JP2018094543A - Function liquid manufacturing device and function liquid manufacturing method - Google Patents

Abstract

PROBLEM TO BE SOLVED: To provide a function liquid manufacturing device generating ozone by energy saving and safe ultraviolet, large in bactericidal effect and having a washing function and a physiological function, and a functional liquid manufacturing method.SOLUTION: There is provided a function liquid manufacturing device 1 for generating ozone micro nano bubble and function water having sterilization, washing and physiological functions by discharging ozone-containing gas water two phase flow which is adsorbed to a micro nano bubble generator 10 by aspirating air or oxygen gas containing ozone generated by storing ultraviolet LED2 in a sleeve of a pipeline constitutional element and irradiating convergence ultraviolet of LED to oxygen molecule in air or oxygen molecule in oxygen gas stored passing through a sleeve 6 as pin point by an aspiration means, in which an ultraviolet LED2 as a light source for sterilization includes a light emission chip, a condenser lens 4 which converges light emission of the light emission chip, and the ultraviolet LED2 converge the light emission of the light emission chip with the condenser lens 4 and irradiates the same.SELECTED DRAWING: Figure 1

Description

  The present invention relates to an aquaculture laver sterilization liquid and aquaculture liquid, an aquaculture seafood sterilization liquid and an aquaculture liquid, an agricultural product sterilization liquid and a cultivation liquid, a food sterilization liquid, a semiconductor device silicon wafer -The present invention relates to a functional liquid manufacturing apparatus and a functional liquid manufacturing method related to cleaning, waste liquid processing, and the like.

  When cultivating a cultured laver net in the seaweed culture, there are problems such as mixed algae and diseases caused by various germs, etc. Is used. As an example of a laver culture acid treatment agent, a solution obtained by adding an inorganic salt and an acid to seawater is disclosed (for example, see Patent Document 1). Moreover, an acid treatment agent having a small pH change is disclosed by mixing a buffer compound containing no organic acid with phosphorus and seawater (see, for example, Patent Document 2). Moreover, an algicidal fungicide that simultaneously eliminates and prevents Aonori diatom and red rot fungi with organic acids such as lactic acid and citric acid is disclosed (for example, see Patent Document 3). However, both of these damage the nori leaf bodies by strong acids and hinder the growth of nori. As a result, dry seaweed becomes hard and inhibits the taste. Leaf bodies damaged by cryopreservation have reduced physiological activity, lost survival competition with miscellaneous algae, and are more susceptible to infection with bacteria. Reduce.

  In addition, the rearing liquid in the onshore aquaculture facility for seafood is contaminated with residual food and fish excrement in the process of circulation use, so solids treatment, foam separation treatment, soluble organic matter treatment, etc. are necessary. In order to prevent diseases caused by bacteria and viruses, ultraviolet sterilization treatment, ozone sterilization treatment, and the like are performed. As an example, an aquaculture facility is disclosed in which ozone supplied from an ozone generator is dispersed in a liquid tank using a bubble disperser (see, for example, Patent Document 4). However, the conventional ultraviolet sterilizer is made of special glass that transmits a sterilization line having a maximum wavelength in the vicinity of 260 nm, and has problems such as higher cost and higher power consumption than an LED.

  Moreover, in hydroponic cultivation, the knowledge which disinfects or disinfects by making an ozone nanobubble contain in a hydroponic liquid, and disinfects the air and a plant in a greenhouse building by ozone nanomist is disclosed (for example, refer patent document 5). ).

  In addition, in the production of fish paste products, a thawing method in which frozen food is immersed in ozone nanobubble water and thawed, and a sterilization manufacturing method in which ozone nano bubble water is added to the raw material of fish paste products and the raw material is sterilized are disclosed. (For example, refer to Patent Document 6).

  Moreover, the knowledge which produces | generates ozone-containing gas with ozone produced | generated with the silent discharge type | mold ozone generator etc., introduce | transduces this ozone-containing gas into a cooling part, and produces | generates liquefied ozone is disclosed (for example, patent document 7). reference).

  Also, an ozone generator is disclosed in which a dielectric is provided in the middle of a high-voltage electrode and a ground electrode by a silent discharge method, and the dielectric is disposed between discharge columns (for example, Patent Document 8). reference)

  Also disclosed is an ultraviolet ray generator including a low-pressure mercury vapor discharge made of quartz glass in which mercury and a rare gas are sealed, and a lighting device having a rectangular wave current or a high frequency power of 10 KHz or more (for example, , See Patent Document 9).

  Further, a throw-in type ultrasonic cleaning apparatus for cleaning a large object to be cleaned is disclosed (for example, see Patent Document 10).

  Further, a deep ultraviolet light emitting element that emits deep ultraviolet light by discharging with a discharge electrode having a high voltage with respect to the reference electrode and causing electrons of plasma generated from a gas filled in a space accommodating both electrodes to collide with the light emitting layer. (For example, refer to Patent Document 11).

  Also disclosed is an apparatus that discharges a gas plasma jet generated by glow discharge under atmospheric pressure in an insulating tube as a target gas (see, for example, Patent Document 12).

  Further, an oxygen incubator is disclosed that concentrates oxygen in the air to evaporate the condensed water generated when the air is cooled and removes it from the drain tank (for example, Patent Document 13). reference).

  Further, an ultraviolet sterilization apparatus having a high sterilization efficiency even with a cutting oil having a low ultraviolet transmittance is disclosed (for example, see Patent Document 14).

  Moreover, the hydroponics apparatus which uses a gas-permeable porous film for the outer part of the hydroponics culture solution storage container is disclosed (for example, refer to reference 15).

  And the hydroponics mat | matte which consists of a biodegradable resin extrusion foam sheet | seat which has cellulose and an acetate diameter resin as a main component is disclosed (for example, refer to reference document 16).

  In addition, conventional ozone generators include silent discharge, electrolysis, ultraviolet lamp, etc., and there are ultraviolet lamps, etc., all of which are expensive and other than the ultraviolet lamp, harmful nitrogen oxidation Sterilization that emits 253.7 sterilization lines around 260 nm, which is the wavelength that shows the maximum value of sterilization action, although it does not produce harmful nitrogen oxides in the ultraviolet lamp system. Although lamps are commonly used, there are problems such as restrictions on the shape and higher power consumption than LEDs. In the ultraviolet sterilization apparatus or the photocatalytic sterilization apparatus, particularly when the transmission medium distance is large or the degree of transparency is large, the ultraviolet light or visible light is absorbed by the transmission medium, and the sterilization effect cannot be exhibited. Moreover, in hydroponics and the like in which the required amount of dissolved oxygen is not so large, there is a need for a dissolved oxygen supply means that does not require power and is highly efficient.

Japanese Patent No. 3296174 JP 2007-91690 A Japanese Patent No. 3121259 JP 11-318270 A JP 2008-206448 A JP 2007-97521 A Japanese Patent Laid-Open No. 2001-133142 JP 2015-67480 A Japanese Patent Laid-Open No. 5-135741 JP2015-112586A Japanese Patent Laid-Open No. 2015-103340 JP 2013-225421 A JP 2006-247552 A JP 2011-225676 A Japanese Patent Laying-Open No. 2005-21107 JP 2003-143984 A

  In view of the above-described prior art, the present invention has as a problem to be solved, ozone generated by an energy-saving and highly safe deep ultraviolet light emitting LED or microplasma excited deep ultraviolet light emitting element, and an ozone micro / nano bubble having a large bactericidal effect. The problem is to make it a liquid. In addition, ozone generated by irradiating oxygen molecules with ultraviolet light from deep liquid ultraviolet light emitting LED or microplasma excited far ultraviolet light emitting element is decomposed by the same deep ultraviolet light emitting LED or microplasma excited deep ultraviolet light emitting element (MIPE). It is a problem not to do. If no measures are taken, a far ultraviolet light emitting LED or a microplasma-excited deep ultraviolet light emitting element in a wavelength range in which oxygen molecules can be slightly ozonated even when irradiated with oxygen molecules. The challenge is to enable ozonization. Another object is to increase the ozone concentration and increase the amount of ozone generated with a simple structure and configuration. Another problem is to produce a functional liquid having a cleaning function and a physiologically active function. The challenge is to disinfect bacteria and viruses extensively. Another problem is not to discharge any environmental pollution load. Further, when the sterilizing power as strong as that of the ozone micro / nano bubble liquid is not required, it is also a problem to substitute with the air micro / nano bubble liquid. Improvement of the reach of ultraviolet rays or natural light to the liquid to be treated and the photocatalyst is a problem. Further, it is a means for inhibiting microorganisms whose nucleic acids have been damaged by ultraviolet light or ultraviolet light-containing natural light to the liquid to be treated and continuing to be irradiated with ultraviolet light or visible light to cause a photorecovery phenomenon. Another problem is to increase the surface area of the photocatalyst per unit volume. Another problem is to supply dissolved oxygen to the liquid to be treated without power.

  In order to solve the above problems, the present invention provides a deep ultraviolet light emitting LED, a microplasma excited far ultraviolet light emitting element or a field emission lamp FEL having a central wavelength in a wavelength range of 240 nm to 200 nm. A deep ultraviolet light emitting LED, a microplasma excited deep ultraviolet light emitting element or a field emission lamp FEL that converges and irradiates light emitted from an ultraviolet light emitting LED or a microplasma excited deep ultraviolet light emitting element with a condenser lens. An excited deep ultraviolet light emitting element or a field emission lamp FEL is arranged in the sleeve to form an ozone generator that constitutes a part of the piping. In deep oxygen light emitting LED, microplasma excited deep ultraviolet light emitting element or field emission lamp FEL having a central wavelength in the wavelength range of 254 nm to 200 nm, in the oxygen molecule in the air or oxygen gas flowing through the sleeve, To the micro / nano bubble generating device in which the deep ultraviolet light emitted from the deep ultraviolet light emitting LED, microplasma-excited deep ultraviolet light emitting element or field emission lamp FEL is irradiated with pinpoint, and the generated ozone-containing air or oxygen gas is sucked by a suction means Since it is sucked and an ozone-containing gas-liquid two-phase flow is generated, when the gas-liquid two-phase flow is discharged into the liquid, ozone microbubbles are generated, and the ozone microbubbles shrink in the liquid. It disappears, but when it disappears, it generates free radicals due to the self-pressurization effect. Sterilization generates the following ozone nanobubbles bubble diameter 1 nm, washing, to produce a functional fluid having physiological activity functions. In order to efficiently generate ozone nanobubbles, it is preferable to generate microbubbles in a liquid containing a certain amount of electrolyte and float them in a natural state or apply simple physical stimulation. Ozone nanobubbles are covered with high-concentration electrolyte ions, making it difficult for the gas to dissolve in the liquid and maintaining a stable state in the liquid for a long time. Here, electromagnetic waves in the wavelength region of 300 nm to 200 nm are defined as far ultraviolet rays. Moreover, except what is conventionally used like seawater, hydroponics, etc., it is expressed as a functional liquid instead of functional water.

  Since the energy of the photon is inversely proportional to the wavelength, the energy of the photon of a conventional ultraviolet lamp that emits a central wavelength of 185 nm to ozonize oxygen molecules is, for example, a far-ultraviolet LED, microplasma having a central wavelength of 240 nm. Since the wavelength is about 1 / 1.3 of the energy of the photon in the excited deep ultraviolet light emitting element or the field emission lamp FEL, the energy density of the photon in the ultraviolet LED is enhanced by about twice or more. If measures are taken, oxygen molecules are ozonized. Accordingly, the deep ultraviolet light emitting LED, the microplasma-excited deep ultraviolet light emitting element or the field emission lamp FEL includes a condenser lens for converging the light emission, and the deep ultraviolet light emitting LED, the microplasma excited deep ultraviolet light emitting element or the field emission lamp FEL With a condenser lens, the energy density (energy per unit area) of the photon in the deep ultraviolet LED, microplasma-excited deep ultraviolet light emitting element or field emission lamp FEL is about 1.3 times or more pinpointed. By irradiating with enhanced focused ultraviolet rays, oxygen molecules are ozonated pinpointed. In selecting the central wavelength emitted by the deep ultraviolet LED, microplasma-excited deep ultraviolet light emitting element or field emission lamp FEL, the total photon that irradiates oxygen molecules should be close to 200 nm or 200 nm as much as possible. Since the amount of energy is large, the amount of generated ozone is increased, which is preferable.

  Further, the photon flux emitted from the deep ultraviolet light emitting LED, the microplasma-excited deep ultraviolet light emitting element or the field emission lamp FEL is composed of a spectral distribution having a plurality of wavelengths except for the laser beam, and ozonizes oxygen molecules. There are many that emit far ultraviolet light in the wavelength region of 242 nm or less. Accordingly, when deep ultraviolet light having a wavelength region of 242 nm or less is condensed by a condensing lens and irradiated to oxygen molecules, the oxygen molecules are ozonized.

  In the second invention, an ozone generator that constitutes a part of a pipe, in which two or more deep ultraviolet light emitting LEDs, a microplasma excited deep ultraviolet light emitting element or a field emission lamp FEL are arranged on a sleeve; Two or more series-connected ozone generator groups in which the ozone generators are arranged in series, and two or more series-connected ozone generator groups are arranged in parallel with each other to increase the ozone concentration and sterilization treatment capacity To increase.

  In the third aspect of the invention, in the gas suction side piping system of the microbubble generator, two or more control pipes are disposed upstream of the gas suction side piping system. One is provided with an air release port equipped with an opening / closing means, and another supply pipe equipped with the opening / closing means is provided with oxygen supply means such as an oxygen gas cylinder or an oxygen hatching device, and the opening / closing means The ozone generator is connected in communication with another control pipe equipped with the above, and the opening and closing means are operated as necessary to select air, oxygen gas, ozone-containing air, or ozone-containing oxygen gas.

