JP2019119697A - Poison bait for controlling myriapod insect pest - Google Patents

Poison bait for controlling myriapod insect pest Download PDF

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JP2019119697A
JP2019119697A JP2017253850A JP2017253850A JP2019119697A JP 2019119697 A JP2019119697 A JP 2019119697A JP 2017253850 A JP2017253850 A JP 2017253850A JP 2017253850 A JP2017253850 A JP 2017253850A JP 2019119697 A JP2019119697 A JP 2019119697A
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controlling
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poison bait
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bait
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JP7079602B2 (en
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真也 向永
Shinya Mukonaga
真也 向永
さやか 菊田
Sayaka Kikuta
さやか 菊田
知幸 引土
Tomoyuki Hikitsuchi
知幸 引土
中山 幸治
Koji Nakayama
幸治 中山
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Dainihon Jochugiku Co Ltd
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Abstract

To provide a poison bait for controlling myriapod insect pest capable of exhibiting high control effect on myriapod insect pest such as centipede.SOLUTION: There is provided a poison bait for controlling myriapod insect pest containing an insect pest controlling component, saccharide which is a feeding stimulating agent, a food flavor which is an attraction component, and a moisturizing component, and agent liquid containing water. The food flavor is at least one kind selected from a group consisting of flesh milk oil, strawberry essence, acetoin, mango essence, bonito tuna extract, Camembert cheese flavor, apple oil, bonito salted fish extract, tuna extract, banana essence, laver flavor, squid paste, and maple essence. The agent liquid is gelatinized by gelatinization agent. The agent liquid and the gelatinization agent are blended at 20:1 to 70:1 as weight ratio. Content of the saccharide in the agent liquid is 10 to 70 wt.%.SELECTED DRAWING: Figure 1

Description

本発明は、多足類害虫防除用毒餌剤に関する。   The present invention relates to a poison bait for controlling a polypod pest.

トビズムカデ、アオズムカデ、アカズムカデ等のムカデは、野外環境に生息し、毒腺のある顎肢を用いて小型の虫等を捕食する。しかし、ムカデは温暖な環境を好む習性を有するため家屋等に侵入することが多く、家屋等での人との接触により刺咬被害を引き起こすことがある。そこで、ムカデ等の多足類害虫を防除する毒餌剤が利用されている。   Centipedes such as tobism kade, oomukade, akazukade, etc. inhabit the field environment, and feed on small insects and the like using the jaw limbs with poisonous glands. However, centipedes often invade houses and the like because they have the habit of preferring a warm environment, and contact with people in the houses and the like may cause bite damage. Therefore, poison baits that control multipod pests such as centipede are used.

例えば、トリメチルグリシンを配合した害虫防除用ベイト剤がある(例えば、特許文献1を参照)。特許文献1の害虫防除用ベイト剤は、トリメチルグリシンによって保湿されることで乾燥、変質を防ぎ、野外での設置でも長期間の薬効を保つものである。   For example, there is a bait for pest control which is blended with trimethylglycine (see, for example, Patent Document 1). The bait agent for pest control of Patent Document 1 is moisturized by trimethylglycine to prevent dryness and deterioration, and maintains the medicinal effect for a long time even when installed in the field.

また、高吸水性ポリマーを配合した害虫防除用ベイト剤組成物がある(例えば、特許文献2を参照)。特許文献2の害虫防除用ベイト剤組成物は、高吸水性ポリマーにより土壌水分等を吸水し、乾燥条件下においても長期間にわたり水分を保持することで、誘引性及び摂食性を向上させるものである。   In addition, there is a bait composition for pest control containing a superabsorbent polymer (see, for example, Patent Document 2). The bait composition for pest control of Patent Document 2 absorbs soil moisture and the like by a superabsorbent polymer, and improves the attractiveness and the feeding property by holding the moisture for a long period of time even under dry conditions. is there.

特開2001−181106号公報JP 2001-181106 A 特開昭57−62201号公報JP-A-57-62201

害虫防除用毒餌剤の誘引性及び摂食性は、害虫の種類によってその効力の発現に差が生じる。しかしながら、特許文献1の害虫防除用ベイト剤は、アリ及びゴキブリを主な防除対象としたものであり、特許文献2の害虫防除用ベイト剤組成物は、農作物に被害を及ぼす土壌害虫を防除対象としたものであり、何れも多足類害虫の防除に最適化されたものではない。そのため、特許文献1及び2の毒餌剤は、多足類害虫に対して必ずしも高い防除効果を奏するものではない。   The attractiveness and feedability of pest control poison baits differ in their manifestation of efficacy depending on the type of pest. However, the bait for pest control of Patent Document 1 mainly targets ants and cockroaches, and the bait composition for pest control of Patent Document 2 is targeted for controlling a soil pest that damages agricultural crops. And none of them are optimized for the control of polypod pests. Therefore, the poison bait of patent document 1 and 2 does not necessarily show a high control effect with respect to a polypod pest.

本発明は、上記問題点に鑑みてなされたものであり、ムカデ等の多足類害虫に対して高い防除効果を奏することができる多足類害虫防除用毒餌剤を提供することを目的とする。   The present invention has been made in view of the above problems, and it is an object of the present invention to provide a multiplicative pest control poison bait capable of exhibiting a high control effect against multipod pests such as centipede. .

上記課題を解決するための本発明に係る多足類害虫防除用毒餌剤の特徴構成は、
多足類害虫防除用毒餌剤であって、
害虫防除成分、摂食促進成分である糖類、誘引成分である食品香料、保湿成分である多価アルコール、及び水を含有する薬液を含むことにある。
The characteristic constitution of the poison bait for controlling a multipod pest according to the present invention for solving the above-mentioned problems is
Poisonous bait for controlling multi-legged insect pests,
It comprises a pest control component, a saccharide which is a feed promoting component, a food flavor which is a attractant component, a polyhydric alcohol which is a moisturizing component, and a drug solution containing water.

