JP2018178336A - Fiber product and fabric for glove - Google Patents

Abstract

PROBLEM TO BE SOLVED: To provide a fabric for glove which is excellent in air ventilation and has a durability, grip force, and high quality of surface friction resistance, and a fiber product using the same.SOLUTION: The fabric for glove that has a knit composition and a textile composition includes a filament string A of 10 to 3000 nm of a single fiber diameter and has an open hole, the shape of open hole is constituted from circle, half circle, fan shape, elliptic, and the three to ten square, the filament string A is a line of thread that obtained from the process of removal by dissolving of sea composition of sea island composition textile from a sea composition and an island composition, and in the rear side and the front side, the coefficient of static friction is in the range of 0.8 to 3.5.SELECTED DRAWING: Figure 2

Description

  The present invention relates to a glove cloth having high surface friction resistance, grip, excellent durability and excellent breathability, and a textile product using the cloth.

  Conventionally, natural leather, artificial leather, synthetic fiber suede and the like have been used for gloves (eg, Patent Document 1). However, although natural leather is excellent in fit and grip, there is a problem in durability. On the other hand, although artificial leather and synthetic fiber suede are excellent in durability, they have a problem that they have poor fit and grip.

  As a countermeasure against this, a glove cloth using ultrafine fibers (for example, Patent Document 2) has been proposed, but in order to obtain an excellent grip, it is a high density cloth, and the air permeability of the cloth is bad. There was a problem with wearing comfort such as stuffiness occurring in the glove during the hot season.

  A glove fabric using ultrafine fibers, which has both fit, grip, long-term durability and wearing comfort, has not been proposed so far.

JP 2005-154925 A Patent No. 5356771 gazette

  The present invention has been made in view of the above background, and its object is to provide a glove cloth having both high surface friction resistance, grip, excellent durability and excellent breathability, and a fiber made of the cloth. To provide products.

  As a result of intensive investigations to achieve the above-mentioned problems, the inventor of the present invention found that through-holes are formed in a glove cloth using ultrafine fibers, thereby providing both high surface friction resistance, grip and excellent durability, and air permeability. The present invention has been accomplished by finding out that an excellent glove cloth can be obtained, and by conducting intensive studies.

Thus, according to the present invention, “a glove fabric having a woven or knitted texture, wherein the fabric comprises filament yarn A having a single fiber diameter of 10 to 3000 nm and is characterized by having a through hole. Fabric for the purpose of
At that time, it is preferable that the shape of the through hole is any one selected from the group consisting of a circle, a semicircle, a sector, an ellipse, and a tridecadecagon. Moreover, in the said through-hole, it is preferable that an outer diameter is in the range of 0.5-15 mm. Moreover, it is preferable that the total area of the said through-hole exists in the range of 0.5 to 10% with respect to a fabric area. Preferably, a plurality of the through holes are formed in a pattern. The number of filaments of the filament yarn A is preferably 500 or more. Preferably, the filament yarn A is a yarn obtained by dissolving and removing the sea component of a sea-island composite fiber comprising a sea component and an island component.
In the glove cloth of the present invention, the cloth is preferably a knit. Further, it is preferable that at least one of the front surface and the back surface of the fabric is subjected to a raising process. Moreover, it is preferable that the static friction coefficient is in the range of 0.8 to 3.5 on both the front and back of the fabric.
Further, according to the present invention, golf gloves, baseball gloves, tennis gloves, various sports gloves, outdoor gloves, work gloves, precision work gloves, medical gloves, life support using the above glove cloth Any textile product selected from the group consisting of gloves is provided.

  According to the present invention, it is possible to obtain a glove cloth having both high surface friction resistance, grip and excellent durability, and excellent in air permeability, and a fiber product using the cloth.

It is a figure which shows the measuring method of a friction coefficient. It is an example (drawing substitute photograph) of the cloth for gloves concerning the present invention.

  Hereinafter, embodiments of the present invention will be described in detail.

