JP2019107014A - Oily food material for coating frozen dessert - Google Patents

Oily food material for coating frozen dessert Download PDF

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Publication number
JP2019107014A
JP2019107014A JP2019035020A JP2019035020A JP2019107014A JP 2019107014 A JP2019107014 A JP 2019107014A JP 2019035020 A JP2019035020 A JP 2019035020A JP 2019035020 A JP2019035020 A JP 2019035020A JP 2019107014 A JP2019107014 A JP 2019107014A
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frozen dessert
food material
weight
oil
coating
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Inventor
佑希 臼井
Yuki Usui
佑希 臼井
暁之 石渡
Akiyuki Ishiwatari
暁之 石渡
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Fuji Oil Co Ltd
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Fuji Oil Co Ltd
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    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23DEDIBLE OILS OR FATS, e.g. MARGARINES, SHORTENINGS, COOKING OILS
    • A23D9/00Other edible oils or fats, e.g. shortenings, cooking oils
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23GCOCOA; COCOA PRODUCTS, e.g. CHOCOLATE; SUBSTITUTES FOR COCOA OR COCOA PRODUCTS; CONFECTIONERY; CHEWING GUM; ICE-CREAM; PREPARATION THEREOF
    • A23G1/00Cocoa; Cocoa products, e.g. chocolate; Substitutes therefor
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23GCOCOA; COCOA PRODUCTS, e.g. CHOCOLATE; SUBSTITUTES FOR COCOA OR COCOA PRODUCTS; CONFECTIONERY; CHEWING GUM; ICE-CREAM; PREPARATION THEREOF
    • A23G1/00Cocoa; Cocoa products, e.g. chocolate; Substitutes therefor
    • A23G1/30Cocoa products, e.g. chocolate; Substitutes therefor
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23GCOCOA; COCOA PRODUCTS, e.g. CHOCOLATE; SUBSTITUTES FOR COCOA OR COCOA PRODUCTS; CONFECTIONERY; CHEWING GUM; ICE-CREAM; PREPARATION THEREOF
    • A23G1/00Cocoa; Cocoa products, e.g. chocolate; Substitutes therefor
    • A23G1/30Cocoa products, e.g. chocolate; Substitutes therefor
    • A23G1/305Products for covering, coating, finishing, decorating
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23GCOCOA; COCOA PRODUCTS, e.g. CHOCOLATE; SUBSTITUTES FOR COCOA OR COCOA PRODUCTS; CONFECTIONERY; CHEWING GUM; ICE-CREAM; PREPARATION THEREOF
    • A23G9/00Frozen sweets, e.g. ice confectionery, ice-cream; Mixtures therefor
    • A23G9/32Frozen sweets, e.g. ice confectionery, ice-cream; Mixtures therefor characterised by the composition containing organic or inorganic compounds
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23GCOCOA; COCOA PRODUCTS, e.g. CHOCOLATE; SUBSTITUTES FOR COCOA OR COCOA PRODUCTS; CONFECTIONERY; CHEWING GUM; ICE-CREAM; PREPARATION THEREOF
    • A23G9/00Frozen sweets, e.g. ice confectionery, ice-cream; Mixtures therefor
    • A23G9/32Frozen sweets, e.g. ice confectionery, ice-cream; Mixtures therefor characterised by the composition containing organic or inorganic compounds
    • A23G9/322Products for covering, coating, finishing, decorating
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23GCOCOA; COCOA PRODUCTS, e.g. CHOCOLATE; SUBSTITUTES FOR COCOA OR COCOA PRODUCTS; CONFECTIONERY; CHEWING GUM; ICE-CREAM; PREPARATION THEREOF
    • A23G9/00Frozen sweets, e.g. ice confectionery, ice-cream; Mixtures therefor
    • A23G9/44Frozen sweets, e.g. ice confectionery, ice-cream; Mixtures therefor characterised by shape, structure or physical form
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23GCOCOA; COCOA PRODUCTS, e.g. CHOCOLATE; SUBSTITUTES FOR COCOA OR COCOA PRODUCTS; CONFECTIONERY; CHEWING GUM; ICE-CREAM; PREPARATION THEREOF
    • A23G9/00Frozen sweets, e.g. ice confectionery, ice-cream; Mixtures therefor
    • A23G9/52Liquid products; Solid products in the form of powders, flakes or granules for making liquid products ; Finished or semi-finished solid products, frozen granules

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Food Science & Technology (AREA)
  • Polymers & Plastics (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Inorganic Chemistry (AREA)
  • Confectionery (AREA)
  • Edible Oils And Fats (AREA)

Abstract

To provide an oily food material for coating a frozen dessert which is excellent in solidification performance, control of a basis weight, inhibitory effect on cracks while maintaining an excellent melt in mouth and a frozen dessert using this.SOLUTION: An oily food material is blended so that all of following conditions are satisfied: in a triglyceride composition in oil and fat, StOO is equal to or more than 10 wt.%, triglyceride in which the total carbon number of a constituent fatty acid is 30-38 is 8-30 wt.%, POP is equal to or less than 15 wt.%, SUS is less than 15 wt.% and/or SUU is less than 30 wt.%, and further preferably the POO content is equal to or less than 20 wt.%.SELECTED DRAWING: None

Description

本発明は、物性と食感を両立した、冷菓被覆用チョコレート類に関する。 The present invention relates to chocolate for coating a frozen dessert which has both physical properties and texture.

