JP2017535254A - Rice seed treatment method - Google Patents

Abstract

The present invention relates to a method for preparing a coated rice seed, wherein the seed coating agent is applied at least partially to the surface of the dried rice seed, wherein the seed coating agent comprises at least an ethylene-vinyl acetate copolymer and at least one pesticide. A method of including is provided. The present invention further provides coated rice seeds and methods for protecting germinating seedlings of rice plants against fungal diseases and / or pests prior to planting.

Description

  The present invention relates to a method for preparing a coated rice seed, wherein the seed coating agent is applied at least partially to the surface of the dried rice seed, the coated rice seed, and the rice against fungal diseases and / or pests before planting. The present invention relates to a method for protecting budding seedlings of plants.

  Disease prevention treatments for transplanted rice and / or for controlling animal pests are known, and pesticides are sprayed or granules are applied to paddy fields or nursery boxes. However, this use of pesticides in paddy fields to prevent rice diseases after transplanting into paddy fields and / or to control animal pests requires large amounts of pesticides or pesticide effects do not last long Have the problem. Even if the amount of pesticides can be reduced by spraying or applying granule pesticides to nursery boxes compared to the amount in paddy fields, in some cases, the amount of pesticide used is still large and the sustainability of the effect is insufficient It is.

  Rice seeds can be dipped or incubated prior to sowing. In order to protect rice seeds, pesticides, in particular fungicides, can be added directly to the seeds after soaking or after germination before soaking or transplanting (Japanese Patent Application Publication No. 9224424, Japanese Patent Application Publication No. 11028006, Japanese Patent Application Publication No. 11049612). However, this strategy is not always satisfactory, because the pesticides used may not remain on the seed surface in sufficient concentrations and are washed away after incubation or after transplanting, respectively. And insufficient pest protection.

  For example, EP 1078563 B1 describes a seed coating composition for low temperature application in which seed is coated with a coating composition comprising a polymer and at least one active ingredient. These compositions can be used on rice seeds for direct sowing but are not suitable for rice seeds because of the coating wash-off if the rice seeds need to be first soaked and incubated before sowing.

Japanese Patent Application Publication No. 9224424 Japanese Patent Application Publication No. 11028006 Japanese Patent Application Publication No. 11049612 EP1078563B1

  Accordingly, the object of the present invention is to remedy these drawbacks, greatly reduce the amount of pesticide used compared to the pesticide used in conventional nursery box processing, and provide a simple, inexpensive, long residue in paddy fields. An object of the present invention is to provide a method for preventing diseases in transplanted rice having effects and / or controlling animal pests.

  By diligently researching to solve the above problem, the present inventors treated rice seeds with at least ethylene-vinyl acetate copolymer and at least one pesticide, so that they were soaked in water, and the pesticide was almost washed away. It has been found that it is possible to obtain coated rice seeds that can be incubated without. Surprisingly, the ethylene-vinyl acetate copolymer is sufficiently water permeable so that there is little or only little germination rate reduction compared to untreated rice seeds, because soaking and incubation are not hindered. Not found. At the same time, the ethylene-vinyl acetate copolymer does not dissolve in immersion water and can serve as a substrate or substrate for agrochemicals, for example.

  Accordingly, a first embodiment of the present invention is a method for preparing a coated rice seed, wherein the seed coating agent is applied at least partially to the surface of the dried rice seed, wherein the seed coating agent comprises at least ethylene-acetic acid. A method characterized in that it comprises a vinyl copolymer and at least one pesticide.

  In the present invention, the term “copolymer” is used for polymers comprising two or more different monomers. In particular, polymers comprising three or four different monomers are also considered “copolymers” according to the invention.

  The term “dried rice seed” means rice in a form suitable for storage for later use as seed. Rice seeds can have a residual water content typical of rice seeds, for example 20% by weight or less, in particular 15% by weight or less, preferably 14% by weight or less. Its water content can be determined by a typical moisture analyzer for cereals such as Pfeuffer HE50 or by titration by the Karl-Fischer method.

  The seed can be coated once or several times, but the composition of the coating layer may be the same or different. For example, the inner coating layer may comprise an ethylene-vinyl acetate copolymer and at least one fungicide, while the next outer layer is optionally a binder such as any suitable type of polymer binder or the present invention. In addition to the ethylene-vinyl acetate copolymer described in 1), at least one insecticide can be included.

According to a preferred embodiment of the invention, the copolymer comprises at least the following monomers:
a) vinyl acetate,
b) (Meth) acrylic acid monomer of the following general formula (I):

(Wherein R is a saturated or unsaturated organic group having at least 3 carbon atoms, R 'is hydrogen or a methyl group), and c) is produced by reacting ethylene.

  These monomers are preferably 35 to 50% by weight of vinyl acetate, in particular 38 to 48% by weight, preferably 40 to 45% by weight; (meth) acrylic acid monomers of the general formula (I) 25 to 55% by weight In particular 30 to 50% by weight, preferably 35 to 45% by weight, particularly preferably 35 to 40% by weight; ethylene 5 to 25% by weight, in particular 8 to 20% by weight, preferably 10 to 18% by weight; And acrylic acid can be present in an amount of 0 to 5% by weight, in particular 0.1 to 4.5% by weight, preferably 0.5 to 4.0% by weight.

  In another embodiment, these monomers are preferably 35 to 50% by weight vinyl acetate, in particular 38 to 48% by weight, preferably 40 to 45% by weight; (meth) acrylic acid of the general formula (I) 25 to 55% by weight of monomer, in particular 30 to 50% by weight, preferably 35 to 45% by weight, particularly preferably 35 to 40% by weight; ethylene 5 to 25% by weight, in particular 10 to 25% by weight, preferably May be present in an amount of from 15 to 23% by weight.

  In another preferred embodiment, in addition to the above components, acrylic acid is present in an amount of 0 to 5% by weight, in particular 0.1 to 4.5% by weight, preferably 0.5 to 4.0% by weight. Exists.

  Such copolymers are advantageous because they can effectively prevent pesticide wash-off from seeds during soaking and incubation while maintaining sufficient water permeability. Furthermore, when such copolymers are used as aqueous dispersions, most pesticides can be added and blended, resulting in a stable dispersion, which facilitates further processing, ie seed coating. Finally, the copolymer with the above amount of monomer provides tackiness at room temperature conditions, which is advantageous for fixing the coating to the seed.

A (meth) acrylic acid monomer is defined as an acrylic acid monomer of formula I (ie R ′ = H), a methacrylic acid monomer of formula I (ie R ′ = CH ₃ ) or a mixture of both.

  In a preferred embodiment, the copolymer does not contain acrylic acid.

  In a particularly preferred embodiment, the copolymer consists of vinyl acetate, a (meth) acrylic acid monomer of general formula (I) and ethylene.

  More preferably, the copolymer comprises 40 to 45 wt% vinyl acetate; 35 to 45 wt% ethylhexyl acrylate, and 15 to 23 wt% ethylene, the polymer comprising acrylic acid chemically bonded within the polymer Absent.

  Unless otherwise specified in the present application, the percentiles in general and especially for the monomers will total 100%.

  The copolymer used in the method of the present invention can be prepared by any method known to those skilled in the art. In particular, the copolymer can be produced by radical emulsion polymerization, by way of example only. Emulsions can be made using standard emulsion polymerization routes under pressure that are widely used in the production of copolymers that incorporate gaseous monomers such as ethylene. Emulsions can be manufactured using batch, semi-batch or continuous feed batches, all three of which are industrially used.

  The (meth) acrylic acid monomer of general formula (I) can comprise one or more alkyl (meth) acrylates, ie one or more (meth) acrylic acid alkyl ester monomers. Useful alkyl (meth) acrylates include linear or branched monofunctional unsaturated (meth) acrylate esters of tertiary or non-tertiary alkyl alcohols, the alkyl group of which is 4 to 15, In particular it has 5 to 10 carbon atoms, ie the substituent R in formula I has 4 to 15 carbon atoms, in particular 5 to 10, and R is preferably n-butyl, n- Pentyl, n-hexyl, cyclohexyl, isoheptyl, n-nonyl, n-decyl, isohexyl, isobornyl, 2-ethyloctyl, isooctyl, 2-ethylhexyl, tetrahydrofurfuryl, ethoxyethoxyethyl, phenoxyethyl, cyclic trimethylpropane formal, 3 , 3,5-trimethylcyclohexyl, t-butylcyclohexyl and / or t- It is selected from the chill. That is, examples of these alkyl acrylates include acrylic acid and n-butyl methacrylate, n-pentyl, n-hexyl, cyclohexyl, isoheptyl, n-nonyl, n-decyl, isohexyl, isobornyl, 2-ethyloctyl, isooctyl. 2-ethylhexyl, tetrahydrofurfuryl, ethoxyethoxyethyl, phenoxyethyl, cyclic trimethylpropane formal, 3,3,5-trimethylcyclohexyl, t-butylcyclohexyl, t-butyl and the like. Preferred alkyl acrylates include isooctyl acrylate, 2-ethylhexyl acrylate, n-butyl acrylate, tetrahydrofurfuryl acrylate, isobornyl acrylate, ethoxyethoxyethyl acrylate, phenoxyethyl acrylate, 3,3, acrylate Examples include 5-trimethylcyclohexyl and cyclohexyl acrylate.

  In a further preferred embodiment, the copolymer is an ethylene-2-ethylhexyl acrylate-vinyl acetate copolymer.

