JP2018081484A - Film for improving writing performance - Google Patents

Abstract

PROBLEM TO BE SOLVED: To provide a film for improving writing performance that can effectively duplicate the writing performance attainable when physically writing on a piece of paper using a pencil by consistently controlling writing vibration within a predetermined range.SOLUTION: A film is provided to improve writing performance for touch panels, including a film as the base material and a layer for improving writing performance. The layer for improving writing performance comprises a curable composition for forming the layer for improving writing performance which consists of an active energy ray-curable resin as a (A) substance and a filler as a (B) substance. In addition, the filler as the (B) substance contains amorphous silica particles, and the arithmetic average particle diameters of the amorphous silica particles shall have values within the range from 0.5 to 3 μm and at the same time the Cv values of the amorphous silica particles shall be within the range from 50 to 200%.SELECTED DRAWING: Figure 2

Description

The present invention relates to a touch improvement film for a touch panel applied to the surface of the touch panel in order to improve the touch with a touch pen.
In particular, the present invention relates to a writing quality improving film that can stably control writing vibration within a predetermined range and effectively reproduce the writing quality when writing on paper with a pencil.

Conventionally, in various electronic devices, touch panels that serve both as display devices and input means have been widely used.
Particularly in recent years, pen input type touch panels using touch pens as input means have begun to spread, and their use in smartphones, electronic paper, tablet PCs, pen tablets, game machines and the like is rapidly expanding.

However, since the display module of a touch panel is usually hard, the writing taste with a touch pen is very different from the writing taste when writing on paper with a pencil, and it is difficult to say that it is good.
Then, in order to improve the writing taste with a touch pen, the film for applying to the surface of a touchscreen is examined (for example, refer patent documents 1-2).

  That is, Patent Document 1 discloses that an ultraviolet curable resin composition containing a polyfunctional (meth) acrylate and an organic and / or inorganic filler in a plastic film does not contain a leveling agent and is diluted with toluene, acetic acid as a diluent solvent. An antiglare hard coat film is disclosed, which is formed by applying an ultraviolet curable resin composition using at least one selected from the group consisting of butyl and 1-butanol and irradiating with ultraviolet rays. .

  Patent Document 2 discloses a protective film having a thickness of 0.1 to 2 mm that is laminated on a touch surface of a touch input device provided on a display surface of a display, and is a surface of the protective film that becomes a new touch surface. A protective film is disclosed, characterized in that the layer is essentially transparent and made of a soft synthetic resin having self-repairing and scratch resistance.

JP 2012-126804 A (Claims etc.) JP-A-6-180628 (Claims etc.)

  However, although the antiglare hard coat film and the like described in Patent Documents 1 and 2 can improve to some extent the scratch resistance and the self-repairing property when a scratch occurs, The vibration that occurs between the two (hereinafter, sometimes referred to as “writing vibration”) is significantly different from the writing vibration when writing on a paper with a pencil, and thus there is a problem that the writing quality is insufficient.

Therefore, as a result of diligent study, the present inventors, as a writing taste improving layer forming composition for forming a writing quality improving layer, in a writing quality improving film including a base film and a writing quality improving layer, The present invention has been completed by finding that these problems can be solved by using a composition containing an active energy ray-curable resin and amorphous silica particles having a predetermined arithmetic average particle size and Cv value. is there.
That is, an object of the present invention is to provide a writing quality improving film that can stably control writing vibration within a predetermined range and can effectively reproduce writing quality when writing on paper with a pencil. To do.

According to the present invention, a writing quality improving film for a touch panel comprising a base film and a writing quality improving layer,
The writing quality improving layer consists of a cured product of a composition for forming a writing quality improving layer containing an active energy ray-curable resin as the component (A) and a filler as the component (B),
(B) The filler as a component contains amorphous silica particles,
The arithmetic average particle diameter of the amorphous silica particles is a value in the range of 0.5 to 3 μm, and
A writing quality improving film is provided in which the Cv value of the amorphous silica particles is set to a value in the range of 50 to 200%, and the above-described problems can be solved.
That is, according to the writing quality improving film of the present invention, as the writing quality improving layer forming composition for forming the writing quality improving layer, the active energy ray curable resin, the predetermined arithmetic average particle diameter and the Cv value are set. Since the composition containing the amorphous silica particles is used, the writing vibration when writing on a paper with a pencil can be effectively reproduced by stably controlling writing vibration.

Moreover, in composing the writing quality improving film of the present invention, the blending amount of the amorphous silica particles as the component (B) is 5 to 25 with respect to 100 parts by weight of the active energy ray-curable resin as the component (A). A value within the range of parts by weight is preferred.
By comprising in this way, the writing taste when writing with a pencil on paper can be reproduced more effectively, and generation | occurrence | production of glare can also be suppressed more effectively.

Moreover, when comprising the writing quality improvement film of this invention, it is preferable to make arithmetic mean roughness Ra in a writing quality improvement layer into the value within the range of 0.05-0.5 micrometer.
By comprising in this way, the writing taste when writing with a pencil on paper can be reproduced more effectively.

In addition, when composing the writing quality improving film of the present invention, the axis of the touch pen writes the pen tip of the touch pen having a hard felt core having a pen tip diameter of 0.5 mm on the surface of the writing quality improving layer. The touch pen is moved at a speed of 100 mm / min in any direction parallel to the film surface of the taste improving film while being brought into contact with the film surface of the taste improving film at a pressure of 3.92 N so as to be orthogonal to the film surface of the taste improving film. Thus, it is preferable to set the pen tip sliding coefficient when the pen tip resistance is measured to a value in the range of 0.05 to 0.5.
By comprising in this way, the writing taste when writing with a pencil on paper can be reproduced more effectively.

Moreover, in constructing the writing quality improving film of the present invention, the haze value is preferably set to a value within the range of 1 to 40%.
By comprising in this way, the writing taste when writing with a pencil on paper can be reproduced more effectively, and generation | occurrence | production of glare can be suppressed more effectively.

Moreover, when comprising the writing quality improvement film of this invention, it is preferable to make the thickness of a writing quality improvement layer into the value within the range of 0.1-50 micrometers.
By comprising in this way, the writing taste when writing with a pencil on paper can be reproduced more effectively, and generation | occurrence | production of glare can be suppressed more effectively.

Moreover, when comprising the writing quality improvement film of this invention, it is preferable to provide an adhesive layer in the surface on the opposite side to the side in which the writing quality improvement layer in a base film is located.
By comprising in this way, it can apply to the surface of a touch panel easily.