  In addition, in the fourth invention, the functional liquid storage tank is used as a pretreatment or combined use in which the ozone in the first invention is sterilized and washed with a functional liquid containing ozone micro / nano bubble liquid generated by being sucked into the micro / nano bubble generator. An ultrasonic generator is installed in the liquid and ultrasonic vibrations are generated in the liquid, so that free radicals are generated due to the cavitation effect and the object to be cleaned is washed and stored in the liquid storage tank. A central wavelength in a wavelength range of 240 nm to 200 nm, which is connected to a circulation pipe of a circulation pump device that circulates and sterilizes bacteria to be sterilized in the sterilization target liquid flowing through a light transmission wall. A deep ultraviolet light emitting LED, a microplasma-excited deep ultraviolet light emitting element or a field emission lamp FEL is disposed and sterilized by irradiation with deep ultraviolet light. Immersing the photocatalytic coating filters on the sterilized solution to over-flow at a light permeable wall, arranged to UV sterilizer and photocatalytic features apparatus for sterilizing by exciting the photocatalyst in the deep UV. A deep ultraviolet light emitting LED having a central wavelength in a wavelength range of 240 nm to 200 nm, a condensing lens for converging light emitted from a microplasma excited deep ultraviolet light emitting element or a field emission lamp FEL, and the far ultraviolet light emitting LED, microplasma excited depth A deep ultraviolet light emitting LED, microplasma excited deep ultraviolet light emitting element or field emission lamp FEL that converges and radiates the light emitted from the ultraviolet light emitting element or field emission lamp FEL with a condenser lens is disposed in the sleeve, and part of the piping Is an ozone generator. In the deep ultraviolet light emitting LED, the microplasma-excited deep ultraviolet light emitting element or the field emission lamp FEL having a central wavelength in the wavelength range of 250 nm to 200 nm on the oxygen molecules in the air or oxygen gas passing through the ultraviolet ozone generator. Is a micro / nano bubble generation device that sucks the generated ozone-containing air or oxygen gas with a suction means by irradiating the focused ultraviolet light of the deep ultraviolet light emitting LED, the microplasma excited deep ultraviolet light emitting element or the field emission lamp FEL at a pinpoint. The ozone-containing gas-liquid two-phase flow generated by suction is discharged into water to produce ozone microbubbles and nanobubbles to produce a functional liquid having sterilization, washing, and physiological activity functions.

  In the fifth invention, an LED, a field emission lamp or an excimer lamp is provided in an ozone generator provided with a vacuum ultraviolet light leakage prevention means, and the LED, the field emission lamp or the excimer lamp is projected. Vacuum ultraviolet light of 200 nm or less from the window is sucked into the micro / nano bubble generating device of the first invention, etc., flows from the air suction port, and irradiates with oxygen molecules in the air flowing down the inside of the ozone generating device. The oxygen molecules are ozonized. The vacuum ultraviolet light of 200 nm or less is absorbed somewhat in the air, so that it is somewhat diminished by passing through the air, but most of it is transmitted and the ozone generator facing the projection window When irradiated with a vacuum ultraviolet light emitting phosphor applied to the inner wall of the substrate or the substrate fixedly disposed on the inner wall, vacuum ultraviolet light is generated, and the vacuum ultraviolet light ozonizes oxygen molecules in the air or oxygen gas. . In order to prevent the vacuum ultraviolet light from leaking and adversely affecting the human body, the ozone generator is provided with vacuum ultraviolet light leakage prevention means such as an opaque cover.

  In the sixth invention, a deep ultraviolet light emitting or vacuum ultraviolet light LED having a central wavelength in a wavelength range of 240 nm to 200 nm, a microplasma excited far ultraviolet light emitting element or a field emission lamp FEL, the deep ultraviolet light emitting LED, Deep ultraviolet light emitting LED, microplasma excited deep ultraviolet light emitting element or field emission lamp FEL having a condensing lens for converging light emitted from plasma excited deep ultraviolet light emitting element or field emission lamp FEL, deep ultraviolet light emitting LED, microplasma excitation A deep ultraviolet light emitting element or a field emission lamp FEL is disposed in a sleeve as a first light source, and a second light source is generated by reflection by a concave mirror irradiated with the light source. The first and second light sources Condensates deep ultraviolet light or vacuum ultraviolet light irradiated by The ozone generating device that constitutes a part of the pipe that ozonizes oxygen molecules in the air or oxygen gas in the vicinity of the focal point of the lens and the concave mirror, and the generated ozone-containing air or oxygen gas is produced by the suction means having the suction means. The ozone-containing gas-liquid two-phase flow that is sucked and generated by the nanobubble generator is discharged into the liquid of the functional liquid storage tank to generate ozone microbubbles and nanobubbles, and has sterilization, washing, and bioactive functions A functional fluid production apparatus for generating a functional fluid is configured.

  In the seventh invention, a micro-nano bubble generating device sucks ozone-containing air or oxygen gas to produce a functional liquid, and a circulation pump circulates the liquid to be treated in the functional liquid storage tank to irradiate ultraviolet rays and A functional liquid production apparatus having a piping system that sterilizes and decomposes contaminants with a photocatalyst, and in an ozone generation unit that converts oxygen in an air or oxygen gas stream into ozone by vacuum ultraviolet rays, is disposed in the ozone generation unit The irradiation light irradiated by the vacuum ultraviolet light projecting means is branched and received in two directions by the branch light receiving means, and a deep ultraviolet light emitting fluorescent powder that emits deep ultraviolet light having a bactericidal effect is applied to the branch light receiving means. In the sterilizing and decomposing means section, deep ultraviolet rays radiated from the ultraviolet light emitting fluorescent powder coating wall are irradiated to the liquid flowing down the light-transmitting liquid flow path to sterilize the cells and decompose the pollutants. , By irradiating the photocatalyst carrying member was immersed in the liquid to sterilize the bacteria to decompose the contaminants. Ozone-containing air or oxygen gas generated by the ozone generator is sucked into the functional liquid storage tank, and an ozone-containing gas-liquid two-phase flow is discharged into the functional liquid to generate ozone micro / nano bubbles. The liquid in the functional liquid storage tank is circulated by the micro / nano bubble generator. Further, a circulating pump for sucking and discharging the liquid flowing down the sterilizing and decomposing means is provided, and a functional liquid manufacturing apparatus for generating a functional liquid having sterilizing, cleaning, and physiologically active functions is provided.

  Further, in the eighth invention, in the seafood / seaweed aquaculture farm that produces a functional liquid having sterilization, washing, and physiologically active functions, as a means for propelling floating bodies such as small boats, rubber boats, etc. Acts as an outboard motor that propells the gas-liquid two-phase flow by ejecting the gas-liquid two-phase flow outlet toward the horizontal rear. As the rudder means, a driver manual operation or a remote control operation is selected. Engine drive, AC power supply motor drive, or the like is selected as the drive source of the circulation pump that supplies the pressurized liquid to the micro / nano bubble generation device. An ozone generator that supplies ozone-containing air or oxygen gas to the micro / nano bubble generator is also configured as necessary.

  In the ninth invention, the pressure pump discharge water of the micro / nano bubble generating device used in the functional liquid production apparatus has velocity head energy, pressure head energy and position head energy, but the pressure pump discharge port If the loss of the location head energy is ignored before it is discharged into the liquid, the head energy that is not effectively used for micro / nano bubble generation is the friction loss head energy. However, since the friction loss head energy is proportional to the square of the speed, in order to effectively use the head energy held by the pressurized pump discharge water for the generation of micro / nano bubbles, pipes and micro / nano bubbles are generated. It is effective to reduce the flow velocity in the apparatus as much as possible. Therefore, it is effective to shorten the piping distance from the pressure pump to the micro / nano bubble generator as much as possible, and it is preferable that the pressure pump is a submersible pump type, but loss due to extension of the transmission line distance is also taken into consideration Therefore, it is generally impossible to determine that the submersible pump type is optimal. It is effective to make the pipe diameter as large as possible in consideration of economy and the like. In the structure of the micro / nano bubble generator, the cross-sectional area to the swirl flow chamber inlet is increased to reduce the flow velocity, convert velocity head energy into pressure energy, and increase the velocity of water with increased pressure head energy. By means of jetting in the direction along the circular inner wall of the swirling flow chamber, a high-speed swirling flow is generated in the swirling flow chamber, and the action contributing to the generation of a large amount of micro / nano bubbles appears. The cross-sectional area of the swirl flow chamber has a conical structure in which the gas suction port end is maximized and the gas-liquid two-phase flow discharge port end is minimized. At the same time, the gas-liquid two-phase flow discharge velocity becomes high, and when it is ejected into the liquid in the surrounding environment, the flow velocity is drastically reduced. In addition, in order to facilitate manufacture and maintenance, as much as possible, except for the cylindrical part that constitutes the swirling flow chamber to be pressed, it is structured to use standard products, and can be easily disassembled and assembled in maintenance. Structure.

  In a tenth aspect of the invention, a 1 MHz to 13.56 MHz medium frequency AC power source is supplied to a solenoid coil that is wound around the ozone generator or the sleeve of the ozone generator, and the solenoid coil Generating an intermediate frequency magnetic field and inducing an intermediate frequency electric field, the intermediate frequency electric field acting on a gas flowing down in the sleeve, exciting oxygen molecules contained in the gas, and disposed in the sleeve The deep ultraviolet light emitting LED excitation The light emitted from the deep ultraviolet light emitting element is condensed by a condensing lens and cooperated with the excitation by pinpoint irradiation of molecules of the target gas to promote the ozonization of oxygen molecules.

  Further, the solenoid coil generates a medium frequency magnetic field at the inlet and the inside of the sleeve, induces oxygen molecules as a paramagnetic substance into the sleeve, and eliminates nitrogen molecules as diamagnetism. Therefore, when the gas flowing into the sleeve is air in the atmosphere, the oxygen gas content in the air is enriched.

  In the eleventh aspect of the invention, a hollow that selectively permeates air sucked from an inlet into an ozone generator or an ozone generator sleeve provided with an ultraviolet light emitting element such as a deep ultraviolet light emitting LED. Oxygen is permeated and introduced into oxygen from the oxygen hatching means provided with the thread membrane to ozonize the oxygen molecules. Air in the atmosphere is sucked into the hollow fiber membrane through an air suction pipe, but air near the dew point is cooled by a cooling means to generate condensed water, and the condensed water is discharged from the air suction pipe with a drain discharger. In this way, it is in a dry air state. Further, by heating the dry air with a heating means having an auxiliary heating source, no condensation occurs even if air comes into contact with the hollow fiber membrane. Between the cooling means and the heating means, a heat transfer working fluid is sealed and a connection means for connecting and communicating is arranged to constitute the heat transfer means. When condensed water is generated, moisture permeates through the hollow fiber membrane earlier than oxygen, so that the permeation of oxygen is inhibited and the oxygen permeation rate decreases. The suction pipe disposed between the ozone generator and the micro / nano bubble generator is added with the suction force of the suction means additionally inserted and the negative pressure suction force of the micro / nano bubble generator to add the hollow Acts as a driving force for selectively sucking and permeating oxygen from the inside of the yarn membrane to the outside. Nitrogen that cannot be permeated is released to the atmosphere by a nitrogen scavenging means, and fresh air in the atmosphere is introduced into the hollow fiber membrane. To replenish the oxygen source.

  In the twelfth aspect of the invention, the transmission distance of ultraviolet light or visible light is made as small as possible in order to increase the ratio of irradiation to the object to be processed without absorbing the ultraviolet light or visible light by the transmission medium. Therefore, even if the treatment method of the liquid to be treated is the flow method or the retention method, it is a means for reducing the depth or thickness of the liquid to be treated. Further, the flow path adjusting means is provided with a plurality of overflow weirs with V notches, and UV or visible light responsive photocatalyst is applied and fixed to the plurality of overflow notches with V notches. An inorganic porous plate having an ultraviolet or visible light responsive photocatalyst applied and fixed to the side wall of the passage and an ultraviolet or visible light responsive photocatalyst applied and fixed is arranged upright on the bottom surface of the processing target liquid flow path, and the processing target liquid And a deep ultraviolet or visible light emitting LED irradiation means for irradiating the ultraviolet or visible light responsive photocatalyst. The deep ultraviolet or visible light emitting LED and a visible light emitting LED pilot lamp electrically connected in series are arranged to serve as blinking confirmation means for the ultraviolet or visible light emitting LED. When the ultraviolet light or visible light is irradiated with ultraviolet light or visible light, it is photoexcited to generate OH radicals, etc., and oxidatively decompose microorganisms or harmful organic substances, and the photocatalyst has super water-repellent performance. Is provided to facilitate the flow rate adjustment. The liquid to be treated, which has been liquefied, is stored in the processing liquid storage tank in a light-shielded state, supplied with dissolved oxygen by the aeration means, and stored as a good supply liquid supplied with sterilization treatment and dissolved oxygen. In addition, the treatment liquid stored in the treatment liquid storage tank is irradiated with natural light in order to prevent the treatment liquid in the sterilized treatment liquid storage tank from being irradiated with natural light and the microorganisms recovering light. A means for preventing this is provided.

  Further, in the thirteenth aspect of the invention, in order to flow down the liquid to be treated by the flow rate adjusting means to flow down and to divert in the lower bottom direction, the porous body is divided into holes at the bottom of the lower diverting means. Is disposed through. The upper end portion of the porous body is submerged under the water surface of the lower flow dividing means and covered with a perforated cap, and the liquid to be treated flows down with the flow rate adjusted, and the porous body at a lower portion than the tank bottom of the lower flow dividing means. Are exposed to the atmosphere, and an ultraviolet-responsive or visible-light-responsive photocatalyst is applied and fixed to the porous body. The porous body is coated and fixed with an ultraviolet-responsive or visible light-responsive photocatalyst, so when irradiated with deep ultraviolet or visible light irradiation means, the photocatalyst is photoexcited to become superhydrophilic, and the film thickness of the falling liquid is reduced. It is adjusted as thin as possible. When ultraviolet light or natural light is irradiated to the flow-down liquid adjusted to be extremely thin, the ultraviolet light contained in the ultraviolet light or natural light acts on the diffusion of microorganisms to sterilize the microorganisms and irradiates the ultraviolet light or visible light responsive photocatalyst, The photocatalyst is photoexcited to generate OH radicals and the like, and oxidatively decompose microorganisms or harmful organic substances. The functionalized liquid to be processed is stored in a processing liquid storage tank in a temporary light-shielded state because the microorganisms recover the light when irradiated with natural light. The deep ultraviolet or visible light irradiating means and a visible light emitting LED pilot lamp electrically connected in series are provided as blinking confirmation means for the ultraviolet or visible light emitting LED.

  In the fourteenth aspect of the present invention, an ultraviolet responsive photocatalyst or a visible light responsive photocatalyst is applied to the inorganic porous plate upright on the side wall and the bottom surface of the flow path of the liquid to be treated for the post-treatment of the flow rate adjusting means The coated inorganic inorganic porous plate is irradiated with ultraviolet rays using a deep ultraviolet light emitting LED or with a visible light emitting LED. A visible light emitting LED pilot lamp for confirming blinking of the ultraviolet light emitting LED or visible light emitting LED is disposed and disposed in series with the ultraviolet light emitting LED or visible light emitting LED. The cylindrical or hollow fiber-like oxygen permeable porous membrane is immersed in the treatment liquid sterilized by ultraviolet sterilization / ultraviolet-responsive photocatalyst or natural light-containing ultraviolet / visible light responsive photocatalyst and the upper end of the cylindrical or hollow fiber-like oxygen permeable porous membrane is immersed therein And a means for supplying dissolved oxygen to the liquid to be processed by arranging the lower part exposed to the atmosphere and penetrating through a hole cut in the bottom plate of the liquid liquid to be processed. The cylindrical or hollow fiber oxygen permeable porous membrane in the treatment target liquid is covered with an upper end opening cap that adjusts the amount of the treatment target liquid flowing into the upper end port, and the flow rate is adjusted. The cylindrical or hollow fiber-like oxygen permeable porous membrane is filled with the liquid to be treated, and a downward flow is formed by siphon action. Since the outside of the cylindrical or hollow fiber-like oxygen permeable porous membrane is exposed to the atmosphere, the oxygen gas in the atmosphere diffuses into the liquid to be treated by a concentration gradient from the outside to the inside according to Henry's law. . If there is no flow in which the liquid to be treated in the cylindrical or hollow fiber oxygen-permeable porous membrane stays, the diffusion movement from the atmosphere to the stationary liquid to be treated is attenuated, but the liquid flow is formed. According to Bernoulli's theorem, the static pressure of the liquid to be treated in the cylindrical or hollow fiber-shaped oxygen permeable porous membrane is lower than in the atmosphere. Therefore, according to Henry's law, the dissolving action of oxygen gas increases and dissolved oxygen The liquid to be treated having a low concentration is replaced, and the action of increasing the amount of dissolved oxygen works.