  The copolymer used in the present invention has a glass transition temperature measured by dynamic differential scanning calorimetry according to DIN 53765 at a heating rate of 20 K / min and tangent method and Tg as the midpoint temperature using nitrogen as the inert gas. It can have a Tg-100 to 20 ° C., and the Tg is particularly −60 to 20 ° C., preferably −10 ° C. or lower, more preferably −20 ° C. or lower. Particularly preferably, Tg is −60 to 0 ° C., −60 to −20 ° C., or −60 to −40 ° C. Since the copolymer remains elastic and sticky under the normal storage temperature conditions of rice seeds, it is advantageous because good immobilization of the coating agent can be achieved and peeling of the coating agent can be avoided .

  The copolymer can be applied to the seed in a form known to those skilled in the art, preferably in the form of a dispersion. An aqueous dispersion is preferred because there is no risk of adverse effects of the solvent on the germination rate. After applying the coating agent, the rice seeds are dried. This can be done at room temperature or slightly elevated, for example at 30 ° C. or 35 ° C. Techniques such as hot air blowing or spray drying can also be used.

  For ease of handling, the copolymer dispersion has a Brookfield viscosity of 500 to 30,000 mPa · s, in particular 1,000 to 30,000 mPa · s as measured according to DIN EN ISO 2555, RVT, spindle number 4 at 20 rpm and 25 ° C. , Preferably from 1,500 to 20,000 mPa · s, more preferably from 2,000 to 10,000 mPa · s. This allows for an easy coating procedure while ensuring the desired coating thickness is achieved. Otherwise, the coating can be repeated one or several times with a drying step after each coating step until the desired coating thickness is achieved. Since the further coating layer may be free of any pesticide, it serves as a protective layer.

  In one embodiment, the copolymer of the present invention is 10,000 to 300,000 g / mol, preferably 100,000 to 300,000 g / mol, more preferably 125,000 to 300,000 g / mol; even more preferably It can have a weight average molecular weight Mw in the range of 200,000 to 280,000 g / mol, for example 240,000 ± 10,000 g / mol, and the monomer is preferably from 35 to 50% by weight of vinyl acetate, in particular from 38 48% by weight, preferably 40 to 45% by weight; (meth) acrylic acid monomer of the general formula (I) 25 to 55% by weight, in particular 30 to 50% by weight, preferably 35 to 45% by weight, particularly preferred 35 to 40% by weight; ethylene 5 to 25% by weight, in particular 10 to 25% by weight, preferably Properly may be present in an amount of 23 wt% to 15, the copolymer is free of acrylic acid.

  In one embodiment, the copolymer of the present invention can have a weight average molecular weight Mw in the range of 10,000 to 125,000 g / mol, and in a first embodiment, the copolymer of the present invention is 10,000 to 75. Can have a weight average molecular weight Mw in the range of 10,000 to 15,000 g / mol, more preferably 10,000 to 18,000 g / mol, and in the second embodiment 75, 000 to 125,000 g / mol.

  In particular, in one embodiment, the copolymer of the present invention has a weight average in the range of Mw 10,000 to 75,000, preferably 10,000 to 25,000 g / mol, more preferably 10,000 to 18,000 g / mol. The monomer preferably has a vinyl acetate content of 35 to 50% by weight, in particular 38 to 48% by weight, preferably 40 to 45% by weight; (meth) acrylic acid monomers 25 to 55 of the general formula (I) % By weight, in particular 30 to 50% by weight, preferably 35 to 45% by weight, particularly preferably 35 to 40% by weight; ethylene 5 to 25% by weight, in particular 10 to 25% by weight, preferably 15 to 23% by weight The copolymer can be present in an amount; the copolymer does not contain acrylic acid. In another embodiment, the copolymers of the present invention can have a weight average molecular weight Mw in the range of 125,000 to 250,000 g / mol.

  In yet another embodiment, the copolymer of the present invention can have a weight average molecular weight Mw ranging from 250,000 to 1,500,000 g / mol, and in a first embodiment, the copolymer of the present invention is 250 Can have a weight average molecular weight Mw in the range of from 7,000 to 750,000 g / mol, in the second embodiment from 750,000 to 1,500,000 g / mol, preferably from 1,000,000 to 1,500. 1,000,000 to 1,450,000 g / mol, more preferably 1,150,000 to 1,450,000 g / mol.

  In particular, in one embodiment, the copolymer of the present invention is from 750,000 to 1,500,000 g / mol, preferably from 1,000,000 to 1,500,000 g / mol, more preferably from 1,150,000. Having a weight average molecular weight Mw in the range of 1,450,000 g / mol, the monomer is preferably 35 to 50% by weight vinyl acetate, in particular 38 to 48% by weight, preferably 40 to 45% by weight; (I) (meth) acrylic acid monomers 25 to 55% by weight, in particular 30 to 50% by weight, preferably 35 to 45% by weight, particularly preferably 35 to 40% by weight; ethylene 5 to 25% by weight, in particular 10 From 25 to 25% by weight, preferably from 15 to 23% by weight; the copolymer does not contain acrylic acid.

  In yet another embodiment, the copolymer of the present invention can have a weight average molecular weight Mw ranging from 1,500,000 to 10,000,000 g / mol, and in a first embodiment, the copolymer of the present invention. Is in the range of 1,500,000 to 5,550,000 g / mol, preferably 1,500,000 to 3,000,000 g / mol, more preferably 1,500,000 to 2,000,000 g / mol. It may have a weight average molecular weight Mw; in a second embodiment, it is from 5,500,000 to 10,000,000 g / mol.

  In particular, in one embodiment, the copolymer of the present invention is from 1,500,000 to 5,550,000 g / mol, preferably 1,500,000 to 3,000,000 g / mol, more preferably 1,500,000. Having a weight average molecular weight Mw in the range of 000 to 2,000,000 g / mol, the monomer is preferably 35 to 50% by weight of vinyl acetate, in particular 38 to 48% by weight, preferably 40 to 45% by weight; (Meth) acrylic acid monomer of the general formula (I) 25 to 55% by weight, in particular 30 to 50% by weight, preferably 35 to 45% by weight, particularly preferably 35 to 40% by weight; ethylene 5 to 25% by weight, In particular it can be present in an amount of 10 to 25% by weight, preferably 15 to 23% by weight; the copolymer does not contain acrylic acid.

  Preferably, in the above paragraph, the (meth) acrylic acid monomer is ethylhexyl acrylate.

  The weight average molecular weight Mw can be determined by gel permeation chromatography (GPC) with trichlorobenzene as solvent and polystyrene as standard.

  In a preferred embodiment, the weight average molecular weight Mw is determined by gel permeation chromatography (GPC) using dichloromethane as the eluent and polystyrene as the standard.

  Starting from the dispersion, the sample for GPC is preferably dehydrated of the dispersion with sodium sulfate (eg 1 g of dispersion / 20 g of sodium sulfate), grinding of the resulting mixture and 6-hour Soxhlet extraction of the mixture with chloroform Prepared by The extract is dried over sodium sulfate, filtered and the solvent is preferably removed under reduced pressure. The residue is used for GPC.

  Preferably, the copolymer of the present invention is a copolymer having a main mass peak at 140,000 ± 20,000 g / mol (GPC dichloromethane, polystyrene standard, flow rate 1.0 mL / min, injection volume 100 μL (microliter)). , T = 30 ° C.).

  More preferably, the main mass peak comprises more than 70% (F [%]) of the polymer mass, more preferably more than 75%, most preferably more than 80%.

  Again preferably, the copolymer has a polydispersity (D = Mw / Mn) in the range of 50 to 150, preferably 80 to 120.

  In the most preferred embodiment, the copolymer of the present invention can have a weight average molecular weight Mw in the range of 200,000 to 280,000 g / mol, vinyl acetate is present in 38 to 48 wt% and is represented by the general formula (I ) (Meth) acrylic acid monomer is present at 35 to 40% by weight; ethylene is present at 15 to 23% by weight; the copolymer is free of acrylic acid and the copolymer is predominantly at 140,000 ± 20,000 g / mol. It has a peak of mass peak (GPC dichloromethane, polystyrene standard, flow rate of 10 mL / min, injection volume 100 μL (microliter), T = 30 ° C.).

  Furthermore, in the most preferred embodiment, the main mass peak comprises more than 80% of the mass of the polymer (F [%]) and the copolymer has a polydispersity (D = Mw / Mn) in the range of 80 to 120.

  In another preferred embodiment, the copolymer of the present invention can have a weight average molecular weight Mw in the range of 125,000 to 250,000 g / mol, vinyl acetate is present at 38 to 48% by weight, and has the general formula ( I) (meth) acrylic acid monomer is present at 35 to 40% by weight; ethylene is present at 15 to 23% by weight; the copolymer is free of acrylic acid and the copolymer is 140,000 ± 20,000 g / mol It has a main mass peak (GPC dichloromethane, polystyrene standard, flow rate 1.0 mL / min, injection volume 100 μL (microliter), T = 30 ° C.).

  Further, in the most preferred embodiment, the main mass peak comprises more than 80% (F [%]) of the mass of the polymer. The copolymer has a polydispersity (D = Mw / Mn) in the range of 80 to 120.

