JP2018039862A5 - - Google Patents

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JP2018039862A5
JP2018039862A5 JP2016172638A JP2016172638A JP2018039862A5 JP 2018039862 A5 JP2018039862 A5 JP 2018039862A5 JP 2016172638 A JP2016172638 A JP 2016172638A JP 2016172638 A JP2016172638 A JP 2016172638A JP 2018039862 A5 JP2018039862 A5 JP 2018039862A5
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water
prepolymer
resin composition
particles
composition according
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JP2016172638A
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JP6802956B2 (en
JP2018039862A (en
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Claims (16)

流動性を有するプレポリマーと、該プレポリマー中での沈降速度が異なる少なくとも2種類の水溶性粒子とを混合して該水溶性粒子を該プレポリマー中に分散させる分散工程と、
該プレポリマー中に分散した該水溶性粒子を重力又は遠心力によって沈降させる沈降工程と、
該プレポリマーを硬化させる硬化工程と、
硬化した該プレポリマー中の該水溶性粒子を水によって溶解除去する粒子溶解工程と、を備えることを特徴とする傾斜多孔質樹脂成形体の製造方法。
A dispersion step of mixing a prepolymer having fluidity with at least two kinds of water-soluble particles having different settling rates in the prepolymer to disperse the water-soluble particles in the prepolymer;
A sedimentation step in which the water-soluble particles dispersed in the prepolymer are sedimented by gravity or centrifugal force;
A curing step for curing the prepolymer;
And a particle dissolution step of dissolving and removing the water-soluble particles in the cured prepolymer with water.
前記分散工程において、プレポリマーに有機溶媒を含有させておくことを特徴とする請求項1に記載の傾斜多孔質樹脂成形体の製造方法。   In the said dispersion | distribution process, the organic solvent is made to contain in a prepolymer, The manufacturing method of the inclination porous resin molding of Claim 1 characterized by the above-mentioned. 前記分散工程において、前記プレポリマーに水不溶性の導電性粒子を添加することを特徴とする請求項1又は2に記載の傾斜多孔質樹脂成形体の製造方法。   3. The method for producing an inclined porous resin molded article according to claim 1, wherein in the dispersion step, water-insoluble conductive particles are added to the prepolymer. 前記請求項1乃至3のいずれか1項の製造方法に用いる傾斜多孔質樹脂成形体用の樹脂組成物であって、
流動性を有するプレポリマーと、該プレポリマー中での沈降速度が異なる少なくとも2種類の水溶性粒子とが混合されている樹脂組成物。
A resin composition for an inclined porous resin molding used in the production method according to any one of claims 1 to 3,
A resin composition in which a prepolymer having fluidity and at least two kinds of water-soluble particles having different settling rates in the prepolymer are mixed.
前記プレポリマーは、シロキサン結合による主骨格を持つシリコーン前駆体であることを特徴とする請求項4に記載の樹脂組成物。   The resin composition according to claim 4, wherein the prepolymer is a silicone precursor having a main skeleton based on a siloxane bond. 前記水溶性粒子は、少なくとも、平均粒子径が100μm以上1000μm以下の水溶性粒子(A)と、平均粒子径が50μm以上300μm以下の水溶性粒子(B)と、を含有していることを特徴とする請求項4又は5に記載の樹脂組成物。   The water-soluble particles include at least water-soluble particles (A) having an average particle diameter of 100 μm or more and 1000 μm or less and water-soluble particles (B) having an average particle diameter of 50 μm or more and 300 μm or less. The resin composition according to claim 4 or 5. 前記水溶性粒子(A)の密度が、前記水溶性粒子(B)の密度よりも0.5g/cm以上高いことを特徴とする請求項6に記載の樹脂組成物。 The resin composition according to claim 6, wherein the density of the water-soluble particles (A) is 0.5 g / cm 3 or more higher than the density of the water-soluble particles (B). 前記水溶性粒子(A)が塩化ナトリウム、前記水溶性粒子(B)がグラニュー糖であることを特徴とする請求項6又は7に記載の樹脂組成物。   The resin composition according to claim 6 or 7, wherein the water-soluble particles (A) are sodium chloride, and the water-soluble particles (B) are granulated sugar. 前記水溶性粒子の前記プレポリマーに対する総体積比率が10%以上350%以下であることを特徴とする請求項4乃至8のいずれか1項に記載の樹脂組成物。   The resin composition according to any one of claims 4 to 8, wherein a total volume ratio of the water-soluble particles to the prepolymer is 10% or more and 350% or less. 前記プレポリマーは有機溶媒を含有していることを特徴とする請求項4乃至9のいずれか1項に記載の樹脂組成物。   The resin composition according to claim 4, wherein the prepolymer contains an organic solvent. 前記プレポリマーには水不溶性の導電性粒子が添加されていることを特徴とする請求項4乃至10のいずれか1項に記載の樹脂組成物。   11. The resin composition according to claim 4, wherein water-insoluble conductive particles are added to the prepolymer. 前記導電性粒子は平均粒子径が10nm以上150μm以下であることを特徴とする請求項11に記載の樹脂組成物。   The resin composition according to claim 11, wherein the conductive particles have an average particle diameter of 10 nm to 150 μm. 前記導電性粒子は炭素粒子からなることを特徴とする請求項11又は12に記載の樹脂組成物。   The resin composition according to claim 11, wherein the conductive particles are made of carbon particles. 前記炭素粒子の前記プレポリマーに対する体積比率が0.5%以上8%以下であることを特徴とする請求項13に記載の樹脂組成物。   The resin composition according to claim 13, wherein a volume ratio of the carbon particles to the prepolymer is 0.5% or more and 8% or less. 樹脂中に空孔と導電性粒子とが分散しており、該空孔の径が傾斜して分布している導電性傾斜多孔質樹脂成形体。   A conductive inclined porous resin molded article in which pores and conductive particles are dispersed in a resin, and the diameters of the pores are inclined and distributed. 請求項15に記載の導電性傾斜多孔質樹脂成形体からなるセンサ材料。A sensor material comprising the conductive inclined porous resin molded body according to claim 15.
JP2016172638A 2016-09-05 2016-09-05 A method for producing an inclined porous resin molded product, and a resin composition used therein. Active JP6802956B2 (en)