本構成の多足類害虫防除用毒餌剤によれば、薬液が摂食促進成分である糖類、誘引成分である食品香料、保湿成分である多価アルコール、及び水を含有することで、多足類害虫に対する優れた誘引性、及び摂食性を発揮し、さらに薬液が害虫防除成分を含有することで、摂食した多足類害虫に対する優れた殺虫効果を発揮することができる。その結果、ムカデ等の多足類害虫に対する高い防除効果を奏することができる。   According to the poison bait for controlling a multi-legged pest of the present invention, the drug solution contains a sugar as a food intake promoting component, a food flavor as a attractant component, a polyhydric alcohol as a moisturizing component, and water. By exerting excellent attraction and feeding properties against pests and further containing a pest control component in the medicinal solution, it is possible to exert excellent insecticidal effect against fed multipod pests. As a result, a high control effect can be exhibited against multipod pests such as centipede.

本発明に係る多足類害虫防除用毒餌剤において、
前記食品香料は、フレッシュミルクオイル、ストロベリーエッセンス、アセトイン、マンゴーエッセンス、鰹・鮪エキス、カマンベールチーズフレーバー、アップルオイル、鰹塩辛エキス、鮪エキス、バナナエッセンス、ノリフレーバー、イカペースト、及びメープルエッセンスからなる群から選択される少なくとも1種であることが好ましい。
In the poison bait for controlling a multipod pest according to the present invention,
The food flavor comprises fresh milk oil, strawberry essence, acetoin, mango essence, persimmon extract, camembert cheese flavor, apple oil, persimmon extract, persimmon extract, banana extract, nori flavor, squid paste, and maple essence It is preferable that it is at least one selected from the group.

本構成の多足類害虫防除用毒餌剤によれば、上記の食品香料を含有することにより、多足類害虫、特にムカデに対する優れた誘引性を発揮し、摂食させることができるため、ムカデに対する高い防除効果を奏することができる。   According to the poison bait for controlling a multi-legged insect pest of the present configuration, by containing the above-mentioned food flavor, it can exert excellent attraction to multi-legged insect pests, particularly centipede, and can be fed, so Can exert a high control effect on

本発明に係る多足類害虫防除用毒餌剤において、
前記薬液は、ゲル化剤でゲル化されていることが好ましい。
In the poison bait for controlling a multipod pest according to the present invention,
The drug solution is preferably gelled with a gelling agent.

本構成の多足類害虫防除用毒餌剤によれば、薬液がゲル化剤でゲル化されていることにより、取り扱いが容易なものとなり、さらに、長期間にわたって乾燥することなく、多足類害虫を防除することができる。   According to the poison bait for controlling a multi-legged insect pest of the present invention, the drug solution is gelled with a gelling agent, which makes it easy to handle, and further, a multi-legged insect pest without drying for a long period of time Can be controlled.

本発明に係る多足類害虫防除用毒餌剤において、
前記薬液と前記ゲル化剤とは、重量比として、20:1〜70:1で配合されていることが好ましい。
In the poison bait for controlling a multipod pest according to the present invention,
It is preferable that the said chemical | medical solution and the said gelatinizing agent are mix | blended by 20: 1-70: 1 as a weight ratio.

本構成の多足類害虫防除用毒餌剤によれば、薬液とゲル化剤との配合比を上記の範囲に調整することにより、多足類害虫が摂食しやすい硬さ、及び含水率の毒餌剤が得られ、多足類害虫に対する高い防除効果を奏することができる。   According to the poison bait for controlling a multipod pest of this constitution, by adjusting the compounding ratio of the chemical solution and the gelling agent to the above range, a poison bait with a hardness and a moisture content which are easily fed by a multipod pest An agent is obtained, and it can exhibit a high control effect against multipod pests.

本発明に係る多足類害虫防除用毒餌剤において、
前記薬液における糖類の含有量は、10〜70重量%であることが好ましい。
In the poison bait for controlling a multipod pest according to the present invention,
It is preferable that content of saccharides in the said chemical | medical solution is 10 to 70 weight%.

本構成の多足類害虫防除用毒餌剤によれば、薬液における糖類の含有量を上記の範囲に調整することにより、低温でも結晶化することなく、多足類害虫に対する優れた摂食性を発揮することができる。   According to the poison bait for controlling a multipod pest of this constitution, by adjusting the content of saccharides in the chemical solution to the above-mentioned range, an excellent feeding property against a multipod pest is exhibited without crystallization even at a low temperature. can do.

本発明に係る多足類害虫防除用毒餌剤において、
前記ゲル化剤は、吸水性樹脂、キサンタンガム、カラギナン、ローカストビーンガム、及び寒天からなる群から選択される少なくとも1種であることが好ましい。
In the poison bait for controlling a multipod pest according to the present invention,
The gelling agent is preferably at least one selected from the group consisting of a water absorbing resin, xanthan gum, carrageenan, locust bean gum, and agar.

本構成の多足類害虫防除用毒餌剤によれば、ゲル化剤が上記の物質であることにより、使い勝手が良好なゲル状の毒餌剤を調整することができる。ゲル状の毒餌剤は、多足類害虫、特にムカデに対する摂食性に優れるため、多足類害虫に対する高い防除効果を奏することができる。   According to the poison bait of the present invention having the above-mentioned constitution, it is possible to adjust a gel-like poison bait which is easy to use because the gelling agent is the above-mentioned substance. Since the gel-like poison bait is excellent in feedability to polypod pests, in particular centipede, it can exert a high control effect on polypod pests.

本発明に係る多足類害虫防除用毒餌剤において、
界面活性剤を含有しないことが好ましい。
In the poison bait for controlling a multipod pest according to the present invention,
It is preferred not to contain a surfactant.

