JP2018082637A - Composition for fried kamaboko, and method for producing fried kamaboko - Google Patents
Composition for fried kamaboko, and method for producing fried kamaboko Download PDFInfo
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- JP2018082637A JP2018082637A JP2016226310A JP2016226310A JP2018082637A JP 2018082637 A JP2018082637 A JP 2018082637A JP 2016226310 A JP2016226310 A JP 2016226310A JP 2016226310 A JP2016226310 A JP 2016226310A JP 2018082637 A JP2018082637 A JP 2018082637A
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Landscapes
- Meat, Egg Or Seafood Products (AREA)
Abstract
Description
本発明は、揚げ蒲鉾用組成物、すなわち、揚げ蒲鉾の調製において生地として用いられる組成物の製造方法に関し、詳しくは、魚肉すり身の代わりに骨肉分離肉を用いて、食感の良好な揚げ蒲鉾の調製が可能な、揚げ蒲鉾用組成物を製造する方法に関する。
さらに本発明は、魚肉すり身の代わりに骨肉分離肉を用いて、食感の良好な揚げ蒲鉾を製造する方法に関する。
The present invention relates to a method for producing a composition for deep-fried salmon, that is, a composition used as a dough in the preparation of deep-fried salmon. More specifically, the present invention relates to a deep-fried salmon having a good texture by using bone meat separated meat instead of fish meat surimi. It is related with the method of manufacturing the composition for deep-fried rice cakes which can be prepared.
Furthermore, the present invention relates to a method for producing a deep-fried rice cake having a good texture using bone meat separated meat instead of fish meat surimi.
さつま揚げ等の揚げ蒲鉾は、魚肉のすり身を調味・加工して揚げたものであり、特有のしっかりした弾力と、均一でなめらかな食感を有する。
近年、揚げ蒲鉾に新たな食感を付与する試みがなされている。たとえば、卵白とトランスグルタミナーゼとを添加混合することにより、さつま揚げにソフトでふわっとした新規な食感を付与する方法(特許文献1)や、トランスグルタミナーゼを添加し作用させた練り物状の動物性食品素材と、トランスグルタミナーゼを添加していない練り物状の動物性食品素材とを混合して得られた混合物を加熱処理することにより、水産練り製品または畜肉練り製品に、粗挽き様のヘテロな食感を付与する方法(特許文献2)が提案されている。
Deep-fried salmon, such as fried satsuma, is prepared by seasoning and processing fish surimi and has a unique firm elasticity and a uniform and smooth texture.
In recent years, attempts have been made to impart a new texture to fried rice cakes. For example, by adding and mixing egg white and transglutaminase, a method for imparting a soft and fluffy texture to sweet potatoes (Patent Document 1), or a kneaded animal food material made to act by adding transglutaminase By heating the mixture obtained by mixing the kneaded animal food material to which no transglutaminase is added, the fishery kneaded product or the livestock kneaded product is given a hetero-like heterogeneous texture. A method (Patent Document 2) has been proposed.
また、揚げ蒲鉾用組成物の主材、すなわち主要な原料として用いられる魚肉すり身は高価であるため、魚肉すり身の代わりに畜肉を用いて、揚げ蒲鉾用組成物を調製しようとする試みがなされている。
しかし、畜肉を主材として用いた場合、製造時の成形性や揚げた後の食感が悪く、魚肉すり身を用いたものと同等の品質を有する揚げ蒲鉾を製造し得る、揚げ蒲鉾用組成物を得ることはできなかった。
In addition, since the main ingredient of the composition for deep-fried salmon, that is, fish surimi used as the main raw material is expensive, attempts have been made to prepare a composition for deep-fried salmon using livestock meat instead of surimi fish meat. Yes.
However, when livestock meat is used as the main ingredient, the moldability at the time of manufacture and the texture after fried are poor, and a composition for fried rice cake that can produce fried rice cake having the same quality as that using fish meat surimi Could not get.
また、肉としての形態を有しないペースト状の肉、いわゆる骨肉分離肉が安価であることから、食肉加工食品の一原料として利用が広がりつつある。
骨肉分離肉の利用に関する技術としては、トランスグルタミナーゼとカゼインナトリウムを混合し、該混合物を加熱してゲル化反応を進行させながら、同時に撹拌して、ゲルの形成と破壊を同時に進行させて、挽き肉状に固形化させる技術が提案されている(特許文献3)。
しかし、骨肉分離肉を用いて、魚肉すり身を主材として含有する揚げ蒲鉾と、同等の食感を有する揚げ蒲鉾を製造する技術は、未だに開発されていない。
In addition, since pasty meat having no form as meat, so-called bone meat separation meat, is inexpensive, its use as a raw material for processed meat products is spreading.
As a technique related to the use of bone-separated meat, transglutaminase and sodium casein are mixed, and the mixture is heated to allow the gelation reaction to proceed while stirring at the same time, so that gel formation and breakage proceed at the same time. A technique for solidifying into a shape has been proposed (Patent Document 3).
However, a technique for producing a deep-fried rice bran containing fish meat surimi as a main ingredient and a deep-fried rice cake having an equivalent texture using bone-separated meat has not yet been developed.
そこで、本発明は、魚肉すり身の代わりに骨肉分離肉を主材として用いながら、成形性が良好で、食感に優れる揚げ蒲鉾を調製し得る揚げ蒲鉾用組成物、および、魚肉すり身を主材として含有する揚げ蒲鉾と、同等の食感を有する揚げ蒲鉾を提供することを目的とした。 Accordingly, the present invention provides a composition for deep-fried salmon that can prepare a deep-fried salmon having good moldability and excellent texture while using bone-separated meat as the main material instead of fish meat surimi, and fish surimi The purpose of the present invention is to provide a deep-fried rice cake having a texture equivalent to that of the deep-fried rice cake contained as.
