JP2018065799A - Cosmetic - Google Patents

Abstract

PROBLEM TO BE SOLVED: To provide a cosmetic that has good feelings in use, such as stickiness and coolness, and a high sterilization effect, and also excels in the persistency of a sterilization component on the skin and the long-term storage stability of the sterilization component.SOLUTION: A cosmetic contains following components (A)-(D): (A) isopropylmethyl phenol of 0.01 mass% or more and 0.2 mass% or less, (B) carboxylic acid or salt thereof of 0.1 mass% or more and 3 mass% or less, (C) 1,3-butylene glycol of 0.1 mass% or more and 10 mass% or less, (D) nonionic surfactant of 10-13 in HLB, of 0.005 mass% or more and 1 mass% or less.SELECTED DRAWING: None

Description

  The present invention relates to cosmetics, particularly skin cosmetics.

  Deodorant cosmetics are used as cosmetics to suppress the stickiness and smell of sebum and sweat and to give a refreshing feeling. Such deodorant cosmetics contain various metal salts that are antiperspirants and bactericidal components. And the technique which improves a feeling of use etc. in addition to an antiperspirant action and a bactericidal action is reported. For example, powdered solid cosmetics containing powder in addition to antiperspirant ingredients and bactericidal ingredients (Patent Document 1), cosmetics containing ferulic acid and a bactericidal agent (Patent Document 2), artepilin C and a bactericidal agent Cosmetics (Patent Document 3), plant extracts such as geranium, cosmetics containing a bactericide and a cationic surfactant (Patent Document 4), benzyl glyceryl ether, isopropylmethylphenol and polyhydric alcohol and / or Deodorant stick (Patent Document 6), antibacterial component, cyclodeodorant composition (Patent Document 5) for external application of skin containing nonionic surfactant, silicone gel, polyhydric alcohol fatty acid ester powder, solidifying agent and deodorant component Dextrin-based compound, external composition for skin containing solid wax (Patent Document 7), aluminum compound and phenol A system fungicide, an aldehyde perfume, antiperspirant deodorant composition containing a chelating agent and water (Patent Document 8) have been reported.

JP 2010-77094 A JP 2010-116376 A JP 2011-126862 A JP2012-51845A JP 2012-219046 A Japanese Patent Laying-Open No. 2015-3891 Japanese Patent Laid-Open No. 2006-88925 JP 2016-113447 A

However, the conventional deodorant cosmetics are not sufficient in the persistence of antiperspirant action and bactericidal action, the feeling of use, in particular, the persistence on the skin of the bactericidal agent necessary for the expression of deodorizing effects and long-term storage stability.
Accordingly, an object of the present invention is to provide a cosmetic that is excellent in not only the feeling of use such as stickiness and coolness and the bactericidal effect, but also the persistence of the bactericidal component on the skin and the long-term storage stability of the bactericidal component. .

  Therefore, as a result of investigating the cause of the disappearance of the bactericidal component from the skin, the present inventor has found that sweating is often the cause. After various studies on the means for leaving the bactericidal component on the skin and the long-term storage stability of the bactericidal component even after a lot of sweating, isopropylmethylphenol, which is a bactericidal component, was added to carboxylic acid or a salt thereof. , 1,3-butylene glycol and a nonionic surfactant with a high HLB are used in combination, the bactericidal component remains sufficiently on the skin even after a large amount of perspiration, and the long-term storage stability is also good. And found that a good cosmetic can be obtained, and completed the present invention.

That is, this invention provides the cosmetics containing the following component (A)-(D).
(A) Isopropylmethylphenol 0.01% by mass or more and 0.2% by mass or less (B) Carboxylic acid or salt thereof 0.1% by mass or more and 3% by mass or less (C) 1,3-butylene glycol 0.1% by mass 10 mass% or less (D) Nonionic surfactant of HLB 10-13 0.005 mass% or more and 1 mass% or less

  In the cosmetic of the present invention, a sufficient amount of isopropylmethylphenol, which is a bactericidal component, remains on the skin even after sweating, the bactericidal effect is maintained, there is no stickiness, a cool feeling is good, and a long-term storage stability is also good. Therefore, the cosmetic of the present invention is useful as a skin cosmetic, particularly as a deodorant cosmetic.

Component (A) of the cosmetic of the present invention is isopropylmethylphenol. Isopropyl methylphenol has a strong bactericidal action and is blended in the cosmetic of the present invention as a bactericidal component and a deodorizing component.
The content of the component (A) is 0.01% by mass or more in the total amount of the cosmetic from the viewpoint of obtaining a sufficient bactericidal effect, the viewpoint of persistence on the skin, the viewpoint of long-term storage stability, and the feeling of use. .2% by mass or less, preferably 0.02% by mass or more, more preferably 0.05% by mass or more, and from the viewpoint of long-term storage stability, preferably 0.15% by mass or less. More preferably, it is 0.10 mass% or less. The range of preferable content of a component (A) is 0.02 mass% or more and 0.15 mass% or less, More preferably, it is 0.05 mass% or more and 0.10 mass% or less.

Component (B) is a carboxylic acid or a salt thereof. The component (B) is blended for decreasing the pH of the skin and expressing the deodorizing effect by suppressing the growth of bacteria and maintaining the deodorizing effect, the stability of the cosmetics, and reducing stickiness.
The carboxylic acid or a salt thereof preferably includes an organic carboxylic acid having 1 to 8 carbon atoms or a salt thereof, more preferably an organic carboxylic acid having 3 to 8 carbon atoms or a salt thereof.
Specific examples of the carboxylic acid of component (B) include monocarboxylic acids such as acetic acid, propionic acid and caprylic acid; dicarboxylic acids such as malonic acid, succinic acid, glutaric acid, adipic acid, maleic acid and fumaric acid; glycolic acid And hydroxycarboxylic acids such as lactic acid, hydroxyacrylic acid, glyceric acid, malic acid, tartaric acid and citric acid; aromatic carboxylic acids such as benzoic acid, salicylic acid and phthalic acid; and acidic amino acids such as glutamic acid and aspartic acid.
Specific examples of the counter ion constituting the salt include alkali metals such as sodium and potassium; alkaline earth metals such as calcium and magnesium; ammonium; alkanolamines such as monoethanolamine, diethanolamine and triethanolamine; arginine, Examples include cations derived from basic amino acids such as lysine. The salt is preferably an alkali metal salt, more preferably a sodium salt.
As the component (B), the viewpoint of leaving the component (A) on the skin, the expression of the deodorizing effect by inhibiting the growth of bacteria and the sustainability of the deodorizing effect, the long-term stability of the component (A), and the stickiness From the viewpoint of reducing feeling, it is preferably one or more selected from the group consisting of dicarboxylic acids, hydroxycarboxylic acids and salts thereof, more preferably citric acid, succinic acid, adipic acid and salts thereof. It is 1 type, or 2 or more types selected from the group which consists of. Furthermore, citric acid that can maintain the pH of the skin at 5 or less is particularly preferable in order to exhibit a deodorizing effect and maintain the effect.

