JP2018148994A - Sanitary product for bedpan - Google Patents
Sanitary product for bedpan Download PDFInfo
- Publication number
- JP2018148994A JP2018148994A JP2017045946A JP2017045946A JP2018148994A JP 2018148994 A JP2018148994 A JP 2018148994A JP 2017045946 A JP2017045946 A JP 2017045946A JP 2017045946 A JP2017045946 A JP 2017045946A JP 2018148994 A JP2018148994 A JP 2018148994A
- Authority
- JP
- Japan
- Prior art keywords
- toilet
- component
- drug
- bowl
- acid
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000008194 pharmaceutical composition Substances 0.000 claims abstract description 39
- 239000005426 pharmaceutical component Substances 0.000 claims abstract description 10
- 229940079593 drug Drugs 0.000 claims description 136
- 239000003814 drug Substances 0.000 claims description 136
- 239000000306 component Substances 0.000 claims description 135
- 239000000203 mixture Substances 0.000 claims description 71
- 239000003205 fragrance Substances 0.000 claims description 27
- 230000000844 anti-bacterial effect Effects 0.000 claims description 14
- 239000000126 substance Substances 0.000 claims description 13
- 239000003795 chemical substances by application Substances 0.000 claims description 12
- 238000004140 cleaning Methods 0.000 claims description 12
- 239000002781 deodorant agent Substances 0.000 claims description 8
- 230000000694 effects Effects 0.000 abstract description 26
- 238000011012 sanitization Methods 0.000 abstract description 10
- 238000007599 discharging Methods 0.000 abstract description 5
- OSVXSBDYLRYLIG-UHFFFAOYSA-N dioxidochlorine(.) Chemical group O=Cl=O OSVXSBDYLRYLIG-UHFFFAOYSA-N 0.000 description 124
- 239000004155 Chlorine dioxide Substances 0.000 description 62
- 235000019398 chlorine dioxide Nutrition 0.000 description 62
- -1 polyoxyethylene Polymers 0.000 description 46
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 37
- 239000000047 product Substances 0.000 description 29
- 239000003921 oil Substances 0.000 description 15
- 235000019198 oils Nutrition 0.000 description 15
- 239000002253 acid Substances 0.000 description 12
- 239000007789 gas Substances 0.000 description 12
- QBWCMBCROVPCKQ-UHFFFAOYSA-N chlorous acid Chemical compound OCl=O QBWCMBCROVPCKQ-UHFFFAOYSA-N 0.000 description 10
- 238000012360 testing method Methods 0.000 description 10
- 239000000499 gel Substances 0.000 description 9
- 241000894006 Bacteria Species 0.000 description 8
- 239000002585 base Substances 0.000 description 8
- 229910001919 chlorite Inorganic materials 0.000 description 8
- 229910052619 chlorite group Inorganic materials 0.000 description 8
- 239000004615 ingredient Substances 0.000 description 8
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 7
- 230000014759 maintenance of location Effects 0.000 description 7
- 238000000034 method Methods 0.000 description 7
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- 230000001877 deodorizing effect Effects 0.000 description 6
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- 230000002378 acidificating effect Effects 0.000 description 5
- 235000014113 dietary fatty acids Nutrition 0.000 description 5
- 229930195729 fatty acid Natural products 0.000 description 5
- 239000000194 fatty acid Substances 0.000 description 5
- 239000000796 flavoring agent Substances 0.000 description 5
- 235000019634 flavors Nutrition 0.000 description 5
- 239000007788 liquid Substances 0.000 description 5
- 239000004745 nonwoven fabric Substances 0.000 description 5
- 239000007921 spray Substances 0.000 description 5
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- ZPVFWPFBNIEHGJ-UHFFFAOYSA-N 2-octanone Chemical compound CCCCCCC(C)=O ZPVFWPFBNIEHGJ-UHFFFAOYSA-N 0.000 description 4
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- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 4
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- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 4
- CRZQGDNQQAALAY-UHFFFAOYSA-N Methyl benzeneacetate Chemical compound COC(=O)CC1=CC=CC=C1 CRZQGDNQQAALAY-UHFFFAOYSA-N 0.000 description 4
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- 230000009471 action Effects 0.000 description 4
- 239000000853 adhesive Substances 0.000 description 4
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- ZOJBYZNEUISWFT-UHFFFAOYSA-N allyl isothiocyanate Chemical compound C=CCN=C=S ZOJBYZNEUISWFT-UHFFFAOYSA-N 0.000 description 4
- 230000003373 anti-fouling effect Effects 0.000 description 4
- 239000008187 granular material Substances 0.000 description 4
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- OSORMYZMWHVFOZ-UHFFFAOYSA-N phenethyl benzoate Chemical compound C=1C=CC=CC=1C(=O)OCCC1=CC=CC=C1 OSORMYZMWHVFOZ-UHFFFAOYSA-N 0.000 description 4
- DTUQWGWMVIHBKE-UHFFFAOYSA-N phenylacetaldehyde Chemical compound O=CCC1=CC=CC=C1 DTUQWGWMVIHBKE-UHFFFAOYSA-N 0.000 description 4
- 239000000843 powder Substances 0.000 description 4
- YGSDEFSMJLZEOE-UHFFFAOYSA-N salicylic acid Chemical compound OC(=O)C1=CC=CC=C1O YGSDEFSMJLZEOE-UHFFFAOYSA-N 0.000 description 4
- 239000007787 solid Substances 0.000 description 4
- 239000004094 surface-active agent Substances 0.000 description 4
- 239000003826 tablet Substances 0.000 description 4
- NPNUFJAVOOONJE-ZIAGYGMSSA-N β-(E)-Caryophyllene Chemical compound C1CC(C)=CCCC(=C)[C@H]2CC(C)(C)[C@@H]21 NPNUFJAVOOONJE-ZIAGYGMSSA-N 0.000 description 4
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 3
- QMMFVYPAHWMCMS-UHFFFAOYSA-N Dimethyl sulfide Chemical compound CSC QMMFVYPAHWMCMS-UHFFFAOYSA-N 0.000 description 3
- 241000402754 Erythranthe moschata Species 0.000 description 3
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 3
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerol Natural products OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 3
- OFOBLEOULBTSOW-UHFFFAOYSA-N Malonic acid Chemical compound OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 3
- MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 description 3
- 150000001241 acetals Chemical class 0.000 description 3
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 3
- 238000010586 diagram Methods 0.000 description 3
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 3
- 238000011156 evaluation Methods 0.000 description 3
- 230000002550 fecal effect Effects 0.000 description 3
- 210000003608 fece Anatomy 0.000 description 3
- 229910052742 iron Inorganic materials 0.000 description 3
- KQNPFQTWMSNSAP-UHFFFAOYSA-N isobutyric acid Chemical compound CC(C)C(O)=O KQNPFQTWMSNSAP-UHFFFAOYSA-N 0.000 description 3
- 150000002825 nitriles Chemical class 0.000 description 3
- NUJGJRNETVAIRJ-UHFFFAOYSA-N octanal Chemical compound CCCCCCCC=O NUJGJRNETVAIRJ-UHFFFAOYSA-N 0.000 description 3
- 239000002304 perfume Substances 0.000 description 3
- 229920003023 plastic Polymers 0.000 description 3
- 239000004033 plastic Substances 0.000 description 3
- NLKNQRATVPKPDG-UHFFFAOYSA-M potassium iodide Chemical compound [K+].[I-] NLKNQRATVPKPDG-UHFFFAOYSA-M 0.000 description 3
- 230000002265 prevention Effects 0.000 description 3
- 238000005507 spraying Methods 0.000 description 3
- KMPQYAYAQWNLME-UHFFFAOYSA-N undecanal Chemical compound CCCCCCCCCCC=O KMPQYAYAQWNLME-UHFFFAOYSA-N 0.000 description 3
- 238000005406 washing Methods 0.000 description 3
- XMGQYMWWDOXHJM-JTQLQIEISA-N (+)-α-limonene Chemical compound CC(=C)[C@@H]1CCC(C)=CC1 XMGQYMWWDOXHJM-JTQLQIEISA-N 0.000 description 2
- XHXUANMFYXWVNG-ADEWGFFLSA-N (-)-Menthyl acetate Chemical compound CC(C)[C@@H]1CC[C@@H](C)C[C@H]1OC(C)=O XHXUANMFYXWVNG-ADEWGFFLSA-N 0.000 description 2
- GRWFGVWFFZKLTI-IUCAKERBSA-N (-)-α-pinene Chemical compound CC1=CC[C@@H]2C(C)(C)[C@H]1C2 GRWFGVWFFZKLTI-IUCAKERBSA-N 0.000 description 2
- MBDOYVRWFFCFHM-SNAWJCMRSA-N (2E)-hexenal Chemical compound CCC\C=C\C=O MBDOYVRWFFCFHM-SNAWJCMRSA-N 0.000 description 2
- 239000001490 (3R)-3,7-dimethylocta-1,6-dien-3-ol Substances 0.000 description 2
- JSNRRGGBADWTMC-UHFFFAOYSA-N (6E)-7,11-dimethyl-3-methylene-1,6,10-dodecatriene Chemical compound CC(C)=CCCC(C)=CCCC(=C)C=C JSNRRGGBADWTMC-UHFFFAOYSA-N 0.000 description 2
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- YRIZYWQGELRKNT-UHFFFAOYSA-N 1,3,5-trichloro-1,3,5-triazinane-2,4,6-trione Chemical compound ClN1C(=O)N(Cl)C(=O)N(Cl)C1=O YRIZYWQGELRKNT-UHFFFAOYSA-N 0.000 description 2
- HNAGHMKIPMKKBB-UHFFFAOYSA-N 1-benzylpyrrolidine-3-carboxamide Chemical compound C1C(C(=O)N)CCN1CC1=CC=CC=C1 HNAGHMKIPMKKBB-UHFFFAOYSA-N 0.000 description 2
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- GKGOLPMYJJXRGD-UHFFFAOYSA-N 2-methyl-4-propyl-1,3-oxathiane Chemical compound CCCC1CCOC(C)S1 GKGOLPMYJJXRGD-UHFFFAOYSA-N 0.000 description 2
- JIMGVOCOYZFDKB-UHFFFAOYSA-N 2-phenylethyl 3-methylbutanoate Chemical compound CC(C)CC(=O)OCCC1=CC=CC=C1 JIMGVOCOYZFDKB-UHFFFAOYSA-N 0.000 description 2
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- ZJPKYCLAROITRY-UHFFFAOYSA-N 3-(1-ethoxyethoxy)-3,7-dimethylocta-1,6-diene Chemical compound CCOC(C)OC(C)(C=C)CCC=C(C)C ZJPKYCLAROITRY-UHFFFAOYSA-N 0.000 description 2
- NOTCZLKDULMKBR-UHFFFAOYSA-N 3-Methoxy-5-methylphenol Chemical compound COC1=CC(C)=CC(O)=C1 NOTCZLKDULMKBR-UHFFFAOYSA-N 0.000 description 2
- XPCTZQVDEJYUGT-UHFFFAOYSA-N 3-hydroxy-2-methyl-4-pyrone Chemical compound CC=1OC=CC(=O)C=1O XPCTZQVDEJYUGT-UHFFFAOYSA-N 0.000 description 2
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Landscapes
- Toilet Supplies (AREA)
- Bidet-Like Cleaning Device And Other Flush Toilet Accessories (AREA)
Abstract
Description
本発明は、開閉可能な便蓋を有する便器に使用される便器用衛生製品に関する。より具体的には、本発明は、便蓋のボウル部側に設置され、薬剤成分をボウル部側に放出させることにより、便器のボウル部を衛生的な状態にすることができる便器用衛生製品に関する。 The present invention relates to a toilet sanitary product used in a toilet having an openable / closable toilet lid. More specifically, the present invention relates to a sanitary product for toilet bowl that is placed on the bowl portion side of the toilet lid and can release the drug component to the bowl portion side, thereby making the bowl portion of the toilet bowl hygienic. About.
家庭や商業施設等において、トイレを衛生的な状態に保つことは、居住者や使用者等の健康維持はもちろん、快適で気分よく生活する上で重要である。 Keeping toilets in a hygienic state in homes and commercial facilities is important not only for maintaining the health of residents and users, but also for living comfortably and comfortably.
トイレを衛生的な状態にする製品(便器用衛生製品)の一つとして、便器用の洗浄剤が知られている。便器用の洗浄剤の中でも、擦り洗い等の手間を減らして簡便に洗浄を行えるものとして、フラッシュ水に希釈して使用されるタイプの便器用洗浄剤が知られている。このような便器用洗浄剤は、便器の手洗い部、貯水タンク、リム部、ボウル部等に設置され、フラッシュ水に便器用洗浄剤を希釈させて便器のボウル部に流水させることによりボウル部を洗浄できるようになっている。しかしながら、フラッシュ水に希釈して使用されるタイプの便器用洗浄剤では、便器のボウル部においてフラッシュ水が通過する部分でしか洗浄作用が発揮できず、フラッシュ水が通過しない部分では洗浄作用を期待できないという点で改善が求められている。 2. Description of the Related Art Toilet bowl cleaners are known as one of the products that make toilets hygienic (sanitary products for toilet bowls). Among toilet bowl cleaners, toilet bowl cleaners of the type that are used after being diluted in flush water are known as those that can be easily washed by reducing the amount of labor such as rubbing. Such toilet cleaner is installed in the hand-washing part, water storage tank, rim part, bowl part, etc. of the toilet bowl, and the bowl part is prepared by diluting the toilet cleaner in flush water and flowing it into the bowl part of the toilet bowl. It can be cleaned. However, toilet cleaners of the type that are used after being diluted in flush water can only exert a cleaning action in the portion where flush water passes in the bowl part of the toilet bowl, and expect a washing action in a portion where flush water does not pass. Improvement is required in that it cannot be done.