  The dispersion can have a solids content of, for example, 30 to 80% by weight, in particular 50 to 70% by weight, preferably 55 to 65% by weight, measured according to DIN EN ISO3251 at 130 ° C. for 30 minutes. When using a dispersion with such a solid content, it is preferred that the dosage of the dispersion for all coating formulations containing agrochemicals is 1 to 20% by weight, more preferably 2 to 15% by weight, most preferably 3 To 12% by weight.

  The pH value of the dispersion can range from 4 to 7, in particular from 4.5 to 6.5, measured according to DIN ISO 976 in a 1: 1 mixture with water. The dispersion can exhibit an average particle size of 0.1 to 5 μm, in particular 0.2 to 2.0 μm. The average particle diameter d50 is a particle diameter at which 50% by weight is recognized in the upper and lower sides. It can be measured using an ultracentrifuge (W. Scholtan, H. Lange, Kolloid, Z. und Z. Polymere 250 (1972), 782-796).

  In order to improve the film-forming properties, it is advantageous for the dispersion to have a minimum film-forming temperature of 0 ° C. measured according to DIN ISO 2115.

  According to a further preferred embodiment of the invention, the dispersion contains little plasticizer and / or nonionic detergent, in particular little alkylphenol ethoxylate. This is advantageous because the copolymer of the present invention can be provided as an aqueous dispersion without the need to add said additives that can cause environmental problems. This is especially true for nonionic detergents, especially alkylphenol ethoxylates.

  In connection with the present invention, any pesticide can be used to provide the coating agent. Therefore, the pesticides are insecticides, fungicides, bactericides, virus killers, acaricides, molluscicides, nematicides, egg killers, repellents, rodenticides, herbicides, safeners, It can be selected from the group comprising fertilizers, biological agents, or mixtures thereof.

  Pesticides, or what are also referred to herein as “active ingredients” (“ai”), are known herein and are described, for example, in the Pesticide Manual (“The Pesticide Manual”, 14th Ed., British Crop). Whether it is specified by “generic name” described in Protection Council 2006) or can be searched on the Internet (for example, http://www.alanwood.net/pesticides).

  Where compound (A) or compound (B) can exist in tautomeric form, such compounds may be present above and below, even if not specifically mentioned in each case where applicable. Are understood to include the corresponding tautomeric forms.

  1) Inhibitors of ergosterol biosynthesis, such as (1.1) Aldimorph, (1.2) Azaconazole, (1.3) Viteltanol, (1.4) Bromuconazole, (1.5) Cyproconazole (1.6) diclobutrazole, (1.7) diphenoconazole, (1.8) diniconazole, (1.9) diniconazole-M, (1.10) dodemorph, (1.11) dodemorph acetate, 1.12) Epoxyconazole, (1.13) Etaconazole, (1.14) Phenalimol, (1.15) Fenbuconazole, (1.16) Fenhexamide, (1.17) Fenpropidin, ( 1.18) fenpropimorph, (1.19) fluquinconazole, (1.20) flurprimidol, (1.21) flusilazole, (1.22) fruto Ahol, (1.23) fluconazole, (1.24) fluconazole-cis, (1.25) hexaconazole, (1.26) imazalyl, (1.27) imazalyl sulfate, (1.28) imibenconazole , (1.29) ipconazole, (1.30) metconazole, (1.31) microbutanyl, (1.32) naphthifine, (1.33) nuarimol, (1.34) oxypoconazole, (1.35) Paclobutrazol, (1.36) Pefrazoate, (1.37) Penconazole, (1.38) Piperalin, (1.39) Prochloraz, (1.40) Propiconazole, (1.41) Prothioconazole , (1.42) Pyributicarb, (1.43) Pyrifenox, (1.44) Kinconazole, (1.45) Simeconazo (1.46) Spiroxamine, (1.47) Tebuconazole, (1.48) Terbinafine, (1.49) Tetraconazole, (1.50) Triadimethone, (1.51) Triadimenol, (1. 52) Tridemorph, (1.53) Triflumizole, (1.54) Trifolin, (1.55) Triticonazole, (1.56) Uniconazole, (1.57) Uniconazole-p, (1.58) Biniconazole, (1.59) voriconazole, (1.60) 1- (4-chlorophenyl) -2- (1H-1,2,4-triazol-1-yl) cycloheptanol, (1.61) 1- (2,2-dimethyl-2,3-dihydro-1H-inden-1-yl) -1H-imidazole-5-carboxylate methyl, (1.62) N ′-{5- (difluoro (Romethyl) -2-methyl-4- [3- (trimethylsilyl) propoxy] phenyl} -N-ethyl-N-methylimidoformamide, (1.63) N-ethyl-N-methyl-N ′-{2-methyl -5- (trifluoromethyl) -4- [3- (trimethylsilyl) propoxy] phenyl} imidoformamide, (1.64) O- [1- (4-methoxyphenoxy) -3,3-dimethylbutane-2- Yl] -1H-imidazole-1-carbothioate, (1.65) pyrisoxazole.

  2) Inhibitors of the respiratory chain in complex I or II, for example (2.1) Bixafen, (2.2) Boscalid, (2.3) Carboxin, (2.4) Diflumetrim, (2.5 ) Fenflam, (2.6) Fluopyram, (2.7) Flutolanil, (2.8) Fluxapyroxad, (2.9) Frametopyr, (2.10) Flumecyclox, (2.11) ) Isopyrazam (mixture of syn-epimeric racemic compound (1RS, 4SR, 9RS) and anti-epimeric racemic compound (1RS, 4SR, 9SR)), (2.12) Isopyrazam (anti-epimeric racemic compound 1RS, 4SR) 9SR), (2.13) isopyrazam (anti-epimeric enantiomer 1R, 4S, 9S), (2.14) isopyrazam. Anti-epimeric enantiomers 1S, 4R, 9R), (2.15) isopyrazam (syn-epimeric racemic compounds 1RS, 4SR, 9RS), (2.16) isopyrazam (syn-epimeric enantiomers 1R, 4S, 9R) (2.17) isopyrazam (syn-epimeric enantiomer 1S, 4R, 9S), (2.18) mepronil, (2.19) oxycarboxin, (2.20) penflufen, (2.21) penthiopyrad. (2.22) sedaxane, (2.23) tifluzamide, (2.24) 1-methyl-N- [2- (1,1,2,2-tetrafluoroethoxy) phenyl] -3- (trifluoromethyl ) -1H-pyrazole-4-carboxamide, (2.25) 3- (difluoromethyl) -1-methyl-N- [2- (1 1,2,2-tetrafluoroethoxy) phenyl] -1H-pyrazole-4-carboxamide, (2.26) 3- (difluoromethyl) -N- [4-fluoro-2- (1,1,2,3) , 3,3-hexafluoropropoxy) phenyl] -1-methyl-1H-pyrazole-4-carboxamide, (2.27) N- [1- (2,4-dichlorophenyl) -1-methoxypropan-2-yl ] -3- (difluoromethyl) -1-methyl-1H-pyrazole-4-carboxamide, (2.28) 5,8-difluoro-N- [2- (2-fluoro-4-{[4- (tri Fluoromethyl) pyridin-2-yl] oxy} phenyl) ethyl] quinazolin-4-amine, (2.29) benzovindiflupyr, (2.30) N-[(1S, 4R) -9- (dichroic) Romethylene) -1,2,3,4-tetrahydro-1,4-methananaphthalen-5-yl] -3- (difluoromethyl) -1-methyl-1H-pyrazole-4-carboxamide, (2.31) N -[(1R, 4S) -9- (dichloromethylene) -1,2,3,4-tetrahydro-1,4-methananaphthalen-5-yl] -3- (difluoromethyl) -1-methyl-1H- Pyrazole-4-carboxamide, (2.32) 3- (difluoromethyl) -1-methyl-N- (1,1,3-trimethyl-2,3-dihydro-1H-inden-4-yl) -1H- Pyrazole-4-carboxamide, (2.33) 1,3,5-trimethyl-N- (1,1,3-trimethyl-2,3-dihydro-1H-inden-4-yl) -1H-pyrazole-4 -Carbo Samid, (2.34) 1-methyl-3- (trifluoromethyl) -N- (1,1,3-trimethyl-2,3-dihydro-1H-inden-4-yl) -1H-pyrazole-4 -Carboxamide, (2.35) 1-methyl-3- (trifluoromethyl) -N-[(1S) -1,1,3-trimethyl-2,3-dihydro-1H-inden-4-yl]- 1H-pyrazole-4-carboxamide, (2.36) 1-methyl-3- (trifluoromethyl) -N-[(1R) -1,1,3-trimethyl-2,3-dihydro-1H-indene- 4-yl] -1H-pyrazole-4-carboxamide, (2.37) 3- (difluoromethyl) -1-methyl-N-[(3S) -1,1,3-trimethyl-2,3-dihydro- 1H-Inden-4-yl] -1 -Pyrazole-4-carboxamide, (2.38) 3- (difluoromethyl) -1-methyl-N-[(3R) -1,1,3-trimethyl-2,3-dihydro-1H-indene-4- Yl] -1H-pyrazole-4-carboxamide, (2.39) 1,3,5-trimethyl-N-[(3R) -1,1,3-trimethyl-2,3-dihydro-1H-indene-4 -Yl] -1H-pyrazole-4-carboxamide, (2.40) 1,3,5-trimethyl-N-[(3S) -1,1,3-trimethyl-2,3-dihydro-1H-indene- 4-yl] -1H-pyrazole-4-carboxamide, (2.41) benodanyl, (2.42) 2-chloro-N- (1,1,3-trimethyl-2,3-dihydro-1H-indene- 4-yl) pyridine-3-ca Luboxamide, (2.43) Isofetamide.

