JP2018024099A - Transfer sheet - Google Patents

Abstract

PROBLEM TO BE SOLVED: To provide a transfer sheet excellent in image deterioration resistance, striking-through suppressibility, and transferability, and used in a transfer printing method using a sublimation type printing ink.SOLUTION: There is provided a transfer sheet used in a transfer printing method using a sublimation type printing ink. The transfer sheet has a base paper, and coating layers having one or more layers at least on one side of the base paper. In the transfer sheet, Gurley air permeability determined based on JIS P8117:2009 is 100 seconds or more and 200 seconds or less.SELECTED DRAWING: None

Description

  The present invention relates to a transfer paper used for transferring a pattern in a transfer printing method for forming a pattern on a substrate such as a fiber material.

  As a method of forming a pattern on a printed material such as a textile material, a pattern is printed on a transfer paper using sublimation printing ink to produce a transfer paper, the transfer paper is brought into close contact with the printed material, and the sublimation printing ink is used. A transfer textile printing method for transferring to a substrate is known (see, for example, Patent Document 1 and Patent Document 2).

Transfer paper used for transfer textile printing is known.
For example, a sheet-like substrate can be used as a sublimation transfer sheet that is excellent in water-based ink absorptivity and capable of obtaining a clear recorded image without bleeding and excellent in ink transfer efficiency to a transfer object during sublimation transfer. Material and an ink receiving layer provided on one side or both sides of the sheet-like base material, and the ink receiving layer contains a pigment, a binder, and a cationic resin. Examples of the binder include starch, starch derivatives, A sublimation transfer sheet is known in which any one of polyvinyl alcohol and modified polyvinyl alcohol or a mixture of two or more thereof is used (see, for example, Patent Document 3).
In addition, it has excellent ink absorption and drying properties in ink jet printing using sublimation textile printing ink, and has good workability, image reproducibility on the surface of transfer paper, heat resistance during heat transfer, after transfer As a sublimation type ink jet printing transfer paper having good properties in terms of image reproducibility and transfer efficiency on the surface of the transferred material, the sublimation type printing ink receiving layer has a sublimation type printing ink receiving layer on a substrate. Contains a water-soluble resin and fine particles, contains the synthetic amorphous silica as the fine particles, and in the relative value of the ultrasonic transmission intensity on the sublimation type printing ink receiving layer side of the sublimation type ink jet printing transfer paper. A sublimation type ink jet printing transfer paper having a minimum value peak within a measurement time of 3 seconds is known (see, for example, Patent Document 4).

  As described in Patent Document 3 and Patent Document 4, an inkjet printing method is used as a method for producing a transfer paper by printing a pattern on a transfer paper using an ink containing a sublimation dye or a sublimation printing ink. Often used.

JP2015-168705A Japanese Patent Laying-Open No. 2015-124324 JP 2010-158875 A JP 2010-058335 A

It is necessary to have two contradictory characteristics between a transfer sheet, which is a white paper before the pattern is printed, and a transfer sheet obtained by printing the pattern on the transfer sheet. That is, the transfer paper is required to have an ability to successfully receive the sublimation type printing ink, and the transfer paper is required to have an ability to transfer the sublimation type printing ink onto the substrate.
Since the transfer paper becomes a transfer paper having a sharp image so as not to deteriorate the image quality of the pattern formed on the substrate, it is necessary to improve the acceptability for the sublimation type printing ink. Furthermore, the transfer paper must not deteriorate the image quality of the pattern formed on the substrate from the transfer paper having a sharp image.

  Further, in order to transfer the sublimation printing ink from the transfer paper to the printing material satisfactorily, the transfer paper needs to be received without penetrating the sublimation printing ink to the depth of the paper. That is, the transfer paper is required to suppress the back-through. “Back-through” is a phenomenon in which sublimation printing ink of an image printed on a transfer paper penetrates to the deep part of the paper.

