JP2018172701A5 - - Google Patents
Download PDFInfo
- Publication number
- JP2018172701A5 JP2018172701A5 JP2018147996A JP2018147996A JP2018172701A5 JP 2018172701 A5 JP2018172701 A5 JP 2018172701A5 JP 2018147996 A JP2018147996 A JP 2018147996A JP 2018147996 A JP2018147996 A JP 2018147996A JP 2018172701 A5 JP2018172701 A5 JP 2018172701A5
- Authority
- JP
- Japan
- Prior art keywords
- mass
- parts
- silane
- heat
- resistant
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- BLRPTPMANUNPDV-UHFFFAOYSA-N silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 claims description 35
- 229910000077 silane Inorganic materials 0.000 claims description 35
- 229920005989 resin Polymers 0.000 claims description 26
- 239000011347 resin Substances 0.000 claims description 26
- 238000004519 manufacturing process Methods 0.000 claims description 19
- 229920005672 polyolefin resin Polymers 0.000 claims description 17
- 239000006087 Silane Coupling Agent Substances 0.000 claims description 15
- 150000001451 organic peroxides Chemical class 0.000 claims description 14
- 239000011256 inorganic filler Substances 0.000 claims description 12
- 229910003475 inorganic filler Inorganic materials 0.000 claims description 12
- 239000004594 Masterbatch (MB) Substances 0.000 claims description 11
- 239000000203 mixture Substances 0.000 claims description 8
- 238000000354 decomposition reaction Methods 0.000 claims description 7
- 239000003054 catalyst Substances 0.000 claims description 6
- 238000009833 condensation Methods 0.000 claims description 6
- 230000005494 condensation Effects 0.000 claims description 6
- SCPYDCQAZCOKTP-UHFFFAOYSA-N silanol Chemical compound [SiH3]O SCPYDCQAZCOKTP-UHFFFAOYSA-N 0.000 claims description 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 5
- ADCOVFLJGNWWNZ-UHFFFAOYSA-N Antimony trioxide Chemical compound O=[Sb]O[Sb]=O ADCOVFLJGNWWNZ-UHFFFAOYSA-N 0.000 claims description 4
- VTYYLEPIZMXCLO-UHFFFAOYSA-L calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims description 4
- 239000011342 resin composition Substances 0.000 claims description 4
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 4
- WNROFYMDJYEPJX-UHFFFAOYSA-K Aluminium hydroxide Chemical compound [OH-].[OH-].[OH-].[Al+3] WNROFYMDJYEPJX-UHFFFAOYSA-K 0.000 claims description 2
- 229960003563 Calcium Carbonate Drugs 0.000 claims description 2
- VTHJTEIRLNZDEV-UHFFFAOYSA-L Magnesium hydroxide Chemical compound [OH-].[OH-].[Mg+2] VTHJTEIRLNZDEV-UHFFFAOYSA-L 0.000 claims description 2
- 229910000019 calcium carbonate Inorganic materials 0.000 claims description 2
- 239000011248 coating agent Substances 0.000 claims description 2
- 238000000576 coating method Methods 0.000 claims description 2
- 238000004132 cross linking Methods 0.000 claims description 2
- FWDBOZPQNFPOLF-UHFFFAOYSA-N ethenyl(triethoxy)silane Chemical compound CCO[Si](OCC)(OCC)C=C FWDBOZPQNFPOLF-UHFFFAOYSA-N 0.000 claims description 2
- NKSJNEHGWDZZQF-UHFFFAOYSA-N ethenyl(trimethoxy)silane Chemical group CO[Si](OC)(OC)C=C NKSJNEHGWDZZQF-UHFFFAOYSA-N 0.000 claims description 2
- 239000003365 glass fiber Substances 0.000 claims description 2
- 239000000347 magnesium hydroxide Substances 0.000 claims description 2
- 229910001862 magnesium hydroxide Inorganic materials 0.000 claims description 2