アイスクリーム等の冷菓製品には、風味バラエティー化や水分移行防止、食感付与のため、チョコレート類などの油脂組成物、油性食品素材でコーティング(被覆)することがある。その場合口溶けを考慮し、液体油、口溶けがシャープで低融点のラウリン系油脂、パーム油などがよく用いられており、冷凍温度域での口溶けが劣るココアバターは少量に制限される傾向にある。一方、製造に際し、次工程への影響や目付量の制御のため、固化速度も重要であり、それを満たすために、固化性が良好な油脂を配合する必要がある。しかし、これらの油脂は食感が硬かったり、口溶けが悪かったり、さらにはひび割れしやすいという問題がある。 Products of frozen desserts such as ice cream are sometimes coated (coated) with an oil and fat composition such as chocolates and an oily food material for the purpose of flavor variety, prevention of water migration and impartation of texture. In that case, in consideration of mouth melting, liquid oil, sharp melting in the mouth, low melting point lauric fat and oil, palm oil etc. are often used, and cocoa butter with poor mouth melting in the freezing temperature range tends to be limited to a small amount . On the other hand, at the time of production, the solidification speed is also important in order to control the influence on the next step and the basis weight, and in order to satisfy it, it is necessary to blend fats and oils having good solidification properties. However, these oils and fats have a problem that the texture is hard, the mouth melts bad, and they are easily cracked.

そこでこれまでに、口溶けを維持しつつ固化速度を上げる、あるいは、固化性は良好だが噛み出しが柔らかいチョコレート類が開発されている。例えば特許文献1によれば、POPとラウリン酸を特定量含有することで、適度な噛み出しの硬さ、口溶け良好な冷菓用チョコレート類が得られるが、コーティング用とした場合のひび割れ防止効果は不十分である。 Therefore, until now, chocolates have been developed which increase the solidification speed while maintaining the melt in the mouth, or which are good in solidification but soft in chewing. For example, according to Patent Document 1, by containing a specific amount of POP and lauric acid, suitable bite hardness and mouth melting good chocolates for frozen desserts can be obtained, but when it is used as a coating, the crack prevention effect is It is not enough.

一方、ひび割れ抑制を目的とした技術も開発されている。
例えば、配合油脂中のトリグリセリド組成において、SSSを8%未満、SUSを25-80%、SUUを2-40%、UUUを5%以上(S:C16−C24の飽和脂肪酸、U:C18以上の不飽和脂肪酸)とするもの(特許文献2)、ジ飽和モノ不飽和グリセリド(S2U)10-85% 、ジ不飽和モノ飽和グリセリド(SU2) 及びトリ不飽和グリセリド(U3)の合計を15-90%、ジ飽和モノ不飽和グリセリド(S2U) 中ジ飽和モノリノレート(S2L) を35%以上とするもの(特許文献3)、エステル交換油脂を油相中に5-50質量%含有し、油相のSFCが10℃で1〜20%、20℃で1〜15%、40℃で0〜6%である油脂組成物(特許文献4)、が挙げられる。これらは一定の柔軟性、ひび割れ抑制の効果は見られるものの、その分やや固化性に劣り、目付量の制御などに難が残る。
On the other hand, technology aimed at crack control has also been developed.
For example, in the triglyceride composition in the blended fat and oil, SSS is less than 8%, SUS is 25-80%, SUU is 2-40%, UUU is 5% or more (S: saturated fatty acid of C16-C24, U: C18 or more Unsaturated fatty acids) (Patent Document 2), 10 to 85% of disaturated monounsaturated glycerides (S2U), 15 to 90 in total of diunsaturated monosaturated glycerides (SU2) and triunsaturated glycerides (U3) % And disaturated monounsaturated glyceride (S2U) containing 35% or more of disaturated monolinoleate (S2L) (Patent Document 3), containing 5-50% by mass of transesterified oil in the oil phase, The fat and oil composition (patent document 4) whose SFC is 1 to 20% at 10 ° C, 1 to 15% at 20 ° C, and 0 to 6% at 40 ° C can be mentioned. Although the effect of a certain softness | flexibility and a crack suppression is seen, these are somewhat inferior to solidification property, and a problem remains in control of a fabric weight etc.