本発明者らは、上記課題を解決すべく鋭意検討した結果、骨肉分離肉および植物性タンパク質にトランスグルタミナーゼを作用させることにより、成形性が良好で、油で揚げた際には食感の優れる揚げ蒲鉾が得られる揚げ蒲鉾用組成物を得ることに成功し、本発明を完成するに至った。 As a result of intensive studies to solve the above-mentioned problems, the inventors of the present invention made transglutaminase act on bone-separated meat and vegetable protein, so that the moldability is good and the texture is excellent when fried in oil. It succeeded in obtaining the composition for deep-fried rice cake which can obtain a deep-fried rice cake, and came to complete this invention.
すなわち、本発明は、以下に関する。
[1]植物性タンパク質および骨肉分離肉を含有する混合物に、トランスグルタミナーゼを添加する、揚げ蒲鉾用組成物の製造方法。
[2]植物性タンパク質および骨肉分離肉を含有する混合物が、さらに澱粉を含有する、[1]に記載の製造方法。
[3]植物性タンパク質および骨肉分離肉を含有する混合物が、さらに調味料を含有する、[1]または[2]に記載の製造方法。
[4]植物性タンパク質が、穀物および豆類のタンパク質の1種以上である、[1]〜[3]のいずれかに記載の製造方法。
[5]植物性タンパク質が、米タンパク、小麦タンパクおよび大豆タンパクからなる群より選択される1種以上である、[1]〜[4]のいずれかに記載の製造方法。
[6][1]〜[5]のいずれかに記載の製造方法により得られた揚げ蒲鉾用組成物を成形する工程、および150℃〜180℃で加熱する工程を含む、揚げ蒲鉾の製造方法。
[7]揚げ蒲鉾用組成物を成形する工程において、畜肉、魚介、野菜およびそれらの加工品からなる群より選択される1種以上を添加する、[6]に記載の製造方法。
[8]植物性タンパク質、骨肉分離肉およびトランスグルタミナーゼを含有する、揚げ蒲鉾用組成物。
[9]さらに澱粉を含有する、[8]に記載の組成物。
[10]さらに調味料を含有する、[8]または[9]に記載の組成物。
[11]植物性タンパク質が、穀物および豆類のタンパク質の1種以上である、[8]〜[10]のいずれかに記載の組成物。
[12]植物性タンパク質が、米タンパク、小麦タンパクおよび大豆タンパクからなる群より選択される1種以上である、[8]〜[11]のいずれかに記載の組成物。
That is, the present invention relates to the following.
[1] A method for producing a composition for deep-fried rice bran, wherein transglutaminase is added to a mixture containing vegetable protein and bone meat separated meat.
[2] The production method according to [1], wherein the mixture containing vegetable protein and bone meat separated meat further contains starch.
[3] The production method according to [1] or [2], wherein the mixture containing vegetable protein and bone meat separated meat further contains a seasoning.
[4] The production method according to any one of [1] to [3], wherein the vegetable protein is one or more of cereal and legume proteins.
[5] The production method according to any one of [1] to [4], wherein the vegetable protein is at least one selected from the group consisting of rice protein, wheat protein and soybean protein.
[6] A method for producing deep-fried rice cake, comprising a step of molding the composition for deep-fried rice cake obtained by the production method according to any one of [1] to [5], and a step of heating at 150 ° C. to 180 ° C. .
[7] The production method according to [6], wherein one or more selected from the group consisting of livestock meat, seafood, vegetables, and processed products thereof are added in the step of forming the fried rice bran composition.
[8] A composition for deep-fried rice bran comprising vegetable protein, bone meat separated meat and transglutaminase.
[9] The composition according to [8], further comprising starch.
[10] The composition according to [8] or [9], further containing a seasoning.
[11] The composition according to any one of [8] to [10], wherein the vegetable protein is one or more of cereal and legume proteins.
[12] The composition according to any one of [8] to [11], wherein the vegetable protein is at least one selected from the group consisting of rice protein, wheat protein and soybean protein.
本発明により、骨肉分離肉を主材として用いながら、成形性の良好な揚げ蒲鉾用組成物を得ることができる。
本発明の揚げ蒲鉾用組成物を油で揚げることにより得られる揚げ蒲鉾は、魚肉すり身を主材として含有する従来の揚げ蒲鉾と同等の、しっかりした弾力と、均一でなめらかな食感を有する。
ADVANTAGE OF THE INVENTION By this invention, the composition for deep-fried rice cake with favorable moldability can be obtained, using bone meat separation meat as a main material.
The deep-fried rice cake obtained by frying the composition for deep-fried rice cake of the present invention has a firm elasticity and a uniform and smooth texture equivalent to those of a conventional deep-fried rice cake containing fish paste as a main ingredient.
本発明の揚げ蒲鉾用組成物は、植物性タンパク質、骨肉分離肉およびトランスグルタミナーゼを含有してなり、植物性タンパク質および骨肉分離肉を含有する混合物に、トランスグルタミナーゼを添加して製造される。 The composition for deep-fried rice bran of the present invention contains vegetable protein, bone meat separated meat and transglutaminase, and is produced by adding transglutaminase to a mixture containing vegetable protein and bone meat separated meat.