The gloved fabric according to the present invention is a gloved fabric having a woven or knitted fabric, and the fabric includes filament yarn A having a single fiber diameter of 10 to 3000 nm.
Here, in the filament yarn A, it is important that the single fiber diameter (diameter of single fiber) is in the range of 10 to 3000 nm (preferably 100 to 800 nm, particularly preferably 510 to 800 nm). When the single fiber diameter is smaller than 10 nm, the fiber strength is lowered, which is not preferable in practical use. On the contrary, when the diameter of the single fiber is larger than 3000 nm, there is a possibility that sufficient grip can not be obtained. Here, when the cross-sectional shape of the single fiber is a modified cross-section other than a round cross-section, the diameter of the circumscribed circle is taken as the diameter of the single fiber. The single fiber diameter can be measured by photographing the cross section of the fiber with a transmission electron microscope.

The number of filaments in the filament yarn A is not particularly limited, but is preferably 500 or more (more preferably 2000 to 20000) in order to obtain high grip. The total fineness (the product of the single fiber fineness and the number of filaments) of the filament yarn A is preferably in the range of 5 to 300 dtex.
The fiber form of the filament yarn A is not particularly limited, but is preferably a long fiber (multifilament yarn). The cross-sectional shape of the single fiber is also not particularly limited, and may be a known cross-sectional shape such as round, triangular, flat or hollow. In addition, normal air processing and false twist crimping may be applied.
The fiber type of the filament yarn A is preferably polyester fiber, polyphenylene sulfide (PPS) fiber, polyolefin fiber or nylon (Ny) fiber.

  Examples of polyesters that form polyester fibers include polyethylene terephthalate (PET), polytrimethylene terephthalate, polybutylene terephthalate, polyethylene naphthalate, and aromatics such as isophthalic acid and metal salt of 5-sulfoisophthalic acid containing these as main repeating units. Aliphatic dicarboxylic acids such as dicarboxylic acids, adipic acid and sebacic acid, hydroxycarboxylic acid condensates such as ε-caprolactone, and copolymers with glycol components such as diethylene glycol, trimethylene glycol, tetramethylene glycol, hexamethylene glycol, etc. preferable. The material may be polyester recycled by material recycling or chemical recycling, or polyethylene terephthalate as described in JP-A-2009-091694, which uses a monomer component obtained by using a biomass, that is, a substance of biological origin as a raw material. Furthermore, polyesters obtained using a catalyst containing a specific phosphorus compound and a titanium compound as described in JP-A-2004-270097 and JP-A-2004-211268 may be used.

Any polyarylene sulfide resin forming a polyphenylene sulfide (PPS) fiber may be used as long as it belongs to a category called polyarylene sulfide resin. As a polyarylene sulfide resin, as its constituent unit, for example, p-phenylene sulfide unit, m-phenylene sulfide unit, o-phenylene sulfide unit, phenylene sulfide sulfone unit, phenylene sulfide ketone unit, phenylene sulfide ether unit, diphenylene sulfide unit And those containing a substituent-containing phenylene sulfide unit, a branched structure-containing phenylene sulfide unit, and the like. Among them, those containing 70 mol% or more, particularly 90 mol% or more of p-phenylene sulfide units are preferable, and poly (p-phenylene sulfide) is more preferable.
Polyolefin fibers also include polypropylene fibers and polyethylene fibers.
Also, nylon fibers include nylon 6 fibers and nylon 66 fibers.

  In the polymer for forming the fiber, a micropore forming agent, a cationic dye dyeable agent, an anticoloring agent, a heat stabilizer, a fluorescent whitening agent, and a gloss may be added within the range not impairing the object of the present invention. One or two or more kinds of an eraser, a colorant, a hygroscopic agent, and inorganic fine particles may be contained.

  In the present invention, in addition to the filament yarn A, when the fabric includes a filament yarn B having a single fiber diameter larger than that of the filament yarn A, the rigidity of the fabric is preferably improved.

The number of filaments in the filament yarn B is not particularly limited, but is preferably in the range of 1 to 300. The filament yarn B is preferably a composite fiber composed of two or more polyester components, at least one of which is polytrimethylene terephthalate. Preferred examples of the other component include polyethylene terephthalate, polytrimethylene terephthalate, polybutylene terephthalate, polylactic acid, polyester obtained by copolymerizing the third component, and the like. Such polyester may be material recycled or chemically recycled polyester. Such polyester may be material recycled or chemically recycled polyester. Furthermore, polyesters obtained using a catalyst containing a specific phosphorus compound and a titanium compound as described in JP-A-2004-270097 and JP-A-2004-211268 may be used. In the polymer, as necessary, within the range not impairing the object of the present invention, a micropore forming agent, a cationic dye dyeable agent, a coloring inhibitor, a heat stabilizer, a brightening agent, a matting agent, coloring The agent, the hygroscopic agent, and the inorganic fine particles may be contained alone or in combination of two or more.
The fiber form of the filament yarn B is not particularly limited and may be a spun yarn, but a long fiber (multifilament yarn) is preferred. The cross-sectional shape of the single fiber is also not particularly limited, and may be a known cross-sectional shape such as round, triangular, flat or hollow. In addition, normal air processing and false twist crimping may be applied.