Fig.1 (a)-(b) is a figure provided in order to demonstrate the structure of the writing quality improvement film of this invention. FIG. 2 is a diagram for explaining a method of measuring the pen tip resistance force. FIGS. 3A to 3B show a movement distance (mm) -pen tip resistance (mN) chart and a frequency (Hz) -amplitude (-) chart in the writing quality improving film of Example 2. FIG. FIG. FIG. 4 is a diagram for explaining a display device with a touch panel to which the writing quality improving film of the present invention is applied. FIGS. 5A to 5B show a movement distance (mm) -pen tip resistance (mN) chart and a frequency (Hz) -amplitude (-) chart in the writing quality improving film of Comparative Example 1. FIG. FIG. 6 (a) to 6 (b) show a movement distance (mm) -pen tip resistance (mN) chart and a frequency (Hz) -amplitude (-) chart in the writing quality improving film of Comparative Example 6. FIG. FIG. FIGS. 7A to 7B are charts showing a movement distance (mm) -pen tip resistance (mN) chart and a frequency (Hz) -amplitude (-) chart when writing with a pencil on paper. FIG.

As shown in FIG. 1A, the embodiment of the present invention is a touch improvement film 1 for a touch panel including a base film 20 and a write improvement layer 10,
The writing taste improving layer 10 is composed of a cured product of a composition for forming a writing taste improving layer containing an active energy ray-curable resin as the component (A) and a filler as the component (B),
(B) The filler as a component contains amorphous silica particles,
The arithmetic average particle diameter of the amorphous silica particles is set to a value within the range of 0.5 to 3 μm, and
The writing quality improving film 1 is characterized in that the Cv value of the amorphous silica particles is set to a value in the range of 50 to 200%.
Hereinafter, specific description will be given with reference to the drawings as appropriate.

1. Writing Quality Improvement Layer (1) Composition for Writing Quality Improvement Layer The writing quality improvement layer in the writing quality improvement film of the present invention comprises at least an active energy ray-curable resin as the component (A) and the component (B). And a cured product of a composition for forming a writing quality improving layer, comprising:
Hereinafter, each component contained in the composition for forming a writing quality improving layer will be described.

(1) -1 (A) component: active energy ray-curable resin The type of the active energy ray-curable resin as the component (A) contained in the composition for forming a writing taste improving layer is not particularly limited. However, it can be selected from conventionally known ones, and examples thereof include energy ray-curable monomers, oligomers, resins, and mixtures thereof.
More specifically, it is preferable to use a polyfunctional (meth) acrylic monomer or a (meth) acrylate prepolymer. From the viewpoint of improving the scratch resistance of the resulting writing quality improving layer, It is more preferable to use a functional (meth) acrylic monomer.

In addition, the polyfunctional (meth) acrylic monomer is preferably a bifunctional or higher polyfunctional (meth) acrylic monomer having two or more (meth) acryloyl groups in the molecule, and is scratch resistant. Is more preferably trifunctional or more, and particularly preferably pentafunctional or more. On the other hand, from the viewpoint of suppressing curling of the writing quality improving film, the polyfunctional (meth) acrylic monomer is preferably 20 functional or less, more preferably 12 functional or less, and 9 functional or less. It is particularly preferred.
Moreover, it is preferable that a polyfunctional (meth) acrylic-type monomer is a molecular weight 1000 or less from a compatible viewpoint with another component.

Specific examples of the polyfunctional (meth) acrylic monomer include, for example, 1,4-butanediol di (meth) acrylate, 1,6-hexanediol di (meth) acrylate, and neopentyl glycol di (meth). Acrylate, polyethylene glycol di (meth) acrylate, hydroxypivalate neopentyl glycol di (meth) acrylate, dicyclopentanyl di (meth) acrylate, caprolactone modified dicyclopentenyl di (meth) acrylate, ethylene oxide modified di (meth) phosphate ) Acrylate, allylated cyclohexyl di (meth) acrylate, isocyanurate di (meth) acrylate, trimethylolpropane tri (meth) acrylate, dipentaerythritol tri (meth) acrylate, propionic acid modification Dipentaerythritol tri (meth) acrylate, pentaerythritol tri (meth) acrylate, propylene oxide modified trimethylolpropane tri (meth) acrylate, tris (acryloxyethyl) isocyanurate, propionic acid modified dipentaerythritol penta (meth) acrylate, Examples include dipentaerythritol hexa (meth) acrylate and caprolactone-modified dipentaerythritol hexa (meth) acrylate.
In addition, these may be used individually by 1 type and may be used in combination of 2 or more type.

Examples of the (meth) acrylate-based prepolymer include polyester acrylate-based, epoxy acrylate-based, urethane acrylate-based, polyol acrylate-based, and the like.
Here, as the polyester acrylate-based prepolymer, for example, by esterifying hydroxyl groups of a polyester oligomer having hydroxyl groups at both ends obtained by condensation of a polyvalent carboxylic acid and a polyhydric alcohol with (meth) acrylic acid, or The terminal hydroxyl group of an oligomer obtained by adding alkylene oxide to a polyvalent carboxylic acid can be obtained by esterification with (meth) acrylic acid.
The epoxy acrylate prepolymer can be obtained, for example, by reacting (meth) acrylic acid with an oxirane ring of a relatively low molecular weight bisphenol-type epoxy resin or novolac-type epoxy resin for esterification.
Moreover, a urethane acrylate type prepolymer can be obtained by reaction of polyether polyol or polyester polyol and polyisocyanate, for example.
Furthermore, the polyol acrylate-based prepolymer can be obtained by esterifying the hydroxyl group of the polyether polyol with (meth) acrylic acid.
In addition, these prepolymers may be used individually by 1 type, may be used in combination of 2 or more type, and may be used together with the polyfunctional (meth) acrylate type monomer mentioned above.

(1) -2 (B) component: filler (i) type
In the present invention, the filler as the component (B) contained in the composition for forming a writing quality improving layer contains silica particles.
The reason for this is that, if silica particles are used, the Cv value is sufficiently large, and the uneven shape on the surface of the writing quality improving layer becomes more complicated. Therefore, the writing quality when writing with pencil on paper is effective. This is because it can be reproduced.
Moreover, it is because it is easy to obtain the writing characteristics even if the arithmetic average particle size is small, and thus the occurrence of glare can be effectively suppressed.
As other fillers, for example, particles made of titania, zirconia, tin oxide, indium oxide, cadmium oxide, antimony oxide, or the like may be used in combination.

(Ii) Shape In addition, the shape of the silica particles is indefinite.
The reason for this is that when amorphous silica particles are used, the Cv value is larger than when spherical particles such as spherical particles are used, and the protrusions on the surface of the writing quality improving layer are not filled with filler. This is because it corresponds to a fixed form and it is easy to obtain writing characteristics.
In the present invention, the term “indefinite shape” means not a regular shape such as a spherical shape or an elliptical shape, but a shape having a large number of irregular corners or surfaces.

