JP2019131248A - Multiple-bottle made of polyester resin and its manufacturing method - Google Patents

Multiple-bottle made of polyester resin and its manufacturing method Download PDF

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JP2019131248A
JP2019131248A JP2018015258A JP2018015258A JP2019131248A JP 2019131248 A JP2019131248 A JP 2019131248A JP 2018015258 A JP2018015258 A JP 2018015258A JP 2018015258 A JP2018015258 A JP 2018015258A JP 2019131248 A JP2019131248 A JP 2019131248A
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bottle
container body
inner container
outer shell
polyester resin
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晃広 山口
Akihiro Yamaguchi
晃広 山口
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Hokkaican Co Ltd
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Abstract

To provide a multiple-bottle made of polyester resin of which the inner container body is easy to be removed from the outer shell bottle and which is easy to be volume reduction deformed.SOLUTION: A multiple-bottle made of polyester resin 1 comprises: an inner container body 3 which has an outer shell bottle 2 having an outer mouth part 4 and an outer shell bottle body 21, a cylindrical inner mouth part 13 provided in the outer mouth part 4 of the outer shell bottle 2, an inner container body 14 connected to the inner mouth part 13 and conforming to the inner shape of the outer shell bottle 2 and is deformed by external pressure; an air path 19 which is formed between the outer mouth part 4 and the inner mouth part 13 and introduces outside air between the outer shell bottle 2 and the inner container body 3; the outer shell bottle body 21 has a shoulder part 5, a body part 6 and a bottom part 7. The inner container body 14 is formed to be thinner than the outer shell bottle body, and an unevenly engraved concave and convex pattern 26 is provided in the part of the inner container body 14 corresponding to the shoulder 5.SELECTED DRAWING: Figure 2

Description

本発明は、外殻ボトル内に配置された内容器体を備えるポリエステル樹脂製多重ボトル及びその製造方法に関する。   TECHNICAL FIELD The present invention relates to a polyester resin multiple bottle including an inner container body disposed in an outer shell bottle and a method for manufacturing the same.

従来、外圧に対して原形復帰可能な外殻ボトルの内部に、外圧による減容により変形する(以下、「減容変形」ということがある)内容器体を配置し、該外殻ボトルと該内容器体との間に外気が導入されるようにした合成樹脂製多重ボトルが知られている(例えば、特許文献1、2参照)。   Conventionally, an inner container body that is deformed by volume reduction due to external pressure (hereinafter sometimes referred to as “volumetric deformation”) is disposed inside an outer shell bottle that can be restored to its original shape against external pressure, Synthetic resin multiple bottles are known in which outside air is introduced between the inner container body (see, for example, Patent Documents 1 and 2).

合成樹脂製多重ボトルは、外殻ボトルの胴部を押圧することにより、内容器体を減容変形させて内容器体に収容されている内容物を注出する一方、押圧が解除されると別途設けられた逆止弁等の作用により外殻ボトルと内容器体との間に外気が導入される。この結果、外気圧により外殻ボトルが原形復帰する一方、内容器体は減容変形された状態が維持される。このようにするときには、内容器体内に外気が侵入することが無いので、内容器体内に収容されている内容物が酸化等により変質することを防止することができる。   When the plastic multi-bottle is pressed against the body part of the outer shell bottle, the inner container body is reduced in volume and the contents contained in the inner container body are poured out, while the pressure is released. Outside air is introduced between the outer shell bottle and the inner container body by the action of a check valve provided separately. As a result, the outer shell bottle is restored to its original shape by the external air pressure, while the inner container body is maintained in the volume-reduced deformation state. When doing so, since the outside air does not enter the inner container body, the contents stored in the inner container body can be prevented from being altered by oxidation or the like.

特開2013−245010号公報JP2013-245010A 特開2010−082916号公報JP 2010-082916 A

多重ボトルとしては従来減容変形が容易な軟質のポリエチレン樹脂製多重ボトルが実用化されているが、ポリエステル樹脂(例えば、ポリエチレンテレフタレート樹脂)は、ポリエチレン樹脂と比較して容器の透明感又は内容物の香味の保持性などが優れているため、多重ボトルもポリエチレン樹脂に変えてポリエステル樹脂で成形することが考えられる。   Conventionally, multiple bottles made of soft polyethylene resin, which can be easily reduced in volume, have been put to practical use as a multiple bottle. Polyester resins (for example, polyethylene terephthalate resin) are more transparent in container or content than polyethylene resin. It is conceivable that the multiple bottles may be molded from a polyester resin instead of a polyethylene resin.

しかしながら、多重ボトルをポリエステル樹脂で成形する場合には、内容器体本体が外殻ボトルの内面に張り付いて外殻ボトルと内容器体本体との間に空気が入り難いという問題がある。また、ポリエステル樹脂では、ポリエチレン樹脂と比較して柔軟性が劣るため、内容器体本体が減容変形し難いという問題がある。   However, when the multiple bottle is molded of polyester resin, there is a problem that the inner container body sticks to the inner surface of the outer shell bottle and it is difficult for air to enter between the outer shell bottle and the inner container body. Further, since the polyester resin is inferior in flexibility as compared with the polyethylene resin, there is a problem that the inner container body is hardly deformed by volume reduction.

本発明は、以上の点に鑑み、内容器体本体が外殻ボトルから剥離し易く、減容変形し易いポリエステル樹脂脂製多重ボトル及びその製造方法を提供することを目的とする。   In view of the above points, an object of the present invention is to provide a multi-bottle made of polyester resin fats and a method for producing the same, in which the inner container body is easily peeled off from the outer shell bottle and is easily reduced in volume.

