JP2018068672A - Spreading fire prevention agent and fire extinguishing tank - Google Patents
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本発明は、火災の延焼防止や消火に用いられる延焼防止薬剤および延焼防止薬剤を貯蔵した消火タンクに関する。 The present invention relates to a fire spread prevention agent used for fire spread prevention and fire extinguishing, and a fire extinguishing tank storing a fire spread prevention chemical.
文化財として保護されている家屋の中には、茅葺き屋根等の植物屋根を備えた古民家等がある。茅葺き屋根等の植物屋根は、周辺の火災からの飛び火による着火延焼のリスクが高く、また、一度着火すると消火が大変困難である。このような植物屋根を有した家屋を火災から守るための延焼防止設備として、放水銃やドレンチャー設備等の散水設備が設置されている場合がある(特許文献1)。 Among the houses protected as cultural properties, there are old houses with plant roofs such as thatched roofs. Plant roofs such as thatched roofs have a high risk of ignition spread due to flying from surrounding fires, and once fired, extinguishing is very difficult. As a fire spread prevention equipment for protecting a house having such a plant roof from a fire, watering equipment such as a water spray gun and a drainage equipment may be installed (Patent Document 1).
これらの消火水を用いた散水設備では、散布中や散布後に消火水が植物屋根から流出するため、延焼防止のためには連続的に消火水を散布しなければならない。そのため、大量の消火水を用意しておかなければならなかった。しかし、文化財家屋等の周辺は、必ずしも消火水用の水源が豊富であるとは限らない。消火水に限りがある場合には、消火水は燃焼物の消火に利用され、予防放水にまで使用する余裕がない。したがって、大型の消火水保管施設を設ける必要があった。しかし、文化財家屋等の周辺には、大容量タンク等の大型の消火水保管設備を設置する場所がない場合が多い。さらに大容量タンクを設置するためには、高額の費用を要する。 In sprinkling facilities using these fire-extinguishing water, fire-extinguishing water flows out from the plant roof during and after spraying, so it is necessary to spray fire-extinguishing water continuously to prevent the spread of fire. Therefore, a large amount of fire-fighting water had to be prepared. However, the area around cultural property houses, etc. is not necessarily rich in water sources for fire extinguishing water. When fire water is limited, fire water is used to extinguish combustibles and cannot be used for preventive water discharge. Therefore, it was necessary to provide a large fire extinguishing water storage facility. However, there are often no places for installing large fire extinguishing water storage facilities such as large-capacity tanks around cultural property houses. In addition, a large cost is required to install a large capacity tank.
そこで本発明者は、高粘度の薬剤を延焼防止や消火の対象物に散布すると、高粘度の薬剤が散布した場に留まるため、散布量を少なくすることができると考え、消火水に換えて高粘度の薬剤である延焼防止薬剤を散布し、植物屋根等に付着させて延焼の防止や消火を行うことを検討した。茅葺き屋根等の植物屋根は、屋根面が急傾斜である場合が多い。延焼防止薬剤は、散布時に茅葺き屋根等の植物屋根の急傾斜な屋根面に保持される粘度を要するが、同時に、散布の際に配管やホースの内部における粘度による圧力損失を軽減する必要があった。そのため、配管やホース内で移動している際には粘度が低くなるように、延焼防止薬剤はチキソトロピー性の高いものとした。チキソトロピー性は剪断応力により粘度が下がり、静止すると粘度が上昇する性質である。 Therefore, the present inventor thinks that if a high-viscosity chemical is sprayed on an object to prevent fire spread or extinguishes, the high-viscosity chemical stays in the place where the high-viscosity chemical is sprayed. We studied spraying fire prevention and fire extinguishing by spraying a fire spreading prevention agent, which is a highly viscous chemical, and attaching it to plant roofs. Plant roofs such as thatched roofs often have steep slopes. The spread fire prevention agent requires a viscosity that is retained on the steep roof surface of a plant roof such as a thatched roof during spraying, but at the same time, it is necessary to reduce the pressure loss due to the viscosity in the piping and hoses during spraying. It was. Therefore, the fire spread preventing agent has a high thixotropic property so that the viscosity becomes low when moving in the pipe or hose. Thixotropic property is a property in which the viscosity decreases due to shear stress and increases when it is stationary.