(Iii) Arithmetic average particle diameter Moreover, the arithmetic average particle diameter of the amorphous silica particle is set to a value within a range of 0.5 to 3 μm.
The reason for this is that when the arithmetic average particle size is less than 0.5 μm, the surface of the writing quality improving layer becomes smooth, making it difficult to effectively reproduce the writing quality when writing with a pencil on paper. This is because there may be cases. On the other hand, when the arithmetic average particle diameter exceeds 3 μm, the protrusion on the surface of the writing quality improving layer becomes too high to overcome the human pen pressure. This is because it may be difficult to reproduce effectively. Alternatively, since the optical action is likely to occur with the pixels of the display, glare is likely to occur.
Therefore, the lower limit value of the arithmetic average particle diameter of the amorphous silica particles is more preferably 0.8 μm or more, and further preferably 1 μm or more.
Further, the upper limit value of the arithmetic average particle diameter of the amorphous silica particles is more preferably 2.5 μm or less, and further preferably 2 μm or less.

(Iv) Cv value Further, the Cv value of the amorphous silica particles is set to a value in the range of 50 to 200%.
This is because when the Cv value is less than 50%, the uneven shape on the surface of the writing quality improving layer becomes monotonous and it may be difficult to obtain sufficient writing quality characteristics. On the other hand, when the Cv value exceeds 200%, the number of particles that do not contribute to writing quality increases, the required amount of particles increases, and glare is likely to occur.
Therefore, the lower limit value of the Cv value of the amorphous silica particles is more preferably 60% or more, and even more preferably 70% or more.
The upper limit value of the Cv value of the amorphous silica particles is more preferably 150% or less, and further preferably 100% or less.

(V) Blending amount The blending amount of the amorphous silica particles is preferably set to a value in the range of 5 to 30 parts by weight with respect to 100 parts by weight of the active energy ray-curable resin as the component (A). .
The reason for this is that when the blending amount is less than 5 parts by weight, the unevenness ratio on the surface of the writing quality improving layer decreases, and it is difficult to effectively reproduce the writing quality when writing with a pencil on paper. This is because it may become. On the other hand, when the amount exceeds 30 parts by weight, glare is likely to occur or the haze value becomes excessively large, and the visibility of the display image on the display is likely to be excessively decreased. Because there is.
Therefore, the lower limit value of the amount of the amorphous silica particles is more preferably 8 parts by weight or more, and even more preferably 10 parts by weight or more.
Further, the upper limit value of the amount of the amorphous silica particles is more preferably 20 parts by weight or less, and further preferably 15 parts by weight or less.

(1) -3 (C) component: leveling agent Moreover, it is preferable that the composition for writing quality improvement layer formation contains a leveling agent as (C) component.
The reason for this is that the inclusion of the leveling agent effectively suppresses the occurrence of streak-like defects or unevenness on the surface of the resulting writing quality improving layer, and the thickness can be controlled uniformly. .
As a result, it is possible to more effectively reproduce the taste of writing on a paper with a pencil.

Examples of the leveling agent include, for example, silicone leveling agents, fluorine leveling agents, acrylic leveling agents, vinyl leveling agents, etc., among others, from the viewpoint of leveling properties and compatibility with other components. Silicone leveling agents and fluorine leveling agents are preferred.
In addition, a leveling agent may be used individually by 1 type, and may be used in combination of 2 or more type.

The silicone leveling agent is preferably polydimethylsiloxane or modified polydimethylsiloxane, and particularly preferably polydimethylsiloxane.
Moreover, as a fluorine-type leveling agent, it is preferable that it is a compound which has a perfluoroalkyl group or a fluorinated alkenyl group in a principal chain or a side chain, As a commercial item, BYK-340 by BYK Japan Co., Ltd., Examples include Footogen 650A manufactured by Neos Co., Ltd., MegaFac RS-75 manufactured by DIC Corporation, V-8FM manufactured by Osaka Organic Chemical Industry Co., Ltd., and the like.

  Further, the amount of the leveling agent is preferably within the range of 0.001 to 10 parts by weight with respect to 100 parts by weight of the active energy ray-curable resin as the component (A). A value within the range of 005 to 5 parts by weight is more preferable, and a value within the range of 0.01 to 3 parts by weight is even more preferable.

(1) -4 (D) Component: Photopolymerization Initiator In addition, from the viewpoint of stably curing the writing taste improving layer, the composition for forming a writing taste improving layer contains a photopolymerization initiator as the component (D). It is preferable.
Examples of the photopolymerization initiator include benzoin, benzoin methyl ether, benzoin ethyl ether, benzoin isopropyl ether, benzoin-n-butyl ether, benzoin isobutyl ether, acetophenone, dimethylaminoacetophenone, 2,2-dimethoxy-2- Phenylacetophenone, 2,2-diethoxy-2-phenylacetophenone, 2-hydroxy-2-methyl-1-phenylpropan-1-one, 1-hydroxycyclohexyl phenyl ketone, 2-methyl-1- [4- (methylthio) Phenyl] -2-morpholino-propan-1-one, 4- (2-hydroxyethoxy) phenyl-2 (hydroxy-2-propyl) ketone, benzophenone, p-phenylbenzophenone, 4,4′-die Tylaminobenzophenone, dichlorobenzophenone, 2-methylanthraquinone, 2-ethylanthraquinone, 2-tertiarybutylanthraquinone, 2-aminoanthraquinone, 2-methylthioxanthone, 2-ethylthioxanthone, 2-chlorothioxanthone, 2,4-dimethylthioxanthone 2,4-diethylthioxanthone, benzyldimethyl ketal, acetophenone dimethyl ketal, p-dimethylaminobenzoate, and the like.
In addition, these may be used individually by 1 type and may be used in combination of 2 or more type.
Moreover, as a compounding quantity of a photoinitiator, it is preferable to set it as the value within the range of 0.2-10 weight part normally with respect to 100 weight part of active energy ray-curable resins as (A) component.

(1) -5 Preparation of composition for forming writing quality improving layer In addition, the composition for forming writing quality improving layer is prepared by adding the above-described components (A) to (D) to an appropriate solvent as necessary. It can be prepared by dissolving or dispersing.
At this time, as components other than the components (A) to (D), for example, an antistatic agent, a surfactant, an antioxidant, an ultraviolet absorber, a silane coupling agent, a light stabilizer, an antifoaming agent, etc. Can be added.
Examples of the solvent used include alcohols such as methanol, ethanol, isopropanol, n-butanol, isobutanol and octanol; ketones such as acetone, methyl ethyl ketone, methyl isobutyl ketone and cyclohexanone; ethyl acetate, butyl acetate and lactic acid Esters such as ethyl and γ-butyrolactone; ethers such as ethylene glycol monomethyl ether (methyl cellosolve), ethylene glycol monoethyl ether (ethyl cellosolve), diethylene glycol monobutyl ether (butyl cellosolve), propylene glycol monomethyl ether; benzene, toluene, xylene And aromatic hydrocarbons such as dimethylformamide, dimethylacetamide, N-methylpyrrolidone and the like.

