JP2018030713A - Paper tube, packaging material, coating agent, method for manufacturing coating agent and method for manufacturing paper tube - Google Patents

Abstract

PROBLEM TO BE SOLVED: To make it possible that winding of a core, to which another core or a foreign matter is not adhered in an unused state, can be instantaneous started, a sheet material can be reliably adhered to the core after winding, and the sheet material can be cleanly peeled off from the core when using a plastic film.SOLUTION: A core 1 comprises an adhered surface 2 for holding an end of a sheet material by application of water onto the surface, the sheet material comprises a plastic sheet or the like, and the adhered surface 2 comprises an aqueous polymer which is at least one kind of polyvinyl acetate derivatives and polyvinyl alcohol derivatives. In the case that the sheet material comprises a PE film, the sheet material does not exhibit a tacky adhesive force and an adhesive force in a water non-application state under the environment of a temperature of 23°C and a humidity of 50%. Water is applied onto the sheet material, and the sheet material is adhered to the adhered surface 2, and consequently, a paper tube, in which the adhered surface exhibits an adhesive force such that a tensile strength becomes 20 N/60 mm or more after an elapse of 24 hours, is provided.SELECTED DRAWING: Figure 1

Description

The present invention relates to a paper tube, a packaging material, a coating agent, a coating agent manufacturing method, and a paper tube manufacturing method.

Taking a paper material, in particular, a core of a sheet material as an example, various contrivances have been made so that the sheet material can be reliably wound (Patent Documents 1 and 2).

As the core for winding the sheet material, a paper tube processed into a cylindrical shape is used, and in order to fix the sheet material 5 winding start end to the outer peripheral surface of the core, the outer periphery of the core The surface has been proposed in which a pressure-sensitive adhesive is applied in a strip shape in a direction parallel to the axis of the core (FIGS. 3 and 4 of Patent Document 2).
Further, for example, in Patent Document 1, there is a winding core for winding a sheet material provided with an inward turn-up portion at a winding start end, and the thickness of the sheet material wound on the outer peripheral surface of the peripheral wall is almost the same. An equal height sheet material end receiving step portion is provided over the entire length, and a recess in which the folded portion of the sheet material is fitted to the lower end of the step portion on the outer peripheral surface of the peripheral wall extends over the entire length. The formed core for sheet material is shown (claim of utility model registration).
Also in Patent Document 1, the pressure sensitive adhesive is used, the sheet material is affixed to the pressure sensitive adhesive, and the winding core is rotated to quickly and accurately set up the winding of the sheet material on the winding core. Expected to do.

However, the core that winds up the sheet material and the pressure-sensitive adhesive is applied to it, dust is attached if the pressure-sensitive adhesive is not covered with release paper until the sheet material starts to be wound, There is a problem that the adhesive strength is reduced due to the influence of moisture, and there is a problem that a process and cost for attaching a release paper are required. Focusing on these problems, a core shown in claim 1 of Patent Document 2 has been proposed.

The winding core of Patent Document 2 is coated on the surface of the cylindrical body with a holding means in a strip shape parallel to the axial direction of the cylindrical body, and the holding means can be dried in the atmosphere to exhibit adhesive force. First, the adhesive force is exhibited by applying a liquid (claim 1). Further, in claim 2 of Patent Document 2, the holding means contains at least one of starch, dextrin, konjac mannan, polyvinyl alcohol, vinyl acetate resin, gum arabic and carboxymethyl cellulose, A winding core is shown in which the liquid is water.

According to the above configuration, in Patent Document 2, in order to solve the above problem, it is possible to reduce the cost by omitting the attachment of the release paper.

No. 3-8689 JP 2005-162468 A

However, in Patent Document 2, the focus is on the formation of the holding means using a natural material such as starch as an adhesive, and there is no disclosure of a sufficient technique that can withstand practical use in the case of using a synthetic resin instead of starch. .
For example, Patent Document 2 does not show a specific adhesive force for a synthetic resin suitable for forming a holding means on a winding core or the like. Further, in Patent Document 2, although a synthetic resin is mentioned, even a synthetic resin having the same composition does not take into consideration that the viscosity varies depending on the degree of polymerization.
Also, for example, when a plastic film is wound around a core, the plastic film can be fixed to the core by fixing the end of the plastic film to the core with the adhesive force developed by the application of moisture. When the film is pulled out from the core, the end may not be peeled cleanly, the plastic film may be broken or a part of the core surface may be peeled off and stuck to the plastic film. No specific means for suppressing such inconvenience when a synthetic resin is used as the means is shown.
Furthermore, when a plurality of paper tubes having the above holding means on the surface are bundled with a band for transportation and storage, the holding means is sticky in a high temperature and humidity environment, and the paper tubes are not separated even if the band is removed. There is a case where it is not easy to leave, and there is no specific means for wiping out such problems when synthetic resin is used for the holding means. In particular, when the holding means is formed using starch or the like, the problem of stickiness is remarkable.
The above problems can be summarized as follows.
That is, as a first problem, Patent Document 2 mentions a synthetic resin as a material constituting the holding means, but does not sufficiently study how to develop practical adhesiveness.
As a second problem, in Patent Document 2, the contradicting action of being easily wound up when a plastic film is necessary around the core and being peeled off from the core neatly when using the plastic film is practical. There is no sufficient disclosure about a configuration using compatible synthetic resins.
As a third problem, in Patent Document 2, when the surface of the paper tube having the synthetic resin as the holding means is not sticky even in an environment of high temperature and humidity, and when moisture is applied, the necessary adhesive force is provided as described above. The conflicting effect of exerting it is not disclosed enough to achieve both.
Therefore, the present invention focuses on adhesive strength and tackiness in a practical range while utilizing an aqueous polymer, and includes the above-mentioned problems including not only paper cores such as winding cores but also packing materials such as edge boards. It is a solution.
The present invention is also intended to provide a coating agent that can easily form the holding means on the user's side and freely at the user's desired location on the paper tube and the packing material.
Furthermore, when fixing the edge part of the sheet | seat material wound up to a core with a double-sided tape, a level | step difference will arise in the winding core surface by the thickness of a double-sided tape, and a level | step difference trace will be made in the wound sheet | seat material. For this reason, conventionally, in order to alleviate the step marks, the sheet material has been wound more than the length that is originally required. The present invention eliminates the problem of upper step marks by eliminating the need for double-sided tape, and eliminates unnecessary tape material that is not used.

In the invention of the present application, a winding core is provided that has an adherend surface that holds the edge of the sheet material by applying moisture to the surface, and the sheet material is any one of plastic film, paper, metal foil, cloth, and nonwoven fabric. The adherend surface includes a water-soluble polymer, and the water-soluble polymer includes at least one of a polyvinyl acetate derivative and a polyvinyl alcohol derivative, and the sheet material is a polyethylene film having a thickness of 50 μm. In this case, even in the environment of at least 23 degrees Celsius and 50% humidity, even if the sheet material is pasted in a state where moisture is not applied, the adherend surface does not exhibit adhesive force and adhesive force, and moisture is applied to the surface. Provided is a paper tube in which the adherend surface exhibits an adhesive strength, wherein a sheet material is pasted and a tensile strength after 24 hours has elapsed is 20 N / 60 mm or more.
Further, in the present invention, when the sheet material is a polyethylene film having a thickness of 50 μm, even if the sheet material is pasted in a state where moisture is not applied in an environment of at least 50 degrees Celsius and 98% humidity. The surface does not exhibit adhesive strength and adhesive strength, and is a paper on which the adherend surface exhibits adhesive strength with a tensile strength of 20 N / 60 mm or more after 24 hours have passed after applying moisture and pasting the sheet material. Could provide a tube.
Further, in the present invention, when the sheet material is a polyethylene film having a thickness of 50 μm, water is applied and the sheet material is adhered in an environment of at least 23 degrees Celsius to 50 degrees Celsius and a humidity of 50% to 98%. Thus, it was possible to provide a paper tube in which the adherend surface exhibited an adhesive force with a tensile strength of less than 120 N / 60 mm after 24 hours.
Furthermore, in the present invention, the water-soluble polymer comprises a polyvinyl acetate resin and polyvinyl alcohol, the polyvinyl acetate resin has higher adhesive force than the polyvinyl alcohol, It was possible to provide a paper tube that has a lower adhesiveness than the polyvinyl acetate resin and has a lower adhesive strength than the polyvinyl acetate resin.
Furthermore, the present invention can provide a paper tube in which the polyvinyl acetate resin has a viscosity of 1 to 40000 mPa · s, and the polyvinyl alcohol has a viscosity of 1 to 3000 mPa · s.
In the present invention, the second polyvinyl alcohol is the first polyvinyl alcohol, and the second adhesive has a lower adhesiveness than the polyvinyl acetate resin and has a higher adhesive pressure than the first polyvinyl alcohol. Thus, the water-soluble polymer contains a water-soluble polymer, and the polyvinyl acetate resin has a higher adhesive strength than the second polyvinyl alcohol.
Further, in the present invention, the second polyvinyl alcohol can provide a paper tube having a viscosity of 3000 to 40000 mPa · s.
Still further, in the present invention, at least a part of the surface of the paper tube includes a coating layer coated with the water-soluble polymer, and the adherend surface is the surface of the coating layer. I was able to provide it.
Furthermore, in the present invention, the first resin having a lower adhesiveness than the polyvinyl acetate resin and having a lower adhesive adhesive force than the polyvinyl acetate resin, and the polyvinyl acetate resin. A second resin having low tackiness and a greater tackiness of the tacky adhesive than the first resin, and the polyvinyl acetate resin having an adhesive strength higher than those of the first and second resins; , Could provide a paper tube with a surface.
A high expression of adhesiveness means that it is easy to stick even when a small amount of water adheres, and a low expression of adhesiveness means that it is difficult to stick.
In the present invention, the water-soluble polymer is a packaging material provided on the surface, and the water-soluble polymer contains at least one of a polyvinyl acetate derivative and a polyvinyl alcohol derivative, and has a humidity of at least 23 degrees Celsius. When a polyethylene film is pasted in a 50% environment with no moisture applied, the adherend surface does not exhibit adhesive strength and adhesive strength, and when moisture is applied and a 50 μm thick polyethylene film is pasted It was possible to provide a packaging material in which the adherend surface exhibited an adhesive strength with a tensile strength after 24 hours of 20 N / 60 mm or more.
Furthermore, in the present invention, a core or a packing material is used as an adherend, and a sheet material, a package, or a packaging box containing the package is used as a paste, and the paste is applied to the adherend. A coating agent for forming an adherend to be fixed on the adherend, comprising a water-soluble polymer as a main component, and the water-soluble polymer includes at least one of a polyvinyl acetate derivative and a polyvinyl alcohol derivative. When the patch is made of a polyethylene film having a thickness of 50 μm, even if the patch is stuck in an environment where moisture is not applied in an environment of at least 23 degrees Celsius and 50% humidity, the adherend surface has adhesive strength. In a container that does not exhibit adhesive strength, applies moisture and applies the patch, and gives a tensile strength of 20 N / 60 mm or more after 24 hours. Coating Agent, method for producing the coating agent, as well as to provide a method for manufacturing a paper tube of applying the coating agent to at least a portion of the surface.
In the present invention, the polyvinyl acetate derivative has an average molecular weight of 100,000 to 700,000, and the polyvinyl alcohol derivative has a paper tube, a packing material, or a polymerization degree of 1200 or less. The coating agent could be provided.
Further, in the present invention, the polyvinyl acetate-based resin has an average molecular weight of 100,000 to 700,000, the first polyvinyl alcohol has a polymerization degree of 1200 or less, and the second Polyvinyl alcohol was able to provide a paper tube having a polymerization degree exceeding 1200.
Still further, in the present invention, the polyvinyl acetate resin has an average molecular weight of 100,000 to 700,000, the first resin is polyvinyl alcohol having a polymerization degree of 1200 or less, and the second resin. Could provide a paper tube of polyvinyl alcohol having a degree of polymerization exceeding 1200.

