JP2019004913A - Oils and fats, and oils and fats-containing food product - Google Patents

Oils and fats, and oils and fats-containing food product Download PDF

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JP2019004913A
JP2019004913A JP2018196538A JP2018196538A JP2019004913A JP 2019004913 A JP2019004913 A JP 2019004913A JP 2018196538 A JP2018196538 A JP 2018196538A JP 2018196538 A JP2018196538 A JP 2018196538A JP 2019004913 A JP2019004913 A JP 2019004913A
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oils
fats
oil
mass
fat
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JP6682598B2 (en
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宗央 築山
Munehisa Tsukiyama
宗央 築山
裕伴 長谷川
Hirotomo Hasegawa
裕伴 長谷川
知洋 粟飯原
Tomohiro AIBARA
知洋 粟飯原
雅崇 安藤
Masataka Ando
雅崇 安藤
世里子 遠藤
Yoriko Endo
世里子 遠藤
村上 祥子
Sachiko Murakami
祥子 村上
拓也 小澤
Takuya Ozawa
拓也 小澤
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Nisshin Oillio Group Ltd
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    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23DEDIBLE OILS OR FATS, e.g. MARGARINES, SHORTENINGS, COOKING OILS
    • A23D9/00Other edible oils or fats, e.g. shortenings, cooking oils
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23DEDIBLE OILS OR FATS, e.g. MARGARINES, SHORTENINGS, COOKING OILS
    • A23D7/00Edible oil or fat compositions containing an aqueous phase, e.g. margarines
    • A23D7/001Spread compositions
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23DEDIBLE OILS OR FATS, e.g. MARGARINES, SHORTENINGS, COOKING OILS
    • A23D7/00Edible oil or fat compositions containing an aqueous phase, e.g. margarines
    • A23D7/003Compositions other than spreads
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23GCOCOA; COCOA PRODUCTS, e.g. CHOCOLATE; SUBSTITUTES FOR COCOA OR COCOA PRODUCTS; CONFECTIONERY; CHEWING GUM; ICE-CREAM; PREPARATION THEREOF
    • A23G1/00Cocoa; Cocoa products, e.g. chocolate; Substitutes therefor
    • A23G1/30Cocoa products, e.g. chocolate; Substitutes therefor
    • A23G1/32Cocoa products, e.g. chocolate; Substitutes therefor characterised by the composition containing organic or inorganic compounds
    • A23G1/36Cocoa products, e.g. chocolate; Substitutes therefor characterised by the composition containing organic or inorganic compounds characterised by the fats used
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23GCOCOA; COCOA PRODUCTS, e.g. CHOCOLATE; SUBSTITUTES FOR COCOA OR COCOA PRODUCTS; CONFECTIONERY; CHEWING GUM; ICE-CREAM; PREPARATION THEREOF
    • A23G9/00Frozen sweets, e.g. ice confectionery, ice-cream; Mixtures therefor
    • A23G9/32Frozen sweets, e.g. ice confectionery, ice-cream; Mixtures therefor characterised by the composition containing organic or inorganic compounds
    • A23G9/327Frozen sweets, e.g. ice confectionery, ice-cream; Mixtures therefor characterised by the composition containing organic or inorganic compounds characterised by the fatty product used, e.g. fat, fatty acid, fatty alcohol, their esters, lecithin, glycerides

Abstract

To provide oils and fats for imparting a milk-like flavor to a food product at a low cost without spending time and effort and to provide a food product containing the oils and fats and imparted with a milk-like flavor.SOLUTION: The oils and fats contain 0.005 to 3 mass% of triacylglycerol bonded with only a 6-10C fatty acid as a constituent fatty acid. In the triacylglycerol bonded with only a 6-10C fatty acid as the constituent fatty acid, the content of a 8C fatty acid in the constituent fatty acids is 20 mass% or more.SELECTED DRAWING: None

Description

本発明は、油脂および該油脂を含有する乳様の風味を有する食品に関する。   The present invention relates to fats and oils and foods having a milky flavor containing the fats and oils.

油脂(脂質)は三大栄養素であるだけではなく、食品に美味しさを付与する重要な成分である。油脂は食品の味をマイルドにし、かつコクを与える。油脂があるために美味しくなる食品としては、天ぷら、フライ食品、ラーメン、パイ、チョコレート、クリーム、チーズなど、多くの食品が挙げられる。油脂には、サラダ油のように無味無臭に近いものから、焙煎胡麻油、バターのように独特の風味が重宝されるものまで、さまざまなものが、用途に合わせて使用されている。また、ラー油やネギ油のように、香辛料の風味を付与した風味油脂も知られている。   Oils and fats (lipids) are not only the three major nutrients, but also important ingredients that give foods a delicious taste. Oils and fats make the food mild and rich. Many foods such as tempura, fried food, ramen, pie, chocolate, cream, and cheese are listed as foods that become delicious due to the presence of oils and fats. Various types of fats and oils are used according to the purpose, from those that are nearly tasteless and odorless, such as salad oil, to those that have a unique flavor, such as roasted sesame oil and butter. Moreover, flavor oils and fats imparted with the flavor of spices such as rar oil and leek oil are also known.

油脂の風味の中でも乳脂肪が持つ乳様の風味は、飲料、クリーム、チーズ、菓子、パン等の食品において、おいしさを左右する重要な要素である。乳様の風味の特徴を出すために、産地限定のバターを使用したり、発酵させたバターを使用したり、乳脂肪を分別して乳様の風味の濃いオレイン部(液状部)と淡白なステアリン部(固体部)に分けたりと、さまざまな乳脂肪が使用されている。また、例えば特許文献1のように、油脂、脂質と蛋白質の複合体、乳固形分及び水を含有してなる混合物を80〜180℃で加熱処理した後、固化しない範囲で冷却してから分離手段を用いて処理液の不溶分を除去して得られる風味油脂の開発や、フレーバーによる乳様の風味の付与も広く行われている。   Among the flavors of fats and oils, the milky flavor of milk fat is an important factor that affects the taste of foods such as beverages, creams, cheeses, confectionery, and bread. In order to bring out the characteristics of the milky flavor, the use of butter limited to the production area, fermented butter, or the separation of milk fat, the milky flavored olein part (liquid part) and pale stearin Various milk fats are used, such as being divided into parts (solid parts). In addition, for example, as in Patent Document 1, a mixture containing fats and oils, a complex of lipid and protein, milk solids and water is heated at 80 to 180 ° C., and then cooled within a range not solidified and then separated. Development of flavored oils and fats obtained by removing insolubles from processing solutions using means, and imparting a milky flavor with flavor are also widely performed.

