JP2019076027A - Manufacturing method of milt-like foods - Google Patents

Manufacturing method of milt-like foods Download PDF

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JP2019076027A
JP2019076027A JP2017205894A JP2017205894A JP2019076027A JP 2019076027 A JP2019076027 A JP 2019076027A JP 2017205894 A JP2017205894 A JP 2017205894A JP 2017205894 A JP2017205894 A JP 2017205894A JP 2019076027 A JP2019076027 A JP 2019076027A
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protein
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soybean
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food
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水野 洋
Hiroshi Mizuno
洋 水野
佑美子 林
Yumiko Hayashi
佑美子 林
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Fuji Oil Co Ltd
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Fuji Oil Co Ltd
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Abstract

To provide a method of easily manufacturing milt-like foods, which is inexpensive, low in contents of purine body or cholesterol, and has texture and flavor specific for natural milt.SOLUTION: Milt-like foods having texture and flavor specific for milt by contacting an emulsified oil and fat composition containing soybean emulsified composition containing specific protein and lipid, soybean protein derived from a specific soybean protein raw material of which percentage of lipid compatible protein in soybean protein is reduced, oil and fat, a seasoning, and cation reactive polysaccharide, with a solution of a soluble cation raw material.SELECTED DRAWING: None

Description

本発明は、白子様食品に関し、魚類由来の白子を全く含有しない純植物性で、白子様の食感、風味を有する白子様食品の製造方法に関する。 TECHNICAL FIELD The present invention relates to a leuko-like food, and relates to a method of producing a leuko-like food having a texture and taste of white matter which is pure plant-like and does not contain any white matter derived from fish.

タラやふぐなどの白子は、その独特のなめらかな食感と風味から、天然の珍味食品として珍重がられる高級食材である。しかしながら、前記の魚類から得られるものであるため、供給量や供給時期に制限があり、比較的高価な食材として流通されている。 Shiroko, such as cod and pufferfish, is a high-grade food that is prized as a natural delicacy food because of its unique smooth texture and flavor. However, since it is obtained from the above-mentioned fish, the supply amount and the supply time are limited, and it is distributed as a relatively expensive food.

また、白子は前記の独特の食感、風味から一般大衆に好まれる食材ではあるが、プリン体やコレステロール含量がかなり高いものであるため、痛風などの疾患者には敬遠される食材であった。 In addition, although whitefish is a food that is preferred by the general public for its unique texture and flavor, it is a food that is avoided by people with diseases such as gout because it has a very high purine body and cholesterol content. .

上記より、安価でかつプリン体やコレステロール含量が低く、天然の白子様の独特の食感を有する白子様食品が検討されている。
特許文献1は、豆腐と海藻ペーストを加熱攪拌した混合物にアルギン酸及び寒天溶液の少なくとも一方を添加し、その混合物をカルシウムと酢と水で希釈した溶液に噴射し、溶液中で凝固させることを特徴とする加工食品の製造方法に関する。本方法により、表面のみが凝固し、白子のような外観の加工食品が得られることが記載されているが、海藻ペーストの調製が煩雑で、汎用性の高い方法とは言えないものであった。
From the above, it has been considered to be an inexpensive white food having a purine body and a low content of cholesterol and having a unique texture of natural white food.
Patent Document 1 is characterized in that at least one of alginic acid and agar solution is added to a mixture obtained by heating and stirring tofu and seaweed paste, and the mixture is sprayed into a solution diluted with calcium, vinegar and water to coagulate in the solution. The present invention relates to a method for producing processed food. According to this method, it is described that only the surface coagulates and a processed food having an appearance like white sheet is obtained, but the preparation of seaweed paste is complicated and can not be said to be a highly versatile method. .

特許文献2は、白子様食品ではないが、特許文献1同様の被覆外層を有する人工イクラ、人工キャビア等の人工魚卵を開示している。本方法は、例えば、それぞれ異なるゲル化剤を含有する内層ゾル、外層ゾルを2重管状ノズルから大気中に放出して粒子を形成し、これを塩化カルシウム溶液中に滴下することにより、ゲル化した粒子を人工魚卵として得る方法である。本方法によると、食したときに天然イクラ特有の膜の破裂感があり、色調、臭いも天然イクラ近似の人工魚卵が得られるが、白子様食品としては膜が強すぎる問題があり、さらに白子様風味を得る方法には言及されていなかった。 Patent Document 2 discloses artificial fish eggs such as artificial salmon roe, artificial caviar and the like having a coated outer layer similar to Patent Document 1, although they are not a leuko-like food. This method is, for example, gelation by releasing the inner layer sol and the outer layer sol containing different gelling agents into the atmosphere from a double tubular nozzle to form particles, which are dropped into a calcium chloride solution. Particles are obtained as artificial fish eggs. According to this method, when eaten, there is a feeling of rupture of a film unique to natural salmon roe, and artificial fish eggs with color tone and odor similar to those of natural salmon roe are obtained. No mention was made of how to obtain the flaky flavor.

特開2013−179904号公報JP, 2013-179904, A 特開平5−308930号公報Unexamined-Japanese-Patent No. 5-308930

本発明者らは、上記を踏まえて、さらに簡便に、安価でかつプリン体やコレステロール含量が低く、天然の白子様の独特の食感及び風味を有する白子様食品を得ることを課題とした。 Based on the above, the present inventors made it a task to obtain a leuko-like food which is simple, inexpensive, has low purine and cholesterol content, and has a unique texture and taste of natural leuko-like.

本発明者らは、上記課題解決に向けて鋭意検討した結果、特定の蛋白質及び脂質を含有する大豆乳化組成物、大豆蛋白質中の脂質親和性蛋白質の割合が低減された特定の大豆蛋白素材由来の大豆蛋白質、油脂、調味料及びカチオン反応性のある多糖類を含有する乳化油脂組成物を、可溶性カチオン素材の水溶液と接触させることにより、表面がゲル化され、白子様の独特の食感及び風味を有する白子様食品が得られることを見出し、本発明を完成させた。 As a result of intensive studies aimed at solving the above problems, the present inventors have derived a soybean emulsion composition containing a specific protein and lipid, and a specific soybean protein material origin in which the proportion of lipophilic protein in soybean protein is reduced. The surface is gelled by bringing the emulsified fat composition containing soy protein, fat and oil, seasoning and cationically reactive polysaccharide into contact with an aqueous solution of a soluble cationic material, and the white food like unique texture and The present inventors have completed the present invention by finding that a flavor-like white powder-like food can be obtained.