In the present invention, paper tubes and packing materials such as a winding core for winding a sheet material can be proposed which are provided with a synthetic resin having a practical property suitable as a holding means.
In the present invention, in a packaging material such as a paper tube such as a core for winding a sheet material, or an edge board that is attached to a packing box that contains a packing or packing material and protects the edge of the packing or packing box, While the sheet material can be easily fixed to the other packing material, it is difficult for foreign matters such as dust to adhere to the sheet material until the fixing is required.
That is, the above-described winding core or packing material is used as an adherend, the winding core that fixes the above-mentioned sheet material or the packing material that is fixed to the above-mentioned package or packing box is used as an adhesive body, and the adherend is fixed to the adhesive body. A surface to be adhered is provided, and the surface can be adhered to the surface by a simple technique of applying moisture. On the other hand, the adherend surface can prevent adhesion of foreign substances without exhibiting adhesive force until moisture is applied.
For example, when the entire outer peripheral surface is the adherend surface and a plurality of formed unused cores are gathered together and bound together with a band, when the band is released, it can be easily separated without sticking to each other it can. In particular, even in a high-temperature and high-humidity environment, the band can be easily separated by unwinding.
Further, when the sheet material is wound around the winding core, the adhesiveness is exhibited by the adhesion of the water, and the edge of the sheet material can be quickly fixed, and the sheet material can be quickly wound. Since the moisture disappears due to drying and permeation into the paper tube after winding, the adherend surface exhibits an adhesive force and reliably holds the edge of the sheet material.
And especially when the sheet material is a plastic film and the sheet material is used, the end of the adhered sheet material can be easily peeled off from the core, and the sheet material can be easily removed from the core to the end. Can do. In particular, the plastic film is surely attracted to the adherend surface formed on the core, but when the plastic film is peeled off from the core, the surface of the core is peeled off or broken, or a part of the plastic film However, the plastic film can be peeled cleanly to the end without remaining on the surface of the core and tearing the plastic film.
Even when the adherend is the packaging material and the patch is a package or a packaging box, the same effects as described above can be obtained.
In addition, at the embodiment level, in the present invention, the operability (workability) of the coating agent is improved by setting the viscosity at the time of coating to 40000 mPa · s or less for the coating agent that forms the adherend surface. In addition, it is easy to manufacture adherends such as a core and packing materials, that is, to form an adherend surface on these adherends.
Moreover, in this invention, the said site | part worker can form the said to-be-adhered body appropriately in a field by apply | coating a coating agent to the existing member. That is, the present invention has provided a coating agent that can respond flexibly according to the form of the member to be adhered on the user side and the situation at the site.
In particular, as described above, when the operator forms the adherend surface on the adherend of the packaging material using the coating liquid, or when using the adherend on which the adherend surface is formed with the coating agent from the beginning. Even in the case of use, the operator can apply moisture to the entire adherend surface and use the entire adherend surface for fixing. It can be selected and limited, and can be used as a material that exerts adhesive force and adhesive force only on a specific portion to be used in the adherend surface. Thus, in this invention, the range which exhibits adhesive force and adhesive force can be selected appropriately by selecting the amount and range of moisture adhesion.
In addition, when a double-sided tape is used for fixing the end of the sheet material to the core as in the conventional case, a step is generated on the surface of the core by the thickness of the double-sided tape. The surface to be deposited is formed by coating, and no step is produced. In the double-sided tape, it is necessary to cover the adhesive surface with a release sheet so that dust or the like does not adhere until it is used, but in the present invention, such trouble is unnecessary.
In the present invention, in particular, when the patch is made of a polyethylene film having a thickness of 50 μm, the adherend surface exhibits an adhesive force and an adhesive force when moisture is not applied in an environment of 50 degrees Celsius and 98% humidity. Without applying water, the tensile strength after application of the patch is set to 20 N / 60 mm or more and less than 120 N / 60 mm, so that in the atmosphere, as described above, 1) winding on the adherend such as a core. A sticker such as a sheet material wound around the core does not stick even when it is hot and humid. On the other hand, the sticker sticks to the adherend (attachment surface) by a simple operation of 2) application of moisture. The conflicting items 1) and 2) were made compatible within a practical range.
More specifically, with respect to the paper tube, the first resin having a lower adhesiveness than the polyvinyl acetate resin and having a lower adhesive strength than the polyvinyl acetate resin and the developed adhesive By providing the surface with a second resin having a higher adhesive strength than the first resin and the polyvinyl acetate resin having an adhesive strength higher than that of the first and second resins, The surface is not sticky even in high-temperature and high-humidity environments, etc., and the adhesive strength and sheet material after the disappearance of water after winding are exhibited while the adhesiveness necessary for winding is expressed from the beginning of winding the sheet material by applying moisture. The peelability at the time was secured.
In the embodiment level, the polyvinyl acetate resin has a viscosity of 1 to 40,000 mPa · s, the first resin has a viscosity of 1 to 3000 mPa · s, and the second resin. This resin can be a polyvinyl alcohol (second polyvinyl alcohol) having a viscosity of 3000 to 40000 mPa · s.
Further, after the sheet material is peeled off, the sheet material cannot be fixed again unless moisture is applied again, and on the other hand, it is reused by applying moisture to the resin held on the paper tube side. Made it possible.
Furthermore, when a double-sided tape is used for fixing the edge of the sheet material to the core, the surface of the core caused by the thickness of the double-sided tape is formed by applying a coating agent in the present invention. By doing so, the step is not generated. In other words, wrinkles are transferred to products such as films (sheet material) due to the above-mentioned level difference, thereby causing a level difference mark. By carrying out the invention, the step is not generated by not using a double-sided tape, so that the transfer of wrinkles to the sheet material is reduced, and the extra length of the sheet material wound as the lower volume can be greatly reduced.

(A) is an overall schematic perspective view of an adherend (core) according to an embodiment of the present invention, and (B) is an overall schematic perspective view showing a modified example of the adherend (core) of (A). (C) is a whole schematic perspective view which shows the example of a change of the to-be-adhered body (core) of (B). (A) is a perspective view of the whole package in another embodiment using the adherend as a packaging material, (B) is a perspective view of the whole package showing a modified example of (A), and (C) is (A) ) Is a perspective view of the whole package showing another modified example, (D) is an overall perspective view of still another modified example using the adherend, and (E) is still another embodiment of the adherend. The whole perspective view which shows a form, (F) is a perspective view of the whole packing material which shows other embodiment of the said to-be-adhered body. The whole schematic side view of FIG. (A)-(C) are explanatory drawings of the peelable evaluation method of this invention. The perspective view which shows the coating agent of the state accommodated in the container for application | coating in the case of implementing this invention as a coating agent. (A) is a partially enlarged schematic cross-sectional view of a paper tube (core 1) whose surface is formed only of a paper material, and (B) is a paper tube (core 1) whose surface is impregnated with a water-insoluble resin. Partially enlarged schematic sectional views, (C) and (D) are partially enlarged schematic sectional views showing a state in which the paper tube surface of (A) is coated with the coating agent according to the present invention, and (E) is of (A). 1 is a partially enlarged schematic cross-sectional view showing a state in which the coating agent according to the present invention is applied to a paper tube and the resin 20 is impregnated on the surface of the paper tube, (F) is the coating agent according to the present invention to the paper tube of (B). FIG. 2 is a partially enlarged schematic cross-sectional view showing a state in which resin 20 is impregnated on the surface of a paper tube by applying a resin. (A) is No. of Table 4-6. The front view which shows arrangement | positioning of the base paper and PE film in the tensile strength test of No. 6, (B) is a side view of (A), (C) is a schematic side view which shows the state which peels the polyethylene film wound around the paper tube.

Hereinafter, preferred embodiments of the present invention will be described with reference to the drawings.
(Outline of adherend)
As shown in FIG. 1, in this embodiment, the adherend 1 is a winding core (hereinafter referred to as the winding core 1 if necessary), and the patch fixed to the adherend 1 is a sheet material.
That is, the winding core 1 is a cylindrical core material around which a sheet material is wound. In this example, the core 1 is a paper tube. Further, in this example, the entire peripheral surface of the core 1 is the adherend surface 2 on which the sheet material is fixed.
The sheet material can be a plastic film, paper, metal foil, cloth or non-woven fabric. In this embodiment, a case where the sheet material is a plastic film is illustrated.
The adherend surface 2 does not exhibit adhesive force when moisture is not attached, and does not adhere other objects including sheet material and dust. Further, the adherend surface 2 exhibits adhesive force when moisture adheres thereto, and fixes the end portion of the sheet material wound around the core 1 to the core 1. Specifically, it is an application surface formed by applying the coating agent on the adherend surface 2. After the coating agent is applied, the moisture of the coating agent is removed from the adherend surface 2 by evaporation or permeation into the paper tube, and the adherend surface 2 is dried. After drying, unless the moisture is applied to the adherend surface 2, the adhesiveness is suppressed and the adherent surface 2 is not sticky. When the plastic film is wound, the adhesiveness is expressed by applying moisture to the dried adherend surface 2. Due to the developed adhesive strength, the end of the plastic film can be attached to the adherend surface 2 and winding can be started immediately. When the adherend surface 2 is dried again after winding, the plastic film is adhered to the adherend surface 2 by the adhesive force of the adherend surface 2.

(Coating agent)
The coating agent contains a water-soluble polymer as a main component and has a viscosity not exceeding 40,000 mPa · s. For example, when the water-soluble polymer is composed of a kind of resin, the viscosity of the resin does not exceed 40000 mPa · s. On the other hand, when the said water-soluble polymer is comprised from multiple types of resin, each resin shall not exceed 40000 mPa * s about each viscosity. The inventor of the present application has confirmed that when the viscosity of the water-soluble polymer exceeds 40000 mPa · s, it is extremely difficult to apply as a coating agent. Based on such knowledge, the viscosity of the coating agent is set to the above 40,000 mPa · s. The range is set so as not to exceed s. However, the viscosity of the resin itself may exceed 40,000 mPa · s as long as it can be handled as not exceeding 40,000 mPa · s by dilution during operation.

(Selection of resin for coating agent)
Specifically, the coating agent can be formed as the water-soluble polymer containing at least one of a polyvinyl acetate derivative and a polyvinyl alcohol derivative.
The water-soluble polymer preferably contains a polyvinyl acetate resin as the polyvinyl acetate derivative and polyvinyl alcohol as the polyvinyl alcohol derivative.

In particular, the water-soluble polymer preferably includes a first resin that is a polyvinyl alcohol derivative and a second resin that is a polyvinyl alcohol derivative.
That is, the first resin has lower adhesiveness than the polyvinyl acetate resin, and the developed adhesive strength is smaller than that of the polyvinyl acetate resin. In addition, the second resin has a greater adhesive strength than the resin of the first resin.
The polyvinyl acetate resin has a higher adhesive strength than the first and second resins.

Polyvinyl alcohol can be used for both the first resin and the second resin. Here, the said polyvinyl alcohol which is 1st resin is made into 1st polyvinyl alcohol, and the said polyvinyl alcohol which is 2nd resin is made into 2nd polyvinyl alcohol.
However, a modified polyvinyl acetate resin can be adopted as the polyvinyl acetate derivative in addition to the polyvinyl acetate resin. Also for polyvinyl alcohol derivatives, modified polyvinyl alcohol can be adopted in addition to polyvinyl alcohol. Both or one of the first and second resins may be modified polyvinyl alcohol.
Hereinafter, the first polyvinyl alcohol is referred to as polyvinyl alcohol A, and the second polyvinyl alcohol is referred to as polyvinyl alcohol B, as necessary.
However, the water-soluble polymer can also be implemented as a polyvinyl alcohol A (first resin) not containing the polyvinyl acetate resin or polyvinyl alcohol B (second resin).

As the above-mentioned polyvinyl acetate resin, it is desirable to adopt a resin having a viscosity of 1 to 40,000 mPa · s at 23 degrees Celsius.
As the polyvinyl alcohol A, it is desirable to employ a polyvinyl alcohol A having a viscosity of 1 to 3000 mPa · s at 23 degrees Celsius.
Further, as the polyvinyl alcohol B, it is desirable to employ a polyvinyl alcohol having a viscosity of 3000 to 40000 mPa · s at 23 degrees Celsius.
Each of the above resins has a resin concentration that is close to the above upper limit for viscosity, and a resin that is closer to the lower limit than the upper limit within the above range is obtained by diluting and adjusting with water such as water or alcohol. Can do.
As an example of each resin that can be used as a coating agent, the concentration is 7% by weight, that is, 7 parts by weight of resin solids are diluted with 93 parts by weight of water to make the whole 100 weights, and the resin temperature is adjusted to 23 degrees Celsius. When the viscosity is measured at 60 rpm using a BL type viscometer, the polyvinyl acetate resin has a property of 10 mPa · s, and the polyvinyl alcohol A has a property of 67.5 mPa · s. As the polyvinyl alcohol B, a product having a property of 107.5 mPa · s could be employed.

Since the above-mentioned polyvinyl acetate resin has a high adhesive property and a high adhesive force, the above-described properties of the polyvinyl acetate resin alone are sticky even with a small amount of moisture. Furthermore, when a plurality of cores are bundled with a band for transportation and storage in a high temperature and humidity environment, there is a risk that the cores may not be separated from each other even if the bands are unwound. On the other hand, the polyvinyl acetate-based resin can immediately start winding of the sheet material by applying moisture to the adherend surface and sticking the sheet material to the core by its adhesive force.
As described above, the polyvinyl alcohol A has a viscosity lower than that of the polyvinyl acetate resin, has low adhesiveness, and has a lower adhesive pressure than the polyvinyl acetate resin. That is, polyvinyl alcohol A is insensitive to moisture as compared with the above-mentioned polyvinyl acetate resin sensitive to moisture. For this reason, by using together the above polyvinyl acetate resin and polyvinyl alcohol A, the adherend surface 2 can be made difficult to stick even in a high temperature and high humidity environment.

The relationship between the resins will be described in more detail.
The polyvinyl acetate resin exhibits adhesiveness with a smaller amount of water than polyvinyl alcohol A and polyvinyl alcohol B. That is, the above-mentioned polyvinyl acetate resin is higher than the polyvinyl alcohol A in terms of expression of adhesiveness with moisture in the air under high temperature and high humidity. The adhesive strength of the polyvinyl acetate resin is stronger than that of polyvinyl alcohol A and polyvinyl alcohol B.
On the other hand, the adhesive strength of the polyvinyl alcohol A is lower than that of the polyvinyl acetate resin.
If there is a sufficient amount of moisture, such as application of moisture, the polyvinyl acetate resin, polyvinyl alcohol A, and polyvinyl alcohol B all exhibit adhesiveness.

