JP2018073681A - Flat sealed battery - Google Patents

Flat sealed battery Download PDF

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JP2018073681A
JP2018073681A JP2016213680A JP2016213680A JP2018073681A JP 2018073681 A JP2018073681 A JP 2018073681A JP 2016213680 A JP2016213680 A JP 2016213680A JP 2016213680 A JP2016213680 A JP 2016213680A JP 2018073681 A JP2018073681 A JP 2018073681A
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gasket
sealing plate
side wall
cylindrical portion
sealed battery
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JP6940861B2 (en
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高司 一村
Takashi Ichimura
高司 一村
陽一 宮田
Yoichi Miyata
陽一 宮田
久保 直人
Naoto Kubo
久保  直人
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Shinsei Kagaku Kogyo Co Ltd
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Shinsei Kagaku Kogyo Co Ltd
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    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10Energy storage using batteries

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Abstract

PROBLEM TO BE SOLVED: To provide a flat sealed battery capable of reducing a resin amount and holding sealing performance by a gasket, while easily forming the gasket.SOLUTION: A flat sealed battery 1 includes: a cylindrical outer can 2 with a bottom having a side wall 21; and a flat surface part 32 that seals a cylinder part 31 of which an outer diameter is smaller than that of the side wall 21 of the outer can 2 and one opening of the cylinder part 31, and comprises: a reverse plate-like sealing plate 3 arranged in the outer can 2 in which the opening part of the cylinder part 31 is opposite to a bottom surface part 22 of the outer can 2; and a gasket 4 arranged between the side wall 21 of the outer can 2 and the cylinder part 31 of the sealing plate 3 air-tightly. The flat sealed battery is formed by sealing a power generation element 5 by the outer can 2, the sealing plate 3, and the gasket 4. The gasket 4 is integrally formed with the outer can 2 by an insert formation across an end part of an upper surface of the bottom surface part 22 from an opening end of an inner side of the side wall 21 of the outer can 2.SELECTED DRAWING: Figure 1

Description

本発明は、コイン形リチウム電池等の扁平状の密閉電池に関する。   The present invention relates to a flat sealed battery such as a coin-type lithium battery.

従来より、側壁を有する有底筒状の外装缶と、該外装缶の側壁よりも外径が小さい筒部と該筒部の一方の開口を塞ぐ平面部とを有し、前記筒部の開口部が前記外装缶の底面部に対向するように外装缶の内方に配置される逆皿状の封口板とを備えた扁平状の密閉電池が知られている。このような扁平状の密閉電池では、例えば特許文献1に開示されるように、電池内部の気密性を保ち且つ外装缶と封口板との電気的な絶縁を確保するために、外装缶と封口板との嵌合部分にガスケットを配置している。さらに、前記特許文献1に開示の密閉電池では、封口板にガスケットをインサート成形している。   Conventionally, it has a bottomed cylindrical outer can having a side wall, a cylindrical portion having an outer diameter smaller than that of the side wall of the outer can, and a flat portion that closes one opening of the cylindrical portion. 2. Description of the Related Art A flat sealed battery is known that includes an inverted dish-shaped sealing plate that is disposed inward of an outer can so that the portion faces the bottom surface of the outer can. In such a flat sealed battery, for example, as disclosed in Patent Document 1, in order to maintain the airtightness inside the battery and to ensure electrical insulation between the outer can and the sealing plate, A gasket is arranged at the mating part with the plate. Furthermore, in the sealed battery disclosed in Patent Document 1, a gasket is insert-molded on the sealing plate.

特開2012−190758号公報JP 2012-190758 A

ところで、前記特許文献1に開示されている構成では、ガスケットは、シール性を考慮して、封口板の筒部の外面と内面を覆うように成形されている。従って、射出成形により封口板にガスケットを一体成形する場合、封口板の筒部の外側及び内側と成形金型との間にガスケットを成形するための空間(キャビティ)を設ける必要がある。
しかしながら、このようにガスケットを成形する場合、型抜きのことを考慮して、封口板の筒部の内側において平面部近くまで樹脂で覆って平坦にする必要がある。その結果、封口板の筒部がキャビティの中間に位置することになり、金型への封口板の位置決めが非常に困難となっていた。
By the way, in the structure currently disclosed by the said patent document 1, in consideration of sealing performance, the gasket is shape | molded so that the outer surface and inner surface of the cylinder part of a sealing board may be covered. Therefore, when the gasket is integrally formed on the sealing plate by injection molding, it is necessary to provide a space (cavity) for molding the gasket between the outside and inside of the cylindrical portion of the sealing plate and the molding die.
However, when the gasket is molded in this way, it is necessary to cover and flatten the resin plate to the vicinity of the flat surface inside the cylindrical portion of the sealing plate in consideration of die cutting. As a result, the cylindrical portion of the sealing plate is positioned in the middle of the cavity, and positioning of the sealing plate to the mold is very difficult.

そこで、特許文献1にも記載されているように、封口板の金型への位置決めとして、ガスケットが形成されない封口板の平面部の外面を受け入れる凹部を可動金型に形成すると共に、封口板の平面部の内面に沿う頭部を有するピンを固定金型の円形穴部に上下動可能に配置させて、可動金型の凹部と固定金型のピンとにより、封口板の平面部を保持して位置決めする。   Therefore, as described in Patent Document 1, as a positioning of the sealing plate to the mold, a concave portion that receives the outer surface of the flat portion of the sealing plate on which the gasket is not formed is formed in the movable mold, and the sealing plate A pin having a head along the inner surface of the flat part is disposed in the circular hole of the fixed mold so as to be movable up and down, and the flat part of the sealing plate is held by the concave part of the movable mold and the pin of the fixed mold. Position.

しかしながら、このような金型を構成するには、金型の構造が複雑となるし、固定金型のピンに封口板を載せて可動金型の凹部を封口板に嵌め合わす際に位置ずれして封口板が損傷したり軸心がずれたりする問題が生じていた。
さらに、封口板の筒部の外側と内側の全体にガスケットを一体成形しなくてはならないので、本来絶縁シールには不要な箇所までガスケットを成形しなくてはならず、無駄な樹脂量が増加していた。さらに、筒部の内側全体に樹脂成形されるので、電池としての内部容量に制限があった。
However, in order to construct such a mold, the structure of the mold becomes complicated, and the position is shifted when the sealing plate is placed on the pin of the fixed mold and the concave portion of the movable mold is fitted to the sealing plate. As a result, the sealing plate is damaged or the shaft is displaced.
Furthermore, since the gasket must be integrally formed on the entire outside and inside of the cylindrical portion of the sealing plate, it is necessary to mold the gasket to places that are not originally required for the insulation seal, which increases the amount of wasted resin. Was. Furthermore, since resin molding is performed on the entire inside of the cylindrical portion, the internal capacity of the battery is limited.