本発明において、「植物性タンパク質」とは、穀物(米、小麦、ハトムギ、トウモロコシ等)、芋類(ヤマトイモ、ナガイモ等)、豆類(大豆、エンドウマメ、インゲンマメ、ルピナス、ヒヨコマメ、アズキ等)、種実類(ラッカセイ、ゴマ、カシューナッツ、アーモンド、ピスタチオ、クルミ等)、野菜(カリフラワー、シュンギク、ホウレンソウ、アスパラガス等)、果物(ブドウ、アボカド、プルーン等)、キノコ(シイタケ、キクラゲ、マッシュルーム、マイタケ、エリンギ等)、海藻(アオサ、ワカメ、ヒジキ、コンブ等)等およびこれらの加工品等の植物性食品に含まれるタンパク質をいい、本発明においては、これら植物性タンパク質の1種以上を用いることができる。
本発明の目的には、穀物および豆類のタンパク質が好ましく、米タンパク、小麦タンパクおよび大豆タンパクがより好ましい。
本発明においては、植物性タンパク質として、上記植物性食品より抽出、精製等して得たタンパク質を用いてもよいが、各社より提供されている市販の製品を利用することもできる。
本発明の揚げ蒲鉾用組成物には、植物性タンパク質は、組成物の全量に対し1重量%〜50重量%含有されることが好ましく、3重量%〜30重量%含有されることがより好ましい。
In the present invention, “vegetable protein” refers to cereals (rice, wheat, pearl barley, corn, etc.), potatoes (Yamatoimo, Chinese yam, etc.), beans (soybeans, peas, kidney beans, lupine, chickpeas, azuki bean, etc.), Seeds (peanuts, sesame, cashew nuts, almonds, pistachios, walnuts, etc.), vegetables (cauliflower, garlic, spinach, asparagus, etc.), fruits (grape, avocado, prunes, etc.), mushrooms (shiitake, mushrooms, mushrooms, maitake, Eringi, etc.), seaweed (Aosa, wakame, hijiki, kombu, etc.) and the like and proteins contained in plant foods such as these processed products, etc. In the present invention, one or more of these plant proteins may be used. it can.
For the purposes of the present invention, cereal and legume proteins are preferred, and rice protein, wheat protein and soy protein are more preferred.
In the present invention, a protein obtained by extraction, purification, etc. from the above-mentioned plant food may be used as the plant protein, but commercially available products provided by various companies can also be used.
In the composition for deep-fried rice bran of the present invention, the vegetable protein is preferably contained in an amount of 1 to 50% by weight, more preferably 3 to 30% by weight, based on the total amount of the composition. .
本発明において、「骨肉分離肉(Mechanically Deboned Meat)」とは、通常鳥獣肉から精肉を分離後、骨等に付着している残肉を機械的に骨肉分離器にかけて分離したものである。骨肉分離肉の調製に用いられる鳥獣肉原料としては、鶏肉、七面鳥肉、豚肉、牛肉等が挙げられる。また、その使用部位、品質等についても特に限定されず、たとえば、鶏肉の場合、廃鶏等をまるまる骨肉分離肉とした比較的色調の白いものや、首やヤゲン(薬研)部分(軟骨、カッパとも呼ばれ、鳥類の特徴である胸骨の先端の柔い部分をさす)を原料とした赤身の強い品質のもの等を用いることができる。
骨肉分離肉は、骨付き肉等をクラッシュしたのち、骨肉分離器の直径約0.5mm〜1.0mm程度の細孔から圧力をかけて押し出すことにより製造され、通常ペースト状を呈する。本発明においては、「骨肉分離肉」として流通している市販の製品を用いることができる。
本発明の揚げ蒲鉾用組成物には、骨肉分離肉は、組成物の全量に対し5重量%〜90重量%含有されることが好ましく、10重量%〜80重量%含有されることがより好ましい。
In the present invention, “Mechanically Deboned Meat” refers to a piece of meat that has been attached to bones or the like after mechanically separating the meat from the normal animal meat, and then mechanically separated by a bone and meat separator. Examples of the raw materials for poultry and meat used in the preparation of bone meat separation include chicken, turkey, pork, and beef. Also, the use site, quality, etc. are not particularly limited. For example, in the case of chicken meat, a relatively white-colored one made of whole chicken separated meat such as abandoned chicken, or a neck or a bevel (yakuken) part (cartilage, kappa) Also, it is possible to use a material with strong red meat quality and the like, which is a raw material of the tip of the sternum, which is a characteristic of birds.
The bone meat separation meat is produced by crushing bone-equipped meat and the like and then extruding it with pressure from pores having a diameter of about 0.5 mm to 1.0 mm of the bone meat separator, and usually takes a paste form. In the present invention, a commercially available product distributed as “bone separated meat” can be used.
In the composition for deep-fried rice bran of the present invention, the bone meat separated meat is preferably contained in an amount of 5 to 90% by weight, more preferably 10 to 80% by weight, based on the total amount of the composition. .
本発明において用い得るトランスグルタミナーゼは、タンパク質上のグルタミンのアミノ基と第1級アミンを縮合させ、アミン上の置換基をグルタミンに転移させて、アンモニアが生成する反応を触媒する転移酵素であり、通常は第1級アミンとしてタンパク質上のリシンのアミノ基が用いられ、架橋酵素として作用する。 Transglutaminase that can be used in the present invention is a transferase that catalyzes a reaction in which ammonia is produced by condensing the amino group of glutamine on a protein with a primary amine, transferring a substituent on the amine to glutamine, Usually, the amino group of lysine on a protein is used as a primary amine and acts as a cross-linking enzyme.
トランスグルタミナーゼは、上記した通り、タンパク質やペプチド中のグルタミン残基を供与体とし、リシン残基を受容体とするアシル転移反応を触媒する活性を有する酵素であり、たとえば、哺乳動物由来のもの、魚類由来のもの、微生物由来のもの等、種々の起源のものが知られている。本発明において用いられるトランスグルタミナーゼは、上述の活性を有すればその起源は特に制限されず、いかなる起源のトランスグルタミナーゼであっても使用でき、また組み換え酵素を使用してもよい。本発明において用いられるトランスグルタミナーゼは市販品であってもよく、具体例としては、味の素株式会社より「アクティバTG」という商品名で市販されている微生物由来のトランスグルタミナーゼ等が挙げられる。
本発明において用いられるトランスグルタミナーゼの活性単位は、次のように測定され、かつ、定義される。
すなわち、温度37℃、pH6.0のトリス(トリスヒドロキシメチルアミノメタン)緩衝液中、ベンジルオキシカルボニル−L−グルタミルグリシンおよびヒドロキシルアミンを基質とする反応系で、トランスグルタミナーゼを作用せしめ、生成したヒドロキサム酸を、トリクロロ酢酸存在下にて鉄錯体とした後、525nmにおける吸光度を測定し、ヒドロキサム酸量を検量線により求めて、1分間に1μモルのヒドロキサム酸を生成せしめる酵素量を1ユニット(1U)とする(特開昭64−27471号公報参照)。
本発明においては、トランスグルタミナーゼは、植物性タンパク質および骨肉分離肉の総含有量1g当たり、0.0001U〜1,000Uが好ましく、0.001U〜100Uがより好ましく、0.01U〜10Uが特に好ましい。
As described above, transglutaminase is an enzyme having an activity of catalyzing an acyl transfer reaction using a glutamine residue in a protein or peptide as a donor and a lysine residue as an acceptor. Those of various origins such as those derived from fish and microorganisms are known. The origin of the transglutaminase used in the present invention is not particularly limited as long as it has the above-mentioned activity, and any transglutaminase of any origin can be used, and a recombinant enzyme may be used. The transglutaminase used in the present invention may be a commercially available product. Specific examples thereof include a transglutaminase derived from a microorganism marketed by Ajinomoto Co., Inc. under the trade name “Activa TG”.