  The content of the component (B) is the viewpoint of leaving the component (A) on the skin, the expression of the deodorizing effect by inhibiting the growth of bacteria and the sustainability of the deodorizing effect, the viewpoint of the long-term stability of the component (A), From the viewpoint of reducing stickiness, it is 0.1% by mass or more and 3% by mass or less, preferably 0.2% by mass or more, more preferably 0.5% by mass or more in the total amount of the cosmetic. Preferably it is 2.8 mass% or less, More preferably, it is 2.5 mass% or less. The specific range of the preferable content of the component (B) is preferably 0.2% by mass or more and 2.8% by mass or less, and more preferably 0.5% by mass or more and 2.5% by mass or less.

Component (C) is 1,3-butylene glycol. Component (C) contributes to the action of leaving component (A) on the skin, the long-term storage stability of component (A), bactericidal performance, cool feeling, and reduction in stickiness. In particular, the effect of allowing a sufficient amount of 1,3-butylene glycol component (A) to remain on the skin is remarkable.
The content of the component (C) is in the total amount of the cosmetic from the viewpoint of obtaining a sufficient bactericidal effect, the viewpoint of persistence on the skin, the viewpoint of long-term storage stability, the viewpoint of reducing stickiness, and the viewpoint of coolness. 0.1 mass% or more and 10 mass% or less, preferably 0.5 mass% or more, more preferably 1.0 mass% or more, further preferably 1.2 mass% or more, and preferably Is 8% by mass or less, more preferably 5% by mass or less, and still more preferably 3% by mass or less. The range of preferable content of component (C) is 0.5% by mass or more and 8% by mass or less, more preferably 1.0% by mass or more and 5% by mass or less, and further preferably 1.2% by mass or more. 3% by mass or less.

  The content ratio (A / C) of the component (A) to the component (C) in the cosmetic of the present invention is a viewpoint that a sufficient amount of the component (A) remains on the skin, and a viewpoint of long-term storage stability of the component (A). From the viewpoint of the development of the deodorizing effect and the sustainability of the deodorizing effect, from the viewpoint of reducing stickiness, and from the viewpoint of coolness, 0.005 or more is preferable, 0.010 or more is more preferable, and 0.02 or more is more preferable. 0.03 or more is further preferable, 0.04 or more is further more preferable, 0.6 or less is preferable, 0.4 or less is more preferable, 0.2 or less is further preferable, and 0.1 or less is even more preferable. The specific A / C range is preferably 0.005 or more and 0.6 or less, more preferably 0.010 or more and 0.5 or less, further preferably 0.01 or more and 0.4 or less, and 0.02 or more and 0 or less. .4 or less is more preferable, 0.03 or more and 0.2 or less is more preferable, and 0.04 or more and 0.1 or less is even more preferable.

Component (D) is an HLB 10-13 nonionic surfactant. By blending the component (D), the emulsion stability of the component (A) in the agent is improved and the adsorption to the container is suppressed, so that the long-term storage stability of the component (A) is improved. Component (D) is a nonionic surfactant having an HLB of 10 to 13, from the viewpoint of improving emulsification stability in the agent of component (A), suppressing adsorption to containers, and improving long-term storage stability. The thing of HLB11-13 is more preferable, and the thing of HLB12-13 is still more preferable.
In the present invention, the HLB value is an index indicating a hydrophilic-lipophilic balance. In the present invention, a value calculated by the following equation by Oda and Teramura et al. Is used. The HLB value is the HLB of each nonionic surfactant before blending.

  The component (D) is preferably a polyoxyethylene alkyl ether or polyoxyethylene alkenyl ether having a C10-18 alkyl group or alkenyl group (hereinafter also referred to as polyoxyethylene alkyl ether in the present invention).

The carbon number indicates the carbon number of the alkyl group or alkenyl group constituting the polyoxyethylene alkyl ether in the present invention, and improves the emulsion stability in the component (A) agent, suppresses adsorption to the container, and stabilizes long-term storage. From the viewpoint of improving the property, the reduction of stickiness, the viewpoint of coolness, and the viewpoint of bactericidal performance, 10 to 16 carbon atoms are preferable, and 12 to 14 carbon atoms are more preferable.
From the same viewpoint, the polyoxyethylene alkyl ether having an alkyl group having the above carbon number is preferable.
Specifically, polyoxyethylene lauryl ether (carbon number 12), polyoxyethylene myristyl ether (carbon number 14), polyoxyethylene cetyl ether (carbon number 16), polyoxyethylene oleyl ether (carbon number 18), etc. Polyoxyethylene lauryl ether is preferable. More specifically, polyoxyethylene lauryl ether (5EO) (HLB: 10.6), polyoxyethylene lauryl ether (6EO) (HLB: 11.5), polyoxyethylene lauryl ether ( 7E.O.) (HLB: 12.2), polyoxyethylene lauryl ether (8E.O.) (HLB: 12.9) and the like, and improvement of emulsification stability in the component (A) agent, Polyoxyethylene lauryl ether (7E.O.) (HLB: 12.2), poly, from the viewpoint of suppressing adsorption to the container and improving long-term storage stability, from the viewpoint of reducing stickiness, from the viewpoint of coolness, and from the viewpoint of bactericidal performance Oxyethylene lauryl ether (6E.O.) (HLB: 11.5) is preferred, and polyoxyethylene lauryl ether (6E.O.) (HLB: 11.5) is more preferred. Masui.
The number of moles of ethylene oxide added to the polyoxyethylene alkyl ether in the present invention is improved in emulsification stability in the component (A) agent, reduced in adsorption to the container and improved in long-term storage stability, reduced in stickiness, From the viewpoint of coolness and the viewpoint of bactericidal performance, 3 or more and 9 or less are preferable, 4 or more and 8 or less are more preferable, and 5 or more and 7 or less are more preferable.