(1)本発明は、無機物を水に分散させたチキソトロピー性を有する延焼防止薬剤であって、前記延焼防止薬剤を十分に攪拌した後に、B型粘度計でSC4−25のスピンドルにより充填量16.1mLで1分間攪拌した直後の粘度が(ア)回転数が130rpm(剪断速度が28.6(1/s))では73〜3,690mPa・sであり、(イ)回転数が60rpm(剪断速度が13.2(1/s))では90〜8,000mPa・sであって、回転数が130rpmでの粘度の1.2〜2.2倍であり、(ウ)回転数が6rpm(剪断速度が1.32(1/s))では880〜64,000mPa・sであって、回転数が130rpmでの粘度の12.1〜17.3倍であることを特徴とする延焼防止薬剤である。 (1) The present invention is a fire spread prevention agent having thixotropy in which an inorganic substance is dispersed in water, and after sufficiently stirring the fire spread prevention agent, a filling amount of 16 by a spindle of SC4-25 with a B type viscometer. The viscosity immediately after stirring for 1 minute at 1 mL is 73 to 3,690 mPa · s when the rotational speed is 130 rpm (shear rate is 28.6 (1 / s)), and (a) the rotational speed is 60 rpm ( When the shear rate is 13.2 (1 / s)), the viscosity is 90 to 8,000 mPa · s, the rotational speed is 1.2 to 2.2 times the viscosity at 130 rpm, and (c) the rotational speed is 6 rpm. (Shear rate is 1.32 (1 / s)) 880 to 64,000 mPa · s, and the rotational speed is 12.1 to 17.3 times the viscosity at 130 rpm. It is a drug.
本発明により、静止状態では延焼防止薬剤が茅葺き屋根等の急傾斜な植物屋根に保持され、散布時には低下した低い粘度で配管内を圧送することができる。 According to the present invention, the fire spread prevention agent is held on a steep plant roof such as a thatched roof in a stationary state, and the inside of the pipe can be pumped at a low viscosity that is reduced during spraying.
(2)また、本発明は、(1)の延焼防止薬剤を貯蔵した消火タンクである。 (2) Moreover, this invention is a fire extinguishing tank which stored the fire spread chemical | drug | medicine of (1).
本発明により、静止状態では茅葺き屋根等の急傾斜な植物屋根に保持され、散布時にはチキソトロピー性により低下した低い粘度で配管内を圧送される延焼防止薬剤を消火タンクに保管することができ、消火タンクを小型化することができる。 According to the present invention, it is possible to store in a fire extinguishing tank a fire-extinguishing agent that is held on a steep plant roof such as a thatched roof in a stationary state and is pumped through a pipe with a low viscosity reduced by thixotropy when sprayed. The tank can be reduced in size.
茅葺き屋根等の急傾斜な植物屋根に散布して用いることができるように、延焼防止薬剤について以下の実験を行った。
水に対し、サポナイトであるクニミネ工業株式会社のスメクトン(登録商標)SAを、量を変えて加えて攪拌により分散させ、複数の濃度のサポナイト溶液を作成した。
そして、茅葺き屋根の模型を作成して、散布実験を行った。図1は、茅葺き屋根模型1への散布実験を表す。幅1m、傾斜面の上下間隔1.6m、厚さ0.4mの茅葺きを、屋根面11が傾斜角45度になるようにして茅葺き屋根模型1を作成し、固定台2の上に設置した。さらに、茅葺き屋根模型1の下部から下方向に2.5m、横方向に8.5mの位置に先端が位置するように、噴霧ノズル3を水平方向から上方に40度の角度をつけて設置した。そして、噴霧ノズル3から茅葺き屋根模型1に向けて、できるだけ均一になるようにサポナイト溶液4を散布した。図1における矢印はサポナイト溶液4の主流の軌道を示すが、サポナイト溶液4はある程度広がって、茅葺き屋根模型1の屋根面に向かって散布される。
The following experiment was conducted on the fire spread prevention agent so that it could be sprayed onto a steep plant roof such as a thatched roof.
Sumenite (registered trademark) SA of Kunimine Kogyo Co., Ltd., which is a saponite, was added to water in various amounts and dispersed by stirring to prepare a saponite solution having a plurality of concentrations.