すなわち、本発明は、以下である。
(1) 下記の大豆乳化組成物A由来の蛋白質1.5〜4重量%、大豆蛋白素材B由来の蛋白質1.5〜4重量%、常温液状油脂1〜5重量%、調味料及びカチオン反応性のある多糖類0.5〜3重量%を含有する乳化油脂組成物の液滴を、可溶性カチオン素材の水溶液と接触させることを特徴とする、白子様食品の製造方法。
大豆乳化組成物A:乾物あたりの蛋白質含量が25重量%以上、脂質含量(クロロホルム/メタノール混合溶媒抽出物としての含量をいう。)が蛋白質含量に対して100重量%以上であって、LCI値(大豆蛋白質中の脂質親和性蛋白質含有割合)が55%以上である大豆乳化組成物。
大豆蛋白素材B:総蛋白質中の脂質親和性蛋白質の割合がLCI値として40%以下であり、脂質含量(クロロホルム/メタノール混合溶媒抽出物としての含量をいう。)が蛋白質含量に対して10重量%未満である大豆蛋白素材。
(2) 大豆乳化組成物A由来の蛋白質と大豆蛋白素材B由来の蛋白質の合計量が3〜8重量%であり、大豆乳化組成物A由来の蛋白質の大豆蛋白素材B由来の蛋白質に対する含有比率が0.3〜3である(1)記載の白子様食品の製造方法。
(3) カチオン反応性のある多糖類がアルギン酸ナトリウムであり、可溶性カチオン素材が塩化カルシウム若しくは乳酸カルシウムである、(1)または(2)記載の白子様食品の製造方法。
That is, the present invention is as follows.
(1) 1.5 to 4% by weight of protein derived from the following soybean emulsified composition A, 1.5 to 4% by weight of protein derived from soybean protein material B, 1 to 5% by weight of normal temperature liquid oil, seasoning and cationic reaction A method for producing a leuco-like food, which comprises bringing droplets of an emulsified oil composition containing 0.5 to 3% by weight of a soluble polysaccharide into contact with an aqueous solution of a soluble cationic material.
Soybean emulsified composition A: The protein content per dry matter is 25% by weight or more, the lipid content (refers to the content as a chloroform / methanol mixed solvent extract) is 100% by weight or more based on the protein content, and the LCI value The soybean emulsion composition whose (the content ratio of lipophilic protein in soybean protein) is 55% or more.
Soy protein material B: The ratio of the lipophilic protein in the total protein is 40% or less as LCI value, and the lipid content (refers to the content as chloroform / methanol mixed solvent extract) is 10 weight to the protein content Soy protein material which is less than%.
(2) The total content of the protein derived from soybean emulsified composition A and the protein derived from soybean protein material B is 3 to 8% by weight, and the content ratio of the protein derived from soybean emulsified composition A to the protein derived from soybean protein material B The method for producing a leuco-like food according to (1), wherein
(3) The method for producing a rattan-like food according to (1) or (2), wherein the cationically reactive polysaccharide is sodium alginate and the soluble cationic material is calcium chloride or calcium lactate.

本発明により、簡便に、安価でかつプリン体やコレステロール含量が低く、天然の白子様の独特の食感及び風味を有する白子様食品の製造方法の提供が可能となった。 According to the present invention, it has become possible to simply provide an inexpensive method for producing a leuko-like food having a low texture of purine and cholesterol and having a unique texture and taste of natural leuko-like.

本発明は、大豆乳化組成物A由来の蛋白質1.5〜4重量%、大豆蛋白素材B由来の蛋白質1.5〜4重量%、常温液状油脂1〜5重量%、調味料及びカチオン反応性のある多糖類0.5〜3重量%を含有する乳化油脂組成物の液滴を、可溶性カチオン素材の水溶液と接触させることを特徴とする、白子様食品の製造方法である。以下、本発明を詳細に説明する。 The present invention comprises 1.5 to 4% by weight of protein derived from soybean emulsion composition A, 1.5 to 4% by weight of protein derived from soybean protein material B, 1 to 5% by weight of normal temperature liquid oil, seasoning and cationic reactivity The method is a method for producing a plague-like food, which comprises bringing droplets of an emulsified oil composition containing 0.5 to 3% by weight of a certain polysaccharide into contact with an aqueous solution of a soluble cationic material. Hereinafter, the present invention will be described in detail.

(大豆乳化組成物A)
本発明に用いる大豆乳化組成物Aとは、豆乳のように大豆蛋白質が脂質と乳化されている素材のうち、乾物あたりの蛋白質含量が25重量%以上、脂質含量が蛋白質含量に対して100重量%以上であることを特徴とするものである。
なお、水溶性窒素指数(NSI:Nitrogen Solubility Index)が特定の範囲になるまであらかじめ変性処理を施した大豆から得られるものが特に好ましい。このような原料から得られる大豆乳化組成物は、含まれる大豆蛋白質のうち、グリシニンやβ-コングリシニン以外の脂質親和性蛋白質(あるいは別の指標としてリポキシゲナーゼ蛋白質)の割合が特に高く、このため、中性脂質および極性脂質を多く含む乳化組成物である。すなわち、乾物あたりの蛋白質含量が25重量%以上、脂質含量が蛋白質含量に対して100重量%以上であって、LCI値(Lipophilic Proteins Content Index)が55%以上、より好ましくは60%以上であることを主要な特徴とするものである。ここで、LCI値は、蛋白質中の脂質親和性蛋白質の割合を推定する指標である。LCI値の測定方法及び大豆乳化組成物の蛋白質および脂質の組成の詳細については、特開2013-143931号公報の記載を援用する。
(Soy emulsion composition A)
The soybean emulsion composition A used in the present invention is a material such as soybean milk in which soybean protein is emulsified with lipids, the protein content per dry matter is 25% by weight or more, and the lipid content is 100% with respect to the protein content % Or more.
In addition, what is obtained from the soybean which modified | denatured-processed previously until water-soluble nitrogen index (NSI: Nitrogen Solubility Index) becomes a specific range is especially preferable. The soybean emulsion composition obtained from such a raw material has a particularly high proportion of lipophilic protein (or lipoxygenase protein as another index) other than glycinin and β-conglycinin among contained soybean proteins, so It is an emulsion composition containing a large amount of lipid and polar lipid. That is, the protein content per dry matter is 25% by weight or more, the lipid content is 100% by weight or more with respect to the protein content, and the LCI value (Lipophilic Proteins Content Index) is 55% or more, more preferably 60% or more Is the main feature. Here, the LCI value is an index for estimating the proportion of the lipophilic protein in the protein. The description of Japanese Patent Application Laid-Open No. 2013-143931 is incorporated for details of the method of measuring the LCI value and the composition of the protein and lipid of the soybean emulsion composition.

(大豆乳化組成物Aの蛋白質)
本発明に用いられる大豆乳化組成物Aの蛋白質含量は乾物あたり25重量%以上、好ましくは30重量%以上である。また蛋白質含量の上限は限定されないが、好ましくは50重量%以下、より好ましくは40重量%以下である。
本発明における蛋白質含量はケルダール法により窒素量として測定し、該窒素量に6.25の窒素換算係数を乗じて求めるものとする。
(Protein of soybean emulsified composition A)
The protein content of the soybean emulsion composition A used in the present invention is 25% by weight or more, preferably 30% by weight or more, per dry matter. The upper limit of the protein content is not limited, but is preferably 50% by weight or less, more preferably 40% by weight or less.
The protein content in the present invention is determined as the amount of nitrogen by the Kjeldahl method, and is determined by multiplying the amount of nitrogen by a nitrogen conversion factor of 6.25.

(大豆乳化組成物Aの脂質)
本発明に用いられる大豆乳化組成物Aの脂質含量は蛋白質含量に対して100重量%以上、好ましくは120〜300重量%、さらに好ましくは120〜200重量%であり、蛋白質よりも脂質が多いことが特徴である。
一般に脂質含量はエーテル抽出法で測定されるが、大豆乳化組成物中には中性脂質のほかにエーテルで抽出されにくい極性脂質も多く含まれるため、本発明における脂質含量は、クロロホルム:メタノールが2:1(体積比)の混合溶媒を用い、常圧沸点において30分間抽出された抽出物量を総脂質量として、脂質含量を算出した値とする。溶媒抽出装置としてはFOSS社製の「ソックステック」を用いることができる。
(Fat of soybean emulsified composition A)
The lipid content of the soybean emulsion composition A used in the present invention is 100% by weight or more, preferably 120 to 300% by weight, more preferably 120 to 200% by weight with respect to the protein content, and contains more lipid than protein. Is a feature.
Generally, the lipid content is measured by the ether extraction method, but since the soybean emulsion composition contains a large amount of polar lipids which are difficult to extract with ether in addition to neutral lipids, the lipid content in the present invention is chloroform: methanol The amount of extract extracted for 30 minutes at normal pressure boiling point is a total lipid amount using a mixed solvent of 2: 1 (volume ratio), and this is the calculated value of the lipid content. As a solvent extraction apparatus, "Sock Tech" manufactured by FOSS can be used.