[1]上記目的を達成するため、本発明は、
円筒状の外口部と、該外口部に連接する外殻ボトル本体と、を有し、外圧に対して原形復帰可能なポリエステル樹脂製の外殻ボトルと、
前記外殻ボトルの前記外口部内に配設される円筒状の内口部と、該内口部に連接し前記外殻ボトルの内面形状に沿う形状の内容器体本体と、を有し、外圧により変形するポリエステル樹脂製の内容器体と、
前記外口部と前記内口部との間に形成されて前記外殻ボトルと前記内容器体との間に外気を導入する通気路と、を備え、
前記外殻ボトル本体は、前記外口部に連接する肩部と、該肩部に連接する胴部と、該胴部に連接する底部と、を備え、
前記外殻ボトルと前記内容器体とがブロー成形にて同時に成形されたポリエステル樹脂製多重ボトルであって、
前記内容器体本体は、前記外殻ボトル本体よりも薄肉であり、
前記肩部及び前記肩部に対応する前記内容器体本体の部分には凹凸模様が設けられていることを特徴とする。
[1] In order to achieve the above object, the present invention provides:
A cylindrical outer mouth portion, and an outer shell bottle main body connected to the outer mouth portion, and an outer shell bottle made of a polyester resin capable of returning to its original shape against an external pressure;
A cylindrical inner mouth portion disposed in the outer mouth portion of the outer shell bottle, and an inner container body body connected to the inner mouth portion and conforming to the inner surface shape of the outer shell bottle, An inner container body made of polyester resin deformed by external pressure;
An air passage formed between the outer mouth portion and the inner mouth portion for introducing outside air between the outer shell bottle and the inner container body,
The outer shell bottle body includes a shoulder connected to the outer opening, a trunk connected to the shoulder, and a bottom connected to the trunk.
The outer shell bottle and the inner container body are polyester resin multiple bottles formed simultaneously by blow molding,
The inner container body is thinner than the outer bottle body,
An uneven pattern is provided on the shoulder and the portion of the inner container body corresponding to the shoulder.

本発明によれば、内容器体本体を外殻ボトル本体の肉厚よりも薄く、外殻ボトルの肩部と内容器体本体とには凹凸模様が形成されるため、ポリエステル樹脂(例えば、ポリエチレンテレフタレート樹脂など)で外殻ボトルと内容器体を製造しても、通気路から吸い込まれた空気が外殻ボトルの肩部と内容器体本体との間に入り込み易くなり、外殻ボトルから内容器体本体を離れ易くすることができて、内容器体の減容変形が容易となる。   According to the present invention, since the inner container body is thinner than the thickness of the outer bottle body, and the unevenness pattern is formed on the shoulder portion of the outer bottle and the inner container body, the polyester resin (for example, polyethylene Even if the outer shell bottle and inner container body are manufactured with terephthalate resin, etc., the air sucked from the air passage can easily enter between the shoulder of the outer shell bottle and the inner container body, and the contents from the outer bottle The container body can be easily separated, and the volume reduction deformation of the inner container body is facilitated.

[2]また、本発明においては、前記凹凸模様は、革製品の表面のようなしわ模様とすることができる。凹凸模様としてしわ模様を付けることによりポリエステル樹脂製多重ボトルの外観の向上を図ることができる。他にも、凹凸模様としては、梨地や木目、布地、格子、などの様々な模様とすることができる。凹凸模様としてしわ模様や、梨地、木目、布地、格子などの模様を選択することにより、肩部にも凹凸模様をつける場合に、外殻ボトルの外観の向上を図ることができる。   [2] In the present invention, the concavo-convex pattern may be a wrinkle pattern such as the surface of a leather product. By applying a wrinkle pattern as the concavo-convex pattern, the appearance of the polyester resin multiple bottle can be improved. In addition, as the concavo-convex pattern, various patterns such as satin, wood grain, fabric, and lattice can be used. By selecting a pattern such as a wrinkle pattern, a pear texture, a wood grain, a fabric, or a lattice as the uneven pattern, it is possible to improve the appearance of the outer shell bottle when an uneven pattern is also provided on the shoulder.

[3]また、本発明においては、前記外殻ボトル及び前記内容器体は、ポリエチレンテレフタレート樹脂からなることが好ましい。かかる構成によれば、ポリエチレンテレフタレート樹脂のような比較的硬い材料で外殻ボトル及び内容器体を製造しても、内容器体本体を外殻ボトルから容易に剥すことができる。   [3] In the present invention, it is preferable that the outer shell bottle and the inner container body are made of polyethylene terephthalate resin. According to this configuration, even when the outer shell bottle and the inner container body are manufactured from a relatively hard material such as polyethylene terephthalate resin, the inner container body main body can be easily peeled from the outer shell bottle.

[4]また、本発明においては、外殻ボトルと内容器体本体との間に離型剤を介在させることが好ましい。かかる構成によれば、より一層外殻ボトルから内容器体本体を剥離させ易くすることができる。離型剤としては、例えば、流動パラフィンやシリコン系化合物を用いることができる。   [4] In the present invention, it is preferable to interpose a release agent between the outer shell bottle and the inner container body. According to such a configuration, the inner container body can be more easily separated from the outer shell bottle. As the mold release agent, for example, liquid paraffin or silicon compound can be used.

[5]本発明のポリエステル樹脂製多重ボトルの製造方法は、
円筒状の外口部と、該外口部に連接する外殻ボトル本体と、を有し、外圧に対して原形復帰可能なポリエステル樹脂製の外殻ボトルと、
前記外殻ボトルの前記外口部内に配設される円筒状の内口部と、該内口部に連接し前記外殻ボトルの内面形状に沿う形状であり前記外殻ボトル本体よりも薄肉の内容器体本体と、を有し、外圧により変形するポリエステル樹脂製の内容器体と、
前記外口部と前記内口部との間に形成されて前記外殻ボトルと前記内容器体との間に外気を導入する通気路と、を備え、
前記外殻ボトル本体は、前記外口部に連接する肩部と、該肩部に連接する胴部と、該胴部に連接する底部と、を備え、
前記外殻ボトルと前記内容器体とはブロー成形にて同時に成形されるポリエステル樹脂製多重ボトルの製造方法であって、
ブロー成形する際に、前記外殻ボトルの元となる有底筒状の外プリフォーム内に、前記外プリフォームよりも薄肉であり前記内容器体の元となる有底筒状の内プリフォームを挿入した状態で、ロッドで前記内プリフォームの底部を押圧しながら、前記外殻ボトル用の型であって、前記肩部に対応する部分に凹凸模様が付された型の中で、ブロー成形により前記外殻ボトルと前記内容器体本体とが同時に形成されることを特徴とする。
[5] A method for producing a polyester resin multiple bottle of the present invention includes:
A cylindrical outer mouth portion, and an outer shell bottle main body connected to the outer mouth portion, and an outer shell bottle made of a polyester resin capable of returning to its original shape against an external pressure;
A cylindrical inner mouth portion disposed in the outer mouth portion of the outer shell bottle, and a shape that is connected to the inner mouth portion and conforms to the inner surface shape of the outer shell bottle, and is thinner than the outer shell bottle main body. An inner container body, and an inner container body made of polyester resin that is deformed by external pressure;
An air passage formed between the outer mouth portion and the inner mouth portion for introducing outside air between the outer shell bottle and the inner container body,
The outer shell bottle body includes a shoulder connected to the outer opening, a trunk connected to the shoulder, and a bottom connected to the trunk.
The outer shell bottle and the inner container body are a method for producing a polyester resin multiple bottle that is simultaneously molded by blow molding,
The bottomed cylindrical inner preform that is thinner than the outer preform and is the source of the inner container body in the bottomed cylindrical outer preform that is the source of the outer shell bottle when blow molding is performed In a state where the bottom of the inner preform is pressed with a rod while the rod is inserted, the mold for the outer shell bottle has a concavo-convex pattern on the portion corresponding to the shoulder. The outer shell bottle and the inner container body are formed at the same time by molding.