  3) Respiratory chain inhibitors in complex III, for example (3.1) amethoctrazine, (3.2) amisulbrom, (3.3) azoxystrobin, (3.4) cyazofamid, (3.5 ) Cumethoxystrobin, (3.6) cuboxystrobin, (3.7) dimoxystrobin, (3.8) enoxastrobin, (3.9) famoxadone, (3) .10) phenamidon, (3.11) fluphenoxystrobin, (3.12) fluoxastrobin, (3.13) cresoxime-methyl, (3.14) methinostrobin, (3. 15) orisatrobin, (3.16) picoxystrobin, 3.17) pyraclostrobin, (3.18) pyramethostrobin, (3.19) pyraoxystrobin, (3.20) pyribencarb, (3.21) triclopyriccarb ), (3.22) Trifloxystrobin, (3.23) (2E) -2- (2-{[6- (3-Chloro-2-methylphenoxy) -5-fluoropyrimidin-4-yl] Oxy} phenyl) -2- (methoxyimino) -N-methylacetamide, (3.24) (2E) -2- (methoxyimino) -N-methyl-2- (2-{[({(1E)- 1- [3- (trifluoromethyl) phenyl] ethylidene} amino) oxy] methyl} phenyl) acetamide, (3. 5) (2E) -2- (methoxyimino) -N-methyl-2- {2-[(E)-({1- [3- (trifluoromethyl) phenyl] ethoxy} imino) methyl] phenyl} acetamide , (3.26) (2E) -2- {2-[({[(1E) -1- (3-{[(E) -1-fluoro-2-phenylvinyl] oxy} phenyl) ethylidene] amino } Oxy) methyl] phenyl} -2- (methoxyimino) -N-methylacetamide, (3.27) phenaminostrobin, (3.28) 5-methoxy-2-methyl-4- (2-{[({(1E) -1- [3- (trifluoromethyl) phenyl] ethylidene} amino) oxy] methyl} phenyl) -2,4-dihydro-3H-1,2,4-triazole- 3-on, (3.29) (2E) -2- {2-[({Cyclopropyl [(4-methoxyphenyl) imino] methyl} sulfanyl) methyl] phenyl} -3-methoxyacrylate, (3.30) N -(3-ethyl-3,5,5-trimethylcyclohexyl) -3-formamido-2-hydroxybenzamide, (3.31) 2- {2-[(2,5-dimethylphenoxy) methyl] phenyl} -2 -Methoxy-N-methylacetamide, (3.32) (2R) -2- {2-[(2,5-dimethylphenoxyoxy) methyl] phenyl} -2-methoxy-N-methylacetamide.

  4) Inhibitors of mitosis and cell division, such as (4.1) benomyl, (4.2) carbendazim, (4.3) chlorphenazole, (4.4) dietofencarb, (4.5) Ethaboxam, (4.6) fluopicolide, (4.7) fuberidazole, (4.8) pencyclon, (4.9) thiabendazole, (4.10) thiophanate-methyl, (4.11) thiophanate, (4.12) ) Zoxamide, (4.13) 5-Chloro-7- (4-methylpiperidin-1-yl) -6- (2,4,6-trifluorophenyl) [1,2,4] triazolo [1,5 -A] pyrimidine, (4.14) 3-chloro-5- (6-chloropyridin-3-yl) -6-methyl-4- (2,4,6-trifluorophenyl) pyridazine.

  5) Compounds capable of having multi-site action, such as (5.1) Bordeaux solution, (5.2) Captahol, (5.3) Captan, (5.4) Chlorothalonyl, (5.5) Copper hydroxide , (5.6) copper naphthenate, (5.7) copper oxide, (5.8) basic copper chloride, (5.9) copper sulfate (2+), (5.10) dichlorofluanide, (5 .11) Dithianon, (5.12) Dodine, (5.13) Dodine Free Base, (5.14) Farbum, (5.15) Fluorophorpet, (5.16) Holpet, (5.17) Guazatine , (5.18) guazatine acetate, (5.19) iminoctadine, (5.20) iminoctadine albecylate, (5.21) iminoctadine triacetate, (5.22) mankappa, (5.23) Mancozeb, (5.24) Mannebu (5.25) methylam, (5.26) methylam zinc, (5.27) oxine copper, (5.28) propamidine, (5.29) propineb, (5.30) sulfur and calcium polysulfide Sulfur agents such as (5.31) thiuram, (5.32) tolylfuranide, (5.33) dineb, (5.34) ziram, (5.35) anilazine.

  6) Compounds capable of inducing host defense such as (6.1) Acibenzoral-S-methyl, (6.2) Isotianil, (6.3) Probenazole, (6.4) Thiazinyl, (6.5) ) Laminarin.

  7) inhibitors of amino acid and / or protein biosynthesis, such as (7.1) andoprim, (7.2) blasticidin-S, (7.3) cyprodinil, (7.4) kasugamycin (7.5) Kasugamycin hydrochloride hydrate, (7.6) Mepanipyrim, (7.7) Pyrimethanyl, (7.8) 3- (5-Fluoro-3,3,4,4-tetramethyl-3 , 4-dihydroisoquinolin-1-yl) quinoline, (7.9) oxytetracycline, (7.10) streptomycin.

  8) Inhibitors of ATP production, for example (8.1) triphenyltin acetate, (8.2) triphenyltin chloride, (8.3) triphenyltin hydroxide, (8.4) silthiofam.

  9) Inhibitors of cell wall synthesis, such as (9.1) Bench Avaricarb, (9.2) Dimethomorph, (9.3) Furmorph, (9.4) Iprovaricarb, (9.5) Mandipropamide, (9 .6) Polyoxin, (9.7) Polyoxolim, (9.8) Validamycin A, (9.9) Variphenate, (9.10) Polyoxin B.

  10) Inhibitors of lipid and membrane synthesis, such as (10.1) biphenyl, (10.2) chloroneb, (10.3) dichlorane, (10.4) edifenphos, (10.5) etridiazole, (10. 6) iodocarb, (10.7) iprobenphos, (10.8) isoprothiolane, (10.9) propamocarb, (10.10) propamocarb hydrochloride, (10.11) prothiocarb, (10.12) pyrazophos , (10.13) Kintozen, (10.14) Technazen, (10.15) Torquelophos-methyl.

  11) Inhibitors of melanin biosynthesis, such as (11.1) carpropamide, (11.2) diclosimet, (11.3) phenoxanyl, (11.4) phthalide, (11.5) pyroxylone, (11.6) ) Tricyclazole, (11.7) 2,2,2-trifluoroethyl {3-methyl-1-[(4-methylbenzoyl) amino] butan-2-yl} carbamate.

  12) Inhibitors of nucleic acid synthesis, such as (12.1) Benalaxyl, (12.2) Benalaxyl-M (kiralaxil), (12.3) Bupilimate, (12.4) Cloziracone, (12.5) Dimethylylmol, (12.6) Ethymol, (12.7) Fulleraxyl, (12.8) Himexazole, (12.9) Metalaxyl, (12.10) Metalaxyl-M (Mefenoxam), (12.11) Offrace, (12. 12) Oxadixyl, (12.13) Oxophosphoric acid, (12.14) Octylinone.

  13) Inhibitors of signal transduction, for example (13.1) Clozolinate, (13.2) Fenpicuronyl, (13.3) Fludioxonil, (13.4) Iprodione, (13.5) Procymidone, (13.6) Quinoxyphene, (13.7) Vinclozoline, (13.8) Proquinazide.

  14) Compounds that can act as uncouplers, such as (14.1) Binapacryl, (14.2) Dinocup, (14.3) Ferimzone, (14.4) Fluazinam, (14.5) Meptyl Gino Cup.

