JP2018205703A5 - - Google Patents

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JP2018205703A5
JP2018205703A5 JP2018087298A JP2018087298A JP2018205703A5 JP 2018205703 A5 JP2018205703 A5 JP 2018205703A5 JP 2018087298 A JP2018087298 A JP 2018087298A JP 2018087298 A JP2018087298 A JP 2018087298A JP 2018205703 A5 JP2018205703 A5 JP 2018205703A5
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Prior art keywords
carbon black
electrophotographic
electrophotographic belt
belt
raw material
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JP2018087298A
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JP2018205703A (en
JP7064374B2 (en
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Priority to US15/988,180 priority Critical patent/US10372067B2/en
Priority to KR1020180060843A priority patent/KR102191948B1/en
Publication of JP2018205703A publication Critical patent/JP2018205703A/en
Publication of JP2018205703A5 publication Critical patent/JP2018205703A5/ja
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Claims (10)

熱可塑性樹脂とカーボンブラックとを含む導電性の基層を有する、エンドレスベルト形状の電子写真用ベルトであって、
該基層は、該熱可塑性樹脂と該カーボンブラックとを含む樹脂混合物の円筒押出成形物であり、
該円筒押出成形物の断面を、0.01nm/pixel以上、1nm/pixel以下の解像度、かつ最低階調が0より大きく、最高階調が255未満とする条件にて透過型電子顕微鏡(TEM)で観察し、TEM画像を得て、さらに、該TEM画像から、該カーボンブラックが占める面積比率が50%以上である、一辺が100nmである正方形領域を抽出し、該正方形領域内における、該カーボンブラックに起因する、該正方形領域を構成する各ピクセルの階調情報を頻度分布化した階調分布において最低階調側から1頻度%を構成する複数個のピクセルのうち、互いに隣接してなるピクセル群の面積が10nm以上であることを特徴とする電子写真用ベルト。
An endless belt-shaped electrophotographic belt having a conductive base layer containing a thermoplastic resin and carbon black.
The base layer is a cylindrical extruded product of a resin mixture containing the thermoplastic resin and the carbon black.
A transmission electron microscope (TEM) is used under the conditions that the cross section of the cylindrical extruded product has a resolution of 0.01 nm / pixel or more and 1 nm / pixel or less, a minimum gradation of more than 0, and a maximum gradation of less than 255. in observation, to obtain a TEM image, further, from the TEM image, the area ratio of the carbon black is occupied by 50% or more, extracting a square region one side is 100 nm, in the square area, the carbon Pixels adjacent to each other among a plurality of pixels constituting 1 frequency% from the lowest gradation side in a gradation distribution in which the gradation information of each pixel constituting the square region is frequency-distributed due to black An electrophotographic belt characterized in that the area of the group is 10 nm 2 or more.
前記熱可塑性樹脂は、ポリエーテルエーテルケトン、もしくはポリフェニレンサルファイドである請求項1に記載の電子写真用ベルト。 The electrophotographic belt according to claim 1, wherein the thermoplastic resin is polyetheretherketone or polyphenylene sulfide. 前記基層の平均膜厚が、25μm以上100μm以下である請求項1または2に記載の電子写真用ベルト。 The electrophotographic belt according to claim 1 or 2, wherein the average film thickness of the base layer is 25 μm or more and 100 μm or less. 前記カーボンブラックが、表面に有機化合物由来の凸部を有する請求項1〜3のいずれか一項に記載の電子写真用ベルト。 The electrophotographic belt according to any one of claims 1 to 3, wherein the carbon black has a convex portion derived from an organic compound on the surface. 前記カーボンブラックが、原料カーボンブラックの表面に有機物を付着させ、該有機物を焼成することにより形成されたものである請求項4に記載の電子写真用ベルト。 The electrophotographic belt according to claim 4, wherein the carbon black is formed by adhering an organic substance to the surface of the raw material carbon black and firing the organic substance. 前記原料カーボンブラックが、アセチレンブラックである請求項5に記載の電子写真用ベルト。 The electrophotographic belt according to claim 5, wherein the raw material carbon black is acetylene black. 電子写真感光体と、
該電子写真感光体に形成された未定着のトナー像が1次転写される中間転写ベルトと、
該中間転写ベルトに転写されたトナー像を記録媒体に2次転写させるための2次転写手段と、
を備えている電子写真画像形成装置であって、
該中間転写ベルトが、請求項1〜6のいずれか一項に記載の電子写真用ベルトである、ことを特徴とする電子写真画像形成装置。
Electrophotographic photosensitive member and
An intermediate transfer belt on which an unfixed toner image formed on the electrophotographic photosensitive member is primarily transferred, and an intermediate transfer belt.
Secondary transfer means for secondarily transferred to a recording medium the toner image transferred to the transfer belts between intermediate,
It is an electrophotographic image forming apparatus equipped with
An electrophotographic image forming apparatus according to any one of claims 1 to 6, wherein the intermediate transfer belt is an electrophotographic belt.
電子写真用ベルトの製造方法であって、It is a method of manufacturing an electrophotographic belt.
原料カーボンブラックの表面に有機物を付着させる工程と、The process of adhering organic substances to the surface of the raw material carbon black,
該有機物を表面に付着させた該原料カーボンブラックを、該有機物の熱分解開始温度以上、該原料カーボンブラックの分解温度以下の温度で焼成することによって、処理済みカーボンブラックを得る工程と、A step of obtaining treated carbon black by firing the raw material carbon black having the organic substance adhered to the surface at a temperature equal to or higher than the thermal decomposition start temperature of the organic substance and lower than the decomposition temperature of the raw material carbon black.
該処理済みカーボンブラックと熱可塑性樹脂とを溶融混錬して導電性樹脂組成物を得る工程と、A step of melt-kneading the treated carbon black and a thermoplastic resin to obtain a conductive resin composition, and
該導電性樹脂組成物をチューブ状に溶融押出しする工程と、を有することを特徴とする電子写真用ベルトの製造方法。A method for producing an electrophotographic belt, which comprises a step of melt-extruding the conductive resin composition into a tube shape.
前記有機物が、非イオン系界面活性剤である請求項8に記載の電子写真用ベルトの製造方法。The method for producing an electrophotographic belt according to claim 8, wherein the organic substance is a nonionic surfactant. 前記非イオン系界面活性剤が、ポリオキシエチレンアルキルエーテルである請求項9に記載の電子写真用ベルトの製造方法。The method for producing an electrophotographic belt according to claim 9, wherein the nonionic surfactant is a polyoxyethylene alkyl ether.
JP2018087298A 2017-05-30 2018-04-27 Electrophotographic belt and electrophotographic image forming apparatus Active JP7064374B2 (en)