  The content of component (D) is the improvement of emulsification stability in the agent of component (A), the viewpoint of suppression of adsorption to the container and the improvement of long-term storage stability, the viewpoint of stickiness reduction, the viewpoint of cool feeling, the sterilization performance From the viewpoint, the total amount of the cosmetic is preferably 0.005% by mass or more, more preferably 0.006% by mass or more, further preferably 0.008% by mass or more, and still more preferably 0.01% by mass. Moreover, 1.0 mass% or less is preferable, 0.8 mass% or less is more preferable, and 0.5 mass% or less is still more preferable. From the same viewpoint, it is 0.005% by mass or more and 1% by mass or less, preferably 0.006% by mass or more and 1% by mass or less, more preferably 0.008% by mass or more and 0.8% by mass or less. More preferably, it is 0.01 mass% or more and 0.5 mass% or less.

  From the viewpoint of further improving the persistence of the component (A) on the skin and the cool feeling, the cosmetic of the present invention has a component (E) HLB value of 4 to 7, and a liquid glyceryl group at 25 ° C. It is preferable to contain the nonionic surfactant which has.

The liquid state at 25 ° C. means that the viscosity at 25 ° C. is 100,000 mPa · s or less.
As such nonionic surfactants, those having a branched alkyl group or alkenyl group having 8 to 22 carbon atoms and bonded to a glyceryl group via an ether bond or an ester bond, or bonded via an alkylene oxide group. preferable.

  The nonionic surfactant having an HLB value of component (E) of 4 to 7 and having a glyceryl group at 25 ° C. includes, for example, alkyl glyceryl ether, glycerin fatty acid ester, polyglycerin fatty acid ester, polyoxyethylene glyceryl. 1 type (s) or 2 or more types chosen from ether fatty acid ester, polyoxyethylene hydrogenated castor oil, polyoxyethylene hydrogenated castor oil fatty acid ester, etc. are preferable. Among these, from the viewpoint of improving the persistence of the component (A) on the skin and improving the cool feeling, one or more selected from alkyl glyceryl ethers and glycerin fatty acid esters are preferable, and further one selected from alkyl glyceryl ethers. Or 2 or more types are preferable.

Examples of such component (E) include isostearyl glyceryl ether (HLB5.4), 2-ethylhexyl glyceryl ether (HLB7), glyceryl monoisostearate (HLB6), monoisostearic acid (degree of polymerization 2) polyglyceryl (HLB5). .5), polyoxyethylene monoisostearate (5) hydrogenated castor oil (HLB4), polyoxyethylene monoisostearate (10) hydrogenated castor oil (HLB5), polyoxyethylene monoisostearate (15) hydrogenated castor oil (HLB7) ), Polyoxyethylene triisostearate (10) hydrogenated castor oil (HLB4), polyoxyethylene triisostearate (15) hydrogenated castor oil (HLB5), polyoxyethylene triisostearate (20) hydrogenated castor oil (H B6), triisostearate, polyoxyethylene (30) hydrogenated castor oil (HLB7) and the like.
Of these, isostearyl glyceryl ether, 2-ethylhexyl glyceryl ether, and glyceryl monoisostearate are preferable from the viewpoint of improving the persistence of the component (A) on the skin and improving cooling sensation. Ether is preferred.

  The content of the component (E) is preferably 0.01 to 1% by mass, more preferably 0.01 to 0.8% by mass in the total amount of the cosmetic from the viewpoint of persistence on the skin and improvement of coolness. Yes, more preferably 0.01 to 0.5% by mass.

  The content mass ratio (D / E) of the component (D) and the component (E) in the cosmetic of the present invention is preferably 1 or more from the viewpoint of the persistence of the component (A) on the skin and long-term storage stability, Moreover, 100 or less is preferable, 80 or less is preferable and 60 or less is more preferable. 1-100 are preferable, as for the preferable range of D / E, 1-80 are more preferable, and 1-60 are more preferable.

  The cosmetics of the present invention, as shown in the examples below, have an excellent bactericidal effect and excellent persistence of the component (A) on the skin, as well as a feeling of use such as no stickiness, and a cool feeling. In addition, the content of the component (A) is maintained even after long-term storage in a resin container such as polyethylene. Therefore, the cosmetic of the present invention is useful as a skin cosmetic (including scalp), and particularly useful as a deodorant cosmetic.

  In addition to the above components, the cosmetics of the present invention include bactericides other than component (A), antiperspirants, powders, fats and oils, waxes, silicones, hydrocarbon oils, higher fatty acids, higher alcohols, and synthetic esters. Oil, other surfactants, polymer compounds, antioxidants, dyes, emulsion stabilizers, pH adjusters, astringents, preservatives, UV absorbers, chelating agents, moisturizers, thickeners, cooling agents, anti Inflammatory agents, amino acids, vitamin agents, various plant extracts, water and the like can be contained.

  Bactericides other than component (A) include benzalkonium chloride, triclosan, piroctone olamine, benzethonium chloride, alkyltrimethylammonium chloride, cetyltrimethylammonium bromide, triclocarban, salicylic acid, paraben, chlorhexidine or a salt thereof, lysozyme Or a salt thereof, acrinol, ethanol, gluconic acid, alkyldiaminoglycine or a salt thereof, popidone iodine, potassium iodide, iodine, cresol, photosensitizer 101, photosensitizer 201, phenoxyethanol, 1,2-pentanediol, halocarbane, Examples include 3,4,4-trichlorocarbanilide, triethyl citrate, resorcin, phenol, sorbic acid, hexachlorophene, silver-supported zeolite, and silver-supported silica.

  Antiperspirants include: chlorohydroxyaluminum, zinc oxide, zinc phenolsulfonate, aluminum chloride, potassium aluminum sulfate, aluminum sulfate, aluminum acetate, allantochlorohydroxyaluminum, aluminum zirconium octachlorohydrate, aluminum zirconium tetrachlorohydrate, Examples include aluminum zirconium trichlorohydrate and zirconium chlorohydrate. In the present invention, there is no problem whether or not the antiperspirant is blended, but it is more preferable not to blend it from the viewpoint of the persistence of the component (A) on the skin and the feeling of use.

  The dosage form of the cosmetic of the present invention is not particularly limited, and examples thereof include creams, roll-on types, mists, lotions, aerosols, sprays, sticks, emulsions, gels, sheet-like forms impregnated with nonwoven fabrics, and the like. The form of cream, roll-on type, spray type, mist or lotion is more preferable from the viewpoint of enhancing the persistence of component (A) on the skin.

  When the cosmetic of the present invention is in the form of a cream, in addition to the component (A), component (B), component (C), component (D), and component (E), the melting point as component (F) Is an oily component at 60 ° C. or higher, polyether-modified silicone as component (G), organic powder as component (H), inorganic powder as component (I), antioxidant as component (J) and component (K) One or more selected from poly (N-acylalkylenimine) -bonded silicone polymers can be contained.