しかしながら、バターや生乳を原料とした風味油脂を使用する場合、乳様の風味を出すために配合量を多くすることが必要であり、コストがかかるものであった。また、フレーバーによる乳様の風味の付与は、比較的安価で手軽に効果が得られる反面、味にコクがなかったり、乳様の風味を安定して持続させることが困難であったり、熱に弱かったりと、その効果には限度があった。従って、手間をかけずに低コストで、食品に安定した乳様の風味を付与する方法の開発が望まれていた。   However, when using flavored oils and fats made from butter or raw milk, it is necessary to increase the blending amount in order to produce a milky flavor, which is costly. In addition, imparting a milk-like flavor with flavor is relatively inexpensive and easy to obtain, but the taste is not rich, it is difficult to stably maintain a milk-like flavor, Even if it was weak, the effect was limited. Accordingly, it has been desired to develop a method for imparting a stable milky flavor to foods at low cost and without labor.

特開2003−164258号公報JP 2003-164258 A

本発明の目的は、手間をかけずに低コストで、食品に乳様の風味を付与するための油脂を提供することである。本発明の目的はまた、該油脂を含有し、乳様の風味が付与された食品を提供することである。   An object of the present invention is to provide an oil and fat for imparting a milky flavor to foods at low cost without labor. An object of the present invention is also to provide a food containing the fat and oil and having a milky flavor.

本発明者らは、上記課題を解決するために鋭意検討を行った結果、油脂中に特定のトリアシルグリセロールを特定量含有させることにより、該油脂を含有する食品に乳様の風味を付与できることを見いだし、本発明を完成するに至った。   As a result of intensive studies to solve the above-mentioned problems, the present inventors are able to impart a milky flavor to foods containing fats and oils by containing specific amounts of specific triacylglycerols in the fats and oils. As a result, the present invention has been completed.

すなわち、本発明の一態様によれば、構成脂肪酸として炭素数が6〜10である脂肪酸のみが結合したトリアシルグリセロールを0.005〜3質量%含有する油脂が提供される。
本発明の好ましい態様によれば、上記構成脂肪酸として炭素数が6〜10である脂肪酸のみが結合したトリアシルグリセロールにおいて、構成脂肪酸のうち、炭素数8の脂肪酸含有量が20質量%以上である、油脂が提供される。
本発明の好ましい態様によれば、上記構成脂肪酸として炭素数が6〜10である脂肪酸のみが結合したトリアシルグリセロールにおいて、構成脂肪酸のうち、炭素数6の脂肪酸含有量が20質量%以下である、油脂が提供される。
本発明の好ましい態様によれば、上記油脂が、油脂が有する構成脂肪酸全量のうち、ラウリン酸を3質量%以上含む油脂である、油脂が提供される。
また、本発明の他の態様によれば、上記油脂を含有する食品が提供される。
本発明の好ましい態様によれば、上記食品が、さらに無脂乳固形分を含有する、食品が提供される。
本発明の好ましい態様によれば、上記食品中の、食品に含まれる全油脂含有量と無脂乳固形分含有量との質量比が10:90〜99.5:0.5である、食品が提供される。
本発明の好ましい態様によれば、上記食品が、乳化物である、食品が提供される。
また、本発明の他の態様によれば、食品に、炭素数が6〜10である脂肪酸のみが結合したトリアシルグリセロールを、食品に含まれる全油脂中に0.005〜3質量%を含有させる、食品に乳様の風味を付与する方法が提供される。
That is, according to one aspect of the present invention, there is provided an oil or fat containing 0.005 to 3% by mass of triacylglycerol to which only fatty acids having 6 to 10 carbon atoms are bound as constituent fatty acids.
According to a preferred aspect of the present invention, in the triacylglycerol in which only the fatty acid having 6 to 10 carbon atoms is bound as the constituent fatty acid, the fatty acid content of carbon number 8 is 20% by mass or more among the constituent fatty acids. Oils and fats are provided.
According to a preferred aspect of the present invention, in the triacylglycerol in which only the fatty acid having 6 to 10 carbon atoms is bound as the constituent fatty acid, the content of fatty acid having 6 carbon atoms in the constituent fatty acid is 20% by mass or less. Oils and fats are provided.
According to the preferable aspect of this invention, the said fats and oils are fats and oils which are 3 fat% or more of lauric acid among the fatty-acid total amount which fats and oils have.
Moreover, according to the other aspect of this invention, the foodstuff containing the said fats and oils is provided.
According to the preferable aspect of this invention, the said foodstuff provides the foodstuff further containing non-fat milk solid content.
According to the preferable aspect of this invention, the foodstuff whose mass ratio of the total fat content contained in foodstuffs and non-fat milk solid content content is 10: 90-99.5: 0.5 in the said foodstuffs. Is provided.
According to a preferred embodiment of the present invention, there is provided a food product, wherein the food product is an emulsion.
Moreover, according to the other aspect of this invention, the foodstuff contains the triacylglycerol which only the C6-C10 fatty acid couple | bonded with 0.005-3 mass% in all the fats and oils contained in a foodstuff. A method for imparting a milky flavor to food is provided.

本発明によれば、食品に乳様の風味を付与するための油脂を提供することができる。本発明によればまた、該油脂を含有し、乳様の風味が付与された食品を提供することができる。   According to the present invention, fats and oils for imparting a milky flavor to food can be provided. According to the present invention, it is also possible to provide a food containing the fat and oil and having a milky flavor.

本発明の油脂は、構成脂肪酸として炭素数が6〜10である脂肪酸のみが結合したトリアシルグリセロール(以下、MCTとも表す)を0.005〜3質量%含有する。MCT含有量が0.005質量%未満の場合、本発明の効果が発現し難い場合があり、また、MCT含有量が3質量%を超えても、得られる効果はほとんど変わらず、MCTは高価な油脂なので、コスト増しとなる。ここでMCTは、グリセロールに炭素数6〜10の脂肪酸が3つエステル結合しているものであれば、同一の脂肪酸が結合していてもよいし、異なる脂肪酸が結合していてもよい。また、例えば、トリオクタノイルグリセロールとトリデカノイルグリセロールとの混合物等、複数の異なる分子種の混合物であってもよい。炭素数6〜10の脂肪酸は、直鎖の飽和脂肪酸であることが好ましい。本発明の油脂中のMCT含有量は、0.01〜2質量%であることが好ましく、さらに0.01〜1質量%であることが好ましく、0.01〜0.6質量%であることがより好ましく、0.05〜0.4質量%であることがさらに好ましい。油脂中のMCT含有量が上記範囲にあると、該油脂を含有した食品に乳様の風味が付与され易いので好ましい。   The fats and oils of the present invention contain 0.005 to 3% by mass of triacylglycerol (hereinafter also referred to as MCT) to which only fatty acids having 6 to 10 carbon atoms are bound as constituent fatty acids. When the MCT content is less than 0.005% by mass, the effects of the present invention may not be easily achieved. When the MCT content exceeds 3% by mass, the obtained effect is hardly changed, and MCT is expensive. The oil and fat increases costs. Here, as long as MCT has three ester bonds of fatty acids having 6 to 10 carbon atoms to glycerol, the same fatty acid may be bound, or different fatty acids may be bound. Further, it may be a mixture of a plurality of different molecular species such as a mixture of trioctanoyl glycerol and tridecanoyl glycerol. The fatty acid having 6 to 10 carbon atoms is preferably a linear saturated fatty acid. The MCT content in the oil and fat of the present invention is preferably 0.01 to 2% by mass, more preferably 0.01 to 1% by mass, and 0.01 to 0.6% by mass. Is more preferable, and it is further more preferable that it is 0.05-0.4 mass%. It is preferable that the MCT content in the oil and fat is in the above range because a milky flavor is easily imparted to the food containing the oil and fat.