(2) Thickness It is also preferable to set the thickness of the writing quality improving layer to a value within the range of 0.1 to 50 μm.
This is because, when the thickness is less than 0.1 μm, it may be difficult to ensure sufficient writing characteristics. On the other hand, when the thickness exceeds 50 μm, the writing quality improving film may be easily curled.
Therefore, the lower limit of the thickness of the writing quality improving layer is more preferably 1 μm or more, and further preferably 3 μm or more.
Further, the upper limit of the thickness of the writing quality improving layer is more preferably 20 μm or less, and further preferably 10 μm or less.

2. Base film The type of the base film is not particularly limited. For example, polyester films such as polyethylene terephthalate, polybutylene terephthalate, and polyethylene naphthalate, polyolefin films such as polyethylene film and polypropylene film, cellophane, and diacetyl. Cellulose film, triacetyl cellulose film, acetyl cellulose butyrate film, polyvinyl chloride film, polyvinylidene chloride film, polyvinyl alcohol film, ethylene-vinyl acetate copolymer film, polystyrene film, polycarbonate film, polymethylpentene film, polysulfone Film, polyether ether ketone film, polyether sulfone film, polyether Luimide film, fluororesin film, polyamide film, acrylic resin film, polyurethane resin film, norbornene polymer film, cyclic olefin polymer film, cyclic conjugated diene polymer film, vinyl alicyclic hydrocarbon polymer film, etc. Or a laminated film thereof.
Of these, a polyethylene terephthalate film, a polycarbonate film, a norbornene polymer film, and the like are preferable in terms of mechanical strength and the like.

In addition, in the base film, it is preferable to perform a surface treatment on one or both sides by a primer treatment, an oxidation method, a concavo-convex method or the like for the purpose of improving the adhesion with a layer provided on the surface.
Further, the thickness of the base film is preferably set to a value within the range of 15 to 300 μm, and more preferably set to a value within the range of 30 to 200 μm.

3. Adhesive layer Moreover, as shown in FIG.1 (b), it is preferable to provide the adhesive layer 30 in the surface on the opposite side to the side in which the writing taste improvement layer 10 in the base film 20 is located.
As an adhesive which comprises this adhesive layer, well-known adhesives, such as an acrylic adhesive, a rubber adhesive, a silicone adhesive, can be used, for example.

4). Characteristics (1) Arithmetic average roughness Ra
Moreover, it is preferable to make arithmetic mean roughness Ra in the writing quality improvement layer of a writing quality improvement film into the value within the range of 0.05-0.5 micrometer.
The reason for this is that when the arithmetic average roughness Ra is less than 0.05 μm, there is no protrusion enough to vibrate the pen tip in relation to the human pen pressure. As a result, it becomes difficult to control the writing vibration within a predetermined range, and it becomes difficult to effectively reproduce the writing feeling when writing on paper with a pencil. Note that the arithmetic average roughness Ra is less than 0.05 μm even when gentle irregularities are formed, but in this case, the writing characteristics are obtained to some extent, but glare occurs. On the other hand, when the arithmetic average roughness Ra is a value exceeding 0.5 μm, there are projections that are too large in relation to the human pen pressure. As a result, it is difficult to control the writing vibration within a predetermined range, and it may be difficult to effectively reproduce the writing taste when writing with a pencil on paper.
Therefore, the lower limit value of the arithmetic average roughness Ra in the writing quality improving layer of the writing quality improving film is more preferably 0.15 μm or more, and further preferably 0.22 μm or more.
In addition, the upper limit value of the arithmetic average roughness Ra in the writing quality improving layer of the writing quality improving film is more preferably 0.4 μm or less, and further preferably 0.3 m or less.

(2) Haze value Moreover, it is preferable to make the haze value of a writing quality improvement film into the value within the range of 1-40%.
This is because when the haze value is less than 1%, the protrusion density on the surface of the writing quality improving layer becomes excessively small. As a result, it is difficult to control the writing vibration within a predetermined range, and it may be difficult to reproduce the writing taste when writing on paper with a pencil. On the other hand, when the haze value exceeds 40%, glare is likely to occur, and the visibility of the display image on the display may be excessively lowered.
Therefore, the lower limit value of the haze value of the writing quality improving film is more preferably 8% or more, and further preferably 10% or more.
The upper limit of the haze value of the writing quality improving film is more preferably 35% or less, and further preferably 30% or less.

Here, a mutual complementary relationship between the arithmetic average roughness Ra and the haze value will be described.
First, the arithmetic average roughness Ra tends to be influenced by the presence of large protrusions. In other words, it is possible to grasp whether or not there is a projection having a height that contributes to the writing quality characteristic by the arithmetic average roughness Ra.
However, when only the arithmetic average roughness Ra is used as an index, it is difficult to reliably determine the writing quality characteristic because the projection density cannot be determined.
On the other hand, the haze value is a numerical value linked to the protrusion density, and the haze value increases as the protrusion density increases.
Therefore, by defining the haze value to be greater than or equal to a predetermined value, it is possible to indirectly define the protrusion density that contributes to the writing quality characteristic.
However, when only the haze value is used as an index, the height of the protrusion cannot be determined, so that it is difficult to reliably obtain the writing quality characteristic.
For the above reasons, by defining both the arithmetic average roughness Ra and the haze value, it is possible to effectively define the height and density of the protrusions necessary to obtain excellent writing characteristics. Become.

(3) Writing Taste Characteristics (3) -1 Pen Tip Sliding Coefficient Further, as shown in FIG. 2, the diameter of the pen tip 52 is 0.5 mm with respect to the surface of the writing taste improving layer 10 in the writing taste improving film 1. While touching the nib 52 of the touch pen 50 having the hard felt core with a pressure of 3.92 N (400 gf) so that the axis of the touch pen 50 is orthogonal to the film surface of the writing quality improving film 1. When the pen tip resistance is measured by moving the touch pen 50 in an arbitrary direction parallel to the film surface of the writing quality improving film 1 at a speed of 100 mm / min, the pen tip sliding coefficient is 0.05-0. A value within the range of 5 is preferable.
The reason for this is that when the nib sliding coefficient is less than 0.05, the nib becomes excessively slippery and the nib controllability is liable to deteriorate, and writing when writing with a pencil on paper. This is because it may be difficult to reproduce the taste. On the other hand, when the nib sliding coefficient exceeds 0.5, the nib is likely to be caught excessively, and conversely, the nib controllability tends to be reduced, and when writing with a pencil on paper. This is because it may be difficult to reproduce the writing taste.
Therefore, the lower limit value of the pen tip sliding coefficient is more preferably 0.17 or more, and further preferably 0.19 or more.
The upper limit value of the pen tip sliding coefficient is more preferably set to a value of 0.3 or less, and further preferably set to a value of 0.25 or less.