Priority Applications (2)

Application Number Priority Date Filing Date Title
US15/988,180 US10372067B2 (en) 2017-05-30 2018-05-24 Electrophotographic belt and electrophotographic image forming apparatus
KR1020180060843A KR102191948B1 (en) 2017-05-30 2018-05-29 Electrophotographic belt and electrophotographic image forming apparatus

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP2017106887 2017-05-30
JP2017106887 2017-05-30

Publications (3)

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JP2018205703A JP2018205703A (en) 2018-12-27
JP2018205703A5 true JP2018205703A5 (en) 2021-06-17
JP7064374B2 JP7064374B2 (en) 2022-05-10

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Family Cites Families (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP4470654B2 (en) 2004-08-31 2010-06-02 富士ゼロックス株式会社 Semiconductive belt and image forming apparatus
JP2007164029A (en) 2005-12-16 2007-06-28 Ricoh Co Ltd Intermediate transfer body and its manufacturing method, and image forming apparatus
US9250547B2 (en) 2014-02-14 2016-02-02 Xerox Corporation Intermediate transfer members and processes
JP6331868B2 (en) 2014-08-19 2018-05-30 富士ゼロックス株式会社 Extruded tubular body, tubular body unit, intermediate transfer body, recording medium transport body, and image forming apparatus
JP2017040871A (en) 2015-08-21 2017-02-23 油化電子株式会社 Lamination belt for image forming apparatus and image forming apparatus

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