本発明の油脂に含有されるMCTは、MCTを構成する脂肪酸全量のうち、炭素数8の脂肪酸の含有量が20質量%以上であることが好ましく、50質量%以上であることがより好ましく、70質量%以上であることがさらに好ましい。また同様に、炭素数6の脂肪酸の含有量が20質量%以下であることが好ましく、10質量%以下であることがより好ましく、5質量%以下であることがさらに好ましい。本発明の油脂に含有されるMCT全量を構成する脂肪酸が、上記構成の範囲にあると、該油脂を含有した食品に乳様の風味が付与され易いので好ましい。
なお、本発明においては、乳様の風味は、乳脂肪が持つ乳由来の風味、もしくは、それに類似した風味を意味する。
The MCT contained in the oil and fat of the present invention is preferably 20% by mass or more, more preferably 50% by mass or more of the content of fatty acids having 8 carbon atoms in the total amount of fatty acids constituting the MCT. More preferably, it is 70 mass% or more. Similarly, the content of fatty acids having 6 carbon atoms is preferably 20% by mass or less, more preferably 10% by mass or less, and further preferably 5% by mass or less. It is preferable that the fatty acid constituting the total amount of MCT contained in the oil and fat of the present invention is in the above-described range because a milky flavor is easily imparted to the food containing the oil and fat.
In the present invention, the milk-like flavor means a flavor derived from milk or similar to that of milk fat.

本発明の油脂に含有されるMCTは、従来公知の方法で製造できる。すなわち、炭素数6〜10の脂肪酸とグリセロールとを、触媒下、好ましくは無触媒下で、また、好ましくは減圧下で、120〜180℃に加熱し、脱水縮合させることにより製造できる。   The MCT contained in the oil of the present invention can be produced by a conventionally known method. That is, it can be produced by heating a fatty acid having 6 to 10 carbon atoms and glycerol under a catalyst, preferably without a catalyst, and preferably under reduced pressure, to 120 to 180 ° C. to cause dehydration condensation.

本発明の油脂は、構成脂肪酸として炭素数が6〜10である脂肪酸のみが結合したトリアシルグリセロールを0.005〜3質量%含有するという条件が満たされる限り、一般に食用に適する油脂を使用することができる。例えば、大豆油、菜種油、コーン油、綿実油、米油、ヒマワリ油、サフラワー油、胡麻油、カカオ脂、シア脂、サル脂、パーム油、パーム核油、ヤシ油、牛脂、豚脂、乳脂、魚油、鯨油等の各種の植物油脂及び動物油脂、並びにこれらに水素添加、分別及びエステル交換から選択された一又は二以上の処理を施した加工油脂が挙げられる。本発明においては、これらの油脂の中から選ばれた1種または2種以上を用いることができる。本発明の油脂は、乳脂肪を含有する場合、乳脂肪の乳様の風味をより強くすることができる。   The fats and oils of the present invention generally use edible fats and oils as long as the condition that 0.005 to 3% by mass of triacylglycerols bound only with fatty acids having 6 to 10 carbon atoms is contained as constituent fatty acids is satisfied. be able to. For example, soybean oil, rapeseed oil, corn oil, cottonseed oil, rice oil, sunflower oil, safflower oil, sesame oil, cocoa butter, shea butter, monkey fat, palm oil, palm kernel oil, coconut oil, beef tallow, pork fat, milk fat, Examples include various vegetable oils and animal fats and oils such as fish oil and whale oil, and processed oils and fats that have been subjected to one or more treatments selected from hydrogenation, fractionation and transesterification. In the present invention, one or more selected from these fats and oils can be used. When the fats and oils of this invention contain milk fat, the milky flavor of milk fat can be made stronger.

本発明の油脂は、油脂を構成する全脂肪酸中にラウリン酸を3質量%以上含む油脂であることが好ましい。本発明の油脂に含まれるラウリン酸含有量は、5質量%以上であることがより好ましく、10質量%以上であることがさらに好ましく、15〜60質量%であることが最も好ましい。本発明の油脂が、全構成脂肪酸中にラウリン酸を3質量%以上含む油脂であると、該油脂を含有した食品に乳様の風味が付与され易いので好ましい。全構成脂肪酸中にラウリン酸を3質量%以上含む油脂とするには、ラウリン酸を含む油脂をベース油として使用することが好ましい。例えば、ヤシ油、パーム核油、ババス油等のラウリン酸を30質量%以上含む油脂、並びにこれらを単独で、もしくは、他の油脂と混合して、水素添加、分別及びエステル交換から選択された一又は二以上の処理を施した加工油脂が挙げられる。本発明においては、これらのラウリン酸を含む油脂とその他の油脂の中から選ばれた1種または2種以上を用いることもできる。   The fats and oils of the present invention are preferably fats and oils containing 3% by mass or more of lauric acid in the total fatty acids constituting the fats and oils. The lauric acid content contained in the oil of the present invention is more preferably 5% by mass or more, further preferably 10% by mass or more, and most preferably 15 to 60% by mass. It is preferable for the fats and oils of the present invention to contain 3% by mass or more of lauric acid in the total constituent fatty acids because a milky flavor is easily imparted to foods containing the fats and oils. In order to obtain an oil containing 3% by mass or more of lauric acid in all the constituent fatty acids, it is preferable to use an oil containing lauric acid as the base oil. For example, fats and oils containing lauric acid such as coconut oil, palm kernel oil, Babas oil and the like of 30% by mass or more, and these alone or mixed with other fats and oils were selected from hydrogenation, fractionation and transesterification Examples thereof include processed fats and oils subjected to one or more treatments. In this invention, 1 type, or 2 or more types chosen from the fats and oils containing these lauric acids and other fats and oils can also be used.