本発明は、上記問題を解決するものであって、封口板と外装缶との間にガスケットが挟み込まれる扁平状の密閉電池において、ガスケットの成形を容易にできながら、樹脂量も軽減でき、ガスケットによるシール性能も保持できる構成とする扁平状の密閉電池を提供することを目的とする。   The present invention solves the above-described problem, and in a flat sealed battery in which a gasket is sandwiched between a sealing plate and an outer can, the gasket can be easily molded and the amount of resin can be reduced. An object of the present invention is to provide a flat sealed battery having a configuration capable of maintaining the sealing performance of the battery.

本発明に係る扁平状の密閉電池は、側壁を有する有底筒状の外装缶と、前記外装缶の側壁よりも外径が小さい筒部と該筒部の一方の開口を塞ぐ平面部とを有し、前記筒部の開口部が前記外装缶の底面部に対向するように前記外装缶の内方に配置される逆皿状の封口板と、前記外装缶の側壁と前記封口板の筒部との間に気密状に挟みこまれて配置されるガスケットとを備え、前記の外装缶、封口板及びガスケットにより発電要素を密閉してなる扁平状の密閉電池であって、前記ガスケットは、前記外装缶の側壁内側の開口端から底面部上面の縁部に亘ってインサート成形により前記外装缶と一体化されていることを特徴とする。   A flat sealed battery according to the present invention includes a bottomed cylindrical outer can having a side wall, a cylindrical portion having an outer diameter smaller than that of the side wall of the outer can, and a flat portion that closes one opening of the cylindrical portion. An inverted dish-shaped sealing plate disposed inside the outer can so that the opening of the cylindrical portion faces the bottom surface of the outer can, and the side wall of the outer can and the cylinder of the sealing plate And a gasket that is sandwiched between and disposed in an airtight manner, and is a flat sealed battery in which a power generation element is sealed by the outer can, the sealing plate, and the gasket, The outer can is integrated with the outer can by insert molding from the opening end inside the side wall to the edge of the upper surface of the bottom surface.

以上の構成により、外装缶の外面を一方の金型に密着させた状態で、外装缶の内側にガスケットを一体成形することが可能となるので、成形時の外装缶の位置決めがし易く、外装缶が補強となってガスケットの強度が高められる。外装缶の内面だけにガスケットを成形するので外装缶の全体を金型で支持することが可能となり、軸心も安定する。その結果、封口板と外装缶の軸心が合わせやすくなる。
さらに、ガスケットの厚みを外装缶の壁面に対して均等にできるので、外装缶のかしめによるガスケットの弾性変形により内側に配置させる封口板の変形を抑えることができ、外装缶の底面部上面の縁部へのガスケットの密着が良好になる。
また、従来のように、封口板の筒部の内側において平面部近くまでガスケットを成形しなくてよくなるので、樹脂量を軽減できる。その結果、樹脂量を軽減できる分、電池の内部容量を増やすことができ、現在の容量を維持または、それよりも大きくできる。
With the above configuration, the gasket can be integrally formed inside the outer can while the outer surface of the outer can is in close contact with one mold, so that the outer can can be easily positioned during molding. The can can be reinforced to increase the strength of the gasket. Since the gasket is formed only on the inner surface of the outer can, the entire outer can can be supported by a mold, and the axis is stable. As a result, the axis of the sealing plate and the outer can can be easily aligned.
Furthermore, since the thickness of the gasket can be made uniform with respect to the wall surface of the outer can, the deformation of the sealing plate placed inside can be suppressed by the elastic deformation of the gasket due to caulking of the outer can, and the edge of the upper surface of the bottom surface of the outer can The gasket adheres well to the part.
Moreover, since it becomes unnecessary to shape | mold a gasket to the plane part vicinity inside the cylinder part of a sealing board like the past, the amount of resin can be reduced. As a result, the amount of resin can be reduced, so that the internal capacity of the battery can be increased, and the current capacity can be maintained or increased.

前記ガスケットは、前記外装缶の開放側に向かって拡径した側壁の内側に一体化され、該外装缶の側壁の開放端部が前記封口板の筒部に向かう方向へかしめられて前記外装缶の側壁と前記封口板の筒部との間に気密状に挟みこまれていることが好ましい。
これにより、封口板と組み合せる前の外装缶の側壁は、開放側に向かって拡径したテーパーになっているので、ガスケットを一体成形した外装缶を金型から型抜きする際も容易に行える。また、ガスケットを一体成形した外装缶は、側壁が開放側に向かって拡径したテーパーになっているので、封口板を外装缶内に組み込み易い。
The gasket is integrated inside a side wall whose diameter is expanded toward the open side of the outer can, and the open end of the side wall of the outer can is caulked in a direction toward the cylindrical portion of the sealing plate, thereby the outer can It is preferable to be sandwiched between the side wall of the sealing plate and the cylindrical portion of the sealing plate in an airtight manner.
As a result, the side wall of the outer can before being combined with the sealing plate has a taper that is increased in diameter toward the open side, so that it can be easily performed when the outer can integrally molded with the gasket is removed from the mold. . Further, since the outer can in which the gasket is integrally formed has a tapered side wall whose diameter increases toward the open side, the sealing plate can be easily incorporated into the outer can.

前記ガスケットは、前記外装缶の底面部縁部に対向する部分に前記封口板の筒部先端部が嵌合する環状凹部と、環状凹部の一部を形成し、外装缶の側壁開口部に向けて突出する環状リブとが形成されていることが好ましい。このように、ガスケットに環状凹部と環状リブが形成されているので、封口板の外装缶に対する位置決めがし易くなり、絶縁シール効果も向上する。   The gasket is formed with an annular recess that fits the tip of the cylindrical portion of the sealing plate at a portion facing the bottom edge of the outer can, and a part of the annular recess, toward the side wall opening of the outer can. It is preferable that an annular rib projecting is formed. Thus, since the annular recess and the annular rib are formed in the gasket, the sealing plate can be easily positioned with respect to the outer can, and the insulating seal effect is improved.

前記ガスケットは、前記環状リブの高さが環状凹部上面を基準として、該ガスケット全体の高さの80%以下とすることが好ましい。このように環状リブの高さを設定することにより、ガスケットを形成する樹脂量を無駄なく、シール効果を上げることができる。   In the gasket, the height of the annular rib is preferably 80% or less of the height of the entire gasket on the basis of the upper surface of the annular recess. By setting the height of the annular rib in this way, the sealing effect can be improved without wasting the amount of resin forming the gasket.