  In the glove cloth according to the present invention, the exposed ratio of the filament yarn A on the surface is 40% or more (more preferably 40 to 95%), and the filament yarn A is exposed on both the front and back of the fabric. Is preferred. In the case where the filament yarn A is not exposed on both the front and back surfaces, the high surface friction resistance and the grip that are the main object of the present invention may not be obtained.

The glove cloth of the present invention has a through hole penetrating from the front surface to the back surface (from the back surface to the front surface). Examples of the shape of the through hole include a circle, a semicircle, a sector, an ellipse, a triangle, a quadrangle, a pentagon, a hexagon, a heptagon, an octagon, a pentagon, and a decagon.
Further, as the size of the through hole, the outer diameter (diameter of circumscribed circle) is preferably in the range of 0.5 to 15 mm (more preferably 0.5 to 3.0 mm).

  In addition, the total area of the through holes (total of the through holes) is preferably in the range of 0.5 to 10% (more preferably 1.0 to 4.0%) relative to the unit area of the fabric. . If the total area of the through holes is smaller than the above range, the air permeability may be reduced and the wearing comfort may be deteriorated. On the other hand, if the total area of the through holes is larger than the above range, the surface frictional resistance or the grip may be reduced, or the physical strength of the fabric may be reduced, and the durability may be reduced.

  Moreover, in order to improve designability as well as to improve air permeability, it is preferable that a plurality of the through holes are formed in a pattern. At that time, as a pattern (dot pattern), a warp lattice, an illusion lattice, a multiple circle, etc. are exemplified. Moreover, it is preferable that the space | interval of the through holes adjacent to each other is in the range of 1 to 50 mm in the warp direction or the weft direction. At this time, the distance is to measure the distance from the center of the through hole to the center of the adjacent through hole.

  The glove cloth of the present invention can be produced, for example, by the following production method. First, a sea-island composite fiber (fiber for filament yarn A) formed of a sea component and an island component having a diameter of 10 to 3000 nm is prepared. As this sea-island type composite fiber, a sea-island type composite fiber (number of islands 100 to 1500) disclosed in Japanese Patent Application Laid-Open No. 2007-2364 is preferably used.

  That is, as the sea component polymer, polyester, polyamide, polystyrene, polyethylene and the like having a good fiber forming property are preferable. For example, as an alkaline aqueous solution-soluble polymer, polylactic acid, ultrahigh molecular weight polyalkylene oxide condensation polymer, polyethylene glycol compound copolymer polyester, polyethylene glycol compound and 5-sodium sulfonic acid isophthalic acid copolymer polyester It is suitable. Among them, a polyethylene terephthalate copolymer polyester having an intrinsic viscosity of 0.4 to 0.6 obtained by copolymerizing 3 to 10% by weight of polyethylene glycol having a molecular weight of 4000 to 12000 with 3 to 12 mol% of 5-sodium sulfoisophthalic acid Is preferred.

  On the other hand, examples of island component polymers include polyester, polyphenylene sulfide, polyolefin, nylon and the like. Polyesters such as fiber-forming polyethylene terephthalate, polytrimethylene terephthalate, polybutylene terephthalate, polylactic acid, and polyesters copolymerized with the third component are preferable, and among these, polytrimethylene terephthalate is most preferable. In the polymer, as necessary, within the range not impairing the object of the present invention, a micropore forming agent, a cationic dye dyeable agent, a coloring inhibitor, a heat stabilizer, a brightening agent, a matting agent, coloring The agent, the hygroscopic agent, and the inorganic fine particles may be contained alone or in combination of two or more.