The oily component having a melting point of component (F) of 60 ° C. or higher is a solid component having a melting point of 60 ° C. or higher and normal temperature (25 ° C.), preferably having a melting point of 60 to 110 ° C.
By using such a high melting point oily component, the persistence of the component (A) can be improved and a smooth feeling of use can be obtained.
In this invention, melting | fusing point is a thing measured by the quasi-drug raw material specification I (General test method, 70. Melting | fusing point measuring method 1st method).

Examples of such oily components are those used in normal skin external preparations, and include solid oils such as hydrocarbons, waxes, esters, silicones, animal waxes, vegetable waxes, mineral waxes, synthetic waxes, and the like. It is selected from waxes and mixtures thereof. For example, paraffin, ceresin, synthetic hydrocarbon wax, Fischer-Tropsch wax, microcrystalline wax, polyethylene wax, ethylene propylene copolymer, candelilla wax, beeswax, carnauba wax and the like can be used.
Of these, hydrocarbons are preferable, and ceresin (melting point: 72 to 76 ° C.), microcrystalline wax (melting point: 60 to 85 ° C.), polyethylene wax (melting point: 75 to 105 ° C.), paraffin wax (melting point: 70 to 78 ° C.) ) Is preferable in terms of the persistence of the component (A) on the skin and the feeling of use.
The content of the component (F) is preferably 0.5 to 10% by mass, more preferably 0.5 to 8% by mass in the total amount of the cosmetic from the viewpoint of the persistence of the component (A) on the skin and the feeling of use. Preferably, 1 to 6% by mass is more preferable.

  By using the polyether-modified silicone of the component (G), the persistence of the component (A) on the skin is improved and a good feeling of use (non-stickiness) can be obtained. The polyether-modified silicone of component (G) may be a dimethylpolysiloxane having a polyoxyethylene group or a polyoxypropylene group, and examples thereof include those represented by the following formula (1) or (2). These may be used alone or in combination of two or more.

(In the formula (1), R ¹ _{is, - (CH 2) 3 -O-} (C 2 H 4 O) p - (C 3 H 6 O) q -A ( where, A is a hydrogen atom or a carbon atoms 1 to 12 alkyl groups, p and q each independently represent an integer of 0 to 50, and p + q ≧ 1, and R ² each independently represents a methyl group or — (CH ₂ ) ₃ -O- (C ₂ H ₄ O) _s- (C ₃ H ₆ O) _t -B (where B represents a hydrogen atom or an alkyl group having 1 to 12 carbon atoms, and s and t are Each independently represents an integer of 0 to 50, and s + t ≧ 1), m represents an integer of 1 to 2000, and n represents an integer of 0 to 1000, provided that n is 0 Wherein at least one of R ² is — (CH ₂ ) ₃ —O— (C ₂ H ₄ O) _s — (C ₃ H ₆ O) _t —B (where B, s and t are as defined above). Yes.)

(In formula (2), r represents an integer of 1 to 20, and x, y and z each independently represents an integer of 1 to 500.)

  Examples of commercially available components (G) include KF6011, KF6012, KF6013, KF6015, KF6016, KF6017, KF6028 (all manufactured by Shin-Etsu Chemical Co., Ltd.) and the like.

  The content of the component (G) is preferably 0.01 to 10% by mass, preferably 0.05 to 5% by mass in the total amount of the cosmetic from the viewpoint of improving the persistence of the component (A) on the skin and the feeling of use. Is more preferable, and 0.1-3 mass% is further more preferable.

  By using the organic powder as the component (H), the persistence of the component (A) on the skin is improved and a good feeling of use is obtained. Component (H) organic powder may be used singly or in combination of two or more. Further, the shape may be any of a spherical shape, a needle shape, and a plate shape. Further, it may be treated with alumina, silica, zinc or the like, or treated with silicone or the like.

  Examples of the organic powder include lauroyl lysine, methylpolysiloxane network polymer, cross-linked methylpolysiloxane, polyamide powder, polyester powder, polyethylene powder, polypropylene powder, polystyrene powder, polyurethane, benzoguanamine powder, polymethylbenzoguanamine powder, tetrafluoro Examples thereof include ethylene powder and crosslinked resin powder.

  The organic powder of component (H) is more preferably at least one selected from a crosslinked resin powder, a methylpolysiloxane network polymer, and a crosslinked methylpolysiloxane. The methylpolysiloxane network polymer and the crosslinked methylpolysiloxane are already commercially available as cosmetic raw materials and can be used without any limitation. Among them, those having a spherical shape and a particle size in the range of 0.09 to 30.0 μm are preferable, and more preferably 0.2 to 15 μm. Here, the average particle diameter is an average particle diameter when the powder is monodispersed, and is a volume average particle diameter of the particle diameter measured by a static light scattering method.

  The methylsiloxane network polymer is a solid obtained by emulsion polymerization of methyltrimethoxysiloxane in an alkaline aqueous solution, and specific examples include Tospearl series (Tospearl 145A, etc.) manufactured by GE Toshiba Silicones. The crosslinked methylpolysiloxane is obtained by polymerizing dimethoxydimethylsiloxane with a small amount of methyltrimethoxysiloxane, and has a crosslinked structure of methyltrimethoxysiloxane inside. This can be produced by emulsion polymerization in the same manner as the methylsiloxane network polymer. Specifically, the Toray Fill series manufactured by Toray Dow Corning Silicone (Trefill E506W, Trefil E505C, Trefil E506C, Trefill E505W). Etc.). These may be used alone or in combination, and those dispersed in various solvents and those previously mixed with other components can be used without any problem. These include, for example, Trefil E507 solution, BY29-119, BY29-122 and the like. In addition, X-52-1139K and X-52-1139G manufactured by Shin-Etsu Chemical Co., Ltd., which are silicone resin / rubber composite powders, may also be mentioned. Among these, Tospearl series which is a methylsiloxane network polymer is particularly preferable in terms of smoothness.

  Examples of the crosslinked resin powder include a crosslinked (meth) acrylate resin powder described in JP-A-2006-225338.

  The content of the organic powder of the component (H) is preferably 1 to 40% by mass, and preferably 3 to 30% by mass in the total amount of the cosmetic from the viewpoint of the persistence of the component (A) on the skin and the feeling of use. Is more preferable, and 5-20 mass% is further more preferable.

Further, by using the inorganic powder of component (I), the persistence of component (A) on the skin is improved, and a good feeling of use is obtained. Inorganic powders of component (I) include titanium oxide, zirconium oxide, zinc oxide, cerium oxide, magnesium oxide, barium sulfate, calcium sulfate, magnesium sulfate, calcium carbonate, magnesium carbonate, talc, mica, kaolin, sericite, Muscovite, synthetic mica, phlogopite, saucite, biotite, lithia mica, silica, porous silica, anhydrous silicic acid, aluminum silicate, magnesium silicate, magnesium aluminum silicate, calcium silicate, barium silicate, silica Examples include strontium acid and metal tungstate.
The inorganic powder of the component (I) preferably contains silicic anhydride from the viewpoint of the persistence of the component (A) on the skin.