本発明によれば、外殻ボトルと内容器体本体とを同時にブロー成形することで、肩部の凹凸模様と、内容器体本体の凹凸模様とを同時に形成することができ、ポリエステル樹脂製多重ボトルの製造が容易となる。また、内プリフォームを外プリフォームよりも薄肉とすることで、ブロー成形で成形される内容器体本体も外殻ボトル本体よりも薄くなり、肩部と内容器体本体とに凹凸模様を設けることで、肩部から内容器体本体を容易に剥離させることができる。これは、ブロー成形後の外殻ボトル本体と内容器体本体とで内部応力に差が生じて、内容器体本体は外殻ボトルの肩部から剥離し易くなり、特に、凹凸模様が形成された肩部と肩部に対応する内容器体本体の部分とは、凹凸模様によって表面積が増えて内部応力の差の影響も大きくなるためと考えられる。   According to the present invention, it is possible to simultaneously form the concavo-convex pattern on the shoulder and the concavo-convex pattern on the inner container body by simultaneously blow-molding the outer shell bottle and the inner container body. The bottle can be manufactured easily. Also, by making the inner preform thinner than the outer preform, the inner container body formed by blow molding is also thinner than the outer bottle body, and an uneven pattern is provided on the shoulder and the inner container body. Thereby, an inner container main body can be easily peeled from a shoulder part. This is because there is a difference in internal stress between the outer shell bottle body after blow molding and the inner container body body, and the inner container body body is easy to peel off from the shoulder portion of the outer shell bottle. It is considered that the shoulder portion and the portion of the inner container body corresponding to the shoulder portion increase the surface area due to the uneven pattern and increase the influence of the difference in internal stress.

本発明のポリエステル樹脂製多重ボトルの実施形態を示す斜視図。The perspective view which shows embodiment of the multiple bottle made from the polyester resin of this invention. 図1のII−II線で切断した断面を示す説明図。Explanatory drawing which shows the cross section cut | disconnected by the II-II line | wire of FIG.

図1及び図2に示すように、本実施形態のポリエステル樹脂製多重ボトル1は、外圧に対して原形復帰可能な外殻ボトル2と、外殻ボトル2の内側に収容され外圧により変形する内容器体3とからなる。   As shown in FIGS. 1 and 2, the polyester resin multiplex bottle 1 of the present embodiment includes an outer shell bottle 2 that can be restored to its original shape with respect to the external pressure, and a content that is accommodated inside the outer shell bottle 2 and is deformed by the external pressure. It consists of the body 3.

外殻ボトル2は、例えばポリエチレンテレフタレート樹脂製であり、円筒状の外口部4と、外口部4に連接する外殻ボトル本体21とを備えている。外殻ボトル本体21は、肩部5と、肩部5に連接する円筒状胴部6と、円筒状胴部6に連接する底部7とを備えている。底部7は、下端に接地する接地部7bを備えると共に、接地部7bの内周側に外殻ボトル2の内側に膨出してポリエステル樹脂製多重ボトル1に自立性を付与する凹部8を備えている。   The outer bottle 2 is made of, for example, polyethylene terephthalate resin, and includes a cylindrical outer opening 4 and an outer bottle main body 21 connected to the outer opening 4. The outer bottle body 21 includes a shoulder portion 5, a cylindrical body portion 6 connected to the shoulder portion 5, and a bottom portion 7 connected to the cylindrical body portion 6. The bottom portion 7 includes a grounding portion 7b that is grounded at the lower end, and a concave portion 8 that bulges inside the outer shell bottle 2 on the inner peripheral side of the grounding portion 7b and imparts self-supporting property to the polyester resin multiple bottle 1. Yes.

外口部4は外周面に雄ねじ部10と、サポートリング11とを備える。肩部5は外口部4に接する部分が四角錐状部となっている。この四角錐状部の下方の肩部5は、四角錐状部から円筒状胴部6に向かって次第に拡径するとともに四角錐の角が滑らかになり円筒状胴部6に連なっている。   The outer opening 4 includes a male screw portion 10 and a support ring 11 on the outer peripheral surface. The shoulder 5 has a quadrangular pyramidal portion in contact with the outer opening 4. The shoulder portion 5 below the quadrangular pyramid portion gradually increases in diameter from the quadrangular pyramid portion toward the cylindrical trunk portion 6, and the corners of the quadrangular pyramid become smooth and are continuous with the cylindrical trunk portion 6.

底部7は、接地部9に接する部分が四角錐状部となっており、四角錐状部の上方に四角錐状部から円筒状胴部6に向かって次第に拡径するとともに四角錐の角が滑らかになり円筒状胴部6に連なっている。また、凹部8は、3段に積層された四角錐台状凹部8a,8b,8cを備えている。   The bottom portion 7 has a quadrangular pyramid portion in contact with the ground contact portion 9, and the diameter of the quadrangular pyramid gradually increases from the quadrangular pyramid portion toward the cylindrical body 6 above the quadrangular pyramid portion. It is smooth and continues to the cylindrical body 6. Moreover, the recessed part 8 is provided with the quadrangular frustum-shaped recessed part 8a, 8b, 8c laminated | stacked on 3 steps | paragraphs.

また、肩部5及び底部7の四角錐状部は、それぞれ上下方向軸に直交する水平断面が四角形状であってその頂点にはRが付されており、該頂点に稜線を備えている。ここで、底部7の稜線は肩部5の稜線の延長上に連なっている。   Further, the quadrangular pyramid portions of the shoulder portion 5 and the bottom portion 7 each have a quadrangular horizontal cross section perpendicular to the vertical axis, and an apex is provided with an R, and the apex is provided with a ridge line. Here, the ridge line of the bottom 7 is continuous with the extension of the ridge line of the shoulder 5.