X3を3%以下、X2Uを40〜60%、POPを18〜37%、XU2を31〜47%、U3を10%以下とする出願(特許文献5)、X3を3%以下、X2Uを15〜34%、XU2を30〜47%、U3を10%以下、C14以下の飽和脂肪酸を10〜34%とする出願(特許文献6)は、パリパリとした食感を有し、かつひび割れしにくい冷菓用チョコレートに関する内容であるが、いずれもアイスを全面コーティングするような、チョコレートの収縮がシビアに影響する場合には効果が不十分である。(X:C16-18の飽和脂肪酸、U:C18の不飽和脂肪酸、P:パルミチン酸、O:オレイン酸) Application that sets X3 to 3% or less, X2U to 40 to 60%, POP to 18 to 37%, XU2 to 31 to 47%, and U3 to 10% or less (Patent Document 5), X3 to 3% or less, X2U to 15 The application (patent document 6) which makes -34%, XU2 30-47%, U3 is 10% or less, and C14 or less saturated fatty acid is 10 to 34% has texture as crispy, and it is hard to be cracked. Although the content is related to chocolate for frozen desserts, the effect is insufficient when the shrinkage of the chocolate affects severe as in the case of coating all over ice. (X: C16-18 saturated fatty acid, U: C18 unsaturated fatty acid, P: palmitic acid, O: oleic acid)

特開2006-280209号公報JP, 2006-280209, A 特表平10-506285号公報Japanese Patent Application Publication No. 10-506285 特開平6-105655号公報JP-A-6-105655 特開2010-268749号公報JP, 2010-268749, A 特開2015-15914号公報JP, 2015-15914, A 特開2015-15915号公報JP, 2015-15915, A

本発明の目的は、良好な口溶けを維持しながら、固化性、目付量の制御、ひび割れ抑制効果に優れた、冷菓被覆用の油性食品素材を提供することにある。 An object of the present invention is to provide an oily food material for coating a frozen dessert, which is excellent in solidifying property, control of area weight, and crack suppressing effect while maintaining good mouth melting.

本発明者らは上記の課題に対して鋭意研究を重ねた結果、油脂中にStOOを一定量以上配合し、さらにトリグリセリド組成を特定範囲に調整することで上記課題を解決可能であることを見出し、本発明を完成させた。 The present inventors have intensively studied the above-mentioned problems, and as a result, they find that the above-mentioned problems can be solved by blending a certain amount or more of StOO in fats and oils and further adjusting the triglyceride composition to a specific range. , Completed the present invention.