  Further, the content of the inorganic powder of the component (I) is 0.1 to 20% by mass in the total amount of the cosmetic from the viewpoint of imparting the persistence of the component (A) on the skin and a smooth use feeling. Preferably, 0.5-15 mass% is more preferable, and 1-10 mass% is further more preferable.

  As an antioxidant of component (J), dibutylhydroxytoluene (BHT); butylhydroxyanisole; vitamin E such as δtocopherol and its derivatives; thiotaurine, evening primrose extract, β-carotene, catechin compound, flavonoid compound, polyphenol compound Etc. can be illustrated. The catechin compound can be used as a green tea extract or the like. Among these, dibutylhydroxytoluene (BHT) or δtocopherol is preferable from the viewpoint of improving the feeling in use. These antioxidants may be used individually by 1 type, and may combine 2 or more types.

  The content of the component (J) is 0.001% by mass or more, particularly 0.005% by mass or more, and 1% by mass or less from the viewpoint of reducing stickiness after application from the viewpoint of preventing oxidation. In particular, the content is preferably 0.5% by mass or less.

  As the poly (N-acylalkylenimine) -bonded silicone polymer of component (K), at least one of the terminal or side chain silicon atoms of the organopolysiloxane segment has an alkylene group containing a hetero atom through the following formula ( Examples thereof include a silicone polymer formed by bonding poly (N-acylalkylenimine) composed of the repeating unit represented by 3).

(Wherein R ³ represents a hydrogen atom, an alkyl group having 1 to 22 carbon atoms, a cycloalkyl group, an aralkyl group or an aryl group, and l represents a number of 2 or 3)

  Preferred examples of such silicone polymers include poly (N-formylethyleneimine) modified silicone, poly (N-acetylethyleneimine) modified silicone, poly (N-propionylethyleneimine) modified silicone, poly (Nn-octa). Noylethyleneimine) modified silicone, poly (Nn-dodecanoylethyleneimine) modified silicone, poly (N-formylpropyleneimine) modified silicone, poly (N-acetylethyleneimine) modified silicone, poly (N-acetylpropyleneimine) ) Modified silicone, poly (N-propionylpropyleneimine) modified silicone, poly (Nn-octanoylpropyleneimine) modified silicone, poly (Nn-dodecanoylpropyleneimine) modified silicone, and the like.

  The content of the component (K) is preferably 0.1 to 10% by mass, preferably 0.2 to 8% by mass in the total amount of the cosmetic from the viewpoint of the persistence of the component (A) on the skin and the feeling of use. Is more preferable, and 0.5-6 mass% is further more preferable.

  The cosmetic of the present invention can be a roll-on type cosmetic. Here, the roll-on type is a cosmetic obtained by filling a roll-on container with a cosmetic composition, and is applied by applying a roll to an application site. For roll-on type cosmetics, in addition to the component (A), component (B), component (C), component (D), and component (E), the lower alcohol having 2 to 4 carbon atoms as the component (L) And the component (M) is selected from the group consisting of sorbitan monooleate, sorbitan trioleate, sorbitan monoisostearate, polyoxyethylene oleyl ether and polyoxyethylene glyceryl triisostearate. One or two or more types, trimethylsiloxysilicic acid as component (O), and poly (N-acylalkylenimine) -bonded silicone polymer as component (K) can be contained. .

  As a C2-C4 lower alcohol of a component (L), ethanol is preferable. The content of the lower alcohol having 2 to 4 carbon atoms of the component (L) is preferably 20 to 80% by mass and more preferably 40 to 80% by mass from the viewpoint of feeling of use and cooling.

By containing a water-soluble polymer as the component (M), the persistence of the component (A) on the skin can be improved. As the water-soluble polymer, any of natural polymers, semi-synthetic polymers, and synthetic polymers can be used.
Examples of natural polymers include xanthan gum, carrageenan, alginic acid and the like. Examples of semi-synthetic polysaccharide polymers include modified polysaccharides such as hydroxycellulose, hydroxypropylcellulose, sodium carboxymethylcellulose, methylcellulose, hydroxymethylcellulose, and cationized cellulose. Synthetic polymers include carbomers (cross-linked polyacrylic acid), polyacrylic acid, sodium polyacrylate, acrylic polymers such as acrylic acid / alkyl methacrylate copolymers; polyvinyl pyrrolidone, polyvinyl alcohol, cationized polyvinyl pyrrolidone, and the like. It is done. Of these, carbomer, acrylic acid / alkyl methacrylate copolymer, hydroxypropylcellulose, and sodium carboxymethylcellulose are preferred.

  Examples of commercially available carbomers include carbopol 910, carbopol 934, carbopol 940, carbopol 941, carbopol 980, carbopol 981 (manufactured by Lubrizol Advanced Materials, Inc.) and the like, and acrylic acid / methacrylic acid. Examples of commercially available acid alkyl copolymers include Carbopol 1382, Carbopol ETD2020, PEMULEN TR-1, PEMULEN TR-2 (manufactured by Lubrizol Advanced Materials, Inc.), and the like. HPC-M, HPC-H (manufactured by Nippon Soda Co., Ltd.), etc., and as a commercial product of sodium carboxymethylcellulose, CMC Daicel (manufactured by Daicel Chemical Industries, Ltd.) Etc. The.

  Component (M) can be used alone or in combination of two or more, and the content is 0.01 mass in the total amount of the cosmetic from the viewpoint of the persistence of component (A) on the skin and the feeling of use. % Or more is preferable, 0.05 mass% or more is more preferable, 5 mass% or less is preferable, and 3 mass% or less is more preferable. Moreover, 0.01-5 mass% is preferable in cosmetics whole quantity, and, as for content of a component (M), 0.05-3 mass% is more preferable.

  As a component (N), one or more selected from the group consisting of sorbitan monooleate, sorbitan trioleate, sorbitan monoisostearate, polyoxyethylene oleyl ether and polyoxyethylene glyceryl triisostearate are included. This improves the persistence of the component (A) on the skin and the feeling of use.

  The content of the component (N) is preferably 0.01 to 3% by mass, and 0.03 to 1% by mass in the total amount of the cosmetic from the viewpoint of the persistence of the component (A) on the skin and the feeling of use. More preferably, 0.05-0.5 mass% is further more preferable.