15) Yet another compound, for example (15.1) Benchazole, (15.2) Betoxazine, (15.3) capsimycin, (15.4) Carvone, (15.5) Quinomethionate, (15) .6) Pyriofenone (clazafenone), (15.7) Kufraneb, (15.8) Cyflufenamide, (15.9) Simoxanil, (15.10) Cyprosulfamide, (15.11) Dazomet, (15.12) Debacarb, (15.13) Dichlorophene, (15.14) Dichromedin, (15.15) Diphenzocoat, (15.16) Diphenzocoat methyl sulfate, (15.17) Diphenylamine (15.18) Ecomate, (15.19) Fe Pyrazamine (fenpyraz amine), (15.20) flumethoverl, (15.21) fluorimide, (15.22) flusulfamide, (15.23) flutianil, (15.24) fosetyl-aluminum, (15.25) fosetyl- Calcium, (15.26) fosetyl-sodium, (15.27) hexachlorobenzene, (15.28) ilumamycin, (15.29) metasulfocarb, (15.30) methyl isothiocyanate, (15.31) Metraphenone, (15.32) mildiomycin, (15.33) natamycin, (15.34) nickel dimethyldithiocarbamate, (15.35) nitrotal-isopropyl, (15.37) oxamocarb, (15. 38) Oxyfenches (15.39) pentachlorophenol and salts, (15.40) phenothrin, (15.41) phosphorous acid and its salts, (15.42) propamocarb-fosetylate, (15.43) propanocine-sodium, (15.44) pyrimorph, (15.45) (2E) -3- (4-tert-butylphenyl) -3- (2-chloropyridine-4 -Yl) -1- (morpholin-4-yl) prop-2-en-1-one, (15.46) (2Z) -3- (4-tert-butylphenyl) -3- (2-chloropyridine) -4-yl) -1- (morpholin-4-yl) prop-2-en-1-one, (15.47) Pyrrolnitrin, (15.48) tebufloquine, (15.49) teclophthalam, (15.50) torniphanide, (15.51) triazoxide, (15.52) trichlamide, (15.53) zaliramide, (15.54) ) 2-Methylpropanoic acid (3S, 6S, 7R, 8R) -8-benzyl-3-[({3-[(isobutyryloxy) methoxy] -4-methoxypyridin-2-yl} carbonyl) amino] -6-methyl-4,9-dioxo-1,5-dioxonan-7-yl, (15.55) 1- (4- {4-[(5R) -5- (2,6-difluorophenyl)- 4,5-dihydro-1,2-oxazol-3-yl] -1,3-thiazol-2-yl} piperidin-1-yl) -2- [5-methyl-3- (trifluoromethyl) -1H Pyrazol-1-yl] ethanone, (15.56) 1- (4- {4-[(5S) -5- (2,6-difluorophenyl) -4,5-dihydro-1,2-oxazole-3] -Yl] -1,3-thiazol-2-yl} piperidin-1-yl) -2- [5-methyl-3- (trifluoromethyl) -1H-pyrazol-1-yl] ethanone, (15.57 ) 1- (4- {4- [5- (2,6-difluorophenyl) -4,5-dihydro-1,2-oxazol-3-yl] -1,3-thiazol-2-yl} piperidine- 1-yl) -2- [5-methyl-3- (trifluoromethyl) -1H-pyrazol-1-yl] ethanone, (15.58) 1- (4-methoxyphenoxy) -3,3-dimethylbutane 2-yl-1H-imidazole-1-ca Boxylate, (15.59) 2,3,5,6-tetrachloro-4- (methylsulfonyl) pyridine, (15.60) 2,3-dibutyl-6-chlorothieno [2,3-d] pyrimidine-4 (3H) -one, (15.61) 2,6-dimethyl-1H, 5H- [1,4] dithino [2,3-c: 5,6-c '] dipyrrole-1,3,5,7 (2H, 6H) -Tetron, (15.62) 2- [5-Methyl-3- (trifluoromethyl) -1H-pyrazol-1-yl] -1- (4- {4-[(5R)- 5-phenyl-4,5-dihydro-1,2-oxazol-3-yl] -1,3-thiazol-2-yl} piperidin-1-yl) ethanone, (15.63) 2- [5-methyl -3- (trifluoromethyl) -1H-pyrazol-1-yl] -1- (4- {4-[(5S) -5-phenyl-4,5-dihydro-1,2-oxazol-3-yl] -1,3-thiazol-2-yl} piperidin-1-yl) ethanone, (15.64) 2- [5-Methyl-3- (trifluoromethyl) -1H-pyrazol-1-yl] -1- {4- [4- (5-phenyl-4,5-dihydro-1, 2-oxazol-3-yl) -1,3-thiazol-2-yl] piperidin-1-yl} ethanone, (15.65) 2-butoxy-6-iodo-3-propyl-4H-chromene-4- ON, (15.66) 2-chloro-5- [2-chloro-1- (2,6-difluoro-4-methoxyphenyl) -4-methyl-1H-imidazol-5-yl] pyridine, (15. 67) 2-phenylphenol and salts, (15 68) 3- (4,4,5-trifluoro-3,3-dimethyl-3,4-dihydroisoquinolin-1-yl) quinoline, (15.69) 3,4,5-trichloropyridine-2,6 -Dicarbonitrile, (15.70) 3-chloro-5- (4-chlorophenyl) -4- (2,6-difluorophenyl) -6-methylpyridazine, (15.71) 4- (4-chlorophenyl) -5- (2,6-difluorophenyl) -3,6-dimethylpyridazine, (15.72) 5-amino-1,3,4-thiadiazole-2-thiol, (15.73) 5-chloro-N '-Phenyl-N'-(prop-2-yn-1-yl) thiophene-2-sulfonohydrazide, (15.74) 5-fluoro-2-[(4-fluorobenzyl) oxy] pyrimidine-4- Ami (15.75) 5-fluoro-2-[(4-methylbenzyl) oxy] pyrimidin-4-amine, (15.76) 5-methyl-6-octyl [1,2,4] triazolo [1, 5-a] pyrimidin-7-amine, (15.77) (2Z) -3-amino-2-cyano-3-phenylacrylate, (15.78) N ′-(4-{[3- ( 4-chlorobenzyl) -1,2,4-thiadiazol-5-yl] oxy} -2,5-dimethylphenyl) -N-ethyl-N-methylimidoformamide, (15.79) N- (4-chloro (Benzyl) -3- [3-methoxy-4- (prop-2-yn-1-yloxy) phenyl] propanamide, (15.80) N-[(4-chlorophenyl) (cyano) methyl] -3- [ 3-methoxy-4- (prop -2-yn-1-yloxy) phenyl] propanamide, (15.81) N-[(5-bromo-3-chloropyridin-2-yl) methyl] -2,4-dichloronicotinamide, (15. 82) N- [1- (5-Bromo-3-chloropyridin-2-yl) ethyl] -2,4-dichloronicotinamide, (15.83) N- [1- (5-Bromo-3-chloro] Pyridin-2-yl) ethyl] -2-fluoro-4-iodonicotinamide, (15.84) N-{(E)-[(cyclopropylmethoxy) imino] [6- (difluoromethoxy) -2,3 -Difluorophenyl] methyl} -2-phenylacetamide, (15.85) N-{(Z)-[(cyclopropylmethoxy) imino] [6- (difluoromethoxy) -2,3-difluorophenyl Methyl} -2-phenylacetamide, (15.86) N ′-{4-[(3-tert-butyl-4-cyano-1,2-thiazol-5-yl) oxy] -2-chloro-5 Methylphenyl} -N-ethyl-N-methylimidoformamide, (15.87) N-methyl-2- (1-{[5-methyl-3- (trifluoromethyl) -1H-pyrazol-1-yl] Acetyl} piperidin-4-yl) -N- (1,2,3,4-tetrahydronaphthalen-1-yl) -1,3-thiazole-4-carboxamide, (15.88) N-methyl-2- ( 1-{[5-Methyl-3- (trifluoromethyl) -1H-pyrazol-1-yl] acetyl} piperidin-4-yl) -N-[(1R) -1,2,3,4-tetrahydronaphthalene -1-yl] 1,3-thiazole-4-carboxamide, (15.89) N-methyl-2- (1-{[5-methyl-3- (trifluoromethyl) -1H-pyrazol-1-yl] acetyl} piperidine- 4-yl) -N-[(1S) -1,2,3,4-tetrahydronaphthalen-1-yl] -1,3-thiazole-4-carboxamide, (15.90) pentyl {6-[({ [(1-Methyl-1H-tetrazol-5-yl) (phenyl) methylene] amino} oxy) methyl] pyridin-2-yl} carbamate, (15.91) phenazine-1-carboxylic acid, (15.92) Quinolin-8-ol, (15.93) quinolin-8-ol sulfate (2: 1), (15.94) tert-butyl {6-[({[(1-methyl-1H-tetrazole-5 -Yl) (phenyl) methylene] amino} oxy) methyl] pyridin-2-yl} carbamate, (15.95) 1-methyl-3- (trifluoromethyl) -N- [2 '-(trifluoromethyl) Biphenyl-2-yl] -1H-pyrazole-4-carboxamide, (15.96) N- (4′-chlorobiphenyl-2-yl) -3- (difluoromethyl) -1-methyl-1H-pyrazole-4 -Carboxamide, (15.97) N- (2 ', 4'-dichlorobiphenyl-2-yl) -3- (difluoromethyl) -1-methyl-1H-pyrazole-4-carboxamide, (15.98) 3 -(Difluoromethyl) -1-methyl-N- [4 '-(trifluoromethyl) biphenyl-2-yl] -1H-pyrazole-4-carboxamide, (15. 9) N- (2 ′, 5′-difluorobiphenyl-2-yl) -1-methyl-3- (trifluoromethyl) -1H-pyrazole-4-carboxamide, (15.100) 3- (difluoromethyl) -1-methyl-N- [4 '-(prop-1-in-1-yl) biphenyl-2-yl] -1H-pyrazole-4-carboxamide, (15.101) 5-fluoro-1,3- Dimethyl-N- [4 '-(prop-1-in-1-yl) biphenyl-2-yl] -1H-pyrazole-4-carboxamide, (15.102) 2-Chloro-N- [4'-( Prop-1-in-1-yl) biphenyl-2-yl] nicotinamide, (15.103) 3- (difluoromethyl) -N- [4 '-(3,3-dimethylbut-1-in-1- Yl) biphenyl-2 Yl] -1-methyl-1H-pyrazole-4-carboxamide, (15.104) N- [4 ′-(3,3-dimethylbut-1-in-1-yl) biphenyl-2-yl] -5 Fluoro-1,3-dimethyl-1H-pyrazole-4-carboxamide, (15.105) 3- (difluoromethyl) -N- (4'-ethynylbiphenyl-2-yl) -1-methyl-1H-pyrazole- 4-carboxamide, (15.106) N- (4′-ethynylbiphenyl-2-yl) -5-fluoro-1,3-dimethyl-1H-pyrazole-4-carboxamide, (15.107) 2-chloro- N- (4'-ethynylbiphenyl-2-yl) nicotinamide, (15.108) 2-chloro-N- [4 '-(3,3-dimethylbut-1-in-1-yl) biphe Nyl-2-yl] nicotinamide, (15.109) 4- (difluoromethyl) -2-methyl-N- [4 ′-(trifluoromethyl) biphenyl-2-yl] -1,3-thiazole-5 -Carboxamide, (15.110) 5-fluoro-N- [4 '-(3-hydroxy