本発明の好ましい実施の形態によれば、本発明の油脂は、ヤシ油、パーム核油、ババス油等およびそれらの分別油、分別硬化油等の油脂を構成する全脂肪酸中にラウリン酸を30質量%以上含む油脂、もしくは、全構成脂肪酸中にラウリン酸を30質量%以上含む油脂と全構成脂肪酸中に炭素数16以上の脂肪酸を90質量%以上含む油脂とのエステル交換油、および、それらの分別油、硬化分別油、分別硬化油等を使用することが好ましい。より具体的には、ヤシ油、パーム核油、パーム核オレイン、パーム核ステアリン、もしくは、それらの油脂とパーム系油脂とのエステル交換油が挙げられる。パーム系油脂とは、パーム油を原料とする加工油脂であり、パームオレイン、パームステアリン、パーム中融点部、パームスーパーオレイン、パームハードステアリン等が挙げられる。   According to a preferred embodiment of the present invention, the fats and oils of the present invention comprise 30 lauric acids in the total fatty acids constituting the fats and oils such as coconut oil, palm kernel oil, Babas oil and the like, and fractionated oil and fractionated hardened oil. Oils and fats containing at least mass%, or transesterified oils of oils and fats containing 30% by mass or more of lauric acid in all constituent fatty acids and oils and fats containing 90% by mass or more of fatty acids having 16 or more carbon atoms in all the constituent fatty acids, and those It is preferable to use a fractionated oil, a hardened fractionated oil, a fractionated hardened oil or the like. More specifically, coconut oil, palm kernel oil, palm kernel olein, palm kernel stearin, or transesterified oils of these oils and palm oils are listed. Palm-based fats and oils are processed fats and oils made from palm oil, and examples include palm olein, palm stearin, palm mid-melting point, palm super olein, and palm hard stearin.

本発明の油脂の好ましい実施の形態の1つとしては、ヤシ油、パーム核油、パーム核オレイン、パーム核ステアリン、およびそれらの硬化油等の全構成脂肪酸中にラウリン酸を30質量%以上含む油脂、もしくは、必要に応じてその他の油脂を混合してラウリン酸含有量を10質量%以上とした油脂に、MCTを構成する全脂肪酸中の炭素数8の脂肪酸の含有量が50質量%以上であるMCTを添加し、油脂中におけるMCT含有量を0.005〜3質量%に調製した油脂が挙げられる。   As one of the preferable embodiment of the fats and oils of this invention, 30 mass% or more of lauric acids is contained in all the constituent fatty acids, such as palm oil, palm kernel oil, palm kernel olein, palm kernel stearin, and those hardened oils. Fats and oils or other fats and oils mixed as required to have a lauric acid content of 10% by mass or more, and the content of C8 fatty acids in all fatty acids constituting MCT is 50% by mass or more The oil and fat which added MCT which is and prepared MCT content in oil and fat to 0.005 to 3 mass% is mentioned.

本発明の油脂のまた別の好ましい実施の形態の1つとしては、ヤシ油、パーム核油、パーム核オレイン、パーム核ステアリン、および、それらの硬化油等のラウリン酸を30質量%以上含む油脂から選ばれる1種以上の油脂と、パーム油、パームオレイン、パームスーパーオレイン、パーム中融点部、パームステアリン、パームハードステアリン、および、それらの硬化油等のパーム系油脂から選ばれる1種以上の油脂とのエステル交換油に、MCTを構成する全脂肪酸中の炭素数8の脂肪酸の含有量が50質量%以上であるMCTを添加し、油脂中におけるMCT含有量を0.005〜3質量%に調製した油脂が挙げられる。上記エステル交換油の原料油である、ラウリン酸を30質量%以上含む油脂とパーム系油脂との混合油の混合比(質量比)は、20:80〜80:20であることが好ましく、30:70〜70:30であることがより好ましい。   As another preferred embodiment of the oil and fat of the present invention, oil and fat containing 30% by mass or more of lauric acid such as coconut oil, palm kernel oil, palm kernel olein, palm kernel stearin, and hardened oil thereof. One or more oils and fats selected from the group consisting of palm oils such as palm oil, palm olein, palm super olein, palm middle melting point, palm stearin, palm hard stearin, and hardened oils thereof. MCT in which the content of C8 fatty acids in all fatty acids constituting MCT is 50% by mass or more is added to the transesterified oil with fats and oils, and the MCT content in the fats and oils is 0.005 to 3% by mass. And the prepared fats and oils. The mixing ratio (mass ratio) of the mixed oil of fat and oil containing 30% by mass or more of lauric acid, which is a raw material oil of the transesterified oil, and palm oil is preferably 20:80 to 80:20, 30 : 70 to 70:30 is more preferable.

本発明において、エステル交換処理の方法は、特に限定されないが、公知の方法により行うことができる。例えば、ナトリウムメトキシド等の合成触媒を使用した化学的エステル交換や、リパーゼを触媒とした酵素的エステル交換のどちらの方法でも行うことができる。化学的エステル交換は、例えば、原料油脂を十分に乾燥させ、ナトリウムメトキシドを原料油脂に対して0.1〜1質量%添加した後、減圧下、80〜120℃で0.5〜1時間攪拌しながら反応を行うことができる。酵素的エステル交換は、例えば、リパーゼ粉末または固定化リパーゼを原料油脂に対して0.02〜10質量%、好ましくは0.04〜5質量%添加した後、40〜80℃、好ましくは40〜70℃で0.5〜48時間、好ましくは0.5〜24時間攪拌しながら反応を行うことができる。   In the present invention, the method for the transesterification treatment is not particularly limited, but can be carried out by a known method. For example, either chemical transesterification using a synthetic catalyst such as sodium methoxide or enzymatic transesterification using lipase as a catalyst can be performed. The chemical transesterification is performed, for example, by sufficiently drying the raw oil and fat, adding 0.1 to 1% by mass of sodium methoxide to the raw oil and fat, and then reducing the pressure at 80 to 120 ° C. for 0.5 to 1 hour. The reaction can be carried out with stirring. In the enzymatic transesterification, for example, lipase powder or immobilized lipase is added in an amount of 0.02 to 10% by mass, preferably 0.04 to 5% by mass, based on the raw material fat, and then 40 to 80 ° C., preferably 40 to 40%. The reaction can be carried out with stirring at 70 ° C. for 0.5 to 48 hours, preferably 0.5 to 24 hours.

本発明の食品は、本発明の油脂を含有する食品である。本発明の食品は、本発明の効果を効率よく得るために、本発明の油脂を2質量%以上含有することが好ましく、5質量%以上含有することがより好ましく、10質量%以上含有することがさらに好ましい。本発明の食品は、食品中の油脂として、本発明の油脂を50質量%以上含むことが好ましく、70質量%以上含むことがより好ましく、80〜100質量%含むことがさらに好ましい。なお、本発明の油脂を含有する食品とは、食品の製造にあたり、本発明の油脂を使用するプロセスを経なくても、食品に含まれる全油脂を基準として、構成脂肪酸として炭素数が6〜10である脂肪酸のみが結合したトリアシルグリセロールを0.005〜3質量%含有する態様を含むものである。   The food of the present invention is a food containing the fat or oil of the present invention. In order to efficiently obtain the effects of the present invention, the food of the present invention preferably contains 2% by mass or more of the oil or fat of the present invention, more preferably 5% by mass or more, and more preferably 10% by mass or more. Is more preferable. The food of the present invention preferably contains 50% by mass or more of the fats and oils of the present invention as fats and oils in the food, more preferably 70% by mass or more, and even more preferably 80 to 100% by mass. In addition, the food containing the fats and oils of the present invention has 6 to 6 carbon atoms as a constituent fatty acid, based on the total fats and oils contained in the foods, without the process of using the fats and oils of the present invention. This includes an embodiment containing 0.005 to 3% by mass of triacylglycerol to which only 10 fatty acids are bound.