The trimethylsiloxysilicic acid of component (O) is not limited as long as it is usually used in cosmetics. Any compound can be used, and is a compound having a crosslinked structure with a siloxane structure as the main skeleton, [(CH _{3) 3 SiO 1/2] X [} SiO 2] represented by the _Y (X is 1 to 3, Y is 0.5 to 8) are preferred.
In addition, the trimethylsiloxysilicic acid preferably has a weight average molecular weight of 1000 to 10,000, more preferably 2000 to 9000, more preferably 3000 to 6000, from the viewpoint of the persistence of the component (A) on the skin and the feeling of use. Are more preferred. Further, the property may be any of liquid, gum, paste, solid, etc. at 25 ° C., but a solid is preferable. Further, from the viewpoint of compoundability, it is preferably a solution or dispersion diluted with a solvent, or a solution or dispersion obtained by mixing in advance. The solvent for diluting or dispersing the component (O) is preferably one or more selected from dimethylpolysiloxane, octamethylcyclotetrasiloxane, decamethylcyclopentasiloxane, and isododecane, and includes volatile dimethylpolysiloxane, deca More preferred is methylcyclopentasiloxane. In addition, volatility has a flash point of 35-90 degreeC.
As a commercially available component (O), KF-7312T, KF-7312J, KF-7312K (manufactured by Shin-Etsu Chemical Co., Ltd.) or the like previously dissolved in a solvent can be preferably used.

  The content of the component (O) is preferably 0.005 to 2% by mass and preferably 0.008 to 1% by mass in the total amount of the cosmetic from the viewpoint of the persistence of the component (A) on the skin and the feeling of use. Is more preferable, and 0.01-0.5 mass% is further more preferable.

  In the case of the roll-on type, the content of the poly (N-acylalkylenimine) -bonded silicone polymer of component (K) is in the total amount of cosmetics in terms of the persistence of component (A) on the skin and the feeling of use. Furthermore, 0.3-5 mass% is preferable, 0.4-4 mass% is more preferable, 0.5-3 mass% is further more preferable.

  When the cosmetic of the present invention is in the form of mist, spray or lotion, in addition to the component (A), component (B), component (C), component (D) and component (E), the component ( One or two selected from polyoxyethylene polyoxypropylene decyl tetradecyl ether (for example, PPG-6 decyl tetradeces-30) as P), polyether-modified silicone as component (G), and ethanol as component (L) More than seeds can be included.

The content of the component (P) is preferably 0.05 to 2% by mass, more preferably 0.08 to 1% by mass in the total amount of the cosmetic, from the viewpoint of coolness and long-term storage stability. -0.5 mass% is further more preferable.
In the case of mist, spray or lotion, the content of component (G) is preferably 0.05 to 2% by mass in the total amount of the cosmetic from the viewpoint of elongation to skin, familiarity, and stability over time, 0 0.08 to 1.5% by mass is more preferable, and 0.1 to 1% by mass is even more preferable.

  Since the cosmetic of the present invention is used in various forms as described above, the components (A) to (D) and other components are added, mixed, heated as necessary, and various forms. It can be manufactured by filling a container according to the above.

  This invention discloses the following cosmetics further regarding embodiment mentioned above.

<1> Cosmetics containing the following components (A) to (D).
(A) Isopropylmethylphenol 0.01% by mass or more and 0.2% by mass or less (B) Carboxylic acid or salt thereof 0.1% by mass or more and 3% by mass or less (C) 1,3-butylene glycol 0.1% by mass 10 mass% or less (D) Nonionic surfactant of HLB 10-13 0.005 mass% or more and 1 mass% or less