また、便器用衛生製品の一つとして、便器用の芳香・消臭剤も知られている。このような芳香・消臭剤は、通常はトイレ内に設置して使用され、トイレの空間内の空気を快適にする効果を奏するようになっている。しかしながら、このような便器用の芳香・消臭剤は、トイレの空間に芳香や消臭効果を付与できるようにトイレ内に設置して使用されるため、トイレの主要な悪臭発生源である便器のボウル部に対して直接的に適用芳香・消臭作用を示すことができず、効果が限定的であった。また、従来、フラッシュ水に希釈して使用される便器用洗浄剤に香料や消臭成分を配合し、フラッシュ水で希釈して、便器のボウル部に対して直接的に芳香・消臭作用を発揮できるものも知られている。しかしながら、前述の通り、フラッシュ水で希釈して使用する態様では、ボウル部においてフラッシュ水が通過しない部分では、所期の効果が付与されず、限定的な効果しか期待できない。 In addition, aroma and deodorant for toilets is also known as one of sanitary products for toilets. Such a fragrance / deodorant is usually installed and used in a toilet, and has the effect of making the air in the toilet space comfortable. However, such toilet fragrances and deodorizers are used in toilets so that they can give fragrances and deodorizing effects to the toilet space. The applied fragrance / deodorant action could not be shown directly on the bowl part of the bowl, and the effect was limited. In addition, fragrances and deodorant ingredients have been blended in toilet bowl cleaners that have been diluted in flush water, and diluted with flush water to directly aroma and deodorize the toilet bowl. What can be demonstrated is also known. However, as described above, in the embodiment in which the flash water is diluted and used, the desired effect is not imparted in the portion where the flush water does not pass in the bowl portion, and only a limited effect can be expected.
このように、従来の便器用衛生製品では、便器のボウル部に対する衛生化の点では、効果が限定的であり、便器のボウル部を衛生的な状態にする効果が高い製品の開発が望まれている。 As described above, the conventional toilet sanitary product has a limited effect in terms of sanitization of the bowl part of the toilet bowl, and development of a product having a high effect of making the bowl part of the toilet bowl hygienic is desired. ing.
本発明の目的は、便器のボウル部を衛生的な状態にする効果に優れた便器用衛生製品を提供することである。 The objective of this invention is providing the sanitary product for toilet bowl excellent in the effect which makes the bowl part of a toilet bowl hygienic.
本発明者等は、前記課題を解決すべく鋭意検討を行ったところ、従来の便器用衛生製品とは使用態様が全く異なるものを採用することによって、前記課題を解決できることを見出した。具体的には、本発明者等は、便器の便蓋のボウル部側に、便器のボウル部の衛生化に有効な薬剤成分を放出させる薬剤組成物を設置し、当該便蓋を閉めた状態にすると、当該薬剤組成物から放出された薬剤成分が便器のボウル部に行き渡り、ボウル部を効果的に衛生化できることを見出した。更に、本発明者等は、薬剤成分として揮散性薬剤を使用することによって、薬剤組成物から薬剤成分をガス状で放出することができ、便器のボウル部の表面全面、リム部(裏面部を含む)、及びリム部の内部(通水部)にまで薬剤成分が行き渡り、より一層効果的に便器を衛生的な状態にできることを見出した。本発明は、これらの知見に基づいて更に検討を重ねることにより完成したものである。 As a result of intensive studies to solve the above-mentioned problems, the present inventors have found that the above-mentioned problems can be solved by adopting a product that is completely different from a conventional toilet sanitary product. Specifically, the present inventors installed a drug composition that releases a drug component effective for sanitizing the bowl part of the toilet bowl on the toilet bowl bowl side, and closed the toilet lid. As a result, it was found that the drug component released from the drug composition spreads over the bowl part of the toilet bowl and the bowl part can be effectively sanitized. Furthermore, the present inventors can release the drug component from the drug composition in the form of gas by using a volatile drug as the drug component, and the entire surface of the bowl portion of the toilet bowl, the rim portion (the back surface portion). It was found that the drug component spreads to the inside of the rim part (water passage part) and can make the toilet bowl more hygienic. The present invention has been completed by further studies based on these findings.
即ち、本発明は、下記に掲げる態様の発明を提供する。
項1. 開閉可能な便蓋を有する便器に使用される便器用衛生製品であって、
薬剤成分を放出させる薬剤組成物を含み、
前記便蓋のボウル部側に設置される、便器用衛生製品。
項2. 前記薬剤成分が、洗浄成分、抗菌成分、香料成分、及び消臭成分よりなる群から選択される少なくとも1種である、項1に記載の便器用衛生製品。
項3. 前記薬剤成分が、揮散性薬剤成分である、項1又は2に記載の便器用衛生製品。
項4. 前記薬剤組成物が、薬剤成分、及び/又は薬剤成分の発生源を含有する、項1〜3のいずれかに記載の便器用衛生製品。
項5. 前記薬剤組成物が、当該薬剤組成物を収容する収容部と、当該薬剤組成物から薬剤成分を容器外に放出するための放出部を有する容器に収容されている、項1〜4のいずれかに記載の便器用衛生製品。
That is, this invention provides the invention of the aspect hung up below.
Item 1. A sanitary product for a toilet used in a toilet having an openable / closable toilet lid,
Including a pharmaceutical composition that releases the pharmaceutical component;
A toilet sanitary product installed on the bowl side of the toilet lid.
Item 2. Item 2. The toilet sanitary product according to Item 1, wherein the drug component is at least one selected from the group consisting of a cleaning component, an antibacterial component, a fragrance component, and a deodorant component.
Item 3. Item 3. The sanitary product for toilet according to Item 1 or 2, wherein the drug component is a volatile drug component.
Item 4. Item 4. The toilet sanitary product according to any one of Items 1 to 3, wherein the drug composition contains a drug component and / or a source of the drug component.
Item 5. Any one of Items 1 to 4, wherein the drug composition is stored in a container having a storage part for storing the drug composition and a release part for releasing a drug component from the drug composition to the outside of the container. Sanitary product for toilet bowl as described in
本発明の便器用衛生製品によれば、便器のボウル部を衛生化する薬剤成分を便器のボウル部に行き渡らせることができるので、便器を衛生的な状態にすることができる。特に、薬剤成分として揮散性薬剤を使用した場合には、便器のボウル部の表面全面、リム部(裏面部を含む)、及びリム部の内部(通水部)にまで薬剤成分を行き渡らせることができるので、より一層効果的に便器を衛生的な状態にすることが可能になる。 According to the toilet sanitary product of the present invention, since the chemical component for sanitizing the bowl portion of the toilet bowl can be distributed to the bowl portion of the toilet bowl, the toilet bowl can be put in a sanitary state. In particular, when a volatile drug is used as the drug component, the drug component should be distributed to the entire surface of the bowl part of the toilet bowl, the rim part (including the back surface part), and the inside of the rim part (water passing part). Therefore, the toilet can be put into a sanitary state even more effectively.
本発明の便器用衛生製品は、開閉可能な便蓋を有する便器に使用される便器用衛生製品であって、薬剤成分を放出させる薬剤組成物を含み、前記便蓋のボウル部側に設置されることを特徴とする。以下、本発明の便器用衛生製品について詳述する。 The sanitary product for toilet of the present invention is a sanitary product for toilet used in a toilet having an openable / closable toilet lid, which includes a pharmaceutical composition that releases a drug component, and is installed on the bowl side of the toilet lid. It is characterized by that. The toilet sanitary product of the present invention will be described in detail below.
・薬剤組成物
本発明の便器用衛生製品では、便器のボウル部を衛生化するために、薬剤成分を放出させる薬剤組成物が含まれる。
-Pharmaceutical composition In the sanitary product for toilet bowl of this invention, in order to sanitize the bowl part of a toilet bowl, the pharmaceutical composition which discharge | releases a pharmaceutical component is contained.
[薬剤成分]
本発明において、「薬剤成分」とは、便器のボウル部を衛生化できる成分であり、具体的には、洗浄成分、抗菌成分、香料成分、消臭成分等が挙げられる。ここで、抗菌成分とは、除菌効果、静菌効果、殺菌効果、抗カビ効果等を含んだ、細菌又は真菌の増殖を抑制又は減少させる成分全てを指す。
[Drug components]
In the present invention, the “pharmaceutical component” is a component that can sanitize the bowl portion of the toilet bowl, and specifically includes a cleaning component, an antibacterial component, a fragrance component, a deodorizing component, and the like. Here, the antibacterial component refers to all components that suppress or reduce the growth of bacteria or fungi, including a bactericidal effect, a bacteriostatic effect, a bactericidal effect, an antifungal effect, and the like.
薬剤成分として使用される洗浄成分の好適な一例として二酸化塩素が挙げられる。二酸化塩素は、抗菌作用を示すことが知られているが、後述する試験例に示すように、糞便や黒ずみ等の汚れを除去する効果(汚れ除去効果)、及び当該汚れの付着を防止する効果(防汚効果)があることが新たに見出されている。 A suitable example of the cleaning component used as the drug component is chlorine dioxide. Chlorine dioxide is known to exhibit antibacterial action, but as shown in the test examples described later, the effect of removing dirt such as feces and darkening (stain removal effect) and the effect of preventing the adhesion of the dirt (Anti-fouling effect) is newly found.
また、薬剤成分として使用される洗浄成分の他の例として、界面活性剤が挙げられる。当該界面活性剤は、非イオン性界面活性剤、カチオン性界面活性剤、アニオン性界面活性剤、及び両性界面活性剤のいずれであってもよい。界面活性剤として、具体的には、ポリオキシエチレン硬化ひまし油、ポリオキシエチレン硬化ひまし油エーテル、ポリオキシエチレンアルキルエーテル、ポリオキシエチレンラウリルエーテル、ポリオキシエチレンオレイルエーテル、ポリオキシエチレン脂肪酸エステル、ポリオキシエチレングリセリルエーテル脂肪酸エステル、アルキルアルカノールアミド、アルキルポリグルコシド、ソルビタン脂肪酸エステル、グリセリン脂肪酸エステル、ポリオキシエチレンソルビタン脂肪酸エステル、ポリオキシエチレンポリオキシプロピレングリコール等の非イオン性界面活性剤;アルキル硫酸塩、ポリオキシエチレンアルキルエーテル硫酸塩、スルホコハク酸塩、N-アシルアミノ酸塩、カルボン酸塩、αオレフィンスルホン酸塩、リン酸エステル等のアニオン性界面活性剤;アルキルアンモニウム塩等のカチオン性界面活性剤;アルキルアミドベタイン、アルキルジメチルアミンオキシド等の両性界面活性剤等が挙げられる。これらの界面活性剤は、1種単独で使用してもよく、2種以上を組み合わせて使用してもよい。 Moreover, surfactant is mentioned as another example of the washing | cleaning component used as a chemical | medical agent component. The surfactant may be any of a nonionic surfactant, a cationic surfactant, an anionic surfactant, and an amphoteric surfactant. Specific examples of surfactants include polyoxyethylene hydrogenated castor oil, polyoxyethylene hydrogenated castor oil ether, polyoxyethylene alkyl ether, polyoxyethylene lauryl ether, polyoxyethylene oleyl ether, polyoxyethylene fatty acid ester, polyoxyethylene Nonionic surfactants such as glyceryl ether fatty acid ester, alkyl alkanolamide, alkyl polyglucoside, sorbitan fatty acid ester, glycerin fatty acid ester, polyoxyethylene sorbitan fatty acid ester, polyoxyethylene polyoxypropylene glycol; alkyl sulfate, polyoxy Ethylene alkyl ether sulfate, sulfosuccinate, N-acyl amino acid salt, carboxylate, α-olefin sulfonate, phosphate ester Anionic surfactants such as: Cationic surfactants such as alkylammonium salts; Amphoteric surfactants such as alkylamidobetaines and alkyldimethylamine oxides. These surfactants may be used individually by 1 type, and may be used in combination of 2 or more type.
薬剤成分として使用される抗菌成分としては、便器のボウル部に対して抗菌作用を発揮できることを限度として特に制限されないが、例えば、二酸化塩素、ジクロロイソシアヌル酸塩、トリクロロイソシアヌル酸塩、オクチルトリメチルアンモニウムクロライド、ジデシルジメチルアンモニウムグルコン酸、クロルヘキシジン、グルコン酸クロルヘキシジン、アリルイソチオシアネート、プロピレングリコールモノメチルエーテル、プロピレングリコールモノプロピルエーテル、ヒノキチオール、安息香酸類、サリチル酸類、ソルビン酸類、パラベン類、塩化クロルヘキシジン、グルコン酸クロルヘキシジン、イソプロピルメチルフェノール、トリクロサン、塩化リゾチーム、ヨウ化カリウム等が挙げられる。これらの抗菌成分は、1種単独で使用してもよく、2種以上を組み合わせて使用してもよい。 The antibacterial component used as the drug component is not particularly limited as long as it can exert an antibacterial action on the bowl part of the toilet bowl. For example, chlorine dioxide, dichloroisocyanurate, trichloroisocyanurate, octyltrimethylammonium chloride , Didecyldimethylammonium gluconic acid, chlorhexidine, chlorhexidine gluconate, allyl isothiocyanate, propylene glycol monomethyl ether, propylene glycol monopropyl ether, hinokitiol, benzoic acids, salicylic acids, sorbic acids, parabens, chlorhexidine chloride, chlorhexidine gluconate, Examples include isopropylmethylphenol, triclosan, lysozyme chloride, potassium iodide and the like. These antibacterial components may be used alone or in combination of two or more.