(大豆乳化組成物Aの乾物含量)
本発明に用いられる大豆乳化組成物Aは通常生クリーム様の性状であり、通常の乾物(dry matter)は15〜30重量%程度であるが、特に限定されるものではない。すなわち加水により低粘度の液状としたものや、濃縮加工されてより高粘度のクリーム状としたものであってもよく、また粉末加工されて粉末状としたものであってもよい。
(Dry matter content of soybean emulsion composition A)
The soybean emulsion composition A used in the present invention usually has a fresh cream-like property, and the usual dry matter is about 15 to 30% by weight, but it is not particularly limited. That is, it may be a liquid having a low viscosity by water, a cream having a higher viscosity after being concentrated and processed, or a powder having a powder processed.

(大豆乳化組成物Aの製造態様)
本発明に用いられる、上記特定の豆乳化組成物は、例えば全脂大豆に加水して懸濁液や豆乳を調製した後、遠心分離機によって分画し、比重が軽い上層部分を取り分けることにより得ることができる。
また、LCI値が55%以上の大豆乳化組成物を効率的に得るには、特定の性質をもつ大豆を原料として使用する。例えば水溶性窒素指数(Nitrogen Solubility Index)が20〜77など、特定の水溶性蛋白を含みかつ乾物あたりの脂質含量が15重量%以上の全脂大豆などの含脂大豆に対して、加水して懸濁液を調製する工程の後、該懸濁液を固液分離し、中性脂質及び極性脂質を不溶性画分に移行させて、蛋白質及び糖質を含む水溶性画分を除去し、不溶性画分を回収することにより得ることができる。この製造態様の詳細については特開2013-143931号報の記載を援用する。
(Manufacturing aspect of soybean emulsion composition A)
The above-mentioned specific soybean emulsified composition used in the present invention is prepared, for example, by adding water to full fat soybean to prepare a suspension or soymilk, and fractionating it with a centrifugal separator to separate the upper layer portion having a low specific gravity. You can get it.
In addition, in order to efficiently obtain a soybean emulsion composition having an LCI value of 55% or more, soybean having a specific property is used as a raw material. For example, water-soluble soybeans such as whole-fat soybeans containing a specific water-soluble protein and having a lipid content per dry matter of 15% by weight or more, such as a water-soluble nitrogen index (Nitrogen Solubility Index) of 20 to 77, After the step of preparing the suspension, the suspension is subjected to solid-liquid separation, and neutral lipids and polar lipids are transferred to the insoluble fraction to remove the water-soluble fraction containing proteins and carbohydrates, and insoluble It can be obtained by collecting fractions. For the details of this production mode, the description in JP-A-2013-143931 is incorporated.

(大豆蛋白素材B)
本発明の原料として使用される特定の大豆蛋白素材Bは、大豆から水抽出されるグリシニン及びβ−コングリシニンを主体とする蛋白質を主な構成成分とし、かつ総蛋白質中の脂質親和性蛋白質の割合が少ないものである。
すなわち、総蛋白質中の脂質親和性蛋白質の割合がLCI値として40%以下であることを特徴とする大豆蛋白素材である。
(大豆蛋白素材Bの製品形態)
大豆蛋白素材Bの製品の形態としては上記要件を満たす限り特に限定されず、具体的には豆乳が挙げられるが、豆乳以外の形態としては、該豆乳を原料としてさらに蛋白質の純度を高めた形態が挙げられ、典型的には豆乳から糖質、灰分等の水溶性成分を除去して蛋白質の純度を高めた分離大豆蛋白や、前記豆乳あるいは分離大豆蛋白の蛋白質をさらに分画してグリシニンあるいはβ−コングリシニンの純度を高めた分画大豆蛋白の形態が挙げられる。
(Soy protein material B)
The specific soybean protein material B used as a raw material of the present invention is mainly composed of glycinin and β-conglycinin-based proteins extracted from soybeans as a main component, and the proportion of the lipophilic protein in the total protein There is little
That is, it is a soy protein material characterized in that the proportion of the lipophilic protein in the total protein is 40% or less as LCI value.
(Product form of soy protein material B)
The form of the product of the soy protein material B is not particularly limited as long as the above requirements are satisfied, and specific examples include soymilk, but as a form other than soymilk, a form in which the purity of protein is further increased using the soymilk as a raw material The soybean protein is typically separated from soymilk by removing water-soluble components such as carbohydrates and ash from the soymilk to increase the purity of the protein, and further fractionating the protein of the soymilk or the separated soy protein to obtain glycinin or The form of fractionated soybean protein which raised the purity of (beta)-conglycinin is mentioned.

(大豆蛋白素材Bの蛋白質)
大豆蛋白素材Bの蛋白質含量は乾物あたりで30〜99重量%の範囲が好ましい。大豆蛋白素材が豆乳の形態の場合、通常は下限が乾物あたり45重量%以上、あるいは50重量%以上、あるいは55重量%以上であり、上限が70重量%以下、あるいは65重量%以下でありうる。蛋白質の分画や他の成分の添加など、加工方法によっては30重量%以上45重量%未満の範囲にもなりうる。また大豆蛋白素材が当該豆乳をさらに精製して蛋白質純度を高めた分離大豆蛋白の形態の場合は、下限が70重量%超、あるいは80重量%以上であり、上限は99重量%以下、あるいは95重量%以下でありうる。なお、本発明における蛋白質含量はケルダール法により窒素量として測定し、該窒素量に6.25の窒素換算係数を乗じて求めるものとする。
(Protein of soy protein material B)
The protein content of the soy protein material B is preferably in the range of 30 to 99% by weight per dry matter. When the soy protein material is in the form of soy milk, the lower limit is usually 45% by weight or more, 50% by weight or more, 55% by weight or more per dry matter, and the upper limit may be 70% by weight or less or 65% by weight or less . Depending on the processing method, such as protein fractionation or addition of other components, it may be in the range of 30% by weight or more and less than 45% by weight. When the soy protein material is in the form of separated soy protein in which the protein purity is increased by further purifying the soymilk, the lower limit is 70% by weight, or 80% by weight or more, and the upper limit is 99% by weight or less, or 95 It may be at most weight percent. The protein content in the present invention is determined as the amount of nitrogen by the Kjeldahl method, and the amount of nitrogen is determined by multiplying the amount of nitrogen conversion by a nitrogen conversion factor of 6.25.

脂質親和性蛋白質は、大豆の主要な酸沈殿性大豆蛋白質の内、グリシニン(7Sグロブリン)とβ−コングリシニン(11Sグロブリン)以外のマイナーな酸沈殿性大豆蛋白質群をいい、レシチンや糖脂質などの極性脂質を多く随伴するものである。以下、単に「LP」と略記することがある。
LPは雑多な蛋白質が混在したものであるが故、各々の蛋白質を全て特定し、LPの含量を厳密に測定することは困難であるが、下記LCI(Lipophilic Proteins Content Index:大豆蛋白質中の脂質親和性蛋白質含有割合))値を求めることにより推定することができる。
これによれば、大豆蛋白素材B中の蛋白質のLCI値は通常40%以下、より好ましくは38%以下、さらに好ましくは36%以下である。
通常の未変性(NSI 90以上)の大豆を原料として一般的な大豆蛋白素材を製造する場合ではLPは可溶性の状態で存在するため、水抽出すると水溶性画分側へ抽出される。一方、大豆蛋白素材Bでは、LPを原料大豆中において加熱処理によって変性させ不溶化させて製造するため、LPが抽出されにくく不溶性画分側に残る。
このように蛋白質中におけるLPの割合を低減することによって脂質の含有量を極めて低レベルに保った大豆蛋白素材を得ることがきる。LP含量の推定方法及びLCI値の測定方法は、特開2013-143931号報の記載を援用する。
Lipophilic proteins are the major acid-precipitable soy proteins of soybean, which are minor acid-precipitable soy protein groups other than glycinin (7S globulin) and β-conglycinin (11S globulin), such as lecithin and glycolipids. It is accompanied by many polar lipids. Hereinafter, it may be simply abbreviated as "LP".
Since LP is a mixture of miscellaneous proteins, it is difficult to identify all the individual proteins and to measure the content of LP strictly. However, the following LCI (Lipophilic Proteins Content Index: lipids in soy protein) It can be estimated by determining the affinity protein content ratio) value.
According to this, the LCI value of the protein in the soy protein material B is usually 40% or less, more preferably 38% or less, and still more preferably 36% or less.
In the case of producing a general soybean protein material by using a normal non-denatured (NSI 90 or more) soybean as a raw material, since LP exists in a soluble state, when it is extracted with water, it is extracted to the water soluble fraction side. On the other hand, in the case of soy protein material B, LP is produced by being denatured and insolubilized by heat treatment in raw soybean, so that LP is difficult to extract and remains on the insoluble fraction side.
By thus reducing the proportion of LP in the protein, it is possible to obtain a soy protein material in which the lipid content is kept at a very low level. The method of estimating the LP content and the method of measuring the LCI value use the description of JP-A-2013-143931.