  In the sea-island composite fiber comprising the above sea component polymer and island component polymer, it is preferable that the melt viscosity of the sea component at the time of melt spinning is larger than the melt viscosity of the island component polymer. Further, the diameter of the island component needs to be in the range of 10 to 1,500 nm. At this time, if the shape of the island component is not a perfect circle, the diameter of the circumscribed circle is obtained. In the sea-island composite fiber, the sea-island composite weight ratio (sea: island) is preferably in the range of 40:60 to 5:95, and particularly preferably in the range of 30:70 to 10:90.

  Such sea-island composite fiber can be easily manufactured, for example, by the following method. That is, melt spinning is performed using the above-mentioned sea component polymer and island component polymer. As a spinneret used for melt spinning, it is possible to use an arbitrary one such as one having a hollow pin group or a micropore group for forming an island component. The discharged sea-island cross-section composite fiber is solidified by a cooling air, preferably melt spun at 400 to 6000 m / min and wound up. The obtained undrawn yarn is made into a composite fiber having desired strength, elongation, and heat shrinkage characteristics through a separate drawing process, or is taken up by a roller at a constant speed without being wound up once, and subsequently a drawing process. It does not matter which method is taken up after passing through. In this sea-island composite fiber, the single fiber fineness, the number of filaments, and the total fineness are preferably within the ranges of single fiber fineness 0.5 to 10.0 dtex, filament number 5 to 75, and total fineness 30 to 170 dtex, respectively. . Moreover, it is preferable that it is in the range of 5 to 30% as a boiling water shrinkage | contraction rate of this sea-island type composite fiber.

  On the other hand, if necessary, a filament yarn B having a single fiber diameter larger than that of the filament yarn A is prepared. In the filament yarn B, the number of filaments and the total fineness is preferably in the range of 1 to 300 filaments and the total fineness of 10 to 800 dtex. Moreover, it is preferable that a single fiber fineness is 1.0 dtex or more. In addition, such a filament yarn B is preferably a composite fiber in which at least one component is polytrimethylene terephthalate, because it is composed of two or more types of polyester components, because an excellent elongation recovery rate can be obtained.

  Then, using the sea-island composite fiber (fiber for filament yarn A) and, if necessary, the filament yarn B, a woven / knitted fabric is usually made such that the sea-island composite fiber is exposed on the front and / or back of the fabric. Weave by At that time, the sea-island composite fiber and the filament yarn B may be included in the woven or knitted fabric as a mixed yarn, but by knitting or interweaving the sea-island composite fiber and the filament B It is preferred to weave the fabric.

  Here, the weave structure and the weave structure are not particularly limited, and examples of the weft knitting structure include plain knitting, rubber knitting, double-sided knitting, pearl knitting, tack knitting, float knitting, single-piece knitting, lace knitting, covered knitting and the like The illustrated warp knitting structure is exemplified by single denby knitting, single atlas knitting, double cord knitting, half knitting, half base knitting, satin knitting, half tricot knitting, fleece knitting, jacquard knitting etc. Examples thereof include, but are not limited to, three-dimensional tissues such as plain weave, twill weave and satin weave, modified tissues, single double weaves such as vertical double weave, horizontal double weave, and vertical velvet. The number of layers may be a single layer or may be a multilayer of two or more layers. Among them, when the fabric is a knitted fabric, the knitted fabric is preferably stretchable, so that it is easy to fit the object.

  Then, the woven or knitted fabric (fabric) is treated with an aqueous alkali solution, and the sea component of the sea-island composite fiber is dissolved and removed with the aqueous alkali solution to obtain a sea-island composite fiber with filament yarn A having a single fiber diameter of 10 to 3000 nm. Do. At that time, as a condition of the alkaline aqueous solution treatment, it is preferable to treat at a temperature of 55 to 65 ° C. using a 3 to 4% concentration aqueous NaOH solution.

  In addition, the fabric may be subjected to a dyeing process before and / or after the dissolution and removal with the aqueous alkaline solution. Calendering (heating and pressing) or embossing may be applied. In addition, various methods for imparting functions such as conventional brushing treatment, water repellent treatment, UV shielding or antistatic agent, antibacterial agent, deodorant, insect repellent, luminous agent, retroreflecting agent, negative ion generating agent, etc. Processing may be additionally applied. In particular, raising the surface by buffing or the like is preferable because high surface frictional resistance and grip and moist hand feeling can be obtained.

  Next, through holes are formed in the fabric by punching or the like. At that time, it is possible to perform punching processing regardless of before and after the processing.