- 239000000155 melt Substances 0.000 claims description 2
- 239000000377 silicon dioxide Substances 0.000 claims description 2
- 238000006243 chemical reaction Methods 0.000 claims 2
- 239000003795 chemical substances by application Substances 0.000 description 3
- 230000000052 comparative effect Effects 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- 150000001336 alkenes Chemical class 0.000 description 1
- 238000004898 kneading Methods 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
Description
すなわち、本発明の課題は以下の手段によって達成された。
（１）ポリオレフィン樹脂１００質量部に対し、有機過酸化物０．０１質量部以上０．６質量部以下と、無機フィラー１０質量部以上４００質量部以下と、エチレン性不飽和基を含有する基、及び加水分解性基を含有する基を有するシランカップリング剤６質量部を超えて１５．０質量部以下とを前記有機過酸化物の分解温度以上の温度において溶融混練して、前記シランカップリング剤と前記ポリオレフィン樹脂とをグラフト化反応させることにより、シランマスターバッチを調製する工程（ａ）と、
前記シランマスターバッチとシラノール縮合触媒とを混合して混合物を得る工程（ｂ）と、
前記混合物を成形して成形体を得る工程（ｃ）と、
前記成形体を水と接触させて耐熱性シラン架橋樹脂成形体を得る工程（ｄ）とを有する耐熱性シラン架橋樹脂成形体の製造方法。
（２）前記シランカップリング剤の混合量が、前記ポリオレフィン樹脂１００質量部に対し、７質量部以上１５．０質量部以下である（１）に記載の耐熱性シラン架橋樹脂成形体の製造方法。
（３）前記シランカップリング剤が、ビニルトリメトキシシラン又はビニルトリエトキシシランである（１）又は（２）に記載の耐熱性シラン架橋樹脂成形体の製造方法。
（４）前記無機フィラーが、シリカ、水酸化アルミニウム、水酸化マグネシウム、炭酸カルシウム及び三酸化アンチモンからなる群から選ばれる少なくとも１種である（１）〜（３）のいずれか１項に記載の耐熱性シラン架橋樹脂成形体の製造方法。
（５）前記工程（ａ）の溶融混合が、密閉型のミキサーで行われる（１）〜（４）のいずれか１項に記載の耐熱性シラン架橋樹脂成形体の製造方法。
（６）前記工程（ａ）において、シラノール縮合触媒を実質的に混合しない（１）〜（５）のいずれか１項に記載の耐熱性シラン架橋樹脂成形体の製造方法。
（７）ポリオレフィン樹脂１００質量部に対し、有機過酸化物０．０１質量部以上０．６質量部以下と、無機フィラー１０質量部以上４００質量部以下と、エチレン性不飽和基を含有する基、及び加水分解性基を含有する基を有するシランカップリング剤６質量部を超えて１５．０質量部以下とを前記有機過酸化物の分解温度以上の温度において溶融混練して、前記シランカップリング剤と前記ポリオレフィン樹脂とをグラフト化反応させることにより、シランマスターバッチを調製する工程（ａ）と、
前記シランマスターバッチとシラノール縮合触媒とを混合して混合物を得る工程（ｂ）とを有する耐熱性シラン架橋性樹脂組成物の製造方法。
That is, the subject of this invention was achieved by the following means.
(1) Group containing 0.01 to 0.6 parts by mass of organic peroxide, 10 to 400 parts by mass of inorganic filler, and ethylenically unsaturated group with respect to 100 parts by mass of polyolefin resin And silane coupling agent having a hydrolyzable group-containing group in excess of 6 parts by mass and 15.0 parts by mass or less at a temperature equal to or higher than the decomposition temperature of the organic peroxide , A step (a) of preparing a silane masterbatch by grafting the ring agent and the polyolefin resin ;
Mixing the silane masterbatch and silanol condensation catalyst to obtain a mixture (b);
A step (c) of forming the mixture to obtain a molded body;
A method for producing a heat-resistant silane cross-linked resin molded product, comprising the step (d) of bringing the molded product into contact with water to obtain a heat-resistant silane cross-linked resin molded product.
(2) The manufacturing method of the heat-resistant silane crosslinked resin molding as described in (1) whose mixing amount of the said silane coupling agent is 7 to 15.0 mass parts with respect to 100 mass parts of said polyolefin resins. .
(3) The method for producing a heat-resistant silane crosslinked resin molded article according to (1) or (2), wherein the silane coupling agent is vinyltrimethoxysilane or vinyltriethoxysilane.
(4) The inorganic filler according to any one of (1) to (3), wherein the inorganic filler is at least one selected from the group consisting of silica, aluminum hydroxide, magnesium hydroxide, calcium carbonate, and antimony trioxide. A method for producing a heat-resistant silane cross-linked resin molded article.