大豆蛋白素材Bは糖質及び蛋白質が乾物の大部分を占める主成分であることができ、この場合は炭水化物(乾物から脂質、蛋白質及び灰分を除いたもの)の含量は、蛋白質との総含量で表すと乾物あたり80重量%以上が好ましく、より好ましくは85重量%以上である。乾物の残成分は灰分と微量の脂質からほぼ構成され、灰分は乾物当たり通常15重量%以下、好ましくは10重量%以下である。食物繊維は炭水化物に含まれるものの、大豆蛋白素材Aは食物繊維質が除去されているので、乾物当たり3重量%以下、好ましくは2重量%以下の微量である。 Soy protein material B can be the main component in which the carbohydrate and protein occupy the majority of the dry matter, in which case the content of carbohydrate (dry matter minus lipid, protein and ash content) is the total content with protein When it represents, 80 weight% or more is preferable per dry matter, More preferably, it is 85 weight% or more. The remaining components of the dry matter consist essentially of ash and traces of lipids, and the ash content is usually at most 15% by weight, preferably at most 10% by weight, based on dry matter. Although dietary fiber is contained in carbohydrates, soy protein material A has a trace amount of 3% by weight or less, preferably 2% by weight or less, based on dry matter, since dietary fiber is removed.

(大豆蛋白素材Bの脂質)
大豆蛋白素材Bは、原料である大豆粉の脂質含量/蛋白質含量の比よりも低い値の脂質しか含まれず、中性脂質と共に極性脂質の含量も低いことが好ましい。これに対し、一般に脱脂豆乳などは大豆をヘキサンで脱脂した脱脂大豆を水抽出して得られるが、この脱脂豆乳は極性脂質が除去されておらずなお多く含まれる。
そのため、大豆蛋白素材B中の脂質含量は、試料を凍結乾燥後、クロロホルム:メタノールが2:1(体積比)の混合溶媒を用い、常圧沸点において30分間抽出された抽出物量を総脂質量として、脂質含量を算出した値とする。溶媒抽出装置としてはFOSS社製の「ソックステック」を用いることができる。なお上記の測定法は「クロロホルム/メタノール混合溶媒抽出法」と称するものとする。
(Lipid of soy protein material B)
It is preferable that the soybean protein material B contains only a lipid having a value lower than the ratio of the lipid content / protein content of soybean powder which is the raw material, and that the content of polar lipids as well as neutral lipids is also low. In contrast, defatted soymilk is generally obtained by extracting the defatted soybean obtained by defatting soybean with hexane, and this defatted soymilk is still contained in a large amount without removal of polar lipids.
Therefore, the lipid content in soy protein material B is the total amount of lipid extracted for 30 minutes at normal pressure boiling point using a mixed solvent of chloroform: methanol 2: 1 (volume ratio) after freeze-drying the sample It is assumed that the lipid content is calculated. As a solvent extraction apparatus, "Sock Tech" manufactured by FOSS can be used. The above measurement method is referred to as “chloroform / methanol mixed solvent extraction method”.

大豆蛋白素材Bは、脂質含量が蛋白質含量に対して10重量%未満が好ましく、より好ましくは9重量%未満、さらに好ましくは8重量%未満、さらに好ましくは5重量%未満、さらに好ましくは4重量%以下であり、3重量%以下とすることも可能である。すなわち蛋白質よりも中性脂質と極性脂質を含めた総脂質が極めて少ない大豆蛋白素材が1つの好ましい態様である。LPが少なくかつ総脂質が少ない大豆蛋白素材を乳酸発酵に供することにより、青臭みが極めて感じにくいすっきりとした風味の乳酸発酵物を得ることができる。このような素材としては、例えば特開2012−16348号に開示される「減脂大豆蛋白素材」が該当する。通常の有機溶剤を用いて脱脂された脱脂大豆から抽出した脱脂豆乳も中性脂質は殆ど含まれないが、極性脂質が一部抽されるため、蛋白質に対する脂質含量はおよそ5〜6重量%である。この態様の場合、乾物あたりでの脂質含量も5重量%以下が好ましく、好ましくは3重量%以下、より好ましくは2重量%以下、さらに好ましくは1.5重量%以下でありうる。 The soy protein material B preferably has a lipid content of less than 10% by weight, more preferably less than 9% by weight, still more preferably less than 8% by weight, still more preferably less than 5% by weight, still more preferably 4% by weight. % Or less and 3 wt.% Or less are also possible. That is, a soy protein material in which total lipids including neutral lipids and polar lipids are extremely less than proteins is one preferred embodiment. By providing a soy protein material having a small amount of LP and a small amount of total lipids for lactic acid fermentation, it is possible to obtain a lactic acid fermented product having a clean flavor that is extremely hard to feel a bluish smell. As such a raw material, for example, "Reduced soybean protein material" disclosed in JP 2012-16348A corresponds. Although defatted soymilk extracted from defatted soybeans defatted with ordinary organic solvents contains almost no neutral lipids, it has a lipid content of approximately 5 to 6% by weight, since polar lipids are partially extracted. is there. In this embodiment, the lipid content per dry matter is also preferably 5% by weight or less, preferably 3% by weight or less, more preferably 2% by weight or less, and further preferably 1.5% by weight or less.

(大豆蛋白素材Bの乾物含量)
大豆蛋白素材Bが豆乳の形態で、性状が液体の場合、乾物(dry matter)は通常3〜20重量%程度であるが、特に限定されるものではない。すなわち加水して低粘度の液状としたものや、減圧濃縮や凍結濃縮等の濃縮加工により高粘度化したものであってもよく、また噴霧乾燥や凍結乾燥等の粉末加工により粉末状としたものであってもよい。
(Dry matter content of soy protein material B)
When the soy protein material B is in the form of soymilk and the property is liquid, the dry matter (dry matter) is usually about 3 to 20% by weight, but it is not particularly limited. That is, it may be a liquid having a low viscosity by hydrolysis, or one having a high viscosity by concentration processing such as vacuum concentration or freeze concentration, or may be powdered by powder processing such as spray drying or lyophilization. It may be

本発明において、大豆乳化組成物A及び大豆蛋白素材Bを併用して白子様食品を調製するが、大豆乳化組成物A由来の蛋白質含量は1.5〜4重量%であり、より好ましくは2〜4重量%、最も好ましくは2〜3.5重量%である。下限未満では、濃厚感に乏しくなり、淡白な風味になる傾向がある。逆に上限を超えると豆乳感がやや強すぎて、違和感のある風味の白子様食品となる傾向にある。また、大豆蛋白素材B由来の蛋白質含量は1.5〜4重量%であり、より好ましくは2〜4重量%、最も好ましくは2〜3.5重量%である。下限未満では、豆乳感がやや強すぎて、違和感のある風味の白子様食品となる傾向にある。逆に上限を超えると、濃厚感が低下し、淡白な風味になる傾向がある。 In the present invention, the emulsified product A and the soy protein material B are used in combination to prepare a leuko-like food, but the protein content derived from the emulsified product A is 1.5 to 4% by weight, more preferably 2 ~ 4 wt%, most preferably 2 to 3.5 wt%. Below the lower limit, there is a tendency for the richness to be poor and to have a pale taste. On the other hand, if the upper limit is exceeded, the soymilk sensation is a little too strong, and it tends to be an odd white food with an unpleasant flavor. The protein content derived from the soy protein material B is 1.5 to 4% by weight, more preferably 2 to 4% by weight, and most preferably 2 to 3.5% by weight. Below the lower limit, the soymilk taste is a little too strong, and it tends to be an odd white food with an unpleasant flavor. On the other hand, if the upper limit is exceeded, the richness tends to be reduced and it tends to be pale.

