JP2019149988A - Water-in-oil-type emulsified oil and fat composition for butter cream - Google Patents

Water-in-oil-type emulsified oil and fat composition for butter cream Download PDF

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JP2019149988A
JP2019149988A JP2018039012A JP2018039012A JP2019149988A JP 2019149988 A JP2019149988 A JP 2019149988A JP 2018039012 A JP2018039012 A JP 2018039012A JP 2018039012 A JP2018039012 A JP 2018039012A JP 2019149988 A JP2019149988 A JP 2019149988A
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JP7098963B2 (en
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利博 伊東
Toshihiro Ito
利博 伊東
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Abstract

To provide an oil and fat composition for butter cream having good plasticity and whippability without containing trans fatty acid, and having good mouth melting and shape retention property as a butter cream.SOLUTION: There is provided a water-in-oil-type emulsified oil and fat composition for butter cream containing following oil and fat (A) and oil and fat (B) with content of the oil and fat (A) of 25 to 70 mass% and content of the oil and fat (B) of 5 to 30 mass%. Oil and fat (A): a transesterification oil and fat between lard or fractionated lard and oil and fat containing aliphatic fatty acid with 22 carbon atoms as constituent fatty acid. Oil and fat (B): a medium melting point part obtained by fractionating palm oil.SELECTED DRAWING: None

Description

本発明は、フィリング、トッピング、およびサンド用途に好適に使用されるバタークリーム用油中水型乳化油脂組成物およびこれを原料とするバタークリームに関する。   The present invention relates to a water-in-oil emulsified oil / fat composition for butter cream that is suitably used for filling, topping, and sand applications, and a butter cream made from the same.

バタークリームは、無水クリームあるいは油中水型クリームであり、クッキー、ビスケット、バターケーキ等のフィリング、トッピングおよびサンド用途等に使用されている。例えば、ビスケットやゴーフル等におけるサンド用途には、ショートニング形態の油脂組成物を原料とし、これに粉糖および呈味成分等を混合・撹拌して製造された無水のバタークリームが使用されている。また、パンやケーキのフィリング、トッピング、サンド用途にはショートニングまたはマーガリンの形態の油脂組成物を原料とし、これにシロップ、呈味成分などを混合し撹拌して製造されたバタークリームが使用されている。   Butter cream is an anhydrous cream or a water-in-oil cream and is used for filling, topping and sanding of cookies, biscuits, butter cakes and the like. For example, an anhydrous butter cream manufactured by mixing and stirring powdered sugar, a taste component and the like with a shortening-type oil and fat composition as a raw material is used for sand applications in biscuits, gourds and the like. Also, for filling, topping and sanding of breads and cakes, butter cream manufactured by mixing and stirring syrup, flavoring ingredients, etc. is used as a raw material for shortening or margarine. Yes.

これらバタークリームを製造する際に使用される油脂組成物に求められる性能としては、油脂組成物に呈味成分等を混合・撹拌し、さらにこれをホイップし保形するので、液状、固体状ではなく、適度な硬さを有する可塑性が必要である。また、季節に対応し広い温度範囲での可塑性、ホイップ性が要求される。また、その油脂組成物を使用して製造したバタークリームでは、口当たりや口溶け等の良好な食感が求められる。
これまでは、このような性能が求められる油脂組成物の原料として各種動植物油脂の部分硬化油(部分水添油)が広く用いられてきた。これら部分硬化油には、通常、構成脂肪酸中にトランス脂肪酸が10〜50質量%程度含まれており、トランス脂肪酸の結晶特性により、可塑性、ホイップ性、口溶けの良さなどのバタークリーム用油脂組成物に求められる機能が得られる。
The performance required for the oil and fat composition used when producing these butter creams is to mix and stir the flavor components and the like in the oil and fat composition, and then whip and retain the shape. However, plasticity having an appropriate hardness is required. In addition, plasticity and whipability in a wide temperature range corresponding to the season are required. Moreover, in the butter cream manufactured using the oil-and-fat composition, favorable food texture, such as a mouthfeel and a melt in a mouth, is calculated | required.
Until now, partially hardened oils (partially hydrogenated oils) of various animal and vegetable oils and fats have been widely used as raw materials for oil and fat compositions that require such performance. These partially hardened oils usually contain about 10 to 50% by mass of trans fatty acids in the constituent fatty acids. Depending on the crystal characteristics of the trans fatty acids, the fat and oil composition for butter cream such as plasticity, whipping properties and good meltability in the mouth. The required function is obtained.

トランス脂肪酸は、天然油脂中にはほとんど存在せず、反芻動物由来の油脂に10質量%未満含まれているに過ぎない。近年の研究では、このトランス脂肪酸が血漿中のLDL/HDLコレステロール比を増大させ、循環器疾患の原因となるとの報告がある。このように、トランス脂肪酸を過剰摂取することが健康へ悪影響を及ぼす懸念があるため、油脂中のトランス脂肪酸含量を少なくした方が好ましく、デンマークでは、2004年より国内の食品について油脂中のトランス脂肪酸含有率を2質量%以下にしなければならないとの制限を設けている。そのため、バタークリーム用油脂組成物中のトランス脂肪酸の含有量は2質量%以下が一つの目標とされる。   Trans fatty acids are hardly present in natural fats and oils, and are contained only in less than 10% by mass in ruminant-derived fats and oils. In recent studies, it has been reported that this trans fatty acid increases the LDL / HDL cholesterol ratio in plasma and causes cardiovascular disease. Thus, since there is a concern that excessive intake of trans fatty acid may adversely affect health, it is preferable to reduce the content of trans fatty acid in fats and oils. In Denmark, trans fatty acids in fats and oils have been used in domestic foods since 2004. There is a restriction that the content must be 2% by mass or less. Therefore, the content of trans fatty acid in the fat or oil composition for butter cream is targeted to be 2% by mass or less.

トランス脂肪酸を含む部分硬化油を用いたバタークリーム用油脂組成物に代替する油脂組成物としては、ラウリン系油脂を用いた油脂組成物(特許文献1)、パーム系油脂と液状油のエステル交換油とPMF(中融点部)を併用した油脂組成物(特許文献2)、ラード系油脂とエルシン酸を含む油脂のエステル交換油を使用した油脂組成物(特許文献3)が開示されている。   As an oil and fat composition that replaces an oil and fat composition for butter cream using a partially hardened oil containing a trans fatty acid, an oil and fat composition using lauric oil and fat (Patent Document 1), a transesterified oil of palm oil and liquid oil And oil composition (Patent Document 2) using PMF (medium melting point part) in combination, and an oil and fat composition (Patent Document 3) using transesterified oil of fat and oil containing lard oil and erucic acid.

特許文献1に記載されている油脂組成物では、ホイップ性を得るために炭素数14以下の飽和脂肪酸、即ちラウリン系油脂を多く配合している。しかし、ラウリン系油脂は加水分解しやすいため保存性が悪い。またトランス脂肪酸を含む部分硬化油を用いた場合と比較し、充分なホイップ性が得られないといった問題があった。
特許文献2においてはトリアシルグリセロールの1または3位と2位にパルミチン酸が結合し、パルミチンが結合していない1、または3位にオレイン酸が結合したトリアシルグリセロール(PPO)を主成分とするエステル交換油とトリアシルグリセロールの1位と3位にパルミチン酸、2位にオレイン酸が結合したトリアシルグリセロール(POP)を主成分とする油脂としてPMFを併用した油脂組成物が記載されている。しかし、マーガリンやショートニングにパーム系油脂を主体に配合した場合、特にPOPを多く含むPMFを使用した場合、POPの結晶化速度が遅く粗大結晶を生じやすいという特性により、保存中にグレインが発生したり、経時的に硬くなってしまったりするという不具合を生じる。
In the oil and fat composition described in Patent Document 1, a saturated fatty acid having 14 or less carbon atoms, that is, a lauric oil and fat is blended in a large amount in order to obtain whipability. However, since lauric fats and oils are easily hydrolyzed, storage stability is poor. Moreover, compared with the case where the partially hardened oil containing trans fatty acid was used, there existed a problem that sufficient whipping property was not obtained.
In Patent Document 2, a triacylglycerol (PPO) in which palmitic acid is bonded to positions 1 and 3 and 2 of triacylglycerol and oleic acid is bonded to position 1 or 3 in which palmitic acid is not bonded is a main component. An oil and fat composition using PMF as an oil and fat mainly composed of triacylglycerol (POP) in which palmitic acid is bonded to the 1st and 3rd positions of the transacyl oil and triacylglycerol and oleic acid is bonded to the 2nd position is described. Yes. However, when blended mainly with palm-based fats and oils in margarine or shortening, especially when PMF containing a large amount of POP is used, grain is generated during storage due to the slow crystallization rate of POP and the tendency to produce coarse crystals. Or the problem of becoming harder with time.