Then, we made a model of a thatched roof and conducted a spraying experiment. FIG. 1 shows a spraying experiment on a
サポナイト溶液4はチキソトロピー性により茅葺き屋根模型1の表面に保持されるとともに、配管やホース(図示せず)の内部では粘性が下がって流動化する。実験によると、サポナイトを混入していない消火水は茅葺き屋根模型1の屋根面11にはほとんど保持されずに下方へ流動し、軒から流出した。しかし、重量濃度1%のサポナイト溶液は茅葺き屋根模型1の屋根面11に辛うじて付着して保持された。重量濃度1%以上の濃度のサポナイト溶液は茅葺き屋根模型1の屋根面11に付着して保持された。重量濃度2%のサポナイト溶液は、サポナイトを混入していない消火水の8.5倍の付着率であり、茅葺き屋根の内部への浸透量もサポナイトを混入していない消火水の8.5倍であった。なお、付着は茅葺き屋根模型1への浸透も含む。そして、付着率は、屋根面11に付着したサポナイト溶液4の付着量と茅葺き屋根模型1に浸透した浸透量の合計を散布量で除したものである。また、浸透量は、屋根面11に付着したサポナイト溶液4を掃除機で吸引して重量を測定し、散布量から差し引くことにより得た。
The
重量濃度4%のサポナイト溶液でも十分な付着率が得られた。しかし、タンク内にガスを封入してサポナイト溶液をあらかじめ加圧した、蓄圧式パッケージタイプの延焼防止設備とした場合、重量濃度4%を超えると、サポナイト溶液4を圧送する場合に必要な圧力を確保することが難しかった。
A sufficient adhesion rate was obtained even with a saponite solution having a weight concentration of 4%. However, in the case of an accumulator package type fire spread prevention equipment in which gas is sealed in a tank and the saponite solution is pre-pressurized, if the weight concentration exceeds 4%, the pressure required for pumping the
以上のことから、スメクトン(登録商標)SAの重量濃度1〜4%溶液が、延焼防止薬剤として好適である。そこで、スメクトン(登録商標)SAの重量濃度1〜4%溶液について、以下のようにしてB型粘度計によりチキソトロピー性を調べた。 From the above, a smecton (registered trademark) SA solution having a weight concentration of 1 to 4% is suitable as a fire spread prevention agent. Accordingly, thixotropic properties of a smecton (registered trademark) SA solution having a weight concentration of 1 to 4% were examined using a B-type viscometer as follows.
水に、サポナイトであるスメクトン(登録商標)SAを加えて分散させ、サポナイト溶液を作成し、スリーワンモーター(メーカー名:アズワン株式会社 製品:トルネードスタンダード SM-102)により1400rpmで3分攪拌した後に1〜2分を目安にして、十分に攪拌するようにサポナイト溶液を入れた容器をハンドシェイクする。その後、サンプルチャンバーに16.1mLを充填し、B型粘度計によりSC4−25のスピンドルで下記の回転数を加えて、1分間経過した直後の粘度を測定した。これを、各濃度のサポナイト溶液について行った。
(ア) 回転数130rpm(剪断速度28.6(1/s))
(イ) 回転数60rpm(剪断速度13.2(1/s))
(ウ) 回転数6rpm(剪断速度1.32(1/s))
その結果、表1の粘性を得た。
Saponite (registered trademark) SA, which is saponite, is added to water and dispersed to prepare a saponite solution. Hand shake the container containing the saponite solution so that it is sufficiently stirred, using ˜2 minutes as a guide. Then, 16.1 mL was filled in the sample chamber, the following rotation speed was added with a spindle of SC4-25 with a B-type viscometer, and the viscosity immediately after 1 minute was measured. This was done for each concentration of saponite solution.
(A) Rotation speed 130 rpm (shear speed 28.6 (1 / s))
(A) Rotational speed 60 rpm (shear speed 13.2 (1 / s))
(C) Rotation speed 6 rpm (shear rate 1.32 (1 / s))
As a result, the viscosity shown in Table 1 was obtained.
したがって、無機物を水に分散させたチキソトロピー性を有する延焼防止薬剤を、1400rpmで3分攪拌した後に容器内でハンドシェイクにより1〜2分攪拌し、B型粘度計でSC4−25のスピンドルにより充填量16.1mLで1分間攪拌した際の粘度が
(ア)回転数が130rpm(剪断速度が28.6(1/s))では73〜3,690mPa・sであり、
(イ)回転数が60rpm(剪断速度が13.2(1/s))では90〜8,000mPa・sであって、回転数が130rpmでの粘度の1.2〜2.2倍であり、
(ウ)回転数が6rpm(剪断速度が1.32(1/s))では880〜64,000mPa・sであって、回転数が130rpmでの粘度の12.1〜17.3倍である、チキソトロピー性を有した、無機物を水に分散させた延焼防止薬剤であれば、茅葺き屋根のような急斜面の屋根に留まって延焼を防止するとともに、消火を行う機能を有し、消火水よりも散布量を少なくすることができる。延焼防止薬剤は消火タンクに貯蔵して用いられるが、散布量を少なくすることができるため、消火タンクの容量を小さくすることができる。
Therefore, a thixotropic anti-spreading agent in which an inorganic substance is dispersed in water is stirred at 1400 rpm for 3 minutes, then stirred by handshaking in a container for 1 to 2 minutes, and filled with a SC4-25 spindle with a B-type viscometer. The viscosity when stirring for 1 minute at an amount of 16.1 mL is 73 to 3,690 mPa · s when the rotational speed is 130 rpm (shear rate is 28.6 (1 / s)),
(B) When the rotational speed is 60 rpm (shear rate is 13.2 (1 / s)), the rotational speed is 90 to 8,000 mPa · s, and the rotational speed is 1.2 to 2.2 times the viscosity at 130 rpm. ,
(C) When the rotational speed is 6 rpm (shear rate is 1.32 (1 / s)), it is 880 to 64,000 mPa · s, and the rotational speed is 12.1 to 17.3 times the viscosity at 130 rpm. If it is a fire spread prevention agent that has thixotropy and dispersed inorganic substances in water, it stays on the roof of steep slopes like thatched roof and has the function of extinguishing fire, and has the function of extinguishing fire, compared to fire water The amount of application can be reduced. The fire spread prevention chemical is stored and used in a fire extinguishing tank, but since the amount of spraying can be reduced, the capacity of the fire extinguishing tank can be reduced.