本発明において、大豆乳化組成物A由来の蛋白質と大豆蛋白素材B由来の蛋白質の合計量は3〜8重量%であるのが好ましく、より好ましくは4〜7重量%である。合計量が3重量%未満であると、濃厚感に乏しく、淡白な風味になる傾向がある。逆に、8重量%を超えると豆乳感がやや強すぎて、違和感のある風味の白子様食品となる傾向にある。 In the present invention, the total amount of the protein derived from the soybean emulsion composition A and the protein derived from the soybean protein material B is preferably 3 to 8% by weight, more preferably 4 to 7% by weight. If the total amount is less than 3% by weight, it tends to have a poor sense of richness and a pale taste. On the other hand, if it exceeds 8% by weight, the soymilk taste is a little too strong, and it tends to be a childlike food with an unpleasant flavor.

大豆乳化組成物A由来の蛋白質の大豆蛋白素材B由来の蛋白質に対する含有比率は、0.3〜3であるのが好ましく、より好ましくは0.5〜2.5である。含有比率が0.3未満であると、濃厚感に乏しくなり、淡白な風味になる傾向がある。逆に上限を超えると豆乳感がやや強すぎて、違和感のある風味の白子様食品となる傾向にある。 The content ratio of the protein derived from the soybean emulsion composition A to the protein derived from the soy protein material B is preferably 0.3 to 3, and more preferably 0.5 to 2.5. When the content ratio is less than 0.3, the rich feeling tends to be poor and the light and white flavor tends to be obtained. On the other hand, if the upper limit is exceeded, the soymilk sensation is a little too strong, and it tends to be an odd white food with an unpleasant flavor.

本発明において、大豆乳化組成物Aと大豆蛋白素材Bを併用して白子様食品を調製するが、その調製の一態様は以下の通りである。
大豆乳化組成物Aとして、例えば特開2013-143931号公報の記載の生クリーム様性状の大豆乳化組成物(乾物含量15〜30重量%、乾物中の蛋白質含量25〜50重量%、乾物中の脂質含量40〜75重量%)を使用し、大豆蛋白素材Bとして、例えば特開2012−16348号公報記載の減脂大豆蛋白素材(乾物含量3〜20重量%、乾物中の蛋白質含量45〜70重量%、乾物中の脂質含量10重量%以下)使用する場合は、大豆乳化組成物A30〜70重量部と大豆蛋白素材B70〜30重量部を調合し、好ましくは大豆乳化組成物Aと大豆蛋白素材Bの合計量を80〜98重量部となるよう調合することにより、目的とする白子様食品を得ることができる。
In the present invention, a lecithin-like food product is prepared by using soybean emulsion composition A and soybean protein material B in combination, and one aspect of the preparation is as follows.
As the soybean emulsion composition A, for example, a cream-like soybean emulsion composition described in JP-A-2013-143931 (dry matter content 15 to 30% by weight, protein content in dry matter 25 to 50% by weight, dry matter) Using a lipid content of 40 to 75% by weight), as a soybean protein material B, for example, a reduced-fat soybean protein material (dry matter content 3 to 20% by weight, protein content in dry matter 45 to 70 described in JP-A-2012-16348). % By weight, lipid content in dry matter 10% by weight or less) When used, 30 to 70 parts by weight of soybean emulsion composition A and 70 to 30 parts by weight of soybean protein material B are prepared, preferably soybean emulsion composition A and soybean protein By preparing the total amount of the raw material B to be 80 to 98 parts by weight, it is possible to obtain the target white powder-like food.

本発明における白子様食品を調製する別の一態様は、大豆乳化組成物Aとして前記生クリーム様性状の大豆乳化組成物に代えて、その濃縮物や乾燥粉末を使用することができる。また、大豆蛋白素材Bとして前記減脂大豆蛋白素材に代えて、その濃縮物や乾燥粉末を使用することができる。かかる濃縮物や乾燥粉末を使用する場合は、大豆乳化組成物Aと大豆蛋白素材B由来の蛋白質含量を調整するよう適量の水に分散、溶解して、白子様食品用の乳化油脂組成物を調製することができる。 In another embodiment of preparing the leuko-like food according to the present invention, a concentrate or dry powder thereof can be used as the soy emulsion composition A in place of the above-mentioned cream-like soy emulsion composition. Moreover, it can replace with the said fat-reduced soy protein raw material as the soy protein raw material B, and can use the concentrate and dry powder. When using such a concentrate or dry powder, it is dispersed and dissolved in an appropriate amount of water so as to adjust the protein content derived from the soybean emulsified composition A and the soybean protein material B, It can be prepared.

(油脂)
本発明の白子様食品は、上昇融点が20℃以下の常温液状油脂を1〜5重量%、好ましくは2〜4重量%、含有するものである。かかる油脂を含有することにより、白子様食品に適度なコク味と旨味を付与することができる。常温液状油脂としては、ナタネ油、大豆油、ひまわり油、綿実油、落花生油、米糠油、コーン油、サフラワー油、オリーブ油、カポック油、胡麻油、月見草油、パーム油、シア脂、サル脂、カカオ脂、ヤシ油、パーム核油等の植物性油脂、乳脂、牛脂、豚脂、魚油、鯨油等の動物性油脂、及び藻類由来油脂が例示でき、これらの油脂の単独または混合油あるいは分別、エステル交換を施した加工油脂も使用することができる。常温液状油の含有量が1重量%未満であると、白子様食品のコク味と旨味が低下して物足りない風味になる。逆に、5重量%を超えるとやや油っぽい食感になる傾向がある。
(Fat and oil)
The white powder-like food of the present invention contains 1 to 5% by weight, preferably 2 to 4% by weight, of a normal temperature liquid oil having a rising point of not more than 20 ° C. By containing such fats and oils, it is possible to impart an appropriate rich taste and umami taste to the white food. Examples of normal temperature liquid oil include rapeseed oil, soybean oil, sunflower oil, cottonseed oil, peanut oil, rice bran oil, corn oil, safflower oil, olive oil, kapok oil, sesame oil, evening primrose oil, palm oil, shea butter, monkey fat, cocoa Examples are vegetable fats and oils such as coconut oil and palm kernel oil, animal fats and oils such as milk fat, beef tallow, pork fat, pork fat, fish oil and soy sauce, and algae-derived fats and oils. It is also possible to use processed processed fats and oils. When the content of the normal temperature liquid oil is less than 1% by weight, the body and the taste of the white-collar-like food are reduced to give an unsatisfactory flavor. On the other hand, if it exceeds 5% by weight, it tends to have a slightly oily texture.

常温液状油脂として、DHA(ドコサヘキサエン酸)やEPA(エイコサペンタエン酸)を含有する魚油や藻類由来油脂を使用することにより、DHA,EPAを含有する健康指向にマッチした白子様食品を得ることができる。特に、藻類由来油脂を用いることにより、白子に近似するような適度な生臭味と魚臭を白子様食品に付与することもできる。常温液状油脂として、魚油そのものを用いると、魚油由来の劣化臭が強く出すぎる傾向にある。 By using fish oil and algae-derived fat and oil containing DHA (docosahexaenoic acid) and EPA (eicosapentaenoic acid) as normal temperature liquid fat and oil, it is possible to obtain a health-matched white-collar-like food containing DHA and EPA. . In particular, by using algae-derived fats and oils, it is possible to impart a moderate fresh odor and fishy odor similar to that of larch to a larch-like food. When fish oil itself is used as the normal temperature liquid oil, the deterioration odor derived from fish oil tends to be too strong.