  In addition, there is a problem of transferability when sublimation type printing ink is transferred from a transfer paper to a substrate. The transfer is performed by bringing the transfer paper and the material to be printed into close contact, and heating and pressurizing as necessary. When forming an image on a substrate as a business, it is desirable to saturate the transfer of the sublimation printing ink in a shorter time, lower heating and lower pressure. Such efficiency regarding transfer is referred to as transferability in the present invention. In particular, time is important as a business.

  The quality of the sublimation transfer sheet of Patent Document 3 and the sublimation type ink jet printing transfer paper of Patent Document 4 is not always sufficient, and in particular, improvement in the suppression of back-through is desired.

In view of the above, an object of the present invention is to provide a transfer paper that satisfies the following items.
(1) There is no image degradation on the substrate and the image degradation resistance is good.
(2) The back-through of the transfer paper is suppressed, and the back-through suppression is excellent.
(3) Transferability is good.

As a result of intensive studies to solve the above problems, the inventors of the present invention can achieve the objects of the present invention as follows.
[1] A transfer paper used in a transfer textile printing method using a sublimation type printing ink, which has a base paper and at least one coating layer on at least one side of the base paper. In the transfer paper, JIS P8117 : Transfer paper having a Gurley air permeability required in conformity with 2009 of 100 seconds to 200 seconds.

  [2] The transfer paper according to [1], wherein the outermost coating layer located on the outermost side with respect to the base paper in the coating layer contains at least kaolin, calcium carbonate, and a water-soluble calcium salt.

  [3] The transfer paper according to [2], wherein the water-soluble calcium salt is at least one selected from the group consisting of calcium chloride and calcium nitrate.

  According to the present invention, it is possible to provide a transfer paper having good image deterioration resistance, excellent anti-through-through prevention property, and good transferability.

The present invention is described in detail below.
In the present invention, the “transfer sheet” refers to a sheet in a blank state before a pattern to be transferred is printed. “Transfer paper” refers to paper on which a pattern to be transferred to the transfer paper is printed.

The transfer paper has a base paper and one or more coating layers on at least one side of the base paper. The coating layer located on the outermost side with respect to the base paper in the coating layer is referred to as the outermost coating layer. When the number of coating layers is one, this coating layer becomes the outermost coating layer. When there are two or more coating layers, the coating layer existing between the base paper and the outermost coating layer is either a coating layer containing a pigment and a binder or a coating layer containing no pigment. There is no particular limitation.
From the viewpoint of production cost, one coating layer is preferable. The coating layer may be provided on one side or both sides of the base paper. When the outermost coating layer according to the present invention is provided on one side of the base paper, the transfer paper may have a conventionally known back coat layer on the back side of the base paper.

The coating amount of the coating layer is not particularly limited. Terms easily brought into close contact against manufacturing cost and the substrate of the transfer sheet, the coating weight is preferably 2 g / m ² or more 70 g / m ² or less per side dry solid content. In the range of the coating amount, the upper limit of the coating amount is more preferably 30 g / m ² or less, and further preferably 10 g / m ² or less. Furthermore, the upper limit of the coating amount is most preferably 8 g / m ² or less because it is easy to prevent the outermost coating layer from being lost when the transfer paper and the substrate are in close contact with each other. When there are a plurality of coating layers on one side, the coating amount is a total value thereof.

  Base paper is chemical pulp such as LBKP (Leaf Bleached Kraft Pulp), NBKP (Needle Bleached Kraft Pulp), GP (Groundwood Pulp), PGW (Pressure Ground Wood pulp), RMP (Refiner Mechanical Pulp), TMP (ThermoMechanical Pulp), CTMP (ChemiThermoMechanical Pulp), CMP (ChemiMechanical Pulp), CGP (ChemiGroundwood Pulp) and other mechanical pulp, and DIP (DeInked Pulp) and other waste paper pulp, at least one pulp selected from calcium carbonate, talc, clay, kaolin, etc. In addition, various types of fillers, and further, papers made from papers containing various additives such as sizing agents, fixing agents, retention agents, cationizing agents, and paper strength agents as necessary. Further, the base paper includes high-quality paper obtained by subjecting papermaking paper to calendar treatment, surface sizing treatment with starch or polyvinyl alcohol, or the like. Furthermore, the base paper includes high-quality paper that has been subjected to surface sizing or surface treatment and then calendered.