一方、内容器体3は、例えばポリエチレンテレフタレート樹脂製であり、外口部4の内周側に配設される円筒状の内口部13と、内口部13に連接し、外殻ボトル2の肩部5、円筒状胴部6、底部7、接地部7b、凹部8の内面形状に沿う形状の内容器体本体14とを備えている。内容器体本体14は、外殻ボトル本体21よりも薄肉に形成されている。内口部13は、上部に外口部4の上端よりも上方に延出された延出部15と、延出部15から径方向外方に張り出す鍔部16とを備えており、鍔部16により外口部4の上端縁に係止されている。   On the other hand, the inner container body 3 is made of, for example, polyethylene terephthalate resin, and is connected to the cylindrical inner mouth portion 13 disposed on the inner peripheral side of the outer mouth portion 4 and the inner mouth portion 13. The inner container body 14 having a shape along the shape of the inner surface of the shoulder 5, the cylindrical body 6, the bottom 7, the grounding portion 7 b, and the recess 8. The inner container body 14 is formed to be thinner than the outer bottle body 21. The inner mouth part 13 includes an extension part 15 that extends upward from the upper end of the outer mouth part 4 and a flange part 16 that projects radially outward from the extension part 15. The part 16 is locked to the upper edge of the outer opening 4.

なお、外殻ボトル2と内容器体3に用いるポリエステル樹脂としては、ポリエチレンテレフタレート樹脂が好適であるが、それに限定されず、例えば、ポリブチレンテレフタレート樹脂、又はポリエチレンナフタレート樹脂などであってもよく、または公知のポリエステル樹脂を単独で、あるいは混合して使用してもよい。   The polyester resin used for the outer bottle 2 and the inner container body 3 is preferably polyethylene terephthalate resin, but is not limited thereto, and may be, for example, polybutylene terephthalate resin or polyethylene naphthalate resin. Alternatively, known polyester resins may be used alone or in combination.

また、内口部13は、外周面に周方向に間隔を存して複数の縦溝17を備えている。縦溝17は鍔部16の下面に形成された横溝18に連設されており、横溝18は鍔部16の外周縁で外部に開放されている。この結果、縦溝17及び横溝18により、外殻ボトル2と内容器体3との間に外気を導入する通気路19が形成されている。各縦溝17は、内口部13の下端まで延びている。   Moreover, the inner port part 13 is provided with a plurality of vertical grooves 17 on the outer peripheral surface at intervals in the circumferential direction. The vertical groove 17 is connected to a horizontal groove 18 formed on the lower surface of the flange portion 16, and the horizontal groove 18 is opened to the outside at the outer peripheral edge of the flange portion 16. As a result, the vertical groove 17 and the horizontal groove 18 form an air passage 19 for introducing outside air between the outer shell bottle 2 and the inner container body 3. Each vertical groove 17 extends to the lower end of the inner opening 13.

肩部5は、外口部4の下端から下方に向かって拡径しながら次第に薄肉となるように形成されている。肩部5には、革製品の表面のしわのようにデコボコに窪んだしわ模様25が全周に亘って設けられている。なお、本実施形態においては、凹凸模様として革製品の表面のしわのようにでこぼこに凹んだしわ模様25を説明したが、本発明の凹凸模様は革製品の表面のしわのような凹凸に限らず、例えば、梨地や、木目、布地、格子、などの他の凹凸模様(シボ模様)であってもよい。   The shoulder portion 5 is formed so as to gradually become thinner while expanding in diameter downward from the lower end of the outer opening portion 4. The shoulder portion 5 is provided with a wrinkle pattern 25 that is recessed in a rugged shape like a wrinkle on the surface of the leather product over the entire circumference. In addition, in this embodiment, although the wrinkle pattern 25 which was dented like a wrinkle of the surface of a leather product was demonstrated as a concavo-convex pattern, the concavo-convex pattern of the present invention is not limited to the unevenness such as a wrinkle on the surface of a leather product, For example, it may be other textured pattern (texture pattern) such as satin, wood grain, fabric, lattice.

図2の断面図に示すように、肩部5に対応する内容器体本体14の部分にも肩部5と同様のしわ模様26が設けられている。   As shown in the cross-sectional view of FIG. 2, a wrinkle pattern 26 similar to that of the shoulder portion 5 is provided in the portion of the inner container body 14 corresponding to the shoulder portion 5.

本実施形態のポリエステル樹脂製多重ボトル1は、図示しない逆止弁付きキャップが外殻ボトル2の外口部4に装着されて用いられるものであり、内容器体3に図示しない内容物が収容されており、該内容物を注出するときには、外口部4及び内口部13を下方に向けて傾ける。そして、外殻ボトル2の円筒状胴部6を把持して押圧すると、内容器体本体14が減容変形することにより、内容物が注出される。ポリエステル樹脂製多重ボトル1では、円筒状胴部6は軸に直交する断面が円形であるので軸に対して任意の方向から押圧することができるので、円筒状胴部6の中央を容易に把持して内容器体本体18を減容変形させることができ、優れたスクイズ性を得ることができる。   The multiple bottle 1 made of polyester resin according to this embodiment is used with a cap with a check valve (not shown) attached to the outer opening 4 of the outer shell bottle 2, and the contents not shown are accommodated in the inner container body 3. When the contents are poured out, the outer opening 4 and the inner opening 13 are inclined downward. And if the cylindrical trunk | drum 6 of the outer shell bottle 2 is hold | gripped and pressed, the content will be poured out because the inner container main body 14 carries out volume reduction deformation. In the multiple bottle 1 made of polyester resin, the cylindrical body 6 has a circular cross section orthogonal to the axis, and can be pressed from any direction against the axis, so the center of the cylindrical body 6 can be easily grasped. Thus, the volume of the inner container body 18 can be reduced and deformed, and an excellent squeeze property can be obtained.

次に、外殻ボトル2の円筒状胴部6の押圧を解除すると、外殻ボトル2と内容器体本体14との間に通気路19の縦溝17から凹凸模様25,26が形成された肩部5と内容器体本体14との間に外気が導入され、自己の復元力により外殻ボトル2は原形に復帰するが、内容器体本体14の中には外気が入り込まず、内容器体本体14は減容変形したままの状態が維持される。   Next, when the pressing of the cylindrical body 6 of the outer shell bottle 2 is released, uneven patterns 25 and 26 are formed from the vertical grooves 17 of the air passage 19 between the outer shell bottle 2 and the inner container body 14. Outside air is introduced between the shoulder 5 and the inner container body 14, and the outer bottle 2 returns to its original shape by its own restoring force. However, outside air does not enter the inner container body 14, and the inner container The body main body 14 is maintained in a state of being deformed and reduced in volume.