  In the fifteenth aspect of the invention, an ultraviolet responsive photocatalyst or a visible light responsive photocatalyst is applied to the inorganic porous plate standing upright on the side wall and the bottom surface of the flow path of the liquid to be treated for the post-treatment of the flow rate adjusting means. The coated porous inorganic plate is irradiated with ultraviolet light by ultraviolet light emitting means or irradiated with natural light, and treated with a liquid to be treated which has been subjected to ultraviolet sterilization / UV-responsive photocatalyst sterilization or natural light-containing UV / visible light-responsive photocatalyst sterilization. A treatment in which the liquid to be treated flows down into a hollow or hollow fiber-like oxygen permeable porous membrane and the dissolved oxygen is supplied by exposing the outside of the hollow fiber-like oxygen permeable porous membrane to the atmosphere to be sterilized and supplied with dissolved oxygen Use liquid. A culture solution produced by adding or not adding a fertilizer component to the treatment solution is disposed below the elevated cultivation bed and is biodegradable in the form of plant-derived pellets, granules or powders in the culture soil. It is applied to a planter containing mixed culture soil containing culture soil containing plastic in an arbitrary mixing ratio. In addition, as a planter in which the mixed culture soil in which the biodegradable plastic derived from the plant is mixed with the culture soil in an arbitrary mixing ratio is added to the culture soil, the planter is used for home use. You can also

  In the sixteenth invention, in order to purify the aqueous solution containing pathogenic bacteria or polluting organic substances, the living environment of the organism is determined by a microfiltration membrane or an ultrafiltration membrane having a pore diameter of 0.1 μm or more. Most microorganisms and coarse organic substances are filtered and separated from the liquid to be treated, and viruses and harmful organic substances remaining in the liquid to be treated are sterilized and decomposed by ultraviolet rays and / or photocatalytic treatment means, Or in order to supply the dissolved oxygen necessary for the growth of fish and shellfish, aeration treatment is performed by aeration means. However, there is no problem even if the aeration means is operated by the aeration means prior to the sterilization and decomposition treatment by the ultraviolet and / or photocatalyst processing means. The ultraviolet light may be natural light-containing ultraviolet light or deep ultraviolet light emitted from a deep ultraviolet light emitting LED, and there is no problem.

  Since the present invention is configured as described above, the following effects can be obtained.

In the first invention, since the deep ultraviolet light emitting LED, the microplasma excited deep ultraviolet light emitting element or the field emission lamp FEL is disposed in the ozone generating device constituting a part of the gas suction pipe of the ozone micro / nano bubble generating device. The effect is extremely safe.

  Further, the light quantum energy per unit area of the photon can be increased by converging the light emitted from the deep ultraviolet light emitting LED, microplasma excited deep ultraviolet light emitting element, or field emission lamp FEL with a condenser lens. This is dangerous to the human body, especially the eyes, but since the deep ultraviolet LED is housed in a sleeve and used, the deep ultraviolet light emitting LED or the microplasma excited deep ultraviolet light emitting element is not exposed to the deep ultraviolet light without exposure. When used as a light-emitting device, it has an extremely safe effect.

  In addition, when a deep ultraviolet light emitting LED, a microplasma excited deep ultraviolet light emitting element or a field emission lamp FEL having a dominant wavelength in a wavelength region of 242 nm or less is used, an effect of increasing ozone generation efficiency is obtained.

  In addition, oxygen remains after sterilization with ozone liquid, and no pollutants or harmful substances are produced. Therefore, there is an effect that no pollution load to the environment is discharged.

  In addition, the ultraviolet ray generation lamp used in the conventional ozone generator has encapsulated mercury in a quartz glass tube and required high power. Since ozone can be generated by FEL, an ozone generator with low output can be obtained, which has the effect of saving energy and reducing cost.

  In addition, when micro / nano bubbles are generated in a liquid containing an electrolyte, free radicals are generated at the time of crushing and the nano bubbles are stable for a long time. There is an effect.

  Moreover, in strawberry cultivation etc., the part directly irradiated with ultraviolet rays is sterilized, and the shaded part is not sterilized.

  In addition, the deep UV light emitting element, the microplasma excited deep ultraviolet light emitting element or the field emission lamp FEL having a center wavelength near 200 nm has a small effect on the ozonization of oxygen molecules, but the light is condensed by a condenser lens. However, by irradiating oxygen molecules at a pinpoint, the ozonization action per unit irradiation area becomes stronger. Therefore, in the past, deep ultraviolet light emitting LEDs, microplasma excited deep ultraviolet which could not be used for ozonization of oxygen molecules. The light emitting element or the field emission lamp FEL can be used for the ozonization of oxygen molecules.

  Moreover, in 2nd invention, an ozone density | concentration raises and the effect which raises a bactericidal effect by using two or more deep ultraviolet light emission LED or microplasma excitation deep ultraviolet light emitting element as the pipe | tube arrange | positioned in series. Play.

  Moreover, since two or more sets of tubes are arranged in parallel with each other, the amount of ozone can be increased, which has the effect of increasing the sterilization treatment capacity.

  In the third aspect of the invention, the gas suction branch of the micro / nano bubble generator is provided with an atmosphere, oxygen gas and ozone gas suction branch, and each branch is equipped with an opening / closing valve, thereby selecting the air suction branch. When the open / close valve is opened and air micro / nano bubble water is generated, the self-pressurization effect of the air micro bubble generates free radicals that oxidize and decompose chemical substances such as pollutants and floats in the liquid for a long time. Since the nanobubbles that stay are generated, the functional liquid having the sterilizing function, cleaning function and physiological activity function is selected, the oxygen gas branch pipe is selected, the on-off valve is opened, and the oxygen micro / nanobubble liquid is generated. The cleaning function is the same as that of the air micro / nano bubble liquid, but the functional liquid is extremely superior in physiological activity function. When the ozone micro / nano bubble liquid is opened, the cleaning function and the physiologically active function are the same, but it can be a functional liquid that is extremely excellent in the sterilization function. Judging the degree of required performance, there is an effect of flexible system operation.

  In the fourth invention, the sterilization target liquid is sucked with a micro / nano bubble generator by ozone generated by an inexpensive and energy-saving deep ultraviolet light emitting LED, a microplasma excited deep ultraviolet light emitting element or a field emission lamp FEL. As a pretreatment to sterilize and wash with the generated ozone micro / nano bubble liquid, sterilization and removal of bacteria attached to the object to be cleaned or organic matter attached to the surface layer of the spore using an ultrasonic vibration device and a sterilizer with ultraviolet / photocatalyst Therefore, it is easy to sterilize and control gram-positive bacteria such as Staphylococcus aureus and spore bacteria, which are resistant only with ozone liquid, with ozone micro / nano bubble liquid, and have a strong bactericidal effect against a wide range of bacteria, etc. Play. Furthermore, the ultraviolet sterilization function and the photocatalyst sterilization function in the ultraviolet / photocatalyst sterilization apparatus have an energy saving effect caused by the action of photon energy emitted from the same deep ultraviolet light emitting LED or microplasma excited deep ultraviolet light emitting element.

  In addition, microbubbles generated by the micro / nanobubble generator, nanobubbles and free radicals are increased, and the cleaning function and physiological activity function are increased.

  In the fifth invention, an LED, a field emission lamp or an excimer lamp is provided in an ozone generator provided with a vacuum ultraviolet light leakage prevention means, and the LED, the field emission lamp or the excimer lamp is projected. Vacuum ultraviolet light of 200 nm or less from the window is sucked into the micro / nano bubble generating device of the first invention, etc., flows from the air suction port, and irradiates with oxygen molecules in the air flowing down the inside of the ozone generating device. The oxygen molecules are ozonized. The vacuum ultraviolet light of 200 nm or less is absorbed somewhat in the air, so that it is somewhat diminished by passing through the air, but most of it is transmitted and the ozone generator facing the projection window When irradiated with a vacuum ultraviolet light emitting phosphor applied to the inner wall of the substrate or the substrate fixedly disposed on the inner wall, vacuum ultraviolet light is generated, and the vacuum ultraviolet light ozonizes oxygen molecules in the air or oxygen gas. Therefore, oxygen molecules are ozonized with a light source such as an LED, a field emission lamp or an excimer lamp, and a vacuum ultraviolet light emitting phosphor is excited with the afterglow of the light source to ozonize oxygen molecules different from the oxygen molecules. Therefore, the apparatus having the same outer shape has an effect of increasing the ozone generation efficiency.

  In the sixth invention, the photon energy obtained by increasing the density of light emitted from the deep ultraviolet light emitting LED, the microplasma excited deep ultraviolet light emitting element or the field emission lamp FEL through the condenser lens in the vicinity of the focal point is converted into oxygen molecules. Irradiated at a pinpoint, ozonized oxygen molecules and deep ultraviolet light diffused again through the focal point of the condenser lens, and deep ultraviolet light reflected by a concave mirror fixed to the wall surface of the sleeve is converted into oxygen molecules. Irradiation is performed to ozonize oxygen molecules, so that the same light source can be used to ozonize oxygen molecules to save energy and improve the ozone concentration.

  Further, in the seventh invention, vacuum ultraviolet light generated by the vacuum ultraviolet light emitting means is irradiated with oxygen molecules in the air or oxygen gas to be ozonized, and the vacuum ultraviolet light that has passed through the air or oxygen gas is converted into two directions. The deep ultraviolet light emitting fluorescent powder coating wall coated with the deep ultraviolet light emitting fluorescent powder that receives the two-way branched irradiation ultraviolet light radiates deep ultraviolet light and irradiates the liquid to be sterilized and decomposed. Irradiate the photocatalyst carrier soaked in it to sterilize the cells and decompose the pollutants, so the vacuum ultraviolet rays irradiated by the vacuum ultraviolet light emitting means can be used for ozone liquid production, sterilization of the cells and decomposition of contaminants Energy saving and economic effect that can be provided.

  Moreover, in the eighth invention, by disposing the gas-liquid two-phase flow in the horizontal rearward direction on a floating body such as a small boat, sterilizing pathogenic bacteria while supplying dissolved oxygen to the target water area, The work to activate the physiology has the effect of achieving a wide range of energy savings.

  In the ninth invention, in the micro / nano bubble generator, the flow velocity of the pressure pump discharge liquid is reduced to reduce the flow velocity other than the swirl flow chamber that contributes to the generation of a large amount of micro / nano bubbles. By using a part of the pressure head energy as the pressure head energy, the friction head energy can be reduced and the speed head head energy contributing to the generation of micro / nano bubbles in the swirling flow chamber can be increased. The swirl flow chamber has a structure in which the conical cylinder shrinks from the gas inlet toward the gas-liquid two-phase flow outlet, thereby increasing the gas-liquid two-phase liquid discharge speed and surrounding the gas-liquid two-phase flow. As a result of drastically decreasing the speed when discharged into the water area, there is an effect of increasing the formation of microbubbles into nanobubbles by increasing the speed difference before and after discharge. Further, as much as possible, the structure is made of standard members and has a structure that is easy to assemble and disassemble, thereby producing an effect of increasing energy generation efficiency and reducing production costs and maintenance costs. Furthermore, since most of the parts and members can be procured as pipe parts, which are mass-produced commercial products, the manufacturing cost and the parts replacement cost are reduced.

  In the tenth invention, even if oxygen molecules are irradiated with the deep ultraviolet light emitting LED irradiating means, the photon energy is weak in order to ozonize the oxygen molecules. By applying high-frequency AC power of 10 MHz to 30 MHz to the solenoid coil disposed on the outer periphery of the sleeve where the oxygen molecules in the photoexcitation energy state are flowing down, the oxygen molecules close to photoexcitation are further applied. By high frequency excitation, there is an effect that a large amount of oxygen molecules can be ozonized.

  In the eleventh aspect of the invention, the photon energy of the deep ultraviolet light emitting LED, microplasma excited deep ultraviolet light emitting element or field emission lamp FEL having a central wavelength in the wavelength range of 240 nm to 200 nm is the energy for ozoneizing oxygen molecules. Although it is weak, it does not supply strong harmonic AC power that generates plasma, but it is a small, low-power, medium-frequency AC power supply that acts on oxygen molecules that are close to the excitation level to generate oxygen ions. And the oxygen molecules are ozonized. Furthermore, the free electrons that have become abundant act on oxygen molecules, and have the effect of promoting dissociation and ozonization of oxygen molecules. Furthermore, paramagnetic air oxygen molecules are attracted by alternating magnetic field lines and diamagnetic nitrogen molecules are eliminated, and oxygen-enriched air is attracted to the micro / nano bubble generator, which has a strong bactericidal action, cleaning action and physiological activity action. It produces the effect of generating ozone micro / nano bubbles.

  In the twelfth aspect of the invention, the photocatalyst is applied and fixed to the flow path of the water to be treated and the photocatalyst-coated fixed porous body, so that the distance of the medium through which ultraviolet rays or natural light-containing ultraviolet rays pass and the arrival of the photocatalyst are reached. Since the distance can be reduced, the effect of increasing UV sterilization / photocatalytic sterilization is achieved.

  In the thirteenth invention, when the light-transmitting porous plate on which the photocatalyst is applied and fixed is suspended downward and the liquid to be treated is flown down and irradiated with ultraviolet rays or ultraviolet rays containing natural light, the light-transmitting porous plates Since the plate becomes superhydrophilic, the wettability with respect to the aqueous solution is remarkably improved, and the attached flow thickness of the liquid to be treated flowing down the light transmission type porous plate can be finely adjusted. Since the photon energy of the transmitted ultraviolet light is difficult to attenuate, there is an effect that the bactericidal effect is not reduced.

