JP2018177688A - Sunscreen cosmetic - Google Patents
Sunscreen cosmetic Download PDFInfo
- Publication number
- JP2018177688A JP2018177688A JP2017079246A JP2017079246A JP2018177688A JP 2018177688 A JP2018177688 A JP 2018177688A JP 2017079246 A JP2017079246 A JP 2017079246A JP 2017079246 A JP2017079246 A JP 2017079246A JP 2018177688 A JP2018177688 A JP 2018177688A
- Authority
- JP
- Japan
- Prior art keywords
- sunscreen cosmetic
- present
- moisturizing effect
- sunscreen
- skin
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000002537 cosmetic Substances 0.000 title claims abstract description 24
- 230000000475 sunscreen effect Effects 0.000 title claims abstract description 22
- 239000000516 sunscreening agent Substances 0.000 title claims abstract description 21
- 229940043375 1,5-pentanediol Drugs 0.000 claims abstract description 5
- JSOVGYMVTPPEND-UHFFFAOYSA-N 16-methylheptadecyl 2,2-dimethylpropanoate Chemical compound CC(C)CCCCCCCCCCCCCCCOC(=O)C(C)(C)C JSOVGYMVTPPEND-UHFFFAOYSA-N 0.000 claims abstract description 5
- WCVRQHFDJLLWFE-UHFFFAOYSA-N pentane-1,2-diol Chemical compound CCCC(O)CO WCVRQHFDJLLWFE-UHFFFAOYSA-N 0.000 claims abstract description 5
- 239000001651 pyrus cydonia seed extract Substances 0.000 claims abstract description 5
- 239000006097 ultraviolet radiation absorber Substances 0.000 claims abstract description 5
- 239000006096 absorbing agent Substances 0.000 claims description 8
- 229940124543 ultraviolet light absorber Drugs 0.000 claims description 2
- YBGZDTIWKVFICR-JLHYYAGUSA-N Octyl 4-methoxycinnamic acid Chemical group CCCCC(CC)COC(=O)\C=C\C1=CC=C(OC)C=C1 YBGZDTIWKVFICR-JLHYYAGUSA-N 0.000 claims 1
- 229960001679 octinoxate Drugs 0.000 claims 1
- 230000003020 moisturizing effect Effects 0.000 abstract description 13
- 230000000052 comparative effect Effects 0.000 description 6
- 238000011156 evaluation Methods 0.000 description 6
- -1 octyl paramethoxycinnamate Chemical compound 0.000 description 6
- 239000000203 mixture Substances 0.000 description 4
- ALYNCZNDIQEVRV-UHFFFAOYSA-N 4-aminobenzoic acid Chemical compound NC1=CC=C(C(O)=O)C=C1 ALYNCZNDIQEVRV-UHFFFAOYSA-N 0.000 description 3
- 241000196324 Embryophyta Species 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 238000002156 mixing Methods 0.000 description 3
- 229940068065 phytosterols Drugs 0.000 description 3
- 230000001953 sensory effect Effects 0.000 description 3
- OIQXFRANQVWXJF-QBFSEMIESA-N (2z)-2-benzylidene-4,7,7-trimethylbicyclo[2.2.1]heptan-3-one Chemical compound CC1(C)C2CCC1(C)C(=O)\C2=C/C1=CC=CC=C1 OIQXFRANQVWXJF-QBFSEMIESA-N 0.000 description 2
- KXTAOXNYQGASTA-UHFFFAOYSA-N 2-benzylidenepropanedioic acid Chemical class OC(=O)C(C(O)=O)=CC1=CC=CC=C1 KXTAOXNYQGASTA-UHFFFAOYSA-N 0.000 description 2
- 235000010469 Glycine max Nutrition 0.000 description 2
- 244000068988 Glycine max Species 0.000 description 2
- 229930182558 Sterol Natural products 0.000 description 2
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 2
- 230000002411 adverse Effects 0.000 description 2
- BLFLLBZGZJTVJG-UHFFFAOYSA-N benzocaine Chemical compound CCOC(=O)C1=CC=C(N)C=C1 BLFLLBZGZJTVJG-UHFFFAOYSA-N 0.000 description 2