(5) The method for producing a heat-resistant silane-crosslinked resin molded article according to any one of (1) to (4), wherein the melt mixing in the step (a) is performed by a closed mixer.
(6) The method for producing a heat-resistant silane-crosslinked resin molded article according to any one of (1) to (5), wherein the silanol condensation catalyst is not substantially mixed in the step (a).
(7) Group containing 0.01 to 0.6 parts by mass of organic peroxide, 10 to 400 parts by mass of inorganic filler, and ethylenically unsaturated group with respect to 100 parts by mass of polyolefin resin And silane coupling agent having a hydrolyzable group-containing group in excess of 6 parts by mass and 15.0 parts by mass or less at a temperature equal to or higher than the decomposition temperature of the organic peroxide , A step (a) of preparing a silane masterbatch by grafting the ring agent and the polyolefin resin ;
A method for producing a heat-resistant silane crosslinkable resin composition comprising the step (b) of mixing the silane master batch and a silanol condensation catalyst to obtain a mixture.
（８）（７）に記載の製造方法により製造されてなる耐熱性シラン架橋性樹脂組成物。
（９）（１）〜（６）のいずれか１項に記載の製造方法により製造されてなる耐熱性シラン架橋樹脂成形体。
（１０）耐熱性シラン架橋樹脂成形体が、シラノール結合を介して前記無機フィラーと架橋してなる前記ポリオレフィン樹脂を含む（９）に記載の耐熱性シラン架橋樹脂成形体。
（１１）（９）又は（１０）に記載の耐熱性シラン架橋樹脂成形体を含む耐熱性製品。
（１２）前記耐熱性シラン架橋樹脂成形体が、電線又は光ファイバケーブルの被覆として設けられている（１１）に記載の耐熱性製品。
（１３）ポリオレフィン樹脂１００質量部に対し、有機過酸化物０．０１質量部以上０．６質量部以下と、無機フィラー１０質量部以上４００質量部以下と、エチレン性不飽和基を含有する基、及び加水分解性基を含有する基を有するシランカップリング剤６質量部を超えて１５．０質量部以下とを前記有機過酸化物の分解温度以上の温度において溶融混練して、前記シランカップリング剤と前記ポリオレフィン樹脂とをグラフト化反応させることにより、得られるシランマスターバッチ。
(8) A heat-resistant silane crosslinkable resin composition produced by the production method according to (7).
(9) A heat-resistant silane crosslinked resin molded article produced by the production method according to any one of (1) to (6).
(10) The heat resistant silane crosslinked resin molded product according to (9), wherein the heat resistant silane crosslinked resin molded product includes the polyolefin resin formed by crosslinking with the inorganic filler through a silanol bond.
(11) A heat resistant product comprising the heat resistant silane crosslinked resin molded article according to (9) or (10).
(12) The heat-resistant product according to (11), wherein the heat-resistant silane-crosslinked resin molded body is provided as a coating for an electric wire or an optical fiber cable.
(13) Group containing 0.01 to 0.6 parts by mass of organic peroxide, 10 to 400 parts by mass of inorganic filler, and ethylenically unsaturated group with respect to 100 parts by mass of polyolefin resin And silane coupling agent having a hydrolyzable group-containing group in excess of 6 parts by mass and 15.0 parts by mass or less at a temperature equal to or higher than the decomposition temperature of the organic peroxide , A silane masterbatch obtained by grafting a ring agent and the polyolefin resin .
実施例１〜１８及び比較例１〜１１は、表１及び表２に示す成分を用いて、それぞれの諸元又は製造条件等を変更して、それぞれ実施した。 Examples 1 to 18 and Comparative Examples 1 to 11 were carried out using the components shown in Tables 1 and 2 while changing the respective specifications or production conditions.