即ち本発明は、
(1)油脂中のトリグリセリド組成が以下1〜4の条件を満たす、冷菓被覆用油性食品素材、
1 StOOが10重量%以上
2 構成脂肪酸の炭素数の合計が30〜38のトリグリセリドが8〜30重量%
3 POPが15重量%以下
4 SUSが15重量%未満、及び/又はSUUが30重量%未満
ただし、
S:炭素数16〜20の飽和脂肪酸
U:炭素数16〜18の不飽和脂肪酸
St:ステアリン酸
O:オレイン酸
P:パルミチン酸
(2)油脂中のPOO含量が20重量%以下である、(1)に記載の冷菓被覆用油性食品素材、
(3)油脂中のPOO含量が15重量%以下である、(1)に記載の冷菓被覆用油性食品素材、
(4)該POPが10重量%以下である、(1)記載の冷菓被覆用油性食品素材、
(5)該POPが10重量%以下である、(2)記載の冷菓被覆用油性食品素材、
(6)該POPが10重量%以下である、(3)記載の冷菓被覆用油性食品素材、
(7)該冷菓被覆用油性食品素材中の油脂分が50重量%以上である、(1)記載の冷菓被覆用油性食品素材、
(8)該冷菓被覆用油性食品素材中の油脂分が50重量%以上である、(2)記載の冷菓被覆用油性食品素材、
(9)該冷菓被覆用油性食品素材中の油脂分が50重量%以上である、(3)記載の冷菓被覆用油性食品素材、
(10)該冷菓被覆用油性食品素材中の油脂分が50重量%以上である、(4)記載の冷菓被覆用油性食品素材、
(11)該冷菓被覆用油性食品素材中の油脂分が50重量%以上である、(5)記載の冷菓被覆用油性食品素材、
(12)該冷菓被覆用油性食品素材中の油脂分が50重量%以上である、(6)記載の冷菓被覆用油性食品素材、
(13)(1)記載の冷菓被覆用油性食品素材を被覆してなる、冷菓、
(14)(11)記載の冷菓被覆用油性食品素材を被覆してなる、冷菓、
(15)(12)記載の冷菓被覆用油性食品素材を被覆してなる、冷菓、
であり、換言すれば、
(16)油脂中のトリグリセリド組成が以下1〜4の条件を満たす、冷菓被覆用油性食品素材、
1 StOOが10重量%以上
2 構成脂肪酸の炭素数の合計が30〜38のトリグリセリドが8〜30重量%
3 POPが15重量%以下
4 SUSが15重量%未満、及び/又はSUUが30重量%未満
である。
ただし、
S:炭素数16〜20の飽和脂肪酸
U:炭素数16〜18の不飽和脂肪酸
St:ステアリン酸
O:オレイン酸
P:パルミチン酸
(17)油脂中のPOO含量が20重量%以下である、(16)に記載の冷菓被覆用油性食品素材、
(18)(16)ないし(17)いずれか1項に記載の冷菓被覆用油性食品素材を被覆してなる、冷菓、
である。
That is, the present invention
(1) An oily food material for coating a frozen dessert, wherein the triglyceride composition in fats and oils satisfies the following conditions 1 to 4,
1 to 10% by weight of StOO 2 8 to 30% by weight of triglyceride having a total carbon number of 30 to 38 of the constituent fatty acids
3 POP 15% or less 4 SUS 15% by weight and / or SUU less than 30% by weight
S: saturated fatty acid having 16 to 20 carbon atoms
U: unsaturated fatty acid having 16 to 18 carbon atoms
St: stearic acid
O: oleic acid
P: Oil food material for covering a frozen dessert according to (1), wherein the POO content in palmitic acid (2) fats and oils is 20% by weight or less,
(3) The oily food material for covering a frozen dessert according to (1), wherein the POO content in the fats and oils is 15% by weight or less,
(4) The oily food material for covering a frozen dessert according to (1), wherein the POP is 10% by weight or less,
(5) The oily food material for covering a frozen dessert according to (2), wherein the POP is 10% by weight or less,
(6) The oily food material for covering a frozen dessert according to (3), wherein the POP is 10% by weight or less,
(7) The oily food material for coating a frozen dessert according to (1), wherein the oil and fat content in the oily food material for coating a frozen dessert is 50% by weight or more,
(8) The oily food material for frozen dessert coating according to (2), wherein the oil and fat content in the oily food material for frozen dessert coating is 50% by weight or more,
(9) The oily food material for frozen dessert coating according to (3), wherein the oil and fat content in the oily food material for frozen dessert coating is 50% by weight or more,
(10) The oily food material for frozen dessert coating according to (4), wherein the oil and fat content in the oily food material for frozen dessert coating is 50% by weight or more,
(11) The oily food material for frozen dessert coating according to (5), wherein the oil and fat content in the oily food material for frozen dessert coating is 50% by weight or more,
(12) The oily food material for frozen dessert coating according to (6), wherein the oil and fat content in the oily food material for frozen dessert coating is 50% by weight or more,
(13) A frozen dessert comprising an oily food material for coating a frozen dessert according to (1),
(14) A frozen dessert comprising an oil-based food material for coating a frozen dessert according to (11),
(15) A frozen dessert comprising an oily food material for coating a frozen dessert according to (12),
In other words,
(16) An oily food material for coating a frozen dessert, wherein the triglyceride composition in fats and oils satisfies the following conditions 1 to 4,
1 to 10% by weight of StOO 2 8 to 30% by weight of triglyceride having a total carbon number of 30 to 38 of the constituent fatty acids
3 POP not more than 15% by weight 4 SUS less than 15% by weight, and / or SUU less than 30% by weight.
However,
S: saturated fatty acid having 16 to 20 carbon atoms
U: unsaturated fatty acid having 16 to 18 carbon atoms
St: stearic acid
O: oleic acid
P: Oil food material for covering a frozen dessert according to (16), wherein the POO content in palmitic acid (17) fat is 20% by weight or less,
(18) A frozen dessert, which is obtained by coating the oily food material for coating a frozen dessert according to any one of (16) to (17),
It is.

本発明によれば、製造時の作業性が良好でありながら、口溶けの良好なチョコレート類、およびこれを用いた冷菓が提供できる。さらに収縮によるひび割れ発生も抑制されるため、特に、全面コーティングされた形状であってもその商品価値が維持される。 According to the present invention, it is possible to provide good melt-in-the-mouth chocolates and frozen desserts using the same, while having good workability at the time of production. Furthermore, since the occurrence of cracking due to shrinkage is also suppressed, the commercial value is maintained even in the case of an entirely coated shape, in particular.

以下、本発明を具体的に説明する。 Hereinafter, the present invention will be specifically described.