本構成の多足類害虫防除用毒餌剤によれば、界面活性剤を含有しないことで、多足類害虫、特にムカデに対する摂食性に優れ、高い防除効果を奏することができる。   According to the poison bait for controlling a multipod pest of the present configuration, by containing no surfactant, it is possible to exhibit excellent feeding property to a polypod pest, especially centipede, and to exert a high control effect.

図1は、食品香料へのトビズムカデの平均接触回数を示すグラフである。FIG. 1 is a graph showing the average number of contacts of tobism kade to food flavors.

本発明に係る多足類害虫防除用毒餌剤は、害虫防除成分、摂食促進成分である糖類、誘引成分である食品香料、保湿成分である多価アルコール、及び水を含有する薬液を含む。以下、本発明の多足類害虫防除用毒餌剤に関する実施形態について説明する。ただし、本発明は、以下に説明する実施形態や図面に記載される構成に限定されることを意図しない。   The poison bait according to the present invention for controlling a pest of a polypod comprises a pest controlling component, a saccharide which is a feed promoting component, a food flavor which is a attracting component, a polyhydric alcohol which is a moisturizing component, and a chemical solution containing water. BEST MODE FOR CARRYING OUT THE INVENTION Hereinafter, an embodiment of the poison bait for controlling a multipod pest of the present invention will be described. However, the present invention is not intended to be limited to the configurations described in the embodiments and drawings described below.

<薬液>
[害虫防除成分]
薬液の主成分の一つである害虫防除成分は、ムカデ、ヤスデ等の多足類害虫の駆除に有効な成分が使用される。そのような成分として、ネオニコチノイド系殺虫剤、カーバメート系殺虫剤が挙げられ、特に、ネオニコチノイド系殺虫剤が好ましい。ネオニコチノイド系殺虫剤としては、例えば、ジノテフラン、アセタミプリド、イミダクロプリド、クロチアニジン、チアクロプリド、チアメトキサム、及びニテンピラムが挙げられ、特に、ジノテフランが好ましい。なお、ジノテフランには、不斉炭素に基づく光学異性体や幾何異性体が存在するが、それらも害虫防除成分に含まれる。カーバメート系殺虫剤としては、プロポクスル、カルバリル、メソミル、チオジカルブが挙げられ、特に、プロポクスルが好ましい。これらのネオニコチノイド系殺虫剤、及びカーバメート系殺虫剤は、単独で使用してもよいし、複数種を組み合わせて使用してもよい。薬液中の害虫防除成分の含有量は、0.1〜1.0重量%が好ましい。このような範囲であれば、例えば、薬液がゲル化剤に含浸された状態においても、害虫防除成分の効果を奏することができる。薬液中の害虫防除成分の含有量が0.1重量%未満である場合、害虫防除成分が不足し殺虫効果が不十分なものとなる。一方、薬液中の害虫防除成分の含有量が1.0重量%を超える場合、害虫防除成分の濃度が高くなるため、薬液を適切に調製し難くなる。
<Chemical solution>
[Pest control ingredients]
As the pest control component which is one of the main components of the medicinal solution, a component effective for controlling polypod pests such as centipede and castor bean is used. Such components include neonicotinoid insecticides and carbamate insecticides, and neonicotinoid insecticides are particularly preferable. Examples of neonicotinoid insecticides include dinotefuran, acetamiprid, imidacloprid, clothianidin, thiacloprid, thiamethoxam, and nitenpyram, with dinotefuran being particularly preferable. In addition, although the optical isomer and geometrical isomer based on asymmetric carbon exist in dinotefuran, they are also contained in a pest control component. Examples of carbamate insecticides include propoxul, carbaryl, mesomyl and thiodicarb, and propoxur is particularly preferable. These neonicotinoid insecticides and carbamate insecticides may be used alone or in combination of two or more. The content of the pest control component in the chemical solution is preferably 0.1 to 1.0% by weight. Within such a range, for example, even in the state where the drug solution is impregnated with the gelling agent, the effect of the pest control component can be exhibited. When the content of the pest control component in the chemical solution is less than 0.1% by weight, the pest control component is insufficient and the insecticidal effect becomes insufficient. On the other hand, when the content of the pest control component in the drug solution exceeds 1.0% by weight, the concentration of the pest control component becomes high, and it becomes difficult to properly prepare the drug solution.

[摂食促進成分]
薬液の主成分の一つである摂食促進成分は、糖類が使用される。糖類としては、例えば、グルコース、及びフルクトース等の単糖類、スクロース、マルトース、及びトレハロース等の二糖類、三温糖、グラニュー糖、及び上白糖等の精製糖が挙げられ、特に、三温糖が好ましい。これらの糖類は、単独で使用してもよいし、複数種を組み合わせて使用してもよい。また、糖類だけではなく、ソルビトール、キシリトール等の糖アルコール、及びその他の甘味料を摂食促進成分として配合することも可能である。薬液中の摂食促進成分の含有量は、10〜70重量%が好ましい。このような範囲であれば、多足類害虫に対する優れた摂食性を発揮することができ、さらに、低温でも摂食促進成分が結晶化することがないため多足類害虫防除用毒餌剤の保存性に優れる。薬液中の摂食促進成分の含有量が10重量%未満であると、多足類害虫の摂食性が不十分なものとなる場合がある。一方、薬液中の摂食促進成分の含有量が70重量%を超えると、低温環境において摂食促進成分が結晶化する虞がある。
[Feeding promoting ingredient]
A saccharide is used as a food intake promoting component which is one of the main components of the drug solution. Examples of saccharides include monosaccharides such as glucose and fructose, disaccharides such as sucrose, maltose and trehalose, purified sugars such as trin heating sugar, granulated sugar and white sucrose, and particularly trin heating sugar preferable. These saccharides may be used alone or in combination of two or more. Not only sugars, but also sugar alcohols such as sorbitol and xylitol, and other sweeteners can be blended as feeding promoting ingredients. The content of the food intake promoting component in the drug solution is preferably 10 to 70% by weight. Within such a range, it is possible to exert an excellent feeding property against polypod pests, and furthermore, since the feeding promoting component is not crystallized even at low temperature, preservation of poison bait for multipod pest control Excellent in quality. If the content of the feeding promoting component in the drug solution is less than 10% by weight, feeding properties of the multipod pest may be insufficient. On the other hand, if the content of the food intake promoting component in the drug solution exceeds 70% by weight, the food intake promoting component may be crystallized in a low temperature environment.