- LGJMUZUPVCAVPU-UHFFFAOYSA-N beta-Sitostanol Natural products C1CC2CC(O)CCC2(C)C2C1C1CCC(C(C)CCC(CC)C(C)C)C1(C)CC2 LGJMUZUPVCAVPU-UHFFFAOYSA-N 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 238000013329 compounding Methods 0.000 description 2
- 239000000839 emulsion Substances 0.000 description 2
- 238000009472 formulation Methods 0.000 description 2
- QUAMTGJKVDWJEQ-UHFFFAOYSA-N octabenzone Chemical compound OC1=CC(OCCCCCCCC)=CC=C1C(=O)C1=CC=CC=C1 QUAMTGJKVDWJEQ-UHFFFAOYSA-N 0.000 description 2
- DXGLGDHPHMLXJC-UHFFFAOYSA-N oxybenzone Chemical compound OC1=CC(OC)=CC=C1C(=O)C1=CC=CC=C1 DXGLGDHPHMLXJC-UHFFFAOYSA-N 0.000 description 2
- 229960001173 oxybenzone Drugs 0.000 description 2
- 238000010561 standard procedure Methods 0.000 description 2
- 150000003432 sterols Chemical class 0.000 description 2
- 235000003702 sterols Nutrition 0.000 description 2
- HEOCBCNFKCOKBX-RELGSGGGSA-N (1s,2e,4r)-4,7,7-trimethyl-2-[(4-methylphenyl)methylidene]bicyclo[2.2.1]heptan-3-one Chemical compound C1=CC(C)=CC=C1\C=C/1C(=O)[C@]2(C)CC[C@H]\1C2(C)C HEOCBCNFKCOKBX-RELGSGGGSA-N 0.000 description 1
- OILXMJHPFNGGTO-UHFFFAOYSA-N (22E)-(24xi)-24-methylcholesta-5,22-dien-3beta-ol Natural products C1C=C2CC(O)CCC2(C)C2C1C1CCC(C(C)C=CC(C)C(C)C)C1(C)CC2 OILXMJHPFNGGTO-UHFFFAOYSA-N 0.000 description 1
- DSSYKIVIOFKYAU-XCBNKYQSSA-N (R)-camphor Chemical compound C1C[C@@]2(C)C(=O)C[C@@H]1C2(C)C DSSYKIVIOFKYAU-XCBNKYQSSA-N 0.000 description 1
- AXTGDCSMTYGJND-UHFFFAOYSA-N 1-dodecylazepan-2-one Chemical compound CCCCCCCCCCCCN1CCCCCC1=O AXTGDCSMTYGJND-UHFFFAOYSA-N 0.000 description 1
- MEZZCSHVIGVWFI-UHFFFAOYSA-N 2,2'-Dihydroxy-4-methoxybenzophenone Chemical compound OC1=CC(OC)=CC=C1C(=O)C1=CC=CC=C1O MEZZCSHVIGVWFI-UHFFFAOYSA-N 0.000 description 1
- KGRVJHAUYBGFFP-UHFFFAOYSA-N 2,2'-Methylenebis(4-methyl-6-tert-butylphenol) Chemical compound CC(C)(C)C1=CC(C)=CC(CC=2C(=C(C=C(C)C=2)C(C)(C)C)O)=C1O KGRVJHAUYBGFFP-UHFFFAOYSA-N 0.000 description 1
- WHQOKFZWSDOTQP-UHFFFAOYSA-N 2,3-dihydroxypropyl 4-aminobenzoate Chemical compound NC1=CC=C(C(=O)OCC(O)CO)C=C1 WHQOKFZWSDOTQP-UHFFFAOYSA-N 0.000 description 1
- ZXDDPOHVAMWLBH-UHFFFAOYSA-N 2,4-Dihydroxybenzophenone Chemical compound OC1=CC(O)=CC=C1C(=O)C1=CC=CC=C1 ZXDDPOHVAMWLBH-UHFFFAOYSA-N 0.000 description 1
- ALBXRBNFWICCSC-UHFFFAOYSA-N 2-(5,5-dimethyl-1,1-diphenylhex-1-en-3-ylidene)propanedioic acid Chemical compound C=1C=CC=CC=1C(=CC(CC(C)(C)C)=C(C(O)=O)C(O)=O)C1=CC=CC=C1 ALBXRBNFWICCSC-UHFFFAOYSA-N 0.000 description 1
- LFNCNUJTQZONPX-UHFFFAOYSA-N 2-[1-[4-amino-2-(2-methylpropyl)phenyl]-3-methylbutylidene]propanedioic acid;1,3,5-triazine Chemical compound C1=NC=NC=N1.CC(C)CC(=C(C(O)=O)C(O)=O)C1=CC=C(N)C=C1CC(C)C LFNCNUJTQZONPX-UHFFFAOYSA-N 0.000 description 1
- JGUMTYWKIBJSTN-UHFFFAOYSA-N 2-ethylhexyl 4-[[4,6-bis[4-(2-ethylhexoxycarbonyl)anilino]-1,3,5-triazin-2-yl]amino]benzoate Chemical compound C1=CC(C(=O)OCC(CC)CCCC)=CC=C1NC1=NC(NC=2C=CC(=CC=2)C(=O)OCC(CC)CCCC)=NC(NC=2C=CC(=CC=2)C(=O)OCC(CC)CCCC)=N1 JGUMTYWKIBJSTN-UHFFFAOYSA-N 0.000 description 1
- LABCWKLLHYSGJX-UHFFFAOYSA-N 2-hydroxybenzoic acid;2-(2-hydroxypropoxy)propan-1-ol Chemical class CC(O)COC(C)CO.OC(=O)C1=CC=CC=C1O LABCWKLLHYSGJX-UHFFFAOYSA-N 0.000 description 1