Ci-3-methylbut-1-in-1-yl) biphenyl-2-yl] -1,3-dimethyl-1H-pyrazole-4-carboxamide, (15.111) 2-chloro-N- [4'- (3-Hydroxy-3-methylbut-1-in-1-yl) biphenyl-2-yl] nicotinamide, (15.112) 3- (difluoromethyl) -N- [4 ′-(3-methoxy-3) -Methylbut-1-in-1-yl) biphenyl-2-yl] -1-methyl-1H-pyrazole-4-carboxamide, (15.113) 5-fluoro-N- [4 '-(3-methoxy- 3-methylbut-1-in-1-yl) biphenyl-2-yl] -1,3-dimethyl-1H-pyrazole-4-carboxamide, (15.114) 2-chloro-N- [4 ′-(3 -Methoxy-3- Tilbut-1-in-1-yl) biphenyl-2-yl] nicotinamide, (15.115) (5-bromo-2-methoxy-4-methylpyridin-3-yl) (2,3,4-trimethoxy) -6-methylphenyl) methanone, (15.116) N- [2- (4-{[3- (4-chlorophenyl) prop-2-yn-1-yl] oxy} -3-methoxyphenyl) ethyl] -N2- (methylsulfonyl) valinamide, (15.117) 4-oxo-4-[(2-phenylethyl) amino] butanoic acid, (15.118) but-3-in-1-yl {6- [ ({[(Z)-(1-methyl-1H-tetrazol-5-yl) (phenyl) methylene] amino} oxy) methyl] pyridin-2-yl} carbamate, (15.119) 4-amino-5- Luolopyrimidin-2-ol (tautomer: 4-amino-5-fluoropyrimidin-2 (1H) -one), (15.120) propyl 3,4,5-trihydroxybenzoate, (15.121) ) 1,3-dimethyl-N- (1,1,3-trimethyl-2,3-dihydro-1H-inden-4-yl) -1H-pyrazole-4-carboxamide, (15.122) 1,3- Dimethyl-N-[(3R) -1,1,3-trimethyl-2,3-dihydro-1H-inden-4-yl] -1H-pyrazole-4-carboxamide, (15.123) 1,3-dimethyl -N-[(3S) -1,1,3-trimethyl-2,3-dihydro-1H-inden-4-yl] -1H-pyrazole-4-carboxamide, (15.124) [3- (4- Chloro-2-ful Orophenyl) -5- (2,4-difluorophenyl) -1,2-oxazol-4-yl] (pyridin-3-yl) methanol, (15.125) (S)-[3- (4-chloro- 2-fluorophenyl) -5- (2,4-difluorophenyl) -1,2-oxazol-4-yl] (pyridin-3-yl) methanol, (15.126) (R)-[3- (4 -Chloro-2-fluorophenyl) -5- (2,4-difluorophenyl) -1,2-oxazol-4-yl] (pyridin-3-yl) methanol, (15.127) 2-{[3- (2-chlorophenyl) -2- (2,4-difluorophenyl) oxiran-2-yl] methyl} -2,4-dihydro-3H-1,2,4-triazole-3-thione, (15.128) 1-{[3- 2-chlorophenyl) -2- (2,4-difluorophenyl) oxiran-2-yl] methyl} -1H-1,2,4-triazol-5-ylthiocyanate, (15.129) 5- (allylsulfanyl) -1-{[3- (2-chlorophenyl) -2- (2,4-difluorophenyl) oxiran-2-yl] methyl} -1H-1,2,4-triazole, (15.130) 2- [ 1- (2,4-dichlorophenyl) -5-hydroxy-2,6,6-trimethylheptan-4-yl] -2,4-dihydro-3H-1,2,4-triazole-3-thione, (15 131) 2-{[rel (2R, 3S) -3- (2-chlorophenyl) -2- (2,4-difluorophenyl) oxiran-2-yl] methyl} -2,4-dihydro-3H- , 2,4-triazole-3-thione, (15.132) 2-{[rel (2R, 3R) -3- (2-chlorophenyl) -2- (2,4-difluorophenyl) oxilan-2-yl ] Methyl} -2,4-dihydro-3H-1,2,4-triazole-3-thione, (15.133) 1-{[rel (2R, 3S) -3- (2-chlorophenyl) -2- (2,4-difluorophenyl) oxiran-2-yl] methyl} -1H-1,2,4-triazol-5-yl thiocyanate, (15.134) 1-{[rel (2R, 3R) -3- (2-chlorophenyl) -2- (2,4-difluorophenyl) oxiran-2-yl] methyl} -1H-1,2,4-triazol-5-yl thiocyanate, (15.135) 5- (allylsulfa Nyl) -1-{[rel (2R, 3S) -3- (2-chlorophenyl) -2- (2,4-difluorophenyl) oxiran-2-yl] methyl} -1H-1,2,4-triazole , (15.136) 5- (allylsulfanyl) -1-{[rel (2R, 3R) -3- (2-chlorophenyl) -2- (2,4-difluorophenyl) oxiran-2-yl] methyl} -1H-1,2,4-triazole, (15.137) 2-[(2S, 4S, 5S) -1- (2,4-dichlorophenyl) -5-hydroxy-2,6,6-trimethylheptane- 4-yl] -2,4-dihydro-3H-1,2,4-triazole-3-thione, (15.138) 2-[(2R, 4S, 5S) -1- (2,4-dichlorophenyl) -5-hydroxy-2,6, -Trimethylheptan-4-yl] -2,4-dihydro-3H-1,2,4-triazole-3-thione, (15.139) 2-[(2R, 4R, 5R) -1- (2, 4-dichlorophenyl) -5-hydroxy-2,6,6-trimethylheptan-4-yl] -2,4-dihydro-3H-1,2,4-triazole-3-thione, (15.140) 2- [(2S, 4R, 5R) -1- (2,4-dichlorophenyl) -5-hydroxy-2,6,6-trimethylheptan-4-yl] -2,4-dihydro-3H-1,2,4 -Triazole-3-thione, (15.141) 2-[(2S, 4S, 5R) -1- (2,4-dichlorophenyl) -5-hydroxy-2,6,6-trimethylheptan-4-yl] -2,4-dihydro-3H-1,2 4-triazol-3-thione, (15.142) 2-[(2R, 4S, 5R) -1- (2,4-dichlorophenyl) -5-hydroxy-2,6,6-trimethylheptan-4-yl ] -2,4-dihydro-3H-1,2,4-triazole-3-thione, (15.143) 2-[(2R, 4R, 5S) -1- (2,4-dichlorophenyl) -5 Hydroxy-2,6,6-trimethylheptan-4-yl] -2,4-dihydro-3H-1,2,4-triazole-3-thione, (15.144) 2-[(2S, 4R, 5S ) -1- (2,4-dichlorophenyl) -5-hydroxy-2,6,6-trimethylheptan-4-yl] -2,4-dihydro-3H-1,2,4-triazole-3-thione, (15.145) 2-Fluoro-6- ( Trifluoromethyl) -N- (1,1,3-trimethyl-2,3-dihydro-1H-inden-4-yl) benzamide, (15.146) 2- (6-benzylpyridin-2-yl) quinazoline (15.147) 2- [6- (3-Fluoro-4-methoxyphenyl) -5-methylpyridin-2-yl] quinazoline, (15.148) 3- (4,4-difluoro-3,3 -Dimethyl-3,4-dihydroisoquinolin-1-yl) quinoline, (15.149) abscisic acid, (15.150) 3- (difluoromethyl) -N-methoxy-1-methyl-N- [1- ( 2,4,6-trichlorophenyl) propan-2-yl] -1H-pyrazole-4-carboxamide, (15.151) N ′-[5-bromo-6- (2,3-dihydro-1H-in) N-2-yloxy) -2-methylpyridin-3-yl] -N-ethyl-N-methylimidoformamide, (15.152) N ′-{5-bromo-6- [1- (3,5- Difluorophenyl) ethoxy] -2-methylpyridin-3-yl} -N-ethyl-N-methylimidoformamide, (15.153) N ′-{5-bromo-6-[(1R) -1- (3 , 5-Difluorophenyl) ethoxy] -2-methylpyridin-3-yl} -N-ethyl-N-methylimidoformamide, (15.154) N ′-{5-bromo-6-[(1S) -1 -(3,5-difluorophenyl) ethoxy] -2-methylpyridin-3-yl} -N-ethyl-N-methylimidoformamide, (15.155) N '-{5-bromo-6-[(cis -4-Isopro (Lucyclohexyl) oxy] -2-methylpyridin-3-yl} -N-ethyl-N-methylimidoformamide, (15.156) N ′-{5-bromo-6-[(trans-4-isopropylcyclohexyl) Oxy] -2-methylpyridin-3-yl} -N-ethyl-N-methylimidoformamide, (15.157) N-cyclopropyl-3- (difluoromethyl) -5-fluoro-N- (2-isopropyl) (Benzyl) -1-methyl-1H-pyrazole-4-carboxamide, (15.158) N-cyclopropyl-N- (2-cyclopropylbenzyl) -3- (difluoromethyl) -5-fluoro-1-methyl- 1H-pyrazole-4-carboxamide, (15.159) N- (2-tert-butylbenzyl) -N-cyclopropyl -3- (difluoromethyl) -5-fluoro-1-methyl-1H-pyrazole-4-carboxamide, (15.160) N- (5-chloro-2-ethylbenzyl) -N-cyclopropyl-3- ( Difluoromethyl) -5-fluoro-1-methyl-1H-pyrazole-4-carboxamide, (15.161) N- (5-chloro-2-isopropylbenzyl) -N-cyclopropyl-3- (difluoromethyl)- 5-fluoro-1-methyl-1H-pyrazole-4-carboxamide, (15.162) N-cyclopropyl-3- (difluoromethyl) -N- (2-ethyl-5-fluorobenzyl) -5-fluoro- 1-methyl-1H-pyrazole-4-carboxamide, (15.163) N-cyclopropyl-3- (difluoromethyl) -5-fur Oro-N- (5-fluoro-2-isopropylbenzyl) -1-methyl-1H-pyrazole-4-carboxamide, (15.164) N-cyclopropyl-N- (2-cyclopropyl-5-fluorobenzyl) -3- (difluoromethyl) -5-fluoro-1-methyl-1H-pyrazole-4-carboxamide, (15.165) N- (2-cyclopentyl-5-fluorobenzyl) -N-cyclopropyl-3- ( Difluoromethyl) -5-fluoro-1-methyl-1H-pyrazole-4-carboxamide, (15.166) N-cyclopropyl-3- (difluoromethyl) -5-fluoro-N- (2-fluoro-6- Isopropylbenzyl) -1-methyl-1H-pyrazole-4-carboxamide, (15.167) N-cyclopropyl 3- (Difluoromethyl) -N- (2-ethyl-5-methylbenzyl) -5-fluoro-1-methyl-1H-pyrazole-4-carboxamide, (15.168) N-cyclopropyl-3- (difluoro Methyl) -5-fluoro-N- (2-isopropyl-5-methylbenzyl) -1-methyl-1H-pyrazole-4-carboxamide, (15.169) N-cyclopropyl-N- (2-cyclopropyl- 5-methylbenzyl) -3- (difluoromethyl) -5-fluoro-1-methyl-1H-pyrazole-4-carboxamide, (15.170) N- (2-tert-butyl-5-methylbenzyl) -N -Cyclopropyl-3- (difluoromethyl) -5-fluoro-1-methyl-1H-pyrazole-4-carboxamide, (15.171 ) N- [5-Chloro-2- (trifluoromethyl) benzyl] -N-cyclopropyl-3- (difluoromethyl) -5-fluoro-1-methyl-1H-pyrazole-4-carboxamide, (15.172) ) N-cyclopropyl-3- (difluoromethyl) -5-fluoro
-1-methyl-N- [5-methyl-2- (trifluoromethyl) benzyl] -1H-pyrazole-4-carboxamide, (15.173) N- [2-chloro-6- (trifluoromethyl) benzyl ] -N-cyclopropyl-3- (difluoromethyl) -5-fluoro-1-methyl-1H-pyrazole-4-carboxamide, (15.174) N- [3-chloro-2-fluoro-6- (tri Fluoromethyl) benzyl] -N-cyclopropyl-3- (difluoromethyl) -5-fluoro-1-methyl-1H-pyrazole-4-carboxamide, (15.175) N-cyclopropyl-3- (difluoromethyl) -N- (2-ethyl-4,5-dimethylbenzyl) -5-fluoro-1-methyl-1H-pyrazole-4-carboxamide, (15. 76) N-cyclopropyl-3- (difluoromethyl) -5-fluoro-N- (2-isopropylbenzyl) -1-methyl-1H-pyrazole-4-carbothioamide, (15.177) 3- (difluoromethyl) ) -N- (7-fluoro-1,1,3-trimethyl-2,3-dihydro-1H-inden-4-yl) -1-methyl-1H-pyrazole-4-carboxamide, (15.178) 3 -(Difluoromethyl) -N-[(3R) -7-fluoro-1,1,3-trimethyl-2,3-dihydro-1H-inden-4-yl] -1-methyl-1H-pyrazole-4- Carboxamide, (15.179) 3- (difluoromethyl) -N-[(3S) -7-fluoro-1,1,3-trimethyl-2,3-dihydro-1H-inden-4-yl -1-methyl-1H-pyrazole-4-carboxamide, (15.180) N ′-(2,5-dimethyl-4-phenoxyphenyl) -N-ethyl-N-methylimidoformamide, (15.181) N '-{4-[(4,5-Dichloro-1,3-thiazol-2-yl) oxy] -2,5-dimethylphenyl} -N-ethyl-N-methylimidoformamide, (15.182) N -(4-Chloro-2,6-difluorophenyl) -4- (2-chloro-4-fluorophenyl) -1,3-dimethyl-1H-pyrazol-5-amine;