前記外装缶の側壁内側の開口端から底面部上面の縁部に亘って外装缶とガスケットとの密着性を上げる密着層が形成されていることが好ましい。このように外装缶に密着層を形成することにより、ガスケットの外装缶への密着を向上でき、シール効果を上げることができる。   It is preferable that an adhesion layer for improving adhesion between the outer can and the gasket is formed from the opening end inside the side wall of the outer can to the edge of the upper surface of the bottom surface. By forming the adhesion layer on the outer can in this way, the adhesion of the gasket to the outer can can be improved, and the sealing effect can be improved.

以上のように、本発明の扁平状密閉電池によれば、ガスケットの成形を容易にできながら、樹脂量も軽減でき、ガスケットによるシール性能も保持できるという効果が得られる。   As described above, according to the flat sealed battery of the present invention, it is possible to reduce the amount of resin and to maintain the sealing performance of the gasket while facilitating the molding of the gasket.

図1は、本発明の一実施形態にかかる扁平状密閉電池の概略構成を示す断面図である。FIG. 1 is a cross-sectional view showing a schematic configuration of a flat sealed battery according to an embodiment of the present invention. 図2は、封口板(負極缶)に外装缶(正極缶)を嵌合して外装缶の側壁をかしめる前の状態を示す断面図であるFIG. 2 is a cross-sectional view showing a state before the outer can (positive electrode can) is fitted to the sealing plate (negative electrode can) and the side wall of the outer can is caulked. 図3は、封口板(負極缶)に外装缶(正極缶)を嵌合して外装缶の側壁をかしめる状態を示す部分拡大断面図であるFIG. 3 is a partially enlarged cross-sectional view showing a state in which the outer can (positive electrode can) is fitted to the sealing plate (negative electrode can) and the side wall of the outer can is caulked. 図4は、金型で外装缶(正極缶)の側壁内面にガスケットを一体成形する様子を示す断面図である。FIG. 4 is a cross-sectional view showing how a gasket is integrally formed on the inner surface of the side wall of an outer can (positive electrode can) with a mold. 図5は、本発明の他の実施形態にかかる扁平状密閉電池の構成を示す部分拡大断面図である。FIG. 5 is a partially enlarged cross-sectional view showing a configuration of a flat sealed battery according to another embodiment of the present invention.

以下、図面を参照し、本発明の実施の形態を詳しく説明する。なお、各図において同一または同等部分については同一の符号を付している。   Hereinafter, embodiments of the present invention will be described in detail with reference to the drawings. In the drawings, the same or equivalent parts are denoted by the same reference numerals.

本発明の扁平状の密閉電池の一実施形態としてコイン型リチウム電池を示す。
図1に示すように、コイン型電池1は、側壁21を有する有底円筒状の正極缶となる外装缶2と、該外装缶2の開口を覆い、外装缶2の内方に配置される負極缶となる逆皿状の封口板3と、外装缶2の側壁21と封口板3の筒部31との間に配置されるガスケット4と、外装缶2及び封口板3の間に形成される空間内に収納される発電要素5とを備えている。コイン型電池1は、外装缶2と封口板3とを嵌め合わすことによって、全体が扁平なコイン状に形成される。コイン型電池1の外装缶2と封口板3との間に形成される空間内には、発電要素5以外に、非水電解液(図示省略)も封入されている。
A coin-type lithium battery is shown as one embodiment of the flat sealed battery of the present invention.
As shown in FIG. 1, the coin-type battery 1 is disposed inside the outer can 2 so as to cover the outer can 2 that is a bottomed cylindrical positive electrode can having a side wall 21 and the opening of the outer can 2. It is formed between the outer can 2 and the sealing plate 3, the gasket 4 disposed between the side plate 21 of the outer can 2 and the cylindrical portion 31 of the sealing plate 3. And a power generation element 5 housed in the space. The coin-type battery 1 is formed into a flat coin shape by fitting the outer can 2 and the sealing plate 3 together. In addition to the power generation element 5, a non-aqueous electrolyte (not shown) is also enclosed in the space formed between the outer can 2 and the sealing plate 3 of the coin-type battery 1.

外装缶2は、ステンレスなどの金属材料からなり、プレス成形によって有底円筒状に形成されている。外装缶2は、円形状の底面部22と、その外周に該底面部22と連続して形成される円筒状の側壁21とを備えている。側壁21は、図2に示すように、封口板3に向けてかしめる前の状態では、縦断面視で、底面部22に対して外側に広がるテーパー状に形成される。外装缶2は、封口板3との間にガスケット4を挟んだ状態で、側壁21の開口端側が内側に曲げられて、該封口板3の外周部に対してかしめられることにより、側壁21の根元部分が略垂直になる。   The outer can 2 is made of a metal material such as stainless steel and is formed in a bottomed cylindrical shape by press molding. The outer can 2 is provided with a circular bottom surface portion 22 and a cylindrical side wall 21 formed continuously with the bottom surface portion 22 on the outer periphery thereof. As shown in FIG. 2, the side wall 21 is formed in a tapered shape that spreads outward with respect to the bottom surface portion 22 in a longitudinal sectional view before being crimped toward the sealing plate 3. The outer can 2 is bent inward on the opening end side of the side wall 21 with the gasket 4 sandwiched between it and the sealing plate 3, and is caulked against the outer peripheral portion of the sealing plate 3. The root part is almost vertical.

封口板3も、外装缶2と同様、ステンレスなどの金属材料からなり、プレス成形によって有底円筒状に形成されている。封口板3は、円形状の平面部32と、その外周に該平面部32と連続して形成される円筒状の筒部31とを備えている。この筒部31は、平面部32の縁部から拡径する基端部31aと、基端部31aからさらに拡径する段部31bと、段部31bから下方に向けてほぼ垂直に延びる開放部31cとを備える。図1に示すように、この段部31bに対して、外装缶2の側壁21の開口端部が折り曲げられてかしめられる。   The sealing plate 3 is also made of a metal material such as stainless steel like the outer can 2 and is formed into a bottomed cylindrical shape by press molding. The sealing plate 3 includes a circular flat portion 32 and a cylindrical tube portion 31 formed continuously with the flat portion 32 on the outer periphery thereof. The cylindrical portion 31 includes a base end portion 31a that expands from the edge of the flat portion 32, a step portion 31b that further expands from the base end portion 31a, and an open portion that extends substantially vertically downward from the step portion 31b. 31c. As shown in FIG. 1, the open end of the side wall 21 of the outer can 2 is bent and caulked against the step 31b.