- DWYHDSLIWMUSOO-UHFFFAOYSA-N 2-phenyl-1h-benzimidazole Chemical class C1=CC=CC=C1C1=NC2=CC=CC=C2N1 DWYHDSLIWMUSOO-UHFFFAOYSA-N 0.000 description 1
- UMZUDTDSLXBKSI-UHFFFAOYSA-N 4-(2-butyl-3,4,5,6-tetramethylphenoxy)-2h-benzotriazole Chemical compound CCCCC1=C(C)C(C)=C(C)C(C)=C1OC1=CC=CC2=C1N=NN2 UMZUDTDSLXBKSI-UHFFFAOYSA-N 0.000 description 1
- KKJKXQYVUVWWJP-JLHYYAGUSA-N 4-[(e)-(4,7,7-trimethyl-3-oxo-2-bicyclo[2.2.1]heptanylidene)methyl]benzenesulfonic acid Chemical compound CC1(C)C2CCC1(C)C(=O)\C2=C\C1=CC=C(S(O)(=O)=O)C=C1 KKJKXQYVUVWWJP-JLHYYAGUSA-N 0.000 description 1
- BVNWQSXXRMNYKH-UHFFFAOYSA-N 4-phenyl-2h-benzotriazole Chemical class C1=CC=CC=C1C1=CC=CC2=C1NN=N2 BVNWQSXXRMNYKH-UHFFFAOYSA-N 0.000 description 1
- OQMZNAMGEHIHNN-UHFFFAOYSA-N 7-Dehydrostigmasterol Natural products C1C(O)CCC2(C)C(CCC3(C(C(C)C=CC(CC)C(C)C)CCC33)C)C3=CC=C21 OQMZNAMGEHIHNN-UHFFFAOYSA-N 0.000 description 1
- 235000011293 Brassica napus Nutrition 0.000 description 1
- 240000002791 Brassica napus Species 0.000 description 1
- LMXBHYVZOVCSHS-UHFFFAOYSA-N COC1(C(NC(N1)=O)=CC1=CC=CC=C1)OC Chemical compound COC1(C(NC(N1)=O)=CC1=CC=CC=C1)OC LMXBHYVZOVCSHS-UHFFFAOYSA-N 0.000 description 1
- SGNBVLSWZMBQTH-FGAXOLDCSA-N Campesterol Natural products O[C@@H]1CC=2[C@@](C)([C@@H]3[C@H]([C@H]4[C@@](C)([C@H]([C@H](CC[C@H](C(C)C)C)C)CC4)CC3)CC=2)CC1 SGNBVLSWZMBQTH-FGAXOLDCSA-N 0.000 description 1
- 241000723346 Cinnamomum camphora Species 0.000 description 1
- QXNVGIXVLWOKEQ-UHFFFAOYSA-N Disodium Chemical compound [Na][Na] QXNVGIXVLWOKEQ-UHFFFAOYSA-N 0.000 description 1
- BTEISVKTSQLKST-UHFFFAOYSA-N Haliclonasterol Natural products CC(C=CC(C)C(C)(C)C)C1CCC2C3=CC=C4CC(O)CCC4(C)C3CCC12C BTEISVKTSQLKST-UHFFFAOYSA-N 0.000 description 1
- 241000208818 Helianthus Species 0.000 description 1
- 235000003222 Helianthus annuus Nutrition 0.000 description 1
- 235000003145 Hippophae rhamnoides Nutrition 0.000 description 1
- 240000000950 Hippophae rhamnoides Species 0.000 description 1
- 239000004909 Moisturizer Substances 0.000 description 1
- WYWZRNAHINYAEF-UHFFFAOYSA-N Padimate O Chemical compound CCCCC(CC)COC(=O)C1=CC=C(N(C)C)C=C1 WYWZRNAHINYAEF-UHFFFAOYSA-N 0.000 description 1
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 1
- 239000007983 Tris buffer Substances 0.000 description 1
- HZYXFRGVBOPPNZ-UHFFFAOYSA-N UNPD88870 Natural products C1C=C2CC(O)CCC2(C)C2C1C1CCC(C(C)=CCC(CC)C(C)C)C1(C)CC2 HZYXFRGVBOPPNZ-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- UBNYRXMKIIGMKK-RMKNXTFCSA-N amiloxate Chemical compound COC1=CC=C(\C=C\C(=O)OCCC(C)C)C=C1 UBNYRXMKIIGMKK-RMKNXTFCSA-N 0.000 description 1
- 229960002709 amiloxate Drugs 0.000 description 1
- 125000005427 anthranyl group Chemical group 0.000 description 1
- 239000003242 anti bacterial agent Substances 0.000 description 1
- 239000002260 anti-inflammatory agent Substances 0.000 description 1
- 229940121363 anti-inflammatory agent Drugs 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 229940111759 benzophenone-2 Drugs 0.000 description 1
- 229940079894 benzophenone-9 Drugs 0.000 description 1
- 150000008366 benzophenones Chemical class 0.000 description 1
- 229940076810 beta sitosterol Drugs 0.000 description 1