  In the fourteenth aspect of the invention, a cylindrical or hollow fiber-shaped oxygen gas permeable membrane is vertically arranged so that a siphon action is generated. And a negative pressure with respect to the atmospheric pressure is generated, so that it acts as a suction force from the atmosphere outside the oxygen gas permeable membrane to the inside. While becoming a new liquid to be treated, the oxygen gas differential pressure between the atmosphere and the liquid to be treated is always maintained at the maximum, gas diffusion and oxygen solubility in the interior are always maintained at the maximum, and the dissolved oxygen dissolution amount is increased The energy saving effect of non-powered oxygen gas supply is achieved.

  In the fifteenth invention, since biodegradable plastic is used as culture soil, it becomes a planter with a small weight of culture soil, and can be operated by a small amount of manpower. There is an effect that does not have a hard time.

  In the sixteenth invention, almost all microorganisms and coarse solid organic matter that cause diseases can be separated by membrane filtration in hydroponic cultivation of crops or in the cultivation of seafood and algae. In the ultraviolet sterilization and the photocatalytic sterilization treatment, the photon energy of the ultraviolet light that passes through the liquid medium to be treated is not easily attenuated.

FIG. 1 is a schematic explanatory longitudinal sectional view according to the first invention.

FIG. 2 is a schematic longitudinal sectional view of an ozone generator according to the first invention.

FIG. 3 is a schematic explanatory longitudinal sectional view according to the second invention.

FIG. 4 is a schematic longitudinal sectional view of a first embodiment relating to hydroponics of the third invention.

FIG. 5 is a schematic longitudinal sectional view of a second embodiment relating to nori culture of the third invention.

FIG. 6 is a schematic explanatory longitudinal sectional view according to the fourth invention.

FIG. 7 relates to the fourth invention, and FIG. 6A is a partially enlarged longitudinal sectional view of the ultraviolet / photocatalyst combined sterilization apparatus in FIG. 6, and FIG. 7B is a schematic explanatory view AA in FIG. It is sectional drawing.

FIG. 8 is a schematic explanatory longitudinal sectional view according to the fifth invention.

FIG. 9 is a schematic explanatory longitudinal sectional view according to the sixth invention.

10A and 10B relate to the seventh invention, wherein FIG. 10A is a schematic sectional plan view, and FIG. 10B is a schematic sectional BB longitudinal sectional view in FIG.

FIG. 11 is related to the eighth invention, (a) is a schematic explanatory longitudinal sectional view, and (b) is a schematic explanatory elevational view in (a).

FIG. 12 is a schematic longitudinal sectional view according to the first embodiment of the ninth invention. (B) is a schematic explanatory CC cross-sectional view in (a).

FIG. 13B is a schematic cross-sectional view along DD line in FIG. 13A according to the second embodiment of the ninth invention.

FIG. 14 relates to the tenth invention, (a) is a schematic explanatory side view for sucking air in the atmosphere, and (b) is a schematic explanatory partial flow chart for sucking oxygen from an oxygen cylinder.

FIG. 15 relates to the eleventh invention, and is a schematic explanatory flow diagram for sucking oxygen-enriched air to the micro / nano bubble generating device through the ozone generating device.

FIG. 16 is a schematic longitudinal cross-sectional view according to the first embodiment of the twelfth aspect of the invention, wherein (a) is a schematic longitudinal cross-sectional view illustrating an ultraviolet sterilization / photocatalytic waste liquid treatment apparatus using an underwater ultraviolet light emitting LED. (B) is a schematic cross-sectional plan view of the EE view in (a), (c) is a front view of the FF view and GG in (b), and (d) These are the schematic explanation expansion longitudinal cross-sectional views of the watertight ultraviolet lamp as described in (a) and (b).

FIG. 17 is a schematic longitudinal cross-sectional view illustrating a natural light-containing ultraviolet sterilization / visible response photocatalyst sterilization apparatus using sunlight, according to a second embodiment of the twelfth invention. It is a schematic explanatory plan sectional view of HH view in a), (c) is a schematic front view of II view and JJ view in (b).

FIG. 18 relates to the first embodiment of the thirteenth invention, wherein (a) shows an ultraviolet sterilization / photocatalyst waste liquid treatment apparatus using a watertight deep UV light emitting LED disposed between a plurality of light transmissive porous ceramic plates. BRIEF DESCRIPTION OF THE DRAWINGS It is the schematic explanatory longitudinal cross-sectional view illustrated, (b) is a schematic explanatory plan sectional view of the KK view in (a), (c) is a schematic explanatory front view of the LL view in (b). .

FIG. 19 shows a second embodiment of the thirteenth aspect of the invention. FIG. 19 (a) shows a natural light-containing ultraviolet sterilization / visible light responsive photocatalyst sterilization apparatus using sunlight and a visible light emitting LED light source with a liquid guideline system. FIG. 2B is a schematic sectional plan view of the MM view in (a), and FIG. 2C is a schematic front view of the NN view in FIG.

FIG. 20 is a schematic longitudinal cross-sectional view of supplying dissolved oxygen through a cylindrical oxygen gas permeable membrane to a sterilization treatment liquid in a natural light-containing ultraviolet sterilization / visible light responsive photocatalyst sterilization tank according to the fourteenth aspect of the invention.

FIG. 21 shows a biodegradation of a culture solution prepared by supplying dissolved oxygen to a sterilization treatment liquid in a natural light-containing ultraviolet sterilization / visible light responsive photocatalyst sterilization tank according to the fifteenth invention using a cylindrical oxygen gas permeable membrane. It is a schematic explanatory longitudinal cross-sectional view applied to the planter containing a mixed plastic particle mixed culture soil.

FIG. 22 is a schematic longitudinal cross-sectional view of a sixteenth aspect of the present invention, in which a liquid to be treated is filtered with a microfiltration membrane, sterilized with an ultraviolet light emitting LED and a photocatalyst, and the processed liquid is aerated. .

  Embodiments of the present invention will be described below with reference to the drawings. However, the Example shown below illustrates the functional water manufacturing apparatus for actualizing the technical idea of this invention, and this invention does not limit a functional liquid manufacturing apparatus to the following. Furthermore, this specification does not limit the members described in the claims to the members of the examples.

  FIG. 1 and FIG. 2 are schematic explanatory longitudinal sectional views according to the first embodiment of the first invention. This embodiment generates ozone microbubbles and has a function of sterilization, washing, and physiological activity. The present invention relates to a functional liquid manufacturing apparatus 1 that generates a liquid. A deep ultraviolet light emitting LED 2 is provided as a light source for generating deep ultraviolet light. The deep ultraviolet light emitting LED 2 includes a light emitting chip 3 that emits deep ultraviolet light having a center wavelength in a wavelength region of 220 nm. The deep ultraviolet light emitting LED 2 includes a condenser lens 4 that converges light emitted from the light emitting chip 3. The deep ultraviolet light emitting LED 2 converges the light emitted from the light emitting chip 3 by the condenser lens 4 and irradiates oxygen molecules contained in the air passing through the short distance forward of the deep ultraviolet light emitting LED 2 at a pinpoint. Ozonize molecules. The far-ultraviolet LED 2 is fixed to the substrate 5 and accommodated in a fluororesin sleeve 6, and is an ozone generator 8 constituting a part of the gas suction pipe 7. Air in the atmosphere flows from the air inlet 6 a of the sleeve 6 and flows through the sleeve 6. The ozone-containing air that has flowed through the sleeve 6 is sucked into the gas suction port 10a of the swirling flow type micro / nano bubble generator 10 immersed in the liquid of the functional liquid storage tank 9 via the gas suction pipe 7. A gas-liquid two-phase flow is discharged into the functional liquid storage tank 9 to generate ozone micro / nano bubbles, and the liquid in the functional liquid storage tank 9 is functionalized. In the swirling flow type micro / nano bubble generating device 10, a high-pressure liquid is introduced in a discharge-side pipe 11 a of a circulation pump 11 to generate a swirling flow and to generate a negative pressure. Air or ozone-containing air is sucked into the flow-type micro / nano bubble generator 10. The air micro / nano bubble has a cleaning function, a sterilization function, and a physiological activity function, and the ozone micro / nano bubble liquid has a physiological activity function similar to the air micro / nano bubble liquid, It has a strong cleaning function and sterilization function. Therefore, in order to select the air micro / nano bubble liquid or the ozone micro / nano bubble liquid according to the situation, the air suction branch pipe 7a and the discharge side pipe 7b of the sleeve 6 are connected to the on-off valve 12a and 12b is provided, and air is sucked from the atmosphere and ozone is sucked from the ozone generator 8, and air or ozone is selected and supplied. In FIG. 3, the position where the two lines intersect represents the focal point of the condenser lens, imitating the locus of light with a dotted line, but the light trace at the focal point of the condenser lens 4 is A specific spread (area) is shown according to the characteristics of the far-ultraviolet LED 2 and the condenser lens 4. At the focal point of the condenser lens 4, the photon energy (energy density) per unit area is the largest, and the oxygen molecules in the vicinity of the focal point are irradiated to ozonize the oxygen molecules. In this embodiment, the swirling flow type micro / nano bubble generating device 10 is used, but a micro / nano bubble generating device such as a venturi type, an orifice type, a pressure type, or a pressure type may be used, and is not limited at all.

  In general, a deep ultraviolet light emitting LED or a microplasma excited deep ultraviolet light emitting element is configured with a spectrum of a plurality of wavelength regions, and therefore, a light beam having an area specific to the light emitting element is shown at the focal point of the condenser lens 4. Therefore, in the condensing by the condensing lens 4, if the photon energy density of 242 nm or less is larger than the photon energy density of the main wavelength, the selection should be focused on the deep ultraviolet region of 242 nm or less.

  FIG. 3 is a longitudinal cross-sectional view schematically illustrating the first embodiment of the second invention. Ozone generation in which a deep ultraviolet light emitting LED 2 is accommodated in a sleeve 6 and constitutes a part of a gas suction pipe 7 is shown. Two sets of apparatuses 8 connected in series are arranged in parallel to increase the ozone concentration and the processing capacity.

  FIG. 4 is a schematic explanatory view according to the first embodiment of the third invention, which is a schematic longitudinal sectional view of an embodiment applied to the field of hydroponics, and shows a swirling flow type micro / nano bubble generator 10A. In order to selectively open and close by judging whether it is air, oxygen, ozone-containing air or ozone-containing oxygen according to the strength of physiological activity and sterilization function required for the functional liquid as the gas sucked into the gas suction port 10Aa On-off valves 12a, 12b, 12c, and 12d are disposed in the atmospheric suction branch 7a, the ozone-containing air suction branch 7b, the ozone-containing oxygen suction branch 7c, and the oxygen gas suction branch 7d, respectively. Although an oxygen gas cylinder 13 is provided as an oxygen gas supply source to the ozone-containing oxygen suction branch 7c and the oxygen gas suction branch 7d, an oxygen hatching apparatus can be used as an alternative to the oxygen gas cylinder 13. When the functional liquid stored in the functional liquid storage tank 9A is used for sterilization of the exposed part of the cultivation target species and the cultivation room space, the swirling flow type micro / nano bubble generating apparatus is passed through the ozone generator 8. The air is sucked into the gas suction port 10Aa of 10A to generate ozone micro / nano bubble liquid, the on-off valve 15Aa arranged in the discharge side pipe 15A of the submersible pump 14A is opened, and the spray liquid is supplied from the spray nozzle 16A. When sprayed and sterilized, and the harvested product is washed and sterilized, the on-off valve 15Ab is opened and the spray nozzle 16B is used for washing and sterilization. In the cultivation of the cultivation target species by the cultivation bed 17 to which the hydroponics method is applied, the cultivation is performed by the discharge side pipe 15B in which the fertilizer solution stored in the functional liquid storage tank 9B is disposed on the discharge side of the submersible pump 14B. The solution is fed to the bed 17 and cultivated. The fertilizer solution in the cultivation bed 17 is sequentially pushed out by the extrusion flow and flows out, and is transferred to the functional liquid storage tank 9B through the return pipe 18 and circulated. When emphasizing the sterilization of pathogenic bacteria, the physiological activity and the strength of the sterilizing function required for the functional liquid as gas to be sucked into the gas suction port 10Ba of the swirling flow type micro / nano bubble generating device 10B through the ozone generator 8 Depending on the air, oxygen, ozone-containing air or ozone-containing oxygen is determined, and the same as the gas sucked into the gas suction port 10Aa of the swirl type micro / nano bubble generating device 10A in the functional liquid storage tank 9A The on-off valves 12a, 12b, 12c and 12d are opened and closed.

  FIG. 5 is a schematic explanatory view according to the first embodiment of the third invention, and is a schematic longitudinal sectional view of the embodiment applied to the field of seaweed cultivation, and is selected similarly to the third embodiment of FIG. In particular, air, ozone-containing air, ozone-containing oxygen gas and oxygen gas are selected and sucked by the swirl type micro / nano bubble generators 10A and 10B, and the functional liquid storage tank 9 and seaweed raw algae storage tank 19 storing seawater are stored. A gas-liquid two-phase flow is discharged. In order to store the seaweed original algae in the seaweed original algae storage tank 19, the seaweed original algae is diluted to about 25% with seawater and stored. In order to maintain the living body, living nori leaves are oxygen respiration and carbon dioxide assimilation, and when dissolved oxygen in stored seawater decreases, the cells of the nori leaves are destroyed and the nori leaves show partial whitening symptoms At the same time, the cell membrane is destroyed and the eluted slime is released. In this case, the oxygen respiration and carbon dioxide assimilation are significantly inhibited by the seawater contamination. In addition, since the laver leaf body and seawater contain various bacteria and the laver leaf body may deteriorate, in this embodiment, first, the on-off valves 12b and 12c are selectively opened, Ozone-containing air or ozone-containing oxygen generated by the ozone generator 8 is sucked by the swirl type micro / nano bubble generators 10A and 10B, and is put into the liquid of the functional liquid storage tank 9 and the laver raw algae storage tank 19, respectively. It discharges ozone-containing gas-liquid two-phase flow, generates ozone micro / nano bubble liquid, supplies oxygen and sterilizes germs. When the sterilization process for 30 minutes is completed, the on-off valve 12d is opened, and oxygen gas discharged from the oxygen gas cylinder 13 is sucked by the swirl type micro / nano bubble generating devices 10A and 10B, and the functional liquid storage tank 9 In addition, an oxygen gas-containing gas-liquid two-phase flow is discharged into the liquid of the seaweed original algae storage tank 19 to generate an oxygen gas micro / nano bubble liquid and supply dissolved oxygen. By virtue of the physiologically active function of the oxygen gas micro / nano bubble solution, the cells of the living laver leaf bodies can be activated and the quality can be improved as compared with the time of collecting cultured laver. When the physiological activation step for 30 minutes is finished, the on-off valve 12a is opened, and the atmosphere is sucked by the swirling flow type micro / nano bubble generating devices 10A and 10B, respectively, and the functional liquid storage tank 9 and the seaweed original algae, respectively. A dissolved oxygen supply process is performed in which an air-containing gas-liquid two-phase flow is discharged into the liquid in the storage tank 19 to generate an air micro / nano bubble liquid to supply dissolved oxygen. The swirling flow type micro / nano bubble generating devices 10A and 10B are respectively introduced with high-pressure liquid by the circulation pump 11 and the submersible pump 14 to generate swirling flow and generate negative pressure, and the gas suction port. 10Aa, 10Ba to the swirl type micro / nano bubble generators 10A, 10B, respectively, according to the sterilization step, physiological activation step or dissolved oxygen supply step, respectively, ozone-containing oxygen gas, oxygen gas or air Is sucked. In addition, the laver original algae storage tank 19 is provided with a stirring blade 20a in a draft tube 19a and driven by a stirring electric speed reducer 20 to generate an upward flow in the draft tube 19a and a descending flow path section. A downward flow is generated in 19b, and the nori seaweed algae is stirred and mixed, and oxygen is supplied to the living nori leaf bodies. Further, the pressure liquid of the circulation pump 11B is sent to the swirling flow type micro / nano bubble generator 10B to generate the gas corresponding to the sterilization process, physiological activation process or oxygen supply process, and the functional liquid. When the gas-liquid two-phase flow of seawater that has been liquefied in the storage tank 9A is discharged to the laver original algae storage tank 19, it flows through the upward flow path section 19c, flows down the overflow weir section 19d, and flows into the trough section 19e. It flows down to the recirculation pipe 21 </ b> A connected in communication and is recirculated to the functional liquid storage tank 9. In order to transfer the seaweed original algae that have been stored in the seaweed original algae storage tank 19 to a salt removal tank (not shown) that stores fresh water called plow water before processing such as dry algae nori. Inhalation is performed by a suction pipe 22 a of a transfer pump 22 that is connected to the bottom 19 e of the seaweed original algae storage tank 19, and a discharge pipe 22 b of the transfer pump 22 is connected to a liquid cyclone 23 that is connected and separated by the liquid cyclone 23. The dewatered seaweed algae are transferred to a salt removal tank (not shown) through a dewatered seaweed algae transfer pipe 23a, and the seawater is returned to the functional water storage tank 9 through a return pipe 21B.