ガスケット4は、ポリプロピレン(PP)といった通常のリチウム電池の分野で常用されている熱可塑性樹脂からなる。ガスケット4は、外装缶2の側壁21と封口板3の筒部31との間に挟みこまれるように、外装缶2の側壁21の内面に射出成形されている。ガスケット4の詳しい構成については後述する。なお、ガスケット4の材料としては、PPに限らず、ポリフェニレンサルファイド(PPS)や、ポリテトラフルオロエチレン(PFA)、ポリエーテルエーテルケトン、ポリアミド樹脂などの熱可塑性樹脂から選ばれ、無機添加剤やエラストマーなどで硬度を調整したものを用いてもよい。   The gasket 4 is made of a thermoplastic resin commonly used in the field of a normal lithium battery such as polypropylene (PP). The gasket 4 is injection-molded on the inner surface of the side wall 21 of the outer can 2 so as to be sandwiched between the side wall 21 of the outer can 2 and the cylindrical portion 31 of the sealing plate 3. The detailed configuration of the gasket 4 will be described later. The material of the gasket 4 is not limited to PP, but is selected from thermoplastic resins such as polyphenylene sulfide (PPS), polytetrafluoroethylene (PFA), polyetheretherketone, polyamide resin, and inorganic additives and elastomers. You may use what adjusted hardness, for example.

発電要素5は、正極活物質等を円盤状に成形した正極材51(電極材)と、負極活物質の金属リチウムまたはリチウム合金を円盤状に形成した負極材52と、不織布製のセパレータ53とを備えている。図1に示すように、外装缶2の内方に正極材51が位置付けられ、封口板3の内方に負極材52が位置付けられている。正極材51と負極材52との間にセパレータ53が配置されている。   The power generating element 5 includes a positive electrode material 51 (electrode material) obtained by forming a positive electrode active material or the like into a disk shape, a negative electrode material 52 formed of a metal lithium or a lithium alloy as a negative electrode active material in a disk shape, and a non-woven separator 53. It has. As shown in FIG. 1, the positive electrode material 51 is positioned inside the outer can 2, and the negative electrode material 52 is positioned inside the sealing plate 3. A separator 53 is disposed between the positive electrode material 51 and the negative electrode material 52.

正極材51は、正極活物質として二酸化マンガンを含有している。この正極材51は、二酸化マンガンに、黒鉛、テトラフルオロエチレン−ヘキサフルオロプロピレン共重合体及びヒドロキシプロピルセルロースを混合して調整された正極合剤を円盤状に形成したものであり、所定の剛性及び導電性を有するステンレス鋼等によって構成された正極リング54で保持している。   The positive electrode material 51 contains manganese dioxide as a positive electrode active material. This positive electrode material 51 is formed by forming a positive electrode mixture prepared by mixing manganese dioxide, graphite, tetrafluoroethylene-hexafluoropropylene copolymer and hydroxypropyl cellulose into a disc shape, and has a predetermined rigidity and It is held by a positive electrode ring 54 made of conductive stainless steel or the like.

正極リング54は、正極材51の側面に接する円筒部54aと、該円筒部54aの一端側から該円筒部54aの内方に向かって延びて正極材51の底面に接する円環状のフランジ部54bとが一体形成されたものである。このような構成の正極リング54によって、該正極リング54内の正極材51の径方向及び一端側への変形を規制することができる。そして、正極リング54の円筒部54aの他端側は開放された状態となっているので、正極材51が自由に膨張できるようになっている。よって、放電時に、負極材52の厚みが小さくなっても、正極材51は正極リング54に沿って負極材52側へ膨張するため、該正極材51と負極材52とが離間するのを防止できる。   The positive electrode ring 54 includes a cylindrical portion 54 a that contacts the side surface of the positive electrode material 51, and an annular flange portion 54 b that extends from one end of the cylindrical portion 54 a toward the inside of the cylindrical portion 54 a and contacts the bottom surface of the positive electrode material 51. Are integrally formed. With the positive electrode ring 54 having such a configuration, the deformation of the positive electrode material 51 in the positive electrode ring 54 in the radial direction and one end side can be restricted. Since the other end side of the cylindrical portion 54a of the positive electrode ring 54 is in an open state, the positive electrode material 51 can freely expand. Therefore, even when the thickness of the negative electrode material 52 is reduced during discharge, the positive electrode material 51 expands toward the negative electrode material 52 along the positive electrode ring 54, thereby preventing the positive electrode material 51 and the negative electrode material 52 from separating. it can.

セパレータ53は、ポリブチレンテレフタレート製の繊維を素材とする不織布を用いて構成される。このセパレータ53は、コイン型電池1内で非水電解液によって含浸されている。なお、セパレータ53の厚みは、例えば、約0.3〜0.4mm程度である。   The separator 53 is configured using a non-woven fabric made of fibers made of polybutylene terephthalate. The separator 53 is impregnated with a non-aqueous electrolyte in the coin-type battery 1. Note that the thickness of the separator 53 is, for example, about 0.3 to 0.4 mm.

非水電解液は、例えば、プロピレンカーボネイトと1,2−ジメトキシエタンとを混合した溶液にLiClOを溶解した溶液である。 The non-aqueous electrolyte is, for example, a solution in which LiClO 4 is dissolved in a solution in which propylene carbonate and 1,2-dimethoxyethane are mixed.

図1から図3に示すように、ガスケット4は、外装缶2の側壁21の内側の開口端から底面部22上面の縁部に亘ってインサート成形によりリング状に形成されている。詳しくは、ガスケット4は、側壁21における内側の開口端から底面部22近くまで至る外側シール壁部41と、外側シール壁部41に連続し外装缶2の底面部22上面の縁部に一体に形成される底部シール部42と、この底部シール部42に形成され、封口板3の筒部31先端部が嵌合する環状凹部43と、環状凹部43の一部を形成し、外装缶2の側壁21開口部に向けて突出する環状リブ44とが形成されている。   As shown in FIGS. 1 to 3, the gasket 4 is formed in a ring shape by insert molding from the opening end inside the side wall 21 of the outer can 2 to the edge of the upper surface of the bottom surface portion 22. Specifically, the gasket 4 is integrated with the outer seal wall 41 extending from the inner opening end of the side wall 21 to the vicinity of the bottom surface 22, and the edge of the upper surface of the bottom surface 22 of the outer can 2 continuously to the outer seal wall 41. A bottom seal portion 42 to be formed, an annular recess 43 formed in the bottom seal portion 42 and into which the tip of the cylindrical portion 31 of the sealing plate 3 is fitted, and a part of the annular recess 43 are formed. An annular rib 44 protruding toward the opening of the side wall 21 is formed.