このとき、内容物は重力により内口部13方向に集中しているので、内容器体本体14は外殻ボトル2の底部7の四角錐状部に対応する部分において、底部7の稜線に挟まれる部分に対応する側面部分に内容器体本体14の内側への谷折れ部が形成されて内側に没入することにより、谷折れ変形が始まる。   At this time, since the contents are concentrated in the direction of the inner mouth portion 13 due to gravity, the inner container body 14 is sandwiched between the ridgelines of the bottom portion 7 in the portion corresponding to the quadrangular pyramid portion of the bottom portion 7 of the outer shell bottle 2. A valley fold portion to the inner side of the inner container body 14 is formed in the side surface portion corresponding to the portion to be bent, and the valley fold deformation is started by immersing in the inner side portion.

ポリエステル樹脂製多重ボトル1では、外殻ボトル2の円筒状胴部6の押圧と該押圧の解除とを繰り返すことにより次第に前記内容物が減少する。前記内容物が減少すると、内容器体本体14の谷折れ変形が、外殻ボトル2の底部7の四角錐状部に対応する部分を起点として、幅方向では内容器体本体14の外側から内方に向けて進行し折り畳まれる。   In the multiple bottle 1 made of polyester resin, the content gradually decreases by repeatedly pressing and releasing the cylindrical body 6 of the outer shell bottle 2. When the content is reduced, the inner container body 14 is deformed in the valley from the outside of the inner container body 14 in the width direction starting from the portion corresponding to the quadrangular pyramidal portion of the bottom 7 of the outer shell bottle 2. Proceeds toward you and folds.

本実施形態においては、肩部5及び内容器体本体14には、しわ模様25、26が存在することにより、内容物充填後の使用時には、両しわ模様25、26の間に外気が導入され、外圧がかかったとき、肩部5に対応する内容器体本体14の部分は、より早く外殻ボトル2から剥離し、折り畳まれた部位が谷部となり折り畳み減容変形が行われる。この結果、内容器体本体14に収容されている内容物を余すことなく注出することができ、残液量を減少させることができる。   In the present embodiment, the wrinkle patterns 25 and 26 are present in the shoulder 5 and the inner container body 14, so that outside air is introduced between the wrinkle patterns 25 and 26 during use after filling the contents. When the external pressure is applied, the portion of the inner container body 14 corresponding to the shoulder portion 5 is peeled off from the outer shell bottle 2 earlier, and the folded portion becomes a trough portion and the volume reduction deformation is performed. As a result, the contents stored in the inner container body 14 can be poured out without any excess, and the amount of remaining liquid can be reduced.

また、本実施形態のポリエステル樹脂製多重ボトル1は、四角錐台状凹部8a,8b,8cからなる形状の凹部8を備えているので、ブロー成形時の加熱圧着により、凹部8では内容器体本体18が外殻ボトル2に密着している。また、凹部8は四角錐台状凹部8a,8b,8cからなり、多数の段差部と屈曲部とを備えていることにより、凹部8においては外殻ボトル2と内容器体本体14との間に外気が侵入することがない。   In addition, the multiple bottle 1 made of polyester resin according to the present embodiment includes the concave portion 8 formed of the quadrangular frustum-shaped concave portions 8a, 8b, and 8c, so that the inner container body is formed in the concave portion 8 by thermocompression bonding during blow molding. The main body 18 is in close contact with the outer shell bottle 2. Further, the concave portion 8 is formed of quadrangular pyramid-shaped concave portions 8a, 8b, and 8c, and includes a large number of step portions and bent portions, so that the concave portion 8 has a space between the outer shell bottle 2 and the inner container body 14. The outside air will not invade.

従って、外殻ボトル2の長さ方向に沿って谷折れ部が形成される間に、凹部8において外殻ボトル2から内容器体本体14が剥離することがなく、内容器体本体14に収容されている内容物をさらに確実に注出することができ、残液量を減少させることができる。   Therefore, the inner container body 14 does not peel from the outer shell bottle 2 in the recess 8 while the valley fold is formed along the length direction of the outer shell bottle 2, and is accommodated in the inner container body 14. Therefore, it is possible to more reliably pour out the contents that have been removed, and to reduce the amount of the remaining liquid.

本実施形態の肩部5にしわ模様25が形成されたポリエステル樹脂製多重ボトル1は、ポリエチレンテレフタレート樹脂からなる外殻ボトル2用の有底筒状外プリフォームと外プリフォームよりも胴部が薄肉の内容器体3用の有底筒状内プリフォームとを用いて、外プリフォームに内プリフォームを挿入し、両プリフォームの胴部の間に離型剤(好ましくは、流動パラフィン)を介在させ、外殻ボトル2の肩部5及び肩部5に対応する内容器体本体14の部分にしわ模様25が形成されるように設計されたブロー成形金型を用いて、金型の内部に両プリフォームを配置して、両方同時にブロー成形することにより製造することができる。ブロー成形後の内容器体本体14も外殻ボトル2よりも薄肉となる。   The multiple bottle 1 made of polyester resin in which a wrinkle pattern 25 is formed on the shoulder portion 5 of the present embodiment has a bottomed cylindrical outer preform for the outer shell bottle 2 made of polyethylene terephthalate resin and a barrel portion that is more than the outer preform. The inner preform is inserted into the outer preform using the bottomed cylindrical inner preform for the thin inner container body 3, and a release agent (preferably liquid paraffin) is provided between the body portions of both preforms. Using a blow molding die designed so that a wrinkle pattern 25 is formed on the shoulder portion 5 of the outer shell bottle 2 and the portion of the inner container body 14 corresponding to the shoulder portion 5. Both preforms can be placed inside and blow molded at the same time. The inner container body 14 after the blow molding is also thinner than the outer shell bottle 2.

ブロー成形金型のしわ模様は機械加工等で形成される。外プリフォームと内プリフォームとを積層して同時に延伸ブロー成形して得られた多重ボトル1には、肩部5のしわ模様25のみならず、肩部5に対応する内容器体本体14の部分にもしわ模様26が同時に形成される。ブロー成形金型の肩部のしわ模様は、肩部5のしわ模様25と内容器体本体14のしわ模様26とが同時に形成されるように設定されている。   The wrinkle pattern of the blow mold is formed by machining or the like. In the multiplex bottle 1 obtained by laminating the outer preform and the inner preform and simultaneously performing stretch blow molding, not only the wrinkle pattern 25 of the shoulder 5 but also the inner container body 14 corresponding to the shoulder 5 is formed. A wrinkle pattern 26 is simultaneously formed on the portion. The wrinkle pattern on the shoulder of the blow mold is set so that the wrinkle pattern 25 on the shoulder 5 and the wrinkle pattern 26 on the inner container body 14 are formed simultaneously.