The activity unit of transglutaminase used in the present invention is measured and defined as follows.
That is, hydroxam produced by reacting transglutaminase in a reaction system using benzyloxycarbonyl-L-glutamylglycine and hydroxylamine as substrates in a tris (trishydroxymethylaminomethane) buffer solution at a temperature of 37 ° C. and pH 6.0. The acid was converted to an iron complex in the presence of trichloroacetic acid, the absorbance at 525 nm was measured, the amount of hydroxamic acid was determined by a calibration curve, and the amount of enzyme that produced 1 μmol of hydroxamic acid per minute was 1 unit (1 U (See Japanese Patent Application Laid-Open No. 64-27471).
In the present invention, transglutaminase is preferably 0.0001 U to 1,000 U, more preferably 0.001 U to 100 U, and particularly preferably 0.01 U to 10 U per 1 g of the total content of vegetable protein and bone meat separated meat. .
本発明の揚げ蒲鉾用組成物には、植物性タンパク質および骨肉分離肉に加えて、さらに澱粉等の結合剤を含有させることができる。
澱粉としては、多数のα−グルコース分子がグリコシド結合によって重合した天然高分子、およびそれらを物理的、化学的、酵素的方法等により加工して得られた加工澱粉を、特に制限なく用いることができる。
天然の澱粉としては、その基原は問わず、トウモロコシ、米、小麦、豆類、ジャガイモ、サツマイモ、タピオカ等、種々の植物由来のものが例示される。
また、加工澱粉としては、アセチル化酸化澱粉、オクテニルコハク酸澱粉ナトリウム、酢酸澱粉、酸化澱粉、ヒドロキシプロピル澱粉、リン酸化澱粉等、食品添加物として認定されている加工澱粉が挙げられる。
上記天然の澱粉および加工澱粉は、1種または2種以上を用いることができる。
本発明の目的には、ジャガイモおよびタピオカ由来の澱粉が好ましく用いられる。
本発明においては、澱粉として、各社より提供されている市販の製品を用いることができる。
本発明の揚げ蒲鉾用組成物には、澱粉は、組成物の全量に対し1重量%〜30重量%含有されることが好ましく、2重量%〜20重量%含有されることがより好ましい。
The composition for deep-fried rice bran of the present invention can further contain a binder such as starch, in addition to the vegetable protein and bone meat separated meat.
As starch, it is possible to use, without particular limitation, natural polymers obtained by polymerizing a number of α-glucose molecules by glycosidic bonds, and processed starch obtained by processing them by physical, chemical, enzymatic methods or the like. it can.
Examples of the natural starch include those derived from various plants such as corn, rice, wheat, beans, potato, sweet potato, tapioca and the like.
Examples of the modified starch include acetylated oxidized starch, sodium octenyl succinate starch, starch acetate, oxidized starch, hydroxypropyl starch, and phosphorylated starch, which are certified as food additives.
The said natural starch and processed starch can use 1 type (s) or 2 or more types.
For the purpose of the present invention, starch derived from potato and tapioca is preferably used.
In the present invention, commercially available products provided by various companies can be used as the starch.
In the composition for deep-fried rice bran of the present invention, starch is preferably contained in an amount of 1 to 30% by weight, more preferably 2 to 20% by weight, based on the total amount of the composition.
本発明の揚げ蒲鉾用組成物には、さらに調味料を含有させることができる。
かかる調味料としては、料理に対して味付けをする目的で使用される食品または食品添加物であれば、特に制限なく用いることができ、たとえば、食塩、糖類(たとえば、ブドウ糖、果糖、ショ糖、乳糖、デキストリン等)、野菜(たとえば、ニンジン、タマネギ、セロリ、ハクサイ、キャベツ等)の粉末およびそれらのエキス、海藻(たとえば、コンブ、ワカメ等)の粉末およびそれらのエキス、キノコ(たとえば、マッタケ、シイタケ、シメジ等)の粉末およびそれらのエキス、魚介類(たとえば、カツオ、サバ、アジ、イワシ、エビ、ホタテ、カキ等)の粉末およびそれらのエキス、畜肉(たとえば、ビーフ、ポーク、チキン等)の粉末およびそれらのエキス、しょうゆ、酵母エキス、うま味調味料(たとえば、アミノ酸系調味料、核酸系調味料等)、甘味料、酸味料、香辛料等が挙げられる。
上記調味料は、1種または2種以上を用いることができ、その含有量については、揚げ蒲鉾に付与すべき所望の味および風味に応じて、適宜決定することができる。
The frying koji composition of the present invention can further contain a seasoning.
