JP2018048342A5 - - Google Patents

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JP2018048342A5
JP2018048342A5 JP2017216227A JP2017216227A JP2018048342A5 JP 2018048342 A5 JP2018048342 A5 JP 2018048342A5 JP 2017216227 A JP2017216227 A JP 2017216227A JP 2017216227 A JP2017216227 A JP 2017216227A JP 2018048342 A5 JP2018048342 A5 JP 2018048342A5
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transparent conductive
adhesive layer
conductive film
pressure
sensitive adhesive
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JP6431968B2 (en
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本発明は、耐加湿白濁性が高く、かつ加湿条件下における誘電率変化が小さい透明導電性フィルム用粘着剤層に関する。
The present invention, resistance to humidification cloudiness resistance is high and dielectric constant change regarding small transparent conductive film pressure-sensitive adhesive layer in humidified conditions.

そこで、本発明は、耐加湿白濁性が高く、かつ加湿条件下における誘電率変化を抑制することができる、透明導電性フィルム用粘着剤層を提供することを目的とする。
Accordingly, the present invention provides resistance to humidification cloudiness resistance is high and the dielectric constant changes in humidified conditions can be suppressed, and an object thereof is to provide a transparent conductive film pressure-sensitive adhesive layer.

上記静電容量方式タッチパネル6は、本発明の透明導電性フィルム用粘着剤層1が用いられているので、耐加湿白濁性が高く、厚さを薄くすることができ、動作の安定性に優れる。また、外観や視認性が良好である。
The capacitive touch panel 6, since the transparent conductive film pressure-sensitive adhesive layer 1 of the present invention is used, resistance to humidification cloudiness resistance is high, it is possible to reduce the thickness, excellent in stability of operation . Also, the appearance and visibility are good.

<誘電率>
粘着剤層(粘着シートからシリコーン処理を施したPETフィルムを剥離したもの)を、銅箔と電極の間に挟み以下の装置により周波数100kHzにおける比誘電率を測定した。測定は3サンプルを作製し、それらの3サンプルの測定値の平均を誘電率とした。なお、粘着剤層の周波数100kHzでの比誘電率は、JIS K 6911に準じて、下記条件で測定した。
測定方法:容量法(装置:Agilent Technologies E4980A Precision LCR Meter使用)
電極構成:12.1mmΦ、0.5mm厚みのアルミ板
対向電極:3oz 銅板
測定環境:23℃、55%R.H.
測定環境(加湿条件):60℃、95%R.H.に、測定治具に粘着剤を固定した状態で30分放置し、30分後の誘電率を測定

Figure 2018048342

<Dielectric constant>
A pressure-sensitive adhesive layer (a film obtained by peeling a silicone-treated PET film from a pressure-sensitive adhesive sheet) was sandwiched between a copper foil and an electrode, and a relative dielectric constant at a frequency of 100 kHz was measured by the following apparatus. Three samples were prepared for measurement, and the average of the measured values of these three samples was taken as the dielectric constant. The relative dielectric constant of the pressure-sensitive adhesive layer at a frequency of 100 kHz was measured according to JIS K 6911 under the following conditions.
Measuring method: Capacity method (apparatus: using Agilent Technologies E4980A Precision LCR Meter)
Electrode configuration: 12.1 mmφ, 0.5 mm thick aluminum plate Counter electrode: 3 oz copper plate Measurement environment: 23 ° C., 55% R.D. H.
Measurement environment (humidification conditions): 60 ° C., 95% R.D. H. Next, leave the adhesive on the measuring jig for 30 minutes and measure the dielectric constant after 30 minutes.
Figure 2018048342

Claims (7)

透明プラスチックフィルム基材の一方の面に、金属酸化物により形成された透明導電性 薄膜を有し、他方の面に機能層を有する透明導電性フィルムの一方の面に、透明導電性フ ィルム用粘着剤層を有する粘着剤層付き透明導電性フィルムであって、
前記透明導電性フィルム用粘着剤層は、
ベースポリマーとしてイソプレン系ポリマーを含むイソプレンゴム系粘着剤から形成さ れた粘着剤層であって、
23℃、55%R.H.環境下の周波数100kHzの比誘電率が3.4以下であり、60℃、95%R.H.の環境下に120時間保存した後の水分率が1重量%以下であ 、かつ、60℃、95%R.H.の環境下における周波数100kHzの比誘電率が、2 3℃、55%R.H.環境下の周波数100kHzの比誘電率の1.2倍以下であることを特徴とする、粘着剤層付き透明導電性フィルム
On one surface of the transparent plastic film substrate, a transparent conductive thin film formed of a metal oxide on one surface of the transparent conductive film having a functional layer on the other surface, transparent conductive off Irumu A transparent conductive film with an adhesive layer having an adhesive layer,
The pressure-sensitive adhesive layer for transparent conductive film is:
An adhesive layer formed from an isoprene rubber-based adhesive containing an isoprene-based polymer as a base polymer ,
23 ° C., 55% R.D. H. The dielectric constant of the frequency 100kHz under environment Ri der 3.4 or less, 60 ℃, 95% R. H. Moisture content after storage for 120 hours under environment Ri der than 1 wt%, and, 60 ° C., 95% R. H. The relative dielectric constant at a frequency of 100 kHz in an environment of 23 ° C. and 55% R.D. H. Characterized in der Rukoto 1.2 times or less of the dielectric constant of the frequency 100kHz of environment, transparent conductive film with an adhesive layer.
前記水分率が0.6重量%以下であることを特徴とする請求項に記載の粘着剤層付き 透明導電性フィルム Transparent conductive film with an adhesive layer according to claim 1, wherein the moisture content is 0.6 wt% or less. 前記イソプレン系ポリマーが、イソプレン−スチレン共重合体を含むことを特徴とするThe isoprene-based polymer contains an isoprene-styrene copolymer. 請求項1または2に記載の粘着剤層付き透明導電性フィルム。The transparent conductive film with an adhesive layer of Claim 1 or 2. 前記イソプレン系ポリマーが、水添物であることを特徴とする請求項1〜3のいずれかThe said isoprene-based polymer is a hydrogenated product. に記載の粘着剤層付き透明導電性フィルム。The transparent conductive film with an adhesive layer of description. 前記透明導電性フィルムの透明導電性薄膜上に、前記透明導電性フィルム用粘着剤層を有することを特徴とする請求項1〜4のいずれかに記載の粘着剤層付き透明導電性フィルム。The transparent conductive film with a pressure-sensitive adhesive layer according to any one of claims 1 to 4 , wherein the pressure-sensitive adhesive layer for the transparent conductive film is provided on the transparent conductive thin film of the transparent conductive film. 前記透明導電性フィルムの機能層上に、前記透明導電性フィルム用粘着剤層を有することを特徴とする請求項1〜4のいずれかに記載の粘着剤層付き透明導電性フィルム。The transparent conductive film with a pressure-sensitive adhesive layer according to any one of claims 1 to 4 , wherein the pressure-sensitive adhesive layer for the transparent conductive film is provided on a functional layer of the transparent conductive film. 請求項1〜6のいずれかに記載の粘着剤層付き透明導電性フィルムを少なくとも1つ有することを特徴とするタッチパネル。
It has at least 1 the transparent conductive film with an adhesive layer in any one of Claims 1-6 , The touchscreen characterized by the above-mentioned.
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