本発明における冷菓被覆用油性食品素材とは、油脂が連続相をなす食品であり、特に、冷菓の表面全体あるいは一部を被覆(コーティング)するためのチョコレート類のことをいう。また、ここでのチョコレート類とは、規約(「チョコレート類の表示に関する公正競争規約」)ないし法規上の制約を受けるものではなく、ココアバター以外の動植物油脂を使用した各種チョコレート類および油脂加工食品、チョコレート製品を包含する。カカオマス、ココアバター、ココア、食用油脂類、糖類、粉乳、乳化剤、香料などの原材料を適宜配合し、常法によりチョコレート類を調製する。 The oily food material for covering a frozen dessert according to the present invention is a food in which fats and oils form a continuous phase, and particularly refers to chocolates for coating the whole or a part of the surface of the frozen dessert. In addition, chocolates here are not subject to the regulations ("fair competition rules for indication of chocolates") or legal restrictions, and various chocolates and oil-processed foods using animal and vegetable fats and oils other than cocoa butter , Including chocolate products. Raw materials such as cacao mass, cocoa butter, cocoa, edible fats and oils, sugars, milk powder, emulsifiers, flavors and the like are appropriately blended to prepare chocolates by a conventional method.

本発明の冷菓とは、冷凍温度域で喫食される菓子類であれば特にその種類は限定されないが、代表的には「乳及び乳製品の成分規格等に関する省令」、いわゆる「乳等省令」で規定される、アイスクリーム、アイスミルク、ラクトアイス、厚生省告示「食品、添加物等の規格基準」で規定される氷菓が挙げられる。 The type of the frozen dessert according to the present invention is not particularly limited as long as it is confectionery that is eaten in a frozen temperature range, but typically, "Ministerial Ordinance on Component Standards of Milk and Dairy Products", so-called "Ministry Ordinance" Ice cream, ice milk, lacto ice, and frozen desserts defined by the Ministry of Health and Welfare notification "standards of food, additives, etc.".

本発明の油性食品素材は、含有する油脂中のトリグリセリド組成が、下記条件のすべてを満たすことを特徴とする。なおここでの油脂とは配合する各種動植物油脂原料の他、ココアバター、カカオマス、ココア、粉乳、及びこれらの調整品に由来する油脂分を含む。
(1)StOOが10重量%以上
(2)構成脂肪酸の炭素数の合計が30〜38のトリグリセリドが10〜25重量%
(3)POPが15重量%以下
(4)SUSが15重量%未満、及び/又はSUUが30重量%未満
ただし、S:炭素数16〜20の飽和脂肪酸、U:炭素数16〜18の不飽和脂肪酸、St:ステアリン酸、O:オレイン酸、P:パルミチン酸をそれぞれ示す。
The oily food material of the present invention is characterized in that the triglyceride composition in the contained fat and oil satisfies all the following conditions. The fats and oils here include cocoa butter, cacao mass, cocoa, powdered milk, and fats and oils derived from these preparations, in addition to various animal and vegetable fats and oils raw materials to be blended.
(1) StOO is 10% by weight or more
(2) 10 to 25% by weight of triglyceride having a total of 30 to 38 carbon atoms of the constituent fatty acids
(3) POP is less than 15% by weight
(4) Less than 15% by weight of SUS and / or less than 30% by weight of SUU where S: saturated fatty acid having 16 to 20 carbon atoms, U: unsaturated fatty acid having 16 to 18 carbon atoms, St: stearic acid, O : Oleic acid, P: palmitic acid respectively.

以下、各項目についてさらに説明する。 Each item will be further described below.

(StOO)
StOO(1、2位、または2、3位の脂肪酸がO、3位または1位の脂肪酸がStのトリグリセリド)は、10重量%以上、好ましくは15重量%以上となるように配合することで、適度な乾きと割れにくさが両立可能となり、また、口溶けの良さも付与される。配合量の上限は特に制限されないが、他物性とのバランス等を考慮すると50重量%程度が適切である。StOOを含有する主な原料としては、シア脂、サル脂、イリッペ脂、マンゴ脂、サフラワー油、ヒマワリ油、大豆油、菜種油等を酵素的エステル交換や分別等により加工処理し単独又は適宜混合した油脂が例示できる。
(StOO)
StOO (1st or 2nd or 3rd or 3rd fatty acid is O, 3 or 1st fatty acid is a triglyceride of St) is blended so as to be 10% by weight or more, preferably 15% by weight or more It is compatible with moderate dryness and cracking, and good mouth melting is also imparted. The upper limit of the compounding amount is not particularly limited, but about 50% by weight is appropriate in consideration of the balance with other physical properties. Main raw materials containing StOO include shea butter, monkey fat, illipepe fat, mango fat, safflower oil, sunflower oil, soybean oil, rapeseed oil etc., processed by enzymatic transesterification or fractionation, etc. alone or mixed appropriately Can be exemplified.