  The glove cloth thus obtained has high surface friction resistance, grip, excellent durability, and excellent breathability.

Here, it is preferable that the static friction coefficient be in the range of 0.8 to 3.5 on both the front and back of the fabric. The air permeability is preferably 10 cc / cm ² · sec or more (more preferably 10 to ²⁰⁰ cc / cm ² · sec).

  Next, the textile product of the present invention is any one selected from the group consisting of sports gloves, outdoor gloves, bike gloves, working gloves, precision working gloves, using the above-mentioned glove cloth. It is a textile product. Since this fiber product uses the above-mentioned glove fabric, it has high surface friction resistance, grip, excellent durability, and is excellent in air permeability.

EXAMPLES The present invention will next be described in detail by way of Examples and Comparative Examples, which should not be construed as limiting the invention thereto. In addition, each measurement item in an Example was measured by the following method.
Melt viscosity
After drying, the polymer is set in an orifice set at the luder melting temperature for spinning and held for 5 minutes, then it is extruded under several levels of load, and the shear rate and the melt viscosity at that time are plotted. Connecting the plots gently, create a shear rate-melt viscosity curve and look at the melt viscosity at a shear rate of 1000 s− ¹ .
<Dissolution rate>
Take up the yarn at a spinning speed of 1000 to 2000 m / min with a nozzle of 0.3φ-0.6 L x 24 H for each of sea and island components, and further stretch so that the residual elongation is in the range of 30 to 60%. To produce an 84 dtex / 24 fil multifilament. The weight loss rate was calculated from the dissolution time and the dissolution amount at a bath ratio of 100 at the temperature at which this is to be dissolved in each solvent.
Coefficient of friction
The coefficient of friction was measured by the following method. That is, under the environment of temperature 20 ° C. and humidity 65% RH, as schematically shown in FIG. 1, the silicone rubber (3) is spread on a smooth table, and then the size is the bottom on the rubber A frictional resistance measuring head (2) of 8 cm × 5 cm, height 3 cm, and weight 103 gr (101 cN) was placed. The sample to be measured was attached to the head (2). Next, the coefficient of static friction when the head (2) was pulled at a speed of 100 mm / min was measured by a tensile tester to obtain a coefficient of friction. The measurement was made on the front and back of the fabric in the vertical direction.
<Tear strength retention rate>
Measured according to JIS L1096-2010 8.17D method (Pendulum method).
The tear strength retention (%) was measured by the following method, and 80% or more was taken as a pass.
Retention rate = (fabric with micropores) / (fabric before micropores) x 100
<Permeability>
It measured by JISL1018-19906.34 (Frazil method), and made air permeability 10 cc / cm < ² > * or more as the pass.
<Total area ratio of through holes>
It calculated | required by the following formula.
Total area ratio of through holes (%) = total area of through holes per unit area (10 cm × 10 cm) (cm ² ) / 100 × 100

Example 1
Polyethylene terephthalate as an island component (melt viscosity at 280 ° C 1200 poise, content of matting agent: 0% by weight), sea component 6 mol% of 5-sodium sulfoisophthalic acid and 6% by weight of polyethylene glycol having a number average molecular weight of 4000 A sea-island composite undrawn fiber of (polyester ratio (sea / island) = 230), sea: island = 30: 70, number of islands = (polyurethane viscosity 1750 poise at 280 ° C) copolymerized with Were melt spun at a spinning temperature of 280 ° C. and a spinning speed of 1500 m / min and wound up once.

  The obtained undrawn yarn was subjected to roller drawing at a drawing temperature of 80 ° C. and a drawing ratio of 2.5, and then was heat set at 150 ° C. and wound up. The obtained sea-island composite fiber (fiber for filament yarn A) is 56 dtex / 10 fil, and when the fiber cross section is observed by transmission electron microscope TEM, the shape of the island is round and the diameter of the island is 700 nm. The

  On the other hand, as the filament yarn B, a polyethylene terephthalate filament (total fineness 56 dtex / 12 fil, manufactured by Teijin Limited) was prepared.