（実施例１〜１４及び比較例１〜１１）
まず、有機過酸化物、無機フィラー及びシランカップリング剤を、表１に示す質量比で、東洋精機製１０Ｌヘンシェルミキサーに投入して、室温（２５℃）で１時間混合して、粉体混合物を得た。
次に、このようにして得られた粉体混合物とポリオレフィン樹脂とを、表１に示す質量比で、日本ロール製２Ｌバンバリーミキサー内に投入し、有機過酸化物（Ｐ）の分解温度以上の温度、具体的には１８０〜１９０℃で約１２分混練り後、材料排出温度１８０〜１９０℃で排出し、シランマスターバッチ（シランＭＢともいう）を得た（工程（ａ））。得られたシランＭＢは、オレフィン樹脂にシランカップリング剤がグラフト反応した少なくとも２種のシラン架橋性樹脂を含有している。
(Examples 1 to 14 and Comparative Examples 1 to 11 )
First, an organic peroxide, an inorganic filler, and a silane coupling agent are put into a 10 L Henschel mixer manufactured by Toyo Seiki at a mass ratio shown in Table 1, and mixed at room temperature (25 ° C.) for 1 hour to obtain a powder mixture. Got.
Next, the powder mixture thus obtained and the polyolefin resin were charged into a 2 L Banbury mixer manufactured by Nippon Roll at a mass ratio shown in Table 1, and the decomposition temperature of the organic peroxide (P) or higher was exceeded. After kneading at a temperature, specifically 180 to 190 ° C. for about 12 minutes, the material was discharged at a material discharge temperature of 180 to 190 ° C. to obtain a silane master batch (also referred to as silane MB) (step (a)). The obtained silane MB contains at least two silane crosslinkable resins obtained by graft-reacting a silane coupling agent to an olefin resin.
Claims (13)
前記シランマスターバッチとシラノール縮合触媒とを混合して混合物を得る工程（ｂ）と、
前記混合物を成形して成形体を得る工程（ｃ）と、
前記成形体を水と接触させて耐熱性シラン架橋樹脂成形体を得る工程（ｄ）とを有する耐熱性シラン架橋樹脂成形体の製造方法。 With respect to 100 parts by mass of polyolefin resin, 0.01 to 0.6 parts by mass of organic peroxide, 10 to 400 parts by mass of inorganic filler , a group containing an ethylenically unsaturated group, and water A silane coupling agent having a group containing a decomposable group is melt-kneaded in excess of 6 parts by mass and 15.0 parts by mass or less at a temperature equal to or higher than the decomposition temperature of the organic peroxide , and the silane coupling agent A step (a) of preparing a silane masterbatch by grafting reaction with the polyolefin resin ;
Mixing the silane masterbatch and silanol condensation catalyst to obtain a mixture (b);
A step (c) of forming the mixture to obtain a molded body;
A method for producing a heat-resistant silane cross-linked resin molded product, comprising the step (d) of bringing the molded product into contact with water to obtain a heat-resistant silane cross-linked resin molded product.
前記シランマスターバッチとシラノール縮合触媒とを混合して混合物を得る工程（ｂ）とを有する耐熱性シラン架橋性樹脂組成物の製造方法。 With respect to 100 parts by mass of polyolefin resin, 0.01 to 0.6 parts by mass of organic peroxide, 10 to 400 parts by mass of inorganic filler , a group containing an ethylenically unsaturated group, and water A silane coupling agent having a group containing a decomposable group is melt-kneaded in excess of 6 parts by mass and 15.0 parts by mass or less at a temperature equal to or higher than the decomposition temperature of the organic peroxide , and the silane coupling agent A step (a) of preparing a silane masterbatch by grafting reaction with the polyolefin resin ;
A method for producing a heat-resistant silane crosslinkable resin composition comprising the step (b) of mixing the silane master batch and a silanol condensation catalyst to obtain a mixture.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2013175676 | 2013-08-27 | ||
| JP2013175676 | 2013-08-27 |
Related Parent Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2015534260A Division JP6523171B2 (en) | 2013-08-27 | 2014-08-27 | Heat resistant silane cross-linked resin molded article and method for producing the same, heat resistant silane cross-linkable resin composition and method for producing the same, silane master batch, and heat resistant product using heat resistant silane cross-linked resin molded article |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2018172701A JP2018172701A (en) | 2018-11-08 |
| JP2018172701A5 true JP2018172701A5 (en) | 2019-02-28 |
| JP6623260B2 JP6623260B2 (en) | 2019-12-18 |
Family
ID=52586605