In the present invention, the “pen tip resistance force” means the resistance force applied to the pen tip when the touch pen is moved under the above-described conditions.
In the present invention, the “pen tip sliding coefficient” means a value obtained by dividing the average value of the maximum value and the minimum value of the “pen tip sliding resistance” by the load (3.92 N).
Further, in the present invention, the “pen nib sliding resistance” means that the influence of the nib initial motion resistance when the pen nib starts to converge in the movement distance (mm) −pen nib resistance (mN) chart, This means the nib resistance when the nib enters a stable sliding state.
Therefore, for example, in the case of the movement distance (mm) -pen nib resistance (mN) chart in the writing quality improving film of Example 2 shown in FIG. 3A, the influence of the nib initial motion resistance is ignored. Since it is small enough to obtain, the nib resistance in the range of the moving distance of 30 mm or more becomes the nib sliding resistance.
In addition, the upper limit value of the moving distance when specifying the pen tip sliding resistance is not particularly limited, but the influence of the pen tip initial movement resistance is usually considered in consideration of fluctuations in the value due to the frictional heat of the pen tip, etc. The position is preferably 50 mm from the converged point.

As described above, the surface shape suitable for the writing quality can be defined by the arithmetic average roughness Ra and the haze value, but it is necessary to consider the influence of the surface material and the like on the actual writing quality.
For example, in the case of a material having high slipperiness and the case of a material that is difficult to slip, even if the surface shape of the writing quality improving layer is the same, the writing quality characteristics are greatly different.
Complementing this is the pen tip sliding coefficient. The force applied to the pen tip as a total can be grasped by the pen tip sliding coefficient.

Here, the measuring method of the pen tip resistance will be described more specifically with an example.
That is, first, as shown in FIG. 2, the writing quality improving film 1 as a measurement object is fixed to the upper surface of the glass plate 40 so that the writing quality improving layer 10 is on the upper side.
Next, after placing the measurement dedicated carriage 70 so as to straddle the writing quality improving film 1, the touch pen 50 is loosely inserted into the through hole 72 provided in the measurement exclusive carriage 70 extending in the vertical direction.
Next, the weight 60 is fixed to the touch pen 50, and the pen tip 52 is brought into contact with the surface of the writing quality improving layer 10 so as to satisfy a pressure condition of a load of 3.92N.
Next, for example, using a detector 100 such as AUTOGRAPH AG-IS 500N manufactured by Shimadzu Corporation, a tension string 90 fixed to the measurement carriage 70 is passed through a pulley 80 in a direction parallel to the film surface. The nib resistance is measured while pulling on D at a speed of 100 mm / min.
In addition, since the force which pushes the pen tip 52 into the writing quality improvement layer 10 becomes strong by setting the pressure condition higher than the pressure condition in normal writing with a load of 3.92 N, the unevenness of the writing quality improvement layer 10 It becomes possible to react to the shape with higher sensitivity, and as a result, even a slight difference in the uneven shape of the writing taste structure layer 10 can be detected.

(3) -2 Nib sliding resistance Further, for the same reason that the above nib sliding coefficient is defined, the average nib sliding resistance is set to a value in the range of 500 to 1000 mN. It is preferable.
Therefore, the lower limit value of the average value of the pen tip sliding resistance is more preferably 520 mN or more, and further preferably 560 mN or more.
The upper limit value of the average value of the pen tip sliding resistance is more preferably 800 mN or less, and even more preferably 700 mN or less.
The average value of the pen tip sliding resistance is the sum of the maximum value and the minimum value of all the pen tip sliding resistance forces existing in the predetermined moving distance section where the pen tip sliding resistance is stable. Means the value divided by the number of them.

Moreover, it is preferable that the difference between the maximum value and the minimum value of the pen tip sliding resistance is set to a value within the range of 10 to 300 mN.
This is because when the difference value is less than 10 mN, the writing vibration becomes excessively small, and it may be difficult to reproduce the writing taste when writing on a paper with a pencil. On the other hand, if the value of the difference exceeds 300 mN, the writing vibration becomes excessively large, and conversely, it may be difficult to reproduce the writing taste when writing with a pencil on paper. .
Therefore, the lower limit of the difference between the maximum value and the minimum value of the pen tip sliding resistance is more preferably 75 mN or more, more preferably 95 mN or more, and 120 mN or more. Is particularly preferred.
The upper limit of the difference between the maximum value and the minimum value of the pen tip sliding resistance is more preferably 200 mN or less, and even more preferably 150 mN or less.

(3) -3 Frequency domain characteristics (i) Amplitude in the frequency range of 1 to 2 Hz In addition, the movement distance (mm) -pen tip resistance force (mN) chart as shown in FIG. In the frequency (Hz) -amplitude (−) chart as shown in FIG. 3B obtained by Fourier transform using Excel (registered trademark), the average value of the amplitude in the frequency range of 1 to 2 Hz is 0. A value in the range of 8 to 3 is preferable.
The reason for this is that when the written vibration is regarded as a superposition of a plurality of vibrations having various frequencies, the characteristic vibration recognized by the human body as “writing quality” is a vibration in the frequency range of 1 to 2 Hz. This is because the inventors of the present invention have found it empirically.
Therefore, by bringing the average value of the amplitude in the frequency range of 1 to 2 Hz close to that when writing with a pencil on paper, the writing quality when writing with a pencil on paper can be effectively reproduced.
Therefore, the lower limit value of the average amplitude value in the frequency range of 1 to 2 Hz is more preferably 1 or more, and even more preferably 1.1 or more.
Further, the upper limit value of the average value of the amplitude in the frequency range of 1 to 2 Hz is more preferably 2 or less, and further preferably 1.6 or less.
The average value of the amplitude means a value obtained by taking the sum of the maximum and minimum values of all amplitudes existing in the target frequency section and dividing the sum by the number.

Moreover, it is preferable that the maximum value of the amplitude in the frequency range of 1 to 2 Hz is a value in the range of 2 to 10.
The reason for this is that when the maximum value is less than 2, the maximum value when writing on a paper with a pencil is too small, and the writing quality when writing with a pencil on paper is effective. This is because it may be difficult to reproduce the image. On the other hand, when the maximum value exceeds 10, it becomes a value that is excessively larger than the maximum value when writing with a pencil on paper, and the writing quality when writing with pencil on paper is effectively reduced. This is because it may be difficult to reproduce.
Therefore, the lower limit value of the maximum amplitude value in the frequency range of 1 to 2 Hz is more preferably 2.5 or more, further preferably 2.7 or more, and 2.8 or more. It is particularly preferable that
In addition, the upper limit value of the maximum amplitude value in the frequency range of 1 to 2 Hz is more preferably 9 or less, and even more preferably 8 or less.

In addition, from the viewpoint of more effectively reproducing the writing taste when writing with a pencil on paper, it is preferable to have at least one peak having an amplitude of 1.5 or more in the frequency range of 1 to 2 Hz. More preferably, the lower limit value is 2 or more, and more preferably 4 or more.
Further, the upper limit value of the number of peaks is preferably 9 or less, and more preferably 8 or less.