However, regarding the developed adhesive strength, the polyvinyl alcohol B is higher than the polyvinyl acetate resin, and the polyvinyl acetate resin is higher than the polyvinyl alcohol A.
As for the above polyvinyl acetate resin alone, (1) Initial tack necessary for starting the winding of the sheet material and (2) Adhesive strength to the sheet material are excellent, but the manifestation of tackiness with a small amount of water (3) Non-adhesiveness with moisture in the atmosphere under high temperature and humidity is inferior to polyvinyl alcohol A.
Therefore, by adding polyvinyl alcohol A to the coating solution, the amount occupied by the polyvinyl acetate resin can be relatively reduced, and (3) non-adhesiveness can be improved.
On the other hand, as described above, in the polyvinyl alcohol A, the adhesiveness in the moisture in the atmosphere is lower than that in the polyvinyl acetate resin, so that (3) non-adhesiveness is improved, but the adhesive developed under water application Since the above-mentioned polyvinyl acetate resin is higher in strength than polyvinyl alcohol A, (1) the initial adhesiveness is lowered.

The adhesive strength developed under water application is strongest for polyvinyl alcohol B, then strong for polyvinyl acetate resin, and weakest for polyvinyl alcohol A. By using together or using the above-mentioned polyvinyl acetate resin and polyvinyl alcohol A and polyvinyl alcohol B in combination, the initial adhesiveness is improved, and all points regarding the conditions of (1), (2) and (3) It is considered preferable.
In addition, the blending ratio of polyvinyl alcohol B with respect to the blend of the polyvinyl acetate resin and polyvinyl alcohol B, or the blend of the polyvinyl acetate resin with polyvinyl alcohol A and polyvinyl alcohol B If it exceeds 40000 mPa · s, it becomes difficult to perform the operation of coating the surface of the paper tube, and the workability of the coating is impaired.
Therefore, when it is necessary to consider the workability of the coating, it is desirable to mix the polyvinyl acetate resin, polyvinyl alcohol A, and polyvinyl alcohol B in the coating agent.
Moreover, (1) Even if initial adhesiveness is relatively inferior, it can be used with polyvinyl alcohol A alone.

As described above, for the coating agent, the above polyvinyl acetate resin, the above polyvinyl alcohol A, and the above polyvinyl alcohol B are blended, and after applying to the adherend and drying the coated surface In a state where moisture is not actively applied, even in a high-temperature and high-humidity atmosphere, the situation of sticking to others can be practically suppressed, and operability (workability) can be secured.

The preferred resin used for the coating agent is as described above, but when not used in a high temperature and high humidity environment, the coating agent contains a polyvinyl acetate derivative and does not contain a polyvinyl alcohol derivative, or the coating agent. However, it is not excluded to include a polyvinyl alcohol derivative and no polyvinyl acetate derivative.
For example, on the assumption that the viscosity is in a range not exceeding the above 40000 mPa · s, the coating agent can be implemented even if it contains a polyvinyl acetate resin and does not contain any of the above polyvinyl alcohol. Of course, the coating agent is based on the premise that the viscosity does not exceed 40000 mPa · s, and includes polyvinyl alcohol A as described above, and does not include polyvinyl alcohol other than polyvinyl acetate resin and polyvinyl alcohol A. Can also be implemented.

(Preferable resin composition of coating agent)
As described above, by blending two types of resins, polyvinyl acetate resin and polyvinyl alcohol A, the quality of the above-mentioned surface property (high temperature and high humidity conditions) is improved compared to the case of one type of polyvinyl acetate resin. Workability can be improved. In addition, even in a hot and humid environment, in a state where moisture is not actively attached, in order to ensure that the adhesiveness is not exerted, the coating agent is at least a polyvinyl acetate resin as described above. And polyvinyl alcohol A are preferably blended and adjusted as described above. When the coating agent is applied to the winding core to form the adherend surface 2, the viscosity may be adjusted to improve operability.

Specifically, as the coating agent, a resin in which 20 to 100 parts by weight of polyvinyl alcohol A is mixed with 80 to 0 parts by weight of a polyvinyl acetate resin is usually in an environment of 23 degrees Celsius and 50% humidity, for example. Of course, even in an environment of high temperature and high humidity, for example, 50 degrees Celsius and 98% humidity, it is not sticky unless water is applied, and sufficient adhesive strength is exhibited by applying water.
One or more kinds of polyvinyl acetate resin and polyvinyl alcohol A may be used.
As described above, the polyvinyl acetate resin can be blended together with the polyvinyl alcohol A (not 0 parts). In particular, the addition of 1 to 20 parts by weight of polyvinyl alcohol B to the total of 99 to 80 parts by weight of the above polyvinyl acetate resin and polyvinyl alcohol A (100 parts by weight as a whole) further increases the viscosity and increases the adhesive strength. Will improve.

The polyvinyl acetate-based resin may use only one kind having a viscosity in the range of 1 mPa · s to 40,000 mPa · s. In addition, the viscosity after blending is 1 mPa · s to 40,000 mPa · s. It is also possible to use a plurality of types of polyvinyl acetate resins having different viscosities on the assumption that they are in the range. In any of the above cases, the viscosity of the polyvinyl acetate resin may be adjusted to 1 mPa · s to 40,000 mPa · s at the time of producing the coating liquid to produce the intended coating agent.
Moreover, also about polyvinyl alcohol A, it is good also as what uses a viscosity in the range of 1 mPa * s-3,000 mPa * s, and also the viscosity after a mixing | blending is 1 mPa * s-3,000 mPa * s. A plurality of types of polyvinyl alcohol A having different viscosities may be used on the premise that they are in the range of s.
Furthermore, also about polyvinyl alcohol B, it is good also as what uses a viscosity in the range of 3,000 mPa * s-40,000 mPa * s, and also the viscosity after a mixing | blending is 3,000 Pa * s-40. A plurality of types of polyvinyl alcohols B having different viscosities may be used on the premise that they are in the range of 1,000 mPa · s.

When the sheet material is a polyethylene film having a thickness of 50 μm, the sheet material is coated with no moisture in an environment of 23 degrees Celsius to 50 degrees Celsius and 50% to 98% humidity. It is preferable to have an adhesive strength in which the adhered tensile strength is less than 5 N / 60 mm, moisture is applied and the sheet material is adhered, and the tensile strength after 24 hours is 20 N / 60 mm or more and less than 200 N / 60 mm. .
In particular, when the sheet material is made of a polyethylene film having a thickness of 50 μm, the paper tube is attached to the sheet material without applying moisture in an environment of at least 23 degrees Celsius and 50% humidity. More preferably, the strength is less than 5 N / 60 mm, the moisture is applied, the sheet material is pasted, and the tensile strength after 24 hours is 20 N / 60 mm or more and less than 120 N / 60 mm and has an adhesive force.
When the sheet material is a polyethylene film having a thickness of 50 μm, the paper tube is attached to the surface where the sheet material is stuck in an uncoated state in an environment of 50 degrees Celsius and 98% humidity. It is preferable that the strength is less than 5 N / 60 mm, the moisture is applied, the sheet material is pasted, and the tensile strength after 24 hours is 20 N / 60 mm or more and less than 120 N / 60 mm and has adhesive strength.
The polyethylene film is based on a standard indicating adhesive strength as tensile strength, and the sheet material is not limited to the polyethylene film.
In addition, the said adhesive force of the to-be-adhered surface was demonstrated on the basis of a 50-micrometer-thick polyethylene film. Therefore, even if the adhesive strength does not change from the above, if the sheet material is a plastic film other than polyethylene and the conditions other than the material of the sheet material are the same as above, the range of the tensile strength is naturally different from the above. It can be a thing. Further, even if the adhesive force does not change and only the thickness of the reference polyethylene film is different, the range of the tensile strength may be different from the above.
For example, when a strong film such as a polypropylene (PP) film is used as the sheet material, even if the conditions other than the material of the sheet material are the same as described above, moisture is applied and the sheet material is pasted for 24 hours. Later tensile strength exceeds 200 N / 60 mm.

The above viscosity is important for the selection of the resin used for the coating agent. Even with the same viscosity, the concentration may differ due to the difference in the degree of polymerization of the resin. Accordingly, for polyvinyl acetate derivatives and polyvinyl alcohol derivatives, even those having a viscosity exceeding 40,000 mPa · s, diluted with water such as water, and those having a viscosity not exceeding 40,000 mPa · s are also included in the present invention. included.
In particular, from the viewpoint of workability at the time of manufacturing a paper material (adhered body) such as a core, the viscosity of the coating solution is preferably 5,000 to 20,000 mPa · s, and is 5000 mPa · s or less. More preferred.
Next, regarding the coating agent, each resin in the case of using three kinds of polyvinyl acetate resin, polyvinyl alcohol A, and polyvinyl alcohol B will be specifically described.

As already stated, the maximum range of the viscosity of the polyvinyl alcohol A used for lowering the viscosity is 1 mPa · s to 3,000 mPa · s, and the preferred range is 1 mPa · s to 1,500 mPa. S, and a more preferable range is 1 mPa · s to 500 mPa · s.
The maximum range of the viscosity of the polyvinyl alcohol B that is relatively large and used to increase the viscosity is 3,000 mPa · s to 40,000 mPa · s, and a preferable range is 5,000 mPa · s to 30,000 mPa · s. A more preferable range is 10,000 mPa · s to 25,000 mPa · s.
As above-mentioned, adhesive force improves by mix | blending 1-20 weight part of polyvinyl alcohol B. As shown in FIG.
As said polyvinyl acetate type-resin, what makes molecular weight (average molecular weight) 100,000-700,000 is preferable, and what makes molecular weight (average molecular weight) 300,000-400,000 is more preferable.
In the first resin, that is, in this example, the first polyvinyl alcohol preferably has a degree of polymerization of 1200 or less, more preferably a degree of polymerization of 300 to 1200, and a degree of polymerization of 500 to 1000. Most preferred. The first resin may be modified polyvinyl alcohol.
In the second resin, that is, in this example, the second polyvinyl alcohol preferably has a degree of polymerization exceeding 1200, more preferably a degree of polymerization of more than 1200 and not more than 3000, and a degree of polymerization of 1300 to 2000. Is most preferred. The second resin may be modified polyvinyl alcohol.
As described above, here, the first polyvinyl alcohol is polyvinyl alcohol A, and the second polyvinyl alcohol is polyvinyl alcohol B.
Incidentally, some of the above-mentioned polyvinyl alcohol B having a polymerization degree exceeding 2000, particularly those having a polymerization degree of 2300 to 2500, will be described as polyvinyl alcohol D (samples d-1 to d-3 in Table 7) as necessary. To do. When it is not necessary to distinguish in particular in the description, the second polyvinyl alcohol including polyvinyl alcohol D is referred to as polyvinyl alcohol B.
Moreover, the polyvinyl alcohol to be used is not limited to one or both of the first polyvinyl alcohol and the second polyvinyl alcohol. For example, a polyvinyl alcohol having a polymerization degree of 1200 or less is used as the first polyvinyl alcohol and a polymerization degree exceeding 1200 and 2000 or less is used as the second polyvinyl alcohol. Unlike the embodiment described below, the polymerization degree is 2300. The above-mentioned polyvinyl alcohol D of ˜2,500 is the third polyvinyl alcohol, the polyvinyl alcohol having a degree of polymerization of more than 2500 is the fourth polyvinyl alcohol, and the polyvinyl alcohol having a higher degree of polymerization than the fourth polyvinyl alcohol is the first. 5. As the sixth polyvinyl alcohol, one or two or more of the fourth, fifth and sixth polyvinyl alcohols are used in combination with both or one of the second and third polyvinyl alcohols. Also good. As long as the above effects of the present invention are obtained, three or more kinds of polyvinyl alcohols belonging to ranges having different degrees of polymerization may be used in combination.
In addition, if the above-mentioned degree of polymerization and blending ratio are established among the respective resins that are the main part of the present invention, the present invention is blended with components other than the respective resins in addition to the respective resins. Including.

From the convenience of resin handling, the concentration of each resin at the time of manufacture, that is, the dilution conditions with water will be described.
For the acceptable range of concentration of polyvinyl acetate resin,
Polyvinyl acetate resin (solid content): water = 5 parts by weight: 95 parts by weight to 95 parts by weight: 5 parts by weight, and the following range is more preferable.
Polyvinyl acetate resin (solid content): Water = 20 parts by weight: 80 parts by weight to 80 parts by weight: 20 parts by weight.
The following range is particularly preferable for the concentration of the polyvinyl acetate resin.
Polyvinyl acetate resin (solid content): Water = 40 parts by weight: 60 parts by weight to 60 parts by weight: 40 parts by weight.