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JP2016172638A JP6802956B2 (en) 2016-09-05 2016-09-05 A method for producing an inclined porous resin molded product, and a resin composition used therein.

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JP2016172638A JP6802956B2 (en) 2016-09-05 2016-09-05 A method for producing an inclined porous resin molded product, and a resin composition used therein.

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JP2018039862A JP2018039862A (en) 2018-03-15
JP2018039862A5 true JP2018039862A5 (en) 2019-09-05
JP6802956B2 JP6802956B2 (en) 2020-12-23

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Publication number Priority date Publication date Assignee Title
CN110862686A (en) * 2019-11-20 2020-03-06 天津工业大学 High-molecular heat-conducting composite material and preparation method thereof
WO2023048099A1 (en) * 2021-09-24 2023-03-30 日東電工株式会社 Resin composition, member for sensing pressure, and input interface

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JPS5532651A (en) * 1978-08-31 1980-03-07 Hokushin Ind Inc Method of manufacturing ranging porous substance
JPH03174457A (en) * 1989-12-01 1991-07-29 Kanebo Ltd Preparation of polyurethane sponge
JPH04120141A (en) * 1990-09-11 1992-04-21 Siegel:Kk Production of gel porous form
JPH05325647A (en) * 1991-03-29 1993-12-10 Siegel:Kk Silicone gel porous conductor and its manufacture
JP2001126539A (en) * 1999-10-27 2001-05-11 Japan Gore Tex Inc Transparent conductive film and method of preparing it
JP4032098B2 (en) * 2002-02-08 2008-01-16 ワタナベ株式会社 Compound liquid for porous silicone rubber molding
JP3992274B2 (en) * 2002-04-18 2007-10-17 キヤノン株式会社 Method for producing sponge rubber
JP3806703B2 (en) * 2003-05-28 2006-08-09 株式会社豊田商会 Porous silicone rubber material and method for producing the same

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