The content of <2> component (A) is preferably 0.02% by mass or more, more preferably 0.05% by mass or more, and preferably 0.15% by mass or less in the total amount of the cosmetic. The cosmetic according to <1>, more preferably 0.1% by mass or less.
<3> Component (B) is preferably an organic carboxylic acid having 1 to 8 carbon atoms or a salt thereof, more preferably an organic carboxylic acid having 3 to 8 carbon atoms or a salt thereof <1> or <2> Cosmetics described.
<1> to <3>, wherein <4> component (B) is one or more selected from monocarboxylic acids, dicarboxylic acids, hydroxycarboxylic acids, aromatic carboxylic acids, acidic amino acids and salts thereof. Cosmetics in any one.
The makeup according to any one of <1> to <4>, wherein <5> component (B) is one or more selected from the group consisting of succinic acid, adipic acid, citric acid and salts thereof. Fee.
The content of <6> component (B) is preferably 0.2% by mass or more, more preferably 0.5% by mass or more, and preferably 2.8% by mass or more in the total amount of the cosmetic. The cosmetic according to any one of <1> to <5>, which is more preferably 2.5% by mass or less.
The content of <7> component (C) is preferably 0.5% by mass or more, more preferably 1.0% by mass or more, and further preferably 1.2% by mass or more in the total amount of the cosmetic. The cosmetic according to any one of <1> to <6>, which is preferably 8% by mass or less, more preferably 5% by mass or less.
<8> The mass ratio (A / C) of the component (A) and the component (C) is preferably 0.005 or more, more preferably 0.010 or more, still more preferably 0.02 or more, and still more preferably 0. 0.03 or more, more preferably 0.4 or more, preferably 0.6 or less, more preferably 0.4 or less, still more preferably 0.2 or less, and even more preferably 0.1 or less. 7>.
<9> The cosmetic according to any one of <1> to <8>, wherein the component (D) is preferably a nonionic surfactant of HLB 11 to 13, more preferably a nonionic surfactant of HLB 12 to 13.
<10> The component (D) is a polyoxyethylene alkyl ether or polyoxyethylene alkenyl ether having an alkyl group or alkenyl group having 10 to 18 carbon atoms, more preferably a polyoxyethylene alkyl group having 10 to 16 carbon atoms. The cosmetic according to any one of <1> to <9>, which is an oxyethylene alkyl ether.
The content of <11> component (D) is preferably 0.005% by mass or more and 0.8% by mass or less, more preferably 0.006% by mass or more and 1% by mass or less, in the total amount of the cosmetic. The cosmetic according to any one of <1> to <10>, more preferably from 0.008% by mass to 0.8% by mass, and still more preferably from 0.01 to 0.5% by mass.
<12> The cosmetic according to any one of <1> to <11>, further comprising a nonionic surfactant having a component (E) HLB value of 4 to 7 and having a liquid glyceryl group at 25 ° C.
<13> Component (E) is selected from alkyl glyceryl ether, glycerin fatty acid ester, polyglycerin fatty acid ester, polyoxyethylene glyceryl ether fatty acid ester, polyoxyethylene hydrogenated castor oil, polyoxyethylene hydrogenated castor oil fatty acid ester and the like <12> description which is 1 type, or 2 or more types, Preferably it is 1 type, or 2 or more types chosen from alkyl glyceryl ether and glycerol fatty acid ester, More preferably, it is 1 type, or 2 or more types chosen from alkyl glyceryl ether Cosmetics.
<14> The content of component (E) is preferably 0.01 to 1% by mass, more preferably 0.01 to 0.8% by mass, and still more preferably 0.01 to 0.5% by mass. A cosmetic according to <12> or <13>.
<15> The mass ratio (D / E) of the component (D) and the component (E) is preferably 1 or more, preferably 100 or less, more preferably 80 or less, and even more preferably 60 or less. Cosmetics in any one of 12>-<14>.
<16> The cosmetic according to any one of <1> to <15>, preferably a skin cosmetic, and more preferably a deodorant cosmetic.
<17> Furthermore, a bactericidal agent other than component (A), preferably benzalkonium chloride, triclosan, piroctone olamine, benzethonium chloride, alkyltrimethylammonium chloride, cetyltrimethylammonium bromide, triclocarban, salicylic acid, paraben, Chlorhexidine or a salt thereof, lysozyme or a salt thereof, acrinol, ethanol, gluconic acid, alkyldiaminoglycine or a salt thereof, popidone iodine, potassium iodide, iodine, cresol, photosensitizer 101, photosensitizer 201, phenoxyethanol, 1,2- Selected from pentanediol, halocarban, 3,4,4-trichlorocarbanilide, triethylcitrate, resorcin, phenol, sorbic acid, hexachlorophene, silver-supported zeolite and silver-supported silica Containing one or more bacteria agent <1> to cosmetic according to any one of <16>.
<18> Further, an antiperspirant, preferably chlorohydroxyaluminum, zinc oxide, zinc phenolsulfonate, aluminum chloride, potassium aluminum sulfate, aluminum sulfate, aluminum acetate, chlorohydroxyaluminum, allantochlorohydroxyaluminum and zinc paraphenolsulfonate. Cosmetics in any one of <1>-<17> containing 1 type, or 2 or more types of antiperspirant chosen from.
<19> The dosage form is selected from a sheet form impregnated with cream, roll-on type, mist, lotion, aerosol, spray, stick, emulsion, gel, nonwoven fabric, etc., preferably cream, roll-on type, spray type, The cosmetic according to any one of <1> to <18>, which is a mist or lotion dosage form.
<20> The dosage form is cream, and the component (F) is an oily component having a melting point of 60 ° C. or higher, component (G) polyether-modified silicone, component (H) organic powder, component (I) inorganic powder, Cosmetics in any one of <1>-<19> containing 1 type, or 2 or more types chosen from component (J) antioxidant and component (K) poly (N-acyl alkylene imine) coupling | bonding silicone type polymer. Fee.
<21> The dosage form is a roll-on type, and component (L) a lower alcohol having 2 to 4 carbon atoms, component (M) a water-soluble polymer, component (N) sorbitan monooleate, sorbitan trioleate, One or more selected from the group consisting of sorbitan monoisostearate, polyoxyethylene oleyl ether and polyoxyethylene glyceryl triisostearate, component (O) trimethylsiloxysilicic acid, and component (K) poly (N-acyl) Cosmetics in any one of <1>-<19> containing 1 type, or 2 or more types chosen from an alkyleneimine) coupling | bonding silicone type polymer.
<22> The dosage form is mist, spray or lotion, and further component (P) polyoxyethylene polyoxypropylene decyl tetradecyl ether (eg PPG-6 decyl tetradec-30), component (G) polyether modified Cosmetics in any one of <1>-<19> containing 1 type, or 2 or more types chosen from silicone and component (L) ethanol.
<23> Use of the cosmetic according to any one of <1> to <19> as a deodorant.

  EXAMPLES Next, an Example is given and this invention is demonstrated still in detail. In the examples,% means mass%.

Examples 1-27 and Comparative Examples 1-5
The cosmetics described in Tables 1 and 2 were produced and evaluated for stickiness, coolness, persistence, bactericidal effect, and stability in containers. The results are shown in Tables 1 and 2.

(Production method)
Using the mixing tank 1, the component (A), the component (C), and a part of water are mixed, and heated and dissolved at 100 to 180 ° C. as described in Japanese Patent No. 5908635.
In the mixing tank 2, the component (B) is added to the remaining water and dissolved. Further, using the blending tank 3, the remaining component (D), component (E), methylpolysiloxane, and menthol are blended and mixed.
What was mixed in the blending tank 3 is added to the blending tank 1 and stirred uniformly. Then, the mixture in the blending tank 2 is added to obtain a cosmetic.

(Evaluation of stickiness)
Sensory evaluation was conducted by five specialist panels, and the average score was taken as the evaluation value.
The scoring was as follows.
Very sticky 1
Sticky 2
Slightly sticky It feels sticky 3
I can't say either, I can't say it's sticky 4
Not sticky 5

(Evaluation of coolness)
Sensory evaluation was conducted by five specialist panels, and the average score was taken as the evaluation value.
The scoring is as follows.
I feel a slight cool feeling 2
Feel the coolness 3
There is a cool feeling 4
There is a very cool feeling 5

(Evaluation of persistence)
The residual property was evaluated by the following procedure.
(I) Apply 10 μL / cm ^{2 of} cosmetic on the inner side of one forearm and dry.
(Ii) Apply 10 μL / cm ^{2 of} cosmetic on the inside of the other forearm and dry. After drying, the sample application part is immersed in water for 30 seconds. Thereafter, the forearm is pulled up from the water, and the portion of the sample application part immersed in water is dried with a dryer.
Cup-shake with 5 mL of ethanol from the sample application part of (iii), (i), (ii), and collect the remaining cosmetic. The collected solution is filtered through a 0.45 μm filter to obtain samples (i) ′ and (ii) ′, respectively.
(Iv) The UV absorbance of isopropylmethylphenol (IPMP) in each sample (i) ′ and (ii) ′ is measured.
(V) The absorbance (A) of (i) ′ and the absorbance (B) of (ii) ′ were applied to the following formula to calculate the residual ratio.
(Residual rate (%)) = (B / A) × 100

(Evaluation of sterilization performance)
The armpit part is wiped with alcohol and a cosmetic is applied at 0.02 g / cm ² . After 8 hours, the bacteria are collected from the site where the preparation is applied with stamp medium (Nissui). The obtained stamp is cultured at 37 ° C. for 12 hours, and the number of colonies that appear is counted. Bactericidal performance is defined by the number of expressed colonies. Using an adult male armpit, a stamp was collected from a region without the fur (N = 5).
1: less than 10 2: less than 50 3: less than 100 4: 100 or more

(Evaluation of stability)
When isopropylmethylphenol (IPMP) is stored in a polyethylene container, the active ingredient is adsorbed in the container. The adsorption suppression effect was evaluated.