薬剤成分として使用される香料成分としては、芳香作用を発揮できることを限度として特に制限されず、天然香料、天然香料から分離された単品香料、合成された単品香料、及びこれらの調合香料のいずれであってもよく、従来公知の香料を使用することができる。具体的には、単品香料として、d-リモネン、カリオフィレン、α-ピネン、β-ピネン、ミルセン、ターピノレン、オシメン、γ-ターピネン、α-フェランドレン、p−サイメン、β-カリオフィレン、β-ファルネセン、1,3,5−ウンデカトリエン、ジフェニルメタン等の炭化水素系香料;シス-3-ヘキセノール、リナロール、ゲラニオール、フェニルエチルアルコール、トランス-2-ヘキセノール、シス-3-ヘキセノール、3-オクタノール、1-オクテン-3-オール、2、6-ジメチル-2-ヘプタノール、9-デセノール、4-メチル-3-デセン-5-オール、10-ウンデセノール、トランス-2-シス-6-ノナジエタノール、リナロール、ゲラニオール、ネロール、シトロネロール、ロジノール、ミルセノール、ラバンジュロール、テオラヒドロゲラニオール、テトラヒドロリナロール、ヒドロキシシトロネロール、ジヒドロミルセノール、アロオキシメノール、ターピネオール、α-ターピネオール、ターピネン-4-オール、l-メントール、ボルネオール、イソプレゴール、ノポール、ファルネソール、ネロリドール、セドロール、パチュリアルコール、ベチベロール、2,4-ジメチル-3-シクロヘキセン-1-メタノール、4-イソプロピルシクロヘキサノール、4-イソプロピルシクロヘキサンメタノール、1-(4-イソプロピルシクロヘキシル)-エタノール、2,2-ジメチル-3-(3-メチルフェニル)-プロパノール、p−t-ブチルシクロヘキサノール、o-t-ブチルシクロヘキサノール、アンブリノール、1-(2-t-ブチルシクロヘキシルオキシ)-2-ブタノール、ペンタメチルシクロヘキシルプロパノール、1-(2,2,6-トリメチルシクロヘキシル)-3-ヘキサノール、ベンジルアルコール、フェニルエチルアルコール、フェノキシエチルアルコール、スチラリルアルコール、アニスアルコール、シンナミックアルコール、フェニルプロピルアルコール、ジメチルベンジルカルビノール、ジメチルフェニルエチルカルビノール、フェニルエチルメチルエチルカルビノール、3-メチル-5-フェニルペンタノール、チモール、カルバクロール、オルシノールモノメチルエーテル、オイゲノール、イソオイゲノール、プロペニルグアエトール、サンタロール、イソボルニルシクロヘキサノール、サンダロア、バグダノール、サンダルマイソルコア、ブラマノール、エバノール、ポリサントール、3,7-ジメチル-7-メトキシオクタン-2-オール等のアルコール系香料;ジフェニルオキシド、p-クレジルエチルエーテル、dl-ローズオキシド、(ネロールオキサイド、ミロキサイド、1,8-シネオール、ローズオキサイド、リメトール、メントフラン、リナロールオキサイド、ブチルジメチルジヒドロキシピラン、アセトキシアミルテトラヒドロピラン、セドリルメチルエーテル、メトキシシクロドデカン、1-メチル-1-メトキシシクロドデカン、エトキシメチルシクロドデシルエーテル、トリクロデセニルメチルエーテル、ルボフィックス、セドロキサイド、アンブロキサン、グリサルバ、ボワジリス、アニソール、ジメチルハイドロキノン、パラクレジルメチルエーテル、アセトアニソール、アネトール、ジヒドロアネトール、エストラゴール、ジフェニルオキサイド、メチルオイゲノール、フェニルエチルイソアミルエーテル、β-ナフチルメチルエーテル、β-ナフチルイソブチルエーテル)等のエーテル系香料;ヘキサナール、シトラール、ヘキシルシンナミックアルデヒド、ヘキシルアルデヒド、オクチルアルデヒド、ノニルアルデヒド、デシルアルデヒド、ウンデシルアルデヒド、ドデシルアルデヒド、トリデシルアルデヒド、トリメチルヘキシルアルデヒド、メチルオクチルアセチルアルデヒド、メチルノニルアセトアルデヒド、トランス-2-ヘキセナール、シス-4-ヘプテナール、2,6-ノナジエナール、シス-4-デセナール、トランス-4-デセナール、ウンデシレンアルデヒド、トランス-2-ドデセナール、トリメチルウンデセナール、2,6,10-トリメチル-5,9-ウンデカジエナール、シトロネラール、ヒドロキシシトロネラール、ペリラルデヒド、メトキシジヒドロシトロネラール、シトロネリルオキシアセトアルデヒド、2,4-ジメチル-3-氏クロヘキセニルカルボキシアルデヒド、イソシクロシトラール、センテナール、マイラックアルデヒド、リラール、ベルンアルデヒド、デュピカール、マセアール、ボロナール、セトナール、ベンズアルデヒド、フェニルアセトアルデヒド、フェニルプロピルアルデヒド、シンナミックアルデヒド、α-アミルシンナミックアルデヒド、α-ヘキシルシンナミックアルデヒド、ヒドロトロピックアルデヒド、アニスアルデヒド、p-メチルフェニルアセトアルデヒド、クミンアルデヒド、シクラメンアルデヒド、3-(p-t-ブチルフェニル)-プロピルアルデヒド、p-エチル-2,2-ジメチルヒドロシンナムアルデヒド、2-メチル-3-(p-メトキシフェニル)-プロピルアルデヒド、p-t-ブチル-α-メチルヒドロシンナミックアルデヒド、サリチルアルデヒド、ヘリオトロピン、ヘリオナール、バニリン、エチルバニリン、メチルバニリン等のアルデヒド系香料;オクチルアルデヒドグリコールアセタール、アセトアルデヒドエチルシス-3-ヘキセニルアセタール、シトラールジメチルアセタール、シトラールジエチルアセタール、アセトアルデヒドエチルリナリルアセタール、アセトアルデヒドエチルリナリルアセタール、ヒドロキシシトロネラールジメチルアセタール、フェニルアセトアルデヒドジメチルアセタール、ヒドラトロピックアルデヒドジメチルアセタール、フェニルアセトアルデヒドヒドグリセリルアセタール、アセトアルデヒドエチルフェニルアセタール、アセトアルデヒドフェニルエチルプロピルアセタール、フェニルプロピルアルデヒドプロピレングリコールアセタール、4,4,6-トリメチル-2-ベンジル-1,3-ジオキサン、2,4,6-トリメチル-2-フェニル-1,3-ジオキサン、2-ブチル-4,4,6-トリメチル-1,3-ジオキサン、テトラヒドロインデノ-m-ジオキシン、ジメチルテトラヒドロインデノ-m-ジオキシン、カラナール等のアセタール系香料;エチルブチレート、スチラリルアセテート、o-t-ブチルシクロへキシルアセテート、蟻酸エチル、蟻酸シス-3-ヘキセニル、蟻酸リナリル、蟻酸シトロネリル、蟻酸ゲラニル、蟻酸ベンジル、蟻酸フェニルエチル、酢酸エチル、酢酸ブチル、酢酸イソアミル、シクロペンチリデン酢酸メチル、酢酸ヘキシル、酢酸シス-3-ヘキセニル、酢酸トランス-3-ヘキセニル、酢酸イソノニル、酢酸シトロネリル、酢酸ラバンジュリル、酢酸ゲラニル、酢酸リナリル、酢酸ミルセニル、酢酸ターピニル、酢酸メンチル、酢酸メンタニル、酢酸ノピル、酢酸n-ボルニル、酢酸イソボルニル、酢酸p-t-ブチルシクロヘキシル、酢酸o-t-ブチルシクロヘキシル、酢酸トリシクロデセニル、酢酸 2,4-ジメチル-3-シクロヘキセン-1-メタニル、酢酸ベンジル、酢酸フェニルエチル、酢酸スチラリル、酢酸シンナミル、酢酸アニシル、酢酸パラクレジル、酢酸ヘリオトロピル、アセチルオイゲノール、アセチルイソオイゲノール、酢酸グアイル、酢酸セドリル、酢酸ベチベリル、酢酸デカヒドロβナフチル、プロピオン酸エチル、プロピオン酸イソアミル、プロピオン酸シロネリル、プロピオン酸シロネリル、プロピオン酸ゲラニル、プロピオン酸リナリル、プロピオン酸ターピニル、プロピオン酸ベンジル、プロピオン酸シンアミル、シクロヘキシルプロピオン酸アリル、プロピオン酸トリシクロデセニル、酪酸エチル、2-メチル酪酸エチル、酪酸ブチル、酪酸イソアミル、酪酸ヘキシル、酪酸リナリル、酪酸ゲラニル、酪酸シトロネリル、酪酸ベンジル、イソ酪酸シス-3-ヘキセニル、
イソ酪酸シトロネリル、イソ酪酸ゲラニル、イソ酪酸リナリル、イソ酪酸ベンジル、イソ酪酸フェニルエチル、イソ酪酸フェノキシエチル、イソ酪酸トリシクロデセニル、吉草酸エチル、吉草酸プロピル、イソ吉草酸シトロネリル、イソ吉草酸ゲラニル、イソ吉草酸シンアミル、イソ吉草酸ベンジル、イソ吉草酸フェニルエチル、カプロン酸エチル、カプロン酸アリル、エナント酸エチル、エナント酸アリル、カプリン酸エチル、チグリン酸シトロネリル、オクチンカルンボン酸メチル、2-ペンチロキシグリコール酸アリル、シス-3-ヘキセニルメチルカーボネート、ケト酸エチル、ピルビン酸イソアミル、アセト酸エチル、レブリン酸エチル、安息香酸メチル、安息香酸エチル、安息香酸イソブチル、安息香酸イソアミル、安息香酸ゲラニル、安息香酸リナリル、安息香酸ベンジル、安息香酸フェニルエチル、安息香酸フェニルエチル、ジヒドロキシメチル安息香酸メチル、フェニル酢酸メチル、フェニル酢酸メチル、フェニル酢酸エチル、フェニル酢酸イソブチル、フェニル酢酸イソアミル、フェニル酢酸ゲラニル、フェニル酢酸ベンジル、フェニル酢酸フェニルエチル、フェニル酢酸p-クレジル、桂皮酸メチル、桂皮酸エチル、桂皮酸ベンジル、桂皮酸シンアミル、桂皮酸フェニルエチル、サリチル酸メチル、サリチル酸エチル、サリチル酸イソブチル、サリチル酸イソアミル、サリチル酸ヘキシル、サリチル酸シス-3-ヘキセニル、サリチル酸ベンジル、サリチル酸フェニルエチル、アニス酸メチル、アニス酸エチル、アンスラニル酸メチル、アンスラニル酸エチル、メチルアンスラニル酸メチル、ジャスモン酸メチル、ジヒドロジャスモン酸メチル、メチルフェミルグリシド酸エチル、フェニルグリシド酸エチル、グリコメル、フラクトン、フレイストン、フルテート、ジベスコン、エチル2-メチル-6-ペンチル-4-オキサ-2-シクロヘキセンカーボネート等のエステル系香料;2-オクタノン、δ-ダマスコン、アセトイン、ジアセチル、ミチルアミルケトン、エチルアミルケトン、メチルヘキシルケトン、メチルノニルケトン、メチルヘプテノン、コアボン、カンファー、カルボン、メントン、d-プレゴン、ピペリトン、フェンチョン、ゲラニルアセトン、セドリルメチルケトン、ヌートカトン、イオノン、α-イオノン、β-イオノン、メチルイオノン、α-n-メチルイオノン、β-n-メチルイオノン、α-イソイオノン、β-イソイオノン、アリルイオノン、イロン、α-イロン、β-イロン、γ-イロン、ダマスコン、α-ダマスコン、β-ダマスコン、δ-ダマスコン、ダマセノン、ダイナスコン、α-ダイナスコン、β-ダイナスコン、マルトール、エチルマルトール、2,5-ジメチル-4-ヒドロキシフランノン、シュガーラクトン、p-t-ブチルシクロヘキサノン、アミルシクロペンタノン、ヘプチルシクロペンタノン、ジヒドロジャスモン、シスージャスモン、フロレックス、プリカトン、4-シクロヘキシル-4-メチル-2-ペンタノン、p-メンテン-6-イルプロパノン、2,2,5-トリメチル-5-ペンチルシクロペンタノン、エトキシビニルテトラシクロヘキサノン、ジヒドロペンタメチルインダノン、イソ・イー・スーパー、トリモフィックス、アセトフェノン、p−メチルアセトフェノン、ベンジルアセトン、カローン、ラズベリーケトン、アニシルアセトン、4-(4-ヒドロキシ-3-メトキシフェニル)-2-ブタノン、メチルナフチルケトン、4-フェニル-4-メチル-2-ペンタノン、ベンゾフェノン等のケトン系香料;ゲラニル酸、シトロネリル酸、安息香酸、フェニル酢酸、フェニルプロピオン酸、桂皮酸、2-メチル-2-ペンテノ酸等のカルボン酸系香料;γ-オクタラクトン、γーノナラクトン、γ-デカラクトン、γ-ウンデカラクトン、δ-デカラクトン、クマリン、ジヒドロクマリン、ジャスモラクトン、ジャスミンラクトン等のラクトン系香料;ムスコン、シベトン、シクロペンタデカノン、シクロヘキサデセノン、シクロペンタデカノリド、12-ケトシクロペンタデカノリド、シクロヘキサデカノリド、シクロヘキサデセノリド、12-オキサ-16-ヘキサデカノリド、11-ヘキサ-16-ヘキサデカノリド、10-オキサ-16-ヘキサデカノリド、エチレンブラシレート、エチレンドデカンジオエート、ムスクケトン、ムスクキシロール、ムスクアンブレット、ムスクチベテン、ムスクモスケン、6-アセチルヘキサメチルインダン、4-アセチルジメチル-t-ブチルインダン、5-アセチルテトラメチルイソプロプルインダン、6−アセチルヘキサテトラリン、ヘキサメチルヘキサヒドロシクロペンタンベンゾピラン等のムスク系香料;アセチルピロール、インドール、スカトール、インドレン、2-アセチルピリジン、マリティマ、6-メチルキノリン、6-イソプロピルキノリン、イソブチルキノリン、2-アセチルピラジン、2,3-ジメチルピラジン、2-イソプロピル-3-メトキシピラジン、2-イソブチル-3-メトキシピラジン、2-セカンダリーブチル-3-メトキシピラジン、トリメチルピラジン、5-メチル-3-ヘプタンオキシム等の窒素含有香料;ゲラニルニトリル、シトロネリルニトリル、5-フェニル-2,6-ノナジエンニトリル、シナモンニトリル、クミンニトリル、ドデカンニトリル、トリデセン-2-ニトリルと等のニトリル系香料;ジメチルスルフィド、2-メチル-4-プロピル-1,3-オキサチアン、イソオシアン酸アリル、p-メンタン-8-チオール-3-オン、p-メンテン-8-チオール、p-メンチルチオプロピオン酸メチル等の硫黄含有香料等が例示される。また、天然香料としては、チュベローズ油、ムスクチンキ、カストリウムチンキ、シベットチンキ、アンバーグリスチンキ、ペパーミント油、ペリラ油、プチグレン油、パイン油、ローズ油、ローズマリー油、しょう脳油、芳油、クラリーセージ油、サンダルウッド油、スペアミント油、スパイクラベンダー油、スターアニス油、ラバンジン油、ラベンダー油、レモン油、レモングラス油、ライム油、ネロリ油、オークモス油、オコチア油、パチュリ油、タイム油、トンカ豆チンキ、テレピン油、ワニラ豆チンキ、バジル油、ナツメグ油、シトロネラ油、クローブ油、ボアドローズ油、カナンガ油、カルダモン油、カシア油、シダーウッド油、オレンジ油、マンダリン油、タンジェリン油、アニス油、ベイ油、コリアンダー油、エレミ油、ユーカリ油、フェンネル油、ガルバナム油、ゼラニウム油、ヒバ油、桧油、ジャスミン油、ベチバー油、ベルガモット油、イランイラン油、グレープフルーツ油、ゆず油等が挙げられる。これらの香料成分は、1種単独で使用してもよく、また2種以上を任意に組み合わせて調香して使用することもできる。
The fragrance component used as a pharmaceutical ingredient is not particularly limited as long as it can exhibit an aroma effect, and any of natural fragrance, single fragrance separated from natural fragrance, synthesized single fragrance, and these blended fragrances There may be used, and conventionally known fragrances can be used. Specifically, as a single flavor, d-limonene, caryophyllene, α-pinene, β-pinene, myrcene, terpinolene, osymene, γ-terpinene, α-ferrandrene, p-cymene, β-caryophyllene, β-farnesene, Hydrocarbon fragrances such as 1,3,5-undecatriene and diphenylmethane; cis-3-hexenol, linalool, geraniol, phenylethyl alcohol, trans-2-hexenol, cis-3-hexenol, 3-octanol, 1- Octen-3-ol, 2,6-dimethyl-2-heptanol, 9-decenol, 4-methyl-3-decen-5-ol, 10-undecenol, trans-2-cis-6-nonadiethanol, linalool, geraniol , Nerol, citronellol, rosinol, myrsenol, lavandulol, theorahydrogeraniol, tetrahydrolinalol, Roxycitronellol, dihydromyrsenol, alloximenol, terpineol, α-terpineol, terpinen-4-ol, l-menthol, borneol, isopulegol, nopol, farnesol, nerolidol, cedrol, patchoulial alcohol, vetiverol, 2,4 -Dimethyl-3-cyclohexene-1-methanol, 4-isopropylcyclohexanol, 4-isopropylcyclohexanemethanol, 1- (4-isopropylcyclohexyl) -ethanol, 2,2-dimethyl-3- (3-methylphenyl) -propanol , Pt-butylcyclohexanol, ot-butylcyclohexanol, ambrinol, 1- (2-tert-butylcyclohexyloxy) -2-butanol, pentamethylcyclohexylpropanol, 1- (2,2,6-trimethylcyclohexyl) ) -3-hexanol, Benzyl alcohol, phenylethyl alcohol, phenoxyethyl alcohol, styryl alcohol, anise alcohol, cinnamic alcohol, phenylpropyl alcohol, dimethylbenzylcarbinol, dimethylphenylethylcarbinol, phenylethylmethylethylcarbinol, 3-methyl-5- Phenylpentanol, thymol, carvacrol, orcinol monomethyl ether, eugenol, isoeugenol, propenyl guaetol, santalol, isobornylcyclohexanol, sandaroa, bagdanol, sandalmysol core, bramanol, evanol, polysanthol, 3 , 7-Dimethyl-7-methoxyoctane-2-ol and other alcoholic fragrances; diphenyl oxide, p-cresyl ethyl ether, dl-rose Xoxide, (nerol oxide, miloxide, 1,8-cineole, rose oxide, limethol, mentfuran, linalool oxide, butyldimethyldihydroxypyran, acetoxyamyltetrahydropyran, cedrylmethyl ether, methoxycyclododecane, 1-methyl-1 -Methoxycyclododecane, ethoxymethylcyclododecyl ether, triclodecenyl methyl ether, rubofix, cedroxide, ambroxan, glycalva, voiris, anisole, dimethylhydroquinone, paracresyl