Such a seasoning can be used without particular limitation as long as it is a food or food additive used for the purpose of seasoning dishes, such as salt, sugar (eg, glucose, fructose, sucrose, Lactose, dextrin, etc.), vegetables (eg, carrots, onions, celery, Chinese cabbage, cabbage, etc.) and their extracts, seaweed (eg, kombu, seaweed, etc.) powders and their extracts, mushrooms (eg, matsutake, Shiitake mushrooms, shimeji mushrooms) and their extracts, fish and shellfish (eg bonito, mackerel, horse mackerel, sardines, shrimp, scallops, oysters etc.) powders and their extracts, livestock (eg beef, pork, chicken etc.) Powders and their extracts, soy sauce, yeast extract, umami seasonings (eg amino acid seasonings, nuclear System seasonings), sweeteners, acidulants, spices, and the like.
The said seasoning can use 1 type (s) or 2 or more types, About the content, it can determine suitably according to the desired taste and flavor which should be provided to fried rice cake.
本発明の揚げ蒲鉾用組成物には、さらに必要に応じて、食品の製造に際して一般的に用いられる他の食品添加物を添加することができる。
かかる食品添加物としては、乳化剤(グリセリン脂肪酸エステル、ショ糖脂肪酸エステル、サポニン、レシチン等)、保存料(安息香酸、安息香酸ナトリウム、ソルビン酸、ソルビン酸カリウム、ε−ポリリシン等)、酸化防止剤(アスコルビン酸、エリソルビン酸、カテキン等)、防かび剤(チアベンタゾール、フルジオキソニル等)、着色料(アナトー色素、ウコン色素、クチナシ色素等)、香料(アセト酢酸エチル、アニスアルデヒド等の合成香料、オレンジ、ラベンダー等の天然香料)等が挙げられ、これらは、1種または2種以上を用いることができる。
The food composition for deep-fried rice cake of the present invention may further contain other food additives that are generally used in the production of foods, if necessary.
Such food additives include emulsifiers (glycerin fatty acid esters, sucrose fatty acid esters, saponins, lecithins, etc.), preservatives (benzoic acid, sodium benzoate, sorbic acid, potassium sorbate, ε-polylysine, etc.), antioxidants. (Ascorbic acid, erythorbic acid, catechin, etc.), fungicides (thiabentazole, fludioxonil, etc.), coloring agents (anato dyes, turmeric dyes, gardenia dyes, etc.), fragrances (synthetic fragrances such as ethyl acetoacetate, anisaldehyde, Natural fragrances such as orange and lavender) and the like, and one or more of them can be used.
本発明の揚げ蒲鉾用組成物の調製に際して、植物性タンパク質と骨肉分離肉の他に、澱粉、調味料、栄養成分等を含有させる場合には、これらの成分を植物性タンパク質と混合した後に、骨肉分離肉を添加して混合することが好ましい。
次いで、トランスグルタミナーゼを添加混合して、通常4℃〜40℃で撹拌し、10分〜60分ほど静置することにより、適度な粘度を有し、成形性の良好な揚げ蒲鉾用組成物を得ることができる。
In the preparation of the composition for deep-fried rice bran of the present invention, in addition to plant protein and bone meat separated meat, when containing starch, seasoning, nutritional components, etc., after mixing these components with plant protein, It is preferable to add and mix bone meat separation meat.
Next, transglutaminase is added and mixed, and usually stirred at 4 ° C. to 40 ° C. and left to stand for about 10 to 60 minutes, whereby a composition for deep-fried rice cake having an appropriate viscosity and good moldability is obtained. Can be obtained.
なお、本発明において、トランスグルタミナーゼとともにグルコースオキシダーゼを用いることにより、より短時間で効率的に、揚げ蒲鉾用組成物を調製することができる。
グルコースオキシダーゼは、β−D−グルコースを酸化してD−グルコノ−δ−ラクトンを生成する酵素であり、一般的には、食品中に含まれる酸素およびグルコースの除去のために使用される。
本発明においてグルコースオキシダーゼの活性は、常法に従って測定することができる。
本発明において用いられるグルコースオキシダーゼの活性単位は、次のように測定され、かつ、定義される。
すなわち、グルコースを基質として、酸素存在下でグルコースオキシダーゼを作用させて過酸化水素を生成させ、生成した過酸化水素に、アミノアンチピリンおよびフェノール存在下でペルオキシダーゼを作用させて生成したキノンイミン色素を波長500nmで測定し、キノンイミン色素の生成量を検量線より求め、前記結果から、1分間に1μmolのグルコースを酸化するのに必要な酵素量を算出し、1ユニット(1U)とする。
In the present invention, by using glucose oxidase together with transglutaminase, a composition for deep-fried koji can be prepared more efficiently in a shorter time.
Glucose oxidase is an enzyme that oxidizes β-D-glucose to produce D-glucono-δ-lactone, and is generally used for removing oxygen and glucose contained in food.
In the present invention, the activity of glucose oxidase can be measured according to a conventional method.
The activity unit of glucose oxidase used in the present invention is measured and defined as follows.
That is, using glucose as a substrate, glucose oxidase is allowed to act in the presence of oxygen to produce hydrogen peroxide, and the quinoneimine dye produced by reacting peroxidase in the presence of aminoantipyrine and phenol to the produced hydrogen peroxide has a wavelength of 500 nm. The amount of quinoneimine dye produced is determined from a calibration curve, and from the results, the amount of enzyme required to oxidize 1 μmol of glucose per minute is calculated to be 1 unit (1 U).
グルコースオキシダーゼとしては、黒カビ(Aspergillus niger)、ペニシリウム アマガサキエンス(Penicillium amagasakiense)等の真菌類により生産されるものが知られているが、上記の酵素活性を示す限り、その起源は特に制限されず、組み換え酵素を使用してもよい。
本発明においては、「ハイデラーゼ15」(天野エンザイム株式会社製)等の市販の製品を用いることもできる。
本発明の揚げ蒲鉾用組成物の調製に際しては、グルコースオキシダーゼの含有量は、植物性タンパク質および骨肉分離肉の総含有量1g当たり、0.0001U〜10,000Uを用いることが好ましく、0.0001U〜1,000Uを用いることがより好ましい。
As glucose oxidase, those produced by fungi such as black mold (Aspergillus niger) and Penicillium amagasakiense are known, but their origin is not particularly limited as long as they show the above enzyme activity. Recombinant enzymes may be used.