(炭素数の合計)
構成脂肪酸の炭素数の合計が30〜38のトリグリセリド(すなわちC30、C32、C34、C36、C38の合計量)は、8〜30重量%、好ましくは10〜25重量%となるように配合する。これにより、冷菓の被覆工程における適度な固化性(乾き速度)と、ひび割れにくさを両立することが可能となる。なおここでの「構成脂肪酸の炭素数の合計」とは、1つのトリグリセリド分子を構成する炭素原子の総数から、グリセリンに由来する3つの炭素原子を除いた合計を意味する。
(Total number of carbons)
The triglyceride having a total carbon number of 30 to 38 (that is, the total amount of C30, C32, C34, C36, and C38) of the constituent fatty acids is blended so as to be 8 to 30% by weight, preferably 10 to 25% by weight. Thereby, it becomes possible to make compatible the moderate solidification property (drying speed) in the coating process of a frozen dessert, and hardness to cracking. Here, the "total carbon number of constituent fatty acids" means the total number of carbon atoms constituting one triglyceride molecule, excluding the three carbon atoms derived from glycerin.

(POP)
POP(1、3位の脂肪酸がP、2位の脂肪酸がOのトリグリセリド)は15重量%以下、より好ましくは10重量%以下となるように配合する。これより多いと割れやすく、また食感は硬く、口溶けも悪くなる場合がある。
(POP)
It is blended so that POP (a fatty acid in the 1st and 3rd positions is P, and a fatty acid in the 2nd position is a triglyceride of 0) is 15% by weight or less, more preferably 10% by weight or less. When it is more than this, it is easily broken, and the texture is hard, and the melting of the mouth may be worse.

(SUS、SUU)
SUS(2-不飽和、1,3−ジ飽和グリセリド)の含有量は15重量%未満、SUU(1-又は3-飽和、ジ不飽和グリセリド)は30重量%未満、どちらか少なくとも1つ、または両方の条件を満たすように配合する。両方の条件を外れると、割れにくさや口溶けが低下する場合がある。
(SUS, SUU)
The content of SUS (2-unsaturated, 1,3-disaturated glyceride) is less than 15% by weight, and SUU (1- or 3-saturated, diunsaturated glyceride) is less than 30% by weight, or at least one of them Or mix to meet both conditions. If both conditions are not satisfied, cracking and poor mouth melting may occur.

(POO)
さらに、POO(1、2位、または2、3位の脂肪酸がO、3位または1位の脂肪酸がPのトリグリセリド)は、20重量%以下、より好ましくは15重量%以下とすることが望ましい。これより多いと被覆後の乾きが低下する場合がある。
(POO)
Furthermore, it is desirable that the POO (the triglyceride at the 1, 2 or 3 position fatty acid O, the triglyceride at the 3 or 1 position fatty acid P) be at most 20 wt%, more preferably at most 15 wt% . If more than this, the dryness after coating may fall.

本発明の油性食品素材に用いる油脂原料としては、前述のトリグリセリド組成を満たすものであれば特に限定されないが、大豆油、綿実油、コーン油、サフラワー油、オリーブ油、パーム油、菜種油、米ぬか油、ゴマ油、カポック油、ヤシ油、パーム核油等の各種の植物油脂及びそれらの硬化油、分別油、エステル交換油等の加工油脂が例示でき、これらを単独ないしは適宜組み合わせて使用することができる。なお、油性食品素材中の油脂分は40重量%以上、好ましくは50重量%以上となるように配合する。これより少ないと被覆用として適した物性を得ることが困難となる。 The fat and oil material used for the oily food material of the present invention is not particularly limited as long as it satisfies the above-mentioned triglyceride composition, but soybean oil, cottonseed oil, corn oil, safflower oil, olive oil, palm oil, rapeseed oil, rice bran oil, Examples of various vegetable oils and fats such as sesame oil, kapok oil, coconut oil and palm kernel oil, and hydrogenated oils thereof and processed oils and fats such as fractionated oils and transesterified oils can be used alone or in combination as appropriate. The fat and oil content in the oily food material is 40% by weight or more, preferably 50% by weight or more. If it is less than this, it will be difficult to obtain physical properties suitable for coating.

以下に実施例および比較例を記載し、本発明をより詳細に説明する。また、例中の%及び部は断りのない限り重量基準を意味する。 The present invention will be described in more detail with reference to the following Examples and Comparative Examples. Also,% and parts in the examples mean weight basis unless otherwise noted.