特許文献3に記載されている油脂組成物は、ラードや分別ラードとベヘン酸を多く含む油脂とをエステル交換して得られる油脂を使用している。しかし、部分硬化油と比較して、十分なホイップ性は得られるものの、エステル交換油によって生じるトリ飽和トリアシルグリセロールの影響などにより口溶けについて不十分であった。   The oil / fat composition described in Patent Document 3 uses an oil / fat obtained by transesterification of lard, fractionated lard, and oil / fat containing a large amount of behenic acid. However, although sufficient whipability can be obtained as compared with partially hardened oil, dissolution in the mouth is insufficient due to the influence of trisaturated triacylglycerol produced by the transesterified oil.

特開2005−60614号公報Japanese Patent Laid-Open No. 2005-60614 特開2013−150625号公報JP 2013-150625 A 特開平11−289976号公報JP-A-11-289976

以上のように、バタークリーム用油脂組成物には良好な可塑性、ホイップ性、バタークリームを製造した際の良好な口溶けおよび保型性が求められ、トランス脂肪酸を含む部分硬化油を用いた場合、これらの物性を全て満たす油脂組成物が実現されている。しかしながら、これらの物性において、優れた性能を示すバタークリーム用油脂組成物は未だ提供されていない。
本発明の目的は、トランス脂肪酸を含まずに、良好な可塑性、ホイップ性を有し、バタークリームとなして良好な口溶けおよび保型性を有するバタークリーム用油脂組成物を提供することにある。
As described above, good plasticity, whipping properties, good meltability and shape retention when producing butter cream are required for the fat and oil composition for butter cream, and when partially cured oil containing trans fatty acid is used, An oil and fat composition satisfying all these physical properties has been realized. However, an oil / fat composition for butter cream showing excellent performance in these physical properties has not yet been provided.
An object of the present invention is to provide an oil / fat composition for butter cream which does not contain trans fatty acid, has good plasticity and whipping properties, and has good mouth melting and shape retention properties as a butter cream.

本発明者は上記課題を解決するため鋭意研究を重ねた結果、炭素数22の脂肪酸を含む油脂の存在に着目し、この油脂とラード系油脂とのエステル交換油脂、およびパーム油中融点部(PMF)の両者を特定量含有する油脂組成物が上記の課題を解決することの知見を見出し、本発明を完成するに至った。
すなわち、本発明は下記の〔1〕〜〔4〕である。
As a result of intensive studies to solve the above-mentioned problems, the present inventor has paid attention to the presence of fats and oils containing a fatty acid having 22 carbon atoms, transesterified fats and oils of these fats and lard-based fats and oils, and a melting point part ( The inventors have found that an oil and fat composition containing a specific amount of both (PMF) solves the above-mentioned problems, and has completed the present invention.
That is, the present invention includes the following [1] to [4].

〔1〕下記の油脂(A)および油脂(B)を含有し、油脂(A)の含有量が25〜70質量%、油脂(B)の含有量が5〜30質量%であるバタークリーム用油中水型乳化油脂組成物。
油脂(A):ラードまたは分別ラードと、炭素数22の飽和脂肪酸を構成脂肪酸として含む油脂とのエステル交換油脂
油脂(B):パーム油を分別して得られる中融点部
〔2〕油脂(A)の構成脂肪酸における、炭素数22の飽和脂肪酸の含有割合が2〜15質量%である、前記の〔1〕に記載のバタークリーム用油中水型乳化油脂組成物。
〔3〕実質的にトランス脂肪酸とラウリン酸を含まない食用油脂(C)20〜70質量%含有する、前記の〔1〕または〔2〕に記載のバタークリーム用油中水型乳化油脂組成物。
〔4〕前記の〔1〕〜〔3〕のいずれかに記載のバタークリーム用油中水型乳化油脂組成物を30〜90質量%含むバタークリーム。
[1] For butter cream containing the following fats and oils (A) and fats and oils (B), wherein the content of fats and oils (A) is 25 to 70% by mass and the content of fats and oils (B) is 5 to 30% by mass Water-in-oil type emulsified fat composition.
Fats and oils (A): Transesterified fats and oils of lard or fractionated lard and fats and oils containing saturated fatty acids having 22 carbon atoms as constituent fatty acids (B): Middle melting point part obtained by fractionating palm oil [2] Fats and oils (A) The water-in-oil emulsified oil / fat composition for butter cream according to [1] above, wherein the content ratio of the saturated fatty acid having 22 carbon atoms in the constituent fatty acid is 2 to 15% by mass.
[3] The water-in-oil emulsified oil / fat composition for butter cream according to [1] or [2] above, containing 20 to 70% by mass of edible fat / oil (C) substantially free of trans fatty acid and lauric acid .
[4] A butter cream containing 30 to 90% by mass of the water-in-oil emulsified fat / oil composition for butter cream according to any one of [1] to [3].

本発明によれば、トランス脂肪酸の含有量が少ない油脂組成物であるにも関わらず、可塑性およびホイップ性に優れ、保管中の状態不良を生じず、製造されるバタークリームの口溶けが良好で、保型性のある油中水型乳化油脂を提供することができる。
本発明のバタークリーム用油中水型乳化油脂は、上記の優れた特性を有するので、単独または他の油脂の添加下で、様々なバリエーションのバタークリーム用油中水型乳化油脂を製造でき、汎用性に富む。
According to the present invention, although it is an oil and fat composition with a low content of trans fatty acid, it is excellent in plasticity and whipping properties, does not cause a bad state during storage, and has good mouth melt of the produced butter cream, It is possible to provide a water-in-oil type emulsified fat with shape retention.
Since the water-in-oil emulsified fats and oils for butter cream of the present invention have the above-described excellent properties, various variations of water-in-oil emulsified fats and oils for butter cream can be produced alone or under the addition of other fats and oils. Rich in versatility.

本発明のバタークリーム用油中水型乳化油脂は、下記の油脂(A)および油脂(B)を含有する。
油脂(A):ラードまたは分別ラードと、炭素数22の飽和脂肪酸を構成脂肪酸として含む油脂とのエステル交換油脂
油脂(B):パーム油を分別して得られる中融点部
The water-in-oil emulsified fat / oil for butter cream of the present invention contains the following fat / oil (A) and fat / oil (B).
Fats and oils (A): Lard or fractionated lard and transesterified fats and oils and fats and oils containing saturated fatty acids having 22 carbon atoms as constituent fatty acids (B): Middle melting point part obtained by fractionating palm oil

(油脂(A))
本発明に使用する油脂(A)は、バタークリーム用油中水型乳化油脂組成物のベース油脂成分であり、油中水型乳化油脂組成物のホイップ性を高め、かつ油脂(B)添加による保存中のグレイン発生や経時的硬化を防ぎ、製造されるバタークリームの口溶けを良好とする油脂(B)の機能を維持する成分である。
(Oil and fat (A))
The fat (A) used in the present invention is a base fat component of a water-in-oil emulsified fat composition for butter cream, improves the whipping property of the water-in-oil emulsified fat composition, and is obtained by adding the fat (B). It is a component that prevents the generation of grains during storage and hardening over time, and maintains the function of the fat (B) that makes the butter cream produced melt well.