For the polyvinyl alcohol A, on the premise that the viscosity is low, that is, the viscosity is 1 mPa · s to 3,000 mPa · s, the allowable range of the concentration is
Polyvinyl alcohol A (solid content): water = 1 part by weight: 99 parts by weight to 95 parts by weight: 5 parts by weight, and the following range is more preferable.
Polyvinyl alcohol A (solid content): water = 1 part by weight: 99 parts by weight to 70 parts by weight: 30 parts by weight.
The concentration of the polyvinyl alcohol A is more preferably in the following range.
Polyvinyl alcohol A (solid content): Water = 1 part by weight: 99 parts by weight to 30 parts by weight: 70 parts by weight.

For the polyvinyl alcohol B, on the premise of a large viscosity, that is, 3,000 mPa · s to 40,000 mPa · s, the allowable range of concentration is
Polyvinyl alcohol B (solid content): water = 5 parts by weight: 95 parts by weight to 95 parts by weight: 5 parts by weight. Preferred ranges are as follows.
Polyvinyl alcohol B (solid content): water = 5 parts by weight: 95 parts by weight to 70 parts by weight: 30 parts by weight.
About the density | concentration of polyvinyl alcohol B, the following range is especially preferable.
Polyvinyl alcohol B (solid content): water = 10 parts by weight: 90 parts by weight to 30 parts by weight: 70 parts by weight.

As described above, the present invention can secure the necessary adhesive force and adhesive force at the time of developing adhesiveness while controlling the expression of adhesiveness by providing a water-soluble polymer with appropriate properties on the adherend surface. In addition, it is possible to achieve a good peelability that allows the plastic film after bonding to be peeled off cleanly.
Further, as described above, in addition to employing a water-soluble polymer having an appropriate property, the paper tube surface is coated with the water-soluble polymer to form the adherend surface, that is, the paper tube surface is water-soluble. By forming a polymer coating layer and setting the surface of the coating layer as the adherend surface, the efficacy of the aqueous polymer can be further enhanced.
However, the above water-soluble polymer should be impregnated into the skin of the paper tube on the surface to be coated, and the surface to be coated is not coated. It does not exclude what exposes the background of the paper tube microscopically rather than covering it.
When the adherend is a paper tube or packaging material, the coating amount of the coating agent according to the present invention is preferably 3 g / square meter to 40 g / square meter, and preferably 5 g / square meter to 30 g / square meter. More preferably, it is 10 g / square meter to 20 g / square meter.
However, if the effect of the present invention can be obtained, it is not excluded to set the coating amount outside the above range.
Next, a preferable state of the aqueous polymer on the adherend surface will be specifically described.

As for the paper tube used as the adherend, generally, the surface of the paper tube (core 1) is formed only by the paper material 11 as shown in FIG. 5A, and the paper tube as shown in FIG. What provided the water-insoluble resin 12 on the surface may be used. The water-insoluble resin 12 is usually not completely coated on the surface of the paper tube, that is, coated with a layer, but impregnated into the skin of the paper, as shown in FIG. 5 (B). Microscopically, the paper portion of the fabric is exposed in some places. Specifically, when the skin of the paper tube is enlarged, there is unevenness (FIG. 5A), the water-insoluble resin 12 enters the concave portion of the skin, and the convex portion of the skin is the above The paper material 11 is exposed without being covered with the water-insoluble resin (FIG. 5B).

When using any of the paper tubes shown in FIGS. 5 (A) and 5 (B), by applying the coating agent to the surface of the paper tube, the paper as shown in FIGS. 5 (C) and 5 (D). It is desirable to form a coating layer that coats the tube surface with the aqueous polymer. That is, it is desirable to coat the paper tube surface by forming a layer with resin. Although not shown in the drawings, the water-insoluble resin 12 is also coated on the surface of the paper tube, and the resin 20 that forms the adherend surface 2 is laminated on the resin 12 layer. Also good. Further, even when an unused adherend is coated along the undulations of the paper material as shown in FIG. 5 (C), the surface is used after winding the plastic film (sticking body). As shown in FIG. 5D, the adherend surface 2 may be in a smooth state due to the smooth plastic film. In this case, even if the adherend surface 2 is smooth, it can be reused as long as appropriate adhesiveness, its adhesive strength, adhesive strength, and peelability can be ensured.

However, the adherend surface 2 can be implemented as shown in FIG. 5 (E) or FIG. 5 (F) as long as the required tackiness can be expressed and the adhesive strength, adhesive strength and peelability can be secured. .
For example, when the resin 20 that forms the adherend surface 2 is applied by application of a coating liquid to the paper tube of FIG. 5A, the surface of which is formed only of paper material, the paper tube of FIG. 5B. Like the water-insoluble resin 12, the paper tube surface is not completely coated, that is, the paper tube surface is not coated by layer formation, but the paper skin may be impregnated. That is, the resin 20 forming the adherend surface 2 may enter the concave portion of the skin, and the convex portion of the skin may not be covered with the resin 20 and the paper material 11 may be exposed (FIG. 5). (E)).

On the other hand, when the resin 20 that forms the adherend surface 2 is applied by applying a coating liquid to the paper tube of FIG. 5B impregnated with the water-insoluble resin, the water-insoluble resin 12 and the above-described The resin 20 may enter the concave portion, and the convex portion may be a state in which the paper material 11 is exposed (FIG. 5F).
For example, by applying the coating agent having the resin 20 to the surface of an adherend such as a paper tube using the container 3 shown in FIG. After the disappearance, the resin 20 (resin solid content) is provided in the paper tube in the state shown in FIGS.

Tables 5 to 8 show the tested samples and the test results (evaluation results), and Tables 1 to 4 show the evaluation methods of the samples.

(Evaluation method for adhesive strength)
Water is applied to the adherend surface 2 of the paper tube shown in FIG. 1 (A), and a sheet material, which is a plastic film (PE film), is applied as a patch as shown in Table 1. The adhesive strength was evaluated based on the time taken to remove. It shows that adhesive force is so strong that the said time is short. In addition, the shorter the time, the higher the adhesiveness developability.

(Evaluation criteria)
In the evaluation of adhesive strength shown in Table 1, water was applied to the surface of the adherend layer 2 of the core 1 having a diameter of 100 mm, which is the paper tube shown in FIG. 1A, and the width (in the axial direction of the core) was 250 mm. The time from when the sheet material having a length of 35 cm was pasted to the surface of the core 1, that is, the adherend surface 2 to when it was wound around the core 1 was measured. In this measurement, as shown in Table 1, after being applied to the surface of the core 1, that is, the adherend surface 2, the winding completed instantaneously, that is, in less than 1 second, is “excellent” and is wound within 1 second to 5 seconds. Winding is completed with “excellent” when completed, “good” when winding is completed within 10 seconds over 5 seconds, and “possible” when winding is completed within 10 seconds but less than 30 seconds Those that took 30 seconds or more to complete were evaluated as “impossible”.

(Surface property)
As shown in FIG. 3A, the paper tube having the dimensions used in Table 1 above, which is the core 1, is bound with three PP (polypropylene) bands r, and the set conditions are 48 with a constant temperature and humidity chamber. After putting the time, the evaluation was made based on whether or not the paper tubes were caught at the moment when the band r was cut with 鋏 h (FIG. 3 (C)) or not (FIG. 3 (B)).

(Workability)
In the process up to the production of the coating agent, the viscosity of the resin mixed at 23 degrees Celsius was measured and evaluated with a BL type viscometer at 60 rpm.

Regarding the evaluation criteria for the workability at the time of producing the coating agent, as shown in Table 2, the viscosity is “excellent” when the viscosity is 5,000 mPa · s or less, and the viscosity is larger than 5,000 mPa · s and 20,000 mPa · s or less. “Good”, “greater than 20,000 mPa · s and less than 40,000 mPa · s” as “allowed”, and 40,000 mPa · s or more as “impossible”.

(Peelability)
The sheet material wound around the paper tube, which is the core 1, was peeled cleanly from the paper tube to the end. As shown in Table 3, those that were not torn by visual observation were rated as ◯, and those that were confirmed by visual inspection were marked as x.

(Test results)
Table 4 shows test item No. 1 with respect to sample a-1 in which the coating surface prepared by applying one kind of polyvinyl acetate resin (single substance) to form the adherend surface 2. 1-No. An evaluation of 5 was made.
The average molecular weight of the polyvinyl acetate resin of sample a-1 is in the range of 300,000 to 400,000.
Test item no. 1 is the above-mentioned adhesive strength. No. 2 is the surface property in a natural state, that is, in an atmosphere of 23 degrees Celsius and 50% humidity in 48 hours. 3 is a surface property at 48 hours in an atmosphere of high temperature and high humidity, ie, 50 degrees Celsius and 98% humidity. Sample a-1 has a viscosity at 23 degrees Celsius of 8,300 mPa · s. 5 is the above-mentioned peelability. Test item No. No. 2 surface property in 48 hours in an atmosphere of 23 degrees Celsius and 50% humidity. The surface property at 48 hours in an atmosphere of high temperature and high humidity, that is, 50 degrees Celsius and 98% humidity is a result after 48 hours have passed in the constant temperature and humidity chamber set to each temperature and humidity.

Furthermore, no. The adhesive strength of 6 was evaluated.
No. The tensile strength of 6 is obtained as a result of the following tensile test. That is, in the tensile test, as a test material, an adherend was used as a base paper p1 (paper) having a thickness of 0.50 mm used on the surface of a paper tube, and a patch was used as a PE (polyethylene) film p3 having a thickness of 50 μm.
As shown in FIG. 6A, the size of the base paper p1 is 140 mm in the vertical width w1 (tensile direction width) and 70 mm in the horizontal width w2, and the size of the PE film p3 is the vertical width w3 (width in the tensile direction). The width w4 was set to 200 mm, and the width w4 was set to 70 mm. As shown in FIG. 6B, the size of the adherend surface 2 of the base paper p1, that is, the adhesive surface p2, was 60 mm in the vertical width (the overlapping width w5 in the tensile direction) and 70 mm in the horizontal width. Specifically, the coating agent is applied to the base paper p1 over the entire width in the longitudinal direction (tensile direction) over 60 mm by a bar coater # 18 at a coating amount of 40 g / square meter, and the PE film p3 is applied to the adhesive surface p2 of the base paper p1. Are in a stacked state.
The test method is
1) As described above, the PE film p3 was placed on the adhesive surface p2 of the base paper p1, and left to dry for one day (24 hours).
2) Humidity was adjusted to 23 degrees Celsius and 50% humidity with a constant temperature and humidity chamber.
3) Grasp the base paper p1 and PE film p3 with a universal testing machine and measure at a tensile speed of 10 mm / min (fix the lower end p10 of the base paper p1 shown in FIG. 6 (B) to the testing machine, and upper end of the PE film p3. p30 was pulled upward).
4) The measurement was performed until it peeled off at the adhesive surface p2 or the PE film p3 was broken.
5) The maximum adhesive strength (N / 60 mm) was measured. “˜N / 60 mm” indicates the force (Newton) when the overlapping width w5 in the tensile direction is 60 mm as described above.
6) The average value of 3 times of 5) was taken.
7) As a test result, it was recorded whether the PE film p3 was broken (denoted as MF) or the adhesive surface P2 (base paper p1 side) was broken (denoted as AF).

As shown in Table 4, the evaluation result of sample a-1 containing 100 parts of polyvinyl acetate resin is No. No. 1 adhesive strength “Excellent”, No. 1 No. 2 is “excellent” with respect to the surface property in the natural state. No. 3 is “impossible” for the surface property of high temperature and high humidity. No. 4 is “good” due to the viscosity of 8,300 mPa · s. Appearance confirmation about the peelability of 5 was ○. In addition, test item No. of sample a-1. Regarding the strength of 6 (tensile strength), the PE film p3 was ruptured (MF) at 120 N or more / 60 mm, and measurement was impossible.
From the evaluation results of sample a-1, it was understood that when the resin of the coating agent was only a polyvinyl acetate resin, adhesive force was generated under high temperature and high humidity conditions, and the paper tubes were caught. That is, it can be seen that the polyvinyl acetate resin alone has high adhesiveness and high adhesive strength and is easily sticky. Moreover, it turns out that the adhesive force of a polyvinyl acetate-type resin is strong.
Therefore, when using the coating agent which uses only a polyvinyl acetate resin as a resin component, it can be grasped that it is suitable for use in the natural state and not suitable for use in high temperature and high humidity.

Table 5 shows b-1 to b-6 in which the adherend surface 2 was formed with a coating agent prepared by blending two types of resins of polyvinyl acetate resin and polyvinyl alcohol A at different blending ratios (weights). For the six samples, test item Nos. 1-No. An evaluation of 6 was made.
For samples b-1 to b-6, those having an average molecular weight of polyvinyl acetate resin in the range of 300,000 to 400,000 and a polymerization degree of polyvinyl alcohol A of 1000 were employed.
For comparison, sample a-1 in Table 4 is also shown. Sample b-1 is 10 parts by weight of polyvinyl alcohol A (100 parts by weight in total) with respect to 90 parts by weight of polyvinyl acetate resin, and sample b-2 is 20 parts by weight of polyvinyl alcohol A with respect to 80 parts by weight of polyvinyl acetate resin (100 in total). Sample b-3 is 40 parts by weight of polyvinyl alcohol A (100 parts by weight in total) with respect to 60 parts by weight of the polyvinyl acetate resin, and sample b-4 is 60 parts by weight of polyvinyl alcohol A with respect to 40 parts by weight of the polyvinyl acetate resin. Parts (total 100 parts by weight), sample b-5 is 20 parts by weight of polyvinyl acetate resin, polyvinyl alcohol A 80 parts by weight (total 100 parts by weight), sample b-6 is 10 parts by weight of polyvinyl acetate resin Polyvinyl alcohol A was 90 parts by weight (total 100 parts by weight).
Sample b-7 contains 100 parts by weight of polyvinyl alcohol A (0 part by weight of a polyvinyl acetate resin).