ガスケット4の外側シール壁部41は、図1から図3に示すように、外装缶2の側壁21の内面全面に密着させて根元部分を除き均一の厚みで形成されて、略円筒状に形成されている。また、外側シール壁部41は、図2に示すように、外装缶2の側壁21のテーパーに沿って射出成形されているので、開口端側へ向かうほど、内径が大きくなるように、全体としてテーパー状に形成されている。これにより、外装缶2内に封口板3を組み込み易くすることができる。   As shown in FIGS. 1 to 3, the outer seal wall portion 41 of the gasket 4 is formed in a substantially cylindrical shape by being in close contact with the entire inner surface of the side wall 21 of the outer can 2 and having a uniform thickness except for the root portion. Has been. Further, as shown in FIG. 2, the outer seal wall portion 41 is injection-molded along the taper of the side wall 21 of the outer can 2, so that the inner diameter becomes larger toward the opening end side as a whole. It is formed in a taper shape. Thereby, the sealing plate 3 can be easily incorporated into the outer can 2.

外側シール壁部41は、外装缶2の側壁21をかしめることにより、封口板3の筒部31の開放部31c及び段部31bを覆うとともに、基端部31aの段部31b側に押し付けられる。外側シール壁部41のうち、封口板3に対して外装缶2がかしめられた際に筒部31の段部31bに対向する部分は、図1及び図3に示すように、外装缶2の側壁21の開口端部と筒部31の段部31bによって圧縮される。これにより、外側シール壁部41によって、外装缶2と封口板3との間がシールされる。また、上記かしめによりテーパー状に拡径していた外装缶2の側壁21が略垂直となり、外側シール壁部41が封口板3の筒部31と密着してシールされる。   The outer seal wall portion 41 covers the open portion 31c and the step portion 31b of the cylindrical portion 31 of the sealing plate 3 by caulking the side wall 21 of the outer can 2 and is pressed against the step portion 31b side of the base end portion 31a. . A portion of the outer seal wall portion 41 that faces the step portion 31b of the cylindrical portion 31 when the outer can 2 is caulked against the sealing plate 3, as shown in FIGS. 1 and 3, Compressed by the open end of the side wall 21 and the step 31 b of the cylindrical portion 31. Thereby, the space between the outer can 2 and the sealing plate 3 is sealed by the outer seal wall portion 41. Further, the side wall 21 of the outer can 2 that has been enlarged in a taper shape by caulking becomes substantially vertical, and the outer seal wall portion 41 is in close contact with the cylindrical portion 31 of the sealing plate 3 and sealed.

ガスケット4の底部シール部42には、環状凹部43と環状リブ44が形成されており、環状凹部43は、封口板3の筒部31開放部31cの厚みとほぼ同じ溝幅に形成している。なお、環状凹部43の溝幅は、筒部31開放部31cの厚みよりも大きくしてもよいし、やや狭くしてもよい。
環状リブ44は、その高さがガスケット4の全体高さの0%超80%以下とすることが好ましい。さらに好ましくは、環状リブ44の高さはガスケット4の全体高さの10%以上50%以下とすることが好ましい。このように環状リブ44の高さを設定することにより、ガスケット4を形成する樹脂量の無駄をできるだけ少なくして、シール効果を上げることができる。
An annular recess 43 and an annular rib 44 are formed in the bottom seal portion 42 of the gasket 4, and the annular recess 43 is formed to have a groove width substantially the same as the thickness of the cylindrical portion 31 opening portion 31 c of the sealing plate 3. . In addition, the groove width of the annular recess 43 may be larger than the thickness of the cylindrical portion 31 opening portion 31c, or may be slightly narrower.
The height of the annular rib 44 is preferably more than 0% and not more than 80% of the total height of the gasket 4. More preferably, the height of the annular rib 44 is 10% or more and 50% or less of the total height of the gasket 4. By setting the height of the annular rib 44 in this way, it is possible to reduce the waste of the amount of resin forming the gasket 4 as much as possible and improve the sealing effect.

この環状凹部43に封口板3の筒部31開放部31cの先端部を圧入状態で嵌め込むことにより、外装缶2に対する封口板3の位置決めを容易に行えるし、環状凹部43に筒部31先端部を圧入するので、外装缶2と封口板3との間が確実にシールされる。また、環状リブ44によりガスケット4の強度も向上される。   By fitting the distal end portion of the cylindrical portion 31 open portion 31c of the sealing plate 3 into the annular concave portion 43 in a press-fitted state, the sealing plate 3 can be easily positioned with respect to the outer can 2, and the distal end portion of the cylindrical portion 31 is inserted into the annular concave portion 43. Since the portion is press-fitted, the space between the outer can 2 and the sealing plate 3 is reliably sealed. Further, the strength of the gasket 4 is improved by the annular rib 44.

以上の構成において、図3に矢印で示すように、封口板3の段部31bに対して外装缶2の側壁21の開口端部をかしめると、ガスケット4の外側シール壁部41は、外装缶2の側壁21の開口端部によって圧縮されるとともに、該筒部31側に押し付けられる。これにより、外側シール壁部41は、外装缶2の側壁21と封口板3の筒部31との間に挟みこまれてシールとして機能する。また、外装缶2の側壁21のかしめにより、封口板3の筒部31が下方に向けて押圧されて、筒部31が環状凹部43内で下方に押し付けられて、ガスケット4の底部シール部42により外装缶2の底面部22と封口板3の筒部31との間がシールされる。このように、外側シール壁部41の筒部31の段部31b上に位置する部分と、ガスケット4の底部シール部42とにより、封口板3と外装缶2との間に形成される空間を外部の空間に対してシールされて隔離状態が維持される。   In the above configuration, as shown by an arrow in FIG. 3, when the opening end portion of the side wall 21 of the outer can 2 is caulked against the step portion 31 b of the sealing plate 3, the outer seal wall portion 41 of the gasket 4 is While being compressed by the open end of the side wall 21 of the can 2, it is pressed against the cylindrical portion 31. Thus, the outer seal wall portion 41 is sandwiched between the side wall 21 of the outer can 2 and the cylindrical portion 31 of the sealing plate 3 and functions as a seal. Further, the cylindrical portion 31 of the sealing plate 3 is pressed downward by caulking of the side wall 21 of the outer can 2, and the cylindrical portion 31 is pressed downward in the annular recess 43, so that the bottom seal portion 42 of the gasket 4 is pressed. Thus, the space between the bottom surface portion 22 of the outer can 2 and the cylindrical portion 31 of the sealing plate 3 is sealed. Thus, a space formed between the sealing plate 3 and the outer can 2 by the portion located on the step portion 31 b of the cylindrical portion 31 of the outer seal wall portion 41 and the bottom seal portion 42 of the gasket 4. It is sealed against the external space and maintained in isolation.

次に、コイン型電池1の製造方法を、図2及び図4に基づいて説明する。
まず、プレス成形によって、封口板3及び外装缶2を、それぞれ形成する。次に、図4に示すように、外装缶2の側壁21の内面側にガスケット4を射出成形する。この射出成形の様子を、図4を用いて以下で説明する。
Next, a method for manufacturing the coin-type battery 1 will be described with reference to FIGS.
First, the sealing plate 3 and the outer can 2 are respectively formed by press molding. Next, as shown in FIG. 4, the gasket 4 is injection-molded on the inner surface side of the side wall 21 of the outer can 2. The state of this injection molding will be described below with reference to FIG.