- NJKOMDUNNDKEAI-UHFFFAOYSA-N beta-sitosterol Natural products CCC(CCC(C)C1CCC2(C)C3CC=C4CC(O)CCC4C3CCC12C)C(C)C NJKOMDUNNDKEAI-UHFFFAOYSA-N 0.000 description 1
- WXNRYSGJLQFHBR-UHFFFAOYSA-N bis(2,4-dihydroxyphenyl)methanone Chemical compound OC1=CC(O)=CC=C1C(=O)C1=CC=C(O)C=C1O WXNRYSGJLQFHBR-UHFFFAOYSA-N 0.000 description 1
- SODJJEXAWOSSON-UHFFFAOYSA-N bis(2-hydroxy-4-methoxyphenyl)methanone Chemical compound OC1=CC(OC)=CC=C1C(=O)C1=CC=C(OC)C=C1O SODJJEXAWOSSON-UHFFFAOYSA-N 0.000 description 1
- SGNBVLSWZMBQTH-PODYLUTMSA-N campesterol Chemical compound C1C=C2C[C@@H](O)CC[C@]2(C)[C@@H]2[C@@H]1[C@@H]1CC[C@H]([C@H](C)CC[C@@H](C)C(C)C)[C@@]1(C)CC2 SGNBVLSWZMBQTH-PODYLUTMSA-N 0.000 description 1
- 235000000431 campesterol Nutrition 0.000 description 1
- 229960000846 camphor Drugs 0.000 description 1
- 229930008380 camphor Natural products 0.000 description 1
- MIOPJNTWMNEORI-UHFFFAOYSA-N camphorsulfonic acid Chemical compound C1CC2(CS(O)(=O)=O)C(=O)CC1C2(C)C MIOPJNTWMNEORI-UHFFFAOYSA-N 0.000 description 1
- 150000001851 cinnamic acid derivatives Chemical class 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- FDATWRLUYRHCJE-UHFFFAOYSA-N diethylamino hydroxybenzoyl hexyl benzoate Chemical compound CCCCCCOC(=O)C1=CC=CC=C1C(=O)C1=CC=C(N(CC)CC)C=C1O FDATWRLUYRHCJE-UHFFFAOYSA-N 0.000 description 1
- QDCHWIWENYCPIL-UHFFFAOYSA-L disodium;4-hydroxy-5-(2-hydroxy-4-methoxy-5-sulfonatobenzoyl)-2-methoxybenzenesulfonate Chemical compound [Na+].[Na+].C1=C(S([O-])(=O)=O)C(OC)=CC(O)=C1C(=O)C1=CC(S([O-])(=O)=O)=C(OC)C=C1O QDCHWIWENYCPIL-UHFFFAOYSA-L 0.000 description 1
- HUVYTMDMDZRHBN-UHFFFAOYSA-N drometrizole trisiloxane Chemical compound C[Si](C)(C)O[Si](C)(O[Si](C)(C)C)CC(C)CC1=CC(C)=CC(N2N=C3C=CC=CC3=N2)=C1O HUVYTMDMDZRHBN-UHFFFAOYSA-N 0.000 description 1
- 229960004697 enzacamene Drugs 0.000 description 1
- 150000002462 imidazolines Chemical class 0.000 description 1
- 230000001771 impaired effect Effects 0.000 description 1
- 230000007794 irritation Effects 0.000 description 1
- 239000006210 lotion Substances 0.000 description 1
- SOXAGEOHPCXXIO-DVOMOZLQSA-N menthyl anthranilate Chemical compound CC(C)[C@@H]1CC[C@@H](C)C[C@H]1OC(=O)C1=CC=CC=C1N SOXAGEOHPCXXIO-DVOMOZLQSA-N 0.000 description 1
- 229960002248 meradimate Drugs 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 230000001333 moisturizer Effects 0.000 description 1
- 239000007764 o/w emulsion Substances 0.000 description 1
- CLJDBQVBSMXSTP-UHFFFAOYSA-N octan-3-yl 2-hydroxybenzoate Chemical class CCCCCC(CC)OC(=O)C1=CC=CC=C1O CLJDBQVBSMXSTP-UHFFFAOYSA-N 0.000 description 1
- FMJSMJQBSVNSBF-UHFFFAOYSA-N octocrylene Chemical group C=1C=CC=CC=1C(=C(C#N)C(=O)OCC(CC)CCCC)C1=CC=CC=C1 FMJSMJQBSVNSBF-UHFFFAOYSA-N 0.000 description 1
- 229960000601 octocrylene Drugs 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 235000019198 oils Nutrition 0.000 description 1
- 239000002674 ointment Substances 0.000 description 1
- 239000002304 perfume Substances 0.000 description 1
- 229940083254 peripheral vasodilators imidazoline derivative Drugs 0.000 description 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 1
- 239000003755 preservative agent Substances 0.000 description 1