[誘引成分]
ムカデは、動物性蛋白質からフルーツ、樹液等の植物由来の物質まで幅広い食性を有し、特に好む食物は諸説ある。そこで、本発明者らは、ムカデの誘引性について詳細に検討を行ったところ、ムカデは特定の種類の食品香料に強く誘引される傾向があることが判明した。この新たな知見に基づき、多足類害虫防除用毒餌剤に、誘引成分として特定の種類の食品香料を含有させた結果、優れた誘引効果が認められた。そこで、薬液の主成分の一つである誘引成分として、食品香料を使用する。食品香料としては、例えば、フレッシュミルクオイル、ストロベリーエッセンス、アセトイン、マンゴーエッセンス、鰹・鮪エキス、カマンベールチーズフレーバー、アップルオイル、鰹塩辛エキス、鮪エキス、バナナエッセンス、ノリフレーバー、イカペースト、及びメープルエッセンスが挙げられる。これらの食品香料は、単独で使用してもよいし、複数種を組み合わせて使用してもよい。さらに、本発明者らによるムカデの誘引性についての検討過程において、多足類害虫防除用毒餌剤に界面活性剤を添加した場合に、ムカデに対する摂食性が低下する傾向があることが明らかとなった。そのため、界面活性剤の添加が不要となる水溶性の食品香料が好ましい。そのような水溶性の食品香料として、例えば、ストロベリーエッセンス、アセトイン、マンゴーエッセンス、鰹・鮪エキス、カマンベールチーズフレーバー、鰹塩辛エキス、鮪エキス、バナナエッセンス、ノリフレーバー、イカペースト、及びメープルエッセンスが挙げられる。薬液中の誘引成分の含有量は、0.1〜5重量%が好ましい。このような範囲であれば、多足類害虫に対する優れた誘引性を発揮することができる。薬液中の誘引成分の含有量が0.1重量%未満であると、多足類害虫の誘引性が不十分なものとなる場合がある。一方、薬液中の誘引成分の含有量が5重量%を超えると、多足類害虫防除用毒餌剤を閉鎖空間に設置した場合等に、臭気が過剰に強くなる虞がある。
[Attractive component]
Centipedes have a wide range of eating habits from animal proteins to plant-derived substances such as fruits, sap, etc. There are various foods that they particularly like. Therefore, when the present inventors examined in detail the attractiveness of centipede, it turned out that centipede tends to be strongly attracted to certain types of food flavors. Based on this new finding, as a result of including a food flavor of a specific type as an attractant component in a poison bait for controlling a multipod pest, an excellent attractive effect was recognized. Therefore, a food flavor is used as an attractive component which is one of the main components of the drug solution. As food flavors, for example, fresh milk oil, strawberry essence, acetoin, mango essence, persimmon extract, camembert cheese flavor, apple oil, persimmon salt extract, persimmon extract, banana extract, nori flavor, squid paste, and maple essence Can be mentioned. These food flavors may be used alone or in combination of two or more. Furthermore, in the process of examining the attractiveness of centipede by the present inventors, it has become clear that the feeding ability to centipede tends to decrease when a surfactant is added to the poison bait for controlling a multipod pest. The Therefore, water-soluble food flavors that do not require the addition of surfactants are preferred. Such water soluble food flavors include, for example, strawberry essence, acetoin, mango essence, persimmon extract, camembert cheese flavor, persimmon salt extract, persimmon extract, banana extract, nori flavor, squid paste, and maple essence Be As for content of the attraction component in a chemical | medical solution, 0.1-5 weight% is preferable. If it is such a range, the outstanding attraction with respect to a polypod pest can be exhibited. When the content of the attractant component in the chemical solution is less than 0.1% by weight, the attractability of the multipod pest may be insufficient. On the other hand, when the content of the attractant component in the chemical solution exceeds 5% by weight, the odor may become excessively strong, for example, when the poison bait for controlling a multipod pest is installed in a closed space.

[保湿成分]
薬液の主成分の一つである保湿成分は、多価アルコールが使用される。多価アルコールとしては、例えば、グリセリンや、1,3−ブチレングリコール、プロピレングリコール、ジプロピレングリコール、トリプロピレングリコール、ジエチレングリコール、トリエチレングリコール、ヘキシレングリコール、及びベンジルグリコール等のグリコール類が挙げられ、特に、グリセリンが好ましい。これらの多価アルコールは、単独で使用してもよいし、複数種を組み合わせて使用してもよい。薬液中の保湿成分の含有量は、10〜40重量%が好ましい。保湿成分の含有量がこのような範囲であれば、多足類害虫防除用毒餌剤を設置後、乾燥、変質を防ぎ、ムカデに対する誘引性及び摂食性を長期間にわたって維持することができる。薬液中の保湿成分の含有量が10重量%未満であると、設置後に多足類害虫防除用毒餌剤が早期に乾燥、変質し、ムカデに対する誘引性及び摂食性を維持できない虞がある。薬液中の保湿成分の含有量が40重量%を超える場合、保湿成分の濃度が高くなるため、薬液を適切に調製し難くなる。
[Moisturizing ingredient]
A polyhydric alcohol is used as the moisturizing component which is one of the main components of the drug solution. Examples of polyhydric alcohols include glycerin and glycols such as 1,3-butylene glycol, propylene glycol, dipropylene glycol, tripropylene glycol, diethylene glycol, triethylene glycol, hexylene glycol, and benzyl glycol. In particular, glycerin is preferred. These polyhydric alcohols may be used alone or in combination of two or more. As for content of the moisturizing component in a chemical | medical solution, 10 to 40 weight% is preferable. When the content of the moisturizing component is in such a range, after installation of the poison bait for controlling a multipod pest, drying and deterioration can be prevented, and attractiveness and feeding property to the centipede can be maintained for a long time. If the content of the moisturizing component in the drug solution is less than 10% by weight, there is a risk that the poison bait for controlling a multi-legged insect pest prematurely dries and degenerates after installation and can not maintain attractiveness and feeding properties to centipede. When the content of the moisturizing component in the drug solution exceeds 40% by weight, the concentration of the moisturizing component becomes high, which makes it difficult to properly prepare the drug solution.