図4に示すように、固定金型6と可動金型7とを備え、固定金型6には外装缶2の外形に沿い、外装缶2が嵌められる円形凹部61が形成されている。また、固定金型6には、円形凹部61の中心部に突出可能に可動ピン62が設けられており、この可動ピン62により固定金型から外装缶2を型抜きするようになっている。可動金型7には、外装缶2の底面部22の上面に接触させる円形凸部71が形成され、固定金型6の円形凹部61内に配置させた外装缶2と円形凸部71との間にガスケット4を形成するためのキャビティ72が形成される。   As shown in FIG. 4, a fixed mold 6 and a movable mold 7 are provided, and the fixed mold 6 is formed with a circular recess 61 in which the outer can 2 is fitted along the outer shape of the outer can 2. Further, the fixed mold 6 is provided with a movable pin 62 so as to be able to protrude at the center of the circular concave portion 61, and the movable can 62 is used to punch out the outer can 2 from the fixed mold. The movable mold 7 is formed with a circular convex portion 71 that is brought into contact with the upper surface of the bottom surface portion 22 of the outer can 2, and between the outer can 2 and the circular convex portion 71 disposed in the circular concave portion 61 of the fixed mold 6. A cavity 72 for forming the gasket 4 is formed therebetween.

固定金型6の円形凹部61内に外装缶2を配置させた状態で可動金型7を閉じることにより、ガスケット4を形成するためのキャビティ72が形成され、このキャビティ72にガスケット4材料の溶融樹脂を注入することにより、ガスケット4が外装缶2の側壁21の内面側に一体に形成される。なお、外装缶2の側壁21内側の開口端から底面部22上面の縁部に亘って外装缶2とガスケット4との密着性を上げる密着層を形成することが好ましい。外装缶2の側壁21内側全面に密着層を形成することでもよい。この密着層はガスケットの素材および金属双方との密着性がある素材、例えばマレイン酸変性ポリプロピレン、クロロスルフォン化ポリエチレンなどより適宜選定される。このように、外装缶2に密着層を形成しておくことにより、外装缶2へのガスケット4の密着を良好にすることができる。   A cavity 72 for forming the gasket 4 is formed by closing the movable mold 7 in a state where the outer can 2 is disposed in the circular recess 61 of the fixed mold 6, and melting of the material of the gasket 4 is formed in the cavity 72. By injecting the resin, the gasket 4 is integrally formed on the inner surface side of the side wall 21 of the outer can 2. In addition, it is preferable to form the contact | adherence layer which raises the adhesiveness of the exterior can 2 and the gasket 4 from the opening edge inside the side wall 21 of the exterior can 2 to the edge part of the bottom face part 22 upper surface. An adhesion layer may be formed on the entire inner surface of the side wall 21 of the outer can 2. This adhesion layer is appropriately selected from materials having adhesion to both the gasket material and the metal, such as maleic acid-modified polypropylene and chlorosulfonated polyethylene. Thus, by forming the adhesion layer on the outer can 2, the adhesion of the gasket 4 to the outer can 2 can be improved.

ガスケット4の射出成形が終了すると、可動金型7が取り外され、そして、固定金型6の可動ピン62を軸方向(図4中の白抜き矢印方向)に移動させることにより、ガスケット4が射出成形された外装缶2を固定金型6から脱離させる。このようにして、外装缶2の側壁21にガスケット4が射出成形された部品が得られる。   When the injection molding of the gasket 4 is completed, the movable mold 7 is removed, and the movable pin 62 of the fixed mold 6 is moved in the axial direction (the direction of the white arrow in FIG. 4), whereby the gasket 4 is injected. The molded outer can 2 is detached from the fixed mold 6. In this manner, a part in which the gasket 4 is injection molded on the side wall 21 of the outer can 2 is obtained.

ここで、固定金型6は、外側シール壁部41の外周面を成形する部分及び外装缶2の側壁21が、開放部に向けて徐々に内径が大きくなるようなテーパー状に形成されているので可動ピン62によって外装缶2を押した時に容易に固定金型6から外装缶2を脱離させることができる。
また、可動金型7の円形凸部71も先端部の径が徐々に小さくなるようなテーパーに形成されているので、可動金型7の離脱も容易に行える。
Here, the fixed mold 6 is formed in a taper shape in which the portion forming the outer peripheral surface of the outer seal wall portion 41 and the side wall 21 of the outer can 2 gradually increase in inner diameter toward the open portion. Therefore, the outer can 2 can be easily detached from the fixed mold 6 when the outer can 2 is pushed by the movable pin 62.
Further, since the circular convex portion 71 of the movable mold 7 is also tapered so that the diameter of the tip portion gradually decreases, the movable mold 7 can be easily detached.

次に、図2に示すように、封口板3を、平面部32が下側になるように配置する。そして、封口板3の内面に負極材52を導電性接着剤等で固定した後、該負極材52の上にセパレータ53及び正極材51を重ねて配置する。   Next, as shown in FIG. 2, the sealing plate 3 is disposed so that the flat portion 32 is on the lower side. And after fixing the negative electrode material 52 to the inner surface of the sealing board 3 with a conductive adhesive etc., the separator 53 and the positive electrode material 51 are piled up on this negative electrode material 52, and are arrange | positioned.

次に、封口板3内に非水電解液を注入し、該封口板3に対してガスケット4が射出成形された外装缶2を被せる。このとき、封口板3の筒部31の先端部をガスケット4の環状凹部43に差し込むことにとより、封口板3の筒部31と外装缶2の側壁21との間にガスケット4を挟みこんだ状態となる。そして、外装缶2の側壁21の開口端部を、封口板3の段部31bを覆うように外装缶2の内側に折り曲げてかしめる。   Next, a non-aqueous electrolyte is injected into the sealing plate 3, and the outer can 2 on which the gasket 4 is injection-molded is placed on the sealing plate 3. At this time, the gasket 4 is sandwiched between the cylindrical portion 31 of the sealing plate 3 and the side wall 21 of the outer can 2 by inserting the tip of the cylindrical portion 31 of the sealing plate 3 into the annular recess 43 of the gasket 4. It becomes a state. And the opening edge part of the side wall 21 of the armored can 2 is bent and crimped inside the armored can 2 so that the step part 31b of the sealing board 3 may be covered.