このようにして製造される多重ボトルの外口部4と内口部13の間には通気路19が設けられており、肩部5には、しわ模様25が形成され、肩部5に対応する内容器体本体14の部分にも同様のしわ模様26が形成される。外殻ボトル2と内容器体本体14とはブロー成形後、ブロー成形金型から取り出されて冷却される。肩部5のしわ模様25と内容器体本体14のしわ模様26とでは、内側と外側との冷却温度の差、肉厚の差などの理由から内部応力などにも差が生じて、肩部5のしわ模様25と内容器体本体14のしわ模様26との間において外気を導入するなどして僅かな外力で容易に剥離させることができる。特にしわ模様25,26が形成された肩部5と内容器体本体14との間では、しわ模様25,26によって、剥離性が向上される。これは、しわ模様25,26の分だけ表面積が増加しているため、しわ模様25,26における内部応力の差も他の部分と比較して顕著となるためと考えられる。   An air passage 19 is provided between the outer opening 4 and the inner opening 13 of the thus manufactured multiple bottle, and a wrinkle pattern 25 is formed on the shoulder 5 to correspond to the shoulder 5. A similar wrinkle pattern 26 is also formed on the inner container body 14. The outer shell bottle 2 and the inner container body 14 are taken out of the blow mold and cooled after blow molding. The wrinkle pattern 25 on the shoulder 5 and the wrinkle pattern 26 on the inner container body 14 cause a difference in internal stress due to a difference in cooling temperature between the inner side and the outer side and a difference in thickness. 5 and the wrinkle pattern 26 of the inner container body 14 can be easily separated with a slight external force, for example, by introducing outside air. In particular, the peelability is improved by the wrinkle patterns 25 and 26 between the shoulder portion 5 where the wrinkle patterns 25 and 26 are formed and the inner container body 14. This is presumably because the surface area is increased by the amount of the wrinkle patterns 25 and 26, so that the difference in internal stress in the wrinkle patterns 25 and 26 is also remarkable as compared with other portions.

本実施形態のポリエステル樹脂製多重ボトル1によれば、外殻ボトル2の肩部5の内面と内容器体本体14の外面とにしわ模様25,26が設けられているため、比較的硬い材料であるポリエチレンテレフタレート樹脂などで外殻ボトルと内容器体を製造しても、通気路19から取り込まれる空気が、しわ模様25,26が形成された肩部5と内容器体本体14との間に入り込むことによって、外殻ボトル2から内容器体本体14を離れ易くすることができる。   According to the multiple bottle 1 made of polyester resin of the present embodiment, since the wrinkle patterns 25 and 26 are provided on the inner surface of the shoulder portion 5 of the outer shell bottle 2 and the outer surface of the inner container body 14, a relatively hard material. Even when the outer shell bottle and the inner container body are manufactured with polyethylene terephthalate resin or the like, the air taken in from the air passage 19 is between the shoulder portion 5 where the wrinkle patterns 25 and 26 are formed and the inner container body main body 14. By entering, the inner container body 14 can be easily separated from the outer shell bottle 2.

また、ポリエステル樹脂で外殻ボトルと内容器体とを形成したポリエステル樹脂製多重ボトルは、外殻ボトルと内容器体とが共にポリエステル樹脂製であり、内容器体に充填する内容物が高温の加熱状態でホットパックされる場合や、内容物の充填後に、外殻ボトルの外面にシュリンクラベルを取り付けるためにラベルを加熱収縮させる場合などにおいて、外殻ボトルと内容器体とが密着した状態でポリエステル樹脂製多重ボトルが加熱される場合、外殻ボトルの肩部と内容器体本体とが剥離し難くなる虞がある。特に離れ難くなった部分が肩部と肩部に対応する内容器体本体の部分である場合には、外気が導入される通気路に近いため、内容器体本体の減容変形に悪影響を与える虞がある。   In addition, in the polyester resin multiplex bottle in which the outer shell bottle and the inner container body are formed of polyester resin, both the outer shell bottle and the inner container body are made of polyester resin, and the contents filled in the inner container body are hot. When the outer shell bottle and the inner container body are in close contact, such as when hot-packed in a heated state or when the label is heated and shrunk to attach a shrink label to the outer surface of the outer shell bottle after filling the contents When the multiple bottle made of polyester resin is heated, there is a possibility that the shoulder of the outer shell bottle and the inner container body are difficult to peel off. In particular, when the part that is difficult to separate is the shoulder and the part of the inner container body corresponding to the shoulder, it is close to the air passage into which the outside air is introduced, and thus adversely affects the volume reduction deformation of the inner container body. There is a fear.

しかしながら、本実施形態のポリエステル樹脂製多重ボトル1においては、高温の内容物を充填するときや、シュリンクラベルを取り付けるために加熱されても、肩部5のしわ模様25及び内容器体本体14のしわ模様26との間で剥離性が向上されているため、通気路19から外気を導入して容易に肩部5から内容器体本体14を剥離させ、外殻ボトル2と内容器体本体14との間の下方にまで容易に外気を送ることができる。   However, in the multiple bottle 1 made of polyester resin according to the present embodiment, the wrinkle pattern 25 of the shoulder portion 5 and the inner container body 14 of the inner container body 14 are filled even when the high temperature contents are filled or when the shrink label is heated. Since the peelability between the wrinkle pattern 26 is improved, the inner container body 14 is easily peeled from the shoulder 5 by introducing outside air from the air passage 19, and the outer shell bottle 2 and the inner container body 14. The outside air can be easily sent to the lower part between.

また、ポリエステル樹脂製多重ボトル1の内容器体本体14にピンホールなどがないかどうか品質確認のためにポリエステル樹脂製多重ボトル1の製造後、一度凹部8を除く外殻ボトル2の部分から内容器体本体14を剥離させてピンホールの有無などの品質確認を行ってもよい。そして、品質確認をした後、内容器体本体14を膨らませて元に戻したポリエステル樹脂製多重ボトル1においても、例えば、加熱した内容物の充填工程や、シュリンクラベルの取り付けのための加熱処理工程などの後の工程においても、本実施形態のポリエステル樹脂製多重ボトル1によれば、しわ模様25,26によって内容器体本体14が外殻ボトル2の肩部5に張り付いて剥離し難くなることを防止することができる。   In addition, after the manufacture of the polyester resin multiple bottle 1 for quality confirmation whether the inner container body 14 of the polyester resin multiple bottle 1 is free of pinholes or the like, the contents from the portion of the outer shell bottle 2 except for the recess 8 once. The body body 14 may be peeled off to check the quality such as the presence or absence of pinholes. And after the quality check, also in the polyester resin multiple bottle 1 in which the inner container body 14 is inflated and returned to its original state, for example, a heating content filling step or a heat treatment step for attaching a shrink label In the subsequent steps such as the above, according to the multiple bottle 1 made of polyester resin of the present embodiment, the inner container body 14 sticks to the shoulder 5 of the outer shell bottle 2 due to the wrinkle patterns 25 and 26 and is difficult to peel off. This can be prevented.