- XATKDVHSLQMHSY-RMKNXTFCSA-N propan-2-yl (e)-3-(4-methoxyphenyl)prop-2-enoate Chemical compound COC1=CC=C(\C=C\C(=O)OC(C)C)C=C1 XATKDVHSLQMHSY-RMKNXTFCSA-N 0.000 description 1
- 229940058287 salicylic acid derivative anticestodals Drugs 0.000 description 1
- 150000003872 salicylic acid derivatives Chemical class 0.000 description 1
- KZJWDPNRJALLNS-VJSFXXLFSA-N sitosterol Chemical compound C1C=C2C[C@@H](O)CC[C@]2(C)[C@@H]2[C@@H]1[C@@H]1CC[C@H]([C@H](C)CC[C@@H](CC)C(C)C)[C@@]1(C)CC2 KZJWDPNRJALLNS-VJSFXXLFSA-N 0.000 description 1
- 229950005143 sitosterol Drugs 0.000 description 1
- KJCLYACXIWMFCC-UHFFFAOYSA-M sodium;5-benzoyl-4-hydroxy-2-methoxybenzenesulfonate Chemical compound [Na+].C1=C(S([O-])(=O)=O)C(OC)=CC(O)=C1C(=O)C1=CC=CC=C1 KJCLYACXIWMFCC-UHFFFAOYSA-M 0.000 description 1
- HCXVJBMSMIARIN-PHZDYDNGSA-N stigmasterol Chemical compound C1C=C2C[C@@H](O)CC[C@]2(C)[C@@H]2[C@@H]1[C@@H]1CC[C@H]([C@H](C)/C=C/[C@@H](CC)C(C)C)[C@@]1(C)CC2 HCXVJBMSMIARIN-PHZDYDNGSA-N 0.000 description 1
- 235000016831 stigmasterol Nutrition 0.000 description 1
- 229940032091 stigmasterol Drugs 0.000 description 1
- BFDNMXAIBMJLBB-UHFFFAOYSA-N stigmasterol Natural products CCC(C=CC(C)C1CCCC2C3CC=C4CC(O)CCC4(C)C3CCC12C)C(C)C BFDNMXAIBMJLBB-UHFFFAOYSA-N 0.000 description 1
- CXVGEDCSTKKODG-UHFFFAOYSA-N sulisobenzone Chemical compound C1=C(S(O)(=O)=O)C(OC)=CC(O)=C1C(=O)C1=CC=CC=C1 CXVGEDCSTKKODG-UHFFFAOYSA-N 0.000 description 1
- 229960000368 sulisobenzone Drugs 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 239000002562 thickening agent Substances 0.000 description 1
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 1
- 150000003918 triazines Chemical class 0.000 description 1
- 235000015112 vegetable and seed oil Nutrition 0.000 description 1
- 239000008158 vegetable oil Substances 0.000 description 1
- 239000011787 zinc oxide Substances 0.000 description 1
Landscapes
- Cosmetics (AREA)
Abstract
Description
本発明は、肌なじみが良好で、高い保湿効果を発揮する日焼け止め化粧料に関する。 The present invention relates to a sunscreen cosmetic which has a good skin familiarity and exhibits a high moisturizing effect.
従来より、紫外線による皮膚への悪影響を防御するため、種々の紫外線吸収剤を含有させた日焼け止め化粧料が開発されている。しかし、紫外線吸収剤、特に有機紫外線吸収剤は、それ自体が、肌なじみやべたつきといった、使用感上の問題があった。 Conventionally, sunscreen cosmetics containing various ultraviolet light absorbers have been developed in order to prevent the adverse effects of ultraviolet light on the skin. However, UV absorbers, in particular organic UV absorbers, themselves have problems in feeling on use such as skin familiarity and stickiness.
また、フィトステロールは植物から得られるステロール類の総称であり、植物油の脱酸工程で得られるガム質から得られることが知られている。（非特許文献１） Phytosterols are a generic term for sterols obtained from plants, and are known to be obtained from gums obtained in the deacidification process of vegetable oils. (Non-patent document 1)
肌なじみが良好で、高い保湿効果を発揮する、日焼け止め化粧料を提供することを課題とする。 It is an object of the present invention to provide a sunscreen cosmetic which has good skin familiarity and exerts a high moisturizing effect.
本発明の日焼け止め化粧料は、下記の（Ａ）〜（Ｃ）を含有する。
（Ａ）有機紫外線吸収剤
（Ｂ）フィトステロール
（Ｃ）ペンチレングリコール、ネオペンタン酸イソステアリル、クインスシードエキスから選択される１種又は２種以上
The sunscreen cosmetic of the present invention contains the following (A) to (C).