As shown in Table 5, sample b-1 has a test item No. 1 (adhesive strength) and No. 1 No. 2 (natural surface properties) is “excellent”. 3 (high temperature and high humidity surface property), “No”, No. For the workability of No. 4, "Good", No. About 5 (peeling property), it was "(circle)". In addition, the test item No. Regarding the strength of 6 (tensile strength), the PE film p3 was ruptured (MF) at 120 N or more / 60 mm, and measurement was impossible.
Sample b-2 has a test item No. 1 (adhesive strength), No. 1 2 (natural surface properties) and No. 2 No. 3 (surface property of high temperature and high humidity) is “excellent”. For the workability of No. 4, “Excellent”, No. About 5 (peeling property), it was "(circle)". In addition, test item No. of sample b-2. Regarding the strength of 6 (tensile strength), the PE film p3 was broken at 120 N or more / 60 mm, and measurement was impossible (MF).
Sample b-3 has test item no. 1 (adhesive strength), No. 1 2 (natural surface properties), No. 2 3 (surface property of high temperature and high humidity) and No. 3 As for the workability of No. 4, all are “excellent”. About 5 (peeling property), it was "(circle)". Sample b-3 has a test item no. Regarding the strength of 6 (tensile strength), the PE film p3 was ruptured (MF) at 120 N or more / 60 mm, and measurement was impossible.
Sample b-4 has a test item no. 1 (adhesive strength), No. 1 2 (natural surface properties), No. 2 3 (surface property of high temperature and high humidity) and No. 3 As for the workability of No. 4, all are “excellent”. About 5 (peeling property), it was "(circle)". Sample b-4 and sample b-5 are test item Nos. With respect to the strength of 6 (tensile strength), the bonded surface was broken (AF) at 87 N / 60 mm.
Sample b-5 was tested item no. No. 1 (adhesive strength) is “good”. 2 (natural surface properties), No. 2 3 (surface property of high temperature and high humidity) and No. 3 As for the workability of No. 4, all are “excellent”. About 5 (peeling property), it was "(circle)". In addition, test item No. of sample b-5. The adhesive surface was broken (AF) at 74 N / 60 mm with a strength of 6 (tensile strength).
Sample b-6 has a test item No. No. 1 (adhesive strength) is “good”. 2 (natural surface properties), No. 2 3 (surface property of high temperature and high humidity) and No. 3 As for the workability of No. 4, all are “excellent”. About 5 (peeling property), it was "(circle)". In addition, test item No. of sample b-6. With respect to the strength of 6 (tensile strength), the adhesive surface was broken (AF) at 69 N / 60 mm.
Sample b-7 was tested item no. No. 1 (adhesive strength) is “OK”. 2 (natural surface properties), No. 2 3 (surface property of high temperature and high humidity) and No. 3 As for the workability of No. 4, all are “excellent”. About 5 (peeling property), it was "(circle)". In addition, test item No. of sample b-7. The adhesive surface was broken (AF) at 67 N / 60 mm for a strength of 6 (tensile strength).

From the result of the above sample b-1, if not used in a hot and humid environment with the conditions shown in Table 5, 10 parts by weight of a polyvinyl alcohol A coating agent is added to 90 parts by weight of the polyvinyl acetate resin. The used adherend 1 can also be used. Moreover, from the result of the sample b-1, the workability at 23 degrees Celsius is also “good” and can withstand practical use.
On the other hand, from the results of samples b-2, b-3, and b-4, in the range of polyvinyl acetate resin: polyvinyl alcohol A = 80 to 40 parts by weight: 20 to 60 parts by weight, the adhesive strength, the natural state and The surface property and workability of high temperature and high humidity are all “excellent”, and the peelability is “Excellent” which is not found in other samples, and the adherend 1 can be formed with a highly practical coating agent. I can grasp.
From the results of samples b-5 and b-6, in the range of the polyvinyl acetate resin: the polyvinyl alcohol A = 20 to 10 parts by weight: 80 to 90 parts by weight, the adhesive strength is “good”, the natural state and It can be understood that the adherend 1 can be formed with an excellent coating agent having sufficient practicality as “excellent” for the surface property and workability of high temperature and high humidity, and “◯” for the peelability.
From the result of sample b-7, when the polyvinyl alcohol A was 100 parts by weight (polyvinyl acetate resin 0 part by weight), the adhesive strength was “OK”, and the above-mentioned natural state and high temperature and high humidity surface properties and work It can be understood that the adherend 1 can be formed with a coating material that can withstand practical use.
In particular, the samples b-1, b-2, and b-3 all had a tensile strength of 120 N or more / 60 mm and the PE film p3 was ruptured (MF). Therefore, the polyvinyl acetate resin: the polyvinyl alcohol A = 90 to In the range of 60 parts by weight: 10 to 40 parts by weight, it can be seen that the adhesion strength of the adherend surface is strong.
In particular, from the samples b-4, b-5, b-6, and b-7 whose tensile strength was 87 N / 60 mm or less and the adhesive surface was broken (AF), the polyvinyl acetate resin: the polyvinyl alcohol A = 40-0. Part by weight: In the range of 60 to 100 parts by weight, it can be seen that the adherend surface is easy to peel off.
From the above samples b-4, b-5, and b-6, within the range of the polyvinyl acetate resin: the polyvinyl alcohol A = 40 to 10 parts by weight: 60 to 90 parts by weight, the above ease of peeling and appropriateness It can be seen that the adhesive strength, surface property, and workability are all secured.

From sample a-1 in Table 5, when the resin is the above-mentioned polyvinyl acetate resin, it can be used as long as use in a high-temperature and high-humidity atmosphere under the above conditions is avoided. Sample b- in Table 5 Combined with the results of 1 to b-7, the coating agent in the range of the polyvinyl acetate resin: the polyvinyl alcohol A = 100 to 0 parts by weight: 0 to 100 parts by weight is used in the high temperature and high humidity environment. It can be used on condition that the workability is avoided and the workability is devised. And in the range of the said polyvinyl acetate-type resin: said polyvinyl alcohol A = 80-0 weight part: 20-100 weight part, the to-be-adhered body 1 by the coating liquid which is practical also in the said hot and humid conditions can be provided. It could be confirmed. In particular, in the range of the above-mentioned polyvinyl acetate resin: the above-mentioned polyvinyl alcohol A = 80 to 10 parts by weight: 20 to 90 parts by weight, it was confirmed that an excellent adherend 1 with a coating agent could be formed. Moreover, it was confirmed that in the range of the polyvinyl acetate resin: the polyvinyl alcohol A = 80 to 40 parts by weight: 20 to 60 parts by weight, a very excellent adherend 1 can be formed using a coating agent. On the other hand, when including the viewpoint of ease of peeling, in the range of the polyvinyl acetate resin: the polyvinyl alcohol A = 40 to 10 parts by weight: 60 to 90 parts by weight as described above, an extremely excellent coating by the coating agent. It was confirmed that the body 1 could be formed.

Table 6 shows c-1 in which the adherend surface 2 is formed with a coating agent prepared by blending three kinds of resins of polyvinyl acetate resin, polyvinyl alcohol A, and polyvinyl alcohol B at different blending ratios (weights). ˜c-3, the same test item No. as in Table 4 and Table 5 was used. 1-No. An evaluation of 5 was made.
For samples c-1 to c-3, the polyvinyl acetate resin has an average molecular weight in the range of 300,000 to 400,000, the polymerization degree of polyvinyl alcohol A is 1000, and the polymerization degree of polyvinyl alcohol B is 1700. Adopted.
For comparison, the data of sample b-1 in Table 5 is also shown in Table 6. Sample c-1 was 85 parts by weight of polyvinyl acetate resin, 10 parts by weight of polyvinyl alcohol A, and 5 parts by weight of polyvinyl alcohol B (100 parts by weight in total). Sample c-2 was 70 parts by weight of polyvinyl acetate resin and polyvinyl alcohol A10. Parts by weight, 20 parts by weight of polyvinyl alcohol B (100 parts by weight in total), and sample c-3 was 65 parts by weight of polyvinyl acetate resin, 10 parts by weight of polyvinyl alcohol A, and 25 parts by weight of polyvinyl alcohol B (100 parts by weight in total).

As shown in Table 6, sample c-1 was No. 1 (adhesive strength), No. 1 2 (surface property in the natural state) and No. 2 3 (surface property of the above-mentioned high temperature and high humidity) is “excellent”. No. 4 (workability) “No”, No. It was "(circle)" about 5 (peeling property). Sample c-2 is No. No. 1 (adhesive strength) “excellent”, no. 2-No. No. 3 (surface property) is “excellent”. No. 4 (workability) is “good”. It was "(circle)" about 5 (peeling property). Sample c-3 was no. No. 1 (adhesive strength) “excellent”, no. 2-No. No. 3 (surface property) is “excellent”. 4 (workability) is “OK”. It was "(circle)" about 5 (peeling property). In addition, any test item No. of samples c-1, c-2, and c-3. Regarding the strength of 6 (tensile strength), the PE film p3 was ruptured (MF) at 120N or more / 60 mm, and measurement was impossible.

From the results shown in Table 6, the above-mentioned polyvinyl acetate resin: the above polyvinyl alcohol A: the above polyvinyl alcohol B = 85 to 65 parts by weight: 10 parts by weight: the coating formed in the range of 5 to 25 parts by weight The body 1 can be said to withstand practical use.
In particular, in the coating solution in the range of the above polyvinyl acetate resin: the polyvinyl alcohol A: the polyvinyl alcohol B = 85 to 70 parts by weight: 10 parts by weight: 5 to 20 parts by weight It can be seen that the adherend 1 can be provided with a coating solution that is extremely excellent in practicality.
Moreover, it turns out that all the samples c-1, c-2, and c-3 have strong adhesive force.
From the above points, the adhesive strength is obtained by blending 5 to 20 parts by weight (total 100 parts by weight) of polyvinyl alcohol B with respect to 95 to 80 parts by weight in combination with the polyvinyl acetate resin and the polyvinyl alcohol A. It can be grasped that it improves.
When sample b-1 is included in Table 7, 0 to 20 parts by weight (100 parts by weight in total) of polyvinyl alcohol B is blended with 100 to 80 parts by weight of the polyvinyl acetate resin and polyvinyl alcohol A. By doing so, it can be understood that the adhesive strength is improved.
In practical use, the polyvinyl acetate B and the polyvinyl alcohol A are combined with 99 to 80 parts by weight, and the polyvinyl alcohol B is added by blending 1 to 20 parts by weight (total 100 parts by weight). It is appropriate to improve the adhesion of the surface.

Table 7 shows the d-1 in which the adherend surface 2 is formed by a coating agent prepared by blending three kinds of resins of polyvinyl acetate resin, polyvinyl alcohol A and polyvinyl alcohol D at different blending ratios (weights). ˜d-3, the same test item No. as in Table 5 and Table 6 was used. 1-No. An evaluation of 5 was made.
About samples d-1 to d-3, the average molecular weight of the polyvinyl acetate resin is in the range of 300,000 to 400,000, the polymerization degree of polyvinyl alcohol A is 1000, and the polymerization degree of polyvinyl alcohol D is 2300. Adopted.
For comparison, the data of sample b-1 in Table 5 is also shown in Table 7.
For polyvinyl alcohol D, the concentration is 7% by weight, that is, 7 parts by weight of resin solids are diluted with 93 parts by weight of water to make the whole 100 parts by weight, the resin temperature is adjusted to 23 degrees Celsius, When the viscosity was measured under the condition of 60 rpm using a meter, the one having a viscosity of 45,000 mPa · s was used.

As shown in Table 7, sample d-1 was No. No. 1 (adhesive strength) is “excellent”. 2 (surface property in the natural state) and No. 2 3 (surface property of the above-mentioned high temperature and high humidity) is “excellent”. No. 4 (workability), “No”, No. It was "(circle)" about 5 (peeling property). Sample d-2 is No. No. 1 (adhesive strength) “excellent”, no. 2-No. No. 3 (surface property) is “excellent”. 4 (workability) is “impossible”. It was "(circle)" about 5 (peeling property). Sample d-3 was no. No. 1 (adhesive strength) “excellent”, no. 2-No. No. 3 (surface property) is “excellent”. 4 (workability) is “impossible”. It was "(circle)" about 5 (peeling property).

From the results in Table 7, the above-mentioned polyvinyl acetate resin: the above polyvinyl alcohol A: the above polyvinyl alcohol D = 85 to 65 parts by weight: 10 parts by weight: 5 to 25 parts by weight, all about workability It is “impossible” and it is understood that there is a problem in workability. If workability can be ensured by devising, it can be said that the adherend 1 to be formed can withstand practical use.