(Ii) Amplitude in a frequency range of 2 to 5 Hz It is preferable that a peak having an amplitude of 5 or more is not present in a frequency range of 2 to 5 Hz.
This is because if the frequency range has a peak with an amplitude of 5 or more, a pen tip catching sensation is generated, or a large vibration different from a delicate vibration such as writing quality can be easily felt.

Moreover, it is preferable to make the average value of the amplitude in the range of frequency 2-5Hz into the value within the range of 0.01-1.5.
The reason for this is that when the average value is less than 0.01, the average value is excessively smaller than the average value when writing on paper with a pencil, and the writing quality when writing with pencil on paper is reduced. This is because it may be difficult to reproduce effectively. Moreover, it is because it becomes difficult to control the amplitude in the frequency range of 1 to 2 Hz, and it may be difficult to effectively reproduce the writing taste when written on paper with a pencil. When the value exceeds 1.5, the average value is excessively larger than the average value when writing with pencil on paper, and the writing taste when writing with pencil on paper is effectively reproduced. This may be difficult. Moreover, it is because it becomes difficult to control the amplitude in the frequency range of 1 to 2 Hz, and it may be difficult to effectively reproduce the writing taste when writing on paper with a pencil.
Therefore, the lower limit value of the average value of the amplitude in the frequency range of 2 to 5 Hz is more preferably 0.1 or more, further preferably 0.2 or more, and 0.3 or more. It is particularly preferable that
Further, the upper limit value of the average value of amplitude in the frequency range of 2 to 5 Hz is more preferably 1.2 or less, further preferably 0.8 or less, and 0.6 or less. It is particularly preferable that

Moreover, it is preferable to make the maximum value of the amplitude in the range of frequency 2-5Hz into the value within the range of 0.1-5.
The reason for this is that when the maximum value is less than 0.1, the maximum value is too small when writing on paper with a pencil, and the writing quality when writing with pencil on paper is reduced. This is because it may be difficult to reproduce effectively. Moreover, it is because it becomes difficult to control the amplitude in the frequency range of 1 to 2 Hz, and it may be difficult to effectively reproduce the writing taste when writing on paper with a pencil. On the other hand, when the maximum value exceeds 5, it becomes a value that is excessively larger than the maximum value when writing with a pencil on paper, and the writing quality when writing with pencil on paper is effectively improved. This is because it may be difficult to reproduce. Moreover, it is because it becomes difficult to control the amplitude in the frequency range of 1 to 2 Hz, and it may be difficult to effectively reproduce the writing taste when writing on paper with a pencil.
Therefore, the lower limit value of the maximum amplitude value in the frequency range of 2 to 5 Hz is more preferably 0.6 or more, further preferably 0.8 or more, and 1 or more. It is particularly preferred.
The upper limit value of the maximum amplitude value in the frequency range of 2 to 5 Hz is more preferably 4 or less, further preferably 3 or less, and 2.4 or less. Particularly preferred.

5. Method for producing writing quality improving film As a method for producing the writing quality improving film of the present invention, first, a composition for forming a writing quality improving layer is formed on the surface of a base film by a conventionally known method, for example, a bar coating method, Coating is performed using a knife coating method, a roll coating method, a blade coating method, a die coating method, a gravure coating method, or the like to form a coating film.
Subsequently, after drying a coating film, an active energy ray is irradiated, a coating film is hardened, and a writing quality improvement film is obtained by making a coating film into a writing quality improvement layer.

Moreover, as hardening of a coating film, it is preferable to irradiate active energy rays, such as an ultraviolet-ray and an electron beam, with respect to a coating film.
The ultraviolet irradiation can be performed by a high pressure mercury lamp, a fusion H lamp, a xenon lamp, or the like, and the irradiation amount is preferably set to an illuminance of 50 to 1000 mW / cm ² and a light amount of about 50 to 1000 mJ / cm ² .
On the other hand, the electron beam irradiation can be performed by an electron beam accelerator or the like, and the irradiation amount is preferably about 10 to 1000 krad.

Moreover, by applying the writing quality improving film of the above-described embodiment to the surface of the touch panel, for example, a display device with a touch panel having excellent writing characteristics as shown in FIG. 4 can be configured.
That is, FIG. 4 is a cross-sectional detail view showing an example of the display device 25 with a touch panel to which the writing quality improving film 1 ′ of the present invention is applied, and the display device with a touch panel 25 has the following structure. .
In addition, in the display device 25 with a touch panel, the writing quality improving layer 10 is the uppermost surface.
The LCD module 21 including the backlight unit 14, the polarizing plate 13, the pressure-sensitive adhesive layer 30 c, and the liquid crystal display element (LCD) 12 is attached so that the liquid crystal display element 12 is in contact with the lower surface of the uneven followable laminated member 11. ing.
On the other hand, the lower substrate 18 made of the retardation film 2 with the transparent conductive film 9 is stuck to the upper surface of the uneven followable laminated member 11 so that the retardation film 2 is in contact therewith.
Furthermore, the upper substrate 17 made of the retardation film 5 with the transparent conductive film 6 is laminated on the spacer 7 so that the transparent conductive film 6 is in contact with the spacer 7 so that the air gap 8 is formed.
And the member 16 which consists of the polarizing plate 4 with the adhesive layer 30b is affixed on the retardation film 5 through the adhesive layer 30b.
The touch panel module 22 is obtained by integrating the lower substrate 18, the spacer 7 for forming the air gap 8, the upper substrate 17, and the member 16.
Furthermore, the writing quality improving film 1 ′ with the pressure-sensitive adhesive layer having the pressure-sensitive adhesive layer 30 a on the lower surface is stuck on the polarizing plate 4 in the touch panel module 22 via the pressure-sensitive adhesive layer 30 a. The writing quality improving film 1 ′ has a writing quality improving layer 10 on the upper surface of the base film 20 and an adhesive layer 30 a on the lower surface.

  Hereinafter, the present invention will be described in more detail by way of examples. However, the present invention is not limited to these descriptions.

[Example 1]
1. Production of writing quality improving film (1) Preparation step of composition for forming writing quality improving layer As shown below, (A) active energy ray-curable resin as component, (B) filler as component, C) A leveling agent as the component and a photopolymerization initiator as the component (D) are mixed and diluted with a mixed solvent of propylene glycol monomethyl ether and isobutanol, so that the solid content concentration is 30% by weight. A composition for improving layer formation was prepared.
In addition, the compounding quantity in the following and Table 1 shows the value converted into the pure part.