(A) Organic UV absorber (B) Phytosterol (C) pentylene glycol, isostearyl neopentanoate, one or more selected from quince seed extract
本発明の日焼け止め化粧料は、有機紫外線吸収剤を含有するにもかかわらず、肌なじみが良好で、かつ高い保湿効果を発揮する。 Although the sunscreen cosmetic of the present invention contains the organic ultraviolet absorber, it has a good skin familiarity and exhibits a high moisturizing effect.
以下本発明を実施するための形態を説明する。 Hereinafter, modes for carrying out the present invention will be described.
本発明の日焼け止め化粧料は、下記の（Ａ）〜（Ｃ）を必須成分として含有する。
（Ａ）有機紫外線吸収剤
（Ｂ）フィトステロール
（Ｃ）ペンチレングリコール、ネオペンタン酸イソステアリル、クインスシードエキスから選択される１種又は２種以上
The sunscreen cosmetic of the present invention contains the following (A) to (C) as essential components.
(A) Organic UV absorber (B) Phytosterol (C) pentylene glycol, isostearyl neopentanoate, one or more selected from quince seed extract
本発明の日焼け止め化粧料に配合する（Ａ）有機紫外線吸収剤の種類は特に限定されず、公知の有機紫外線吸収剤を制限無く使用できる。このような公知の有機紫外線吸収剤として、例えばパラメトキシ桂皮酸オクチル、メトキシ桂皮酸イソプロピル、メトキシ桂皮酸イソアミル等の桂皮酸誘導体；パラアミノ安息香酸（以下、「ＰＡＢＡ」と略記する）、エチルＰＡＢＡ、エチル−ジヒドロキシプロピルＰＡＢＡ、エチルヘキシル−ジメチルＰＡＢＡ、グリセリルＰＡＢＡ等のＰＡＢＡ誘導体；ホモサラート、エチルヘキシルサリチラート、ジプロピレングリコールサリチラート、ＴＥＡサリチラート等のサリチル酸誘導体；ベンゾフェノン−１、ベンゾフェノン−２、ベンゾフェノン−３またはオキシベンゾン、ベンゾフェノン−４、ベンゾフェノン−５、ベンゾフェノン−６、ベンゾフェノン−８、ベンゾフェノン−９、ベンゾフェノン−１２等のベンゾフェノン誘導体；３−ベンジリデンショウノウ、４−メチルベンジリデンショウノウ、ベンジリデンショウノウスルホン酸、メト硫酸ショウノウベンザルコニウム、テレフタリリデンジショウノウスルホン酸、ポリアクリルアミドメチルベンジリデンショウノウ等のベンジリデンショウノウ誘導体；アニソトリアジン、ジエチヘキシルブタミドトリアゾン、２，４，６−トリス（ジイソブチル−４’−アミノベンザルマロナート）−ｓ−トリアジン、２，４−ビス−〔｛４−（２−エチルヘキシルオキシ）−２−ヒドロキシ｝−フェニル〕−６−（４−メトキシフェニル）−１，３，５−トリアジン、２，４，６−トリス〔４−（２−エチルヘキシルオキシカルボニル）アニリノ〕−１，３，５−トリアジン等のトリアジン誘導体；フェニルジベンゾイミダゾールテトラスルホン酸二ナトリウム等のフェニルベンゾイミダゾール誘導体；ドロメトリゾールトリシロキサン、メチレンビス（ベンゾトリアゾリルテトラメチルブチルフェノール）等のフェニルベンゾトリアゾール誘導体；アントラニル酸メンチル等のアントラニル誘導体；ジメトキシベンジリデンオキソイミダゾリジンプロピオン酸２−エチルヘキシル等のイミダゾリン誘導体；ベンザルマロナート官能基を有するポリオルガノシロキサン等のベンザルマロナート誘導体；１，１−ジカルボキシ（２，２’−ジメチルプロピル）−４，４−ジフェニルブタジエン等の４，４−ジアリールブタジエン誘導体；オクトクリレン、２−〔４−（ジエチルアミノ）−２−ヒドロキシベンゾイル〕安息香酸ヘキシル、４−ｔｅｒｔ−ブチル−４’−メトキシジベンゾイルメタンなどが挙げられる。有機紫外線吸収剤は１種を単独で又は２種以上を組み合わせて使用できる。本発明においては、紫外線吸収能と皮膚への安全性の観点からパラメトキシ桂皮酸オクチルを用いることが最も好ましい。 The type of the organic ultraviolet absorber (A) to be added to the sunscreen cosmetic of the present invention is not particularly limited, and known organic ultraviolet absorbers can be used without limitation. Examples of such known organic UV absorbers include cinnamic acid derivatives such as octyl paramethoxycinnamate, isopropyl methoxycinnamate, and isoamyl methoxycinnamate; paraaminobenzoic acid (hereinafter abbreviated as "PABA"), ethyl PABA, ethyl -PABA derivatives such as dihydroxypropyl PABA, ethylhexyl-dimethyl PABA, glyceryl PABA; homosalates, ethylhexyl salicylates, dipropylene glycol salicylates, salicylic acid derivatives such as TEA salicylates; benzophenone-1, benzophenone-2, benzophenone-3 or Benzophenone derivatives such as oxybenzone, benzophenone-4, benzophenone-5, benzophenone-6, benzophenone-8, benzophenone-9, benzophenone-12; -Benzylidene camphor derivatives such as benzylidene camphor, 4-methylbenzylidene camphor, benzylidene camphor sulfonic acid, camphor benzbenzalkonium methesulfate, terephthalylidene di camphor sulphonic acid, polyacrylamidomethyl