table 2) Comparison results of addition of water-soluble soybean polysaccharide powder and aqueous solution
Figure 2019165664

表2に示したように、水溶性大豆多糖類を粉末にて添加した場合、優れたべたつき抑制効果を示したが、水溶性大豆多糖類の水溶液を添加するとべたつき抑制効果がない結果となった。従って、水溶性大豆多糖類を粉末の形態で添加することが重要であることがわかった。   As shown in Table 2, when water-soluble soybean polysaccharide was added as a powder, an excellent stickiness-inhibiting effect was shown, but when an aqueous solution of water-soluble soybean polysaccharide was added, there was no stickiness-inhibiting effect. . Therefore, it was found that it is important to add the water-soluble soybean polysaccharide in the form of powder.

(糖液Brixとべたつきの関係)(試験例1)
べたつきを生じる糖液Brixの濃度がどの程度になるのかを確認するため、各種糖液を用いてべたつきの有無を確認した。糖として、グラニュー糖、水あめ(スドージャム株式会社)、オリゴ糖液(マルデックPH400、昭和産業株式会社)を使用し、それぞれ、糖液のBrixが70%、60%、50%、40%になるように水を用いて溶解または希釈して糖液を調製した。べたつきの評価はパネラー4名にて行った。パネラーはそれぞれの糖液を1滴指に取り、2本の指で接着と剥離を行い、粘りや糸引きを生じてべたつくか否かを判定した。
(Relationship between sugar solution Brix and stickiness) (Test Example 1)
In order to confirm the concentration of the sugar solution Brix that causes stickiness, the presence or absence of stickiness was confirmed using various sugar solutions. As sugar, granulated sugar, water candy (Sudojam Co., Ltd.) and oligosaccharide liquid (Maldec PH400, Showa Sangyo Co., Ltd.) are used, so that Brix of the sugar liquid is 70%, 60%, 50% and 40%, respectively. A sugar solution was prepared by dissolving or diluting the solution with water. Stickiness was evaluated by 4 panelists. The panelist took each sugar solution on one drop finger, adhered and peeled off with two fingers, and judged whether stickiness or stringing occurred and it was sticky.

(表3)各種糖液のBrixとべたつき評価結果

Figure 2019165664
◎:強くべたつく ○:べたつく ×:べたつかない (Table 3) Brix and stickiness evaluation results of various sugar solutions
Figure 2019165664
◎: Strongly sticky ○: Sticky ×: Not sticky

表3の結果のように、糖液Brixが60%でべたつきが生じ、70%ではさらにべたつきが増強されることが確認された。   As shown in the results of Table 3, it was confirmed that the stickiness occurred when the sugar solution Brix was 60%, and the stickiness was further enhanced when the sugar solution Brix was 70%.

Claims (4)

Brix 60%以上の糖液で被覆された食品に対して、水溶性大豆多糖類を粉末形態で添加することを特徴とする、食品のべたつき抑制方法。 A method for suppressing stickiness of food, comprising adding water-soluble soybean polysaccharide in a powder form to food coated with a sugar solution of Brix 60% or more. 糖液のBrixが70%以上である、請求項1記載の食品のべたつき抑制方法。 The method for suppressing stickiness of food according to claim 1, wherein Brix of the sugar solution is 70% or more. 水溶性大豆多糖類を食品重量に対して、0.01〜5重量%添加する、請求項1または2記載の食品のべたつき抑制方法。 The method for suppressing stickiness of food according to claim 1 or 2, wherein the water-soluble soybean polysaccharide is added in an amount of 0.01 to 5% by weight based on the weight of the food. Brix 60%以上の糖液で被覆された食品用の、水溶性大豆多糖類を主体とする、食品のべたつき抑制剤。 Brix A food stickiness suppressant mainly composed of water-soluble soybean polysaccharide for foods coated with 60% or more sugar solution.
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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2019208471A (en) * 2018-06-08 2019-12-12 クラシエフーズ株式会社 Cooked meat-like heat-sterilized process food in sealed container and method for producing the same, and method for preventing binding and stickiness of cooked meat-like heat-sterilized process food in sealed container

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2019208471A (en) * 2018-06-08 2019-12-12 クラシエフーズ株式会社 Cooked meat-like heat-sterilized process food in sealed container and method for producing the same, and method for preventing binding and stickiness of cooked meat-like heat-sterilized process food in sealed container
JP7028447B2 (en) 2018-06-08 2022-03-02 クラシエフーズ株式会社 Cooked meat-like heat-sterilized food in a sealed container and its manufacturing method, and cooked meat-like heat-sterilized food in a sealed container.

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