Family Applications (3)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2015534260A Active JP6523171B2 (en) | 2013-08-27 | 2014-08-27 | Heat resistant silane cross-linked resin molded article and method for producing the same, heat resistant silane cross-linkable resin composition and method for producing the same, silane master batch, and heat resistant product using heat resistant silane cross-linked resin molded article |
| JP2018147997A Active JP6767438B2 (en) | 2013-08-27 | 2018-08-06 | Heat-resistant silane cross-linked resin molded body and its manufacturing method, heat-resistant silane cross-linked resin composition and its manufacturing method, silane masterbatch, and heat-resistant product using heat-resistant silane cross-linked resin molded body |
| JP2018147996A Active JP6623260B2 (en) | 2013-08-27 | 2018-08-06 | Heat-resistant silane cross-linked resin molded body and production method thereof, heat-resistant silane cross-linkable resin composition and production method thereof, silane masterbatch, and heat-resistant product using heat-resistant silane cross-linked resin molded body |
Family Applications Before (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2015534260A Active JP6523171B2 (en) | 2013-08-27 | 2014-08-27 | Heat resistant silane cross-linked resin molded article and method for producing the same, heat resistant silane cross-linkable resin composition and method for producing the same, silane master batch, and heat resistant product using heat resistant silane cross-linked resin molded article |
| JP2018147997A Active JP6767438B2 (en) | 2013-08-27 | 2018-08-06 | Heat-resistant silane cross-linked resin molded body and its manufacturing method, heat-resistant silane cross-linked resin composition and its manufacturing method, silane masterbatch, and heat-resistant product using heat-resistant silane cross-linked resin molded body |
Country Status (3)
| Country | Link |
|---|---|
| JP (3) | JP6523171B2 (en) |
| CN (1) | CN105473654A (en) |
| WO (1) | WO2015030055A1 (en) |
Families Citing this family (17)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2015046478A1 (en) | 2013-09-27 | 2015-04-02 | 古河電気工業株式会社 | Heat-resistant silane cross-linked resin molded article and production method for same, heat-resistant silane cross-linking resin composition and production method for same, silane masterbatch, and heat-resistant product employing heat-resistant silane cross-linked resin molded article |
| KR101462486B1 (en) * | 2014-06-20 | 2014-11-19 | 화인케미칼 주식회사 | Elastic infill for artificial turf |
| JP6858115B2 (en) * | 2015-03-03 | 2021-04-14 | 古河電気工業株式会社 | Method for Producing Silane Crosslinkable Rubber Composition and Silane Crosslinkable Rubber Mold |
| WO2016140252A1 (en) * | 2015-03-03 | 2016-09-09 | 古河電気工業株式会社 | Silane-crosslinkable rubber composition, silane-crosslinked rubber molded body, production method for said composition and said molded body, and silane-crosslinked rubber molded article |
| JP6706870B2 (en) * | 2015-03-03 | 2020-06-10 | 古河電気工業株式会社 | SILANE CROSSLINKABLE RUBBER COMPOSITION, SILANE CROSSLINKED RUBBER MOLDED BODY, PROCESS FOR PRODUCING THE SAME, AND SILANE CROSSLINKED RUBBER MOLDED ARTICLE |
| CN105761839B (en) * | 2016-04-29 | 2017-12-08 | 东莞市民兴电缆有限公司 | A kind of high flexibility fireproof cable and preparation method thereof |
| EP3339366A1 (en) | 2016-12-22 | 2018-06-27 | Borealis AG | A crosslinkable polyolefin composition |
| CN107176631A (en) * | 2017-06-07 | 2017-09-19 | 常州市海若纺织品有限公司 | A kind of method that water purification agent is prepared based on waste aluminium plastic material |
| EP3732020B1 (en) * | 2017-12-26 | 2023-05-17 | Braskem America, Inc. | Method of additive manufacturing using high performance polyolefins |
| CN108623883A (en) * | 2018-05-16 | 2018-10-09 | 安徽华美高分子材料科技有限公司 | A kind of refractory polyethylene track CABLE MATERIALS and preparation method thereof |
| JP7305346B2 (en) * | 2018-12-25 | 2023-07-10 | 矢崎エナジーシステム株式会社 | Crosslinking agent masterbatch |
| KR102103953B1 (en) * | 2019-04-09 | 2020-04-23 | 한국신발피혁연구원 | Epdm rubber composition having excellent heat resistant and low compression set |