benzylidene camphor, etc .; anisotriazine, diethylhexylbutamidotriol Azone, 2,4,6-tris (diisobutyl-4'-aminobenzalmalonate) -s-triazine, 2,4-bis-[{4- (2-ethylhexyloxy) -2-hydroxy} -phenyl] Triazine derivatives such as -6- (4-methoxyphenyl) -1,3,5-triazine, 2,4,6-tris [4- (2-ethylhexyloxycarbonyl) anilino] -1,3,5-triazine; Phenyl dibenzimidazo Phenylbenzimidazole derivatives such as disodium tetratetrasulfonate; phenylbenzotriazole derivatives such as drometrizoletrisiloxane, methylenebis (benzotriazolyltetramethylbutylphenol); anthranyl derivatives such as menthyl anthranilate; dimethoxybenzylidene oxoimidazolidine propion Imidazoline derivatives such as 2-ethylhexyl acid; benzalmalonate derivatives such as polyorganosiloxanes having benzalmalonate functional groups; 1,1-dicarboxy (2,2'-dimethylpropyl) -4,4-diphenylbutadiene Etc .; octocrylene, hexyl 2- [4- (diethylamino) -2-hydroxybenzoyl] benzoate, 4-tert-butyl-4′-me Toxidibenzoylmethane and the like can be mentioned. Organic ultraviolet absorbers can be used singly or in combination of two or more. In the present invention, it is most preferable to use octyl paramethoxycinnamate from the viewpoint of ultraviolet light absorbing ability and safety to the skin.
有機紫外線吸収剤の配合量は１〜２０質量％が好ましい。１質量％未満では充分な日焼け止め効果を得ることができず、２０質量％を超えるとべたつきや、皮膚への一次刺激性が高まるなど、使用感に悪影響を及ぼす場合がある。 As for the compounding quantity of an organic ultraviolet absorber, 1-20 mass% is preferable. If it is less than 1% by mass, a sufficient sunscreen effect can not be obtained, and if it exceeds 20% by mass, the feeling of use may be adversely affected, such as stickiness and an increase in primary irritation to the skin.
本発明の日焼け止め化粧料に配合する（Ｂ）フィトステロールは、植物由来のステロール類の総称であり、β-シトステロール、カンペステロール、スティグマステロール、ブラシカステロール等の混合物であり、その種類は限定されない。かかるフィトステロールの起源植物としては、大豆、ヒマワリ、菜種、シーバックソーン等が挙げられるが、大豆由来のフィトステロールを用いることが一般的である。 The phytosterol (B) to be added to the sunscreen cosmetic of the present invention is a generic term for sterols of plant origin, and is a mixture of β-sitosterol, campesterol, stigmasterol, brashcasterol and the like, and the type thereof is not limited. Examples of plants from which such phytosterols are derived include soybeans, sunflowers, rapeseeds, sea buckthorns, etc. However, it is common to use phytosterols derived from soybeans.
フィトステロールの配合量は０．００２〜１質量％が好ましく、さらには０．００２〜０．１質量％がより好ましい。０．００２質量％未満の配合では肌なじみ改善効果が見込めない場合がある。１質量％を超えて配合するとべたつきの原因となる場合がある。 The blending amount of phytosterol is preferably 0.002 to 1% by mass, and more preferably 0.002 to 0.1% by mass. If the amount is less than 0.002% by mass, there may be cases where the skin familiar improvement effect can not be expected. Blending in excess of 1% by mass may cause stickiness.
本発明の日焼け止め化粧料には（Ｃ）ペンチレングリコール、ネオペンタン酸イソステアリル、クインスシードエキスから選択される１種又は２種以上を配合する。（Ｃ）を配合することにより、本発明の日焼け止め化粧料に高い保湿効果を付与することができる。 The sunscreen cosmetic of the present invention contains (C) one or more selected from pentylene glycol, isostearyl neopentanoate, and quince seed extract. By blending (C), a high moisturizing effect can be imparted to the sunscreen cosmetic of the present invention.