(油性食品素材(チョコレート類)の調製)
表1に示す原材料配合に従い、常法にてロール掛け、コンチング処理を行い、それぞれチョコレート類を調製した。なお、粒度は18μm、粘度は300cp(40℃、B型粘度計、2号ロータ、30rpm)に調整した。また表中「植物油脂A」はStOO含有量約40%の油脂であり、原料としてはハイオレイックひまわり油とステアリン酸の1,3特異性リパーゼによるエステル交換油脂の分別低融点部を用いた。
(Preparation of oily food material (chocolate))
According to the raw material composition shown in Table 1, it rolled by a conventional method and performed conching processing, and prepared chocolates, respectively. The particle size was adjusted to 18 μm, and the viscosity was adjusted to 300 cp (40 ° C., B-type viscometer, No. 2 rotor, 30 rpm). Further, in the table, "vegetable oil A" is an oil having a StOO content of about 40%, and as a raw material, a low melting point portion of transesterified oil with high oleic sunflower oil and 1,3 specific lipase of stearic acid was used.

(アイスコーティングテスト)
チョコレート類は加温融解して40℃に調整し、市販のアイスクリームバーを用いたコーティングテストを実施した(室温20℃)。評価項目及び観点は下記の通りである。すべての項目について◎ないしは○であるものを合格とした。
(Ice coating test)
The chocolates were warmed and melted to adjust to 40 ° C., and a coating test was performed using a commercially available ice cream bar (room temperature 20 ° C.). Evaluation items and viewpoints are as follows. All items were rated ◎ or 合格.

(たれ終わり)
固化速度の指標として、チョコレートにアイスクリームバー全体を浸して引き揚げた時点から、表面からのたれ落ちが終了するまでの時間(秒数)を計測した。
◎:10秒未満
○:10秒以上、12秒未満
△:12秒以上、15秒未満
×:15秒以上
(Finish end)
As an indicator of the solidification rate, the time (seconds) from the point of immersion and withdrawal of the whole ice cream bar in chocolate to the end of falling from the surface was measured.
:: less than 10 seconds ○: 10 seconds or more, less than 12 seconds Δ: 12 seconds or more, less than 15 seconds ×: 15 seconds or more

(乾き)
固化速度の指標として、チョコレートにアイスクリームバー全体を浸して引き揚げた時点から、表面が固化して乾くまでの時間(秒数)を計測した。
◎:12秒未満
○:12秒以上、17秒未満
△:17秒以上、20秒未満
×:20秒以上
(Dry)
As an indicator of the solidification rate, the time (seconds) until the surface was solidified and dried was measured from the time when the whole ice cream bar was dipped and withdrawn in chocolate.
:: Less than 12 seconds ○: More than 12 seconds and less than 17 seconds Δ: More than 17 seconds and less than 20 seconds ×: More than 20 seconds

(目付量)
アイスクリームバーに付着したチョコレートの重量を測定し、予め設定した適正量(7g)との比較で判定した。
◎:適切(±10%以内)
○:やや多い(+10〜15%)
△:やや少ない(−10〜15%)
×:多すぎる、または少なすぎる(+15%以上、または−15%以下)
(Amount of weight)
The weight of the chocolate adhering to the ice cream bar was measured and judged by comparison with an appropriate amount (7 g) set in advance.
:: Appropriate (within ± 10%)
○: somewhat more (+10 to 15%)
:: somewhat less (-10 to 15%)
X: too much or too little (+ 15% or more, or -15% or less)

(収縮・割れ)
冷凍(-20℃)、7日保存後、収縮によるひび割れ発生の有無を目視にて観察した。
◎:ほとんどひび割れなし
○:小さなひび割れあるが、許容範囲
△:やや目立つひび割れあり
×:目立つひび割れあり
(Shrink and crack)
After freezing (−20 ° C.) and storage for 7 days, the occurrence of cracking due to shrinkage was visually observed.
:: almost no cracks ○: small cracks but acceptable range △: some noticeable cracks ×: some noticeable cracks

(口溶け)
冷凍(-20℃)、7日保存後、口溶けについて官能評価を行った。
◎:特に良好
○:良好
△:やや悪い
×:悪い
(Mouth melts)
After frozen (−20 ° C.) and stored for 7 days, sensory evaluation was performed for mouth melting.
:: particularly good ○: good △: somewhat bad ×: bad

(表1)

Figure 2019107014
(Table 1)
Figure 2019107014

(評価)
表1の実施例1〜4に示す通り、StOOを10重量%以上、かつC30〜C38の合計量を8〜30重量%となるように油脂を配合することで、すべての評価項目で合格となる品質が得られた。StOOの含有量が少ない配合では乾きが遅く(比較例1)、C30-38合計量の含有量を増やすことで乾きは改善されるが、多すぎると収縮・割れが発生した(比較例2)。また、StOOを10重量%以上配合しても、C30-C38合計量が少ないと乾きが遅くなっていた(比較例3、4、5)。
(Evaluation)
As shown in Examples 1 to 4 of Table 1, by blending the fats and oils so that StOO is 10% by weight or more and the total amount of C30 to C38 is 8 to 30% by weight, all evaluation items pass and Quality was obtained. Drying is slow when the content of the StOO content is small (Comparative Example 1), but drying is improved by increasing the content of the total amount of C30-38, but shrinkage and cracking occurred when the content is too large (Comparative Example 2) . Further, even when StOO was blended at 10 wt% or more, the drying was delayed when the total amount of C30-C38 was small (Comparative Examples 3, 4 and 5).