(調味料)
本発明の白子様食品は、適量の調味料を含有するものである。調味料としては、昆布、かつお節、魚粉由来の和風だしの素の顆粒または粉末タイプのものが使い勝手が良く、添加量としては白子様食品に対して0.5〜2重量%が適当である。かかる調味料添加により、白子様食品に適度な香りと旨味を付与することができる。
(seasoning)
The white-collar-like food of the present invention contains an appropriate amount of seasoning. As seasonings, it is convenient to use granules or powder type of kelp, dried bonito, Japanese-style soup stock derived from fish powder, and the addition amount is preferably 0.5 to 2% by weight with respect to the Shirako-like food. By adding such a seasoning, it is possible to impart an appropriate flavor and taste to the Shirako-like food.

(カチオン反応性のある多糖類)
本発明に用いるカチオン反応性のある多糖類とは、可溶性カチオン素材とそれぞれ水溶液で接触させることにより、速やかにゲルを形成するものであり、カラギナン、LMペクチン、ジェランガム、アルギン酸ナトリウムなどが例示できる。特に、冷水でも速やかにゲル形成するアルギン酸ナトリウムの利用が好ましいが、かかるカチオン反応性のある多糖類の白子様食品用の乳化油脂組成物に対する添加量は0.1〜3重量%、好ましくは0.5〜2重量%である。
(Polysaccharides with cationic reactivity)
The cationically reactive polysaccharide used in the present invention is one which forms a gel rapidly by contacting with a soluble cationic raw material respectively in an aqueous solution, and carrageenan, LM pectin, gellan gum, sodium alginate and the like can be exemplified. In particular, it is preferable to use sodium alginate which rapidly forms a gel even in cold water, but the addition amount of such cationically reactive polysaccharides to the emulsified oil composition for white food is 0.1 to 3% by weight, preferably 0. 0.5 to 2% by weight.

本発明に用いる可溶性カチオン素材としては、塩化カルシウム、乳酸カルシウムが例示でき、可溶性カチオン素材の水溶液濃度は0.1〜5重量%、好ましくは0.5〜2重量%である。 Examples of the soluble cationic material used in the present invention include calcium chloride and calcium lactate. The aqueous solution concentration of the soluble cationic material is 0.1 to 5% by weight, preferably 0.5 to 2% by weight.

(増粘剤)
本発明の白子様食品には、カチオン反応性のある多糖類以外に、白子様食品の内包部分に適度なとろみを付与するために増粘剤を配合することができる。増粘剤としては、アラビアガム、トラガントガム、グアーガム、キサンタンガム、タマリンドガム、ローカストビーンガムなどが例示できる。かかる増粘剤の適度な添加量は白子様食品用の乳化油脂組成物に対し、0.01〜3重量%、好ましくは0.05〜2重量%である。
(Thickener)
In addition to the cationically reactive polysaccharide, a thickener can be added to the white matter-like food of the present invention in order to impart an appropriate amount of consistency to the inclusion part of the white matter-like food. As a thickener, gum arabic, tragacanth gum, guar gum, xanthan gum, tamarind gum, locust bean gum etc. can be illustrated. An appropriate amount of the thickener added is 0.01 to 3% by weight, preferably 0.05 to 2% by weight, based on the emulsified oil-and-fat composition for a lecithin-like food.

本発明の白子様食品には、風味や食感を損なわない範囲で、乳化剤を使用することができる。乳化剤としては、特に限定されるものではなく、従来公知の乳化剤を使用することができ、レシチン、ショ糖脂肪酸エステル、プロプレングリコール脂肪酸エステル、ソルビタン脂肪酸エステル、グリセリン脂肪酸エステル、ポリグリセリン脂肪酸エステル、酢酸モノグリセリド、酒石酸モノグリセリド、酢酸酒石酸混合モノグリセリド、クエン酸モノグリセリド、ジアセチル酒石酸モノグリセリド、乳酸モノグリセリド等各種有機酸モノグリセリド、ポリオキシエチレンソルビタン脂肪酸エステルが例示できる。 An emulsifier can be used in the white food product of the present invention as long as the flavor and texture are not impaired. The emulsifier is not particularly limited, and conventionally known emulsifiers can be used, and lecithin, sucrose fatty acid ester, propylene glycol fatty acid ester, sorbitan fatty acid ester, glycerin fatty acid ester, polyglycerin fatty acid ester, acetic acid Examples include various organic acid monoglycerides such as monoglycerides, tartaric acid monoglycerides, acetic acid tartaric acid mixed monoglycerides, citric acid monoglycerides, diacetyl tartaric acid monoglycerides, lactic acid monoglycerides, and polyoxyethylene sorbitan fatty acid esters.

以上の乳化剤のほかに、公知の添加剤として、リン酸塩等のpH調整剤等も使用することができる。また、日持ち向上の目的で、グリシン、酢酸ナトリウム、卵白リゾチームなどの日持ち向上剤を使用することもできる。 In addition to the above emulsifiers, pH adjusters such as phosphate can be used as well-known additives. Further, for the purpose of improving the shelf life, it is also possible to use a shelf life improving agent such as glycine, sodium acetate, egg white lysozyme and the like.

(製造方法)
本発明の白子様食品は、例えば、以下の手順で製造することができる。
(1) 大豆乳化組成物A、大豆蛋白素材B、常温液状油脂、調味料及びカチオン反応性のある多糖類を混合後に予備乳化し、高圧ホモゲナイザーなどを用いて均質化後、85℃前後の加熱殺菌を行い、その後に品温3〜7℃まで冷却して、乳化油脂組成物を得る。
(2) 上記で得られた乳化油脂組成物の液滴を、あらかじめ5〜20℃に調温した0.1〜5重量%濃度の可溶性カチオン素材の水溶液中に滴下または射出し、乳化油脂組成物の表面をゲル化させる。
(3) 乳化油脂組成物の液滴表面がゲルによって被覆された白子様食品を可溶性カチオン素材の水溶液中から取り出して、白子様食品を得る。
(Production method)
The white-collar-like food of the present invention can be produced, for example, according to the following procedure.
(1) Pre-emulsify after mixing soybean emulsion composition A, soybean protein material B, normal temperature liquid oil, seasoning, and cationic reactive polysaccharide, and homogenize using a high-pressure homogenizer etc. and then heat around 85 ° C. Sterilization is performed and then cooled to an article temperature of 3 to 7 ° C. to obtain an emulsified oil composition.
(2) Droplets of the emulsified fat composition obtained above are dropped or injected into an aqueous solution of a soluble cationic material having a concentration of 0.1 to 5% by weight, which has been adjusted to 5 to 20 ° C. Gelate the surface of the object.
(3) The white-collar-like food in which the droplet surface of the emulsified fat / oil composition is covered with gel is taken out from the aqueous solution of the soluble cationic material to obtain a white-collar-like food.

上記の方法で得られる本発明の白子様食品は、安価でかつプリン体やコレステロール含量が低く、魚類由来の白子様の独特の食感及び風味を有するものである。例えば、常温液状油脂として植物性油脂を用いた場合、天然の白子との対比において、プリン体含量を90%削減し、コレステロール含量も90%以上削減した安価な白子様食品を得ることができる。さらに、常温液状油脂として、DHA,EPAに富む藻類由来油脂を使用した場合、プリン体やコレステロール含量が低く、機能性表示可能なレベルのDHA,EPAを含有し、しかも白子様の適度な生臭みと魚臭を有する白子様食品を得ることができる。 The white-collar-like food of the present invention obtained by the above-mentioned method is inexpensive and has a low content of purine and cholesterol and has a unique texture and taste of white-collar derived from fish. For example, when vegetable fats and oils are used as normal temperature liquid fats and oils, it is possible to obtain an inexpensive white powder like food in which the purine content is reduced by 90% and the cholesterol content is also reduced by 90% or more. Furthermore, when an algal-derived fat rich in DHA and EPA is used as the normal temperature liquid fat and oil, the purine body and cholesterol content are low, DHA and EPA containing functional displayable levels are contained, and a mild white odor similar to that of white matter And white fish-like food having a fishy odor can be obtained.