[その他の成分]
薬液には、本発明の効果に支障を来たさない限り、必要に応じ、カビ類や菌類等を対象とした防カビ剤、抗菌剤、殺菌剤、ビトレックス等の苦味剤、pH調整剤、着色剤等を適宜配合してもよい。防カビ剤、抗菌剤、及び殺菌剤としては、ヒノキチオール、2−メルカプトベンゾチアゾール、2−(4−チアゾリル)ベンツイミダゾール、5−クロロ−2−メチル−4−イソチアゾリン−3−オン、トリホリン、3−メチル−4−イソプロピルフェノール、オルト−フェニルフェノール等が挙げられる。また、上述したように、多足類害虫防除用毒餌剤に界面活性剤を添加した場合、ムカデに対する摂食性が低下する傾向があるため、本発明に係る多足類害虫防除用毒餌剤は、界面活性剤を含有しないことが好ましい。
[Other ingredients]
If necessary, the chemical solution may be an antifungal agent for molds and fungi, an antibacterial agent, a bactericidal agent, a bitter taste agent such as Vitrex, and a pH adjuster, as long as the effects of the present invention are not impaired. And colorants may be appropriately blended. Antifungal agents, antibacterial agents and bactericidal agents include hinokitiol, 2-mercaptobenzothiazole, 2- (4-thiazolyl) benzimidazole, 5-chloro-2-methyl-4-isothiazolin-3-one, trifolin, 3 And -methyl-4-isopropylphenol, ortho-phenylphenol and the like. In addition, as described above, when a surfactant is added to the poison bait for controlling a multipod pest, the feedability to the centipede tends to decrease, and therefore, the poison bait for controlling a pest of the present invention is It is preferred not to contain a surfactant.

<ゲル化剤>
ゲル化剤は、薬液をゲル化させ、ゲル状の多足類害虫防除用毒餌剤を形成するものである。これにより、多足類害虫防除用毒餌剤は、取り扱いが容易なものとなり、さらに、長期間にわたって乾燥することなく、多足類害虫を防除することができる。ゲル化剤としては、例えば、吸水性樹脂、キサンタンガム、カラギナン、ローカストビーンガム、及び寒天等を使用することができる。さらに、本発明者らは、ゲル化剤の種類によって摂食性に相違があることを見出し、ゲルの性状に注目してムカデに対する摂食性を検討したところ、曳糸性の高いゲルではムカデに対する摂食性が低下する傾向があることが判明した。そのため、ゲル化剤としては、曳糸性が低い吸水性樹脂の使用が好ましい。そのような吸水性樹脂として、自重の100倍以上の水を吸収することができるアクリル酸重合体部分ナトリウム塩架橋物等のアクリル酸系吸水性ポリマーが挙げられる。薬液とゲル化剤とは、重量比として、20:1〜70:1で配合されることが好ましい。薬液とゲル化剤との配合比がこのような範囲であれば、ムカデが摂食しやすい硬さ、及び含水率の粒状の毒餌剤が得られ、ムカデに対する高い防除効果を奏することができる。薬液とゲル化剤との配合比が20:1より小さい、即ち薬液をゲル化剤に対して20:1の配合比よりも減らすと、摂食促進成分による摂食性、及び誘引成分による誘引性が十分に効力を示さず、多足類害虫を防除できない虞がある。薬液とゲル化剤との配合比が70:1より大きい、即ち薬液をゲル化剤に対して70:1の配合比よりも増やすと、多足類害虫防除用毒餌剤の粘度が過度に小さくなり、取り扱いの面で不便なものとなる虞がある。
<Gelling agent>
The gelling agent is to gel the drug solution to form a gel-like poison bait for pest control. As a result, the poison bait for controlling a multipod pest can be easily handled, and can control a multipod pest without drying for a long period of time. As a gelling agent, for example, a water absorbent resin, xanthan gum, carrageenan, locust bean gum, agar and the like can be used. Furthermore, the present inventors have found that there is a difference in the feeding property depending on the type of the gelling agent, and when the feeding property to centipede was examined paying attention to the properties of the gel, the gel with high spinnability was consumed on the centipede. It turned out that eating habits tend to decrease. Therefore, it is preferable to use a water-absorbent resin with low spinnability as a gelling agent. As such a water-absorbing resin, acrylic acid-based water-absorbing polymers such as acrylic acid polymer partial sodium salt cross-linked products capable of absorbing water 100 times or more of their own weight can be mentioned. The drug solution and the gelling agent are preferably blended in a weight ratio of 20: 1 to 70: 1. If the compounding ratio of the drug solution and the gelling agent is in such a range, it is possible to obtain a granular poison bait with hardness and moisture content easy for the centipede to feed, and to exert a high control effect on the centipede. When the compounding ratio of the drug solution to the gelling agent is less than 20: 1, that is, if the drug solution is less than the compounding ratio of 20: 1 with respect to the gelling agent, the feedability by the feeding promoting component and the attraction by the attractant component May not be effective enough to control polypod pests. If the compounding ratio of the drug solution and the gelling agent is greater than 70: 1, that is, if the drug solution is more than the compounding ratio of 70: 1 with respect to the gelling agent, the viscosity of the poison bait for controlling a multipod pest is excessively low. And there is a risk of inconvenience in terms of handling.