本発明の食品は、本発明の油脂の他に、無脂乳固形分を含有することが好ましい。無脂乳固形分を含有すると、本発明の食品に乳様の風味が付与され易いので好ましい。無脂乳固形分は、乳製品に含まれる水分と脂肪とを除いた固形分であり、無脂乳脂固形分を含む乳製品としては、例えば、生乳、牛乳、脱脂乳、加工乳、クリームチーズ、ナチュラルチーズ、プロセスチーズ、濃縮乳、脱脂濃縮乳、加糖練乳、無糖練乳、無糖脱脂練乳、加糖脱脂練乳、全脂粉乳、脱脂粉乳、生クリーム、クリームパウダー、サワークリーム、乳清蛋白質、ホエー、ホエーパウダー、ホエー蛋白質濃縮物、ミルクプロテイン濃縮物、バターミルク、バターミルクパウダー、加糖粉乳、調製粉乳、はっ酵乳、ヨーグルト、乳酸菌飲料、乳飲料、カゼインカルシウム、カゼインナトリウム、カゼインカリウム、カゼインマグネシウム、乳清ミネラル等が挙げられる。   The food of the present invention preferably contains non-fat milk solids in addition to the fat of the present invention. Containing non-fat milk solids is preferable because a milky flavor is easily imparted to the food of the present invention. The non-fat milk solid content is a solid content excluding moisture and fat contained in the dairy product. Examples of the dairy product containing the non-fat milk fat solid content include raw milk, cow milk, skim milk, processed milk, and cream cheese. , Natural cheese, processed cheese, concentrated milk, defatted concentrated milk, sweetened condensed milk, unsweetened condensed milk, unsweetened defatted condensed milk, sweetened defatted condensed milk, whole fat powdered milk, defatted powdered milk, fresh cream, cream powder, sour cream, whey protein, whey , Whey powder, whey protein concentrate, milk protein concentrate, buttermilk, buttermilk powder, sweetened powdered milk, prepared milk powder, fermented milk, yogurt, lactic acid bacteria beverage, milk drink, casein calcium, casein sodium, casein potassium, casein magnesium, A whey mineral etc. are mentioned.

本発明の食品は、食品に含まれる全油脂と無脂乳固形分とを質量比で10:90〜99.5:0.5含有することが、食品の乳様の風味をより向上させる上で好ましい。本発明の食品における、食品に含まれる全油脂含有量と無脂乳固形分含有量との質量比は、20:80〜98:2であることがより好ましく、30:70〜95:5であることがさらに好ましく、40:60〜90:10であることが最も好ましい。   The food of the present invention contains the total fat and non-fat milk solids contained in the food in a mass ratio of 10:90 to 99.5: 0.5 to further improve the milky flavor of the food. Is preferable. In the food of the present invention, the mass ratio of the total fat content and the non-fat milk solid content contained in the food is more preferably 20:80 to 98: 2, and 30:70 to 95: 5. More preferably, it is most preferably 40:60 to 90:10.

本発明の食品は、また、乳化物であることが好ましい。乳化物とすることで、乳様の風味をより感じ易く、本発明の効果を効率的に得やすいので好ましい。乳化物は、油中水型、水中油型、複合乳化型等いずれの乳化型でもよい。乳化物の形態における本発明の食品中の本発明の油脂含有量は、2〜96質量%であることが好ましく、4〜90質量%であることがより好ましい。   The food of the present invention is also preferably an emulsion. It is preferable to use an emulsion because the milky flavor can be more easily felt and the effects of the present invention can be obtained efficiently. The emulsion may be any emulsion type such as a water-in-oil type, an oil-in-water type, or a composite emulsion type. The fat content of the present invention in the food of the present invention in the form of an emulsion is preferably 2 to 96% by mass, more preferably 4 to 90% by mass.

本発明の食品の好ましい態様としては、本発明の油脂を含むショートニング、シュガークリーム、ミルクチョコレート等の無水食品、ホイップクリーム、アイスクリーム、飲料用クリーム、調理用クリーム、フラワーペースト等のクリーム類、およびそれらを使用した、飲料、ソース、シチュウ、グラタン、チーズ様食品等、また、マーガリン、ファットスプレッド、バタークリーム等の油中水型食品、およびそれらを使用した菓子類、パン類等、また、各種ガナッシュ類等が挙げられる。
上記食品は、本発明の油脂を使用することを除いては、それぞれ各食品について通常行われる方法にて製造することができる。
Preferred embodiments of the food of the present invention include shortening, sugar cream, milk chocolate and other anhydrous food containing the fat and oil of the present invention, whipped cream, ice cream, beverage cream, cooking cream, cream such as flower paste, and the like. Beverages, sauces, stew, gratin, cheese-like foods, etc. using them, water-in-oil foods such as margarine, fat spread, butter cream, and confectionery, breads, etc. using them Examples include ganaches.
The said foodstuff can be manufactured by the method normally performed about each foodstuff except using the fats and oils of this invention, respectively.

以下、本発明を実施例によってさらに詳細に説明するが、本発明は以下の実施例の内容に限定して解釈されるものではない。   EXAMPLES Hereinafter, although an Example demonstrates this invention further in detail, this invention is limited to the content of the following Examples, and is not interpreted.

<分析方法>
トリアシルグリセロール含有量は、AOCS Ce5−86に準じて測定した。
各脂肪酸含有量は、AOCS Ce1f−96に準じて測定した。
<Analysis method>
The triacylglycerol content was measured according to AOCS Ce5-86.
Each fatty acid content was measured according to AOCS Ce1f-96.