本発明に使用する油脂(A)は、ラードまたは分別ラードと炭素数22の脂肪酸を含む油脂とをエステル交換して得られる油脂である。
該エステル交換に用いられるラードとしては特に制限はなく、豚のいずれの部位から得られたものであってもよい。また、分別ラードとしては、それらのラードを高融点の結晶部や、低融点の液状部に分画して得られる種々の分別油を用いることができる。本発明においては、上記ラードを1種用いてもよいし、2種以上組み合わせて用いてもよく、また分別ラードを1種用いてよいし、2種以上組み合わせて用いてもよい。あるいは、該ラード1種以上と分別ラード1種以上とを組み合わせて用いてもよい。
The fats and oils (A) used in the present invention are fats and oils obtained by transesterification of lard or fractionated lard and fats and oils containing 22 fatty acids.
The lard used for the transesterification is not particularly limited, and may be obtained from any part of the pig. Moreover, as the fraction lard, various fraction oils obtained by fractionating these lards into a high melting point crystal part or a low melting point liquid part can be used. In the present invention, one kind of the lard may be used, two or more kinds may be used in combination, one kind of sorting lard may be used, or two or more kinds may be used in combination. Alternatively, one or more lards and one or more lards may be used in combination.

一方、炭素数22の飽和脂肪酸を構成脂肪酸として含む油脂としては特に制限はないが、例えば炭素数22の不飽和脂肪酸を高い割合で含む、ハイエルシン酸ナタネ油や、イワシ、サバ、サンマ、ニシン、アンチョビ、マグロ、カツオなどの魚油を、完全に水素添加した極度水添油を好ましく挙げることができる。本発明においては、これらの油脂は1種用いてもよいし、2種以上を組み合わせて用いてもよい。
炭素数22の飽和脂肪酸、すなわちベヘン酸は、炭素数22の不飽和脂肪酸、例えば炭素数22の一価不飽和脂肪酸であるエルシン酸などを完全に水素添加することなどで得られる。
On the other hand, fats and oils containing saturated fatty acids having 22 carbon atoms as constituent fatty acids are not particularly limited. For example, oil rapeseed oil containing high percentage of unsaturated fatty acids having 22 carbon atoms, sardine, mackerel, saury, herring, An extremely hydrogenated oil obtained by completely hydrogenating fish oil such as anchovies, tuna and bonito can be preferably mentioned. In the present invention, these fats and oils may be used alone or in combination of two or more.
The saturated fatty acid having 22 carbon atoms, that is, behenic acid is obtained by completely hydrogenating an unsaturated fatty acid having 22 carbon atoms, for example, erucic acid which is a monounsaturated fatty acid having 22 carbon atoms.

本発明においては、これらの油脂を、前記のラードまたは分別ラードに加え、エステル交換反応を行うが、常法に従って行うことができる。このエステル交換はランダムエステル交換、あるいは位置特異的なエステル交換のどちらでも良い。触媒としてナトリウムメチラート等のアルカリ触媒を用いる方法、あるいはリパーゼ製剤等の酵素触媒を用いる方法のどちらを用いても構わない。油脂の使用量は、エステル交換して得られた油脂の融点が30〜50℃の範囲になるように適宜選定するのが有利である。このようにして、実質的にトランス脂肪酸を含まないエステル交換油脂が得られる。本発明においては、このエステル交換油脂は、その構成脂肪酸における、炭素数22の飽和脂肪酸の含有割合が好ましくは2〜15質量%、より好ましくは4〜10質量%であるものが、特に優れた機能を有する。したがって、該飽和脂肪酸の含有量が、上記範囲になるように、炭素数22の飽和脂肪酸を構成脂肪酸として含む油脂をエステル交換に使用すればよい。エステル交換油脂における上記炭素数22の飽和脂肪酸の含有量がこの範囲内であれば、品質改良効果が十分に発揮され、該油脂を使用したマーガリンやショートニングの口溶けが良好に保たれる。   In the present invention, these fats and oils are added to the lard or the fraction lard and subjected to a transesterification reaction, and can be performed according to a conventional method. This transesterification may be either random transesterification or regiospecific transesterification. Either a method using an alkali catalyst such as sodium methylate as a catalyst or a method using an enzyme catalyst such as a lipase preparation may be used. It is advantageous to appropriately select the amount of oil used so that the melting point of the oil obtained by transesterification is in the range of 30 to 50 ° C. In this way, a transesterified fat and oil substantially free of trans fatty acids is obtained. In the present invention, the transesterified oil / fat is particularly excellent in that the content ratio of the saturated fatty acid having 22 carbon atoms in the constituent fatty acid is preferably 2 to 15% by mass, more preferably 4 to 10% by mass. It has a function. Therefore, what is necessary is just to use the fats and oils which contain a C22 saturated fatty acid as a constituent fatty acid so that content of this saturated fatty acid may become the said range. If content of the said C22 saturated fatty acid in transesterified fats and oils exists in this range, the quality improvement effect will fully be exhibited and the melt of margarine and shortening using this fats and oils will be kept favorable.

(油脂(B))
本発明に用いる油脂(B)は、油脂(A)に添加してもホイップ性、可塑性を失うことなく、本発明のバタークリームの口溶けを改善する成分である。
発明に使用する油脂(B)は、パーム油を分別して得られる中融点部(パームミッドフラクション、以下、PMFとする。)である。PMFとしては、代表的なものとしてソフトパームミッドフラクション(以下、ソフトPMFとする。)とハードパームミッドフラクション(以下、ハードPMFとする。)が挙げられる。
ソフトPMFは、パーム油を分別処理して得られる軟質部(パームオレインと呼ばれることもある)を、更に分別処理して得られる硬質部のことあり、ヨウ素価は約40〜50である。
ハードPMFは、ソフトPMFを分別処理して得られる硬質部のことであり、ヨウ素価は約30〜40である。
また、本発明の油中水型乳化油脂組成物には、トランス脂肪酸が過度に生成しない程度にヨウ素価を0.5〜6程度下げる軽微な水素添加を施したPMFも好適に使用できるが、部分硬化油を使用しないという観点からは、水素添加を施さないPMFを使用することが好ましい。
(Oil and fat (B))
The fat (B) used in the present invention is a component that improves the melting of the butter cream of the present invention without losing the whipping property and plasticity even when added to the fat (A).
The fat (B) used in the invention is a medium melting point part (palm mid fraction, hereinafter referred to as PMF) obtained by fractionating palm oil. Typical examples of the PMF include a soft palm mid fraction (hereinafter referred to as soft PMF) and a hard palm mid fraction (hereinafter referred to as hard PMF).
Soft PMF is a hard part obtained by further subjecting a soft part (sometimes referred to as palm olein) obtained by fractionating palm oil to an iodine value of about 40-50.
Hard PMF is a hard part obtained by fractionating soft PMF and has an iodine value of about 30-40.
In addition, in the water-in-oil emulsified oil / fat composition of the present invention, PMF that has been subjected to slight hydrogenation that lowers the iodine value by about 0.5 to 6 to the extent that trans fatty acids are not excessively generated can be suitably used. From the viewpoint of not using partially hardened oil, it is preferable to use PMF that is not subjected to hydrogenation.