Claims (15)

油脂中のトリグリセリド組成が以下 (1)〜(4)の条件を満たす、冷菓被覆用油性食品素材。
(1)StOOが10重量%以上
(2)構成脂肪酸の炭素数の合計が30〜38のトリグリセリドが8〜30重量%
(3)POPが15重量%以下
(4)SUSが15重量%未満、及び/又はSUUが30重量%未満
ただし、
S:炭素数16〜20の飽和脂肪酸
U:炭素数16〜18の不飽和脂肪酸
St:ステアリン酸
O:オレイン酸
P:パルミチン酸
The oily food material for frozen dessert coating | cover whose triglyceride composition in fats and oils satisfy | fills the conditions of following (1)-(4).
(1) StOO is 10% by weight or more
(2) 8 to 30% by weight of triglyceride having a total of 30 to 38 carbon atoms of the constituent fatty acids
(3) POP is less than 15% by weight
(4) less than 15% by weight of SUS and / or less than 30% by weight of SUU;
S: saturated fatty acid having 16 to 20 carbon atoms
U: unsaturated fatty acid having 16 to 18 carbon atoms
St: stearic acid
O: oleic acid
P: Palmitic acid
油脂中のPOO含量が20重量%以下である、請求項1に記載の冷菓被覆用油性食品素材。 The oily food material for frozen dessert coating according to claim 1, wherein the POO content in the fats and oils is 20% by weight or less. 油脂中のPOO含量が15重量%以下である、請求項1に記載の冷菓被覆用油性食品素材。 The oily food material for covering a frozen dessert according to claim 1, wherein the POO content in the fats and oils is 15% by weight or less. 該POPが10重量%以下である、請求項1記載の冷菓被覆用油性食品素材。 The oily food material for frozen dessert coating according to claim 1, wherein the POP is 10% by weight or less. 該POPが10重量%以下である、請求項2記載の冷菓被覆用油性食品素材。 The oily food material for frozen dessert coating according to claim 2, wherein the POP is 10% by weight or less. 該POPが10重量%以下である、請求項3記載の冷菓被覆用油性食品素材。 The oily food material for frozen dessert coating according to claim 3, wherein said POP is 10% by weight or less. 該冷菓被覆用油性食品素材中の油脂分が50重量%以上である、請求項1記載の冷菓被覆用油性食品素材。 The oil-based food material for frozen dessert coating according to claim 1, wherein the fat and oil content in the oil-based food material for frozen dessert coating is 50% by weight or more. 該冷菓被覆用油性食品素材中の油脂分が50重量%以上である、請求項2記載の冷菓被覆用油性食品素材。 The oil-based food material for frozen dessert coating according to claim 2, wherein the fat and oil content in the oil-based food material for frozen dessert coating is 50% by weight or more. 該冷菓被覆用油性食品素材中の油脂分が50重量%以上である、請求項3記載の冷菓被覆用油性食品素材。 The oil-based food material for frozen dessert coating according to claim 3, wherein the fat and oil content in the oil-based food material for frozen dessert coating is 50% by weight or more. 該冷菓被覆用油性食品素材中の油脂分が50重量%以上である、請求項4記載の冷菓被覆用油性食品素材。 The oil-based food material for frozen dessert coating according to claim 4, wherein the fat and oil content in the oil-based food material for frozen dessert coating is 50% by weight or more. 該冷菓被覆用油性食品素材中の油脂分が50重量%以上である、請求項5記載の冷菓被覆用油性食品素材。 The oil-based food material for coating a frozen dessert according to claim 5, wherein the fat and oil content in the oil-based food material for coating a frozen dessert is 50% by weight or more. 該冷菓被覆用油性食品素材中の油脂分が50重量%以上である、請求項6記載の冷菓被覆用油性食品素材。 The oil-based food material for frozen dessert coating according to claim 6, wherein the fat and oil content in the oil-based food material for frozen dessert coating is 50% by weight or more. 請求項1記載の冷菓被覆用油性食品素材を被覆してなる、冷菓。 A frozen dessert comprising the oily food material for coating a frozen dessert according to claim 1 coated thereon. 請求項11記載の冷菓被覆用油性食品素材を被覆してなる、冷菓。 A frozen dessert, which is obtained by coating the oily food material for coating a frozen dessert according to claim 11. 請求項12記載の冷菓被覆用油性食品素材を被覆してなる、冷菓。 A frozen dessert comprising the oily food material for coating a frozen dessert according to claim 12 coated thereon.
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