実施の形態では延焼防止薬剤としてクニミネ工業株式会社のスメクトン(登録商標)SAを用いたが、延焼防止や消火に関係する付着率等は上記(ア)〜(ウ)の粘度を備えていれば同様である。したがって、上記(ア)〜(ウ)の粘度を備えていれば、他の無機物を混入したチキソトロピー性を有する延焼防止薬剤であってもよい。また、記載した実験では45度の傾斜を有した植物屋根について記載したが、傾斜は40度〜60度でもほぼ同様の結果が得られた。 In the embodiment, smecton (registered trademark) SA of Kunimine Kogyo Co., Ltd. was used as a fire spread prevention agent. However, the adhesion rate related to fire spread prevention and fire extinguishing has the above-mentioned viscosities (a) to (c). It is the same. Therefore, as long as it has the above-mentioned viscosities (a) to (c), it may be a fire spread preventing agent having thixotropy mixed with other inorganic substances. Moreover, in the experiment described, although it described about the plant roof which has 45 degree | times inclination, the substantially same result was obtained even if inclination was 40 to 60 degree | times.
1 茅葺き屋根模型、11 屋根面、2 固定台、3 噴霧ノズル、4 サポナイト溶液 1 Thatched roof model, 11 Roof surface, 2 Fixing stand, 3 Spray nozzle, 4 Saponite solution
Claims (2)
前記延焼防止薬剤を十分に攪拌した後に、B型粘度計でSC4−25のスピンドルにより充填量16.1mLで1分間攪拌した直後の粘度が
(ア)回転数が130rpmでは73〜3,690mPa・sであり、
(イ)回転数が60rpmでは90〜8,000mPa・sであって、回転数が130rpmでの粘度の1.2〜2.2倍であり、
(ウ)回転数が6rpmでは880〜64,000mPa・sであって、回転数が130rpmでの粘度の12.1〜17.3倍であることを特徴とする延焼防止薬剤。 A fire spread prevention agent having thixotropic properties in which an inorganic substance is dispersed in water,
After thoroughly stirring the fire spread prevention agent, the viscosity immediately after stirring for 1 minute at a filling amount of 16.1 mL with a SC4-25 spindle with a B-type viscometer is (a) 73 to 3,690 mPa · s,
(B) The rotation speed is 90 to 8,000 mPa · s at 60 rpm, and the rotation speed is 1.2 to 2.2 times the viscosity at 130 rpm.
(C) A fire spread prevention agent characterized by having a rotational speed of 880 to 64,000 mPa · s at 6 rpm and a rotational speed of 12.1 to 17.3 times the viscosity at 130 rpm.
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JP2020151286A (en) * | 2019-03-22 | 2020-09-24 | 能美防災株式会社 | Fire extinguisher |
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JPH07558A (en) * | 1991-02-15 | 1995-01-06 | Mitsubishi Gas Chem Co Inc | Fire extinguishing agent using swellable silicate compound |
JP2014008309A (en) * | 2012-07-02 | 2014-01-20 | Nohmi Bosai Ltd | Foam fire-extinguishing apparatus |
JP2015100483A (en) * | 2013-11-22 | 2015-06-04 | 能美防災株式会社 | Fire extinguishing agent tank |
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Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
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JPH07558A (en) * | 1991-02-15 | 1995-01-06 | Mitsubishi Gas Chem Co Inc | Fire extinguishing agent using swellable silicate compound |
JP2014008309A (en) * | 2012-07-02 | 2014-01-20 | Nohmi Bosai Ltd | Foam fire-extinguishing apparatus |
JP2015100483A (en) * | 2013-11-22 | 2015-06-04 | 能美防災株式会社 | Fire extinguishing agent tank |
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JP2020151286A (en) * | 2019-03-22 | 2020-09-24 | 能美防災株式会社 | Fire extinguisher |
JP7274898B2 (en) | 2019-03-22 | 2023-05-17 | 能美防災株式会社 | fire extinguisher |
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