これにより、ガスケット4は、図1に示すように、外装缶2の側壁21と封口板3の筒部31との間に挟みこまれた状態となる。すなわち、上述のような製造方法によって、ガスケット4の外側シール壁部41は、封口板3の段部31bと外装缶2の側壁21の開口端部との間に挟みこまれる。また、封口板3の筒部31先端部がガスケット4の環状凹部43に嵌め込まれることにより、ガスケット4の底部シール部42が封口板3の筒部31と外装缶2の底面部22との間に挟みこまれる。このようにして、図1に示すような構成のコイン型電池1が得られる。   Thereby, the gasket 4 will be in the state pinched | interposed between the side wall 21 of the armored can 2, and the cylinder part 31 of the sealing board 3, as shown in FIG. That is, the outer sealing wall portion 41 of the gasket 4 is sandwiched between the step portion 31 b of the sealing plate 3 and the opening end portion of the side wall 21 of the outer can 2 by the manufacturing method as described above. Further, the end portion of the cylindrical portion 31 of the sealing plate 3 is fitted into the annular recess 43 of the gasket 4, so that the bottom seal portion 42 of the gasket 4 is located between the cylindrical portion 31 of the sealing plate 3 and the bottom surface portion 22 of the outer can 2. Sandwiched between. In this way, a coin-type battery 1 having a configuration as shown in FIG. 1 is obtained.

以上の構成により、外装缶2の外面全体を一方の固定金型6に密着させた状態で、外装缶2の内側にガスケット4を一体成形するので、ガスケット4の成形時の外装缶2の位置決めがし易く、外装缶2が補強となってガスケット4の強度が高められる。また、外装缶2の内面だけにガスケット4を成形するので外装缶2の外面全体を固定金型6で支持することが可能となり、軸心も安定する。その結果、封口板3と外装缶2の同軸が合わせやすくなる。   With the above configuration, since the gasket 4 is integrally molded inside the outer can 2 with the entire outer surface of the outer can 2 being in close contact with one fixed mold 6, the positioning of the outer can 2 at the time of molding the gasket 4. The outer can 2 is reinforced and the strength of the gasket 4 is increased. Further, since the gasket 4 is formed only on the inner surface of the outer can 2, the entire outer surface of the outer can 2 can be supported by the fixed mold 6, and the axis is stable. As a result, the sealing plate 3 and the outer can 2 can be easily aligned with each other.

さらに、ガスケット4の厚みを外装缶2の側壁21に対して薄い肉厚で均等にできるので、外装缶2のかしめによるガスケット4の弾性変形により内側に配置させる封口板3の変形を抑えることができ、外装缶2の内側角部(底面部22上面の周縁)へのガスケット4の密着も良好になる。また、外装缶2の側壁21は、開放側に向かって拡径したテーパーになっているので、外装缶2を金型から型抜きする際も容易に行える。封口板3への組み込みも容易に行える。   Furthermore, since the thickness of the gasket 4 can be made uniform with a small thickness with respect to the side wall 21 of the outer can 2, it is possible to suppress deformation of the sealing plate 3 disposed on the inside by elastic deformation of the gasket 4 due to caulking of the outer can 2. In addition, the adhesion of the gasket 4 to the inner corner of the outer can 2 (periphery of the upper surface of the bottom portion 22) is improved. Further, since the side wall 21 of the outer can 2 has a taper that is expanded toward the open side, the outer can 2 can be easily removed from the mold. Incorporation into the sealing plate 3 can be easily performed.

また、従来のように、封口板3の筒部31の内側深くに至るまでガスケットを成形しなくてよくなるので、樹脂量を軽減できる。その結果、樹脂量を軽減できる分、電池の内部容量を増やすことができ、現在の容量を維持または、それよりも大きくできる。
さらに、ガスケット4に環状凹部43と環状リブ44が形成されているので、封口板3の位置決めがし易くなり、絶縁シール効果も向上する。
Moreover, since it becomes unnecessary to shape | mold a gasket until it goes deep inside the cylinder part 31 of the sealing board 3 like the past, the amount of resin can be reduced. As a result, the amount of resin can be reduced, so that the internal capacity of the battery can be increased, and the current capacity can be maintained or increased.
Furthermore, since the annular recess 43 and the annular rib 44 are formed in the gasket 4, the sealing plate 3 can be easily positioned and the insulating sealing effect is improved.

以上、本発明の実施形態の一つを説明したが、上述した実施形態は本発明を実施するための例示に過ぎない。よって、本発明は上述した実施の形態に限定されることなく、その趣旨を逸脱しない範囲内で上述した実施の形態を適宜変形して実施することが可能である。   Although one embodiment of the present invention has been described above, the above-described embodiment is merely an example for carrying out the present invention. Therefore, the present invention is not limited to the above-described embodiment, and can be implemented by appropriately modifying the above-described embodiment without departing from the spirit thereof.

例えば、図5に示すように、ガスケット4は、前記実施形態と同様に外側シール壁部41と底部シール部42とを設けるが、環状凹部43及び環状リブ44を形成しないようにすることができる。この場合、外装缶開口部を内径側及び下方向へ加圧してカシメをおこなう。封口板3の筒部31先端部を底部シール部42に押し付けるようにして、封口板先端部をガスケットの底部へ食い込ませる。このように構成することによっても、ガスケット4の外側シール壁部41と底部シール部42とにより封口板3と外装缶2との間を2箇所でシールすることができる。   For example, as shown in FIG. 5, the gasket 4 is provided with the outer seal wall portion 41 and the bottom seal portion 42 as in the above-described embodiment, but the annular recess 43 and the annular rib 44 can be prevented from being formed. . In this case, caulking is performed by pressurizing the outer can opening to the inner diameter side and downward. The front end portion of the cylindrical plate 31 of the sealing plate 3 is pressed against the bottom seal portion 42 so that the front end portion of the sealing plate bites into the bottom portion of the gasket. Also with this configuration, the sealing plate 3 and the outer can 2 can be sealed at two locations by the outer seal wall portion 41 and the bottom seal portion 42 of the gasket 4.

また、前記実施形態では、正極材51の正極活物質として二酸化マンガンを含有した材料を用いていて、負極材52の負極活物質として金属リチウムまたはリチウム合金を用いている。しかしながら、正極活物質または負極活物質として機能する材料であれば、これ以外のものを正極材51及び負極材52として用いてもよい。   In the embodiment, a material containing manganese dioxide is used as the positive electrode active material of the positive electrode material 51, and metallic lithium or a lithium alloy is used as the negative electrode active material of the negative electrode material 52. However, any other material that functions as a positive electrode active material or a negative electrode active material may be used as the positive electrode material 51 and the negative electrode material 52.