methyl ether, acetanisole, anethole, dihydroanethole, estra Galle, diphenyl oxide, methyl eugenol, phenyl ethyl isoamyl ether, β-naphthyl methyl ether, β-naphthyl isobutene Ether-based fragrances such as hexyl ether; hexanal, citral, hexylcinnamic aldehyde, hexylaldehyde, octylaldehyde, nonylaldehyde, decylaldehyde, undecylaldehyde, dodecylaldehyde, tridecylaldehyde, trimethylhexylaldehyde, methyloctylacetylaldehyde, methyl Nonylacetaldehyde, trans-2-hexenal, cis-4-heptenal, 2,6-nonadienal, cis-4-decenal, trans-4-decenal, undecylene aldehyde, trans-2-dodecenal, trimethylundecenal, 2,6 , 10-trimethyl-5,9-undecadienal, citronellal, hydroxycitronellal, perialdehyde, methoxydihydrocitronellal, citronellyloxyacetaldehyde, 2,4-dimethyl-3-chlorohexenyl carboxaldehyde, isocyclocitral, centenal, mylacaldehyde, lyral, bernaldehyde, dupicard, macear, boronal, setneral, benzaldehyde, phenylacetaldehyde, phenylpropylaldehyde, cinnamic aldehyde, α-amylcinnamic aldehyde, α-hexylcinnamic aldehyde, hydrotropic aldehyde, anisaldehyde, p-methylphenylacetaldehyde, cuminaldehyde, cyclamenaldehyde, 3- (pt-butylphenyl) -propylaldehyde, p-ethyl-2 , 2-Dimethylhydrocinnamaldehyde, 2-methyl-3- (p-methoxyphenyl) -propylaldehyde, pt-butyl-α-methylhydrocinnamic aldehyde, salicylaldehyde Aldehyde fragrances such as heliotropin, helional, vanillin, ethyl vanillin, methyl vanillin; octyl aldehyde glycol acetal, acetaldehyde ethyl cis-3-hexenyl acetal, citral dimethyl acetal, citral diethyl acetal, acetaldehyde ethyl linalyl acetal, acetaldehyde ethyl linalyl acetal, Hydroxycitronellal dimethyl acetal, phenylacetaldehyde dimethyl acetal, hydrotropic aldehyde dimethyl acetal, phenyl acetaldehyde hydroglyceryl acetal, acetaldehyde ethyl phenyl acetal, acetaldehyde phenylethyl propyl acetal, phenylpropyl aldehyde propylene glycol acetal, 4,4,6-to Limethyl-2-benzyl-1,3-dioxane, 2,4,6-trimethyl-2-phenyl-1,3-dioxane, 2-butyl-4,4,6-trimethyl-1,3-dioxane, tetrahydroindene Non-m-dioxins, dimethyltetrahydroindeno-m-dioxins, acetal fragrances such as caranal; ethyl butyrate, styryl acetate, ot-butylcyclohexyl acetate, ethyl formate, cis-3-hexenyl formate, linalyl formate, Citronellyl formate, geranyl formate, benzyl formate, phenylethyl formate, ethyl acetate, butyl acetate, isoamyl acetate, methyl cyclopentylidene acetate, hexyl acetate, cis-3-hexenyl acetate, trans-3-hexenyl acetate, isononyl acetate, citronellyl acetate , Lavandulyl acetate, geranyl acetate, linalyl acetate, myrcenyl acetate, terpinyl acetate, menthyl acetate, Mentanyl acid, nopyrulacetate, n-bornyl acetate, isobornyl acetate, pt-butylcyclohexyl acetate, ot-butylcyclohexyl acetate, tricyclodecenyl acetate, 2,4-dimethyl-3-cyclohexene-1-methanyl acetate, benzyl acetate , Phenylethyl acetate, styraryl acetate, cinnamyl acetate, anisyl acetate, paracresyl acetate, heliotropyl acetate, acetyl eugenol, acetylisoeugenol, guayl acetate, cedol acetate, vetiberyl acetate, decahydro β-naphthyl acetate, ethyl propionate, isoamyl propionate, propion Sileryl acid, Sileryl propionate, Geranyl propionate, Linalyl propionate, Terpinyl propionate, Benzyl propionate, Cinnamyl propionate, Allyl cyclohexylpropionate, Propione Phosphate tricyclodecenyl, ethyl butyrate, 2-methylbutyrate, butyl butyrate, isoamyl butyrate, butyric acid hexyl butyrate, linalyl butyrate, geranyl butyrate, citronellyl butyrate, benzyl, isobutyric acid cis-3-hexenyl,
Citronellyl isobutyrate, geranyl isobutyrate, linalyl isobutyrate, benzyl isobutyrate, phenylethyl isobutyrate, phenoxyethyl isobutyrate, tricyclodecenyl isobutyrate, ethyl valerate, propyl valerate, citronellyl isovalerate, isovaleric acid Geranyl, cinnamyl isovalerate, benzyl isovalerate, phenylethyl isovalerate, ethyl caproate, allyl caproate, ethyl enanthate, allyl enanthate, ethyl caprate, citronellyl tiglate, methyl octyne carbamate, 2- Allyl pentyloxyglycolate, cis-3-hexenylmethyl carbonate, ethyl ketoate, isoamyl pyruvate, ethyl acetoate, ethyl levulinate, methyl benzoate, ethyl benzoate, isobutyl benzoate, isoamyl benzoate, geranyl benzoate Linalyl benzoate, benzyl benzoate, phenylethyl benzoate, phenylethyl benzoate, methyl dihydroxymethylbenzoate, methyl phenylacetate, methyl phenylacetate, ethyl phenylacetate, isobutyl phenylacetate, isoamyl phenylacetate, geranyl phenylacetate, phenylacetic acid Benzyl, phenylethyl acetate, p-cresyl phenylacetate, methyl cinnamate, ethyl cinnamate, benzyl cinnamate, cinnamic cinnamate, phenylethyl cinnamate, methyl salicylate, ethyl salicylate, isobutyl salicylate, isoamyl salicylate, hexyl salicylate, salicylic acid Cis-3-hexenyl, benzyl salicylate, phenylethyl salicylate, methyl anisate, ethyl anisate, methyl anthranilate, ethyl anthranilate, methylan Methyl ranylate, methyl jasmonate, methyl dihydrojasmonate, ethyl methylfemilglycidate, ethyl phenylglycidate, glycomel, flactone, Freyston, frutate, divescon, ethyl 2-methyl-6-pentyl-4-oxa-2 -Ester flavors such as cyclohexene carbonate; 2-octanone, δ-damascone, acetoin, diacetyl, mitylamyl ketone, ethyl amyl ketone, methyl hexyl ketone, methyl nonyl ketone, methyl heptenone, coabon, camphor, carvone, menthone, d-pregon , Piperitone, fenchon, geranylacetone, cedryl methyl ketone, nootkatone, ionone, α-ionone, β-ionone, methylionone, α-n-methylionone, β-n-methylionone, α-isoionone, β-isoionone , Allyl ionone, iron, α-iron, β-iron, γ-iron, damascon, α-damascon, β-damascon, δ-damascon, damasenone, dynascon, α-dynascon, β-dynascon, maltol, ethyl maltol, 2, 5-dimethyl-4-hydroxyfuranone, sugar lactone, pt-butylcyclohexanone, amylcyclopentanone, heptylcyclopentanone, dihydrojasmon, cis-jasmon, florex, pricatone, 4-cyclohexyl-4-methyl-2-pentanone , P-Menten-6-ylpropanone, 2,2,5-trimethyl-5-pentylcyclopentanone, ethoxyvinyltetracyclohexanone, dihydropentamethylindanone, iso-e super, trimofix, acetophenone, p-methylacetophenone , Benzylacetone , Aromatics such as carone, raspberry ketone, anisylacetone, 4- (4-hydroxy-3-methoxyphenyl) -2-butanone, methyl naphthyl ketone, 4-phenyl-4-methyl-2-pentanone, benzophenone; geranyl Acid, citronellic acid, benzoic acid, phenylacetic acid, phenylpropionic acid, cinnamic acid, 2-methyl-2-pentenoic acid and other carboxylic acid-based fragrances; γ-octalactone, γ-nonalactone, γ-decalactone, γ-undecalactone Lactone fragrances such as δ-decalactone, coumarin, dihydrocoumarin, jasmolactone, jasmine lactone; muscone, sibeton, cyclopentadecanone, cyclohexadecenone, cyclopentadecanolide, 12-ketocyclopentadecanolide, Cyclohexadecanolide, cyclohexadecenolide, 12-oxa-16-hexadecanolide, 11-hexa-16-hexadecanolide, 10-oxa-16-hexadecanolide, ethylene brushate, ethylene dodecanedioate, musk ketone, musk xylol, musk ambrette, musk tivetene, musk mosken, 6-acetylhexamethylindane, 4-acetyldimethyl- Musk flavors such as t-butylindane, 5-acetyltetramethylisopropylpropane, 6-acetylhexatetralin, hexamethylhexahydrocyclopentanebenzopyran; acetylpyrrole, indole, skatole, indolene, 2-acetylpyridine, maritima, 6-methylquinoline, 6-isopropylquinoline, isobutylquinoline, 2-acetylpyrazine, 2,3-dimethylpyrazine, 2-isopropyl-3-methoxypyrazine, 2-isobutyl-3-methoxypyrazine, 2-secondary Nitrogen-containing fragrances such as ru-3-methoxypyrazine, trimethylpyrazine, 5-methyl-3-heptaneoxime; geranyl nitrile, citronellyl nitrile, 5-phenyl-2,6-nonadiene nitrile, cinnamon nitrile, cumin nitrile, dodecane Nitrile perfumes such as nitrile and tridecene-2-nitrile; dimethyl sulfide, 2-methyl-4-propyl-1,3-oxathiane, allyl isocyanocyanate, p-menthan-8-thiol-3-one, p-menthen Sulfur-containing fragrances such as -8-thiol and methyl p-menthylthiopropionate are exemplified. Natural flavors include tuberose oil, mustin tincture, castrium tincture, civet tincture, ambergris tincture, peppermint oil, perilla oil, petitgren oil, pine oil, rose oil, rosemary oil, ginseng oil, fine oil, clary sage Oil, sandalwood oil, spearmint oil, spike lavender oil, star anise oil, lavandin oil, lavender oil, lemon oil, lemongrass oil, lime oil, neroli oil, oak moss oil, okothia oil, patchouli oil, thyme oil, tonka bean Tincture, turpentine oil, vanilla bean tincture, basil oil, nutmeg oil, citronella oil, clove oil, bored rose oil, cananga oil, cardamom oil, cassia oil, cedarwood oil, orange oil, mandarin oil, tangerine oil, anise oil, bay oil , Coriander oil, Elemi oil, Yu Cali oil, fennel oil, galbanum oil, geranium oil, hiba oil, hinoki oil, jasmine oil, vetiver oil, bergamot oil, ylang ylang oil, grapefruit oil, citron oil, and the like. These perfume ingredients may be used alone or in combination with any combination of two or more.