また、本実施形態においては、外殻ボトル2と内容器体本体14とを同時にブロー成形することで、肩部5のしわ模様25と、内容器体本体14のしわ模様26とを同時に形成することができ、ポリエステル樹脂製多重ボトル1の製造が容易となる。   In the present embodiment, the outer bottle 2 and the inner container body 14 are simultaneously blow-molded to simultaneously form the wrinkle pattern 25 of the shoulder 5 and the wrinkle pattern 26 of the inner container body 14. Therefore, it is easy to manufacture the multiple bottle 1 made of polyester resin.

また、本実施形態では、外殻ボトル2と内容器体本体14との間に離型剤を介在させている。これにより、外殻ボトル2から内容器体本体14を更に剥離させ易くすることができる。離型剤としては、例えば、流動パラフィンやシリコン系化合物を用いることができる。   In the present embodiment, a release agent is interposed between the outer shell bottle 2 and the inner container body 14. Thereby, the inner container body 14 can be further easily separated from the outer shell bottle 2. As the mold release agent, for example, liquid paraffin or silicon compound can be used.

尚、本実施形態では、外殻ボトル2における肩部5の外口部4に連接する部分を四角錐状部としているが、肩部5全体を四角錐状部としてもよい。また、本実施形態では、外殻ボトル2における底部7の接地部7bに連接する部分を四角錐状部としているが、底部7全体を四角錐状部としてもよい。または、肩部及び底部の一方または両方を円錐状に形成してもよい。   In this embodiment, the portion connected to the outer opening 4 of the shoulder 5 in the outer shell bottle 2 is a quadrangular pyramid, but the entire shoulder 5 may be a quadrangular pyramid. Moreover, in this embodiment, although the part connected to the earthing | grounding part 7b of the bottom part 7 in the outer shell bottle 2 is made into the quadrangular pyramid part, it is good also considering the bottom part 7 whole as a quadrangular pyramid part. Alternatively, one or both of the shoulder and the bottom may be formed in a conical shape.

また、本実施形態では、外殻ボトル2における四角錐状部を上下方向軸に直交する水平断面が四角形状である四角錐状としているが、四角錐状部は水平断面が三角形状である三角錐状、五角形状である五角錐状、六角形状である六角錐状のいずれか1つの多角錐状であってもよい。また、多角錐状は、多角形の頂点がカットされ、或いは多角形の頂点にRが付されていてもよく、さらに、前記頂点に挟まれた辺を外方に膨出させてもよく、膨出させた辺に1以上の頂点を備えていてもよい。   In the present embodiment, the quadrangular pyramid portion of the outer shell bottle 2 has a quadrangular pyramid shape whose horizontal cross section perpendicular to the vertical axis is quadrangular, but the quadrangular pyramid portion is a triangular shape whose horizontal cross section is triangular. Any one of a pyramid shape, a pentagonal pyramid shape, and a hexagonal pyramid shape that is a hexagonal shape may be used. In addition, the polygonal pyramid may be cut at the vertex of the polygon, or may have R attached to the vertex of the polygon, and may further bulge the sides sandwiched between the vertices outward, One or more vertices may be provided on the bulged side.

また、本実施形態では、外口部4の外周面に雄ねじ部10を備える構成としているが、外口部4は雄ねじ部10を備えない単なる円筒状であってもよく、このようにすることにより例えば醤油ボトル等の打栓式口部等に適用することができる。   Moreover, in this embodiment, although it is set as the structure provided with the external thread part 10 in the outer peripheral surface of the outer opening part 4, the outer opening part 4 may be a mere cylindrical shape which is not provided with the external thread part 10, and does in this way. For example, it can be applied to a plug-type mouth portion such as a soy sauce bottle.

また、本実施形態では、円筒状胴部6のスクイズ性等への影響を考慮して、しわ模様25を肩部5にのみ設けているものを説明した。しかしながら、本発明の肩部の凹凸模様は、これに限らず、肩部の上半分にのみ凹凸模様を設けてもよい。また、胴部や底部に凹凸模様を付してもよい。   Further, in the present embodiment, the case where the wrinkle pattern 25 is provided only on the shoulder portion 5 has been described in consideration of the influence on the squeeze property of the cylindrical body portion 6. However, the uneven pattern of the shoulder portion of the present invention is not limited to this, and the uneven pattern may be provided only on the upper half of the shoulder portion. Moreover, you may give an uneven | corrugated pattern to a trunk | drum or a bottom part.

1 ポリエステル樹脂製多重ボトル
2 外殻ボトル
3 内容器体
4 外口部
5 肩部
6 胴部
7 底部
7b 接地部
8 凹部
10 雄ねじ部
11 サポートリング
13 内口部
14 内容器体本体
15 延出部
16 鍔部
17 縦溝
18 横溝
19 通気路
21 外殻ボトル本体
25 肩部のしわ模様
26 内容器体本体のしわ模様
DESCRIPTION OF SYMBOLS 1 Polyester resin multiple bottle 2 Outer shell bottle 3 Inner container body 4 Outer mouth part 5 Shoulder part 6 Body part 7 Bottom part 7b Grounding part 8 Recessed part 10 Male thread part 11 Support ring 13 Inner mouth part 14 Inner container body 15 Extension part 16 Wrinkle 17 Vertical groove 18 Horizontal groove 19 Ventilation path 21 Outer shell bottle body 25 Wrinkle pattern on shoulder 26 Wrinkle pattern on inner container body

Claims (5)