  Paper making is performed using a conventionally known paper machine by adjusting the stock to acid, neutral or alkaline. Examples of the paper machine include a long net paper machine, a twin wire paper machine, a combination paper machine, a circular net paper machine, and a Yankee paper machine.

  In paper stock, other additives include pigment dispersants, thickeners, fluidity improvers, antifoaming agents, antifoaming agents, mold release agents, foaming agents, penetrating agents, colored dyes, colored pigments, fluorescent enhancers. One or more of whitening agents, ultraviolet absorbers, antioxidants, antiseptics, antibacterial agents, water resistance agents, wet paper strength enhancers, dry paper strength enhancers, etc. can be used to achieve the desired effects of the present invention. It can mix | blend suitably in the range which is not impaired.

The basis weight of the base paper is not particularly limited. The basis weight of the base paper is preferably 10 g / m ² or more and 100 g / m ² or less, and more preferably 40 g / m ² or more and 90 g / m ² or less, from the viewpoint of easy handling when the transfer paper and the substrate are in close contact. Further, the thickness of the transfer paper is not particularly limited. The thickness of the transfer paper is preferably 0.01 mm or more and 0.5 mm or less, and more preferably 0.05 mm or more and 0.3 mm or less from the viewpoint of ease of handling when the transfer paper and the substrate are in close contact.

The transfer paper has one or more coating layers on at least one side of the base paper.
The coating layer or the outermost coating layer can be provided on the base paper or the coating layer by coating and drying each coating layer coating solution. The method of providing is not particularly limited. Examples thereof include a method of coating and drying using a conventionally known coating apparatus and drying apparatus in the papermaking field. Examples of conventionally known coating devices include size presses, gate roll coaters, film transfer coaters, blade coaters, rod coaters, air knife coaters, comma coaters, gravure coaters, bar coaters, E bar coaters, curtain coaters, and the like. Can do. Examples of dryers include various dryers such as straight tunnel dryers, arch dryers, air loop dryers, sine curve air float dryers, hot air dryers, infrared heating dryers, dryers using microwaves, etc. Can do.

The transfer paper has a Gurley air permeability required in accordance with JIS P8117: 2009 of 100 seconds to 200 seconds.
When the Gurley air permeability is less than 100 seconds, it is not possible to obtain the back-through suppression and transferability. When the Gurley air permeability exceeds 200 seconds, it is particularly difficult to obtain image degradation resistance.

  The Gurley air permeability is determined by the time required for a certain volume of air to pass through the sheet. Prepare an inner cylinder plugged with a piece of paper, and place the inner cylinder in an outer cylinder filled with oil or other liquid. At this time, the air in the inner cylinder passes through the sheet piece while being compressed by the weight of the inner cylinder. At this time, the inner cylinder gradually descends in the outer cylinder. Gurley permeability measures the time (seconds) required for a certain volume of air to pass through. The value of Gurley air permeability, that is, time (seconds) is longer when the air permeability of the paper is small, and shorter when the air permeability of the paper is large. In the present invention, the Gurley air permeability is a value determined using, for example, a B-type Gurley densometer manufactured by Toyo Seiki Seisakusho.

  The Gurley air permeability is a conventionally known physical quantity in the papermaking field, and can be adjusted by a conventionally known method in the papermaking field. For example, the type of pulp used for the base paper, the freeness condition by beating, the type and amount of the filler for the base paper, the presence or absence of the calendering of the base paper and the processing conditions, the amount of surface sizing agent such as starch and polyvinyl alcohol applied to the base paper Depending on the presence / absence of calendering treatment after the coating layer is provided and the processing conditions thereof, the type and amount of the pigment in the coating layer, the type and amount of the binder, the coating amount, and the like can be appropriately adjusted. For example, increasing the amount of filler on the base paper, calendaring on the base paper, increasing the amount of surface sizing agent applied, increasing the coating amount or having the calendering after coating increases the value of Gurley air permeability, that is, time (seconds). Show the trend.