(バタークリーム用油中水型乳化油脂組成物)
本発明は、上記記載の油脂(A)と油脂(B)を少なくとも含む油中水型乳化油脂組成物である。ただし、実用上の観点から油脂(A)を25〜70質量%、好ましくは30〜50質量%、より好ましくは35〜45質量%含有し、油脂(B)を5〜30質量%、好ましくは10〜20質量%含むことが好ましい。油脂(A)が多すぎると口溶けが悪化し、少なすぎると十分なホイップ性を維持できない。また油脂(B)が多すぎるとグレイン発生や経時的硬化が抑えられず、保型性も低下する。一方で油脂(B)が少なすぎると良好な口溶けを発揮できない。
油脂(A)と油脂(B)の含有率は、油中水型乳化油脂組成物から、水や乳化剤の含有量を除いた値から算出される値である。
(Water-in-oil emulsified oil / fat composition for butter cream)
The present invention is a water-in-oil emulsified oil / fat composition containing at least the oil / fat (A) and the oil / fat (B) described above. However, from a practical viewpoint, the fat (A) is contained in an amount of 25 to 70% by mass, preferably 30 to 50% by mass, more preferably 35 to 45% by mass, and the fat or oil (B) in an amount of 5 to 30% by mass, preferably It is preferable to contain 10-20 mass%. If the oil (A) is too much, the melting of the mouth deteriorates, and if it is too little, sufficient whipping properties cannot be maintained. Moreover, when there are too many fats and oils (B), generation | occurrence | production of a grain and hardening with time cannot be suppressed, and shape retention property will also fall. On the other hand, when there is too little oil and fat (B), a good mouth melt cannot be exhibited.
The content rate of fats and oils (A) and fats and oils (B) is a value computed from the value remove | excluding the content of water and an emulsifier from the water-in-oil type emulsified fat composition.

(実質的にトランス脂肪酸とラウリン酸を含まない食用油脂(C))
本発明は、上記記載の油脂(A)と油脂(B)を少なくとも上記配合量で含む油中水型乳化油脂組成物である。すなわち、この2種の油脂のみからなるものであってもよいし、当該油脂と、これら以外の実質的にトランス脂肪酸とラウリン酸を含まない食用油脂(C)との混合物であってもよく、通常、マーガリンなどの油中水型乳化油脂組成物を製造する際には、上記混合物を用いてもよい。ここで、実質的にトランス脂肪酸とラウリン酸を含まない食用油脂(C)としては、ラウリン系油脂を除く、天然の動植物油脂、例えば常温で固体のパーム油、パームステアリン、牛脂、ラードおよびこれらの分別油脂や、常温で液体の大豆油、ナタネ油、米ぬか油、コーン油、ヒマワリ油、ハイオレイックヒマワリ油、サフラワー油、ハイオレイックサフラワー油、綿実油、魚油など、さらには、これらの動植物油脂を完全水添した油脂を挙げることができる。これらの実質的にトランス脂肪酸とラウリン酸を含まない食用油脂(C)は1種用いてもよいし、2種以上を組み合わせて用いてもよい。
実質的にトランス脂肪酸を含まないとは、油脂中のトランス脂肪酸が、2質量%以下、好ましくは1質量%以下、より好ましくは0.5質量%以下であることをいう。
実質的にラウリン酸を含まないとは、油脂中のラウリン酸が、2質量%以下、好ましくは1質量%以下、より好ましくは0.5質量%以下であることをいう。
(Edible oil and fat substantially free of trans fatty acid and lauric acid (C))
The present invention is a water-in-oil emulsified oil / fat composition containing at least the above-described oil / fat (A) and oil / fat (B) in the above-mentioned blending amount. That is, it may be composed only of these two types of fats and oils, and may be a mixture of the fats and oils and edible fats and oils (C) substantially free of trans fatty acids and lauric acid, Usually, when manufacturing a water-in-oil emulsified oil and fat composition such as margarine, the above mixture may be used. Here, as edible fats and oils (C) substantially free of trans fatty acid and lauric acid, natural animal and vegetable fats and oils excluding lauric fats and oils, such as palm oil, palm stearin, beef tallow, lard, and these which are solid at room temperature Soybean oil, rapeseed oil, rice bran oil, corn oil, sunflower oil, high oleic sunflower oil, safflower oil, high oleic safflower oil, cottonseed oil, fish oil, etc. The fats and oils which completely hydrogenated animal and vegetable fats and oils can be mentioned. These edible fats and oils (C) substantially free of trans fatty acid and lauric acid may be used singly or in combination of two or more.
The phrase “substantially free of trans fatty acid” means that the trans fatty acid in the fat is 2% by mass or less, preferably 1% by mass or less, more preferably 0.5% by mass or less.
The phrase “substantially free of lauric acid” means that the lauric acid in the fat is 2% by mass or less, preferably 1% by mass or less, more preferably 0.5% by mass or less.

これらの実質的にトランス脂肪酸とラウリン酸を含まない食用油脂(C)は、バタークリーム用油中水型乳化油脂組成物中に、実質的にトランス脂肪酸とラウリン酸を含まない油脂の合計として、または実質的にトランス脂肪酸を含まない油脂とラウリン酸を含まない油脂の合計含有量として、20〜70質量%が好ましく、35〜65質量%がより好ましく、40〜60質量%が更に好ましい。この範囲内であることによって、油脂(A)と油脂(B)を併用する効果が損なわれることなく発揮される。
実質的にトランス脂肪酸とラウリン酸を含まない食用油脂(C)の含有率は、油中水型乳化油脂組成物から、水や乳化剤の含有量を除いた値から算出される値である。
These edible fats and oils (C) substantially free of trans fatty acid and lauric acid are as a sum of fats and oils substantially free of trans fatty acid and lauric acid in the water-in-oil emulsified fat composition for butter cream. Alternatively, the total content of fats and oils substantially free of trans fatty acid and lauric acid is preferably 20 to 70% by mass, more preferably 35 to 65% by mass, and still more preferably 40 to 60% by mass. By being in this range, the effect of using the oil (A) and the oil (B) in combination is exhibited without being impaired.
The content of the edible fat / oil (C) substantially free of trans fatty acid and lauric acid is a value calculated from a value obtained by removing the water and emulsifier contents from the water-in-oil emulsified fat composition.

本発明のバタークリーム用油中水型乳化油脂組成物は、実質的にトランス脂肪酸とラウリン酸を含まないことが好ましい。
実質的にトランス脂肪酸を含まないとは、油脂組成物中のトランス脂肪酸が、2質量%以下、好ましくは1質量%以下、より好ましくは0.5質量%以下であることをいう。
実質的にラウリン酸を含まないとは、油脂組成物中のラウリン酸が、2質量%以下、好ましくは1質量%以下、より好ましくは0.5質量%以下であることをいう。
The water-in-oil emulsified oil / fat composition for butter cream of the present invention preferably contains substantially no trans fatty acid and lauric acid.
The phrase “substantially free of trans fatty acid” means that the trans fatty acid in the oil or fat composition is 2% by mass or less, preferably 1% by mass or less, more preferably 0.5% by mass or less.
“Substantially free of lauric acid” means that the lauric acid in the oil or fat composition is 2% by mass or less, preferably 1% by mass or less, more preferably 0.5% by mass or less.

また、本発明の可塑性油脂を用いて、油中水型乳化油脂組成物を製造する際には、所望により、一般的に食用油脂製品に使用されている他の原料、例えばグリセリン脂肪酸エステル、プロピレングリコール脂肪酸エステル、ソルビタン脂肪酸エステル、ショ糖脂肪酸エステル、リン脂質などの乳化剤、トコフェロール、L−アスコルビン酸パルミチン酸エステル、茶抽出物などの酸化防止剤、カロチンなどの着色料、脱脂粉乳、クリームなどの乳成分、食塩、酸味料、調味料、香料、重合リン酸塩などの乳化安定剤、増粘安定剤などを、適宜使用することができる。   In addition, when producing a water-in-oil emulsified oil / fat composition using the plastic oil / fat of the present invention, other raw materials generally used in edible oil / fat products, for example, glycerin fatty acid esters, propylene, are used as desired. Glycolic fatty acid esters, sorbitan fatty acid esters, sucrose fatty acid esters, emulsifiers such as phospholipids, tocopherols, L-ascorbic acid palmitic acid esters, antioxidants such as tea extracts, coloring agents such as carotene, skim milk powder, creams, etc. Emulsification stabilizers such as milk components, salt, acidulant, seasoning, fragrance, and polymerized phosphate, and thickening stabilizers can be used as appropriate.