(Surface roughness)
After applying (coating) a water-repellent resin as an application agent, it can be confirmed that the surface roughness and the swell quality are improved by applying (coating) an adhesive resin.
As the water-repellent resin, any one of acrylic resin, acrylic-styrene resin, polyurethane resin, and alkyd resin can be adopted, and two or more of these resins are mixed. Can be used.
As said adhesive resin, the coating agent which concerns on this invention is employable.

Specifically, for the surface roughness, four samples e-1 to e-4 shown in Table 8 were prepared and evaluated according to JIS B 0601. In Table 8, the evaluation item No. 1 is the average roughness (Ra) of the sample surface; 2 is the maximum height (Ry) of the roughness curve of the sample. 3 is the maximum height (Rmax) of the cross-sectional curve of the sample. 4 shows the waviness (Wt) of the sample.
The seam gap is a gap between sides where the strip-shaped paper material is joined by rolling the strip-shaped paper material into a cylindrical shape when forming the paper tube.

Samples e-1 and e-2 in Table 8 were portions having no seam gap, and sample e-1 was coated on the adherend 1 with an acrylic resin as an example in which only the water-repellent resin was coated. Sample e-2 was prepared by coating the adherend 1 with each of an acrylic resin and an adhesive resin as an example of coating the adherend 1 with a water-repellent resin and an adhesive resin. The adhesive resin having the same properties as the sample c-2 in Table 6 above was used.
Samples e-3 and e-4 in Table 8 were portions having a seam gap, and sample e-3 was coated on the adherend 1 with an acrylic resin as an example in which only the water-repellent resin was coated. Sample e-4 was prepared by coating the adherend 1 with an acrylic resin and an adhesive resin as examples in which each of a water-repellent resin and an adhesive resin was coated. For sample e-4, the same adhesive resin as that of sample c-2 in Table 6 was used.

As shown in Table 8, sample e-1 was evaluated item No. No. 1 (average roughness) 2.30 μm, No. 1 No. 2 (maximum height of roughness curve), 14.37 μm, no. 3 (maximum height of the cross-sectional curve) 43.73 μm, No. 3 4 (swell) was 23.41 μm.
Sample e-2 is evaluated item no. No. 1 (average roughness), 1.40 μm, No. 1 No. 2 (maximum height of the roughness curve), 8.87 μm, no. 3 (maximum height of the cross-sectional curve) 25.10 μm, No. 3 4 (swell) was 14.95 μm.
Sample e-3 was evaluated item no. No. 1 (average roughness) 2.36 μm, No. 1 No. 2 (maximum height of the roughness curve), 15.37 μm, no. 3 (maximum height of the cross-sectional curve) 50.20 μm, no. 4 (swell) was 31.11 μm.
Sample e-4 is evaluated item No. No. 1 (average roughness) 1.57 μm, No. 1 No. 2 (maximum height of roughness curve) 10.10 μm, No. 2 3 (maximum height of the cross-sectional curve) 48.29 μm, No. 3 4 (swell) was 30.08 μm.

As described above, the sample e-2 coated with both the water-repellent resin and the adhesive resin with respect to the sample e-1 coated with only the water-repellent resin is No. 1-No. It can be understood that the roughness value (μm) is small for any of the four items. Similarly, the sample e-4 coated with the water-repellent resin and the adhesive resin is the same as the sample e-3 coated only with the water-repellent resin. 1-No. It can be understood that the roughness value (μm) is small for any of the four items.
From the results shown in Table 8, it was confirmed that the surface roughness and the swell quality were improved by coating the adhesive resin after coating the water-repellent resin.

The inventor of the present application, as shown in FIG. 6 (C), in the field, the PE film (sheet material 10) after one week that was actually attached to the adherend surface and wound on the core 1, The film was taken in the reverse direction of the winding direction, pulled, peeled off the PE film, and the surfaces of the PE film and the core 1 were visually observed. The coating agent for forming the adherend surface was the same as sample c-2 (Table 6).
As a result, it was confirmed that the PE film could be peeled cleanly without breaking, and that the resin on the adherend surface was not attached to the PE film side.

Samples b-1 to b-7 shown in Table 5 had a polymerization degree of polyvinyl alcohol of 1000. For the samples b-1 to b-7, the polyvinyl alcohol to be blended had a polymerization degree of 300, and the other conditions in Table 5 were changed without changing other conditions. 1-No. No. 5 was evaluated, and the polymerization degree of polyvinyl alcohol to be further blended was set to 200. 1 and No. The results of the evaluation of 4 are shown in Table 9. In Table 9, the polyvinyl alcohol polymerization degree samples 1000 shown in Table 5 and the sample a-1 in Table 4 are also shown.
That is, in Table 9, b-1 to b in which the adherend surface 2 was formed with a coating agent prepared by blending two kinds of resins of polyvinyl acetate resin and polyvinyl alcohol A at different blending ratios (weights). For the six samples of -6, the same test item no. 1-No. An evaluation of 5 was made.
In any of the samples b-1 to b-6 in Table 9 where the degree of polymerization of polyvinyl alcohol A is 300 or 200, as described above, a polyvinyl acetate resin having an average molecular weight in the range of 300,000 to 400,000 Sample b-1 is 10 parts by weight of polyvinyl alcohol A (100 parts by weight in total) with respect to 90 parts by weight of polyvinyl acetate resin, and sample b-2 is 20 parts by weight of polyvinyl alcohol A with respect to 80 parts by weight of polyvinyl acetate resin. (100 parts by weight in total), sample b-3 is 40 parts by weight of polyvinyl alcohol A (100 parts by weight in total) with respect to 60 parts by weight of polyvinyl acetate resin, and sample b-4 is polyvinyl with respect to 40 parts by weight of polyvinyl acetate resin. Alcohol A 60 parts by weight (total 100 parts by weight), sample b-5 is a polyacetate based on 20 parts by weight of polyvinyl acetate resin. Nyl alcohol A 80 parts by weight (total 100 parts by weight), sample b-6 is polyvinyl alcohol A 90 parts by weight (total 100 parts by weight) with respect to 10 parts by weight of polyvinyl acetate resin, and sample b-7 is polyvinyl Alcohol A is 100 parts by weight (polyvinyl acetate resin 0 parts by weight).

First, each sample b-1 to b7 in which the degree of polymerization of polyvinyl alcohol A in Table 9 is 300 will be described.
Sample b-1 has a test item no. 1 (adhesive strength) and No. 1 No. 2 (natural surface properties) is “excellent”. 3 (high temperature and high humidity surface property), “No”, No. For the workability of No. 4, “Excellent”, No. About 5 (peeling property), it was "(circle)".
Sample b-2 has a test item No. 1 (adhesive strength), No. 1 2 (natural surface properties), No. 2 3 (surface property of high temperature and high humidity) and No. 3 As for the workability of No. 4, all are “excellent”. About 5 (peeling property), it was "(circle)".
Sample b-3 has test item no. No. 1 (adhesive strength) “Good”, No. 2 (natural surface properties), No. 2 3 (surface property of high temperature and high humidity) and No. 3 As for the workability of No. 4, all are “excellent”. About 5 (peeling property), it was "(circle)".
Sample b-4 has a test item no. No. 1 (adhesive strength) “Good”, No. 2 (natural surface properties), No. 2 3 (surface property of high temperature and high humidity) and No. 3 As for the workability of No. 4, all are “excellent”. About 5 (peeling property), it was "(circle)".
Sample b-5 was tested item no. No. 1 (adhesive strength) is “OK”. 2 (natural surface properties), No. 2 3 (surface property of high temperature and high humidity) and No. 3 As for the workability of No. 4, all are “excellent”. About 5 (peeling property), it was "(circle)".
Sample b-6 has a test item No. No. 1 (adhesive strength) is “OK”. 2 (natural surface properties), No. 2 3 (surface property of high temperature and high humidity) and No. 3 As for the workability of No. 4, all are “excellent”. About 5 (peeling property), it was "(circle)".
Sample b-7 was tested item no. No. 1 (adhesive strength) is “impossible”. 2 (natural surface properties), No. 2 3 (surface property of high temperature and high humidity) and No. 3 As for the workability of No. 4, all are “excellent”. About 5 (peeling property), it was "(circle)".

From the result of sample b-1 in which the degree of polymerization of polyvinyl alcohol A in Table 9 is 300, if not used in a hot and humid environment with the conditions shown in Table 9, 90 parts by weight of polyvinyl acetate resin is used. In contrast, it can be seen that the adherend 1 using 10 parts by weight of the coating agent of polyvinyl alcohol A can be used. In addition, regarding the result of sample b-1, the workability at 23 degrees Celsius is “excellent” and can be said to be practical.
On the other hand, from the results of samples b-2, b-3, and b-4 in which the degree of polymerization of polyvinyl alcohol A in Table 9 is 300, polyvinyl acetate resin: polyvinyl alcohol A = 80 to 40 parts by weight: 20 to 60 In the range of parts by weight, the adhesive strength, the natural state and the surface properties of hot and humid, and the workability are all “excellent” or “good”, and the peelability is “Excellent” and not excellent in other samples. It can be understood that the adherend 1 can be formed with a highly practical coating agent.
In particular, sample b-2 in which the degree of polymerization of polyvinyl alcohol A in Table 9 is 300 is No. 1-No. 5 is “excellent”, and it can be understood that it is most preferable that the coating ratio is about 80 parts by weight: 20 parts by weight of polyvinyl acetate resin: polyvinyl alcohol A.
Further, from the results of samples b-5 and b-6 in which the degree of polymerization of polyvinyl alcohol A in Table 9 is 300, the polyvinyl acetate resin: the polyvinyl alcohol A = 20 to 10 parts by weight: 80 to 90 parts by weight. In the range, the adhesive strength is “OK”, the above-mentioned natural state and high-temperature and high-humidity surface properties and workability are both “excellent”, and the peelability is “◯”. It can be understood that the kimono 1 can be formed.
From the result of sample b-7 in which the degree of polymerization of polyvinyl alcohol A in Table 9 is 300, when the polyvinyl alcohol A is 100 parts by weight (polyvinyl acetate resin 0 part by weight), the above natural state and high temperature and high humidity surface It can be understood that although both excellent and workability are “excellent” and peelability is “◯”, the adhesive strength is “impossible” and impractical.
From the above samples b-4, b-5 and b-6 with a polymerization degree of polyvinyl alcohol A of 300 in Table 9, the polyvinyl acetate resin: the polyvinyl alcohol A = 80 to 20 parts by weight: 10 to 90 In the range of parts by weight, it can be seen that the above ease of peeling and appropriate adhesive strength, surface properties, and workability are all ensured.

From sample a-1 in Table 9, when the resin is the above-mentioned polyvinyl acetate resin, it can be used as long as the use in a high-temperature and high-humidity atmosphere under the above conditions is avoided. Combined with the results of samples b-1 to b-6 with a degree of polymerization of 300, the coating agent in the range of polyvinyl acetate resin: polyvinyl alcohol A = 100 to 0 parts by weight: 10 to 90 parts by weight It can be used on the condition that it avoids the use in the high temperature and high humidity environment and devise the workability. And in the range of the polyvinyl acetate resin: the polyvinyl alcohol A = 80 to 10 parts by weight: 20 to 90 parts by weight from the sample in which the polymerization degree of the polyvinyl alcohol A in Table 9 is 300, even under the high temperature and high humidity conditions. It was confirmed that the adherend 1 with a practical coating solution could be provided. In particular, it was confirmed that an excellent adherend 1 with a coating agent could be formed in the range of the above polyvinyl acetate resin: the above polyvinyl alcohol A = 80 to 40 parts by weight: 20 to 60 parts by weight.

Next, each sample b-1 to b7 in which the polymerization degree of polyvinyl alcohol A in Table 9 is 200 will be described.
Samples b-1 to b-3 all have test item nos. 1 (adhesive strength) is “good”. The workability of 4 was “excellent”.
Sample b-4 and sample b-5 have test item Nos. No. 1 (adhesive strength) is “OK”. The workability of 4 was “excellent”.
Sample b-6 and sample b-7 are both No. Although the workability of No. 4 is “excellent”, the test item No. About 1 (adhesive strength), it was “impossible”.
From the results of samples b-1 to b-5 in which the degree of polymerization of polyvinyl alcohol A in Table 9 is 200, polyvinyl acetate resin: polyvinyl alcohol A = 90: 10-20: In the range of 80, it can be seen that a coating solution having no problem with respect to adhesive strength and peelability can be obtained. In consideration of the result of sample b-1, when not used at high temperature and high humidity, polyvinyl alcohol A having a polymerization degree of 200 is in the range of polyvinyl acetate resin: polyvinyl alcohol A = 90: 10 to 20:80. It can be said that it can be used. In particular, from the results of samples b-2 to b-5, those having a polymerization degree of polyvinyl alcohol A of 200 are those of high temperature and high humidity in the range of polyvinyl acetate resin: polyvinyl alcohol A = 80: 20 to 20:80. It turns out that it is excellent even in the environment.