| JP7203783B2 (en) * | 2020-03-27 | 2023-01-13 | 古河電気工業株式会社 | HEAT-RESISTANT FLAME-RETARDANT CROSS-LINKED FLUORO-RUBBER MOLDED PRODUCT, METHOD FOR MANUFACTURING THE SAME, AND HEAT-RESISTANT PRODUCT |
| EP4286475A4 (en) * | 2021-01-29 | 2024-07-17 | Sumitomo Electric Industries | Resin composition and power cable |
| CN116457899A (en) * | 2021-01-29 | 2023-07-18 | 住友电气工业株式会社 | Resin composition and power cable |
| JP6892185B1 (en) * | 2021-03-17 | 2021-06-23 | 株式会社Ｔｂｍ | Inorganic substance powder-filled resin composition and molded product |
| KR102629770B1 (en) * | 2023-11-10 | 2024-01-26 | 박제호 | Modified asphalt coating material composition for waterproofing bridge surface having high durability and constructing method of bridge surface waterproofing using the same |
Family Cites Families (16)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS53134044A (en) * | 1977-04-28 | 1978-11-22 | Showa Electric Wire & Cable Co Ltd | Production of corsslinked moldings |
| DE2740053A1 (en) * | 1977-09-06 | 1979-05-03 | Klaus Prof Dr Med Gersonde | USE OF ALLOSTERIC EFFECTORS WITH THE LIPID VESICLES WITH AN IRREVERSIBLE INCORPORATION FOR THE IMPROVED O DEEP 2 DISCHARGE OF THE HAEMOGLOBIN IN ERYTHROCYTES |
| JPS6017353B2 (en) * | 1978-03-03 | 1985-05-02 | 古河電気工業株式会社 | Crosslinking method for polyolefin resin |
| JPH02166106A (en) * | 1988-12-19 | 1990-06-26 | Showa Electric Wire & Cable Co Ltd | Production of crosslinked polypropylene molding |
| JPH03233809A (en) * | 1989-12-20 | 1991-10-17 | Hitachi Cable Ltd | Electric wire cable |
| JPH04149238A (en) * | 1990-10-15 | 1992-05-22 | Showa Electric Wire & Cable Co Ltd | Flame retardant silane-crosslinked polyolefin composition |
| JP3105938B2 (en) * | 1991-05-17 | 2000-11-06 | 昭和電線電纜株式会社 | Flame retardant resin composition |
| JPH05198215A (en) * | 1991-09-24 | 1993-08-06 | Hitachi Cable Ltd | Electric-wire/cable |
| JPH0616745A (en) * | 1992-06-29 | 1994-01-25 | Hitachi Cable Ltd | Electric wire-cable |
| JP3486105B2 (en) * | 1998-06-17 | 2004-01-13 | 矢崎総業株式会社 | Flame-retardant crosslinked olefin resin composition and method for producing flame-retardant crosslinked olefin resin |
| DE112008001781B8 (en) * | 2007-07-12 | 2016-09-29 | Autonetworks Technologies, Ltd. | A composition for a flame-retarded silane-crosslinked olefin resin, a process for the production thereof, and its use for coating a conductor, a flame-retarded silane-crosslinked olefin resin, and a process for producing the same |
| JP5151890B2 (en) * | 2008-10-10 | 2013-02-27 | 日立電線株式会社 | Method for producing non-halogen flame retardant thermoplastic composition and non-halogen flame retardant thermoplastic composition |
| JP5640889B2 (en) * | 2011-05-20 | 2014-12-17 | 日立金属株式会社 | Electric wire / cable |
| JP5896626B2 (en) * | 2011-06-08 | 2016-03-30 | リケンテクノス株式会社 | Method for producing electric wire molded body comprising silane crosslinkable flame retardant polyolefin and silanol catalyst resin composition |
| US20130048338A1 (en) * | 2011-08-29 | 2013-02-28 | Hitachi Cable, Ltd. | Coated wire and method of manufacturing the same |
| CN104204048B (en) * | 2012-03-30 | 2018-03-16 | 古河电气工业株式会社 | The manufacture method of heat-resistant resin composition and by the heat-resistant resin composition manufactured by the manufacture method and the products formed of the heat-resistant resin composition is used |
-
2014
- 2014-08-27 WO PCT/JP2014/072443 patent/WO2015030055A1/en active Application Filing
- 2014-08-27 CN CN201480045774.4A patent/CN105473654A/en active Pending
- 2014-08-27 JP JP2015534260A patent/JP6523171B2/en active Active
-
2018
- 2018-08-06 JP JP2018147997A patent/JP6767438B2/en active Active
- 2018-08-06 JP JP2018147996A patent/JP6623260B2/en active Active
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| JP2018172701A5 (en) | ||
| JP6858115B2 (en) | Method for Producing Silane Crosslinkable Rubber Composition and Silane Crosslinkable Rubber Mold | |