前記実施形態では、外装缶2を正極缶とし、封口板3を負極缶としたかが、逆に正極缶が封口板で、負極缶が外装缶であってもよい。
前記実施形態では、封口板3及び外装缶2を、それぞれ有底円筒状に形成して、コイン型電池1をコイン状に形成したが、この限りではなく、扁平形電池を、多角柱状など、円柱状以外の形状に形成してもよい。
In the embodiment, whether the outer can 2 is a positive electrode can and the sealing plate 3 is a negative electrode can, conversely, the positive electrode can may be a sealing plate and the negative electrode can may be an outer can.
In the above embodiment, the sealing plate 3 and the outer can 2 are each formed in a bottomed cylindrical shape, and the coin-type battery 1 is formed in a coin shape. You may form in shapes other than column shape.

本発明の扁平形密閉電池は、ガスケットを用いるあらゆる扁平状の密閉電池に良好に適用できるものである。   The flat sealed battery of the present invention can be suitably applied to any flat sealed battery using a gasket.

1 コイン型電池
2 外装缶
3 封口板
4 ガスケット
5 発電要素
6 固定金型
7 可動金型
21 側壁
22 底面部
31 筒部
31a 基端部
31b 段部
31c 開放部
32 平面部
41 外側シール壁部
42 底部シール部
43 環状凹部
44 環状リブ
51 正極材
52 負極材
53 セパレータ
54 正極リング
54a 円筒部
54b フランジ部
61 円形凹部
62 可動ピン
71 円形凸部
72 キャビティ
DESCRIPTION OF SYMBOLS 1 Coin type battery 2 Exterior can 3 Sealing plate 4 Gasket 5 Power generation element 6 Fixed mold 7 Movable mold 21 Side wall 22 Bottom face part 31 Tube part 31a Base end part 31b Step part 31c Open part 32 Plane part 41 Outer seal wall part 42 Bottom seal portion 43 Annular recess 44 Annular rib 51 Positive electrode material 52 Negative electrode material 53 Separator 54 Positive electrode ring 54a Cylindrical portion 54b Flange portion 61 Circular recess 62 Movable pin 71 Circular protrusion 72 Cavity

Claims (5)

側壁を有する有底筒状の外装缶と、
前記外装缶の側壁よりも外径が小さい筒部と該筒部の一方の開口を塞ぐ平面部とを有し、前記筒部の開口部が前記外装缶の底面部に対向するように前記外装缶の内方に配置される逆皿状の封口板と、
前記外装缶の側壁と前記封口板の筒部との間に気密状に挟みこまれて配置されるガスケットとを備え、
前記の外装缶、封口板及びガスケットにより発電要素を密閉してなる扁平状の密閉電池であって、
前記ガスケットは、前記外装缶の側壁内側の開口端から底面部上面の縁部に亘ってインサート成形により前記外装缶と一体化されていることを特徴とする扁平状の密閉電池。
A bottomed cylindrical outer can having a side wall;
The outer casing has a cylindrical portion having an outer diameter smaller than that of the side wall of the outer can and a flat portion that blocks one opening of the cylindrical portion, and the outer opening of the outer casing can face the bottom surface of the outer can. An inverted dish-shaped sealing plate placed inside the can;
A gasket that is arranged in an airtight manner between the side wall of the outer can and the cylindrical portion of the sealing plate,
A flat sealed battery in which a power generation element is sealed by the outer can, the sealing plate and the gasket,
The flat sealed battery according to claim 1, wherein the gasket is integrated with the outer can by insert molding from an opening end inside the side wall of the outer can to an edge of the upper surface of the bottom surface.
前記ガスケットは、前記外装缶の開放側に向かって拡径した側壁の内側に一体化され、該外装缶の側壁の開放端部が前記封口板の筒部に向かう方向へかしめられて前記外装缶の側壁と前記封口板の筒部との間に気密状に挟みこまれている請求項1記載の扁平状の密閉電池。   The gasket is integrated inside a side wall whose diameter is expanded toward the open side of the outer can, and the open end of the side wall of the outer can is caulked in a direction toward the cylindrical portion of the sealing plate, thereby the outer can The flat sealed battery according to claim 1, which is sandwiched between the side wall of the sealing plate and the cylindrical portion of the sealing plate in an airtight manner. 前記ガスケットは、前記外装缶の底面部上面の縁部に対向する部分に前記封口板の筒部先端部が嵌合する環状凹部と、該環状凹部の一部を形成し、前記外装缶の側壁開口部に向けて突出する環状リブとが形成されている請求項1又は2に記載の扁平状の密閉電池。   The gasket forms an annular recess that fits the tip of the cylindrical portion of the sealing plate at a portion facing the edge of the upper surface of the bottom surface of the outer can, and a part of the annular recess, and the side wall of the outer can The flat sealed battery according to claim 1, wherein an annular rib protruding toward the opening is formed. 前記ガスケットは、前記環状リブの高さが前記環状凹部上面を基準として、該ガスケット全体の高さの80%以下である請求項3に記載の扁平状の密閉電池。   4. The flat sealed battery according to claim 3, wherein the gasket has a height of the annular rib that is 80% or less of a height of the entire gasket with respect to the top surface of the annular recess. 前記外装缶の側壁内側の開口端から底面部上面の縁部に亘って外装缶とガスケットとの密着性を上げる密着層が形成されている請求項1〜4の何れか1項に記載の扁平状の密閉電池。   The flatness of any one of Claims 1-4 in which the adhesion layer which raises the adhesiveness of an exterior can and a gasket is formed from the opening edge inside the side wall of the said exterior can to the edge of the upper surface of a bottom face part. Sealed battery.
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Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH08124545A (en) * 1994-10-20 1996-05-17 Seiko Instr Inc Button type battery and manufacture of gasket therefor
JPH09129201A (en) * 1995-10-31 1997-05-16 Matsushita Electric Ind Co Ltd Sealed battery
JPH09171803A (en) * 1995-12-21 1997-06-30 Matsushita Electric Ind Co Ltd Manufacture of sealing packing for battery
JP2008097882A (en) * 2006-10-06 2008-04-24 Sumitomo Electric Fine Polymer Inc Gasket, sealed secondary battery, and electrolytic capacitor
WO2014050056A1 (en) * 2012-09-28 2014-04-03 パナソニック株式会社 Nonaqueous electrolytic battery

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH08124545A (en) * 1994-10-20 1996-05-17 Seiko Instr Inc Button type battery and manufacture of gasket therefor
JPH09129201A (en) * 1995-10-31 1997-05-16 Matsushita Electric Ind Co Ltd Sealed battery
JPH09171803A (en) * 1995-12-21 1997-06-30 Matsushita Electric Ind Co Ltd Manufacture of sealing packing for battery
JP2008097882A (en) * 2006-10-06 2008-04-24 Sumitomo Electric Fine Polymer Inc Gasket, sealed secondary battery, and electrolytic capacitor
WO2014050056A1 (en) * 2012-09-28 2014-04-03 パナソニック株式会社 Nonaqueous electrolytic battery

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