以下、本発明の多足類害虫防除用毒餌剤を用いて実施したムカデの誘引性、及び摂食性に関する実施例について説明する。   Hereinafter, the Example regarding the attractability of the centipede implemented using the poison bait of the multipod pest control | control of this invention, and feeding property is described.

〔実施例1〕
害虫防除成分としてジノテフラン0.3g、誘引成分としてアセトイン1g、及び鰹・鮪エキス1g、摂食促進成分として三温糖40g、保湿成分としてグリセリン20g、その他の成分としてイソチアゾリン系抗菌剤0.02g、及びビトレックス0.002gを、精製水に混合して100gとすることで、薬液を調製した。さらに、吸水性樹脂(三洋化成、サンフレッシュ)0.3gに薬液10gを分注して膨潤させることで、実施例1の多足類害虫防除用毒餌剤を得た。
Example 1
0.3 g of dinotefuran as a pest control component, 1 g of acetoin as an attractant component, and 1 g of acupuncture extract, 40 g of three-point sugar as a food intake promoting component, 20 g of glycerin as a moisturizing component, 0.02 g of an isothiazoline antibacterial agent as another component And 0.002 g of Vitrex was mixed with purified water to make 100 g to prepare a drug solution. Further, 10 g of the drug solution was dispensed into 0.3 g of a water-absorbent resin (Sanyo Kasei, San Fresh) and allowed to swell, whereby a poison bait for controlling a multipod pest of Example 1 was obtained.

実施例1の多足類害虫防除用毒餌剤は、ゲル状の粒状体の集塊となり、取り扱いが容易であった。また、石膏を流し込んだプラスチックケース(幅21cm、長さ37cm、高さ28cm)に供試虫(トビズムカデ)を1匹放ち、馴化させた後に、実施例1の多足類害虫防除用毒餌剤2gをプラスチックケースに設置して、トビズムカデの行動を観察したところ、実施例1の多足類害虫防除用毒餌剤は、ムカデに対して優れた誘引性、摂食性、及び致死効果を示した。   The poison bait for controlling a polypod pest of Example 1 was a clump of gel-like particles, and was easy to handle. Moreover, after releasing one test insect (Tobism kade) in a plastic case (width 21 cm, length 37 cm, height 28 cm) poured with plaster and acclimating, 2 g of poison bait for controlling a multipod pest of Example 1 Was placed in a plastic case, and the behavior of Tobism kade was observed. As a result, the poison bait for controlling a multipod pest of Example 1 showed excellent attractiveness, feeding and killing effects on centipede.

様々な食品香料について誘引性確認試験を行い、ムカデに対する高い誘引性を有する食品香料を選定した。誘引性確認試験では、石膏を流し込んだプラスチックケース(幅21cm、長さ37cm、高さ28cm)に供試虫(トビズムカデ)を1匹放ち、馴化させた後に、食品香料のサンプル2gを入れたシャーレ(直径3.8cm、高さ1cm、蓋に直径2mmの小孔を6つ開口)をプラスチックケースに設置して、トビズムカデの行動を1時間観察した。プラスチックケースはサンプル毎に3つ用意し、シャーレへのトビズムカデの平均接触回数を求めた。図1は、食品香料へのトビズムカデの平均接触回数を示すグラフである。図1には、コントロールとして水道水2gを入れたシャーレへのトビズムカデの平均接触回数(2.9回)を合わせて示している。   The attractiveness verification test was done about various food flavors, and the food flavor having high attraction to centipede was selected. In the attractiveness confirmation test, after releasing one test insect (Tobism kade) in a plastic case (width 21 cm, length 37 cm, height 28 cm) in which gypsum is poured and acclimating, a petri dish containing 2 g of a sample of food flavor (The diameter of 3.8 cm, height of 1 cm, 6 small holes of 2 mm in diameter were opened in the lid) in a plastic case, and the behavior of the tobism kade was observed for 1 hour. Three plastic cases were prepared for each sample, and the average number of times of tobism kade contact with petri dishes was determined. FIG. 1 is a graph showing the average number of contacts of tobism kade to food flavors. FIG. 1 also shows the average number of times of contact of Tobism kade (2.9 times) with a petri dish containing 2 g of tap water as a control.

誘引性確認試験の結果、平均接触回数が5回以上である食品香料を、ムカデに対する誘引性が高い食品香料として選定した。具体的には、図1において破線より上側に示したフレッシュミルクオイル、ストロベリーエッセンス、アセトイン、マンゴーエッセンス、鰹・鮪エキス、カマンベールチーズフレーバー、アップルオイル、鰹塩辛エキス、鮪エキス、バナナエッセンス、ノリフレーバー、イカペースト、及びメープルエッセンスが、平均接触回数が5以上となり優れた誘引性を有することが確認された。   As a result of the attraction confirmation test, a food flavor having an average contact number of 5 or more was selected as a food flavor having high attraction to centipede. Specifically, fresh milk oil, strawberry essence, acetoin, mango essence, persimmon extract, camembert cheese flavor, apple oil, persimmon salt extract, persimmon extract, banana extract, nori flavor shown above the broken line in FIG. The squid paste and the maple essence were confirmed to have an average number of contacts of 5 or more and to have excellent attractiveness.

〔実施例2〜7、比較例1〜4、参考例1〕
実施例1に準じて表1に示す各種の組成で多足類害虫防除用毒餌剤を調製し、摂食性確認試験を実施した。
[Examples 2 to 7, Comparative Examples 1 to 4, Reference Example 1]
According to Example 1, the poison bait for controlling a multi-legged insect pest was prepared with various compositions shown in Table 1, and an eating test was conducted.