  The outermost coating layer of the transfer paper preferably contains at least kaolin, calcium carbonate, and a water-soluble calcium salt as pigments. This is because the image deterioration resistance, the back-through suppression property or the transfer property is improved.

  The content ratio of kaolin and calcium carbonate in the outermost coating layer is preferably kaolin: calcium carbonate = 9: 1 to 5: 5. When the inkjet printing method is used in the method of printing a pattern on the transfer paper, the calcium carbonate is preferably heavy calcium carbonate from the viewpoint of printability for the inkjet printing method.

The outermost coating layer can contain a conventionally known pigment in addition to kaolin and calcium carbonate. Examples of conventionally known pigments include inorganic pigments such as talc, satin white, lithopone, titanium oxide, zinc oxide, silica, alumina, aluminum hydroxide, zinc oxide, activated clay, diatomaceous earth, and organic pigments such as plastic pigments. Can be mentioned. The outermost coating layer can be used in combination with kaolin and calcium carbonate in combination of one or more of these pigments.
The proportion of kaolin and calcium carbonate in the pigment of the outermost coating layer is preferably 80% by mass or more.

  The water-soluble calcium salt is a calcium salt that can be finally dissolved in 1% by mass or more in 20 ° C. water. Examples of the water-soluble calcium salt include salt compounds such as calcium nitrate, calcium chloride, calcium formate, calcium acetate, and calcium lactate, and complex salt compounds such as ethylenediaminetetraacetic acid calcium. One or more water-soluble calcium salts are selected from the group consisting of these. Among these, the water-soluble calcium salt is preferably at least one selected from the group consisting of calcium chloride and calcium nitrate.

  The content of the water-soluble calcium salt in the outermost coating layer is preferably 2 parts by mass or more and 30 parts by mass or less with respect to 100 parts by mass of the pigment in the outermost coating layer. The lower limit of the content is more preferably 5 parts by mass or more, and still more preferably 10 parts by mass or more. The upper limit of the content is more preferably 25 parts by mass or less, and further preferably 20 parts by mass or less.

The outermost coating layer preferably contains a conventionally known binder in the coated paper field.
Examples of conventionally known binders include starch and various modified starches thereof, cellulose derivatives such as carboxymethylcellulose and hydroxyethylcellulose, natural polymer resins such as casein, gelatin, soy protein, pullulan, gum arabic, karaya gum and albumin or derivatives thereof. , Polyvinylpyrrolidone, polyvinyl alcohol and various modified polyvinyl alcohols thereof, polyacrylamide, polyethyleneimine, polypropylene glycol, polyethylene glycol, maleic anhydride resin, acrylic resin, methacrylate ester-butadiene copolymer, styrene-butadiene copolymer, Functional group-modified copolymers with ethylene-vinyl acetate copolymers or monomers containing functional groups such as carboxy groups of these various copolymers, melamine resins, urea trees The binder of the thermosetting synthetic resin etc., polyurethane resins, unsaturated polyester resins, polyvinyl butyral, can be exemplified alkyd resin latex. The outermost coating layer can contain one or more selected from the group consisting of these binders.
From the viewpoint of image deterioration resistance, the binder is preferably at least one selected from the group consisting of starch and its various modified starches, and polyvinyl alcohol and its various modified polyvinyl alcohols.

  5 mass parts or more and 60 mass parts or less are preferable with respect to 100 mass parts of pigments in the outermost coating layer, and, as for content of the binder in an outermost coating layer, 20 mass parts or more and 40 mass parts or less are more preferable.