In the present invention, commercially available products such as “Hyderase 15” (manufactured by Amano Enzyme Inc.) can also be used.
In preparing the composition for deep-fried rice bran of the present invention, the glucose oxidase content is preferably 0.0001 U to 10,000 U per 1 g of the total content of vegetable protein and bone meat separated meat, 0.0001 U It is more preferable to use ~ 1,000U.
本発明の揚げ蒲鉾用組成物の調製に際し、グルコースオキシダーゼは、植物性タンパク質と骨肉分離肉の混合物に、あるいは、澱粉、調味料、栄養成分等を含有させる場合には、これらと植物性タンパク質および骨肉分離肉との混合物に、トランスグルタミナーゼとともに添加し、通常4℃〜40℃にて作用させる。
グルコースオキシダーゼを併用する場合、成形に適する粘度を有する揚げ蒲鉾用組成物を得るのに要する時間が、トランスグルタミナーゼを単独で用いる場合に比べて短縮され、グルコースオキシダーゼの併用により、揚げ蒲鉾用組成物の製造効率を向上させることができる。
In the preparation of the composition for deep-fried rice bran of the present invention, glucose oxidase is mixed with vegetable protein and bone meat separated meat, or when starch, seasoning, nutritional components, etc. are contained, these and vegetable protein and It is added together with transglutaminase to the mixture with the bone meat separation meat, and is usually allowed to act at 4 ° C to 40 ° C.
When glucose oxidase is used in combination, the time required to obtain a composition for deep-fried rice cake having a viscosity suitable for molding is shortened compared to the case where transglutaminase is used alone. The production efficiency can be improved.
本発明の揚げ蒲鉾用組成物を適宜所望の形状に成形した後、150℃〜180℃で加熱することにより、揚げ蒲鉾を得ることができる。
150℃〜180℃で加熱する手段としては、150℃〜180℃の油で揚げることが、好ましい手段として挙げられる。
150℃〜180℃での加熱は、成形した揚げ蒲鉾用組成物の表面が、きつね色になる程度の時間、好ましくは4分〜10分程度行うことが好ましい。
すなわち、本発明の揚げ蒲鉾の製造方法は、上記した本発明の揚げ蒲鉾用組成物を成形する工程、および、成形した揚げ蒲鉾用組成物を、150℃〜180℃で加熱する工程を含む。
After forming the composition for deep-fried rice cake of this invention into a desired shape suitably, a deep-fried rice cake can be obtained by heating at 150 to 180 degreeC.
As a means for heating at 150 ° C. to 180 ° C., frying with oil at 150 ° C. to 180 ° C. is a preferred means.
The heating at 150 ° C. to 180 ° C. is preferably performed for a period of time such that the surface of the molded frying koji composition becomes dark brown, preferably about 4 to 10 minutes.
That is, the manufacturing method of the deep-fried rice cake of this invention includes the process of shape | molding the composition for deep-fried rice cake of this invention mentioned above, and the process of heating the molded composition for deep-fried rice cake at 150 to 180 degreeC.
本発明の揚げ蒲鉾用組成物を成形する工程において、畜肉、魚介、野菜およびそれらの加工品からなる群より選択される1種以上の食材を添加することにより、得られる揚げ蒲鉾の味、風味等にバリエーションを加えることができ、また、揚げ蒲鉾の栄養成分の種類および栄養価を向上させることができる。
上記食材の好適な例としては、ヤマイモ、ジャガイモ等の芋類、枝豆等の豆類、ゴボウ、ニンジン等の根菜類、エビ等の魚介類、鶏肉等の畜肉類、豆腐等の加工品等が挙げられ、これらは適宜細切したり、すりおろしたりして添加することができる。
なお、揚げ蒲鉾用組成物に上記食材を添加する場合、必要に応じて小麦粉等や水を加えて、揚げ蒲鉾用組成物の粘度を調整することができる。
In the step of forming the composition for deep-fried rice cake of the present invention, the taste and flavor of the deep-fried rice cake obtained by adding one or more ingredients selected from the group consisting of livestock meat, seafood, vegetables and processed products thereof Etc., and the kind and nutrient value of the fried rice cake can be improved.
Preferable examples of the above-mentioned ingredients include potatoes such as yams and potatoes, beans such as edamame, root vegetables such as burdock and carrot, fishery products such as shrimp, livestock meat such as chicken, and processed products such as tofu. These can be added by being appropriately chopped or grated.
In addition, when adding the said foodstuff to the composition for deep-fried rice cakes, the viscosity of the composition for deep-fried rice cakes can be adjusted by adding flour etc. and water as needed.
以下、実施例により本発明を詳細に説明する。なお、以下において、特に記載しない場合、「%」は重量%を示す。 Hereinafter, the present invention will be described in detail by way of examples. In the following, “%” indicates wt% unless otherwise specified.
[実施例1、比較例1〜3]揚げ蒲鉾用組成物の製造
表1に示す組成にて、実施例1および比較例1〜3の揚げ蒲鉾用組成物を得た。
<製造方法>
まず副材(本明細書において、主材以外に含有される調味料、製造用剤等の食品添加物等をいう)中の澱粉、植物性タンパク質および調味料を水に添加して混合し、次いで主材を添加して混合、撹拌した後、トランスグルタミナーゼを加えて混合し、25℃で撹拌した後20分〜30分静置して、揚げ蒲鉾用組成物とした。
表中の各成分としては、下記原料を使用した。なお、特に記載しないものについては、食品用として市販されている一般的な原料を用いた。
(1)澱粉
タピオカ加工澱粉:「ST3205」(東海澱粉株式会社製)
(2)植物性タンパク質
(i)粉末状小麦タンパク:「A−グルG」(グリコ栄養食品株式会社製)
(ii)粉末状大豆タンパク:「ニューフジプロ−SE」(不二製油株式会社製)
(3)調味料
アミノ酸系調味料:「新・ねり味−KF」(味の素株式会社製)
(4)主材
(i)魚肉(イトヨリ)すり身:「冷凍イトヨリすり身」(スターフィッシュ(STARFISH)(タイ)社製)
(ii)鶏ムネ肉ミンチ:国産ムネ肉(チルド)を自社にてミンチとした。
(iii)骨肉分離肉:「国産若鶏冷凍すり身」(株式会社ウェルファムフーズ社製)
(5)酵素
トランスグルタミナーゼ:「アクティバTG−K」(100U/g)(味の素株式会社製)
[Example 1, Comparative Examples 1 to 3] Manufacture of composition for deep-fried rice cake In the composition shown in Table 1, compositions for deep-fried rice cake of Example 1 and Comparative Examples 1 to 3 were obtained.