Samples c-1 to c-3 in Table 6 have a weight ratio of polyvinyl acetate resin: polyvinyl alcohol A: polyvinyl alcohol B of 85: 10: 5, 70:10:20, and 65:10, respectively. : 25.
Table 10 shows samples c-1 to c-3 together with a sample c-x having a weight ratio of polyvinyl acetate resin: polyvinyl alcohol A: polyvinyl alcohol B of 80:10:10, and 75:10: Sample cy to be 15 and sample c-4 to be 60:10:30 were added. For sample c-x, sample cy, and sample c-4, the molecular weight of the polyvinyl acetate resin and the degree of polymerization of polyvinyl alcohol A and polyvinyl alcohol B are the same as those of samples c-1 to c-3 in Table 6 ( The results of the degree of polymerization 1700) are noted. Moreover, regarding each sample of Table 10 including the sample c-x, the sample cy, and the sample c-4, the molecular weight of the polyvinyl acetate resin and the degree of polymerization of the polyvinyl alcohol A are the values of each sample c-1 to 1 of Table 6. No change was made from No. c-3 and the polymerization degree of polyvinyl alcohol B was set to 3000. 1-No. Results of 5 tests were added. In addition, the data of samples c-1 to c-3 in Table 6 are also shown in Table 10 for easy comparison.

For sample c-x in which the degree of polymerization of polyvinyl alcohol B in Table 10 is 1700, no. 1-No. For each item of “3”, “Excellent”, No. No. 4, “Good”, No. 5 was “◯”.
Further, for sample cy in which the degree of polymerization of polyvinyl alcohol B in Table 10 is 1700, no. 1 is “Hide”, No. 1 2 and no. 3 is “excellent”. 4 is “good”. 5 was “◯”.
For sample c-4 in which the degree of polymerization of polyvinyl alcohol B in Table 10 is 1700, no. 1 is “Hide”, No. 1 2 and no. 3 is “excellent”. 4 is “OK”. 5 was “◯”.
For samples c-1, xx, cy and c-2 in which the degree of polymerization of polyvinyl alcohol B in Table 10 is 3000, no. 1 is “Hide”, No. 1 2 and no. 3 is “excellent”. 4 is “good”. 5 was “◯”.
For sample c-3 in which the degree of polymerization of polyvinyl alcohol B in Table 10 is 3,000, no. 1 is “Hide”, No. 1 2 and no. 3 is “excellent”. 4 is “OK”. 5 was “◯”.
For sample c-4 in which the degree of polymerization of the polyvinyl alcohol B in Table 10 is 3000, no. 1 is “Hide”, No. 1 2 and no. 3 is “excellent”. 4 is “impossible”. 5 was “◯”.
From Table 10, when the degree of polymerization of polyvinyl alcohol A is 1000, the weight ratio of the polyvinyl alcohol A is 10 parts by weight, and the degree of polymerization of polyvinyl alcohol B is 1700, polyvinyl acetate resin: polyvinyl alcohol B = 85 It can be seen that a coating solution that can withstand practical use can be provided in the range of 5:60 to 30:30, and a satisfactory coating solution can be provided in the range of polyvinyl acetate resin: polyvinyl alcohol B = 85: 5 to 70:20.
Further, from Table 10, when the polymerization degree of polyvinyl alcohol A is 1000, the weight ratio of the polyvinyl alcohol A is 10 parts by weight, and the polymerization degree of polyvinyl alcohol B is 3000, polyvinyl acetate resin: polyvinyl alcohol B = It can be seen that an application liquid that can withstand practical use can be provided in the range of 85: 5 to 65:25, and an excellent application liquid can be provided in the range of polyvinyl acetate resin: polyvinyl alcohol B = 85: 5 to 70:20. .

Next, each sample of polyvinyl alcohol A having a polymerization degree of 300 in Table 9 is shown again in Table 11, and the blending ratio of polyvinyl acetate resin at the same ratio as each of samples b-3 to b-7 in Table 9 The polyvinyl alcohol B having a polymerization degree of 1700 was fixed at a ratio of 20 parts by weight, and the ratio of the polyvinyl alcohol A was changed so as to be 80 parts by weight together with the polyvinyl acetate resin. Indicates.
Specifically, sample b in which polyvinyl alcohol B having a degree of polymerization of 1700 is 20 parts by weight is shown in parentheses in Table 11 and polyvinyl alcohol B is 20 parts by weight with respect to 60 parts by weight of polyvinyl acetate resin. -3a, sample b-4a with 40 parts by weight of polyvinyl alcohol A resin relative to 40 parts by weight of polyvinyl acetate resin, sample b-5a with 60 parts by weight of polyvinyl alcohol A relative to 20 parts by weight of polyvinyl acetate resin Sample b-6a containing 70 parts by weight of polyvinyl alcohol A with respect to 10 parts by weight of the polyvinyl acetate resin and No. of sample b-7a having 80 parts by weight of polyvinyl alcohol A with respect to 0 part by weight of the polyvinyl acetate resin . The test result of 1 is shown.
From Table 11, the following evaluation could be performed.
No. Sample b-3a and sample b-4a are “excellent” with respect to the adhesive strength of 1. Sample b-3 and sample b-4 in which polyvinyl alcohol A having a polymerization degree of 300 is changed only in the ratio and polyvinyl alcohol B is not added. It can be seen that it is superior to “good”. No. For the adhesive strength of 1, sample b-5 and sample b-6 in which polyvinyl alcohol A having a polymerization degree of 300 is changed only in the blending ratio and polyvinyl alcohol B is not added are “possible”, whereas sample b-5a and It turns out that sample b-6a is "good" and good. No. For the adhesive strength of 1, the ratio of the polyvinyl alcohol A having a polymerization degree of 300 is changed, and the sample b-7 without adding the polyvinyl alcohol B is “impossible”, whereas the sample b-7a is “possible” It can be seen that it can withstand practical use.

Table 12 shows a sample of the polymerization degree 300 of polyvinyl alcohol A in Table 9 again, and the blending ratio of the polyvinyl acetate resin is changed at the same ratio as each of samples b-3 to b-7 in Table 9. In addition, a sample is shown in which both the polyvinyl alcohols are changed with the blending ratio between the remaining components of polyvinyl alcohol A having a polymerization degree of 300 and polyvinyl alcohol B having a polymerization degree of 1700 being the same.
Specifically, in Table 12, sample b-3b in Table 11 is written together, and sample b-4b in which each of polyvinyl alcohol A and polyvinyl alcohol B is 30 parts by weight with respect to 40 parts by weight of the polyvinyl acetate resin. Sample b-5b in which polyvinyl alcohol A and polyvinyl alcohol B are 40 parts by weight with respect to 20 parts by weight of polyvinyl acetate resin, and polyvinyl alcohol A and polyvinyl alcohol B with respect to 10 parts by weight of polyvinyl acetate resin. Sample b-6b in which 50 parts by weight of each of polyvinyl alcohol A and polyvinyl alcohol B with respect to 0 part by weight of polyvinyl acetate resin is shown.
From Table 12, the following evaluation could be performed.
No. For the adhesive strength of 1, the sample b-4b is “excellent”, and the polyvinyl alcohol A having a polymerization degree of 300 is changed only in proportion, and is extremely superior to the “good” of the sample b-4 in which the polyvinyl alcohol B is not added. It turns out that it is a thing. No. For the adhesive strength of 1, the ratio of the polyvinyl alcohol A having a polymerization degree of 300 is changed only, and the samples b-5 and b-6 to which the polyvinyl alcohol B is not added are “OK”, whereas the samples b-5b and It can be seen that all of b-6b are “excellent” and excellent. No. For the adhesive strength of 1, the ratio of the polyvinyl alcohol A having a polymerization degree of 300 is changed only in the ratio, and the sample b-7 to which the polyvinyl alcohol B is not added is “impossible”, whereas the sample b-7b is “good” and good. You can see that

From the results shown in Tables 9 to 12, the above polyvinyl acetate resins can be used with a molecular weight (average molecular weight) of 300,000 to 400,000, both when used alone and when used in combination with the first polyvinyl alcohol. Moreover, it turns out that what makes the polymerization degree 300-1000 can be used as polyvinyl alcohol A used together. Moreover, when using polyvinyl alcohol B in addition to these resin, it turns out that the thing with a polymerization degree of 1700-3000 can be employ | adopted for polyvinyl alcohol B. Moreover, although the surface property and workability | operativity are not evaluated about the polyvinyl alcohol A of 200 degree of polymerization, it is thought that the polyvinyl alcohol A can be used in the range of 200-1000 degree of polymerization from the numerical tendency of each sample.
From the numerical trend of each sample as well as the range of molecular weight of the polyvinyl acetate resin and the degree of polymerization of each polyvinyl alcohol that can be directly grasped from each sample, if the resin can be procured, the polyvinyl acetate type The resin can be used by extending the molecular weight (average molecular weight) to a range of 100,000 to 700,000, and the polyvinyl alcohol A can be used by extending the upper limit of the polymerization degree to 1200, and the polyvinyl alcohol B can be used for the polymerization degree. It can be considered that the lower limit can be extended to a range larger than 1200.

Table 13 and Table 14 show the solid content concentrations of the resins of the samples in Table 5, Table 6, Table 9, and Table 10, respectively.
Tables 15 and 16 show the resin solid contents of the samples in Tables 11 and 12.
Regarding the molecular weight of the polyvinyl acetate resin and the degree of polymerization of polyvinyl alcohol A and polyvinyl alcohol, each sample in Table 13 is the same as that shown in Table 5, and each sample in Table 14 is the same as that shown in Table 6. .
That is, in each sample of Table 13 and Table 14, the polyvinyl acetate resin has a molecular weight (average molecular weight) of 300,000 to 400,000, and a polymerization degree of polyvinyl alcohol A is 1,000. In each sample of Table 14, polyvinyl alcohol B has a polymerization degree of 1700.
Moreover, in each sample of Table 15 and Table 16, the polyvinyl acetate resin has a molecular weight (average molecular weight) of 300,000 to 400,000, a polymerization degree of polyvinyl alcohol A is 300, and a polymerization degree of polyvinyl alcohol B is 1700. To do.

The ratio of the solid content concentration between the blended resins for each sample shown in Table 13 to Table 16 is the ratio between the constituent resins of the paper tube formed by applying each sample as a coating liquid and the finished product of the packaging material. . The paper tube and the packing material are completed after the application liquid is applied and dried, that is, the water is volatilized. The solid content concentration ratios in Table 13 to Table 16 correspond to the solid content ratio between the resins in the finished paper tube or packaging material.
For example, when a coating liquid equivalent to the sample cy in Table 14 is applied during the manufacturing process of the paper tube, the component ratio of the resin provided in the paper tube completed as a product is calculated from the solid content concentration shown in Table 14, Vinyl acetate resin (average molecular weight 300,000 to 400,000): polyvinyl alcohol A (polymerization degree 1000): polyvinyl alcohol B (polymerization degree 1700) = 35.25: 0.60: 2.55. With respect to the weight ratio of the solid content of this sample cy, the concentration of 47% at a concentration of 47% for polyvinyl acetate resin is 47% × 0.75 = 35.25%, and the concentration of polyvinyl alcohol A is also 6% × 0. .1 = 0.60%, polyvinyl alcohol B is similarly calculated at a concentration of 17% × 0.15 = 2.55%.

Regarding the finished paper tube (unused product) using the same coating liquid as the samples in Table 13 to Table 16, the weight ratio of the resin in the unused state is summarized as shown in the following 1) to 4). is there.
1) Polyvinyl acetate resin of each sample of Table 13: Polyvinyl alcohol A
Sample a-1 = 100 (47% ÷ 0.47): 0: 0
Sample b-1 = 42.30: 0.60
Sample b-2 = 37.60: 1.20
Sample b-3 = 28.20: 2.40
Sample b-4 = 18.80: 3.60
Sample b-5 = 9.40: 4.80
Sample b-6 = 4.70: 5.40
Sample b-7 = 0: 100 (6% ÷ 0.06)
It is.
2) Polyvinyl acetate resin: polyvinyl alcohol A: polyvinyl alcohol B of each sample in Table 14
Sample b-1 = 42.30: 0.60: 0
Sample c-1 = 39.95: 0.60: 0.85
Sample c−x = 37.60: 0.60: 1.70
Sample cy = 35.25: 0.60: 2.55
Sample c-2 = 32.90: 0.60: 3.40
Sample c-3 = 30.55: 0.60: 4.25
Sample c-4 = 28: 20: 0.60: 5.10
It is.
3) Polyvinyl acetate resin of each sample in Table 15: Polyvinyl alcohol A: Polyvinyl alcohol B
Sample b-3a = 28.20: 1.20: 3.40
Sample b-4a = 18.80: 2.40: 3.40
Sample b-5a = 9.40: 3.60: 3.40
Sample b-6a = 4.70: 4.20: 3.40
Sample b-7a = 0: 4.80: 3.40
It is.
4) Polyvinyl acetate resin: polyvinyl alcohol A: polyvinyl alcohol B of each sample in Table 16
Sample b-4b = 18.80: 1.80: 5.10
Sample b-5b = 9.40: 2.40: 6.80
Sample b-6b = 4.70: 2.70: 7.65
Sample b-7b = 0: 3.00: 8.50
It is.