また、薬剤成分として使用される消臭成分としては、便器のボウル部に対して消臭作用を発揮できることを限度として特に制限されないが、例えば、ジクロロイソシアヌル酸塩、トリクロロイソシアヌル酸塩;イネ、松、ヒノキ、笹、柿、茶等の植物の抽出物;脱塩型ベタイン化合物;変性有機酸化合物;アルカノールアミン;二酸化塩素;オゾン;アルデヒド化合物;グリコールエーテル化合物;フィトンチッド系香料;低級脂肪族アルデヒド系香料等が挙げられる。これらの消臭成分は、1種単独で使用してもよく、また2種以上を任意に組み合わせて使用してもよい。 The deodorant component used as the drug component is not particularly limited as long as it can exert a deodorizing action on the bowl part of the toilet bowl. For example, dichloroisocyanurate, trichloroisocyanurate; rice, pine Extracts of plants such as cypress, cypress, persimmon, persimmon and tea; desalted betaine compounds; modified organic acid compounds; alkanolamines; chlorine dioxide; ozone; aldehyde compounds; glycol ether compounds; phytoncide-based fragrances; A fragrance | flavor etc. are mentioned. These deodorant components may be used alone or in any combination of two or more.
これらの薬剤成分は、1種単独で使用してもよく、また2種以上を組み合わせて使用してもよい。 These drug components may be used alone or in combination of two or more.
これらの薬剤成分の中でも、好ましくは、揮散(気化)性薬剤成分が挙げられる。揮散性薬剤成分とは、常温常圧下(25℃、1atm程度)で揮散(気化)する薬剤成分であり、具体的には、25℃における蒸気圧が1×10-7Pa以上である薬剤成分が該当する。揮散性薬剤成分は、便器の便蓋を閉めた状態になっている際に、便器の便蓋とボウル部で形成された空間内にガス状で放出され、ボウル部の表面全面に薬剤成分を行き渡らせることができ、薬剤成分による衛生化効果をより一層有効に付与することが可能になる。 Among these drug components, a volatile (vaporization) drug component is preferable. Volatile drug components are drug components that volatilize (vaporize) at room temperature and normal pressure (25 ° C., about 1 atm). Specifically, the drug component has a vapor pressure of 1 × 10 −7 Pa or more at 25 ° C. Is applicable. When the toilet lid of the toilet bowl is closed, the volatile drug component is released in the form of a gas into the space formed by the toilet lid of the toilet bowl and the bowl portion, and the drug component is applied to the entire surface of the bowl portion. Thus, the sanitization effect of the drug component can be more effectively imparted.
揮散性薬剤成分として、具体的には、二酸化塩素等の揮散性の洗浄成分;香料成分;二酸化塩素、アリルイソチオシアネート等の抗菌成分;二酸化塩素、オゾン等の消臭成分が挙げられる。これらの揮散性薬剤成分は、1種単独で使用してもよく、また2種以上を任意に組み合わせて使用してもよい。これら揮散性薬剤成分の中でも、二酸化塩素は、洗浄、抗菌、及び消臭作用を示し、便器のボウル部の衛生化において卓越した効果を奏するので好適に使用される。 Specific examples of the volatile chemical component include volatile cleaning components such as chlorine dioxide; fragrance components; antibacterial components such as chlorine dioxide and allyl isothiocyanate; and deodorizing components such as chlorine dioxide and ozone. These volatile chemical components may be used alone or in any combination of two or more. Among these volatile drug components, chlorine dioxide is preferably used because it exhibits cleaning, antibacterial, and deodorizing effects, and has an excellent effect in sanitizing the bowl portion of the toilet bowl.
本発明で使用される薬剤組成物は、薬剤成分を放出できる限り、その組成については、特に制限されず、薬剤成分自体を含有している態様(以下、「態様1の薬剤組成物」と表記する)、また、薬剤成分の発生源を含み、薬剤成分を発生できるように設計されている態様(以下、「態様2の薬剤組成物」と表記する)であってもよい。 The drug composition used in the present invention is not particularly limited as long as the drug component can be released, and is an embodiment containing the drug component itself (hereinafter referred to as “the drug composition of embodiment 1”). In addition, an embodiment (hereinafter, referred to as “a pharmaceutical composition of embodiment 2”) that includes a generation source of a pharmaceutical component and is capable of generating the pharmaceutical component may be used.
前記態様1の薬剤組成物における薬剤成分の含有量については、使用する薬剤成分の種類、薬剤組成物の剤型等に応じて適宜設定すればよいが、例えば、0.0001〜30重量%、好ましくは0.001〜20重量%、より好ましくは0.01〜20重量%、更に好ましくは0.1〜10重量%が挙げられる。 The content of the drug component in the drug composition of aspect 1 may be appropriately set according to the type of drug component used, the dosage form of the drug composition, etc., for example, 0.0001 to 30% by weight, Preferably 0.001-20 weight%, More preferably, it is 0.01-20 weight%, More preferably, 0.1-10 weight% is mentioned.
前記態様2の薬剤組成物では、薬剤成分の発生源を含み、薬剤成分を発生できるように構成されていればよく、態様2の薬剤組成物に使用される薬剤成分の種類については、組成物中で生成されることができるものである限り、特に制限されない。 The pharmaceutical composition of aspect 2 only needs to be configured so as to contain a source of generation of the pharmaceutical ingredient and be able to generate the pharmaceutical ingredient. For the types of pharmaceutical ingredients used in the pharmaceutical composition of aspect 2, the composition There is no particular limitation as long as it can be produced therein.
前記態様2の薬剤組成物で使用される薬剤成分の好適な例としては、二酸化塩素が挙げられる。以下、薬剤成分として二酸化塩素を使用する場合の態様2の薬剤組成物を「二酸化塩素発生組成物」と表記し、その組成等について説明する。 A preferred example of the drug component used in the drug composition of aspect 2 is chlorine dioxide. Hereinafter, the chemical composition of Embodiment 2 in the case of using chlorine dioxide as a pharmaceutical ingredient is referred to as “chlorine dioxide generating composition”, and the composition and the like will be described.
(二酸化塩素発生組成物の組成等)
二酸化塩素は、水の存在下で亜塩素酸塩と酸との反応により発生するので、二酸化塩素発生組成物は、二酸化塩素の発生源としては、亜塩素酸塩及び酸を含んでいればよい。
(Composition of chlorine dioxide generating composition)
Since chlorine dioxide is generated by the reaction of chlorite and acid in the presence of water, the chlorine dioxide generating composition only needs to contain chlorite and acid as a source of chlorine dioxide. .
二酸化塩素の発生源の一成分として使用される亜塩素酸塩の種類については、特に制限されないが、例えば、亜塩素酸リチウム、亜塩素酸ナトリウム、亜塩素酸塩カリウム等の塩素酸のアルカリ金属塩;亜塩素酸カルシウム、亜塩素酸マグネシウム、亜塩素酸バリウム等の亜塩素酸のアルカリ土類金属塩等が挙げられる。これらの亜塩素酸塩は、1種単独で使用してもよく、また2種以上を組み合わせて使用してもよい。 The type of chlorite used as a component of the source of chlorine dioxide is not particularly limited. For example, alkali metals of chloric acid such as lithium chlorite, sodium chlorite, and potassium chlorite Salt; alkaline earth metal salts of chlorous acid such as calcium chlorite, magnesium chlorite, and barium chlorite. These chlorites may be used individually by 1 type, and may be used in combination of 2 or more type.
二酸化塩素発生組成物における亜塩素酸塩の含有量については、態様2の薬剤組成物の形状、二酸化塩素を放出させる態様、設置部位等に応じて適宜設定すればよいが、例えば、0.1〜30重量%、好ましくは1〜10重量%が挙げられる。 The content of chlorite in the chlorine dioxide generating composition may be appropriately set according to the shape of the pharmaceutical composition of aspect 2, the aspect of releasing chlorine dioxide, the installation site, etc. -30% by weight, preferably 1-10% by weight.
二酸化塩素の発生源の一成分として使用される酸の種類については、水に溶解すると酸性を示し、水の存在下で亜塩素酸塩から酸化塩素を発生させ得るものであることを限度として特に制限されないが、例えば、リン酸、リン酸二水素カリウム、リン酸二水素ナトリウム、亜硫酸ナトリウム、亜硫酸カリウム、ピロ亜硫酸ナトリウム、ピロ亜硫酸カリウム、酸性へキサメタリン酸ナトリウム、酸性ヘキサメタリン酸カリウム、酸性ピロリン酸ナトリウム、酸性ピロリン酸カリウム、スルファミン酸、ギ酸、酢酸、プロピオン酸、酪酸、吉草酸、シュウ酸、マロン酸、コハク酸、グルタル酸、アジピン酸、ピメリン酸、フマル酸、マレイン酸、フタル酸、イソフタル酸、テレフタル酸、グルタミン酸、アスパラギン酸、グリコール酸、リンゴ酸、酒石酸、クエン酸、乳酸、ヒドロキシアクリル酸、α−オキシ酪酸、グリセリン酸、タルトロン酸、サリチル酸、没食子酸、トロパ酸、アスコルビン酸、グルコン酸等の固体状の酸;塩酸、硫酸等の液体状の酸が挙げられる。これらの酸は、1種単独で使用してもよく、また2種以上を組み合わせて使用してもよい。 The kind of acid used as a component of the chlorine dioxide source is particularly limited to the extent that it is acidic when dissolved in water and can generate chlorine oxide from chlorite in the presence of water. Without limitation, for example, phosphoric acid, potassium dihydrogen phosphate, sodium dihydrogen phosphate, sodium sulfite, potassium sulfite, sodium pyrosulfite, potassium pyrosulfite, acidic sodium hexametaphosphate, acidic potassium hexametaphosphate, acidic sodium pyrophosphate , Acidic potassium pyrophosphate, sulfamic acid, formic acid, acetic acid, propionic acid, butyric acid, valeric acid, oxalic acid, malonic acid, succinic acid, glutaric acid, adipic acid, pimelic acid, fumaric acid, maleic acid, phthalic acid, isophthalic acid , Terephthalic acid, glutamic acid, aspartic acid, glycolic acid, malic acid Solid acids such as tartaric acid, citric acid, lactic acid, hydroxyacrylic acid, α-oxybutyric acid, glyceric acid, tartronic acid, salicylic acid, gallic acid, tropic acid, ascorbic acid, gluconic acid; liquids such as hydrochloric acid and sulfuric acid Examples include acids. These acids may be used individually by 1 type, and may be used in combination of 2 or more type.