Component (A): 100 parts by weight of dipentaerythritol hexaacrylate
(Manufactured by Shin-Nakamura Chemical Co., Ltd., NK Ester A-DPH)
Component (B): 9.5 parts by weight of silica particles
(Created by pulverizing silica particles with an average particle size of 7 μm with a ball mill, arithmetic average particle size: 1.5 μm, Cv value: 88%, shape: irregular)
Component (C): 0.1 part by weight of polydimethylsiloxane
(SH28 manufactured by Toray Dow Corning Co., Ltd.)
Component (D): 1 part by weight of 1-hydroxycyclohexyl phenyl ketone
(BASF Corp., Irgacure 184)

Further, the Cv value of the component (B) means a variation coefficient of the particle size distribution represented by the following formula (1).
Cv value (%) = (standard deviation particle diameter / arithmetic average particle diameter) × 100 (1)
Moreover, the arithmetic average particle diameter and Cv value of (B) component were measured using the laser diffraction scattering type particle size distribution measuring apparatus (Horiba Ltd. make, LA-920).
At this time, propylene glycol monomethyl ether was used as a dispersion solvent.

(2) Coating step Next, the obtained composition for forming a writing quality improving layer was applied to an easy-adhesion layer of a PET film with an easy-adhesion layer as a base film (manufactured by Toray Industries, Inc., Lumirror U48, thickness: 125 μm). Application was performed to form an application layer.

(3) Drying process Next, the obtained coating layer was dried under conditions of 70 ° C. for 1 minute using a hot air drying apparatus.

(4) Curing step Next, the dried coating layer is irradiated with ultraviolet rays under the following conditions using an ultraviolet irradiation device (GS Yuasa Corporation, light source: high-pressure mercury lamp) to cure the coating layer. Thus, a final writing quality improving film was obtained as a writing quality improving layer having a thickness of 5 μm.
Lamp power: 1.4kW
Conveyor speed: 1.2 m / min Illuminance: 100 mW / cm ²
Light intensity: 240 mJ / cm ²

2. Evaluation (1) Measurement of nib resistance The nib resistance in the resulting writing quality improving film was measured.
That is, as shown in FIG. 2, the pen tip of a touch pen (manufactured by Wacom Co., Ltd., ACK-2003) provided with a hard felt core having a pen tip diameter of 0.5 mm is applied to the surface of the writing quality improving layer. The touch pen is brought into contact with the film surface of the writing quality improving film in any one direction parallel to the film surface of the writing quality improving film while being brought into contact with the pressure condition of the load 3.92N so that the axis of the touch pen is orthogonal to the film surface of the writing quality improving film. It was moved at a speed of 100 mm / min.
Then, using a detector (manufactured by Shimadzu Corporation, AUTOGRAPH AG-IS 500N), the nib resistance (mN) corresponding to the movement distance (mm) is measured, and the movement distance (mm) −nib resistance. A force (mN) chart was obtained.
Further, from the obtained moving distance (mm) -pen tip resistance (mN) chart, the average value, maximum value, and minimum value of the tip sliding resistance are obtained, and the tip sliding coefficient (-) is calculated. did. The obtained results are shown in Table 1.
In addition, the range of the movement distance when obtaining the average value, the maximum value, and the minimum value was set to a range from the point where the influence of the pen tip initial movement resistance converged to 50 mm. That is, the above-described various analyzes were performed using a moving distance of 30 to 80 mm.

(2) Fourier transform Next, the obtained moving distance (mm) -pen nib resistance (mN) chart is Fourier-transformed using Excel (registered trademark) to obtain a frequency (Hz) -amplitude (-) chart. It was.
Moreover, from the obtained frequency (Hz) -amplitude (-) chart, the average value of the amplitude in the range of 1 to 2 Hz and 2 to 5 Hz, the maximum value, and the number of peaks whose amplitude is greater than or equal to a predetermined value were obtained. The results are shown in Table 1.

(3) Measurement of arithmetic average roughness Ra The arithmetic surface roughness Ra in the obtained writing quality improving film was measured.
That is, using a contact type roughness meter (manufactured by Mitutoyo Corporation, SV3000S4), the arithmetic average roughness Ra (μm) in the writing quality improving layer of the obtained writing quality improving film is compliant with JIS B 0601-1994. And measured. The obtained results are shown in Table 1.

(4) Measurement of haze value The haze value of the obtained writing quality improving film was measured.
That is, using a haze meter (Nippon Denshoku Industries Co., Ltd., NDH2000), the haze value (%) of the obtained writing quality improving film was measured according to JIS K 7136-2000. The obtained results are shown in Table 1.

(5) Evaluation of writing taste (5) -1 Pen tip flow feeling The pen tip flow feeling in the obtained writing taste improving film was evaluated.
That is, the obtained writing quality improving film was fixed on a glass plate so that the writing quality improving layer was on top, and used as a sample.
Next, the panelist was made to perform a predetermined writing operation in a simulated manner with a touch pen (manufactured by Wacom Co., Ltd., ACK-2003) on the sample, and evaluated according to the following criteria to evaluate the pen tip flow feeling. The obtained results are shown in Table 1.
◎: The pen tip does not flow ○: The pen tip slightly flows ×: The pen tip flows too much

(5) -2 Pen tip catch feeling Similarly, the pen tip catch feeling was evaluated according to the following criteria. The obtained results are shown in Table 1.
◎: The pen tip does not feel stuck ○: The pen tip feels slightly stuck ×: The pen tip is too caught

(5) -3 Scratching sound Similarly, the scratching sound was evaluated according to the following criteria. The obtained results are shown in Table 1.
◎: Sounds smooth and smooth ○: Sounds smooth and smooth, but slightly small △: Slightly smooth sound is heard ×: Sounds that are smooth are not heard

(5) -4 Vibration Similarly, vibration was evaluated according to the following criteria. The obtained results are shown in Table 1.
◎: Moderate vibration is transmitted to the hand ○: Vibration is transmitted to the hand but is not satisfactory ×: Vibration transmitted to the hand is too small or too large

(6) Evaluation of glare Generation | occurrence | production of the glare in the obtained writing taste improvement film was evaluated.
That is, first, a lattice-shaped pattern provided with a light transmission portion so as to be 200 ppi (pixels / inch) was prepared.
Such a lattice-shaped pattern was prepared by providing a metal vapor deposition layer on a glass plate, performing a resist treatment on the metal vapor deposition layer, etching, and then removing the resist.
Next, the prepared grid pattern was placed on a backlight (Bright Box 5000, manufactured by King Corp.).
Next, the resulting writing quality improving film was placed on the lattice pattern so that the writing quality improving layer was on top, and the occurrence of glare was confirmed.
Next, the writing quality improving film is moved in a direction parallel to the film surface on the lattice pattern, and when the occurrence of the glare previously confirmed is moved together with the writing quality improving film, the occurrence of the glare is generated. Judging from the writing quality improving film, it was evaluated according to the following criteria. The obtained results are shown in Table 1.
◎: No glare is confirmed ○: Glare is slightly confirmed ×: Glare is remarkably confirmed

[Example 2]
In Example 2, when preparing the composition for forming a writing quality improving layer, the writing quality improving film was the same as in Example 1 except that the blending amount of the silica particles as the component (B) was changed to 10 parts by weight. Were manufactured and evaluated. The obtained results are shown in Table 1. FIG. 3A shows a movement distance (mm) -pen tip resistance (mN) chart, and FIG. 3B shows a frequency (Hz) -amplitude (-) chart.