本発明の油中水型乳化油脂組成物を製造する場合、その製造方法としては特に制限はなく、従来公知の方法を用いることができる。例えば、以下のような製造方法により製造することができる。
マーガリンの形態の油脂組成物の場合は、まず、連続相となる油脂成分を加熱溶解し、これに各種乳化剤を溶解もしくは分散させる。これに水を加え、ボテーター、コンビネーター、パーフェクター等により急冷捏和処理し、さらに場合によっては熟成(テンパリング)することによって得ることができる。このときの熟成温度は油脂組成により、混合された油脂の主要な固体脂の各結晶多型の融点、簡易的には混合油脂の融点、SFC/SFIなどにより適宜選択することが出来る。水相の含有量は、マーガリン形態の油脂組成物100質量部中に10〜15質量部であることが好ましい。さらに、油相にはトコフェロール、香料、着色料等、その他油溶性の添加物を、水相には、食塩、粉乳、濃縮乳、香料、呈味成分、その他水溶性添加物等を添加することができる。
When manufacturing the water-in-oil type emulsified oil-fat composition of this invention, there is no restriction | limiting in particular as a manufacturing method, A conventionally well-known method can be used. For example, it can be manufactured by the following manufacturing method.
In the case of an oil / fat composition in the form of margarine, first, an oil / fat component to be a continuous phase is dissolved by heating, and various emulsifiers are dissolved or dispersed therein. It can be obtained by adding water, quenching and kneading with a botator, a combinator, a perfector or the like, and further aging (tempering) in some cases. The aging temperature at this time can be appropriately selected depending on the oil composition, depending on the melting point of each crystal polymorph of the main solid fat of the mixed fat, simply the melting point of the mixed fat, SFC / SFI, and the like. The content of the aqueous phase is preferably 10 to 15 parts by mass in 100 parts by mass of the margarine oil composition. In addition, other oil-soluble additives such as tocopherols, fragrances, and coloring agents are added to the oil phase, and salt, powdered milk, concentrated milk, fragrances, flavoring ingredients, and other water-soluble additives are added to the aqueous phase. Can do.

油中水型乳化油脂組成物を製造する際に添加する乳化剤としては、グリセリン脂肪酸エステル、プロピレングリコール脂肪酸エステル、ソルビタン脂肪酸エステル、ショ糖脂肪酸エステル、リン脂質等の乳化剤が挙げられる。これらの乳化剤は、単独で用いることもでき、または2種以上を組み合わせて用いることもできる。   Examples of the emulsifier added when producing the water-in-oil emulsified oil / fat composition include glycerin fatty acid esters, propylene glycol fatty acid esters, sorbitan fatty acid esters, sucrose fatty acid esters, and phospholipids. These emulsifiers can be used alone or in combination of two or more.

(バタークリーム)
本発明のバタークリーム用油中水型乳化油脂組成物に水溶性成分や呈味成分等を加えて、これを起泡することにより、バタークリームを製造することができる。
水溶性成分や呈味成分としては、例えば、砂糖等の結晶状態の糖類、シロップ、水飴等の液状の糖類、粉乳や練乳等の乳製品類、粉末卵黄等の卵類、ココアパウダー等のカカオ製品類、果肉ジャム類、果汁類、チーズ類、ピーナッツペースト等のナッツ類を挙げることができるが、特に限定されるものではない。
(Butter cream)
A butter cream can be manufactured by adding a water-soluble component, a taste component, etc. to the water-in-oil emulsified oil / fat composition for butter cream according to the present invention and foaming it.
Examples of water-soluble ingredients and taste ingredients include sugars and other crystalline sugars, liquid sugars such as syrup and syrup, dairy products such as milk powder and condensed milk, eggs such as powdered egg yolk, and cocoa powder such as cocoa powder. Although nuts, such as products, fruit jams, fruit juices, cheeses, peanut paste, can be mentioned, it is not specifically limited.

バタークリームを起泡するためには、撹拌/混合装置であれば特に限定されるものではなく、例えば、縦型ミキサー、連続ホイップマシーン等を用いて行うことができる。   The foaming of the butter cream is not particularly limited as long as it is a stirring / mixing device, and can be performed using, for example, a vertical mixer, a continuous whipping machine or the like.

また、バタークリームを製造する場合、原料となる本発明のバタークリーム用油脂組成物はバタークリーム100質量部中30〜90質量部含有させることが好ましい。30質量部より少ないとバタークリームの乳化状態が反転したり、バタークリームの保型性が悪くなったりする。また、90質量部より多いと、バタークリームが油っぽくなり、風味が悪化しやすい。   Moreover, when manufacturing a butter cream, it is preferable to contain the oil-fat composition for butter cream of this invention used as a raw material 30-90 mass parts in 100 mass parts of butter cream. When the amount is less than 30 parts by mass, the emulsified state of the butter cream is reversed, or the shape retention of the butter cream is deteriorated. Moreover, when more than 90 mass parts, a butter cream will become oily and a flavor will deteriorate easily.

以下に、実施例および比較例を挙げ、本発明をさらに詳しく説明する。 Hereinafter, the present invention will be described in more detail with reference to Examples and Comparative Examples.

〔油脂(A)の製造〕
本発明では油脂(A)として以下の製造例A−1〜A−4、および、a−1〜a−4について、下記組成の混合油脂をナトリウムメチラートを用いた化学的エステル交換法により製造した。
製造例A−1
ラード; 95質量部
ハイエルシン菜種極度硬化油; 5質量部
製造例A−2
ラード; 90質量部
ハイエルシン菜種極度硬化油; 10質量部
製造例A−3
ラード分別油低融点画分; 80質量部
ハイエルシン菜種極度硬化油; 20質量部
製造例A−4
ラード分別油低融点画分; 70質量部
ハイエルシン菜種極度硬化油; 30質量部
製造例a−1
ラード;95質量部
ハイエルシン菜種極度硬化油; 5質量部
ただし、エステル交換未実施
製造例a−2
ラード; 95質量部
菜種極度硬化油; 5質量部
製造例a−3
ラード; 100質量部
製造例a−4
パームオレイン; 100質量部
[Manufacture of fats and oils (A)]
In the present invention, as fats and oils (A), the following production examples A-1 to A-4 and a-1 to a-4 are produced by a chemical transesterification method using sodium methylate for mixed fats and oils having the following composition. did.
Production Example A-1
Lard; 95 parts by mass Hyelsin rapeseed extremely hardened oil; 5 parts by mass Production Example A-2
Lard; 90 parts by mass Hyelsin rapeseed extremely hardened oil; 10 parts by mass Production Example A-3
Lard fractionation oil low melting point fraction; 80 parts by mass Hyelsin rapeseed extremely hardened oil; 20 parts by mass Production Example A-4
Lard fractionated oil low melting point fraction; 70 parts by mass Hyelin rapeseed extremely hardened oil; 30 parts by mass Production Example a-1
Lard: 95 parts by mass Hyelsin rapeseed extremely hardened oil; 5 parts by mass However, transesterification not carried out Production Example a-2
95 parts by mass Rapeseed extremely hardened oil; 5 parts by mass Production Example a-3
Lard; 100 parts by mass Production Example a-4
Palm olein; 100 parts by mass

製造例A−1〜A−4、および、a−1〜a−4の脂肪酸組成を基準油脂分析法2.4.2.1−1996にて分析を行った結果、炭素数22の飽和脂肪酸をA−1およびa−1は2.4質量%、A−2は質量4.8%、A−3は質量9.6%、A−4は14.4質量%含有し、a−2〜a−4の含有量は1質量%未満だった。   As a result of analyzing the fatty acid composition of Production Examples A-1 to A-4 and a-1 to a-4 by the standard fat analysis method 2.4.2.1-1996, a saturated fatty acid having 22 carbon atoms was obtained. A-1 and a-1 are 2.4% by mass, A-2 is 4.8% by mass, A-3 is 9.6% by mass, A-4 is 14.4% by mass, a-2 The content of ~ a-4 was less than 1% by mass.