<原料油脂の調製>
〔MCT1〕:トリアシルグリセロールを構成する脂肪酸がn−オクタン酸(炭素数8)とn−デカン酸(炭素数10)であり、その質量比が75:25であるMCT(日清オイリオグループ株式会社製)を、MCT1とした。
〔MCT2〕:トリアシルグリセロールを構成する脂肪酸がn−オクタン酸であるMCT(日清オイリオグループ株式会社社内製)をMCT2とした。
〔MCT3〕:トリアシルグリセロールを構成する脂肪酸がn−オクタン酸(炭素数8)とn−デカン酸(炭素数10)であり、その質量比が30:70であるMCT(日清オイリオグループ株式会社社内製)をMCT3とした。
〔植物油脂1〕:パーム中融点画分(日清オイリオグループ株式会社製、ラウリン酸含有量0質量%、MCT含有量0質量%)を植物油脂1とした。
〔植物油脂2〕:パーム核油(日清オイリオグループ株式会社製、ラウリン酸含有量46.1質量%、MCT含有量0質量%)を植物油脂2とした。
〔植物油脂3〕:ヤシ硬化油(日清オイリオグループ株式会社製、ラウリン酸含有量47.2質量%、MCT含有量0質量%)を植物油脂3とした。
〔植物油脂4〕:ヤシ油とパーム油とを質量比15:85で混合した油脂(日清オイリオグループ株式会社社内製、ラウリン酸含有量7.1質量%、MCT含有量0質量%)を植物油脂4とした。
〔エステル交換油1(IE1)〕:パーム油65質量部と菜種油35質量部とを混合した後、1,3選択性有するリパーゼ製剤を対油0.5質量%添加し、60℃で16時間エステル交換反応を行った。反応終了後、リパーゼ製剤をろ過で除去し、常法の精製方法に従って、脱色、脱臭処理してエステル交換油1(IE1、日清オイリオグループ株式会社社内製、ラウリン酸含有量0質量%、MCT含有量0質量%)を得た。
〔エステル交換油2(IE2)〕:パーム油60質量部とパーム核油40質量部とを混合した混合油を、減圧下120℃に加熱することにより十分に乾燥させた後、対油0.1質量%のナトリウムメチラートを添加し、減圧下、110℃で0.5時間攪拌しながらエステル交換反応を行った。反応終了後、ナトリウムメチラートを水洗除去し、常法の精製方法に従って、脱色、脱臭して、エステル交換油2(IE2、日清オイリオグループ株式会社社内製、ラウリン酸含有量18.2質量%、MCT含有量0質量%)を得た。
<Preparation of raw oil and fat>
[MCT1]: MCT (Nisshin Oillio Group shares) in which triacylglycerol is composed of n-octanoic acid (8 carbon atoms) and n-decanoic acid (10 carbon atoms) in a mass ratio of 75:25 MCT1).
[MCT2]: MCT (manufactured by Nisshin Oillio Group, Inc.) in which the fatty acid constituting triacylglycerol is n-octanoic acid was designated as MCT2.
[MCT3]: MCT (Nisshin Oillio Group shares) in which triacylglycerol is composed of n-octanoic acid (8 carbon atoms) and n-decanoic acid (10 carbon atoms) in a mass ratio of 30:70 MCT3 was made in-house.
[Vegetable fats and oils 1]: The palm middle melting point fraction (manufactured by Nissin Oilio Group Co., Ltd., lauric acid content 0 mass%, MCT content 0 mass%) was used as vegetable oil 1.
[Vegetable oil / fat 2] Palm oil (manufactured by Nisshin Oillio Group, Inc., lauric acid content 46.1% by mass, MCT content 0% by mass) was defined as vegetable oil / fat 2.
[Vegetable fat / oil 3]: Hardened coconut oil (manufactured by Nissin Oilio Group, lauric acid content 47.2% by mass, MCT content 0% by mass) was used as vegetable oil / fat 3.
[Vegetable fats and oils 4]: fats and oils (manufactured by Nisshin Oilio Group, in-house, lauric acid content 7.1 mass%, MCT content 0 mass%) mixed with palm oil and palm oil at a mass ratio of 15:85 Vegetable oil 4 was obtained.
[Transesterified oil 1 (IE1)]: After mixing 65 parts by mass of palm oil and 35 parts by mass of rapeseed oil, 0.5% by mass of a lipase preparation having 1,3 selectivity was added and the mixture was added at 60 ° C. for 16 hours. A transesterification reaction was performed. After completion of the reaction, the lipase preparation was removed by filtration, and decolorized and deodorized according to a conventional purification method to obtain transesterified oil 1 (IE1, Nisshin Oillio Group, in-house, lauric acid content 0% by mass, MCT A content of 0% by mass) was obtained.
[Transesterified oil 2 (IE2)]: A mixed oil obtained by mixing 60 parts by mass of palm oil and 40 parts by mass of palm kernel oil was sufficiently dried by heating to 120 ° C. under reduced pressure, and then 0. 1% by mass of sodium methylate was added, and a transesterification reaction was carried out with stirring at 110 ° C. for 0.5 hours under reduced pressure. After completion of the reaction, sodium methylate was removed by washing with water, followed by decolorization and deodorization according to a conventional purification method, and transesterified oil 2 (IE2, Nisshin Oillio Group, in-house, lauric acid content 18.2% by mass , MCT content 0 mass%) was obtained.

表1〜2の配合に従って、例1〜12の油脂を調製した。   The fats and oils of Examples 1 to 12 were prepared according to the formulations shown in Tables 1 and 2.

Figure 2019004913
Figure 2019004913

Figure 2019004913
Figure 2019004913

<アイスクリームの製造>
以下の製造手順1〜6により、表3に示す配合に従って、例1〜例12の油脂をそれぞれ使用したクリーム(アイスクリームミックス)を製造した。出来上がったクリームは、5℃で1日エージングした後、アイスクリーマーにてフリージングし、カップに充填した後、−20℃で1日以上保管した。
製造手順
1.水相原料および油相原料をそれぞれ別々の容器を用いて、70℃で加熱混合溶解した。
2.1で調製した水相原料を撹拌しながら、そこに1で調製した油相原料を徐々に加え混合した。
3.80度まで加熱して殺菌した。
4.ホモミキサーにて予備乳化を行った(4000rpm、10分)
5.ホモジナイザーを用いてホモジナイズした(1段目100kg/cm、2段目10kg/cm)。
6.氷水浴を用いて5℃まで冷却して、O/Wクリームを得た。
<Manufacture of ice cream>
According to the composition shown in Table 3, creams (ice cream mix) using the oils and fats of Examples 1 to 12 were produced according to the following production procedures 1 to 6. The finished cream was aged at 5 ° C. for 1 day, frozen with an ice creamer, filled in a cup, and stored at −20 ° C. for 1 day or more.
Manufacturing procedure The aqueous phase raw material and the oil phase raw material were heated and mixed and dissolved at 70 ° C. using separate containers.
While stirring the aqueous phase raw material prepared in 2.1, the oil phase raw material prepared in 1 was gradually added thereto and mixed.
3. Sterilized by heating to 80 degrees.
4). Pre-emulsification was performed with a homomixer (4000 rpm, 10 minutes)
5. Homogenization was performed using a homogenizer (first stage 100 kg / cm 2 , second stage 10 kg / cm 2 ).
6). It cooled to 5 degreeC using the ice water bath, and obtained O / W cream.