The outermost coating layer can contain various conventionally known additives in the coated paper field as necessary. Examples of additives include dispersants, fixing agents, thickeners, fluidity improvers, antifoaming agents, mold release agents, foaming agents, penetrating agents, coloring pigments, colored dyes, fluorescent whitening agents, UV absorbers , Antioxidants, preservatives, antifungal agents and the like.
Further, the outermost coating layer can contain various conventionally known auxiliaries by a transfer printing method. The auxiliary agent is added to optimize various physical properties of the outermost coating layer coating solution or to improve the dyeing property of the transferred sublimation printing ink. Examples of the auxiliary agent include various surfactants, humectants, wetting agents, pH adjusting agents, alkali agents, thickening agents, deaerating agents and reduction inhibitors.

The transfer paper can be obtained by printing a pattern on the side of the transfer paper having the outermost coating layer using various conventionally known printing methods including sublimation type printing ink.
Various printing methods for printing the design on the transfer paper are conventionally known printing methods and are not particularly limited. Examples of the printing method include a gravure printing method, an ink jet printing method, an electrophotographic printing method, a screen printing method, and the like. Among these, the ink jet printing method is preferable in terms of high image quality and downsizing of the apparatus.

  The transfer textile printing method using sublimation textile printing ink is a method having a step of printing a pattern on a transfer paper to obtain a transfer paper and a step of bringing the transfer paper into close contact with a substrate. The process of making it adhere | attach includes heating and pressurization as needed. The conditions for heating and pressurizing in the step of adhering are conventionally known conditions in the transfer printing method. Examples of the step of bringing in close contact include a method in which the transfer paper is brought into close contact with the substrate to be printed with a press or a heating drum and heated and pressurized.

  The substrate is a fiber material and is not particularly limited. The fiber material may be either a natural fiber material or a synthetic fiber material. Examples of natural fiber materials include cellulosic fiber materials such as cotton, hemp, lyocell, rayon and acetate, and protein fiber materials such as silk, wool and animal hair. Examples of the synthetic fiber material include polyamide fiber (nylon), vinylon, polyester, and polyacryl. Examples of the configuration of the fiber material include woven fabrics, knitted fabrics, nonwoven fabrics, and the like alone, mixed spinning, mixed fiber, and union. Furthermore, these configurations may be combined. Moreover, you may pre-process a to-be-printed material with the chemical | medical agent effective in dyeing | staining promotion as needed.

  Hereinafter, the present invention will be described in more detail with reference to examples. The present invention is not limited to these examples. Here, “parts by mass” and “% by mass” represent “parts by mass” and “% by mass” of the amount of dry solids or the amount of substantial components, respectively. The coating amount of the coating layer represents the dry solid content.

<Base paper>
A pulp slurry consisting of 100 parts by weight of LBKP is added with a filler, 1.2 parts by weight of amphoteric starch, 0.8 parts by weight of a sulfuric acid band, and 0.1 parts by weight of an alkyl ketene dimer type sizing agent, and the paper is made with a long paper machine. A surface sizing agent was adhered to both sides with a size press device, and machine calendar processing was performed to prepare a base paper.
Change the drainage of the pulp as appropriate so that the Gurley permeability obtained in accordance with JIS P8117: 2009 of the transfer paper to be obtained is a predetermined value, and use calcium carbonate as the filler and change the blending amount accordingly In addition, as the surface sizing agent, various starches and various modified starches were used to appropriately change the adhesion amount. In addition, the calendar conditions were appropriately changed so that the Gurley air permeability required in accordance with JIS P8117: 2009 of the obtained transfer paper was a predetermined value.

<Outermost coating layer coating solution>
The outermost coating layer coating solution was prepared according to the following contents.
Kaolin parts are listed in Table 1. Heavy calcium carbonate parts are listed in Table 1. silica parts are listed in Table 1. Phosphate esterified starch 15 parts by weight Polyvinyl alcohol 10 parts by weight Water-soluble salt Types and parts are listed in Table 1 And mixed and dispersed with water to adjust the concentration to 48% by mass.