二酸化塩素発生組成物における酸の含有量については、二酸化塩素発生組成物の形状、二酸化塩素を放出させる態様、設置部位等に応じて適宜設定すればよいが、亜塩素酸塩の全量と反応するために必要とされる最少量以上であることが望ましく、具体的には、0.01〜15重量%、好ましくは1〜10重量%が挙げられる。 The acid content in the chlorine dioxide generating composition may be appropriately set according to the shape of the chlorine dioxide generating composition, the mode of releasing chlorine dioxide, the installation site, etc., but it reacts with the total amount of chlorite. Therefore, it is desirable that the amount is at least the minimum amount required for the purpose, specifically 0.01 to 15% by weight, preferably 1 to 10% by weight.
二酸化塩素発生組成物において、二酸化塩素の発生源として、前記亜塩素酸塩と酸とを含んでさえいれば、水を配合していなくても、空気中の水蒸気を吸収したり、フラッシュ水に希釈させて使用する態様の場合にはフラッシュ水を利用したりすることにより、亜塩素酸塩と酸とを反応させて二酸化塩素を発生させることができるため、必ずしも水は含まれていなくてもよい。但し、効率的に二酸化塩素を発生させるという観点からは、二酸化塩素発生組成物には水が含まれていることが望ましい。 In the chlorine dioxide generating composition, as long as the chlorine dioxide generating source contains the chlorite and the acid, even if water is not blended, it absorbs water vapor in the air or in flash water. In the case of using it after diluting, by using flash water, chlorine dioxide can be generated by reacting chlorite and acid, so water is not necessarily contained. Good. However, from the viewpoint of efficiently generating chlorine dioxide, it is desirable that the chlorine dioxide generating composition contains water.
二酸化塩素発生組成物において水を含有させる場合、水の含有量については、態様2の薬剤組成物の形状等に応じて適宜設定すればよいが、例えば、30〜99.69重量%、好ましくは70〜97重量%が挙げられる。 When water is contained in the chlorine dioxide generating composition, the water content may be appropriately set according to the shape of the pharmaceutical composition of aspect 2, etc., for example, 30 to 99.69% by weight, preferably 70-97 weight% is mentioned.
二酸化塩素発生組成物において水を含有させる場合、二酸化塩素発生組成物を水溶液の状態にしてもよく、また、二酸化塩素発生組成物をゲル状にしてゲル中に水分を保持させたり、水分を保持させた水分保持基剤を含有させたりしてもよい。 When water is contained in the chlorine dioxide generating composition, the chlorine dioxide generating composition may be in the form of an aqueous solution, or the chlorine dioxide generating composition may be gelled to retain moisture in the gel or retain moisture. A moisture retention base may be included.
ゲル状にしてゲル中に水分を保持させる場合、ゲル化に使用されるゲル化剤の種類については、特に制限されないが、アルギン酸、寒天、カラギーナン、フコイダン等の褐藻、緑藻或いは紅藻由来成分;ビャッキュウ抽出物、ペクチン、ローカストビーンガム、アロエ多糖体などの多糖類;キサンタンガム、トラガントガム、グアーガムなどのガム類;カルボキシメチルセルロース、ヒドロキシエチルセルロースなどのセルロース誘導体;ポリビニルアルコール、ポリビニルピロリドン、カルボキシビニルポリマー、アクリル酸・メタクリル酸共重合体などの合成高分子類;ポリグルタミン酸及びその誘導体;グルコシルトレハロースと加水分解水添澱粉を主体とする糖化合物;デンプン系、セルロース系、合成ポリマー系等の各種吸水性樹脂等が挙げられる。 When water is retained in the gel in the form of a gel, the type of gelling agent used for gelation is not particularly limited, but is derived from brown algae, green algae, or red algae such as alginic acid, agar, carrageenan, fucoidan; Polysaccharides such as beech extract, pectin, locust bean gum and aloe polysaccharide; gums such as xanthan gum, tragacanth gum and guar gum; cellulose derivatives such as carboxymethylcellulose and hydroxyethylcellulose; polyvinyl alcohol, polyvinylpyrrolidone, carboxyvinyl polymer, acrylic acid Synthetic polymers such as methacrylic acid copolymers; polyglutamic acid and its derivatives; sugar compounds mainly composed of glucosyl trehalose and hydrolyzed hydrogenated starch; various water-absorbing trees such as starch-based, cellulose-based, synthetic polymer-based Etc. The.
二酸化塩素発生組成物にゲル化剤を含有させる場合、その含有量については、特に制限されないが、例えば、0.2〜25重量%、好ましくは1〜10重量%が挙げられる。 When the gelling agent is contained in the chlorine dioxide generating composition, the content thereof is not particularly limited, and examples thereof include 0.2 to 25% by weight, preferably 1 to 10% by weight.
水分を保持させた水分保持基剤を含有させる場合、使用される水分保持基剤の種類としては、水を保持できる特性を有していることを限度として特に制限されないが、例えば、珪藻土、ゼオライト、カオリン、パーライト、ベントナイト、炭等の多孔質物質が挙げられる。これらの水分保持基剤は、1種単独で使用してもよく、また2種以上を組み合わせて使用してもよい。 In the case of containing a moisture retention base that retains moisture, the type of moisture retention base used is not particularly limited as long as it has the property of retaining water, but for example, diatomaceous earth, zeolite , Porous materials such as kaolin, pearlite, bentonite, and charcoal. These moisture retention bases may be used alone or in combination of two or more.
二酸化塩素発生組成物に水分保持基剤を含有させる場合、その含有量については、特に制限されないが、例えば、0.2〜25重量%、好ましくは1〜10重量%が挙げられる。 When the moisture retention base is contained in the chlorine dioxide generating composition, the content is not particularly limited, but for example, 0.2 to 25% by weight, preferably 1 to 10% by weight.
また、二酸化塩素発生組成物に水分を保持させた水分保持基剤を含有させる場合には、更に、必要に応じて潮解性の固形剤を含んでいてもよい。水分保持基剤に水分を保持させた場合、二酸化塩素発生組成物における水含有量が比較的少なくなり、二酸化塩素の発生速度が遅くなることがあるが、更に潮解性の固形剤を含有させることによって二酸化塩素の発生を促進させることが可能になる。潮解性の固形剤の種類については、特に制限されないが、例えば、塩化アルミニウム、塩化カルシウム、塩化マグネシウム、リン酸一水素カリウム、グリセリン等が挙げられる。これらの潮解性の固形剤は、1種単独で使用してもよく、また2種以上を組み合わせて使用してもよい。 Further, when the chlorine dioxide generating composition contains a moisture retention base that retains moisture, it may further contain a deliquescent solid agent as necessary. When moisture is retained in the moisture retention base, the water content in the chlorine dioxide generating composition may be relatively low, and the generation rate of chlorine dioxide may be slowed down. This makes it possible to promote the generation of chlorine dioxide. The type of deliquescent solid agent is not particularly limited, and examples thereof include aluminum chloride, calcium chloride, magnesium chloride, potassium monohydrogen phosphate, and glycerin. These deliquescent solid agents may be used singly or in combination of two or more.
二酸化塩素発生組成物に潮解性の固形剤を含有させる場合、その含有量については、特に制限されないが、例えば、0.1〜30重量%、好ましくは1〜20重量%が挙げられる。 When the deliquescent solid agent is contained in the chlorine dioxide generating composition, the content is not particularly limited, but for example, 0.1 to 30% by weight, preferably 1 to 20% by weight.
更に、二酸化塩素発生組成物に水が含まれている場合、当該二酸化塩素発生組成物中に水には二酸化塩素が溶存させた状態で含まれていてもよい。このように溶存した二酸化塩素を含有させることにより、より一層効率的に二酸化塩素を放出させることが可能になる。 Furthermore, when water is contained in the chlorine dioxide generating composition, water may contain chlorine dioxide dissolved in the chlorine dioxide generating composition. By containing the dissolved chlorine dioxide in this way, it becomes possible to release chlorine dioxide more efficiently.
二酸化塩素発生組成物に溶存状態の二酸化塩素を含有させる場合、二酸化塩素の含有量については、水の含有量等に応じて適宜設定すればよいが、例えば、10ppm〜10000ppm、好ましくは50〜6000ppmが挙げられる。 When the dissolved chlorine dioxide is contained in the chlorine dioxide generating composition, the chlorine dioxide content may be appropriately set according to the water content and the like, for example, 10 ppm to 10000 ppm, preferably 50 to 6000 ppm. Is mentioned.
[その他の成分]
本発明で使用される薬剤組成物には、前述する成分の他に、水、有機溶剤、酵素、殺菌剤、キレート剤、着色剤、顔料、乳化剤、可溶化剤、増量剤、溶解性調整剤、漂白剤、撥水剤、親水剤、充填剤、pH調整剤、緩衝剤、消泡剤、賦形剤等が含まれていてもよい。これらの成分の含有量については、薬剤組成物の形状、使用する成分の種類等に応じて適宜設定すればよい。
[Other ingredients]
In addition to the components described above, the pharmaceutical composition used in the present invention includes water, organic solvents, enzymes, bactericides, chelating agents, colorants, pigments, emulsifiers, solubilizers, extenders, solubility modifiers. , Bleach, water repellent, hydrophilic agent, filler, pH adjuster, buffer, antifoaming agent, excipient and the like may be included. What is necessary is just to set suitably about content of these components according to the shape of a pharmaceutical composition, the kind of component to be used, etc.
[形状]
本発明で使用される薬剤組成物の形状については、その組成や薬剤成分の放出方法等に応じて適宜設定すればよいが、例えば、液状、ゲル状、ペースト状、錠剤状、粉末状、顆粒状等が挙げられる。
[shape]
The shape of the pharmaceutical composition used in the present invention may be appropriately set according to the composition, the method for releasing the pharmaceutical component, etc., for example, liquid, gel, paste, tablet, powder, granule And the like.
[薬剤組成物の設置方法及び薬剤成分の放出方法]
本発明の便器用衛生製品において、薬剤組成物は便蓋のボウル部側に設置される。このように便蓋のボウル部側に薬剤組成物を設置することにより、トイレを使用していない時(即ち、便器の便蓋を閉めた状態になっている際)に、便器の便蓋とボウル部で形成された空間内に薬剤成分が放出され、便器のボウル部の表面に薬剤成分を行き渡らせることが可能になり、ボウル部の衛生化効果を図ることができる。
[Installation method of drug composition and release method of drug component]
In the sanitary product for toilet according to the present invention, the pharmaceutical composition is placed on the bowl side of the toilet lid. By installing the pharmaceutical composition on the bowl side of the toilet lid in this manner, when the toilet is not in use (ie, when the toilet lid is closed), The drug component is released into the space formed by the bowl portion, and the drug component can be spread over the surface of the bowl portion of the toilet, so that the sanitizing effect of the bowl portion can be achieved.
本発明の便器用衛生製品は、洋式便器、和式便器、和式便器を簡易に洋式に変更する改造用便器・便座が取り付けられた便器、ポータブル便器等のいずれにも使用できるが、好ましくは洋式便器が挙げられる。なお、和式便器の場合には、前記便蓋はトイレカバーに該当し、前記ボウル部とは便器容器に該当する。 The toilet sanitary product of the present invention can be used for any of Western style toilets, Japanese style toilets, toilet bowls equipped with a modified toilet bowl / toilet seat that easily changes the Japanese style toilet bowl to Western style, portable toilet bowls, etc. Western-style toilets are listed. In the case of a Japanese style toilet, the toilet lid corresponds to a toilet cover, and the bowl portion corresponds to a toilet bowl.
図1及び2に、薬剤組成物1を洋式便器の便蓋2のボウル部3側に設置した態様の模式図を示す。図1では、洋式便器の便蓋2は空いた状態になっており、図2では、洋式便器の便蓋2は閉めた状態になっている。なお、図1及び2では、便宜上、貯水タンクからボウル部へのフラッシュ水の流路等については省略している。 The schematic diagram of the aspect which installed the chemical | medical agent composition 1 in the bowl part 3 side of the toilet lid 2 of a western style toilet in FIG. 1 and 2 is shown. In FIG. 1, the toilet lid 2 of the western style toilet is in an open state, and in FIG. 2, the toilet lid 2 of the western style toilet is in a closed state. In FIGS. 1 and 2, for the sake of convenience, the flow path of flush water from the water storage tank to the bowl portion is omitted.
本発明において、「薬剤組成物から薬剤成分を放出させる」とは、薬剤組成物から薬剤成分のみを放出させる態様、薬剤成分と共に他の成分(基剤、添加剤)を放出させる態様の双方が含まれる。 In the present invention, “releasing the drug component from the drug composition” means both an aspect in which only the drug component is released from the drug composition and an aspect in which other components (base, additive) are released together with the drug component. included.