〔油脂(B)および類似物の準備〕
本発明では油脂(B)として下記のB−1、B−2を、および油脂(B)として類似物のb−1を使用した。
製造例B−1
ソフトPMF(ヨウ素価45)
製造例B−2
ハードPMF(ヨウ素価35)
製造例b−1
パームオレイン(ヨウ素価56)
[Preparation of fat (B) and the like]
In the present invention, the following B-1 and B-2 were used as the fat / oil (B), and the similar b-1 was used as the fat / oil (B).
Production Example B-1
Soft PMF (Iodine value 45)
Production Example B-2
Hard PMF (Iodine value 35)
Production Example b-1
Palm olein (Iodine number 56)

(実施例1〜23、比較例1〜15)
表1〜表4に実施例および比較例に使用する成分の組成を示す。混合した油脂に乳化剤を溶解し、水を加え、60℃で乳化した後、急冷混練し油中水型乳化油脂組成物を得た。実施例1〜8、11〜16、20〜21および比較例1〜5、9〜15は20℃で、実施例9〜10、17〜19、22〜23および比較例6〜8は25℃で、24時間保管後、7℃で24時間保管したのち、下記の性能評価を実施した。
(Examples 1-23, Comparative Examples 1-15)
Tables 1 to 4 show the compositions of the components used in the examples and comparative examples. An emulsifier was dissolved in the mixed fat and oil, water was added, and the mixture was emulsified at 60 ° C., and then rapidly cooled and kneaded to obtain a water-in-oil type emulsified fat composition. Examples 1-8, 11-16, 20-21 and Comparative Examples 1-5, 9-15 are 20 ° C., Examples 9-10, 17-19, 22-23 and Comparative Examples 6-8 are 25 ° C. Then, after storage for 24 hours, after storage at 7 ° C. for 24 hours, the following performance evaluation was performed.

性能評価は下記の通り、実施した。
(グレイン抑制)
製造した油中水型乳化油脂組成物を7℃保管30日目に、実施例1〜8、11〜16、20〜21および比較例1〜5、9〜15は20℃恒温槽にて、実施例9〜10、17〜19、22〜23および比較例6〜8は25℃恒温槽にて5時間調温後、油脂組成物の表面付近および内部から5gずつサンプリングし、サンプリング下油脂組成物をステンレス製のへらにて薄く延ばし、グレインの発生を目視にて確認し、下記の3段階で評価した。
◎:グレインの発生なし
○:小さなグレインの数が10個未満
×:小さなグレインが10個以上や大きなグレインがある
The performance evaluation was performed as follows.
(Grain suppression)
The manufactured water-in-oil emulsified oil / fat composition was stored at 7 ° C on the 30th day, and Examples 1-8, 11-16, 20-21 and Comparative Examples 1-5, 9-15 were in a 20 ° C constant temperature bath. In Examples 9 to 10, 17 to 19, 22 to 23 and Comparative Examples 6 to 8, after 5 hours of temperature adjustment in a thermostatic bath at 25 ° C., 5 g was sampled from the vicinity and the inside of the oil and fat composition, and the oil and fat composition under sampling was sampled. The product was thinly stretched with a stainless steel spatula, and the occurrence of grains was visually confirmed and evaluated in the following three stages.
◎: No grain generation ○: The number of small grains is less than 10 ×: There are 10 or more small grains or large grains

(経時的硬化抑制)
製造した油中水型乳化油脂組成物を硬度測定用容器に充填し、実施例1〜8、11〜16、20〜21および比較例1〜5、9〜15は20℃で、実施例9〜10、17〜19、22〜23および比較例6〜8は25℃で24時間さらに7℃で24時間保管した後に、実施例1〜8、11〜16、20〜21および比較例1〜5、9〜15は10℃の恒温水槽にて、実施例9〜10、17〜19、22〜23および比較例6〜8は15℃の恒温水槽にて24時間浸漬させレオメーター((株)サン科学製)にてマーガリンの硬度を測定した(硬度1)。同様に実施例1〜8、11〜16、20〜21および比較例1〜5、9〜15は20℃で、実施例9〜10、17〜19、22〜23および比較例6〜8は25℃で24時間保管した後に、7℃で20日間保管し、さらに実施例1〜8、11〜16、20〜21および比較例1〜5、9〜15は10℃の恒温水槽にて、実施例9〜10、17〜19、22〜23および比較例6〜8は15℃の恒温水槽にて24時間浸漬させ、同様に硬度を測定した(硬度2)。
(硬度2)/(硬度1)で示される数値によって、下記の3段階で評価した。
◎:1.5未満
○:1.5以上2.0未満
×:2.0以上
(Inhibition of curing over time)
The manufactured water-in-oil emulsified oil / fat composition was filled into a container for hardness measurement, and Examples 1 to 8, 11 to 16, 20 to 21 and Comparative Examples 1 to 5 and 9 to 15 were at 20 ° C. -10, 17-19, 22-23 and Comparative Examples 6-8 were stored at 25 ° C. for 24 hours and further at 7 ° C. for 24 hours, then Examples 1-8, 11-16, 20-21 and Comparative Examples 1 Nos. 5 and 9 to 15 are 10 ° C. constant temperature water baths, and Examples 9 to 10, 17 to 19, 22 to 23 and Comparative Examples 6 to 8 are immersed in a 15 ° C. constant temperature water bath for 24 hours. ) The hardness of margarine was measured at 1). Similarly Examples 1-8, 11-16, 20-21 and Comparative Examples 1-5, 9-15 are 20 degreeC, Examples 9-10, 17-19, 22-23 and Comparative Examples 6-8 are After storing at 25 ° C. for 24 hours, it was stored at 7 ° C. for 20 days, and Examples 1 to 8, 11 to 16, 20 to 21 and Comparative Examples 1 to 5 and 9 to 15 were in a constant temperature water bath at 10 ° C. Examples 9 to 10, 17 to 19, 22 to 23 and Comparative Examples 6 to 8 were immersed in a constant temperature water bath at 15 ° C. for 24 hours, and the hardness was similarly measured (hardness 2).
The evaluation was made according to the following three levels according to the numerical value represented by (hardness 2) / (hardness 1).
◎: Less than 1.5 ○: 1.5 or more and less than 2.0 ×: 2.0 or more

(ホイップ性)
製造した油中水型乳化油脂組成物を実施例1〜8、11〜16、20〜21および比較例1〜5、9〜15は15℃、実施例9〜10、17〜19、22〜23および比較例6〜8は20℃に調温後、500g計量しフラットビーターを装着したホバートミキサーにて、低速で30秒、中速で1分攪拌する。ソルビトールを750g加え、低速で30秒、中速で1分攪拌する。水を300g加え、低速で30秒攪拌する。さらに中速で攪拌し、水がホイップクリームに吸水されたことを目視で確認できた時点で攪拌を止める。
(調温後の定容積重量)/(吸水後の定容積重量)で示される数値によって、下記の3段階で評価した。
◎:0.9未満
○:0.9以上1.0未満
×:1.0以上
(Whipped)
The water-in-oil type emulsified oil / fat composition produced was prepared at 15 ° C. for Examples 1-8, 11-16, 20-21 and Comparative Examples 1-5, 9-15, Examples 9-10, 17-19, 22-22. In No. 23 and Comparative Examples 6 to 8, after adjusting the temperature to 20 ° C., 500 g was weighed and stirred at a low speed for 30 seconds and at a medium speed for 1 minute in a Hobart mixer equipped with a flat beater. Add 750 g of sorbitol and stir for 30 seconds at low speed and 1 minute at medium speed. Add 300 g of water and stir at low speed for 30 seconds. Further, the mixture is stirred at a medium speed, and the stirring is stopped when it can be visually confirmed that the water has been absorbed into the whipped cream.
The following three levels were evaluated based on the numerical value represented by (constant volume weight after temperature adjustment) / (constant volume weight after water absorption).
◎: Less than 0.9 ○: 0.9 or more and less than 1.0 ×: 1.0 or more

(保型性)
ホイップ性の評価と同様に吸水させたホイップクリームを絞り袋に入れ、花型で射出し、25℃で24時間保管した後の外観を下記の3段階で評価した。
◎:表面につやがあり、エッジがシャープで良好な状態
○:良好な状態
×:型崩れやエッジの消失、離水など何らかの問題がある状態
(Shape retention)
In the same manner as the evaluation of the whipping property, the whipped cream soaked in water was put into a squeeze bag, injected in a flower shape, and stored for 24 hours at 25 ° C., and the appearance was evaluated in the following three stages.
A: The surface is glossy and the edge is sharp and in good condition. ○: The object is in good condition. X: There are some problems such as loss of shape, loss of edge, and water separation.