  All listed mixing partners of classifications (1) to (15) are suitable bases or acids and salts, especially physiologically acceptable, such as sodium, potassium, ammonium, etc., if that is possible by functional groups. It may be formed in the form of a salt.

  With respect to insecticides, acaricides and nematicides, the following substances can be used.

1) Acetylcholinesterase (AChE) inhibitors, such as carbamates, such as alanicarb, aldicarb, bendiocarb, benfuracarb, butocarboxyme, butoxycarboxym, carbaryl, carbofuran, carbosulfan, etiophencarb, fenobucarb, formethanate, furiocarb, isoprocarb, methiocarb , Mesomil, metorcarb, oxamyl, pyrimicarb, propoxyl, thiodicarb, thiophanox, triazamate, trimetacarb, XMC, and xylylcarb; Phos, Chlormefos, Chlorpyrifos, Chlorpi Phos-methyl, coumaphos, cyanophos, demeton-S-methyl, diazinon, dichlorvos / DDVP, dicrotophos, dimethoate, dimethylvinphos, disulfotone, EPN, ethion, etoprophos, fan fur, phenamiphos, fenitrothion, fenthion, phostiazeto, heptenophos, imiciaphos , Isofenphos, O- (methoxyaminothiophosphoryl) salicylic acid isopropyl, isoxathione, malathion, mecarbam, methamidophos, methidathion, mevinphos, monocrotophos, naredo, ometoate, oxydemeton methyl, parathion, parathion methyl, phentoate, forate, hosalon, Phosmet, phosphamidone, phoxime, pyrimiphos-methyl, propenophos, propetanephos, Prothiophos, pyraclofos, pyridafenthione, quinalphos, sulfotep, tebupyrimfos, temefos, terbufos, tetrachlorbinphos, thiometone, triazophos, trichlorfone and bamidthione;
2) GABA-dependent chloride channel antagonists such as cyclodiene organochlorines such as chlordane and endosulfan; or phenylpyrazoles (fiprols) such as (16.1) etiprole and (16.2) fipronil;
3) Sodium channel modulators / voltage-gated sodium channel blockers, such as pyrethroids such as acrinathrin, alletrin, d-cis-trans-allerin, d-trans-alletrin, bifenthrin, bioalletrin, bioalletrin S-cyclopentenyl isomers, Bioresmethrin, cycloprotorin, cyfluthrin, β-cyfluthrin, cyhalothrin, λ-cyhalothrin, γ-cyhalothrin, cypermethrin, α-cypermethrin, β-cypermethrin, θ-cypermethrin, ζ-cypermethrin, ciphenothrin [(1R ) -Trans isomer], deltamethrin, enpentrin [(EZ)-(1R) isomer), esfenvalerate, etofenprox, fenpropatoline, fenvalerate, flucitrinate, Lumethrin, τ-fulvalinate, halfenprox, imiprothrin, cadetrin, permethrin, phenothrin [(1R) -trans isomer], praretrin, pyrethrin (insecticidal chrysanthemum), resmethrin, silafluophene, tefluthrin, tetramethrin, tetramethrin [(1R) isomer ], Tralomethrin and transfluthrin; or DDT; or methoxychlor;
4) Nicotinic acetylcholine receptor (nAChR) agonists such as neonicotinoids such as (17.1) acetamiprid, (17.2) clothianidin, (17.3) dinotefuran, (17.4) imidacloprid, (17 .5) Nitenpyram, (17.6) thiacloprid and (17.7) thiamethoxam; or (17.8) nicotine; or (17.9) sulfoxafurol;
5) nicotinic acetylcholine receptor (nAChR) allosteric activators such as spinosins, such as (18.1) spinetoram and (18.2) spinosad;
6) Chloride channel activators such as avermectins / milbemycins such as abamectin, emamectin benzoate, lepimectin, and milbemectin;
7) Juvenile hormone mimetics such as juvenile hormone analogs such as hydroprene, quinoprene, and metoprene; or phenoxycarb; or pyriproxyfen;
8) Various non-specific (multi-site) inhibitors such as alkyl halides such as methyl bromide and other alkyl halides; or chloropicrin; or sulfuryl fluoride; or borax; or tartar;
9) selective feeding inhibitors such as pymetrozine; or flonicamid;
10) Tick growth inhibitors such as clofentezin, hexothiazox and difluvidazine; or etoxazole;
11) Microbial disruptors in the cell membrane of the digestive tract of insects, for example, Bacillus thuringiensis subspecies isralensis, Bacillus sphaericus, Bacillus sp. aizawai), Bacillus thuringiensis subspecies kurstaki, Bacillus thuringiensis subspecies tenebrionis and Bacillus thuringiensis subspecies B Protein: Cry1Ab, Cry1Ac, Cry1Fa, Cry2Ab, mCry3A, Cry3Ab, Cry3Bb, Cry34 / 35Ab1;
12) Inhibitors of mitochondrial ATP synthase, such as diafenthiuron; or organotin acaricides, such as azocyclotin, cyhexatin, and phenbutatin oxide; or propargite; or tetradiphone;
13) Oxidative phosphorylation uncouplers that act by blocking the proton gradient, such as chlorfenapyr, DNOC and sulfuramide;
14) Nicotinic acetylcholine receptor (nAChR) channel blockers such as bensultap, cartap hydrochloride, thiocyclam, and thiosultap-sodium;
15) Chitin biosynthesis inhibitors, type 0, such as bistrifluron, chlorfluazuron, diflubenzuron, flucycloxuron, flufenoxuron, hexaflumuron, lufenuron, novallon, nobiflumuron, teflubenzuron and triflumuuron;
16) Chitin biosynthesis inhibitors, type 1, such as buprofezin;
17) molting disruptors such as cyromazine;
18) ecdysone receptor agonists such as chromafenozide, halofenozide, methoxyphenozide and tebufenozide;
19) Octopamine receptor agonists such as Amitraz;
20) Mitochondrial complex III electron transport inhibitors, such as hydramethylnon; or acequinosyl; or fluacrylpyrim;
21) Mitochondrial complex I electron transport inhibitors such as METI-type acaricides such as phenazaquin, fenpyroximate, pyrimidifen, pyridaben, tebufenpyrad and tolfenpyrad; or rotenone (Delice);
22) Voltage-gated sodium channel blockers such as indoxacarb; or metaflumizone;
23) Inhibitors of acetyl-CoA carboxylase, such as tetronic and tetramic acid derivatives such as spirodiclofen, spiromesifen and spirotetramat;
24) Mitochondrial complex IV electron transport inhibitors such as phosphines such as aluminum phosphide, calcium phosphide, phosphine and zinc phosphide; or cyanide;
25) Mitochondrial complex II electron transport inhibitors, such as sienopyrafen and cyflumetofen;
28) Ryanodine receptor modulators such as diamides such as (19.1) chlorantraniliprole, (19.2) cyantraniliprole and (19.3) fulvendiamide.