(Example of change)
In the example shown in FIG. 1A above, the adherend surface 2 is formed on the entire outer peripheral surface (side surface of the cylinder) of the core 1. In addition, as shown in FIG. 1B, the adherend surface 2 can also be implemented as a streak region extending in the axial direction of the core 1, that is, in the thrust direction of the core 1, on the outer peripheral surface. As shown in FIG. 1B, the adherend surface 2 may be formed linearly over the entire axial width of the core 1 on the outer peripheral surface of the core 1. That is, the adherend surface 2 can be implemented by fixing only the vicinity of the edge of the sheet material to the core 1 in the form shown in FIG.
In FIG. 1 (B), the adherend surface 2 is a single streak, but as shown in FIG. 1 (C), the adherend surface 2 can also be implemented as two streaks, and more than three streaks. Can also be implemented. As shown in FIG. 1C, each of the adherend surfaces 2 extends in parallel with each other along the axial direction with a gap therebetween.
In addition to a straight line, that is, a continuous line as shown in FIGS. 1B and 1C, the adherend surface 2 can also be implemented as an intermittently provided broken-line area or dotted.

Although the paper tube of the embodiment described above is a round paper tube, that is, a round tube, the paper tube may be a square paper tube.
Further, in the embodiment shown in FIGS. 1A to 1C, the adherend 1 is the core 1, but the adherend 1 is not limited to the core. For example, the adherend 1 can be implemented as a packaging material (hereinafter referred to as a packaging material 1 as necessary). As the packaging material 1, the present invention can be carried out with respect to an edge member (edge board). The adherend surface 2 is formed on the surface of the edge contact member facing the package. When a plurality of packages 1 are packed together, fastening with a band is performed, but in the present invention, before fastening with a band, moisture is attached to the adherend surface 2 of the edge contact member by spraying or the like. The package can be bundled and fixed by exerting adhesive force. That is, conventionally, the packaging that is fastened with the band using the edge contact member requires a plurality of workers. Specifically, some workers hold the rim members against a group of packages that are bundled together, while other workers hang on the package with bands or strings held by them. It was necessary to conclude. However, in the packing material according to the present invention, as described above, moisture is attached to the edge contact member and applied to the package, so that even if the operator does not hold the package, the package does not collapse, and one worker Thus, the fastening of the band and the string can be completed.

A specific example using the adherend 1 as a packaging material is shown in FIGS. In each example of FIG. 2, the packaging material 1 is a packaging material such as the above-mentioned edge board or cushioning material that protects the corners and edges of the cargo.
The example shown to FIG. 2 (A) makes the load (packaged goods k) to pack into a some box. As shown in FIG. 2 (A), in this example, the adherend 1 is a plate material having a substantially L-shaped cross section disposed at the corners (sides) of a plurality of stacked packages. The surface on the (valley side) is the adherend surface 2. The adherend 1 that is a packing material can be fixed to the package k by applying the adherend surface 2 coated with the coating agent to the corners (sides) of the stacked package k. For this reason, even if the operator does not hold down the packing material (the adherend 1) or the stacked package k, the fastening band m such as a band can be fastened without causing collapse of the load.

The example shown in FIG. 2 (A) illustrates a case in which a plurality of packing materials k that are substantially rectangular parallelepiped are stacked and the whole is collected as a rectangular parallelepiped aggregate, and a packing material is provided on each side of the rectangular parallelepiped that the aggregate exhibits. The above-mentioned adherend 1 was arranged and fixed. On the other hand, in the example shown to FIG. 2 (B), the packaged goods k are made into three lumps of the upper stage k1, the middle stage k2, and the lower stage k3 from the top. By interposing a spacer (not shown) between the chunks forming the upper stage k1, the middle stage k2, and the lower stage k3, an interval is provided between the chunks. In the example shown in FIG. 2B, each lump is an aggregate of a plurality of thin plates or a plurality of sheet-like members, and the cross section is substantially L-shaped for each lump so that the lump is not separated. The packaging material is fixed as the adherend 1. Also in this case, the fastening material m such as a band can be hung after fixing the thin plates constituting the lump in a bundled state by the packing material.

In addition, as shown in FIG. 2 (C), the package k is a plurality of bags filled with contents, and the adherend 1 is fixed to the corner of the assembly formed by stacking the bags. As shown in FIG. 2 (D), the adherend 1 can be fixed to the upper sides of a plurality of drum-shaped loads placed on the pallet g and the fastening band m can be hung. .
Furthermore, as shown in FIG. 2 (E), the above-mentioned adherend 1 formed in an annular shape as a cushioning material or a protective material can be fixed to the edges of both bottom surfaces of the member wound in a roll shape exhibiting a cylinder. .
Further, as shown in FIG. 2 (F), the adherend 1 can be fixed as a reinforcing material, a cushioning material or a protective member at a corner portion inside a packing box n such as a cardboard box.

In the case shown in FIGS. 1A to 1C in which the adherend 1 is the above-described core, or in each example of FIG. 2, for example, the coating agent t is accommodated and provided in the container 3 shown in FIG. It is assumed that the customer can apply the coating agent t to the winding core or packing material at the site and use it as the adherend 1. In addition, as in the case of the above-described core provided as the adherend 1, in each example of FIG. 2, the packaging material as the adherend 1 from the beginning and the above-described coating agent applied are provided to the consumer. Can be implemented. In FIG. 4, reference numeral 5 denotes a lid of the container 3, and 4 denotes a lead-out part made of felt, cloth, or a mesh-like member provided at the mouth of the container 3 and capable of sucking and applying the coating agent t in the container 3. Indicates. The application agent t in the container 3 can be applied by pressing the lead-out part 4 against the member to be the adherend 1. However, application of the coating agent t by a known applicator other than the container 3 shown in FIG. 4 such as spraying is not limited.

Further, as described above, it is possible to apply (coat) the adhesive to any portion by filling the container 3 with the adhesive as the application agent t and applying (coating) an appropriate amount at the time of use. Further, by coloring the coating agent t, it is possible to easily determine where it is applied (coated) after application.

(Summary)
In the present invention, in an unused state where no moisture is applied, the wound core does not adhere to other wound cores or foreign matter such as dust. Winding can be started immediately by applying moisture to the adherend surface provided on the core surface and sticking the sheet material, and the sheet material can be securely bonded to the core after winding, as a sheet material When using a plastic film, it was possible to provide a sheet material that can be removed cleanly from the core.
The use of the adherend 1 of the present invention is not limited to the above-described core and packing material, but is particularly suitable for use as the above-described adhesive core and packing material.
That is, the adherend 1 according to the present invention is
a. It is provided in a state where it is applied in advance to the core and the packing material (packing material such as an edge board), and is suitable for use as an adhesive that is improved by applying water at the time of use.
b. By selling even a single resin, it is suitable for use by customers as it can be wound up by applying a required amount of resin at a required place or can be temporarily fixed by adhesion.
That is, in the winding core, once the sheet material that is an adhesive member is attached to the winding core that is the adherend 1 due to the adhesion of moisture and then dried, the sheet material is securely fixed. When peeling off, the sheet material peels cleanly. In this way, the film product and the paper tube are peeled off beautifully and the surface of the paper tube is not torn, so the influence of paper dust and the like is reduced, and the use in the clean room is easier to use than the conventional product.

DESCRIPTION OF SYMBOLS 1 Adhering body 2 Adhering surface 3 Container 4 Deriving part 5 Lid h 鋏 r (for fastening used in the test) Band t Coating agent

Claims (18)

A winding core comprising an adherend surface that holds an edge of a sheet material by applying moisture to the surface, and the sheet material is a plastic film, paper, metal foil, cloth, or nonwoven fabric,
The adherend surface comprises a water-soluble polymer;
The water-soluble polymer includes at least one of polyvinyl acetate derivatives and polyvinyl alcohol derivatives,
When the sheet material is a polyethylene film having a thickness of 50 μm, in an environment of at least 23 degrees Celsius and 50% humidity,
Even if the sheet material is stuck in a state where moisture is not applied, the adherend surface does not exhibit adhesive strength and adhesive strength, and the tensile strength after 24 hours has passed since the moisture is applied and the sheet material is stuck. A paper tube in which the adherend surface exhibits an adhesive force of 20 N / 60 mm or more. When the sheet material is a polyethylene film having a thickness of 50 μm, in an environment of at least 50 ° C. and 98% humidity
Even if the sheet material is adhered in a state where moisture is not applied, the adherend surface does not exhibit adhesive force and adhesive strength, and the tensile strength after 24 hours has elapsed since the moisture was applied and the sheet material was adhered. The paper tube according to claim 1, wherein the adherend surface exhibits an adhesive force of 20 N / 60 mm or more. When the sheet material is a polyethylene film having a thickness of 50 μm, 24 hours have passed after applying moisture and pasting the sheet material in an environment of at least 23 degrees Celsius to 50 degrees Celsius and a humidity of 50% to 98%. The paper tube according to claim 1, wherein the adherend surface exhibits an adhesive force with a tensile strength of less than 120 N / 60 mm. As the water-soluble polymer, comprising a polyvinyl acetate resin and polyvinyl alcohol,
The polyvinyl acetate resin has a higher adhesive force than the polyvinyl alcohol,
The polyvinyl alcohol is less adhesive than the polyvinyl acetate resin, and the adhesive strength of the developed polyvinyl alcohol is smaller than that of the polyvinyl acetate resin. The paper tube according to any one of claims 1 to 3, wherein The polyvinyl acetate resin has a viscosity of 1 to 40,000 mPa · s,
The paper tube according to claim 4, wherein the polyvinyl alcohol has a viscosity of 1 to 3000 mPa · s. Using the polyvinyl alcohol as the first polyvinyl alcohol, a second polyvinyl alcohol having a lower adhesiveness than that of the polyvinyl acetate-based resin and having a higher adhesive strength than the first polyvinyl alcohol. The water-soluble polymer comprises,
The paper tube according to claim 4 or 5, wherein the adhesive strength of the polyvinyl acetate resin is higher than that of the second polyvinyl alcohol. The paper tube according to claim 6, wherein the second polyvinyl alcohol has a viscosity of 3000 to 40000 mPa · s. At least a part of the paper tube surface includes a coating layer coated with the water-soluble polymer,
The paper tube according to claim 1, wherein the adherend surface is a surface of the coating layer. A first resin having a lower adhesiveness than the polyvinyl acetate resin and having a lower adhesive strength than the polyvinyl acetate resin;
A second resin having a lower adhesiveness than that of the polyvinyl acetate-based resin, and a higher adhesive strength than the first resin,
The polyvinyl acetate-based resin having an adhesive force higher than that of the first and second resins;
A paper tube with a surface. A packaging material provided with a water-soluble polymer on its surface,
The water-soluble polymer includes at least one of polyvinyl acetate derivatives and polyvinyl alcohol derivatives,
In an environment of at least 23 degrees Celsius and 50% humidity,
When a polyethylene film is applied in a state where moisture has not been applied, the adherend surface does not exhibit adhesive strength and adhesive strength, and when a polyethylene film having a thickness of 50 μm is applied after applying moisture, the tensile strength after 24 hours has elapsed. Is a packaging material in which the adherend surface exhibits an adhesive force of 20 N / 60 mm or more. Using the core and the packing material as the adherend, and applying the sheet material, the package, or the packing box containing the package as the patch, the adherend surface for fixing the patch is applied to the adherend. A coating agent to be formed on the adherend,
Mainly water-soluble polymer,
The water-soluble polymer includes at least one of polyvinyl acetate derivatives and polyvinyl alcohol derivatives,
When the patch is a polyethylene film having a thickness of 50 μm, even if the patch is stuck in an uncoated state in an environment of at least 23 degrees Celsius and 50% humidity, Adhesive strength is applied to the adherend surface by applying moisture to the applied body and applying a sticking strength to the coated surface to give a tensile strength of 20 N / 60 mm or more after 24 hours. Coating agent. The polyvinyl acetate derivative has an average molecular weight of 100,000 to 700,000,
The paper tube according to any one of claims 1 to 8, wherein the polyvinyl alcohol derivative has a polymerization degree of 1200 or less. The polyvinyl acetate resin has an average molecular weight of 100,000 to 700,000,
The paper tube according to any one of claims 6 to 8, wherein the first polyvinyl alcohol has a polymerization degree of 1200 or less, and the second polyvinyl alcohol has a polymerization degree of more than 1200. The polyvinyl acetate-based resin has an average molecular weight of 100,000 to 700,000, and the first resin is polyvinyl alcohol having a polymerization degree of 1200 or less,
The paper tube according to claim 9, wherein the second resin is polyvinyl alcohol having a degree of polymerization exceeding 1200. The polyvinyl acetate derivative has an average molecular weight of 100,000 to 700,000,
The packaging material according to claim 10, wherein the polyvinyl alcohol derivative has a polymerization degree of 1200 or less. The polyvinyl acetate derivative has an average molecular weight of 100,000 to 700,000,
The coating agent according to claim 11, wherein the polyvinyl alcohol derivative has a polymerization degree of 1200 or less. The manufacturing method of the coating agent of Claim 11 or 16. A method for producing a paper tube, wherein the coating agent according to claim 11 or 16 is applied to at least a part of the surface of the paper tube.

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