[Example 3]
In Example 3, a writing quality improving film was prepared in the same manner as in Example 1 except that when the composition for forming a writing quality improving layer was prepared, the blending amount of the silica particles as the component (B) was changed to 12 parts by weight. Were manufactured and evaluated. The obtained results are shown in Table 1.

[Comparative Example 1]
In Comparative Example 1, when preparing the composition for forming a writing quality improving layer, as silica particles as the component (B), Cyclohovic 702 (arithmetic average particle diameter: 4.1 μm) manufactured by Fuji Silysia Chemical Ltd. , Cv value: 48%, shape: amorphous) A writing quality improving film was produced and evaluated in the same manner as in Example 1 except that 8.9 parts by weight were used. The obtained results are shown in Table 1. 5A shows the movement distance (mm) -pen tip resistance chart obtained, and FIG. 5B shows the frequency (Hz) -amplitude (-) chart obtained.

[Comparative Example 2]
In Comparative Example 2, when preparing the composition for forming a writing quality improving layer, PMMA particles (arithmetic average particle size: 3.0 μm, Cv value: 32%, shape: spherical) as resin particles as component (B) A writing quality improving film was produced and evaluated in the same manner as in Example 1 except that 7 parts by weight was used. The obtained results are shown in Table 1.

[Comparative Example 3]
In Comparative Example 3, PMMA particles (arithmetic average particle diameter: 1.5 μm, Cv value: 26%, shape: spherical) were used as resin particles as component (B) when preparing the composition for forming a writing quality improving layer. ) Was used and evaluated in the same manner as in Example 1 except that 1.5 parts by weight was used. The obtained results are shown in Table 1.

[Comparative Example 4]
In Comparative Example 4, a writing quality improving film was prepared in the same manner as in Comparative Example 3, except that when the composition for forming a writing quality improving layer was prepared, the blending amount of the resin particles as the component (B) was changed to 3 parts by weight. Were manufactured and evaluated. The obtained results are shown in Table 1.

[Comparative Example 5]
In Comparative Example 5, a writing quality improving film was prepared in the same manner as in Comparative Example 3, except that when the composition for forming a writing quality improving layer was prepared, the blending amount of the resin particles as the component (B) was changed to 8 parts by weight. Were manufactured and evaluated. The obtained results are shown in Table 1.

[Comparative Example 6]
In Comparative Example 6, a writing quality improving film was prepared in the same manner as in Comparative Example 3, except that when the composition for forming a writing quality improving layer was prepared, the blending amount of the resin particles as the component (B) was changed to 10 parts by weight. Were manufactured and evaluated. The obtained results are shown in Table 1. The obtained results are shown in Table 1. Moreover, the movement distance (mm) -pen nib resistance (mN) chart obtained by Fig.6 (a) is shown, and the frequency (Hz)-amplitude (-) chart obtained by FIG.6 (b) is shown.

[Reference Example 1]
In Reference Example 1, paper (Kokuyo S & T Co., Ltd., Campus Notebook A Ruled-201A) was used instead of the writing quality improving film, and pencil (Mitsubishi Pencil Co., Ltd., Uni, hardness: HB) instead of the touch pen. ) Was used in the same manner as in Example 1 (except for the evaluation of arithmetic average roughness Ra, haze value, and glare). The obtained results are shown in Table 1. Moreover, the movement distance (mm) -pen nib resistance (mN) chart obtained by Fig.7 (a) is shown, and the frequency (Hz)-amplitude (-) chart obtained by FIG.7 (b) is shown.

As described above in detail, according to the present invention, as a composition for forming a writing quality improving layer for forming a writing quality improving layer in a writing quality improving film including a base film and a writing quality improving layer. By using a composition containing an active energy ray-curable resin and amorphous silica particles having a predetermined arithmetic average particle size and Cv value, the writing vibration can be stably controlled within a predetermined range, and the paper It has become possible to effectively reproduce the writing taste when writing with a pencil.
Therefore, the writing quality improving film of the present invention is expected to contribute significantly to improving the writing quality and visibility when inputting with a touch pen on the touch panel.

1: writing quality improving film, 2: phase difference film, 4: polarizing plate, 5: phase difference film, 6: transparent conductive film, 7: spacer, 8: air gap, 9: transparent conductive film, 10: writing quality improvement Layer: 11: Concavity and convexity followable laminated member, 12: Liquid crystal display element (LCD), 13: Polarizing plate, 14: Backlight unit, 16: Member, 17: Upper substrate, 18: Lower substrate, 20: Base film, 22: Touch panel module, 25: Display device with touch panel, 30: Adhesive layer, 40: Glass plate, 50: Touch pen, 52: Pen tip, 60: Weight, 70: Measurement carriage, 72: Through hole, 80: Pulley , 90: tension string, 100: detector

Claims (7)

A writing quality improving film for a touch panel including a base film and a writing quality improving layer,
The writing quality improving layer is composed of a cured product of a composition for forming a writing quality improving layer containing an active energy ray-curable resin as the component (A) and a filler as the component (B).
The filler as the component (B) contains amorphous silica particles,
The arithmetic average particle diameter of the amorphous silica particles is a value in the range of 0.5 to 3 μm, and
A writing quality improving film, wherein the amorphous silica particles have a Cv value in a range of 50 to 200%.   The blending amount of the amorphous silica particles as the component (B) is set to a value within the range of 5 to 25 parts by weight with respect to 100 parts by weight of the active energy ray-curable resin as the component (A). The writing quality improving film according to claim 1.   3. The writing quality improving film according to claim 1, wherein the arithmetic average roughness Ra in the writing quality improving layer is set to a value within a range of 0.05 to 0.5 μm.   The pen tip of the touch pen provided with a hard felt core having a pen tip diameter of 0.5 mm with respect to the surface of the writing quality improving layer so that the axis of the touch pen is perpendicular to the film surface of the writing quality improving film. When the touch pen is moved at a speed of 100 mm / min in any one direction parallel to the film surface of the writing quality improving film while being contacted under a pressure condition of a load of 3.92 N, the pen tip resistance is measured. The writing point improving film according to any one of claims 1 to 3, wherein the pen tip sliding coefficient is set to a value within a range of 0.05 to 0.5.   The writing quality improving film according to any one of claims 1 to 4, wherein a haze value is set to a value within a range of 1 to 40%.   The writing quality improving film according to any one of claims 1 to 5, wherein the writing quality improving layer has a thickness in a range of 0.1 to 50 µm.   The writing quality improving film according to any one of claims 1 to 6, further comprising a pressure-sensitive adhesive layer on a surface opposite to the side on which the writing quality improving layer is located in the base film.