以下に実施例を示し、本発明の詳細をより具体的に説明する。なお、例中、「部」あるいは「%」はいずれも重量基準を表すものとする。
各例における風味評価は、下記の方法及び基準で、パネラー5人の平均値により評価した。
(方法)各例で調製した白子様食品を沸騰したお湯で約2分間ゆでて火を通し、ざるに上げる。室温で放冷し、冷めてからポン酢に漬けて風味評価を行った。
(評価基準)
(食感) :◎適度なとろみ ○:とろみがやや弱い又はやや強い △とろみが弱い又は強い
×:とろみなし
(濃厚感) :◎非常に良好 ○:良好 △:やや弱い ×:淡白
(旨味) :◎非常に良好 ○:良好 △:やや弱い ×:淡白
(豆乳風味):◎殆どなし ○:すっきりした豆乳風味 △:豆乳風味がやや強い
×:豆乳風味が強すぎる
(生臭み) :◎白子近似 ○:白子よりやや弱い又はやや強い △:白子より弱い又は強い
×:淡白又は生臭すぎる
Examples are shown below, and the details of the present invention will be described more specifically. In the examples, "parts" or "%" are all based on weight.
The flavor evaluation in each case was evaluated by the average value of five panelists according to the following method and standard.
(Method) The white food like food prepared in each example is boiled for about 2 minutes in boiling water, heated, and raised. The mixture was allowed to cool at room temperature, cooled, and then dipped in ponzu for flavor evaluation.
(Evaluation criteria)
(Feeling texture): 適度 Moderate stiffness ○: Slightly weak or strong △ Poor or strong texture
X: good feeling (very thick): 非常 very good o: good :: slightly weak x: light white (auspicious): very good o: good :: slightly weak x: light white (soy milk flavor): ◎ almost none ○ : Clean soy milk flavor :: Soy milk flavor is slightly strong
X: Soymilk flavor is too strong (fresh smell): 白 Shiroko approximation ○: Slightly weaker or slightly stronger than Shiro :: Weaker or stronger than Shiro
X: too pale or too fresh

実施例1
大豆乳化物A(不二製油(株)製「濃久里夢」:乾物含量19.8%、乾物あたりの蛋白含量28.3%、乾物あたりの脂質62.1%、LCI値67%)28.8部、大豆蛋白素材B(不二製油(株)製「美味投入」:乾物含量10.0%、乾物あたりの蛋白質含量54.0%、乾物あたりの脂質5%、LCI値34%)67.2部、DHAとEPAを合計で515m/g 含有する藻類由来油脂3部、昆布だし1部、アルギン酸ナトリウム1部及びキサンタンガム0.1部をホモミキサーを用いて混合し、予備乳化した。その後、5Mpaの圧力でホモゲナイザーを用いて均質化した。均質化後、掻きとり式連続熱交換機に通し、80〜90℃で加熱殺菌、充填し、トンネルフリーザーにて急冷後、冷蔵庫でエージングを行い、乳化油脂組成物を得た。
上記で得られた乳化油脂組成物を、10℃の1%塩化カルシウム水溶液中にスポイトを用いて射出し、乳化油脂組成物の表面がゲル化した直径5mm×長さ100mm程度の白子様食品を得た。塩化カルシウム水溶液から白子様食品を取り出し、風味評価を行った。
Example 1
Soybean emulsion A ("Naguri Yume" manufactured by Fuji Oil Co., Ltd .: dry matter content 19.8%, protein content per dry matter 28.3%, lipid per dry matter 62.1%, LCI value 67%) 28 .8 parts, soy protein material B ("Good taste input" made by Fuji Oil Co., Ltd .: dry matter content 10.0%, protein content per dry matter 54.0%, lipid 5% per dry matter, LCI value 34%) 67.2 parts, 3 parts of algae derived fat and fat containing 515 m / g of DHA and EPA in total, 1 part of kelp soup stock, 1 part of sodium alginate and 0.1 part of xanthan gum were mixed using a homomixer and pre-emulsified. It was then homogenized using a homogenizer at a pressure of 5 Mpa. After homogenization, it was passed through a scraping-type continuous heat exchanger, heat-sterilized at 80-90 ° C. for filling, quenched in a tunnel freezer, and then aged in a refrigerator to obtain an emulsified oil composition.
The emulsified oil / fat composition obtained above is injected into a 1% aqueous solution of calcium chloride at 10 ° C. using a dropper, and the surface of the emulsified oil / oil composition is a gelled white food having a diameter of about 5 mm × length 100 mm. Obtained. White matter-like food was taken out from the calcium chloride aqueous solution and the taste was evaluated.

実施例2
実施例1の「濃久里夢」28.8部を48部に、「美味投入」67.2部を48部にそれぞれ代えて、実施例1同様に白子様食品の調製を行い、風味評価を行った。
Example 2
Shiroko like food was prepared in the same manner as in Example 1 except that 28.8 parts of “Nikuri Yume” of Example 1 were replaced by 48 parts, and 67.2 parts of “good taste input” were replaced by 48 parts, and the flavor was evaluated. went.

実施例3
実施例1の「濃久里夢」28.8部を67.2部に、「美味投入」67.2部を28.8部にそれぞれ代えて、実施例1同様に白子様食品の調製を行い、風味評価を行った。
Example 3
In the same manner as in Example 1, the preparation of the Shirako-like food was carried out in the same manner as in Example 1 except that 28.8 parts of "Nikuri Yume" of Example 1 were replaced with 67.2 parts, and 67.2 parts of "Good taste input" was replaced with 28.8 parts. , Taste evaluation was performed.

比較例1
実施例1の「濃久里夢」28.8部を19.2部に、「美味投入」67.2部を76.8部にそれぞれ代えて、実施例1同様に白子様食品の調製を行い、風味評価を行った。
Comparative Example 1
In the same manner as in Example 1, Shiroko-like food was prepared in the same manner as in Example 1 except that 28.8 parts of "Nikuri Yume" of Example 1 were replaced with 19.2 parts and 67.2 parts of "Good taste input" was replaced with 76.8 parts. , Taste evaluation was performed.

比較例2
実施例1の「濃久里夢」28.8部を76.8部に、「美味投入」67.2部を19.2部にそれぞれ代えて、実施例1同様に白子様食品の調製を行い、風味評価を行った。
Comparative example 2
In the same manner as in Example 1, Shiroko-like food was prepared in the same manner as in Example 1 except that 28.8 parts of "Nikuri Yume" of Example 1 were replaced with 76.8 parts, and 67.2 parts of "Good taste input" was replaced with 19.2 parts. , Taste evaluation was performed.

比較例3
実施例1の「濃久里夢」28.8部、「美味投入」67.2部を、市販の無調整豆乳(全固形分9.2%、蛋白質含量4.9%、脂質含量3.7%)96部に変更して、実施例1同様に白子様食品の調製を行い、風味評価を行った。
Comparative example 3
28.8 parts of “Naguri Yume” of Example 1 and 67.2 parts of “delicious feed” are commercially available unadjusted soymilk (total solids 9.2%, protein content 4.9%, lipid content 3.7) %) It changed into 96 parts, prepared the white-collar like foodstuff like Example 1, and performed flavor evaluation.