  FIG. 6 and FIG. 7 are schematic longitudinal cross-sectional views according to the first embodiment of the fourth invention. The bacterial cells, spores, and organic substances adhering to the liquid are washed, and the functional liquid in the functional liquid storage tank 9 is communicated with the circulation pump 27, the sand filtration tank 25, and the ultraviolet / photocatalyst sterilizer 26 in order through the circulation pipe 27. The bacteria floating in the functional liquid are sterilized and controlled by circulating the circulation piping system 28 in which the discharge port 27a is submerged in the functional liquid storage tank 9 while being connected. In the present embodiment, in the ultrasonic cleaning device 29, only the throwing-type ultrasonic transducer 24 is illustrated, and the ultrasonic oscillator is not illustrated. When the cultured laver disease bacteria contained in the functional fluid circulating in the circulation piping system 28 flow through the ultraviolet light / photocatalyst sterilizer 26, the light transmitting wall 30a of the reaction cell 30 made of quartz glass. The far-UV light emitting LED 2 having a central wavelength of 265 nm disposed at a distance from each other is decomposed and sterilized by far-ultraviolet light, and the photocatalyst of the UV / photocatalyst combined sterilizer 26 is excited by deep ultraviolet light. As shown in FIG. 7, the photocatalyst sterilizer 26 excites and generates free radicals generated by exciting the photocatalyst layer 32 of the photocatalyst-coated filter 31 immersed in the liquid to which the liquid to be treated flows across the light transmitting wall 30a. Sterilized with. The ultraviolet light emitting LED 2 is housed in a sleeve 6B made of a fluororesin so that there is no leakage of ultraviolet rays to the outside and the sleeve 6B is not deteriorated by far ultraviolet rays. The microplasma-excited far ultraviolet light-emitting element 33 having a central wavelength of 210 nm includes a condenser lens 4 that converges the light emitted from the microplasma-excited far ultraviolet light-emitting element 33. An ozone generator 8 that constitutes a part of the gas suction pipe 7 is provided in the resin sleeve 6A. Ozone air or oxygen gas generated by irradiating oxygen molecules in the air or oxygen gas flowing through the ozone generator 8 with the focused far ultraviolet rays of the microplasma-excited deep ultraviolet light emitting element 33 at a pinpoint. The ozone-containing gas-liquid two-phase flow generated by being sucked into the swirling flow type micro / nano bubble generating device 10 sucked by the suction means is discharged into the water to generate ozone micro bubbles and sterilize by generating nano bubbles. A functional liquid having a washing and bioactive function is generated. As the pathogenic fungi of cultured seaweed, there are many fungi, fungus and red seaweed pathogenic fungi, and the diseases of laver leaf bodies caused by these fungi are related to environmental conditions such as seawater temperature, salinity and solar radiation, and the physiological conditions of cultured laver. Since it occurs depending on the state, in order to reduce the concentration of pathogenic bacteria adhering to cultured laver leaves and reduce the chance of morbidity, it is also important to wash and control the pathogenic bacteria, so Sterilization with ozone micro / nano bubble liquid by washing and removing organic substances and pathogens adhering to the cultured laver leaf body with the ultrasonic transducer 24 and pretreatment for sterilizing the pathogens with the ultraviolet light / photocatalyst sterilizer 26 Works effectively and has a strong bactericidal effect against a wide range of bacteria. In this embodiment, the throwing-type ultrasonic vibrator 24 is used. However, a fixed ultrasonic vibrator can also be used, and as an alternative to the sand filtration tank, a solid-liquid separation that has been widely used conventionally. A device such as a drum filter or a hydrocyclone can also be used and is not obstructed.

  FIG. 8 is a schematic longitudinal sectional view according to the first embodiment of the fifth invention, wherein a field emission lamp 34 is disposed through the tube wall 6a of the sleeve 6 of the ozone generator 8, 200 nm vacuum ultraviolet light is sucked into the swirling flow type micro / nano bubble generator 10 (not shown) from the projection window 34 a of the field emission lamp 34 and flows into the sleeve 6 from the air inlet 6 a. Oxygen molecules in the air flowing down are irradiated to ozonize the oxygen molecules. The 200 nm vacuum ultraviolet light is absorbed somewhat in the air, so it is somewhat diminished by passing through the air, but most of it is transmitted and the inner wall of the sleeve facing the projection window 34a. The vacuum ultraviolet light-emitting phosphor 35 applied to 6b is irradiated to generate vacuum ultraviolet light, and the vacuum ultraviolet light ozonizes oxygen molecules in the air. In order to prevent the vacuum ultraviolet light from leaking from the synthetic quartz vacuum tube 34b other than the synthetic quartz light projection window 34a and adversely affecting the human body, the opaque cover 36 is provided on the vacuum tube 34b. Cover with.

  FIG. 9 is a schematic longitudinal sectional view according to the first embodiment of the sixth invention, which is a short distance front of a deep ultraviolet light emitting LED 2 having a light emitting chip 3 that emits deep ultraviolet light having a central wavelength in a wavelength region of 220 nm. The oxygen molecules contained in the air passing in the vicinity of the focal point of the lens are irradiated with pinpoints to ozonize the oxygen molecules, and the ultraviolet rays collected by the condenser lens 4 pass through the focal point of the condenser lens and are concave mirrors. The oxygen molecules are ozonized at the focal point of the concave mirror 37.

  FIG. 10 is a schematic explanatory view according to the first embodiment of the seventh invention, wherein (a) is a schematic cross-sectional plan view of the ozone generation / ultraviolet sterilization / photocatalytic sterilization unit 38, and (b) is (a). The ozone generation / ultraviolet ray sterilization / photocatalyst sterilization unit 38 is composed of an air or oxygen gas flow path section 39 and a sterilization / decomposition flow path section 40. FIG. Depending on the selection of the gas flowing into the air or oxygen gas flow path 39, the gas suction tube 7 on the inflow side is replaced with the atmospheric suction branch 7a, the ozone-containing air suction branch 7b, the ozone-containing oxygen gas suction shown in FIG. The gas suction pipe 7a connected to the branch pipe 7c is connected to the gas suction port 10a of the swirling flow type micro / nano bubble generating apparatus 10, and vacuum ultraviolet rays having a wavelength of 200 nm generated by the field emission lamp 41 are projected. Oxygen gas is irradiated from the light windows 41Aa and 41Ba to the oxygen gas flowing down the air or the oxygen gas flow channel 39 to be ozonized. The vacuum ultraviolet light is transmitted through a gas such as air or oxygen gas, irradiated to the deep ultraviolet light emitting body 43 coated with the deep ultraviolet light emitting phosphor 42, and the deep ultraviolet light emitting phosphor coated on the deep ultraviolet light emitting body 43. 42 emits deep ultraviolet light having a main wavelength of 260 nm, sterilizes or decomposes contaminants by irradiating the sterilization target liquid in the sterilization / decomposition flow path 40 and irradiates the porous body 44 coated with a photocatalyst Or decompose pollutants. In the present embodiment, the field emission lamp 41 is exemplified as the vacuum ultraviolet irradiation means, but it may be a vacuum ultraviolet light emitting LED, a microplasma excitation ultraviolet light emitting element, or an excimer lamp, and is not limited at all.

  FIG. 11 is a schematic explanatory view according to the first embodiment of the eighth invention, wherein (a) is a schematic vertical sectional view of a swirling flow type micro / nano bubble generating device as an outboard propulsion means, (b ) Is a longitudinal cross-sectional view taken along the line CC in (a), in which a swirling flow type micro / nano bubble generating device 10 is disposed as a propulsion means for the outboard motor 46 equipped in the small boat 45. Then, the discharge pipe 11a of the circulation pump 11 is connected to the gas suction port 10a of the swirling flow type micro / nano bubble generating device 10 by supplying pressure water to the swirling flow type micro / nano bubble generating device 10. Yes.

  FIG. 12 is a schematic explanatory view according to the first embodiment of the ninth invention, wherein (a) is a schematic vertical sectional view of the swirling flow type micro / nano bubble generating device 10, and (b) is (a). In FIG. 1, the discharge side pipe 11 a connected to the circulation pump 11 shown in FIG. 1 of the first embodiment is connected in communication with a liquid inflow socket 47 that is a liquid inlet, and pressurized liquid is supplied. It flows into the pressure chamber 48. Since the flow passage cross-sectional area of the pressure chamber 48 is much larger than the flow passage cross-sectional area of the discharge side pipe 11 a and the liquid inflow socket 47, a part of the velocity head energy in the discharge side pipe 11 a is in the pressure chamber 48. Since it is converted to pressure head energy and the liquid flow velocity in the pressure chamber 48 is reduced, fluid friction loss is reduced. The high pressure liquid in the pressure chamber 48 is ejected from the liquid ejection nozzle 49 in a tangential direction along the inner wall surface 51 a of the conical cylinder 51 constituting the swirling flow chamber 50, and swirling flow is generated in the swirling flow chamber 50. The gas is sucked from the gas suction port 53a drilled in the inner lid 53 into the swirl cavity 52 formed near the cylinder center position of the conical cylinder 51 by the far-center separation action, and the swirl cavity 52 Form. The centripetal force acts on the gas due to the specific gravity difference between the gas and the liquid, and is expressed as the far centripetal separation action where the centrifugal force acts on the liquid. The gas sucked into the gas suction port 53a is sucked by the gas inflow socket 54 and the gas suction pipe 7, but the suction side (not shown) of the gas suction pipe 7 is in the atmosphere when sucking air. When oxygen gas is sucked and connected to an oxygen cylinder or an oxygen hatching device, it is connected to an ozone generator when ozone gas is sucked. Here, the structure of the swirl type micro / nano bubble generator 10 will be described. As members constituting the outermost shell including the pressure chamber 48, pipe-standard caps 56A and 56B are screwed and connected to both ends 55a and 55b of the cylindrical body 55 to constitute the outermost shell body 57. The inner lid 53 is welded to a press-processed cap 58 screwed into one end 51a of the conical body 51 in a direction in which the gas suction port 53a faces the swirling flow chamber 50. Further, the gas inflow socket 54 is welded. In this embodiment, the press-processed cap 58 is used. However, a spatula-drawn cap may be used, or a pipe standard cap can be used. When the pipe standard cap is applied, the cap and the cylinder are used. It is also necessary to consider raising the size of the cylindrical body 57 by one rank so that the reduction in the cross-sectional area of the liquid flow path constituted by the body 57 does not increase the fluid resistance. A groove 56Aa for the O-ring 59 is drilled at the axial center position of the cap 56A, and a hole 56Ab into which the hexagon nipple 60 is inserted is drilled. In addition, a pipe standard different diameter socket 61 is welded to the axial center position of the cap 56B, and the other end 51b of the conical cylinder 51 is screwed into one end 61a of the socket 61. When the hexagonal nipple 60 is inserted into the hole 56Ab and screwed into the gas inflow socket 54, the conical cylinder 51 is fixed and watertightness and airtightness are maintained. When high-pressure water is introduced into the pressure chamber 48 from the liquid inflow socket 47, high-speed water is ejected from the liquid ejection nozzle 49 into the swirling flow chamber 50 to generate a liquid swirling flow. The gas that is directed to the phase flow discharge port 61a and sucked from the gas suction port 53a generates a swirl cavity 52, and is directed to the gas-liquid two-phase flow discharge port 61a. When the liquid is ejected from the liquid 61a in the surrounding environment, the flow velocity is rapidly reduced and fine bubbles are generated.

  FIG. 13 is a schematic explanatory view according to the second embodiment of the ninth invention, wherein (a) is a schematic vertical sectional view of the swirling flow type micro / nano bubble generating device 10, and (b) is (a). FIG. 13 is a schematic sectional view taken along the line D-D. In this embodiment, it is mainly constituted by a screw joint. However, as shown in FIG. Also, the inner lid 53 can be configured to be pressed and sealed with the end plate 63.