(口溶け)
ホイップ性の評価と同様に吸水させたホイップクリームを食し、その口溶けを以下の評価基準で評価した。
◎:最良
○:良好
×:不良
(Melting mouth)
The whipped cream that had absorbed water was eaten in the same manner as the evaluation of whipping properties, and the melting of the mouth was evaluated according to the following evaluation criteria.
◎: Best ○: Good ×: Bad

Figure 2019149988
Figure 2019149988

Figure 2019149988
Figure 2019149988

実施例1〜19はグレイン抑制効果、経時的硬化抑制効果、ホイップ性、保型性、口溶けの全ての評価項目で良好な結果が得られ、バタークリーム用油中水型乳化油脂組成物として優れた機能を有していることが明らかとなった。
本発明に用いる油脂(A)に相当するA−1を35〜55質量%含有し、かつ本発明に用いる油脂(B)に相当するB−1を10〜20質量%含む実施例3〜7および14と15は特に優れた評価結果を示した。
Examples 1 to 19 are excellent as a water-in-oil emulsified oil / fat composition for butter cream, with good results obtained in all the evaluation items of grain suppression effect, temporal curing suppression effect, whipability, shape retention, and mouth melting. It became clear that it has a function.
Examples 3 to 7 containing 35 to 55% by mass of A-1 corresponding to the oil (A) used in the present invention and 10 to 20% by mass of B-1 corresponding to the oil (B) used in the present invention. And 14 and 15 showed particularly excellent evaluation results.

Figure 2019149988
Figure 2019149988

比較例1〜2は油脂(A)が少ないため経時的硬化抑制効果やグレイン発生抑制効果が認められず、またホイップ性が発揮されなかった。一方で比較例5〜6は、油脂(A)が多すぎるため、良好な口溶けが得られなかった。
比較例3〜4は油脂(B)であるPMFが少ないため口溶けが十分ではなく、一方比較例7〜8は多すぎるため、経時的硬化やグレインの発生の程度がひどく、特に比較例7では保型性も不十分であった。
In Comparative Examples 1 and 2, since there were few fats and oils (A), the time-dependent curing inhibitory effect and the grain generation inhibitory effect were not recognized, and the whipping property was not exhibited. On the other hand, since comparative examples 5-6 had too many fats and oils (A), favorable mouth melt | dissolution was not obtained.
In Comparative Examples 3-4, the amount of PMF which is the fat (B) is small, so the melting of the mouth is not sufficient. On the other hand, Comparative Examples 7-8 are too much, and the degree of time-dependent curing and grain generation is severe. The shape retention was also insufficient.

Figure 2019149988
Figure 2019149988

実施例20は本発明に用いる油脂(B)に相当する油脂としてハードPMFであるB−2を使用し、実施例21〜23は炭素数22の飽和脂肪酸量の異なる、本発明に用いる油脂(A)に相当するA−2〜A−4を使用したバタークリーム用油中水型乳化油脂組成物である。この実施例20〜23はいずれもグレイン抑制効果、経時的硬化抑制効果、ホイップ性、保型性、口溶けの全ての評価項目で良好な結果が得られ、バタークリーム用油中水型乳化油脂組成物として優れた機能を有していることが明らかとなった。
炭素数22の飽和脂肪酸を4〜10%含有する本発明に用いる油脂(A)に相当するA−2を35〜40質量%含有し、かつ本発明に用いる油脂(B)に相当するB−1を10質量%含む実施例20〜21は特に優れた評価結果を示した。
Example 20 uses B-2 which is hard PMF as an oil and fat corresponding to the oil and fat (B) used in the present invention, and Examples 21 to 23 are different in the amount of saturated fatty acid having 22 carbon atoms and used in the present invention ( It is a water-in-oil emulsified oil / fat composition for butter cream using A-2 to A-4 corresponding to A). In Examples 20 to 23, good results were obtained in all the evaluation items of grain suppression effect, time-dependent curing suppression effect, whipping property, shape retention property, and mouth melting, and a water-in-oil emulsified fat composition for butter cream. It became clear that it has an excellent function as a product.
B-2 corresponding to 35 to 40% by mass of A-2 corresponding to the fat (A) used in the present invention containing 4 to 10% of saturated fatty acid having 22 to 22 carbon atoms and corresponding to the fat (B) used in the present invention. Examples 20-21 containing 10% by mass of 1 showed particularly excellent evaluation results.

比較例9は炭素数22の飽和脂肪酸を含む油脂を使用しているものの、エステル交換されていないためか、経時的硬化抑制効果やグレイン発生抑制効果が認められず、口溶けも十分ではなかった。
比較例10〜12は炭素数22の飽和脂肪酸を含む油脂を使用しないため、経時的硬化抑制効果やグレイン発生抑制効果および良好なホイップ性が認められず、比較例10については口溶けも十分ではなかった。
Although the comparative example 9 uses fats and oils containing a saturated fatty acid having 22 carbon atoms, the effect of inhibiting the curing over time and the effect of suppressing the generation of grains were not observed because of the lack of transesterification, and the dissolution in the mouth was not sufficient.
Since Comparative Examples 10 to 12 do not use fats and oils containing saturated fatty acids having 22 carbon atoms, the effect of suppressing time-dependent hardening, the effect of suppressing grain generation and good whipping properties are not recognized, and the melting of mouth for Comparative Example 10 is not sufficient. It was.

比較例13および14については、ホイップ性は発揮されたものの、炭素数22の飽和脂肪酸を含む油脂を使用しないため、経時的硬化抑制効果やグレイン発生抑制効果が認められなかった。
比較例15はパーム油を分別して得られる中融点部を用いていないため、経時的硬化抑制効果やグレイン発生抑制効果は認められ、ホイップ性も保型性も発揮されたが、十分な口溶けは得られなかった。
About Comparative Examples 13 and 14, although the whip property was exhibited, since the fats and oils containing a C22 saturated fatty acid were not used, the temporal hardening inhibitory effect and the grain generation inhibitory effect were not recognized.
Since Comparative Example 15 does not use the middle melting point part obtained by fractionating palm oil, the effect of suppressing hardening over time and the effect of suppressing grain generation were observed, and whipability and shape retention were also exhibited, It was not obtained.

(実施例24〜29)
表5に実施例24〜29に使用する成分の組成を示す。混合した油脂に乳化剤を溶解し、水を加え、60℃で乳化した後、急冷混練し油中水型乳化油脂組成物を得た。実施例24〜26は20℃で、実施例27〜29は25℃で、24時間保管後、7℃で24時間保管したのち、下記の通り性能評価を実施した。
(Examples 24-29)
Table 5 shows the composition of the components used in Examples 24-29. An emulsifier was dissolved in the mixed fat and oil, water was added, and the mixture was emulsified at 60 ° C., and then rapidly cooled and kneaded to obtain a water-in-oil type emulsified fat composition. Examples 24-26 were 20 degreeC, Example 27-29 was 25 degreeC, and after storing for 24 hours, after storing for 24 hours at 7 degreeC, performance evaluation was implemented as follows.