本発明の状日焼け止め化粧料は、上述の成分の他に、通常の化粧料に用いられる任意成分を、本発明の効果を阻害しない程度に配合することができる。具体的には、油剤、界面活性剤、増粘剤、防腐剤、香料、保湿剤、抗酸化剤、抗炎症剤、抗菌剤等を挙げることができる。酸化チタンや酸化亜鉛等の紫外線散乱剤については、配合しない方が好ましい。 In addition to the above-mentioned components, the sunscreen cosmetic of the present invention can be blended with optional components used in ordinary cosmetics to an extent that the effects of the present invention are not impaired. Specifically, oil agents, surfactants, thickeners, preservatives, perfumes, moisturizers, antioxidants, anti-inflammatory agents, antibacterial agents and the like can be mentioned. It is more preferable not to mix | blend about ultraviolet-ray scattering agents, such as a titanium oxide and a zinc oxide.
本発明の日焼け止め化粧料の剤型は、乳化型であることが好ましく、さらに水中油乳化型化粧料であることが好ましい。 The formulation of the sunscreen cosmetic of the present invention is preferably an emulsion type, and more preferably an oil-in-water emulsion cosmetic.
本発明の日焼け止め化粧料は定法により調製することができる。 The sunscreen cosmetic of the present invention can be prepared by a conventional method.
本発明の日焼け止め化粧料は、例えば、ローション剤、乳剤、軟膏の剤型で用いることができる。 The sunscreen cosmetic of the present invention can be used, for example, in the form of lotions, emulsions, and ointments.
以下、実施例により本発明を具体的に説明するが、これにより本発明の範囲が限定されるものではない。なお、配合量は特に断りのない限り質量％である。 EXAMPLES Hereinafter, the present invention will be specifically described by way of examples, but the scope of the present invention is not limited thereby. In addition, a compounding quantity is mass% unless there is particular notice.
まず、本発明の実施例及び比較例の評価方法を示す。 First, the evaluation method of the Example of this invention and a comparative example is shown.
＜肌なじみ評価＞
本発明の日焼け止め化粧料を定法により塗布した後、３名の専門パネルを用いて官能的に評価した。実施例及び比較例の各試料を塗布後の肌なじみについて合議により下記の４段階で評価した。なお、官能評価は実施例、比較例を区別がつかない状態で使用し、絶対評価で評価を行った。以下の官能試験も同様である。
◎：肌なじみが非常に良い
○：肌なじみが良い
△：肌なじみがあまり良くない
×：肌なじみが悪い
<Skin familiar evaluation>
After the sunscreen cosmetic of the present invention was applied by a standard method, it was evaluated using a panel of three specialists. Each sample of the example and the comparative example was evaluated by the following four steps by consultation about the skin familiar after application. In addition, sensory evaluation used an Example and a comparative example in the state which can not be distinguished, and evaluated by absolute evaluation. The following sensory test is also the same.
:: very good skin familiarity ○: good skin familiarity :: poor skin familiarity x: poor skin familiarity
＜保湿効果感評価＞
本発明の日焼け止め化粧料を塗布した後、３名の専門パネルを用いて官能的に評価した。実施例及び比較例の各試料を塗布後の保湿効果感について合議により下記の４段階で評価した。
◎：保湿効果感が非常に良い
○：保湿効果感がよい
△：保湿効果感があまり良くない
×：保湿効果感が悪い
<Moisturizing effect feeling evaluation>
After applying the sunscreen cosmetic of the present invention, the sensory evaluation was performed using three expert panels. Each sample of the example and the comparative example was evaluated by the following four steps by consultation about the moisturizing effect feeling after application.
:: very good moisturizing effect ○: good moisturizing effect △: poorly moisturizing effect ×: poor moisturizing effect
表１に示す処方を用い、実施例１〜４及び比較例１、２を定法により調製した。 Using the formulation shown in Table 1, Examples 1 to 4 and Comparative Examples 1 and 2 were prepared by a standard method.
表１に示した通り、本発明の実施例は肌なじみ、保湿効果感ともに良好な使用感であった。これに対し比較例１、２は、肌なじみ、保湿効果感ともに良好な使用感ではなかった。 As shown in Table 1, in the examples of the present invention, both the skin familiarity and the feeling of moisturizing effect were good in use feeling. On the other hand, Comparative Examples 1 and 2 did not have a good feeling of use on both the skin and the moisturizing effect.
Claims (2)
（Ａ）有機紫外線吸収剤
（Ｂ）フィトステロール
（Ｃ）ペンチレングリコール、ネオペンタン酸イソステアリル、クインスシードエキスから選択される１種又は２種以上 Sunscreen cosmetics containing the following (A)-(C).
(A) Organic UV absorber (B) Phytosterol (C) pentylene glycol, isostearyl neopentanoate, one or more selected from quince seed extract
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