Next, using a 40 gauge tricot machine, polyester filament yarn B was placed in L1 and a sea-island composite fiber was placed in L2 to knit a satin knit fabric, as shown in the structure diagram.
Organization chart L1: 12/10 //
L2: 10/45 //

  Next, in order to remove the sea component of the sea-island composite fiber, the knitted fabric was subjected to 30% alkali reduction at 70 ° C. with a 3.5% aqueous NaOH solution. After that, high-pressure dyeing at 130 ° C. for 30 minutes was performed, buffing was performed to raise both sides, and dry heat setting was performed at 170 ° C. as a final set. Next, a glove cloth having through holes was obtained by physically punching holes (punching process, dot pattern of tanning grid) using a pin having a diameter of 1.4 mm and 17,000 pins per square meter.

  In the obtained glove cloth, the filament diameter of the filament yarn A was 700 nm, and the filament diameter of the filament yarn B was 30 μm. The obtained through holes were 2.5% per unit area.

The coefficient of friction was 2.6 on the surface and 2.4 on the back. The tear strength retention was 88% in the vertical direction and 88% in the horizontal direction. The air permeability was 66 cc / cm ² · sec.

  When a golf glove was obtained using the obtained glove cloth and used, it had high surface friction resistance, grip power, fit feeling and moist hand feeling. Moreover, durability was also favorable. The glove cloth was used at a portion of the golf glove in contact with the golf club.

Example 2
The procedure of Example 1 was repeated except that the holes were physically opened using 10000 in diameter and 40,000 pins per square meter. In the obtained glove cloth, the filament diameter of the filament yarn A was 700 nm, and the filament diameter of the filament yarn B was 30 μm. The obtained through holes were 3.2% per unit area. The surface photograph of the obtained glove cloth is shown in FIG.

The coefficient of friction was 2.5 for the surface and 2.3 for the back. The tear strength retention rate was 98% in the vertical direction and 99% in the horizontal direction. The air permeability was 94 cc / cm ² · sec.

  When a golf glove was obtained using the obtained glove cloth and used, it had high surface friction resistance, grip power, fit feeling and moist hand feeling. Moreover, durability was also favorable. The glove cloth was used at a portion of the golf glove in contact with the golf club.

Comparative Example 1
In Example 1, after final setting at 170 ° C., the fine holes were left unopened by pins. In the obtained glove cloth, the coefficient of friction was 2.7 on the surface and 2.4 on the back. The tear strength retention rate was 100% in both the vertical and horizontal directions, but the air permeability was a very low value of 3.3 cc / cm ² · sec.

When a golf glove was obtained using the obtained glove cloth and used, a sufficient grip was obtained as compared with that obtained in Example 1, but the air permeability was 3.3 cc / cm ^2.・ It was not comfortable to wear because it was as low as sec.

  According to the present invention, a glove cloth having high surface friction resistance, grip, excellent durability and excellent breathability and a fiber product using the cloth are provided, and its industrial value is extremely large. It is.

1: Pulley 2: Head (with sample)
3: Silicone rubber

Claims (11)

  A gloved fabric having a woven or knitted fabric, said fabric comprising filament yarns A having a single fiber diameter of 10 to 3000 nm and having through holes.   The glove cloth according to claim 1, wherein the shape of the through hole is any one selected from the group consisting of a circle, a semicircle, a sector, an ellipse, and a tridecadecagon.   The glove cloth according to claim 1, wherein an outer diameter of the through hole is in a range of 0.5 to 15 mm.   The glove cloth according to any one of claims 1 to 3, wherein the total area of the through holes is in the range of 0.5 to 10% with respect to the cloth area.   The glove cloth according to any one of claims 1 to 4, wherein a plurality of the through holes are formed in a pattern.   The glove cloth according to any one of claims 1 to 5, wherein the number of filaments of the filament yarn A is 500 or more.   The glove cloth according to any one of claims 1 to 6, wherein the filament yarn A is a yarn obtained by dissolving and removing a sea component of a sea-island composite fiber comprising a sea component and an island component.   The glove cloth according to any one of claims 1 to 7, wherein the cloth is a knit.   The glove cloth according to any one of claims 1 to 8, wherein at least one of the front surface and the back surface of the cloth is napped.   The glove fabric according to any one of claims 1 to 9, wherein the static friction coefficient is in the range of 0.8 to 3.5 on both the front and back surfaces of the fabric. A golf glove, a baseball glove, a tennis glove, various sport gloves, an outdoor glove, a work glove, a precision work glove, a medical glove, a life, which use the glove cloth according to any one of claims 1 to 10. Any textile product selected from the group consisting of auxiliary gloves.