性能評価は下記の通り、実施した。
(グレイン抑制)
製造した油中水型乳化油脂組成物を7℃保管30日目に、実施例24〜26は20℃恒温槽にて、実施例27〜29は25℃恒温槽にて5時間調温後、油脂組成物の表面付近および内部から5gずつサンプリングし、サンプリング下油脂組成物をステンレス製のへらにて薄く延ばし、グレインの発生を目視にて確認し、下記の3段階で評価した。
◎:グレインの発生なし
○:小さなグレインの数が10個未満
×:小さなグレインが10個以上や大きなグレインがある
The performance evaluation was performed as follows.
(Grain suppression)
The manufactured water-in-oil emulsified oil / fat composition was stored at 7 ° C. on the 30th day, and after adjusting the temperature for Examples 24 to 26 in a 20 ° C. thermostatic bath and Examples 27 to 29 in a 25 ° C. thermostatic bath for 5 hours, Samples of 5 g were sampled from the vicinity and the inside of the oil and fat composition, and the sampled oil and fat composition was thinly extended with a stainless steel spatula, and the occurrence of grains was visually confirmed and evaluated in the following three stages.
◎: No grain generation ○: The number of small grains is less than 10 ×: There are 10 or more small grains or large grains

(経時的硬化抑制)
製造した油中水型乳化油脂組成物を硬度測定用容器に充填し、25℃で24時間さらに7℃で24時間保管した後に、実施例24〜26は15℃の恒温水槽にて、実施例27〜29は20℃の恒温水槽にて24時間浸漬させレオメーター((株)サン科学製)にてマーガリンの硬度を測定した(硬度1)。同様に25℃で24時間保管した後に、7℃で20日間保管し、さらに実施例24〜26は15℃の恒温水槽にて、実施例27〜29は20℃の恒温水槽にて24時間浸漬させ、同様に硬度を測定した(硬度2)。
(硬度2)/(硬度1)で示される数値によって、下記の3段階で評価した。
◎:1.5未満
○:1.5以上2.0未満
×:2.0以上
(Inhibition of curing over time)
After the water-in-oil type emulsified oil / fat composition thus prepared was filled in a hardness measurement container and stored at 25 ° C. for 24 hours and further at 7 ° C. for 24 hours, Examples 24-26 are examples of a 15 ° C. constant temperature water bath. Nos. 27 to 29 were immersed in a constant temperature water bath at 20 ° C. for 24 hours, and the hardness of margarine was measured with a rheometer (manufactured by Sun Kagaku Co., Ltd.) (hardness 1). Similarly, after storing at 25 ° C. for 24 hours, it was stored at 7 ° C. for 20 days. Examples 24-26 were immersed in a constant temperature water bath at 15 ° C., and Examples 27-29 were immersed in a constant temperature water bath at 20 ° C. for 24 hours. The hardness was measured in the same manner (hardness 2).
The evaluation was made according to the following three levels according to the numerical value represented by (hardness 2) / (hardness 1).
◎: Less than 1.5 ○: 1.5 or more and less than 2.0 ×: 2.0 or more

(ホイップ性)
製造した油中水型乳化油脂組成物を実施例24〜26は20℃、実施例27〜29は25℃に調温後、500g計量しフラットビーターを装着したホバートミキサーにて、低速で30秒、中速で2分30秒攪拌する。還元澱粉糖化物を550g、ジャムを50g加え、低速で30秒、中速で30秒攪拌する。0.4質量%クエン酸水溶液を300g加え、低速で攪拌し、水がホイップクリームに吸水されたことを目視で確認できた時点で攪拌を止める。中速でさらに30秒攪拌した後、定容積重量を測定した。
(調温後の定容積重量)/(吸水後の定容積重量)で示される数値によって、下記の3段階で評価した。
◎:0.9未満
○:0.9以上1.0未満
×:1.0以上
(Whipped)
The water-in-oil type emulsified oil / fat composition thus prepared was adjusted to 20 ° C. in Examples 24-26 and 25 ° C. in Examples 27-29, and then weighed 500 g, and then 30 seconds at low speed in a Hobart mixer equipped with a flat beater. Stir at medium speed for 2 minutes 30 seconds. Add 550 g of reduced starch saccharified product and 50 g of jam, and stir for 30 seconds at low speed and 30 seconds at medium speed. Add 300 g of 0.4 mass% citric acid aqueous solution, stir at low speed, and stop stirring when it is confirmed visually that water has been absorbed into the whipped cream. After stirring for 30 seconds at medium speed, the constant volume weight was measured.
The following three levels were evaluated based on the numerical value represented by (constant volume weight after temperature adjustment) / (constant volume weight after water absorption).
◎: Less than 0.9 ○: 0.9 or more and less than 1.0 ×: 1.0 or more

(保型性)
ホイップ性の評価と同様に吸水させたホイップクリームを絞り袋に入れ、花型で射出し、実施例24〜26は25℃、実施例27〜29は30℃で24時間保管した後の外観を下記の3段階で評価した。
◎:表面につやがあり、エッジがシャープで良好な状態
○:良好な状態
×:型崩れやエッジの消失、離水など何らかの問題がある状態
(Shape retention)
In the same manner as the evaluation of whipping property, the whipped cream soaked in water is put into a squeeze bag and injected in a flower shape. Examples 24 to 26 have an appearance after being stored at 25 ° C. and Examples 27 to 29 at 30 ° C. for 24 hours. Evaluation was made in the following three stages.
A: The surface is glossy and the edge is sharp and in good condition. ○: The object is in good condition. X: There are some problems such as loss of shape, loss of edge, and water separation.

(口溶け)
ホイップ性の評価と同様に吸水させたホイップクリームを食し、その口溶けを以下の評価基準で評価した。
◎:最良
○:良好
×:不良
(Melting mouth)
The whipped cream that had absorbed water was eaten in the same manner as the evaluation of whipping properties, and the melting of the mouth was evaluated according to the following evaluation criteria.
◎: Best ○: Good ×: Bad

Figure 2019149988
Figure 2019149988

実施例24〜29は食用油脂(C)としてパームステアリンを使用して、油中水型乳化油脂組成物としての硬度を高めた組成であるが、全評価項目で良好な結果が得られ、バタークリーム用油中水型乳化油脂組成物として優れた機能を有していることが明らかとなった。   Examples 24-29 are the composition which increased the hardness as a water-in-oil type emulsified oil-fat composition using palm stearin as edible oil-fat (C), but a favorable result was obtained by all the evaluation items, butter It became clear that it has the function outstanding as a water-in-oil type emulsified oil-fat composition for creams.

Claims (4)

下記の油脂(A)および油脂(B)を含有し、油脂(A)の含有量が25〜70質量%、油脂(B)の含有量が5〜30質量%であるバタークリーム用油中水型乳化油脂組成物。
油脂(A):ラードまたは分別ラードと、炭素数22の飽和脂肪酸を構成脂肪酸として含む油脂とのエステル交換油脂
油脂(B):パーム油を分別して得られる中融点部
Oil-in-water for butter cream containing the following fats and oils (A) and fats and oils (B), wherein the content of fats and oils (A) is 25 to 70% by mass and the content of fats and oils (B) is 5 to 30% by mass. Type emulsified oil and fat composition.
Fats and oils (A): Lard or fractionated lard and transesterified fats and oils and fats and oils containing saturated fatty acids having 22 carbon atoms as constituent fatty acids (B): Middle melting point part obtained by fractionating palm oil
油脂(A)の構成脂肪酸における、炭素数22の飽和脂肪酸の含有割合が2〜15質量%である、請求項1に記載のバタークリーム用油中水型乳化油脂組成物。   The water-in-oil type emulsified oil-fat composition for butter creams of Claim 1 whose content rate of a C22 saturated fatty acid in the constituent fatty acid of fats and oils (A) is 2-15 mass%. 更に、実質的にトランス脂肪酸とラウリン酸を含まない食用油脂(C)を20〜70質量%含有する、請求項1または2に記載のバタークリーム用油中水型乳化油脂組成物。   Furthermore, the water-in-oil type emulsion oil-fat composition for butter creams of Claim 1 or 2 which contains 20-70 mass% of edible fats and oils (C) which does not contain trans fatty acid and lauric acid substantially. 請求項1〜3のいずれか1項に記載のバタークリーム用油中水型乳化油脂組成物を30〜90質量%含むバタークリーム。

The butter cream containing 30-90 mass% of the water-in-oil type emulsified oil-fat composition for butter creams of any one of Claims 1-3.

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