円筒状の外口部と、該外口部に連接する外殻ボトル本体と、を有し、外圧に対して原形復帰可能なポリエステル樹脂製の外殻ボトルと、
前記外殻ボトルの前記外口部内に配設される円筒状の内口部と、該内口部に連接し前記外殻ボトルの内面形状に沿う形状の内容器体本体と、を有し、外圧により変形するポリエステル樹脂製の内容器体と、
前記外口部と前記内口部との間に形成されて前記外殻ボトルと前記内容器体との間に外気を導入する通気路と、を備え、
前記外殻ボトル本体は、前記外口部に連接する肩部と、該肩部に連接する胴部と、該胴部に連接する底部と、を備え、
前記外殻ボトルと前記内容器体とはブロー成形にて同時に成形されるポリエステル樹脂製多重ボトルであって、
前記内容器体本体は、前記外殻ボトル本体よりも薄肉に形成され、
前記肩部及び前記肩部に対応する前記内容器体本体の部分には凹凸模様が設けられていることを特徴とするポリエステル樹脂製多重ボトル。
A cylindrical outer mouth portion, and an outer shell bottle main body connected to the outer mouth portion, and an outer shell bottle made of a polyester resin capable of returning to its original shape against an external pressure;
A cylindrical inner mouth portion disposed in the outer mouth portion of the outer shell bottle, and an inner container body body connected to the inner mouth portion and conforming to the inner surface shape of the outer shell bottle, An inner container body made of polyester resin deformed by external pressure;
An air passage formed between the outer mouth portion and the inner mouth portion for introducing outside air between the outer shell bottle and the inner container body,
The outer shell bottle body includes a shoulder connected to the outer opening, a trunk connected to the shoulder, and a bottom connected to the trunk.
The outer shell bottle and the inner container body are polyester resin multiple bottles that are simultaneously molded by blow molding,
The inner container body is formed thinner than the outer bottle body,
A multiple bottle made of polyester resin, wherein the shoulder portion and the portion of the inner container body corresponding to the shoulder portion are provided with an uneven pattern.
請求項1記載のポリエステル樹脂製多重ボトルであって、
前記凹凸模様は、しわ模様であることを特徴とするポリエステル樹脂製多重ボトル。
The multiple bottle made of polyester resin according to claim 1,
The multi-bottle made of polyester resin, wherein the uneven pattern is a wrinkle pattern.
請求項1または請求項2に記載のポリエステル樹脂製多重ボトルであって、
前記外殻ボトル及び前記内容器体は、ポリエチレンテレフタレート樹脂からなることを特徴とするポリエステル樹脂製多重ボトル。
A multiple bottle made of polyester resin according to claim 1 or claim 2,
The outer bottle and the inner container body are made of polyethylene terephthalate resin.
請求項1から請求項3の何れか1項に記載のポリエステル樹脂製多重ボトルであって、
前記外殻ボトルと前記内容器体本体の間に離型剤が介在されていることを特徴とするポリエステル樹脂製多重ボトル。
A multiple bottle made of polyester resin according to any one of claims 1 to 3,
A polyester resin multiple bottle, wherein a release agent is interposed between the outer shell bottle and the inner container body.
円筒状の外口部と、該外口部に連接する肩部と、該肩部に連接する胴部と、該胴部に連接する底部と、を有し、外圧に対して原形復帰可能なポリエステル樹脂製の外殻ボトルと、
前記外殻ボトルの前記外口部内に配設される円筒状の内口部と、該内口部に連接し前記外殻ボトルの内面形状に沿う形状の内容器体本体と、を有し、外圧により変形するポリエステル樹脂製の内容器体と、
前記外口部と前記内口部との間に形成されて前記外殻ボトルと前記内容器体との間に外気を導入する通気路と、
を備えるポリエステル樹脂製多重ボトルの製造方法であって、
ブロー成形する際に、前記外殻ボトルの元となる有底筒状の外プリフォーム内に、前記外プリフォームよりも薄肉であり前記内容器体の元となる有底筒状の内プリフォームを挿入した状態で、ロッドで前記内プリフォームの底部を押圧しながら、前記外殻ボトル用の型であって、前記肩部に対応する部分に凹凸模様が付された型の中で、ブロー成形により前記外殻ボトルと前記内容器体本体とが同時に形成されることを特徴とする合成樹脂製ブロー成形多重ボトルの製造方法。
It has a cylindrical outer opening, a shoulder connected to the outer opening, a trunk connected to the shoulder, and a bottom connected to the shoulder, and can be restored to its original form with respect to external pressure. An outer bottle made of polyester resin;
A cylindrical inner mouth portion disposed in the outer mouth portion of the outer shell bottle, and an inner container body body connected to the inner mouth portion and conforming to the inner surface shape of the outer shell bottle, An inner container body made of polyester resin deformed by external pressure;
An air passage formed between the outer mouth portion and the inner mouth portion for introducing outside air between the outer shell bottle and the inner container body;
A method for producing a multiple bottle made of polyester resin comprising:
The bottomed cylindrical inner preform that is thinner than the outer preform and is the source of the inner container body in the bottomed cylindrical outer preform that is the source of the outer shell bottle when blow molding is performed In a state where the bottom of the inner preform is pressed with a rod while the rod is inserted, the mold for the outer shell bottle has a concavo-convex pattern on the portion corresponding to the shoulder. A method for producing a synthetic resin blow-molded multiple bottle, wherein the outer shell bottle and the inner container body are simultaneously formed by molding.
JP2018015258A 2018-01-31 2018-01-31 Multiple-bottle made of polyester resin and its manufacturing method Pending JP2019131248A (en)

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JPH0740426A (en) * 1993-07-28 1995-02-10 Toppan Printing Co Ltd Hollow container having hologram and production thereof
JPH10139027A (en) * 1996-11-12 1998-05-26 Mitsubishi Plastics Ind Ltd Plastic bottle
JP2003192031A (en) * 2001-12-21 2003-07-09 Kao Corp Lamination-separable container
JP2004209690A (en) * 2002-12-27 2004-07-29 Yoshino Kogyosho Co Ltd Method for manufacturing bottle container made of thermoplastic synthetic resin
JP2010082916A (en) * 2008-09-30 2010-04-15 Yoshino Kogyosho Co Ltd Blow molded container and method for molding the same
JP2014091580A (en) * 2013-12-18 2014-05-19 Yoshino Kogyosho Co Ltd Delamination container
JP2016216082A (en) * 2015-05-19 2016-12-22 東洋製罐グループホールディングス株式会社 Stretch blow double container and manufacturing method thereof
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Patent Citations (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH0428525A (en) * 1990-05-24 1992-01-31 Dainippon Printing Co Ltd Biaxially-oriented blow molded vessel having oxygen barrier property and manufacture thereof
JPH0740426A (en) * 1993-07-28 1995-02-10 Toppan Printing Co Ltd Hollow container having hologram and production thereof
JPH10139027A (en) * 1996-11-12 1998-05-26 Mitsubishi Plastics Ind Ltd Plastic bottle
JP2003192031A (en) * 2001-12-21 2003-07-09 Kao Corp Lamination-separable container
JP2004209690A (en) * 2002-12-27 2004-07-29 Yoshino Kogyosho Co Ltd Method for manufacturing bottle container made of thermoplastic synthetic resin
JP2010082916A (en) * 2008-09-30 2010-04-15 Yoshino Kogyosho Co Ltd Blow molded container and method for molding the same
JP2014091580A (en) * 2013-12-18 2014-05-19 Yoshino Kogyosho Co Ltd Delamination container
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