表1に、実施例1〜3及び比較例1〜3の白子様食品の評価結果を示す。
表1

Figure 2019076027
In Table 1, the evaluation result of the white-collar-like foodstuff of Examples 1-3 and Comparative Examples 1-3 is shown.
Table 1
Figure 2019076027

表1に示すように、大豆乳化組成物A由来の蛋白質1.5〜4重量%及び大豆蛋白素材B由来の蛋白質1.5〜4重量%を含有する実施例1〜3は、白子様のとろみのある食感で、濃厚感、旨味とも良好であり、豆乳風味は殆どなく、白子様の生臭みのある風味を有していた。大豆乳化組成物A由来の蛋白質が1.1%であった比較例1は、旨味良好で、豆乳風味は殆どなく、白子様の生臭みのある風味ではあったが、やや淡白な物足りない風味であった。大豆乳化組成物A由来の蛋白質が4.5%であった比較例は、濃厚感のある白子様の生臭みのある風味であったが、旨味にやや乏しく、豆乳風味がやや強い風味であった。無調整豆乳を使用した比較例3では、濃厚感、旨味とも乏しく、豆乳風味もやや強い違和感のあるものであった。 As shown in Table 1, Examples 1 to 3 containing 1.5 to 4% by weight of protein derived from soybean emulsified composition A and 1.5 to 4% by weight of protein derived from soybean protein material B The texture was thick, good in richness and umami taste, almost no soymilk flavor, and had a fresh white odor like flavor. Comparative Example 1 in which the protein derived from the soybean emulsion composition A was 1.1% had good umami taste, almost no soymilk flavor, and had a mild white odor like fresh odor, but it was a somewhat light white taste there were. The comparative example in which the protein derived from the soybean emulsion composition A was 4.5% had a flavor with a thickish white-child-like fresh odor, but the taste was slightly poor and the soymilk flavor was slightly strong. The In Comparative Example 3 in which unadjusted soymilk was used, both the rich feeling and the umami taste were poor, and the soymilk flavor was also somewhat uncomfortable.

実施例4
実施例2において、DHAとEPAを合計で515m/g含有する藻類由来油脂3部を精製菜種油3部に代えて、1%塩化カルシウム水溶液を1%乳酸カルシウム水溶液に代えて、実施例1同様に白子様食品を調製し、風味評価を行った。
Example 4
In Example 2, 3 parts of algae derived fat and oil containing a total of 515 m / g of DHA and EPA in place of 3 parts of refined rapeseed oil and 1% calcium chloride aqueous solution instead of 1% calcium lactate aqueous solution as in Example 1 An eggplant-like food was prepared and its flavor was evaluated.

比較例4
実施例4において、「濃久里夢」48部を49.5部に、「美味投入」48部を49.5部にそれぞれ代えて、精製菜種油3部を0部に代えて、実施例1同様に白子様食品を調製し、風味評価を行った。
Comparative example 4
In Example 4, 48 parts of "Nikuri Yume" are replaced by 49.5 parts, 48 parts of "delicious feed" are replaced by 49.5 parts, and 3 parts of refined rapeseed oil is replaced by 0 parts as in Example 1. Were prepared and evaluated for flavor.

比較例5
実施例4において、「濃久里夢」48部を46.5部に、「美味投入」48部を46.5部にそれぞれ代えて、精製菜種油3部を6部に代えて、実施例1同様に白子様食品を調製し、風味評価を行った。
Comparative example 5
In Example 4, 48 parts of "Nikuri Yume" are replaced by 46.5 parts, 48 parts of "delicious feed" are replaced by 46.5 parts, and 3 parts of refined rapeseed oil is replaced by 6 parts as in Example 1. Were prepared and evaluated for flavor.

表2に、実施例4及び比較例4〜5の白子様食品の評価結果を示す。
表2

Figure 2019076027
In Table 2, the evaluation result of the white-collar-like foodstuff of Example 4 and Comparative Examples 4-5 is shown.
Table 2
Figure 2019076027

表2に示すように、実施例4は、白子様の生臭みは白子よりやや弱いが、白子様のとろみのある食感で、濃厚感、旨味とも良好であり、豆乳風味は殆どないものであった。精製菜種油無添加の比較例4は、濃厚感に乏しく、白子様の生臭みも弱い、淡白な風味であった。また、精製菜種油6%添加の比較例5は、白子様の風味、食感ではあるが、実施例4と対比して油っぽい食感であった。 As shown in Table 2, Example 4 had a mild texture similar to that of Shirako, but it had a texture with a mild consistency like Shirako, both richness and umami taste, and had almost no soymilk flavor. there were. Comparative Example 4 in which the refined rapeseed oil was not added had a poor feeling of richness and a light white flavor with weak white taste like fresh odor. In addition, Comparative Example 5 in which 6% of refined rapeseed oil was added had an oily texture in contrast to Example 4, although it had a white-collar-like flavor and texture.

本発明により、簡便に、安価でかつプリン体やコレステロール含量が低く、天然の白子様の独特の食感及び風味を有する白子様食品の製造方法の提供が可能となった。 According to the present invention, it has become possible to simply provide an inexpensive method for producing a leuko-like food having a low texture of purine and cholesterol and having a unique texture and taste of natural leuko-like.

Claims (3)

下記の大豆乳化組成物A由来の蛋白質1.5〜4重量%、大豆蛋白素材B由来の蛋白質1.5〜4重量%、常温液状油脂1〜5重量%、調味料及びカチオン反応性のある多糖類0.5〜3重量%を含有する乳化油脂組成物の液滴を、可溶性カチオン素材の水溶液と接触させることを特徴とする、白子様食品の製造方法。
大豆乳化組成物A:乾物あたりの蛋白質含量が25重量%以上、脂質含量(クロロホルム/メタノール混合溶媒抽出物としての含量をいう。)が蛋白質含量に対して100重量%以上であって、LCI値(大豆蛋白質中の脂質親和性蛋白質含有割合)が55%以上である大豆乳化組成物。
大豆蛋白素材B:総蛋白質中の脂質親和性蛋白質の割合がLCI値として40%以下であり、脂質含量(クロロホルム/メタノール混合溶媒抽出物としての含量をいう。)が蛋白質含量に対して10重量%未満である大豆蛋白素材。
1.5 to 4% by weight of protein derived from soybean emulsion composition A described below, 1.5 to 4% by weight of protein derived from soybean protein material B, 1 to 5% by weight of normal temperature liquid oil, seasoning and cationic reactivity A method for producing a leuco-like food, which comprises bringing droplets of an emulsified oil composition containing 0.5 to 3% by weight of a polysaccharide into contact with an aqueous solution of a soluble cationic material.
Soybean emulsified composition A: The protein content per dry matter is 25% by weight or more, the lipid content (refers to the content as a chloroform / methanol mixed solvent extract) is 100% by weight or more based on the protein content, and the LCI value The soybean emulsion composition whose (the content ratio of lipophilic protein in soybean protein) is 55% or more.
Soy protein material B: The ratio of the lipophilic protein in the total protein is 40% or less as LCI value, and the lipid content (refers to the content as chloroform / methanol mixed solvent extract) is 10 weight to the protein content Soy protein material which is less than%.
大豆乳化組成物A由来の蛋白質と大豆蛋白素材B由来の蛋白質の合計量が3〜8重量%であり、大豆乳化組成物A由来の蛋白質の大豆蛋白素材B由来の蛋白質に対する含有比率が0.3〜3である請求項1記載の白子様食品の製造方法。 The total amount of protein derived from soybean emulsified composition A and protein derived from soybean protein material B is 3 to 8% by weight, and the content ratio of protein derived from soybean emulsified composition A to protein derived from soybean protein material B is 0. The method for producing a leuco-like food according to claim 1, which is 3 to 3. カチオン反応性のある多糖類がアルギン酸ナトリウムであり、可溶性カチオン素材が塩化カルシウム若しくは乳酸カルシウムである、請求項1または請求項2記載の白子様食品の製造方法。 The method for producing a rattan-like food according to claim 1 or 2, wherein the cationically reactive polysaccharide is sodium alginate, and the soluble cationic material is calcium chloride or calcium lactate.
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