本発明の便器用衛生製品において、薬剤組成物から薬剤成分を放出させる方法については、便器の便蓋を閉めた状態になっている際に、便蓋を閉めた状態で形成される便器の内部空間(便蓋とボウル部等によって形成される空間)内に薬剤成分を放出できることを限度として特に制限されない。例えば、薬剤成分として揮散性薬剤成分を使用する場合には、当該揮散性薬剤成分を揮散(気化)させることにより、薬剤成分を放出させてもよい。また、薬剤組成物を噴霧又は滴下させることによって、薬剤成分を放出させてもよい。揮散性薬剤成分を揮散させて放出させる場合、使用される薬剤組成物は、液状、ゲル状、ペースト状、錠剤状、粉末状、顆粒状等のいずれの形態であってもよい。また、薬剤成分を噴霧又は滴下させて放出させる場合、使用される薬剤組成物は、液状であることが望ましい。 In the toilet sanitary product of the present invention, for the method of releasing the drug component from the pharmaceutical composition, the inside of the toilet formed with the toilet lid closed when the toilet lid of the toilet bowl is closed There is no particular limitation as long as the drug component can be released into a space (a space formed by a toilet lid and a bowl portion). For example, when a volatile drug component is used as the drug component, the drug component may be released by volatilization (vaporization) of the volatile drug component. Alternatively, the drug component may be released by spraying or dropping the drug composition. When the volatile drug component is volatilized and released, the drug composition used may be in any form such as liquid, gel, paste, tablet, powder, granule and the like. In addition, when the drug component is sprayed or dropped to be released, the drug composition to be used is desirably in a liquid state.
これらの放出方法の中でも、ボウル部の表面全面に薬剤成分を行き渡らせて薬剤成分による衛生化効果をより一層有効に付与するという観点から、好ましくは、薬剤成分として揮散性薬剤成分を使用し、当該揮散性薬剤成分を揮散させる方法が挙げられる。 Among these release methods, from the viewpoint of more effectively imparting a sanitizing effect by the drug component by spreading the drug component over the entire surface of the bowl portion, preferably, a volatile drug component is used as the drug component, The method of volatilizing the said volatile chemical | medical agent component is mentioned.
薬剤組成物から揮散性薬剤成分を揮散させて放出させる場合、熱、超音波等の物理的手段を用いて揮散性薬剤成分を強制的に放出させてもよいが、使用簡便性や低コスト化等の観点から、自然揮散によって揮散性薬剤成分を放出させることが好ましい。 When volatilizing drug components are volatilized and released from the pharmaceutical composition, the volatilizing drug components may be forcibly released using physical means such as heat and ultrasonic waves, but they are easy to use and reduce costs. From such a viewpoint, it is preferable to release the volatile drug component by natural volatilization.
また、薬剤組成物から薬剤成分を噴霧させて放出させる場合であれば、例えば、噴霧ノズルを介して薬剤成分を放出させればよい。また、薬剤組成物から揮散性薬剤を滴下させて放出させる場合であれば、例えば、重力滴下、ポンプ等の機械的な手段を用いた滴下等によって薬剤成分を放出させればよい。 Moreover, what is necessary is just to discharge | release a chemical | medical component through a spray nozzle, for example, when spraying and releasing a chemical | medical component from a pharmaceutical composition. In addition, when a volatile drug is dropped from a drug composition and released, the drug component may be released by, for example, gravity dropping or dropping using mechanical means such as a pump.
本発明の便器用衛生製品によって、放出させる薬剤成分の量については、使用する薬剤成分の種類等に応じて適宜調節すればよい。例えば、薬剤成分として二酸化塩素を揮散させて放出させて、洗浄、抗菌、消臭作用を付与する場合であれば、便器の便蓋を閉じた状態で12時間放置した際に、便蓋を閉めた状態で形成される便器の内部空間(便蓋とボウル部等によって形成される空間)内の二酸化塩素ガス濃度が0.01ppm以上、好ましくは0.01〜100ppm、更に好ましくは0.02〜10ppm、特に好ましくは0.1〜1ppmとなるように設定することが望ましい。便蓋とボウル部によって形成される空間内の二酸化塩素ガス濃度を前記範囲になるようにコントロールすることによって、より一層優れた洗浄作用(汚れ除去効果と防汚効果)を付与することが可能になる。発生させる二酸化塩素ガス量は、薬剤組成物に含有させる二酸化塩素の含有量及び/又は二酸化塩素の発生源の組成や含有量を適宜調節することによってコントロールすることができる。 The amount of the drug component to be released by the toilet sanitary product of the present invention may be appropriately adjusted according to the type of the drug component used. For example, if chlorine dioxide is volatilized and released as a drug component to provide cleaning, antibacterial, and deodorizing effects, the toilet lid is closed when left for 12 hours with the toilet lid closed. The chlorine dioxide gas concentration in the interior space (space formed by the toilet lid and bowl portion, etc.) of the toilet bowl formed in a wet state is 0.01 ppm or more, preferably 0.01-100 ppm, more preferably 0.02- It is desirable to set it to 10 ppm, particularly preferably 0.1 to 1 ppm. By controlling the concentration of chlorine dioxide gas in the space formed by the toilet lid and bowl so that it falls within the above range, it is possible to provide even better cleaning action (stain removal effect and antifouling effect). Become. The amount of chlorine dioxide gas to be generated can be controlled by appropriately adjusting the content of chlorine dioxide contained in the pharmaceutical composition and / or the composition and content of the chlorine dioxide generation source.
[容器]
本発明の便器用衛生製品において、薬剤組成物は、容器に収容して便蓋のボウル部側に設置して使用されるが、薬剤組成物が粘着性を有するゲル状である場合であれば、当該薬剤組成物剤は、容器に収容せずに、そのまま設置部位に吸着させてもよい。
[container]
In the toilet sanitary product of the present invention, the pharmaceutical composition is used by being housed in a container and placed on the bowl side of the toilet lid, if the pharmaceutical composition is in the form of an adhesive gel. The drug composition agent may be adsorbed to the installation site as it is without being accommodated in the container.
薬剤組成物を収容する容器としては、具体的には、薬剤組成物を収容する収容部と、当該薬剤組成物から薬剤成分を容器外に放出するための放出部を有する容器を使用すればよい。当該容器は、便器の便蓋等に固定するために、粘着剤や吸盤等の固定部が設けられていればよい。以下、薬剤成分の放出方法毎に使用される容器について説明する。 As the container for storing the pharmaceutical composition, specifically, a container having a storing section for storing the pharmaceutical composition and a discharging section for discharging the drug component from the drug composition to the outside of the container may be used. . The container only needs to be provided with a fixing portion such as an adhesive or a suction cup in order to fix the container to the toilet lid or the like of the toilet bowl. Hereinafter, the container used for every discharge | release method of a pharmaceutical component is demonstrated.
(揮散性薬剤成分を揮散させて放出させる容器)
揮散性薬剤成分を含む薬剤組成物を使用する場合であれば、当該薬剤組成物を収容する容器の一態様として、薬剤組成物を収容する収容部と、揮散性薬剤成分が透過可能な透過性フィルム(揮散性薬剤成分透過性フィルム)からなる放出部を有する容器が挙げられる。
(Container that volatilizes and releases volatile chemical components)
If a drug composition containing a volatile drug component is used, as one aspect of a container for storing the drug composition, a container that stores the drug composition and a permeability that allows the volatile drug component to permeate. The container which has the discharge | release part which consists of a film (volatile chemical | medical agent component permeable film) is mentioned.
放出部として使用される揮散性薬剤成分透過性フィルムとしては、いわゆる香料透過性フィルムを使用でき、国際公開第98/23304号パンフレット、特開平6-219479号公報、米国特許第5,518,790号明細書等に開示されており、公知である。揮散性薬剤成分透過性フィルムの構成素材については、特に制限されるものではないが、例えば、ポリエチレン、ポリプロピレン、エチレン酢酸ビニル共重合体、エチレンエチルアクリレート、紙及びこれらの混合物等が挙げられる。これらの中でも、好ましくはリニアローデンシティポリエチレン(LLDPE)が挙げられる。放出部として使用される揮散性薬剤透過性フィルムは、1種の素材からなる単層フィルムであってもよく、また同一又は異なる素材からなる2以上の層が積層された複層フィルムであってもよい。 As the volatile drug component permeable film used as the release part, a so-called perfume permeable film can be used, such as WO98 / 23304 pamphlet, JP-A-6-219479, U.S. Pat.No. 5,518,790, etc. And is publicly known. The constituent material of the volatile drug component permeable film is not particularly limited, and examples thereof include polyethylene, polypropylene, ethylene vinyl acetate copolymer, ethylene ethyl acrylate, paper, and a mixture thereof. Among these, linear low density polyethylene (LLDPE) is preferable. The volatile drug permeable film used as the release part may be a single layer film made of one material, or a multilayer film in which two or more layers made of the same or different materials are laminated. Also good.
揮散性薬剤成分透過性フィルムからなる放出部を有する容器は、揮散性薬剤成分透過性フィルムのみによって構成されていてもよく、また揮散性薬剤成分透過性フィルムと揮散性薬剤成分非透過性部材とを組み合わせて構成されているものであってもよい。本発明において、揮散性薬剤成分非透過性部材とは、薬剤組成物のみならず揮散性薬剤成分も透過させない部材のことである。このような揮散性薬剤成分非透過性部材については、例えば、ガラス、ポリ塩化ビニリデン、ポリエチレンテレフタレート、エチレン酢酸ビニルコポリマー、アルミニウム等を初めとして様々なタイプの部材が知られており、これらを適宜選択し使用できる。当該揮散性薬剤成分非透過性部材は、前記揮散性薬剤成分透過性フィルムと組み合わされて、薬剤組成物を包囲できる容器を形成できる限り、フィルム状、シート状、袋状、容器状等の様々な形態をとることができる。 A container having a release part composed of a volatile drug component permeable film may be constituted only by the volatile drug component permeable film, and the volatile drug component permeable film, the volatile drug component non-permeable member, and May be configured in combination. In the present invention, the volatile drug component non-permeable member is a member that does not allow not only the drug composition but also the volatile drug component to pass therethrough. As for such a volatile drug component non-permeable member, various types of members such as glass, polyvinylidene chloride, polyethylene terephthalate, ethylene vinyl acetate copolymer, aluminum and the like are known, and these are appropriately selected. Can be used. As long as the volatile drug component non-permeable member can be combined with the volatile drug component permeable film to form a container that can surround the drug composition, the volatile drug component non-permeable member can be a variety of films, sheets, bags, containers, etc. Can take various forms.
揮散性薬剤成分透過性フィルムからなる放出部を有する容器には、便蓋等に固定するために粘着剤や吸盤等の固定部が直接設けられていてもよいが、当該容器は、取り外し可能な支持体に支持され、当該支持体に便蓋等に固定するための固定部が設けられていてもよい。 A container having a discharge part made of a volatile drug component permeable film may be directly provided with a fixing part such as an adhesive or a suction cup for fixing to a toilet lid or the like, but the container is removable. The support may be provided with a fixing portion for fixing to the toilet lid or the like.
揮散性薬剤成分透過性フィルムからなる放出部を有する容器は、あらゆる形状の薬剤組成物に適用できるが、特に、液状又はゲル状の薬剤組成物を収容する容器として好適に使用される。 A container having a release part made of a volatile drug component permeable film can be applied to drug compositions of any shape, but is particularly preferably used as a container for storing a liquid or gel drug composition.
また、例えば、揮散性薬剤成分を含み、保形性を有する形状(ゲル状、錠剤状、顆粒状、粉末状等)の薬剤組成物を使用する場合であれば、不織布からなる放出部を有する容器を使用してもよい。不織布からなる放出部を有する容器は、不織布のみによって容器状(袋状)に形成されていてもよく、また不織布と揮散性薬剤成分非透過性部材とを組み合わせて構成されているものであってもよい。揮散性薬剤成分非透過性部材の素材や形状等については、前述した通りである。 In addition, for example, if a pharmaceutical composition containing a volatile drug component and having a shape-retaining property (gel, tablet, granule, powder, etc.) is used, it has a release part made of a nonwoven fabric. Containers may be used. A container having a discharge portion made of a nonwoven fabric may be formed into a container shape (bag shape) only by the nonwoven fabric, and is configured by combining a nonwoven fabric and a volatile drug component impermeable member. Also good. The material and shape of the volatile drug component non-permeable member are as described above.
不織布からなる放出部を有する容器には、便蓋等に固定するために粘着剤や吸盤等の固定部が直接設けられていてもよいが、当該容器は、取り外し可能な支持体に支持され、当該支持体に便蓋等に固定するための固定部が設けられていてもよい。 A container having a discharge part made of a nonwoven fabric may be directly provided with a fixing part such as an adhesive or a suction cup for fixing to a toilet lid or the like, but the container is supported by a removable support, A fixing part for fixing to the toilet lid or the like may be provided on the support.
更に、例えば、揮散性薬剤成分を含み、保形性を有する形状(ゲル状、錠剤状、顆粒状、粉末状等)の薬剤組成物を使用する場合には、薬剤組成物を固定した状態で維持できる収容部と、当該薬剤組成物から揮散される揮散性薬剤成分を容器外に放出するための開口部(放出部)を有する容器を使用してもよい。 Furthermore, for example, when using a drug composition having a volatile drug component and having a shape-retaining property (gel, tablet, granule, powder, etc.), the drug composition is in a fixed state. You may use the container which has the accommodating part which can be maintained, and the opening part (release | release part) for discharging | emitting the volatile chemical | medical agent component volatilized from the said pharmaceutical composition out of a container.
また、揮散性薬剤成分を含む薬剤組成物を使用し、熱、超音波等の物理的手段を用いて揮散性薬剤成分を強制的に放出させる場合であれば、使用する容器は、前記収容部及び前記放出部に加えて、熱、超音波等を付与するための物理的手段、及び当該物理的手段を稼働させるための電力供給源等を備えていればよい。 In addition, if a drug composition containing a volatile drug component is used and the volatile drug component is forcibly released using physical means such as heat and ultrasonic waves, the container used is the container. In addition to the emission unit, a physical means for applying heat, ultrasonic waves, and the like, and a power supply source for operating the physical means may be provided.