| JP6523171B2 (en) | Heat resistant silane cross-linked resin molded article and method for producing the same, heat resistant silane cross-linkable resin composition and method for producing the same, silane master batch, and heat resistant product using heat resistant silane cross-linked resin molded article | |
| JP6523405B2 (en) | Heat resistant silane crosslinkable resin composition and method for producing the same, heat resistant silane crosslinked resin molded article and method for producing the same, and heat resistant product using the heat resistant silane crosslinked resin molded article | |
| JP2017155238A5 (en) | Heat-resistant silane cross-linked resin molded product and method for producing the same, heat-resistant silane cross-linked resin composition and method for producing the same, and heat-resistant product using heat-resistant silane cross-linked resin molded product | |
| JP6858139B2 (en) | Heat-resistant crosslinked fluororubber molded product and its manufacturing method, silane masterbatch, masterbatch mixture and its molded product, and heat-resistant products | |
| JP7060581B2 (en) | Flame-retardant crosslinked resin molded article and its manufacturing method, silane masterbatch, masterbatch mixture and its molded article, and flame-retardant products. | |
| JP7354819B2 (en) | Resin compositions, crosslinked resin compositions, molded bodies, wire covering materials, and wires | |
| WO2016056635A1 (en) | Crosslinked resin molded body, crosslinkable resin composition, manufacturing method therefor, silane masterbatch, and molded article | |
| JP2016121203A (en) | Heat resistant silane crosslinked resin molded body, crosslinkable resin molded body, heat resistant silane crosslinkable resin composition and manufacturing method of them, silane master batch and heat resistant product | |
| JP2020007475A (en) | Heat resistant crosslinked fluorine rubber molded body and manufacturing method therefor, silane master batch, master batch mixture, and heat resistant product | |
| JP2019019327A (en) | Silane coupling agent preliminary mixing filler and filler containing the same | |
| JP6294077B2 (en) | Method for producing exfoliated graphite derivative and method for producing exfoliated graphite / resin composite material | |
| JP2021155590A (en) | Crosslinked fluororubber composition, wiring material using the same, method for manufacturing the same, and catalyst composition for silane crosslinking | |
| JP6738799B2 (en) | Silane-crosslinkable rubber composition and method for producing silane-crosslinked rubber molding | |
| JP6706870B2 (en) | SILANE CROSSLINKABLE RUBBER COMPOSITION, SILANE CROSSLINKED RUBBER MOLDED BODY, PROCESS FOR PRODUCING THE SAME, AND SILANE CROSSLINKED RUBBER MOLDED ARTICLE | |
| WO2020013187A1 (en) | Heat-resistant crosslinked fluororubber molded product and production method thereof, and heat-resistant product | |
| JP6325413B2 (en) | Crosslinked resin molded body, crosslinkable resin composition and production method thereof, silane masterbatch, and molded article | |
| JP2021155592A (en) | Heat-resistant flame-retardant crosslinked fluororubber molding, method for producing the same, and heat-resistant product | |
| JP6688634B2 (en) | SILANE CROSSLINKABLE RUBBER COMPOSITION, SILANE CROSSLINKED RUBBER MOLDED BODY, PROCESS FOR PRODUCING THEM, AND SILANE CROSSLINKED RUBBER MOLDED ARTICLE | |
| JP7426876B2 (en) | Crosslinked fluororubber composition, wiring material using the same, and manufacturing method thereof | |
| JP6598474B2 (en) | Silane-crosslinkable rubber composition, silane-crosslinked rubber molded article, production method thereof, and silane-crosslinked rubber molded article | |
| JP6639937B2 (en) | Method for producing heat-resistant silane-crosslinked thermoplastic elastomer molded article, silane masterbatch, and heat-resistant product | |
| JP6462606B2 (en) | Heat-resistant silane cross-linked resin molded body, heat-resistant silane cross-linkable resin composition and production method thereof, silane masterbatch, and heat-resistant product | |
| WO2020196048A1 (en) | Composite cable |