A 100 g polyethylene container was filled with 80 g preparation, stored at 50 ° C. for one month, the amount of IPMP contained in the preparation was quantified, and the amount adsorbed on the container was evaluated.
AA is more than 95% compared to the initial AA
If BB is over 93% BB
If 90% or more remains
If less than 90% DD

Production Example 1
A beaker was charged with 82 g of lauryl methacrylate, 3 g of methacrylic acid, 15 g of ethylene glycol dimethacrylate, and 2 g of lauroyl peroxide, and dissolved by stirring. 400 g of ion-exchanged water in which 0.75 g of sodium N-stearoyl-N-methyltaurine (SMT) was dissolved was added thereto and dispersed with a homomixer until the particle size became 2.2 μm. The dispersion of polymerized particles was neutralized by adding 3.9 g of 1N NaOH dropwise. The dispersion was poured into a four-necked flask and purged with nitrogen for 30 minutes while stirring. The temperature inside the flask was heated to 80 ° C. with an oil bath, polymerization was performed for 5 hours after reaching 80 ° C., and then cooled to room temperature. The dispersion liquid of the polymerized particles was lyophilized and the particles were collected to obtain a resin powder A.

  Next, the manufacture example of this invention cosmetics is shown.

The obtained skin cosmetics had high persistence and high sterilizing ability.
Formulation example: Cream

Formulation example: Roll-on

Formulation example: lotion mist

Formulation example: Gel

Formulation example: Latex

Formulation Example: Sheet 4 g of a liquid composition having the following composition was impregnated by spraying onto ² g of 100% cotton nonwoven fabric (basis weight 50 g / m ² ) to produce a sheet-shaped cosmetic. The impregnation rate of the liquid composition with respect to 100 parts by mass of the sheet base material is 200 parts by mass.

* 1: Emulgen 108 (manufactured by Kao Corporation)
* 2: Emulgen 409PV (made by Kao Corporation)
* 3: Penetor GE-IS (manufactured by Kao Corporation)
* 4: Penetor GE-EH (Kao Corporation)
* 5: EMALEX GWIS-100EX (Nippon Emulsion Co., Ltd.)
* 6: Silicone KF-96L-2CS (manufactured by Shin-Etsu Chemical Co., Ltd.)
* 7: SI-UGE (Kao Corporation)
* 8: Silicone KF-6025 (manufactured by Shin-Etsu Chemical Co., Ltd.)
* 9: Tocopherol 100 (Nisshin Oillio Group, Inc.)
* 10: Esthe Mall N-01 (Nisshin Oillio Group, Inc.)
* 11: Silicone KT-18 (made by Momentive Performance Materials Japan GK)
* 12: Ceresin # 810K (manufactured by Nikko Rica Corporation)
* 13: HNP-9 (Nippon Seiwa Co., Ltd.)
* 14: Silicone X-52-1621 (manufactured by Shin-Etsu Chemical Co., Ltd.)
* 15: Silicone KSP-105 (manufactured by Shin-Etsu Chemical Co., Ltd.)
* 16: Silicone KF-7712K (manufactured by Shin-Etsu Chemical Co., Ltd.)
* 17: Leodoll AO10V (manufactured by Kao Corporation)
* 18: NIKKOL PEN-4630 (Nikko Chemicals)
* 19: EMALEX ET-8020 (Nippon Emulsion Co., Ltd.)
* 20: Adeka Carpole DL-80 (manufactured by ADEKA Corporation)
* 21: Saracos 99 (Nisshin Oillio Group)
* 22: IPP (manufactured by Higher Alcohol Industry)
* 23: AQUPEC HV-701EDR (manufactured by Sumitomo Seika Kogyo Co., Ltd.)
* 24: NIKKOL BL-21 (Nikko Chemicals)

Claims (11)

Cosmetics containing the following components (A) to (D).
(A) Isopropylmethylphenol 0.01% by mass or more and 0.2% by mass or less (B) Carboxylic acid or salt thereof 0.1% by mass or more and 3% by mass or less (C) 1,3-butylene glycol 0.1% by mass 10 mass% or less (D) Nonionic surfactant of HLB 10-13 0.005 mass% or more and 1 mass% or less   The component (D) is at least one selected from polyoxyethylene alkyl ethers having an alkyl group having 10 to 18 carbon atoms and polyoxyethylene alkenyl ethers having an alkenyl group having 10 to 18 carbon atoms. Cosmetics.   Furthermore, the cosmetics of Claim 1 or 2 containing the nonionic surfactant which has a component (E) HLB value of 4-7, and is a liquid at 25 degreeC, and has a glyceryl group.   The cosmetic according to any one of claims 1 to 3, wherein the content ratio of the component (A) to the component (C) ((A) / (C)) is 0.005 or more and 0.6 or less.   The cosmetic according to claim 3 or 4, wherein a content mass ratio ((D) / (E)) of the component (D) and the component (E) is 1 or more and 100 or less.   It is a cream form, The cosmetics of any one of Claims 1-5.   Furthermore, an oily component having a melting point of 60 ° C. or higher as component (F), polyether-modified silicone as component (G), organic powder as component (H), inorganic powder as component (I), and antioxidant as component (J) The cosmetic according to claim 6, comprising one or more selected from poly (N-acylalkylenimine) -bonded silicone polymers as an agent and component (K).   The cosmetic according to any one of claims 1 to 5, which is a roll-on type.   Furthermore, the lower alcohol having 2 to 4 carbon atoms as the component (L), the water-soluble polymer as the component (M), the sorbitan monooleate, the sorbitan trioleate, the sorbitan monoisostearate, the polyoxyethylene oleyl as the component (N) One or more selected from the group consisting of ether and polyoxyethylene glyceryl triisostearate, trimethylsiloxysilicic acid as component (O), and poly (N-acylalkylenimine) -bonded silicone polymer as component (K) Cosmetics of Claim 8 containing 1 type, or 2 or more types chosen from these.   The cosmetic according to any one of claims 1 to 5, which is in the form of mist, spray or lotion.   Furthermore, 1 type, or 2 or more types chosen from polyoxyethylene polyoxypropylene decyl tetradecyl ether as a component (P), polyether modified silicone as a component (G), and ethanol as a component (L) are contained. Cosmetics described.