摂食性確認試験では、石膏を流し込んだプラスチックケース(幅21cm、長さ37cm、高さ28cm)に供試虫(トビズムカデ)を1匹放ち、馴化させた後に、自由移動中のムカデの前方、又は静止中のムカデの頭部付近に多足類害虫防除用毒餌剤(サンプル)を提示し、摂食回数を記録し、摂食率(%)を下式により求めた。試験結果を、表1に示す。
摂食率(%) = Ce/Cd × 100
Cd:サンプルの提示回数
Ce:摂食回数
In the feedability confirmation test, one test insect (Tobism kade) is released in a plastic case (width 21 cm, length 37 cm, height 28 cm) in which gypsum is poured, and after acclimating, it is in front of a freely moving centipede, or A poisoned bait (sample) for controlling a multipod pest was presented near the head of a resting centipede, the number of times of feeding was recorded, and the feeding rate (%) was determined by the following formula. The test results are shown in Table 1.
Feeding rate (%) = Ce / Cd × 100
Cd: Number of samples presented Ce: Number of food intake

Figure 2019119697
Figure 2019119697

摂食性確認試験の結果、本発明の特徴構成を備えた実施例2〜7の多足類害虫防除用毒餌剤では、誘引成分として複数種類の食品香料を含有する実施例2〜4、6〜7、及び誘引成分として食品香料を1種類のみ含有する実施例5の何れでも摂食率が50%以上となり、優れた摂食性が確認された。また、実施例2〜7の多足類害虫防除用毒餌剤のうち、摂食促進成分の含有量が最も少ない実施例2の摂食率が最も低く、摂食促進成分の含有量が最も多い実施例7の摂食率が最も高くなることから、摂食促進成分の含有量が多い程、多足類害虫防除用毒餌剤の摂食性が向上する傾向が確認された。なお、実施例2〜7の多足類害虫防除用毒餌剤は、ゲル状の粒状体の集塊となり、中でも薬液とゲル化剤との配合比が30:1である実施例3と、薬液とゲル化剤との配合比が50:1である実施例2、4、5、及び7とは、適度な硬さを有し取り扱いが容易であった。薬液とゲル化剤との配合比が70:1である実施例6は、他のものと比較して粘度がやや低くなったが、十分な取り扱い性を有するものであった。このように、本発明の特徴構成を備えた実施例2〜7の多足類害虫防除用毒餌剤は、優れた摂食性、及び良好な取り扱い性を両立したものであり、多足類害虫の防除に適することが確認された。   As a result of the feedability confirmation test, in the poison bait for controlling a multi-legged insect pest of Examples 2 to 7 provided with the characteristic constitution of the present invention, Examples 2 to 4 and 6 to contain plural kinds of food flavors as attractive components. The food intake rate was 50% or more in any of Example 7 and Example 5 which contained only one type of food flavor as an attractant component, and excellent food intake was confirmed. In addition, among the poison baits for controlling a multipod pest of Examples 2 to 7, the feeding rate of Example 2 having the lowest content of the feeding promoting component is the lowest, and the content of the feeding promoting component is the highest. From the fact that the feeding rate of Example 7 is the highest, it was confirmed that the feeding property of the poison bait for controlling a multi-legged insect pest is improved as the content of the feeding promoting component is larger. In addition, the poison bait for multi-legged insect pest control of Examples 2 to 7 is a clump of gel-like particles, and among them, Example 3 in which the compounding ratio of the drug solution and the gelling agent is 30: 1, In Examples 2, 4, 5, and 7 in which the compounding ratio of the gel to the gelling agent was 50: 1, the hardness was appropriate and the handling was easy. Example 6 in which the compounding ratio of the drug solution and the gelling agent was 70: 1 had a slightly lower viscosity than the others, but had sufficient handleability. As described above, the poison bait for controlling a multi-legged insect pest of Examples 2 to 7 provided with the characteristic constitution of the present invention has both excellent feedability and good handleability, It was confirmed to be suitable for control.

一方、摂食促進成分を含有していない比較例1の多足類害虫防除用毒餌剤では、摂食促進成分以外の組成が同一である実施例4の多足類害虫防除用毒餌剤と比較して、摂食率が低下することが確認された。誘引成分を含有していない比較例2の多足類害虫防除用毒餌剤では、誘引成分以外の組成が同一である実施例4の多足類害虫防除用毒餌剤と比較して、摂食率が低下することが確認された。保湿成分を含有していない比較例3の多足類害虫防除用毒餌剤では、保湿成分以外の組成が同一である実施例5の多足類害虫防除用毒餌剤と比較して、摂食率が低下することが確認された。このように、本発明の特徴構成を備えていない比較例1〜3の多足類害虫防除用毒餌剤は、何れも摂食率が41%以下の低い値であり、摂食性が劣るものであることが確認された。なお、比較例4は、本発明に規定する誘引成分の好ましい含有量の範囲である0.1〜5重量%から外れた値(アセトイン0.04重量%、鰹・鮪エキス0.04重量%)で誘引成分を含有するように調製されている。このような比較例4では、誘引成分の含有量以外の組成が同一である実施例4の多足類害虫防除用毒餌剤と比較して、摂食率が低下することが確認された。   On the other hand, in the poison bait for controlling a multipod pest of Comparative Example 1 which does not contain a feeding promoting component, the poisoning bait for controlling a polypod pest of Example 4 having the same composition except for the feeding promoting component is compared. It was confirmed that the food intake rate decreased. In the poison bait for controlling a multi-legged insect pest of Comparative Example 2 which does not contain an attractant component, the food intake rate is compared with the poison bait for controlling a multi-legged insect pest of Example 4 having the same composition other than the attractant component. Was confirmed to decrease. In the poison bait for controlling a multi-legged insect pest of Comparative Example 3 which does not contain a moisturizing component, the food intake rate is compared with the poisoning bait for controlling a multi-legged insect pest of Example 5 having the same composition except the moisturizing component. Was confirmed to decrease. Thus, the poison bait for controlling a multi-legged insect pest of Comparative Examples 1 to 3 which does not have the characteristic constitution of the present invention has a low feeding rate of 41% or less, and is inferior in feeding ability. It was confirmed that there is. Comparative Example 4 is a value outside the range of 0.1 to 5% by weight, which is the range of the preferable content of the attractant component specified in the present invention (acetoin 0.04% by weight, anther & persimmon extract 0.04% by weight Are prepared to contain an attractant component. In such a comparative example 4, it was confirmed that a food intake rate falls compared with the poisoning bait of Example 4 in which the composition other than content of an attraction component is the same.