Figure 2019004913
Figure 2019004913

<アイスクリームの風味評価>
上記で製造した例1〜例12の油脂を使用したアイスクリームついて、以下の基準に従って、パネラー5名により乳様の風味の評価を行った。結果を表1、2に示した。

乳様の風味の評価基準
◎:例1と比較して有意に乳様の風味の強さを感じる
○:例1と比較して乳様の風味の強さを感じる
△:例1と比較して僅かに乳様の風味の強さを感じる
▲:例1と比較して極僅かに乳様の風味の強さを感じる
×:例1と比較して乳様の風味を感じない
<Ice cream flavor evaluation>
About the ice cream using the fats and oils of Examples 1 to 12 produced above, milky flavor was evaluated by five panelists according to the following criteria. The results are shown in Tables 1 and 2.

Evaluation criteria for milky flavor ◎: Feeling the strength of milky flavor significantly compared to Example 1 ○: Feeling the strength of milky flavor compared to Example 1 Δ: Compared with Example 1 A slight milky-like flavor is felt ▲: The milky-flavored strength is felt slightly compared with Example 1. ×: The milky flavor is not felt compared with Example 1

表4の配合に従って、例13〜16の油脂を調製した。   The fats and oils of Examples 13 to 16 were prepared according to the formulations shown in Table 4.

Figure 2019004913
Figure 2019004913

<ホイップクリームの製造>
以下の製造手順1〜6により、表5に示す配合に従って、例13〜例16の油脂をそれぞれ使用したホイップクリームを製造した。5℃で1日エージングした後、ホイップクリームに対して7質量%の砂糖を加えて泡立てた後、風味評価を実施した。
製造手順
1.水相原料および油相原料をそれぞれ別々の容器を用いて、70℃で加熱混合溶解した。
2.1で調製した水相原料を撹拌しながら、そこに1で調製した油相原料を徐々に加え混合した。
3.80度まで加熱して殺菌した。
4.ホモミキサーにて予備乳化を行った(4000rpm、10分)
5.ホモジナイザーを用いてホモジナイズした(1段目50kg/cm、2段目10kg/cm)。
6.氷水浴を用いて5℃まで冷却して、ホイップクリームを得た。
<Manufacture of whipped cream>
According to the formulation shown in Table 5, the whipped cream which each used the fats and oils of Examples 13-16 was manufactured by the following manufacturing procedures 1-6. After aging at 5 ° C. for 1 day, 7% by mass of sugar was added to the whipped cream, and the flavor was evaluated.
Manufacturing procedure The aqueous phase raw material and the oil phase raw material were heated and mixed and dissolved at 70 ° C. using separate containers.
While stirring the aqueous phase raw material prepared in 2.1, the oil phase raw material prepared in 1 was gradually added thereto and mixed.
3. Sterilized by heating to 80 degrees.
4). Pre-emulsification was performed with a homomixer (4000 rpm, 10 minutes)
5. Homogenization was performed using a homogenizer (first stage 50 kg / cm 2 , second stage 10 kg / cm 2 ).
6). The mixture was cooled to 5 ° C. using an ice water bath to obtain whipped cream.

Figure 2019004913
Figure 2019004913

<ホイップクリームの風味評価>
上記で製造した例13〜例16の油脂を使用したホイップクリームついて、以下の基準に従って、パネラー5名により乳様の風味の評価を行った。結果を表4に示した。

乳様の風味の評価基準
◎:例13と比較して有意に乳様の風味の強さを感じる
○:例13と比較して乳様の風味の強さを感じる
△:例13と比較して僅かに乳様の風味の強さを感じる
▲:例13と比較して極僅かに乳様の風味の強さを感じる
×:例13と比較して乳様の風味を感じない
<Flavor evaluation of whipped cream>
About the whipped cream which used the fats and oils of Examples 13-16 manufactured above, evaluation of milky taste was performed by five panelists according to the following criteria. The results are shown in Table 4.

Evaluation criteria for milky flavor ◎: Feeling the strength of milky flavor significantly compared to Example 13 ○: Feeling the strength of milky flavor compared to Example 13 Δ: Compared with Example 13 Feels slightly milky flavor ▲: feels slightly milky flavor compared to Example 13 ×: does not feel milky flavor compared to Example 13

表6の配合に従って、例17〜18の油脂を調製した。
なお、原料油脂として、さらに以下のものを使用した。
〔植物油脂5〕:パーム油(日清オイリオグループ株式会社製、ラウリン酸含有量0質量%、MCT含有量0質量%)を植物油脂5とした。
〔植物油脂6〕:ヤシ油(日清オイリオグループ株式会社製、ラウリン酸含有量47.2質量%、MCT含有量0質量%)を植物油脂6とした。
〔植物油脂7〕:紅花油(日清オイリオグループ株式会社社内製、ラウリン酸含有量0質量%、MCT含有量0質量%)を植物油脂7とした。
According to the composition of Table 6, the fats and oils of Examples 17 to 18 were prepared.
In addition, the following were further used as raw material fats and oils.
[Vegetable oil / fat 5]: Palm oil (manufactured by Nisshin Oillio Group, lauric acid content 0 mass%, MCT content 0 mass%) was used as vegetable oil 5.
[Vegetable oil / fat 6]: Palm oil (manufactured by Nisshin Oillio Group, lauric acid content: 47.2% by mass, MCT content: 0% by mass) was defined as vegetable oil / fat 6.
[Vegetable fats and oils 7]: Safflower oil (Nisshin Oillio Group, in-house, lauric acid content 0 mass%, MCT content 0 mass%) was used as vegetable oil 7

Figure 2019004913
Figure 2019004913

<コーヒーホワイトナーの製造>
以下の製造手順1〜6により、表7に示す配合に従って、例17、18の油脂をそれぞれ使用したコーヒーホワイトナーを製造した。5℃で1日エージングした後、コーヒーホワイトナーの風味評価を実施した。
製造手順
1.水相原料および油相原料をそれぞれ別々の容器を用いて、70℃で加熱混合溶解した。
2.1で調製した水相原料を撹拌しながら、そこに1で調製した油相原料を徐々に加え混合した。
3.ホモジナイザーを用いてホモジナイズした(1段目200kg/cm、2段目50kg/cm)。
4.85度10分間の加熱殺菌を行った。
5.ホモジナイザーを用いてホモジナイズした(1段目150kg/cm、2段目50kg/cm)。
6.氷水浴を用いて30℃まで冷却して、コーヒーホワイトナーを得た。
<Manufacture of coffee whitener>
Coffee whiteners using the oils and fats of Examples 17 and 18 were produced according to the formulation shown in Table 7 by the following production procedures 1 to 6. After aging at 5 ° C. for 1 day, the flavor of the coffee whitener was evaluated.
Manufacturing procedure The aqueous phase raw material and the oil phase raw material were heated and mixed and dissolved at 70 ° C. using separate containers.
While stirring the aqueous phase raw material prepared in 2.1, the oil phase raw material prepared in 1 was gradually added thereto and mixed.
3. Homogenization was performed using a homogenizer (first stage 200 kg / cm 2 , second stage 50 kg / cm 2 ).
4.85 degreeC heat sterilization for 10 minutes was performed.
5. Homogenization was performed using a homogenizer (first stage 150 kg / cm 2 , second stage 50 kg / cm 2 ).
6). The mixture was cooled to 30 ° C. using an ice water bath to obtain a coffee whitener.