<Manufacturing method>
First, starch, vegetable protein, and seasoning in secondary materials (referred to as food additives such as seasonings and manufacturing agents contained in addition to the main material in this specification) are added to water and mixed. Next, the main material was added, mixed and stirred, then transglutaminase was added and mixed. After stirring at 25 ° C., the mixture was allowed to stand for 20 to 30 minutes to obtain a frying koji composition.
The following raw materials were used as each component in the table. In addition, about what is not described in particular, the general raw material marketed for foods was used.
(1) Starch Tapioca processed starch: “ST3205” (manufactured by Tokai Starch Co., Ltd.)
(2) Vegetable protein (i) Powdered wheat protein: “A-Guru G” (manufactured by Glico Nutrition Foods Co., Ltd.)
(Ii) Powdered soybean protein: “New Fuji Pro-SE” (Fuji Oil Co., Ltd.)
(3) Seasoning Amino acid-based seasoning: “New Neri-KF” (manufactured by Ajinomoto Co., Inc.)
(4) Main materials (i) Fish meat surimi: “Frozen itori surimi” (STARFISH (Thailand))
(Ii) Chicken fillet mince: Domestic fillet (chilled) was minced in-house.
(Iii) Bone meat separation meat: “Domestic young chicken frozen surimi” (manufactured by Wellfam Foods Co., Ltd.)
(5) Enzyme Transglutaminase: “Activa TG-K” (100 U / g) (Ajinomoto Co., Inc.)
実施例1および比較例1〜3の揚げ蒲鉾用組成物を成形し、170℃の油で6分間揚げて、揚げ蒲鉾(さつま揚げ)を製造した。
揚げ蒲鉾用組成物の成形性、得られたさつま揚げの食感(なめらかさおよび弾力)を3名のパネラーにより評価させ、評価結果を次の基準により表1に併せて示した。また、表1には、さつま揚げの食感について、パネラーの感想も示した。
<評価基準>
(1)成形性
○;組成物が適度な粘度を有し、成形が容易である。
△;成形は可能であるが、組成物の粘度がやや低く、成形しづらい。
×;組成物の粘度が低く、成形が不可能である。
(2)さつま揚げのなめらかさ
○;均一になめらかである。
△;部分的になめらかでない。
×;全体的になめらかでない。
(3)さつま揚げの弾力
○;しっとりとした弾力がある。
△;やや弾力がない、または硬い。
×;弾力がない。
The composition for deep-fried rice cake of Example 1 and Comparative Examples 1-3 was shape | molded, and it fried for 6 minutes with 170 degreeC oil, and the deep-fried rice cake (satsumaage) was manufactured.
The moldability of the composition for deep-fried rice cake and the texture (smoothness and elasticity) of the obtained deep-fried fish cake were evaluated by three panelists, and the evaluation results are also shown in Table 1 according to the following criteria. Table 1 also shows the panelists' impressions about the texture of fried fish cakes.
<Evaluation criteria>
(1) Formability ○: The composition has an appropriate viscosity and is easy to mold.
Δ: Molding is possible, but the viscosity of the composition is slightly low and molding is difficult.
X: The viscosity of the composition is low and molding is impossible.
(2) Smoothness of fish cake ○: Uniformly smooth.
Δ: Partially smooth.
X: Overall smooth.
(3) Elasticity of Satsumaage ○;
Δ: Slightly inelastic or hard.
X: There is no elasticity.
表1に示されるように、主材として魚肉すり身を含有する比較例1の揚げ蒲鉾用組成物は、トランスグルタミナーゼが添加されていなくても成形性は良好で、油で揚げて得られたさつま揚げは、しっとりした弾力と、均一でなめらかな食感を有していた。
しかし、魚肉すり身の代わりに鶏ムネ肉ミンチを含有し、トランスグルタミナーゼが添加された比較例2の揚げ蒲鉾用組成物は、成形性は良好であったが、油で揚げて得られたさつま揚げの食感はなめらかさに欠け、全体的に硬く、粒感があり、比較例1で得られたさつま揚げの食感とは大きく異なる食感であった。また、魚肉すり身の代わりに骨肉分離肉を含有し、トランスグルタミナーゼが添加されていない比較例3の揚げ蒲鉾用組成物は、成形性が悪く、油で揚げて得られたさつま揚げは、なめらかではあるが、フニャフニャした弾力のない食感を有していた。
これに対し、魚肉すり身の代わりに骨肉分離肉を含有し、トランスグルタミナーゼが添加された本発明の実施例1の揚げ蒲鉾用組成物は、成形性が良好で、油で揚げて得られたさつま揚げは、比較例1で得られたさつま揚げと同等の弾力があり、均一な滑らかさのある食感を有していた。
As shown in Table 1, the composition for fried salmon of Comparative Example 1 containing fish meat as the main material has good moldability even when no transglutaminase is added, and the fish cake obtained by fried in oil Had a moist elasticity and a uniform and smooth texture.