  FIG. 14 is a schematic explanatory view according to the first embodiment of the tenth aspect of the present invention, which sucks air in the atmosphere and ozonizes oxygen molecules in the air. FIG. 4 is a schematic cross-sectional view schematically illustrating ozonization of oxygen molecules, and (b) is a schematic cross-sectional view schematically illustrating oxygenation of oxygen molecules using the ozone generator as an object gas. First, in (a), as in FIG. 1 of Example 1, a deep ultraviolet light emitting LED 2 is provided as a light source that emits deep ultraviolet light. The deep ultraviolet light emitting LED 2 includes a light emitting chip 3 that emits deep ultraviolet light having a central wavelength in a wavelength region of 220 nm and a condensing lens 4 that converges light emitted from the light emitting chip 3. The deep ultraviolet light emitting LED 2 converges the light emitted from the light emitting chip 3 by the condenser lens 4 and irradiates oxygen molecules contained in the air passing through the short distance forward of the deep ultraviolet light emitting LED 2 at a pinpoint. Ozonize molecules. However, in deep ultraviolet rays having a central wavelength in the wavelength region of 220 nm, the photon energy is weak to ozonize oxygen molecules, and most of the oxygen molecules flowing down in the sleeve 6 flow down as oxygen molecules. However, when a solenoid coil 64 is wound around the outer periphery of the sleeve 6 and a medium frequency AC power is applied by a medium frequency AC power supply 65, an energy level at which the oxygen molecules are dissociated is reached depending on the 220 nm wavelength deep ultraviolet light emitting LED2. When an intermediate frequency alternating magnetic field generated by the solenoid coil 64 acts on the oxygen molecule, the oxygen molecule vibrates actively and dissociates to generate oxygen atoms, ions, and free electrons. Combines with oxygen molecules to produce ozone. The free electrons also vibrate actively, excite oxygen molecules and actively generate ozone. Further, due to the medium frequency alternating magnetic field generated in the solenoid coil 64, the paramagnetic oxygen molecules are strongly magnetized, and coupled with the attraction action of the swirling flow type micro / nano bubble generator (not shown), the sleeve 6 Since the nitrogen molecules sucked into the inside are diamagnetic materials, they are exhausted from the air, and the air flowing into the sleeve 6 becomes oxygen enriched air enriched in oxygen. Next, also in (b), the ozone generation device 8 uses the oxygen gas supplied from an oxygen gas supply source (not shown) as a target gas, and the ozone generation mechanism that ozone-converts oxygen molecules is the same as in (a). However, since the only gas sucked into the micro / nano bubble generating apparatus (not shown) is ozone, it can be a functional liquid rich in sterilization, cleaning, and physiological activity functions.

  FIG. 15 is a schematic explanatory view according to the first embodiment of the eleventh aspect of the present invention. The ozone generator 8 includes a sleeve 6 and an ultraviolet LED emits deep ultraviolet light having a central wavelength in a wavelength region of 220 nm. In order to improve the ability to ozonize oxygen molecules, further comprising a deep ultraviolet light emitting LED 2 having a light emitting chip 3 that radiates and a condensing lens 4 that converges the light emission of the light emitting chip 3. A solenoid coil 64 that generates an intermediate frequency alternating magnetic field by an intermediate frequency AC power source 65 is wound around the outer periphery of the sleeve 6. In the embodiment of the preceding paragraph, the intake to the sleeve 6 was air in the atmosphere. However, in this embodiment, in order to inhale the oxygen-enriched air, the oxygen-enriched with a hollow fiber membrane 66a provided therein. The device 66 is connected in communication with the oxygen enriched air suction branch 7e. Since the hollow fiber membrane 66a has a performance that allows moisture such as water vapor to preferentially permeate over oxygen in the air and does not easily permeate nitrogen, in order to cool the intake air and generate condensed water, A cooling device 68 provided with a cooling portion 67a of the heat pipe 67 is connected in communication with the air suction end 7f of the oxygen enriched air suction branch 7e. Condensed water generated in the cooling device 68 is discharged by a drain discharger 69 connected to the cooling device 68. In order to remove dust in the dry air flowing down the cooling device 68 and prevent the pores of the hollow fiber membrane 66a from being clogged, the dust filter 70 is connected in communication. A heating device 71 provided with a heating portion 67b of the heat pipe 67 is connected between the dust filter 70 and the oxygen hatching device 66 to heat the dry air, and the hollow fiber membrane. Eliminating permeation factors for oxygen permeating 66a. In the present embodiment, the cooling part 67a and the heating part 67b of the heat pipe 67 are provided for cooling and heating the air, but it can also be an evaporation part and a condensation part in the heat pump air conditioner. In order to make the pressure outside the hollow fiber membrane 66a lower than the inside of the hollow fiber membrane 66a and to facilitate the permeation of oxygen, a blower 72 placed behind the oxygen hatching device 66 is connected in communication with the gas suction pipe 7. As the suction force for lowering the pressure outside the hollow fiber membrane 66a, the suction force of the blower 72 and the swirling flow type micro / nano bubble generating device 10 acts.

  FIG. 16 is a schematic explanatory view according to the first embodiment of the twelfth aspect of the present invention, and supplies the culture solution 73 stored in the functional liquid storage tank 9A to the elevated culture bed 17 in the circulation hydroponics. The liquid pump 74 pumps the liquid to the elevated cultivation bed 17 having a downward slope. The waste culture solution in which nutrients are absorbed by the cultivated plant, the nutrient composition is changed, and various germs are propagated flows down to the waste culture solution tank 75, and the waste liquid pump 76 uses the ultraviolet sterilization / ultraviolet response photocatalyst waste liquid treatment device 77A. The liquid is pumped to the flow rate adjusting tank 78 provided with the diving weir 78a. The water to be treated rectified by the submerged weir 78a is adjusted in flow rate by a plurality of first V-notched first overflow weirs 78b and flows down to the ultraviolet sterilization / ultraviolet responsive photocatalyst waste liquid treatment tank 79A. The liquid supply pump 74 may be a constant flow rate pump with variable flow rate (the same applies hereinafter). The side wall 79Aa and the bottom plate 79Ab of the UV sterilization / UV response photocatalyst waste liquid treatment tank 79A are coated and fixed with UV sterilization / UV response photocatalyst. A water-tight deep ultraviolet light comprising a light-transmitting porous ceramic plate 80 and a plurality of deep ultraviolet light-emitting LEDs 2 having a main wavelength of 260 nm disposed on a substrate 6 and housed in a water-tight quartz glass tube 81. A lamp 82 is provided. A light-shielding lid 83 is disposed above the flow rate adjusting tank 78 and the UV sterilization / UV-responsive photocatalyst waste liquid tank 79A to prevent ultraviolet rays from leaking and causing danger to the human body. A proximity switch 84 is provided that blinks the watertight ultraviolet lamp 82 in accordance with the opening and closing of the light shielding lid 83 without blinking the ultraviolet lamp 82 only by a manual switch (not shown). The treated water that has been treated in the ultraviolet sterilization / ultraviolet-responsive photocatalyst waste tank 79A flows down the plurality of V-notched second overflow weirs 78c and passes through the temporarily treated water storage pits 78d. And then stored in the functional liquid storage tank 9B. Since the nutrient composition of the treated water in the functional liquid storage tank 9B is broken, the composition is adjusted and transferred to the functional liquid storage tank 9A by the transfer pump 85, but the discharge port 85b of the transfer pipe 85a of the transfer pump 85 is used. The micro / nano bubble generating device 10 is provided to supply dissolved oxygen. In the micro / nano bubble generation device 19, air in the atmosphere is sucked to generate micro / nano bubbles, but oxygen is sucked from an oxygen supply device, which is supposed to promote the cell activity of plants or seafood. Micro / nano bubbles can also be generated (the same applies hereinafter).

  FIG. 17 is a schematic explanatory view according to the second embodiment of the twelfth aspect of the present invention, and is stored in the functional liquid storage tank 9A in the elevated culture bed 17 in the circulating hydroponics similar to FIG. The cultivated culture solution 73 is pumped by the feed pump 74 to the upright cultivation bed 17 having a downward slope. The waste culture liquid in which the nutrients are absorbed by the cultivated plant, the nutrient composition is changed, and the germs are propagated flows down to the waste culture liquid tank 75 and is treated with the visible light sterilization / visible light response type photocatalytic waste liquid by the waste liquid pump 76. The liquid is pumped to the flow rate adjusting tank 78 provided with the diving weir 78a of the device 86A. The water to be treated rectified by the submerged weir 78a is adjusted in flow rate by a plurality of V-notched first overflow weirs 78b and flows down to the visible light sterilization / visible light responsive photocatalyst tank 87A. A visible light responsive photocatalyst is applied and fixed to the bottom plate 87Ab of the visible light sterilizing / visible light responsive photocatalyst waste liquid treatment tank 87A, and the visible light sterilizing / visible light responsive photocatalyst is applied and fixed upright on the bottom plate 87Ab. A light-transmitting porous ceramic plate 80 is disposed, and a waterproof fish-collecting lamp 88 having a visible light-emitting LED is disposed. The treated water that has been treated in the visible light ray sterilization / visible ray responsive photocatalyst waste liquid treatment tank 87A flows down a plurality of V-notched second overflow weirs 78c, and temporarily treated water storage pits It flows down via 78d and is stored in the functional liquid storage tank 9B. Since the nutrient composition of the treated water in the functional liquid storage tank 9B is broken, the composition is adjusted and transferred to the functional liquid storage tank 9A by the transfer pump 85, but the discharge port 85b of the transfer pipe 85a of the transfer pump 85 is used. The micro / nano bubble generating device 10 is provided to supply dissolved oxygen.

  FIG. 18 is a schematic explanatory view according to the first embodiment of the thirteenth invention, and is stored in the functional liquid storage tank 9A in the elevated culture bed 17 in the circulating hydroponics similar to FIG. The cultivated culture solution 73 is pumped by the feed pump 74 to the upright cultivation bed 17 having a downward slope. The waste culture liquid in which the nutrients are absorbed by the cultivated plant, the nutrient composition is changed, and the germs are propagated flows down into the waste culture liquid tank 75, and the waste liquid pump 76 uses the UV sterilization / UV response photocatalyst waste liquid treatment apparatus 77B. The liquid is pumped to the flow rate adjusting tank 78 provided with the diving weir 78a. The water to be treated rectified by the diving weir 78a is adjusted in flow rate by the first overflow weir 78b having a plurality of V-notches and flows down to the ultraviolet sterilization / ultraviolet response photocatalyst tank 79B. The side wall 79Ba and the bottom plate 79Bb of the ultraviolet sterilization / ultraviolet responsive photocatalyst waste liquid treatment tank 79B are coated and fixed with an ultraviolet responsive photocatalyst. The porous porous ceramic plate 80 is disposed through the diversion holes 79Bc drilled in the bottom plate 79Bb. An upper end 80a of the light-transmitting porous ceramic plate 80 is submerged under the liquid surface and covered with a flow rate adjusting hole cap 89, and the liquid to be treated flows down with the flow rate adjusted, and is located below the flow dividing hole 79Bc. The light-transmitting porous ceramic plate 80 is disposed so as to be exposed to the atmosphere, and an ultraviolet-responsive photocatalyst is applied and fixed to the light-transmitting porous ceramic plate 80. Since the light-transmitting porous ceramic plate 80 is coated and fixed with an ultraviolet-responsive photocatalyst, the photocatalyst is photoexcited, so that it becomes superhydrophilic and the film thickness of the falling liquid can be adjusted as thin as possible. When the ultra-thin adjusted flow-down solution is irradiated with ultraviolet rays, the ultraviolet rays act on the nucleic acids of the microorganisms to sterilize the microorganisms and irradiate the ultraviolet-responsive photocatalyst to photoexcite the photocatalyst to generate OH radicals, etc. It produces and oxidatively decomposes microorganisms or harmful organic substances. As the ultraviolet lamp for irradiating the light-transmitting porous ceramic plate 80 and the liquid to be processed flowing along the light-transmitting porous ceramic plate 80, the watertight deep ultraviolet lamp 82 in FIG. doing. The treated water that has been treated in the ultraviolet sterilization / ultraviolet responsive photocatalyst waste liquid treatment tank 79B flows down the overflow advection pipe 90 and is stored in the functional liquid storage tank 9B. Since the nutrient composition of the treated water in the functional liquid storage tank 9B is broken, the composition is adjusted and transferred to the functional liquid storage tank 9A by the transfer pump 85, but the discharge port 85b of the transfer pipe 85a of the transfer pump 85 is used. The micro / nano bubble generating device 10 is provided to supply dissolved oxygen.

  FIG. 19 is a schematic explanatory view according to the second embodiment of the thirteenth invention, and is stored in the functional liquid storage tank 9A in the elevated culture bed 17 in the circulation hydroponics similar to FIG. The cultivated culture solution 73 is pumped by the feed pump 74 to the upright cultivation bed 17 having a downward slope. The waste culture liquid in which the nutrients are absorbed by the cultivated plant, the nutrient composition is changed, and the germs are propagated flows down to the waste culture liquid tank 75 and is treated with the visible light sterilization / visible light response type photocatalytic waste liquid by the waste liquid pump 76. The liquid is pumped to the flow rate adjusting tank 78 provided with the diving weir 78a of the device 86B. The water to be treated rectified by the diving weir 78a is adjusted in flow rate by a plurality of V-notched first overflow weirs 78b and flows down to the visible light sterilization / visible light responsive photocatalyst tank 87B. The visible light responsive photocatalyst is applied and fixed to the side wall 87Ba and the bottom plate 87Bb of the visible light sterilization / visible light responsive photocatalyst waste liquid treatment tank 87B, and the visible light responsive photocatalyst is applied and fixed to divert downward. The light-transmitting porous ceramic plate 80 is disposed through the flow dividing hole 80Bc cut out in the bottom plate 80Bb. An upper end 80a of the light-transmitting porous ceramic plate 80 is submerged below the liquid surface and covered with a flow rate adjusting hole cap 89, and the liquid to be treated flows down with the flow rate adjusted, and a portion below the flow dividing hole 80Bc. The light transmissive porous ceramic plate 80 is disposed so as to be exposed to the atmosphere, and a visible light responsive photocatalyst is applied and fixed to the light transmissive porous ceramic plate 80. Since the light transmissive porous ceramic plate 80 is coated and fixed with a visible light responsive photocatalyst, the photocatalyst is photoexcited, so that it becomes superhydrophilic and the film thickness of the falling liquid can be adjusted as thin as possible. When natural light is irradiated to the flow-down solution adjusted to be extremely thin, ultraviolet rays contained in the natural light act on the nucleic acid of the microorganism to sterilize the microorganism and irradiate the visible light responsive photocatalyst to photoexcite the photocatalyst. OH radicals are generated to oxidize and decompose microorganisms or harmful organic substances. The natural light that irradiates the light-transmitting porous ceramic plate 80 and the liquid to be processed flowing along the light-transmitting porous ceramic plate 80 is received by the daylighting unit 91a, the light guide unit 91b, the branching unit 91c, and the irradiation unit 92d. The liquid light guide system 91 is configured to illuminate, guide and irradiate light. However, in the case of cloudy or rainy patterns where natural light cannot be extracted, the driving device is controlled by an illuminance sensor (not shown) and natural light cannot be collected. 92, the light source of the visible light LED floodlight 93 having a visible light wavelength is moved to the upper side of the daylighting unit 91a to be turned on, and the daylighting unit 91a of the liquid light guide system 91 is daylighted to guide the light. Irradiated. The treated water that has been treated in the visible light sterilization / visible ray responsive photocatalyst tank 87B flows down the overflow advection pipe 90 and is stored in the functional liquid storage tank 9B. Since the nutrient composition of the treated water in the functional liquid storage tank 9B is broken, the composition is adjusted and transferred to the functional liquid storage tank 9A by the transfer pump 85, but the discharge port 85b of the transfer pipe 85a of the transfer pump 85 is used. The micro / nano bubble generating device 10 is provided to supply dissolved oxygen.