Figure 2019004913
Figure 2019004913

<コーヒーホワイトナーの風味評価>
インスタントコーヒー2gに熱湯100gを注いだコーヒーに、上記で製造した例17、18の油脂を使用したコーヒーホワイトナーを5g添加して撹拌した後、以下の基準に従って、パネラー5名により乳様の風味の評価を行った。結果を表6に示した。

乳様の風味の評価基準
◎:例17と比較して有意に乳様の風味の強さを感じる
○:例17と比較して乳様の風味の強さを感じる
△:例17と比較して僅かに乳様の風味の強さを感じる
▲:例17と比較して極僅かに乳様の風味の強さを感じる
×:例17と比較して乳様の風味を感じない
<Flavor evaluation of coffee whitener>
After adding 5 g of coffee whitener using the oils and fats of Examples 17 and 18 prepared above to 100 g of hot water poured into 2 g of instant coffee and stirring, the milky flavor was given by 5 panelists according to the following criteria. Was evaluated. The results are shown in Table 6.

Evaluation criteria for milky flavor ◎: Feeling the strength of milky flavor significantly compared with Example 17 ○: Feeling the strength of milky flavor compared with Example 17 Δ: Compared with Example 17 Feels slightly milky flavor ▲: feels slightly milky flavor compared to Example 17 ×: does not feel milky flavor compared to Example 17

表8の配合に従って、例19〜20の油脂を調製した。
なお、原料油脂として、さらに以下のものを使用した。
〔植物油脂8〕:パームステアリン(日清オイリオグループ株式会社内製、ラウリン酸含有量0質量%、MCT含有量0質量%)を植物油脂8とした。
〔植物油脂9〕:菜種油(日清オイリオグループ株式会社製、ラウリン酸含有量0質量%、MCT含有量0質量%)を植物油脂9とした。
〔バターオイル1〕:バターオイル(日清オイリオグループ株式会社社内製、ラウリン酸含有量2.6質量%、MCT含有量0質量%)をバターオイル1とした。
According to the formulation of Table 8, the fats and oils of Examples 19 to 20 were prepared.
In addition, the following were further used as raw material fats and oils.
[Vegetable oil / fat 8]: Palm stearin (manufactured by Nisshin Oillio Group Co., Ltd., lauric acid content 0 mass%, MCT content 0 mass%) was used as vegetable oil 8.
[Vegetable oil / fat 9]: Rapeseed oil (manufactured by Nisshin Oillio Group, lauric acid content 0% by mass, MCT content 0% by mass) was used as vegetable oil / fat 9.
[Butter oil 1]: Butter oil (made by Nisshin Oillio Group, in-house, lauric acid content 2.6 mass%, MCT content 0 mass%) was used as butter oil 1.

Figure 2019004913
Figure 2019004913

<マーガリンの製造>
以下の製造手順1〜4により、表9に示す配合に従って、例19、20の油脂をそれぞれ使用したマーガリンを製造した。5℃で1日エージングした後、風味評価を実施した。
製造手順
1.水相原料および油相原料をそれぞれ別々の容器を用いて、70℃で加熱混合溶解した。
2.1で調製した油相原料を撹拌しながら、そこに1で調製した水相原料を徐々に加え混合した。
3.80度まで加熱して殺菌した。
4.オンレーターを使用して常法のとおりに急冷混練を行った。
<Manufacture of margarine>
By the following production procedures 1 to 4, margarines using the oils and fats of Examples 19 and 20 were produced according to the formulation shown in Table 9. After aging at 5 ° C. for 1 day, flavor evaluation was performed.
Manufacturing procedure The aqueous phase raw material and the oil phase raw material were heated and mixed and dissolved at 70 ° C. using separate containers.
While stirring the oil phase raw material prepared in 2.1, the water phase raw material prepared in 1 was gradually added and mixed there.
3. Sterilized by heating to 80 degrees.
4). Quenching and kneading were performed as usual using an onlator.

Figure 2019004913
Figure 2019004913

<マーガリンの風味評価>
上記で製造した例19、20の油脂を使用したマーガリンついて、以下の基準に従って、パネラー5名により乳様の風味(乳脂肪の味の強さ)評価を行った。結果を表8に示した。

乳様の風味の評価基準
◎:例19と比較して有意に乳脂肪の味の強さを感じる
○:例19と比較して乳脂肪の味の強さを感じる
△:例19と比較して僅かに乳脂肪の味の強さを感じる
▲:例19と比較して極僅かに乳脂肪の味の強さを感じる
×:例19と比較して乳脂肪の味が少ない
<Margarine flavor evaluation>
About margarine using the fats and oils of Examples 19 and 20 produced above, milky flavor (intensity of milk fat taste) was evaluated by five panelists according to the following criteria. The results are shown in Table 8.

Evaluation criteria for milky taste ◎: Feeling the strength of milk fat taste significantly compared to Example 19 ○: Feeling the strength of milk fat taste compared to Example 19 Δ: Compared to Example 19 Slightly feels the intensity of milk fat taste ▲: feels slightly slightly the intensity of milk fat taste compared to Example 19 ×: less milk fat taste than Example 19

Claims (1)

構成脂肪酸として炭素数が6〜10である脂肪酸のみが結合したトリアシルグリセロールを含む、乳化物である食品であって、
前記構成脂肪酸として炭素数が6〜10である脂肪酸のみが結合したトリアシルグリセロールの、構成脂肪酸全量に占める炭素数8の脂肪酸の含有量が75質量%以上であり、
前記乳化物である食品に含まれる油脂全量に占める、前記構成脂肪酸として炭素数が6〜10である脂肪酸のみが結合したトリアシルグリセロールの含有量が0.005〜3質量%であり、
前記乳化物である食品に含まれる、全油脂の含有量と無脂乳固形分含有量との質量比が60.1:39.9〜91.2:8.8である、
前記乳化物である食品。
A food that is an emulsion containing triacylglycerol to which only a fatty acid having 6 to 10 carbon atoms is bound as a constituent fatty acid,
The content of the fatty acid having 8 carbon atoms in the total amount of the constituent fatty acid of the triacylglycerol to which only the fatty acid having 6 to 10 carbon atoms is bound as the constituent fatty acid is 75% by mass or more,
The content of triacylglycerol to which only fatty acids having 6 to 10 carbon atoms are bound as the constituent fatty acid in the total amount of fats and oils contained in the food that is the emulsion is 0.005 to 3% by mass,
The mass ratio of the total fat content and the non-fat milk solid content contained in the food that is the emulsion is 60.1: 39.9 to 91.2: 8.8.
A food which is the emulsion.
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