However, the composition for deep-fried rice cake of Comparative Example 2 containing chicken minced meat mince instead of fish meat surimi and added with transglutaminase had good moldability, but the fried rice was obtained by fried with oil. The texture was not smooth, was generally hard and grainy, and was significantly different from the texture of the fish cake obtained in Comparative Example 1. In addition, the composition for fried rice cake of Comparative Example 3 containing bone meat separated meat instead of fish meat surimi and not added with transglutaminase has poor moldability, and the fish cake obtained by fried in oil is smooth. However, it had a crisp and supple texture.
On the other hand, the composition for deep-fried rice cake of Example 1 of the present invention containing bone separated meat instead of fish surimi and added with transglutaminase has good moldability and is deep-fried with sweet potato Had the same elasticity as the fish cake obtained in Comparative Example 1, and had a texture with uniform smoothness.
なお、表1中実施例1として示される組成にて、さらにグルコースオキシダーゼ(「ハイデラーゼ15」(天野エンザイム株式会社))を、植物性タンパク質および骨肉分離肉の総含有量に対し30U/gとなるように、トランスグルタミナーゼとともに添加して揚げ蒲鉾用組成物を調製した。その場合、表1には結果を示していないが、実施例1の場合よりも短時間で、適度な粘度を有し、成形性の良好な揚げ蒲鉾用組成物を得ることができた。 In addition, in the composition shown as Example 1 in Table 1, glucose oxidase ("Hyderase 15" (Amano Enzyme Co., Ltd.)) is 30 U / g with respect to the total content of vegetable protein and bone meat separation meat. Thus, the composition for deep-fried rice cake was prepared by adding with transglutaminase. In that case, although the results are not shown in Table 1, a composition for deep-fried rice cake having an appropriate viscosity and good moldability could be obtained in a shorter time than in the case of Example 1.
[実施例2]揚げ蒲鉾用組成物の製造
表2に示す副材中、澱粉、植物性タンパク質、調味料および卵白粉を水に添加して混合し、次いで主材である骨肉分離肉を添加して混合した。次に、トランスグルタミナーゼを添加して、25℃で撹拌した後、20分〜30分静置して、揚げ蒲鉾用組成物を得た。
なお、表2中の各原料としては、上記実施例1の場合と同様の原料を用い、卵白粉としては、食品用として市販されている一般的な原料を用いた。
[Example 2] Manufacture of composition for deep-fried rice cake In the auxiliary materials shown in Table 2, starch, vegetable protein, seasoning and egg white powder are added to water and mixed, and then the main material, bone meat separated meat, is added And mixed. Next, after adding transglutaminase and stirring at 25 degreeC, it stood still for 20 to 30 minutes, and the composition for deep-fried rice cake was obtained.
In addition, as each raw material in Table 2, the raw material similar to the case of the said Example 1 was used, and the general raw material marketed for foods was used as egg white powder.
実施例2の揚げ蒲鉾用組成物は、良好な成形性を示した。 The composition for deep-fried rice cake of Example 2 showed good moldability.
[実施例3]豆腐・ヤマイモ入り鶏つみれの製造
表3に示す組成にて、実施例1の揚げ蒲鉾用組成物に、水切りした木綿豆腐、冷凍とろろおよびつぶしたエダマメを添加して混合し、成形した後、170℃の油で5分間揚げ、豆腐・ヤマイモ入り鶏つみれを製造した。
[Example 3] Manufacture of chicken curd with tofu and yam In the composition shown in Table 3, to the composition for deep-fried rice cake of Example 1, drained cotton tofu, frozen mash and crushed edamame were added and mixed. After molding, it was fried in oil at 170 ° C. for 5 minutes to produce chicken tsunami with tofu and yam.
[実施例4]エビ入り鶏つみれの製造
表4に示す組成にて、実施例1の揚げ蒲鉾用組成物に、冷凍小エビを刻んで添加して混合し、成形した後、170℃の油で5分間揚げ、エビ入り鶏つみれを製造した。
[Example 4] Manufacture of shrimp-filled chicken tsumele After the composition shown in Table 4 was added to the fried salmon composition of Example 1, chopped and mixed with frozen shrimp, molded, and then oiled at 170 ° C And fried for 5 minutes to produce shrimp-filled chicken breast.
[実施例5]ゴボウ天かき揚げの製造
表5に示す組成にて、実施例1の揚げ蒲鉾用組成物に、小麦粉(中力粉)、水および冷凍ささがきゴボウを添加して混合し、成形した後、170℃の油で5分間揚げ、ゴボウ天かき揚げを製造した。
[Example 5] Manufacture of deep-fried burdock oysters In the composition shown in Table 5, wheat flour (medium flour), water and frozen burdock burdock were added to the composition for deep-fried rice cake of Example 1, mixed and molded. After that, deep-fried burdock tempura was produced with 170 ° C. oil for 5 minutes.
実施例3の豆腐・ヤマイモ入り鶏つみれ、実施例4のエビ入り鶏つみれ、および実施例5のゴボウ天かき揚げは、いずれも均一ななめらかさと、弾力のある食感を有していた。 The chicken curd with tofu and yam of Example 3, the chicken curd with shrimp of Example 4, and the burdock fried chicken of Example 5 all had a uniform smoothness and an elastic texture.
以上、詳述したように、本発明により、骨肉分離肉を主材として用いて、成形性が良好で、揚げ蒲鉾の製造に適する揚げ蒲鉾用組成物を提供することができる。
本発明の揚げ蒲鉾用組成物を成形し、150℃〜180℃で加熱して得られた揚げ蒲鉾は、魚肉すり身を主材とする揚げ蒲鉾と同等の食感を有する。
As described above in detail, according to the present invention, it is possible to provide a composition for deep-fried rice cake that has good moldability and is suitable for the production of deep-fried rice cake using bone meat separated meat as a main material.
The deep-fried rice cake obtained by shaping the composition for deep-fried rice cake of the present invention and heating at 150 ° C. to 180 ° C. has a texture equivalent to that of the deep-fried rice cake made mainly from fish meat surimi.
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