なお、界面活性剤を含有する参考例1の多足類害虫防除用毒餌剤は、界面活性剤以外の組成が、摂食促進成分を60重量%含有し摂食率が最も高い88%であった実施例7の多足類害虫防除用毒餌剤と同一であるにも関わらず、摂食率が0%であった。このことから、多足類害虫防除用毒餌剤に界面活性剤を添加した場合、ムカデに対する摂食性が低下することが確認された。以上の結果より、誘引性確認試験においてムカデに対する誘引性が高い食品香料として選定したもののうち、水溶性が高いストロベリーエッセンス、アセトイン、マンゴーエッセンス、鰹・鮪エキス、カマンベールチーズフレーバー、鰹塩辛エキス、鮪エキス、バナナエッセンス、ノリフレーバー、イカペースト、及びメープルエッセンスは、多足類害虫防除用毒餌剤を調製する際に、可溶化剤として界面活性剤を添加する必要がないため、誘引成分により適した食品香料であることが確認された。   In addition, the poison bait of the multipod pests pest control of the reference example 1 containing surfactant is 60% by weight containing 60% by weight of composition other than surfactant, and the feeding rate is the highest. The feeding rate was 0% despite being identical to the poison bait for controlling polypod pests of Example 7. From this, it was confirmed that when a surfactant is added to the poison bait for controlling a multipod pest, feedability to centipede decreases. From the above results, among the food flavors selected as highly attractive to centipede in the attractiveness confirmation test, strawberry essence having high water solubility, acetoin, mango essence, persimmon, persimmon extract, camembert cheese flavor, persimmon extract, persimmon extract, persimmon Extract, Banana Essence, Nori Flavor, Squid Paste, and Maple Essence are more suitable as attractive components as they do not require the addition of surfactants as solubilizers when preparing poison bait for multi-legged pest control It was confirmed to be a food flavor.

本発明の多足類害虫防除用毒餌剤は、ムカデ、ヤスデ等の多足類害虫を駆除する用途に利用可能であり、多足類害虫のうち特に、トビズムカデ、アオズムカデ、アカズムカデ等のムカデ類に対して好適に利用可能であり、さらにはワラジムシ、ダンゴムシ等にも利用可能である。   The poison bait of the present invention for controlling pests of polypods can be used for controlling polypod pests such as centipede and yasuda, and among polypod pests, it is particularly useful for centipedes such as tobism kades, osmukade and akasumkade It can be suitably used, and it can also be used as a larch, a rubber gum and the like.

Claims (7)

多足類害虫防除用毒餌剤であって、
害虫防除成分、摂食促進成分である糖類、誘引成分である食品香料、保湿成分である多価アルコール、及び水を含有する薬液を含む多足類害虫防除用毒餌剤。
Poisonous bait for controlling multi-legged insect pests,
A poison bait comprising a pest control component, a saccharide which is a feed promoting component, a food flavor which is a attractant component, a polyhydric alcohol which is a moisturizing component, and a chemical solution containing water.
前記食品香料は、フレッシュミルクオイル、ストロベリーエッセンス、アセトイン、マンゴーエッセンス、鰹・鮪エキス、カマンベールチーズフレーバー、アップルオイル、鰹塩辛エキス、鮪エキス、バナナエッセンス、ノリフレーバー、イカペースト、及びメープルエッセンスからなる群から選択される少なくとも1種である請求項1に記載の多足類害虫防除用毒餌剤。   The food flavor comprises fresh milk oil, strawberry essence, acetoin, mango essence, persimmon extract, camembert cheese flavor, apple oil, persimmon extract, persimmon extract, banana extract, nori flavor, squid paste, and maple essence The poison bait according to claim 1, which is at least one selected from the group consisting of 前記薬液は、ゲル化剤でゲル化されている請求項1又は2に記載の多足類害虫防除用毒餌剤。   The poisoned bait according to claim 1 or 2, wherein the drug solution is gelled with a gelling agent. 前記薬液と前記ゲル化剤とは、重量比として、20:1〜70:1で配合されている請求項1〜3の何れか一項に記載の多足類害虫防除用毒餌剤。   The poisoning bait according to any one of claims 1 to 3, wherein the chemical solution and the gelling agent are blended at a weight ratio of 20: 1 to 70: 1. 前記薬液における糖類の含有量は、10〜70重量%である請求項1〜4の何れか一項に記載の多足類害虫防除用毒餌剤。   Content of the saccharides in the said chemical | medical solution is 10 to 70 weight%, The poisoned bait agent for multipedia insect pest control as described in any one of Claims 1-4. 前記ゲル化剤は、吸水性樹脂、キサンタンガム、カラギナン、ローカストビーンガム、及び寒天からなる群から選択される少なくとも1種である請求項1〜5の何れか一項に記載の多足類害虫防除用毒餌剤。   The said gelling agent is at least 1 sort (s) selected from the group which consists of a water absorbing resin, xanthan gum, carrageenan, locust bean gum, and agar, The polypod pest control as described in any one of Claims 1-5. Poison bait. 界面活性剤を含有しない請求項1〜6の何れか一項に記載の多足類害虫防除用毒餌剤。   The poisoning bait according to any one of claims 1 to 6, which does not contain a surfactant.
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