  FIG. 20 is a schematic explanatory diagram according to the fourteenth aspect of the invention. The culture solution 73 stored in the functional liquid storage tank 9A is placed on the elevated culture bed 17 in the circulating hydroponics similar to FIG. The liquid feed pump 74 pumps the liquid to the elevated cultivation bed 17 having a downward slope. The waste culture liquid in which nutrients are absorbed by the cultivated plant, the nutrient composition is changed, and various germs are propagated flows down to the waste culture liquid tank 75, and the waste liquid pump 77 uses the natural light-containing ultraviolet ray sterilization / visible light responsive photocatalyst. The liquid is pumped to the flow rate adjusting tank 78 provided with the diving weir 78a of the waste liquid processing device 86B. The flow rate of the water to be treated rectified by the diving weir 78a is adjusted by the first overflow weir 78b having a plurality of V-notches, and flows down to the natural light containing ultraviolet sterilization / visible light responsive photocatalyst waste liquid treatment tank 87B. The bottom plate 87Bb of the natural light-containing ultraviolet sterilization / visible light responsive photocatalyst tank 87B passes through a diverting hole 87Bc having a cylindrical oxygen gas permeable film 94 drilled in the bottom plate 87Bb in order to divert it downward. Arrange. An upper end 94a of the cylindrical oxygen gas permeable membrane 94 is submerged below the liquid surface and covered with a flow rate adjusting hole cap 89, and the liquid to be processed flows down with the flow rate adjusted, and is located below the diverting hole 87Bc. The cylindrical oxygen gas permeable membrane 94 is exposed and disposed in the atmosphere. When the water to be treated flows into the inside 94b of the cylindrical oxygen gas permeable membrane 94, the inside 94b of the cylindrical oxygen gas permeable membrane 94 is large around the outside 94c of the cylindrical oxygen gas permeable membrane 94 according to Bernoulli's theorem. The pressure is lower than the atmospheric pressure, and in accordance with Henry's law, the action of dissolving and diffusing into the water to be treated where oxygen gas in the air flows down inside the cylindrical oxygen gas permeable membrane 94 is enhanced. The treated water that has been sterilized with the natural light-containing ultraviolet sterilization / visible light responsive photocatalyst in the natural light-containing ultraviolet sterilization / visible light responsive photocatalyst waste liquid treatment tank 87B, and dissolved oxygen dissolved in the cylindrical oxygen gas permeable membrane 94 is functional. After moving to the liquid storage tank 9B and adjusting the fertilizer composition, the liquid is sent to the functional liquid storage tank 9A by the advection pump 85.

  FIG. 21 is a schematic explanatory view according to the fifteenth aspect of the invention. In the twentieth embodiment of FIG. 22, the liquid to be treated transferred to the functional liquid storage tank 9B is transferred to the elevated liquid tank 95 by the transfer pump 85. However, in order to divert the bottom plate 95b of the elevated liquid tank 95 in the lower bottom direction, a cylindrical oxygen gas permeable film 94 is disposed through the diverting hole 87Bc drilled in the bottom plate 87Bb. An upper end 94a of the cylindrical oxygen gas permeable membrane 94 is submerged below the liquid surface and covered with a flow rate adjusting hole cap 89, and the liquid to be processed flows down with the flow rate adjusted, and is located below the diverting hole 87Bc. The cylindrical oxygen gas permeable membrane 94 is exposed and disposed in the atmosphere. The liquid to be treated supplied with dissolved oxygen by the cylindrical oxygen gas permeable membrane 94 is a new culture produced by mixing granular biodegradable plastics with culture soil, which is disposed in the lower open ground of an elevated cultivation bed. The plant solution 97 provided with the soil 96 is applied with a culture solution distribution pipe 98. In addition, the ratio which mixes a granular biodegradable plastic with culture soil is not specifically limited, A flow receiving biodegradable plastic can also be made into 100%.

  FIG. 22 is a schematic explanatory view according to the sixteenth aspect of the invention, and is a microfiltration membrane module with a membrane supply pump 99 disposed in a waste culture solution tank 75 for storing waste culture solution discharged from the elevated cultivation bed 17. When the waste culture liquid is supplied to 100, the membrane filtration treatment liquid is transferred to the flow rate adjustment tank 78 of the visible light sterilization / visible light response type photocatalyst waste liquid treatment device 86A, and the visible light sterilization / visible light response type is adjusted while the flow rate is adjusted. After flowing down to the photocatalyst waste liquid treatment tank 87A, subjected to ultraviolet sterilization / photocatalyst sterilization treatment, and supplementing and adjusting the fertilization effect of the membrane filtration treatment liquid in the functional liquid storage tank 9B, the advection pump 85 disposed in the functional liquid storage tank 9B After passing through the micro / nano bubble generator 10 disposed in the discharge side pipe 85a, the micro / nano bubble-containing gas-liquid two-phase flow is transferred to the functional liquid storage tank 9A. On the other hand, the concentrated sewage produced by separating the membrane filtration solution from the waste culture solution is transferred to the concentrated sewage storage tank 101, temporarily stored, and discarded. In this embodiment, a sterilization treatment with natural light-containing ultraviolet light and a natural light-containing visible light responsive photocatalyst sterilization treatment are used, but an ultraviolet sterilization treatment with a deep ultraviolet light emitting LED and an ultraviolet responsive photocatalyst sterilization can also be used.

  In the present invention, the light emitted from the light-emitting chip 3 in the ultraviolet LED 2 is converged by the condenser lens 4 to increase the energy density of the photons and to irradiate oxygen molecules at a pinpoint, thereby generating ozone and swirling the ozone. Ozone micro / nano bubble liquid produced by discharging a gas-liquid two-phase flow generated by suction using a micro / nano bubble generator into the liquid is inexpensive, safe and energy-saving, so nori culture, seafood It can be used in various fields such as aquaculture, agricultural production, food industry, silicon wafer production for semiconductor devices, wastewater treatment, store and household cleaning, sterilization and deodorization.

1 Functional liquid production equipment 2 Deep UV light emitting LED
3 Light emitting chip 4 Condensing lens 5 Substrate 6, 6A, 6B Sleeve 7 Gas suction pipe 8 Ozone generator 6a, 6Ba Air inlet 9, 9A, 9B Functional liquid storage tank 10, 10A, 10B Micro / nano bubble generator 10a, 10Aa 10Ba Gas vent 11, 11A, 11B Circulation pump 11a Discharge side piping 7a Atmospheric suction branch 7b Discharge side piping 12a, 12b, 12c, 12d, 15Aa, 15Ab On-off valve 7b Ozone-containing air suction branch 7c Ozone-containing oxygen gas suction branch 7d Oxygen gas suction branch 13 Oxygen gas cylinders 14A, 14B, 14 Submersible pumps 15A, 15B Discharge-side piping 16A, 16B Spray nozzle 17 High-arrangement cultivation bed 18 Reflux piping 19 Nori seaweed algae storage tank 19a Draft tube 20a Stirring blade 20 Stirring motor Reducer 19b Downstream channel section 19c Upstream channel section 19d Overflow weir section 19e Trough section 21A, 21B Reflux pipe 19e Bottom section 22 Transfer pump 22a Suction pipe 22b Discharge pipe 23 Liquid cyclone 23a Dewatered seaweed transfer pipe 24 Cast-in type ultrasonic wave Vibrator 25 Sand filtration tank 26 UV / photocatalyst sterilizer 27 Circulation piping 27a Discharge port 28 Circulation piping system 29 Ultrasonic cleaning device 30 Reaction cell 30a Light transmission wall 31 Photocatalyst coating filter 32 Photocatalyst layer 33 Microplasma excited deep ultraviolet light emitting device 34, 41A, 41B Field emission lamp 34a Projection window part 6b Inner wall 35 Vacuum ultraviolet light emitting phosphor 34b Vacuum tube 36 Shielding cover 37 Concave mirror 38 Ozone generation / UV sterilization / photocatalyst sterilization unit 39 Air or oxygen gas flow path part 40 Sterilization / decomposition Channel part 41Aa , 41Ba Projection window 42 Vacuum ultraviolet light emitting phosphor coating film 43 Deep ultraviolet light emitting material 44 Porous material 45 Small ship 46 Outboard motor 47 Liquid inflow socket 48 Pressure chamber 49 Liquid ejection nozzle 50 Swirling flow chamber 51 Conical cylinder 52 Swirl Cavity 53 Inner lid 53a Gas suction port 54 Gas inflow socket 55 Cylindrical body 55a, 55b Both ends 56A, 56B Cap 57 Outermost shell body 51a One end 58 Cap 59 O-ring 56Aa Groove 60 Hex nipple 56Ab hole 61 Different diameter socket 61a One end 51b The other end 61a Gas-liquid two-phase flow outlet 62 Flange 63 End plate 64 Solenoid coil 65 Medium frequency AC power supply 66a Hollow fiber membrane 66 Oxygen hatching device 7e Oxygenated air suction branch 67 Heat pipe 67a Cooling unit 68 Cooling device 7f Air suction End 69 Drain discharger 70 Dust cup Illter 67b Heating unit 71 Heating device 72 Blower 9A Functional liquid storage tank 73 Culture liquid 74 Liquid supply pump 75 Waste culture liquid tank 76 Waste liquid pump 77A Ultraviolet sterilization / ultraviolet response photocatalyst waste liquid treatment device 78a Submerged weir 78 Flow rate adjustment tank 78b First pass Flow weir 79A UV sterilization / UV response photocatalyst waste liquid treatment tank 79Aa Side wall 79Ab Bottom plate 80 Light transmissive porous ceramic plate 81 Watertight quartz glass tube
82 Watertight Deep UV Light
83 Shading cover 84 Proximity switch 78c Second overflow weir 78d Temporary treated water storage pit 9B Functional liquid storage tank 85 Advection pump 85b Advection pipe 85c Discharge port 86A Visible light sterilization / visible light response type photocatalyst waste liquid treatment device 87A Visible light sterilization / visible Photoresponsive photocatalyst treatment tank 87Ab Bottom plate
88 Waterproof Fish Collection Light 77B UV Sterilization / UV Responsive Photocatalytic Waste Liquid Treatment Equipment 79B UV Sterilization / UV Responsive Photocatalytic Treatment Tank 79Ba Side Wall 79Bb Bottom Plate 79Bc Distributing Hole 80a Upper End 89 Flow Control Opening Cap 90 Overflow Advection Tube 86B Natural Light Containing UV Sterilization・ Visible light responsive photocatalyst waste liquid treatment equipment 87B Natural light-containing UV sterilization ・ Visible light responsive photocatalyst treatment tank 87Ba Side wall 87Bb Bottom plate 87Bc Distributing hole 91a Daylighting unit
91b Light guide portion 91c Branch portion 91d Irradiation portion 91 Liquid light guide system 92 Drive device 93 Visible light LED projector 94 Cylindrical oxygen permeable membrane 94a Upper end 94b Inside 94c Outside 95 High placement tank 96 Culture soil 97 Planter 98 Culture solution Distribution pipe 99 Membrane supply pump 100 Microfiltration membrane module 101 Concentrated sewage storage tank

Claims (19)