(薬剤成分を噴霧させて放出させる容器)
薬剤組成物から薬剤成分を噴霧させて放出させる場合であれば、薬剤組成物を収容する収容部と、当該収容部から供給された薬剤組成物を噴霧させて容器外に放出させるための噴霧ノズル(放出部)を有する容器を使用すればよい。また、噴霧ノズルから薬剤組成物を噴霧させるために必要な電力供給源等を備えていてもよい。
(Container that sprays and releases drug components)
If the drug component is to be sprayed and released from the drug composition, a container for storing the drug composition and a spray nozzle for spraying the drug composition supplied from the container and discharging it to the outside of the container What is necessary is just to use the container which has (discharge | release part). Moreover, you may provide the electric power supply source etc. which are required in order to spray a pharmaceutical composition from a spray nozzle.
(薬剤成分を滴下させて放出させる容器)
薬剤組成物から薬剤成分を滴下させて放出させる場合であれば、薬剤組成物を収容する収容部と、当該収容部から供給された薬剤組成物を滴下させて容器外に放出させるための細孔部(放出部)を有する容器を使用すればよい。また、ポンプ等の機械的手段を用いて薬剤組成物を滴下する場合であれば、当該機械的手段を稼働させるために必要な電力供給源等を備えていてもよい。
(Container that drops and releases drug components)
If the drug component is dropped from the drug composition to be released, the container for storing the drug composition and the pores for dropping the drug composition supplied from the container to be released out of the container A container having a part (discharge part) may be used. In addition, if the pharmaceutical composition is dropped using mechanical means such as a pump, a power supply source necessary for operating the mechanical means may be provided.
以下、実施例等に基づいて本発明を詳細に説明するが、本発明はこれらによって限定されるものではない。 EXAMPLES Hereinafter, although this invention is demonstrated in detail based on an Example etc., this invention is not limited by these.
試験例1:糞便の除去効果の評価
表1に示す組成のゲル状の薬剤組成物を調製し、糞便のモデル汚垢としてサラダ油及びカーボンブラックをサラダ油:カーボンブラックの質量比が100:2となるように混合したものを使用して、以下の試験を行った。
Test Example 1: Evaluation of Fecal Removal Effect A gel-like pharmaceutical composition having the composition shown in Table 1 was prepared, and salad oil and carbon black as a stool model stain were used in a mass ratio of salad oil: carbon black of 100: 2. The following tests were conducted using the mixture.
各薬剤組成物30gを、収容部と当該収容部から容器外部に連通している開口部を有する容器に収容した。開閉可能な便蓋を有する便器[TOTO社製の貯水タンク(型番:S721)及びTOTO社製の便器(型番:C720)]のボウル部に、モデル汚垢3gを約200cm2となるように塗布した。次いで、便器の便蓋のボウル部側に、容器に収容した各ゲル状洗浄剤と取り付け、便蓋を閉めた状態で12時間放置した。その後、便器内空間(便蓋とボウル部等によって形成されている空間)から、100mlの空気をシリンジで吸引し、二酸化塩素の気体検知管(No.23M(測定範囲0.1〜10ppm)、又はNo.23L(測定範囲0.025〜1.2ppm)(いずれも株式会社ガステック製))を差し込み、二酸化塩素ガス濃度を測定した。更に、12時間放置後に、約13Lの水をフラッシュし、残存するモデル汚垢の残存量を目視で判断し、下記判定基準に従って、汚垢除去効果を評価した。
<汚垢除去効果の判定基準>
◎:モデル汚垢の残存率が5%未満である。
○:モデル汚垢の残存率が5%以上20%未満である。
△:モデル汚垢の残存率が20%以上50%未満である。
×:モデル汚垢の残存率が50%以上である。
30 g of each pharmaceutical composition was accommodated in a container having an accommodating part and an opening communicating from the accommodating part to the outside of the container. 3 g of model dirt is applied to the bowl part of a toilet bowl [TOTO water storage tank (model number: S721) and TOTO toilet bowl (model number: C720)] having an openable and closable toilet lid so as to be about 200 cm 2. did. Next, each gel-like cleaning agent contained in the container was attached to the toilet bowl bowl side, and left for 12 hours with the toilet lid closed. Thereafter, 100 ml of air is sucked with a syringe from the toilet space (the space formed by the toilet lid and the bowl, etc.), and a chlorine dioxide gas detector tube (No. 23M (measurement range 0.1 to 10 ppm), Alternatively, No. 23L (measurement range: 0.025 to 1.2 ppm) (both manufactured by Gastec Co., Ltd.) was inserted, and the chlorine dioxide gas concentration was measured. Further, after leaving for 12 hours, about 13 L of water was flushed, the remaining amount of the model dirt remaining was visually judged, and the dirt removing effect was evaluated according to the following criteria.
<Judgment criteria for dirt removal effect>
A: Model dirt residual rate is less than 5%.
○: Model dirt residual rate is 5% or more and less than 20%.
Δ: Model dirt residual rate is 20% or more and less than 50%.
X: Model dirt residual rate is 50% or more.
得られた結果を表1に示す。この結果、二酸化塩素の発生源を含む薬剤組成物を便蓋に設置することにより、便器内の空間に二酸化塩素ガスを放出でき、便器のボウル部における汚垢の除去効果が奏されることが確認された。 The obtained results are shown in Table 1. As a result, by installing a pharmaceutical composition containing a chlorine dioxide source on the toilet lid, chlorine dioxide gas can be released into the space inside the toilet, and the effect of removing dirt in the bowl portion of the toilet can be achieved. confirmed.
試験例2:糞便及び黒ずみの除去効果及び防汚効果の評価(フィールド試験)
前記試験例1で調製した薬剤組成物を使用し、以下のフィールド試験を行った。4人家族の家庭用便器の便蓋のボウル部側に、容器に収容した各薬剤組成物と取り付けた。使用した容器は、前記試験例1の場合と同様である。7日間便器の清掃をすることなく、家庭用便器を使用した。なお、便器を使用しない場合には、便蓋を閉めた状態にしておいた。また、4人家族の家庭用便器は、通常、1日当たりのトイレの使用回数は15〜25回である。7日間使用後の便器について、糞便汚れ及び黒ずみの有無を目視にて確認し、下記判定基準に従って、糞便汚れ及び黒ずみの除去効果を評価した。
<汚垢除去効果の判定基準>
◎:糞便汚れ及び黒ずみの付着が全く認められない。
○:糞便汚れ又は黒ずみの付着が僅かに認められる。
△:糞便汚れ又は黒ずみの付着が少しだけ認められる。
×:糞便汚れ又は黒ずみの付着がかなり認められる。
Test Example 2: Evaluation of fecal and darkening removal effect and antifouling effect (field test)
Using the pharmaceutical composition prepared in Test Example 1, the following field test was conducted. Each drug composition contained in a container was attached to the bowl side of the toilet lid of a household toilet for a family of four. The container used is the same as in the case of Test Example 1. A household toilet was used without cleaning the toilet for 7 days. When the toilet bowl was not used, the toilet lid was closed. In addition, a toilet for a family of four usually uses 15 to 25 toilets per day. The toilet after 7 days of use was visually checked for the presence or absence of stool stain and darkening, and the removal effect of stool stain and darkening was evaluated according to the following criteria.
<Judgment criteria for dirt removal effect>
(Double-circle): Feces dirt and darkening adhesion are not recognized at all.
○: Stool stain or darkening is slightly observed.
(Triangle | delta): Only slight adhesion of feces dirt or darkening is recognized.
X: Adherence of faecal dirt or darkening is considerably recognized.
得られた結果を表2に示す。この結果、二酸化塩素の発生源を含むゲル状洗浄剤を便蓋に設置することにより、清掃することなくトイレを7日間使用しても、糞便汚れ及び黒ずみの付着が十分に抑制できており、便器内の空間に二酸化塩素ガスを放出させることにより、優れた汚れ除去効果と防汚効果が奏されることが確認された。 The obtained results are shown in Table 2. As a result, by installing a gel-like cleaning agent containing a chlorine dioxide source on the toilet lid, even if the toilet is used for 7 days without cleaning, it is possible to sufficiently suppress the adhesion of fecal dirt and darkening, It was confirmed that excellent dirt removal effect and antifouling effect were exhibited by releasing chlorine dioxide gas into the space in the toilet.
参考例1:黒ずみ発生防止効果の評価
表3に示す組成のゲル状の薬剤組成物を調製し、各薬剤組成物10gを用いて、黒ずみ発生防止効果の評価を行った。直径8.7cmのプラスチックシャーレにポテトデキストロース寒天培地を作成し、Cladosporium halotolerans(NBRC111839)(黒ずみの原因菌)を1×108 cells/ml濃度となるように調整した菌液を100μl塗布した。次いで、蓋付きのプラスチックケース(容量25cm×15cm×10cm)に、菌を塗布したシャーレ(蓋を開けた状態)と、容器に収容した薬剤組成物を入れて、当該プラスチックケースを密閉し、22.5℃で5日間静置した。なお、使用した容器は、前記試験例1の場合と同様である。その後、プラスチックシャーレ上の菌の繁殖状態を目視にて確認し、下記判定基準に従って、黒ずみ発生防止効果を評価した。ケース内の二酸化塩素濃度は、試験終了後(5日間静置後)にケースの蓋をわずかに開けた隙間から100mlの空気をシリンジで吸引し、そのシリンジを試験例1と同様の二酸化塩素の気体検知管に接続して、二酸化塩素ガス濃度を測定した。
<黒ずみ発生防止効果の判定基準>
○:シャーレに菌のコロニーが一切認められない。
△:シャーレに認められる菌のコロニー数が10個以下である。
×:シャーレに認められる菌のコロニー数が11個以上100個以下である。
××:シャーレに無数の菌のコロニー数が認められる。
Reference Example 1: Evaluation of prevention of darkening occurrence Gelled pharmaceutical compositions having the compositions shown in Table 3 were prepared, and the prevention of darkening occurrence was evaluated using 10 g of each pharmaceutical composition. A potato dextrose agar medium was prepared in a plastic petri dish with a diameter of 8.7 cm, and 100 μl of a bacterial solution prepared by adjusting Cladosporium halotolerans (NBRC111839) (causing bacteria of darkening) to a concentration of 1 × 10 8 cells / ml was applied. Then, a petri dish (capacity 25 cm × 15 cm × 10 cm) with a lid is placed with a petri dish (in a state where the lid is opened) coated with bacteria and a drug composition contained in a container, and the plastic case is sealed, 22 And left at 5 ° C. for 5 days. The container used is the same as in the case of Test Example 1. Thereafter, the propagation state of the bacteria on the plastic petri dish was visually confirmed, and the effect of preventing darkening was evaluated according to the following criteria. The concentration of chlorine dioxide in the case was determined by suctioning 100 ml of air with a syringe through the gap where the case was slightly opened after the test was completed (after 5 days of standing). Connected to a gas detector tube, the chlorine dioxide gas concentration was measured.
<Judgment criteria for prevention of darkening>
○: No fungal colonies are observed in the petri dish.
Δ: The number of colonies of bacteria found in the petri dish is 10 or less.
X: The number of colonies of bacteria recognized in the petri dish is 11 or more and 100 or less.
Xx: Countless number of colonies of bacteria are observed in petri dish.
得られた結果を表3に示す。この結果、二酸化塩素の発生源を含む薬剤組成物を用いて二酸化塩素ガスを放出させることにより、黒ずみの原因菌となる菌の繁殖を効果的に抑制できることが確認された。 The obtained results are shown in Table 3. As a result, it was confirmed that the growth of bacteria that cause blackening can be effectively suppressed by releasing chlorine dioxide gas using a pharmaceutical composition containing a chlorine dioxide generation source.
1 便器用衛生製品
2 便蓋
3 ボウル部
4 水
1 Sanitary product for toilet bowl 2 Toilet lid 3 Bowl part 4 Water
Claims (5)
薬剤成分を放出させる薬剤組成物を含み、
前記便蓋のボウル部側に設置される、便器用衛生製品。 A sanitary product for a toilet used in a toilet having an openable / closable toilet lid,
Including a pharmaceutical composition that releases the pharmaceutical component;
A toilet sanitary product installed on the bowl side of the toilet lid.
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2017
- 2017-03-10 JP JP2017045946A patent/JP7357429B2/en active Active
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2022
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Patent Citations (9)
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US4216553A (en) * | 1977-05-12 | 1980-08-12 | Walter Haberle | Toilet with folding lid |
JPS63165367U (en) * | 1987-04-15 | 1988-10-27 | ||
JP3053744U (en) * | 1997-04-28 | 1998-11-13 | 貞三 林 | A toilet with a built-in device that automatically performs cleaning, sterilization, disinfection, drying, etc. after each use |
JP2004076298A (en) * | 2002-08-12 | 2004-03-11 | Hideo Sumino | Toilet bowl usable by sitting thereon |
JP2006206882A (en) * | 2004-12-27 | 2006-08-10 | Lion Corp | Composition slowly soluble in water and cleaning method using it |
JP3134078U (en) * | 2007-05-23 | 2007-08-02 | 高橋 早苗 | Waste container with sterilization and deodorizing function |
JP2009127385A (en) * | 2007-11-27 | 2009-06-11 | Panasonic Electric Works Co Ltd | Toilet bowl apparatus |
JP2011047218A (en) * | 2009-08-27 | 2011-03-10 | Kobayashi Pharmaceutical Co Ltd | Chemical agent feeder |
JP3198786U (en) * | 2015-05-11 | 2015-07-23 | 株式会社アメータ | Hygiene products and Western toilet |
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JP2022132515A (en) | 2022-09-08 |
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