<Transfer paper>
A transfer sheet was prepared by the following procedure.
On the base paper, the outermost coating layer coating solution shown in Table 1 is coated on both sides with an air knife coater and dried, and then the Gurley permeability required for the transfer paper obtained in accordance with JIS P8117: 2009 The transfer sheet of each example and each comparative example was obtained by calendaring so that the degree became a predetermined value. The coating amount was 6 g / m ² per side.

<Transfer paper>
By using an ink jet printer (JV2-130II, manufactured by MIMAKI ENGINEERING CO., LTD.) Using a sublimation printing ink on the transfer paper obtained as described above, an evaluation pattern using sublimation printing ink (cyan, magenta, yellow, black) is provided. Printing was performed to obtain a transfer paper.

<Evaluation of penetration-through inhibition>
The transfer paper obtained as described above was subjected to a sensory evaluation of the see-through suppression performance based on the following criteria from the degree of image viewing from the back surface of the transfer paper. In the present invention, if the transfer paper is evaluated as A or B, it is excellent in the see-through suppression.
A: There is almost no see-through, which is good.
B: Slightly see-through is observed, but generally good.
C: There is a see-through, but there is no practical problem.
D: See-through is recognized, which causes a practical problem.

<Printing>
A polyester cloth was used as the substrate. The obtained transfer paper and the polyester cloth were brought into close contact with each other, and the dye was transferred to the polyester cloth by heating at 200 ° C. for 60 seconds using a thermal transfer press (manual wide swinger Model 221 manufactured by INSTA). Thereafter, the transfer paper was peeled from the polyester cloth to obtain a polyester cloth on which a pattern was formed.
Separately, in order to evaluate transferability, transfer was performed while changing the heating time from 60 seconds to 75 seconds or 90 seconds.

<Evaluation of image degradation resistance>
From the point of sharpness of the pattern, the image quality of the printed material on which the pattern was formed was sensory evaluated according to the following criteria. In the present invention, if the transfer paper is evaluated as A or B, the image deterioration resistance is good.
A: Good level.
B: Almost no deterioration in image quality is observed, and the level is generally good.
C: Deterioration in image quality is recognized, but there is no practical problem.
D: Level at which deterioration of an image which is practically impossible is recognized.

<Evaluation of transferability>
In the printed material on which the pattern was formed by changing the heating time at the time of adhesion, the change in color developability in 60 seconds, 75 seconds and 90 seconds was subjected to sensory evaluation according to the following criteria. In the present invention, the transfer paper has good transferability if the evaluation is A or B.
A: There is no change.
B: There is almost no change.
C: Although a change is recognized between 60 seconds and 75 seconds,
There is almost no change between 75 seconds and 90 seconds.
D: between 60 and 75 seconds and between 75 and 90 seconds,
Change is observed.

  The evaluation results are shown in Table 1.

From the evaluation results of Table 1, it can be seen that Examples 1 to 14 corresponding to the present invention have excellent anti-through-through suppression properties and good image deterioration resistance and transferability. However, it is understood that Comparative Examples 1 to 4 that do not satisfy the configuration of the present invention cannot obtain these effects.
Mainly from the comparison between Examples 1 to 8 and Examples 9 to 11, it is understood that the outermost coating layer preferably contains kaolin, calcium carbonate and a water-soluble calcium salt.
Further, mainly from the comparison between Examples 1 to 5 and Example 6, it can be seen that the water-soluble calcium salt is preferably at least one selected from the group consisting of calcium chloride and calcium nitrate.

Claims (3)

  A transfer paper used in a transfer textile printing method using a sublimation type printing ink, comprising a base paper, and at least one coating layer on at least one side of the base paper. In the transfer paper, in accordance with JIS P8117: 2009 A transfer paper having a Gurley air permeability determined in conformity with 100 seconds to 200 seconds.   The transfer paper according to claim 1, wherein the outermost coating layer located on the outermost side with respect to the base paper in the coating layer contains at least kaolin, calcium carbonate, and a water-soluble calcium salt.   The transfer paper according to claim 2, wherein the water-soluble calcium salt is at least one selected from the group consisting of calcium chloride and calcium nitrate.