In a deep ultraviolet light emitting LED, microplasma-excited deep ultraviolet light emitting element or field emission lamp FEL having a central wavelength in a wavelength range of 240 nm to 200 nm, light emission of the deep ultraviolet light emitting LED, microplasma excited deep ultraviolet light emitting element or field emission lamp FEL A deep ultraviolet light emitting LED, a microplasma excited deep ultraviolet light emitting element or a field emission lamp FEL having a condenser lens for converging the light, and the deep ultraviolet light emitting LED, microplasma excited deep ultraviolet light emitting element or a field emission lamp FEL in a sleeve A deep ultraviolet light emitting LED having a central wavelength in the wavelength range of 240 nm to 200 nm in the ozone generator that constitutes a part of the pipe disposed, and in the oxygen molecules in the air or oxygen gas flowing in the sleeve ,micro A micro / nano bubble generation device that sucks the generated ozone-containing air or oxygen gas by a suction means by the focused ultraviolet light of a laser-excited deep ultraviolet light emitting element or a field emission lamp FEL, and the micro / nano bubble generation device. The ozone-containing gas-liquid two-phase flow generated by suction is discharged into the liquid in the functional liquid storage tank to generate ozone microbubbles and nanobubbles to generate a functional liquid having sterilization, washing, and physiologically active functions. A functional liquid manufacturing apparatus characterized by the above. One or more deep ultraviolet light emitting LEDs, microplasma-excited deep ultraviolet light emitting elements or field emission lamps FEL are arranged on the sleeve, and an ozone generator that constitutes a part of the piping and two or more ozone generators are connected in series. 2. The functional liquid production apparatus according to claim 1, wherein two or more series-connected ozone generator groups disposed in parallel and two or more series-connected ozone generator groups are disposed in parallel with each other. Gas suction side pipe of micro / nano bubble generator, two or more control pipes of the gas suction side pipe, air supply means, oxygen gas supply means and ozone-containing gas supply means arranged in each of the control pipes 3. A functional liquid manufacturing apparatus according to claim 1, further comprising an opening / closing means for selecting a gas type supplied from the air supply means, oxygen gas supply means and ozone-containing gas supply means. The functional liquid production apparatus according to claim 1, wherein the ozone-containing gas-liquid two-phase flow sucked and generated by the micro / nano bubble generator is discharged into the liquid of the functional liquid storage tank to generate ozone micro bubbles and nano bubbles. An ultrasonic vibration device for ultrasonically cleaning an object to be cleaned in the functional liquid storage tank as a pretreatment or a simultaneous use of sterilizing and cleaning with a functional liquid that has been generated and sterilized, washed, and a functional liquid having a physiologically active function A circulation pipe equipped with a circulation pump through which the liquid to be sterilized is circulated, and the liquid to be sterilized by being connected to the circulation pipe and flowing through the light transmitting wall of the light transmitting cell. Deep ultraviolet light emitting LED or microplasma excited deep ultraviolet light emitting element having a central wavelength in a wavelength range of 300 nm to 200 nm for sterilizing bacteria, the deep ultraviolet light emitting LED, microplasma excited Dispose of ultraviolet light emitting element or field emission lamp FEL by irradiating deep ultraviolet light and disinfecting ultraviolet light and photocatalyst with a photocatalyst coating porous body immersed in the liquid to be sterilized flowing through the light transmitting wall. The functional liquid manufacturing apparatus according to claim 1, 2, or 3. The ozone generator according to claim 1, wherein a field emission lamp disposed through a sleeve in the ozone generator, and vacuum ultraviolet light having a main wavelength of 200 nm or less from a light projection window portion of the field emission lamp, A tube facing the light projection window, irradiated with oxygen molecules in the air flowing down the sleeve or oxygen molecules in the oxygen gas, ozonized, then transmitted through the air layer, and irradiated with the ultraviolet light The functional liquid production according to claim 1, 2 or 3, wherein oxygen molecules are ozonated by vacuum ultraviolet light having a main wavelength of 200 nm or less, which is emitted from a vacuum ultraviolet light emitting phosphor having a main wavelength of 200 nm or less, which is applied to a wall. apparatus. In a deep ultraviolet light emitting LED, a microplasma excited deep ultraviolet light emitting element or a field emission lamp FEL having a dominant wavelength in a wavelength range of 240 nm to 200 nm, the deep ultraviolet light emitting LED, a microplasma excited deep ultraviolet light emitting element or a field emission lamp FEL Deep ultraviolet light-emitting LED, microplasma-excited far ultraviolet light-emitting element or field emission lamp FEL provided with a condensing lens for converging light emission, and deep ultraviolet light-emitting LED, microplasma-excited deep ultraviolet light-emitting element or field emission lamp FEL, etc. One light source is fixedly disposed in the sleeve, and the first ozone generating means, and the inner wall surface of the sleeve receives the emission radiation of the first light emitting means, and emits excitation light in the main wavelength range of 300 nm to 250 nm. Deep UV light emitting fluorescent powder is concave A second ozone generation means provided with a second light source and an ultraviolet light emitting phosphor applied to the plate, and oxygen molecules in the air or oxygen gas flowing through the sleeve, An ozone generator that irradiates the light source and the second light source to generate ozone, a micro / nano bubble generator that sucks the generated ozone-containing air or oxygen gas by a suction means, and a suction to the micro / nano bubble generator The generated ozone-containing gas-liquid two-phase flow is discharged into the liquid of the functional liquid storage tank to generate ozone microbubbles and nanobubbles to generate a functional liquid having sterilization, washing, and physiologically active functions. The functional liquid production apparatus according to claim 1, 2, 3, 4 or 5. In a functional liquid production apparatus having a piping system for producing functional liquid by sucking ozone with a micro / nano bubble generator and a piping system for circulating a liquid to be treated with a circulation pump and sterilizing and decomposing contaminants with ultraviolet rays and a photocatalyst An ozone generating unit that converts oxygen in an air or oxygen gas stream into ozone by a vacuum ultraviolet irradiation unit, an ultraviolet and photocatalytic sterilization unit, a vacuum ultraviolet irradiation unit disposed in the ozone generation unit, and the vacuum ultraviolet irradiation unit A deep ultraviolet fluorescent powder coating wall that receives irradiation light emitted from the substrate, emits deep ultraviolet light, and divides and emits light in two directions; a partition wall between the ozone generation unit, the ultraviolet light, and the photocatalyst sterilization unit, Transparent sterilization that transmits deep ultraviolet light emitted by the fluorescent powder and deep ultraviolet light emitted by the deep ultraviolet fluorescent powder coating wall are irradiated and sterilized and decomposed into liquid flowing down the light-transmitting liquid flow path. In addition, a sterilizing and decomposing means for carrying and sterilizing and decomposing by supporting the photocatalyst immersed in the liquid, and sucking the functional liquid in the functional liquid storage tank by sucking the ozone-containing air or oxygen gas generated in the ozone generating unit A micro / nano bubble generator for generating ozone micro / nano bubbles by discharging an ozone-containing gas-liquid two-phase flow into the functional liquid, and a circulation pump for sucking and discharging the liquid flowing down the sterilizing and decomposing means are provided. The functional liquid production apparatus according to claim 1, 2 or 3, wherein a functional liquid having sterilization, washing, and physiologically active functions is generated. In a seafood / seaweed aquaculture farm that produces a functional liquid having sterilization, washing, and bioactive functions, a floating body, an outboard micro / nano bubble generator for propelling the floating body, rudder means, and the micro / nano bubble It comprises at least a circulation pump that supplies pressurized liquid to the generator and an ozone generator that supplies ozone-containing air or oxygen gas to the micro / nano bubble generator. The functional liquid production apparatus according to 3, 4, 5, 6, 7 or 8. In the pressure pump discharge liquid possessed energy of the micro / nano bubble generator used in the functional liquid production apparatus, the speed head energy reducing means and the turning speed head energy converting means using the pressure head energy increased by the speed head energy reduction amount And a production and maintenance cost reduction means using a commercially available piping member. 9. The functional liquid production apparatus according to claim 1, wherein A sleeve of an ozone generator or ozone generator having a deep ultraviolet LED, a solenoid coil wound around the sleeve, and a high frequency AC power of 10 MHz to 30 MHz supplied to the solenoid coil 7. The functional liquid production apparatus according to claim 1, wherein a high-frequency AC power supply control device is provided. Oxygen hatching in which a hollow fiber membrane is provided in an oxygen hatching means in which an oxygen hatching gas is applied to a gas flow flowing into a sleeve of an ozone generator or ozone generator having a deep ultraviolet LED. Means, gas suction means disposed outside the hollow fiber membrane, in communication connection with the gas suction pipe of the micro / nano bubble generator, and an air suction pipe for atmospheric air sucked into the hollow fiber membrane A cooling means that cools below the dew point of the suction air in the middle of the suction pipe, a drain discharger that removes the condensed water generated by cooling with the cooling means from the air suction pipe, the cooling means and the hollow fiber Heating means inserted in communication with the air suction pipe between the membrane, a connecting pipe connecting the heating means and the cooling means, and a heat transfer hydraulic fluid enclosed in the connecting pipe It is characterized by arranging heat transfer means Functional liquid manufacturing apparatus according to claim 2, 3, 4, 5 or 6, wherein that. In the purification treatment of aqueous solutions containing pathogenic bacteria or polluting organic substances, flow rate adjusting means for adjusting the flow rate of the liquid to be treated and flowing down, ultraviolet light or natural light-containing ultraviolet sterilization / ultraviolet light or visible light disposed downstream of the flow rate adjusting means Responsive photocatalyst sterilization waste liquid treatment tank, and light transmissive porous plate coated with ultraviolet or visible light responsive photocatalyst immersed in the treatment liquid of the ultraviolet light or natural light containing ultraviolet sterilization / ultraviolet light or visible light responsive photocatalyst sterilization tank A waterproof deep ultraviolet ray or visible light emitting LED underwater ultraviolet ray or visible light irradiating means immersed in a treatment liquid of the ultraviolet ray or natural light-containing ultraviolet sterilization / ultraviolet ray or visible light responsive photocatalyst sterilization waste liquid treatment tank; An ultraviolet or visible light emitting LED is provided with a visible light emitting LED pilot lamp electrically connected in series with an underwater ultraviolet or visible light irradiation means. Functional liquid manufacturing equipment. In the purification treatment of aqueous solutions containing pathogenic bacteria or polluting organic substances, flow rate adjusting means for adjusting the flow rate of the liquid to be treated and flowing down, ultraviolet light or natural light-containing ultraviolet sterilization / ultraviolet light or visible light disposed downstream of the flow rate adjusting means Response type photocatalyst sterilization waste liquid treatment tank and light transmission type porous coated with ultraviolet or visible light responsive photocatalyst immersed in the treatment liquid of the ultraviolet ray or natural light containing ultraviolet sterilization / ultraviolet light or visible light response type photocatalyst sterilization waste liquid treatment tank And a waterproof deep ultraviolet or visible light emitting LED irradiating means immersed in a liquid to be treated in the treatment liquid of the ultraviolet or natural light-containing ultraviolet sterilization / ultraviolet or visible light responsive photocatalyst sterilization waste liquid treatment tank, the waterproof deep ultraviolet or visible Visible light emitting LED pilot lamp electrically connected in series with the light emitting LED irradiating means, and the ultraviolet light or natural light containing ultraviolet sterilization / UV light or visible light response Light penetrating through a diversion hole drilled in the bottom of the processing tank for photocatalytic sterilization waste liquid, the upper end is immersed below the surface of the water, the lower part is exposed to the atmosphere, and UV or visible light responsive photocatalyst is applied UV or visible light emitting LED irradiating means for irradiating the mold porous plate, the visible light emitting LED pilot lamp electrically connected in series, and the deep UV or visible light emitting LED irradiating means for ultraviolet or visible light responsive type 13. The functional liquid production apparatus according to claim 12, wherein when irradiated with a light-transmitting porous plate coated with a photocatalyst, OH radicals and the like generated by photoexcitation of the ultraviolet light or visible light responsive photocatalyst are generated. In the purification treatment of aqueous solutions containing pathogenic bacteria or polluting organic substances, flow rate adjusting means for adjusting the flow rate of the liquid to be treated and flowing down, ultraviolet light or natural light-containing ultraviolet sterilization / ultraviolet light or visible light disposed downstream of the flow rate adjusting means Responsive photocatalyst sterilization waste liquid treatment tank and light transmission type coated with ultraviolet or visible light responsive photocatalyst immersed in the treatment liquid of the ultraviolet light or natural light containing ultraviolet sterilization / ultraviolet light or visible light responsive photocatalyst sterilization tank A porous plate, a waterproof ultraviolet or visible light emitting LED underwater ultraviolet irradiation means immersed in a liquid to be treated in the ultraviolet or natural light-containing ultraviolet sterilization / ultraviolet or visible light responsive photocatalyst sterilization tank, and the waterproof ultraviolet or visible light emitting LED Visible light emitting LED pilot lamp electrically connected in series with underwater ultraviolet light irradiation means, and ultraviolet light or natural light containing ultraviolet light sterilization / ultraviolet light or visible light Cylindrical shape penetrating through a diversion hole drilled in the bottom of the answer type photocatalyst sterilization waste liquid treatment tank, the upper end is immersed below the water surface, and the lower part is immersed in the water receiving tank to be treated in the atmosphere or below. Alternatively, the functional liquid production apparatus according to claim 12 or 13, wherein the functional liquid production apparatus comprises a hollow fiber oxygen gas permeable membrane. In the purification treatment of aqueous solutions containing pathogenic bacteria or polluting organic substances, flow rate adjusting means for adjusting the flow rate of the liquid to be treated and flowing down, ultraviolet light or natural light-containing ultraviolet sterilization / ultraviolet light or visible light disposed downstream of the flow rate adjusting means Light coated with UV or visible light responsive photocatalyst immersed in the liquid to be treated in the responsive photocatalyst sterilization waste liquid treatment tank and the ultraviolet or natural light-containing UV sterilization / ultraviolet light or visible light responsive photocatalyst sterilization waste liquid treatment tank Transmission type porous plate, waterproof ultraviolet ray or visible light emitting LED underwater ultraviolet ray irradiation means immersed in the treatment liquid of the ultraviolet ray or natural light containing ultraviolet sterilization / ultraviolet light or natural light containing ultraviolet light responsive photocatalyst sterilization waste liquid treatment tank, and the waterproof ultraviolet ray Alternatively, visible light emitting LED irradiating means electrically connected in series with visible light emitting LED underwater ultraviolet irradiating means, and ultraviolet or natural light-containing UV sterilization Ultraviolet or visible light responsive photocatalyst sterilization waste liquid treatment tank penetrating through a diverting hole drilled at the bottom, the upper end is immersed below the surface of the water, below the bottom is in the atmosphere or the liquid receiving tank to be disposed below Cultivated soil and plant-derived small pieces, pellets, and particles that are sprayed with the immersed cylindrical or hollow fiber oxygen permeable membrane and the treatment liquid released from the cylindrical or hollow fiber oxygen permeable membrane. Alternatively, the functional liquid production apparatus according to claim 12 or 13, wherein the functional liquid production apparatus comprises a culture soil in which a biodegradable plastic such as a powder is mixed at an arbitrary blending ratio. In purification treatment of aqueous solutions containing pathogenic bacteria or polluting organic substances, microfiltration membranes and ultrafiltration membranes having a pore size of 0.1 μm or more, ultraviolet light (including natural light-containing ultraviolet rays) and / or photocatalytic sterilization treatment means, aeration An apparatus for producing a functional liquid, characterized by comprising means. In purification treatment of aqueous solutions containing pathogenic bacteria or polluting organic substances, a flow rate adjustment step for adjusting the flow rate of the liquid to be treated and a flow-through porous inorganic plate coated with an ultraviolet-responsive photocatalyst is immersed in the liquid to be treated. A step, a step of irradiating the light-transmitting porous inorganic plate with deep ultraviolet rays, a step of sterilizing the liquid to be treated with deep ultraviolet rays, and a function of generating OH radicals and the like generated by exciting the ultraviolet-responsive photocatalyst with ultraviolet rays. Liquid manufacturing apparatus method. In a functional water storage tank in which functional water in which an object to be sterilized is stored is stored, a deep ultraviolet light emitting LED, a microplasma excited deep ultraviolet light emitting element or a field emission lamp FEL having a central wavelength in a wavelength range of 240 nm to 200 nm is part of a pipe. In the ozone generator disposed in the sleeve constituting the above, the deep ultraviolet light emitting LED, the microplasma excited deep ultraviolet light emitting element or the field emission lamp FEL is the deep ultraviolet light emitting LED, the microplasma excited deep ultraviolet light emitting element or the field emission. A condensing lens for converging the light emitted by the lamp FEL, and converging and irradiating the light emitted from the deep ultraviolet LED, the microplasma-excited ultraviolet light emitting element or the field emission lamp FEL with the condensing lens; Oxygen in the air flowing through Oxygen molecules in a child or oxygen gas are irradiated with focused ultraviolet light from a far ultraviolet light emitting LED, a microplasma excited deep ultraviolet light emitting element or a field emission lamp FEL having a central wavelength in a wavelength range of 240 nm to 200 nm at a pinpoint, And a gas-liquid two-phase flow generated by sucking the generated ozone gas-containing air or oxygen gas with the suction means of the micro / nano bubble generating device is discharged into the liquid to generate ozone micro bubbles 6. The method for producing a functional liquid according to claim 1, comprising a step of generating nanobubbles. In purification treatment of aqueous solutions containing pathogenic bacteria or pollutant organic substances, in a flow rate adjusting step for adjusting the flow rate of the liquid to be treated and flowing down, and in a diverting hole drilled in the bottom of the diverting means arranged downstream of the flow rate adjusting step A diverting step for diverting, light that passes through the diverting holes, has an upper end immersed under the water surface of the lower diverting means, and exposed to the atmosphere below the bottom of the lower diverting means, and is coated with a natural light-responsive photocatalyst A transmission type porous plate, a visible light irradiation step for irradiating the light transmission type porous plate coated with the natural light responsive photocatalyst, and a functional liquid that generates OH radicals generated by photoexcitation of the natural light responsive photocatalyst Manufacturing equipment method.