  Additional active ingredients with unknown or unknown mechanism of action, such as aphidopropene, azadirachtin, bencrothiaz, benzoximate, biphenazate, bromopropyrate, quinomethionate, cryolite, dicophor, difluvidazine, fluenesulfone, flometokin, flufenelim , Fluphenoxystrobin, flufiprolol, fluopyram, flupirazifuron, fufenozide, heptafluthrin, imidacrotiz, iprodione, meperfluthrin, pikondin, piflumbide, pyrifluquinazone, pyriminostrobin, iodoflustrobin, iodine And further, Bacillus farmus (especially strain C); CM I-1582, such as, but not limited to, VOTiVO ™, BioNem, or the following known active compounds: 3-bromo-N- {2-bromo-4-chloro-6- [(1-Cyclopropylethyl) carbamoyl] phenyl} -1- (3-chloropyridin-2-yl) -1H-pyrazole-5-carboxamide (known from WO 2005/077934) and 1- {2-fluoro-4- Methyl-5-[(2,2,2-trifluoroethyl) sulfinyl] phenyl} -3- (trifluoromethyl) -1H-1,2,4-triazol-5-amine (known from WO 2006/043635), {1 '-[(2E) -3- (4-Chlorophenyl) prop-2-en-1-yl] -5-fluorospiro [indole- , 4'-piperidin] -1 (2H) -yl} (2-chloropyridin-4-yl) methanone (known from WO 2003/106457), 2-chloro-N- [2- {1-[(2E)- 3- (4-Chlorophenyl) prop-2-en-1-yl] piperidin-4-yl} -4- (trifluoromethyl) phenyl] isonicotinamide (known from WO 2006/003494), 3- (2,5 -Dimethylphenyl) -4-hydroxy-8-methoxy-1,8-diazaspiro [4.5] dec-3-en-2-one (known from WO 2009/049851), 3- (2,5-dimethylphenyl) -8-methoxy-2-oxo-1,8-diazaspiro [4.5] dec-3-en-4-ylethyl carbonate (known from WO 2009/049851), 4 (But-2-yn-1-yloxy) -6- (3,5-dimethylpiperidin-1-yl) -5-fluoropyrimidine (known from WO 2004/099160), 4- (but-2-yne-1- Yloxy) -6- (3-chlorophenyl) pyrimidine (known from WO 2003/076415), PF1364 (CAS registration number 1204776-60-2), 4- [5- (3,5-dichlorophenyl) -5- (trifluoromethyl) ) -4,5-dihydro-1,2-oxazol-3-yl] -2-methyl-N- {2-oxo-2-[(2,2,2-trifluoroethyl) amino] ethyl} benzamide ( WO 2005/085216), 4- {5- [3-chloro-5- (trifluoromethyl) phenyl] -5- (trifluoromethyl) -4 , 5-Dihydro-1,2-oxazol-3-yl} -N- {2-oxo-2-[(2,2,2-trifluoroethyl) amino] ethyl} -1-naphthamide (from WO 2009/002809) Known), methyl 2- [2-({[3-bromo-1- (3-chloropyridin-2-yl) -1H-pyrazol-5-yl] carbonyl} amino) -5-chloro-3-methylbenzoyl ] -2-Methylhydrazinecarboxylate (known from WO 2005/085216), methyl 2- [2-({[3-bromo-1- (3-chloropyridin-2-yl) -1H-pyrazol-5-yl] Carbonyl} amino) -5-cyano-3-methylbenzoyl] -2-ethylhydrazinecarboxylate (known from WO 2005/085216), methyl 2- [2- ( [3-Bromo-1- (3-chloropyridin-2-yl) -1H-pyrazol-5-yl] carbonyl} amino) -5-cyano-3-methylbenzoyl] -2-methylhydrazinecarboxylate (WO2005 / 085216), methyl 2- [3,5-dibromo-2-({[3-bromo-1- (3-chloropyridin-2-yl) -1H-pyrazol-5-yl] carbonyl} amino) benzoyl ] -2-ethylhydrazinecarboxylate (known from WO2005 / 085216), 1- (3-chloropyridin-2-yl) -N- [4-cyano-2-methyl-6- (methylcarbamoyl) phenyl] -3 -{[5- (trifluoromethyl) -2H-tetrazol-2-yl] methyl} -1H-pyrazole-5-carboxamide (W 2010-0669502), N- [2- (5-Amino-1,3,4-thiadiazol-2-yl) -4-chloro-6-methylphenyl] -3-bromo-1- (3-chloro Pyridin-2-yl) -1H-pyrazole-5-carboxamide (known from CN 102057925), 3-chloro-N- (2-cyanopropan-2-yl) -N- [4- (1,1,1,2 , 3,3,3-heptafluoropropan-2-yl) -2-methylphenyl] phthalamide (known from WO 2012/034472), 8-chloro-N-[(2-chloro-5-methoxyphenyl) sulfonyl]- 6- (Trifluoromethyl) imidazo [1,2-a] pyridine-2-carboxamide (known from WO 2010/129500), 8-chloro-N-[(2-chloro -5-methoxyphenyl) sulfonyl] -6- (trifluoromethyl) imidazo [1,2-a] pyridine-2-carboxamide (known from WO 2009/080250), N-[(2E) -1-[(6- Chloropyridin-3-yl) methyl] pyridin-2 (1H) -ylidene] -2,2,2-trifluoroacetamide (known from WO 2012/029672), 1-[(2-chloro-1,3-thiazole- 5-yl) methyl] -4-oxo-3-phenyl-4H-pyrido [1,2-a] pyrimidine-1-ium-2-olate (known from WO 2009/099929), 1-[(6-chloropyridine) -3-yl) methyl] -4-oxo-3-phenyl-4H-pyrido [1,2-a] pyrimidine-1-ium-2-olate (WO2009 / 99929), (5S, 8R) -1-[(6-chloropyridin-3-yl) methyl] -9-nitro-2,3,5,6,7,8-hexahydro-1H-5,8 -Epoxyimidazo [1,2-a] azepine (known from WO2010 / 069266), (2E) -1-[(6-chloropyridin-3-yl) methyl] -N'-nitro-2-pentylidenehydrazine carboxy Imidoamide (known from WO 2010/060231), 4- (3- {2,6-dichloro-4-[(3,3-dichloroprop-2-en-1-yl) oxy] phenoxy} propoxy) -2- Methoxy-6- (trifluoromethyl) pyrimidine (known from CN10133940), N- [2- (tert-butylcarbamoyl) -4-chloro-6-methylphenyl -1- (3-chloro-2-yl) -3- (fluoromethoxy)-1H-pyrazole-5-carboxamide formulations based on (from WO2008 / 134 969 known).

  The pesticide or a plurality of pesticides can be independently selected from the above substances, and can be combined in any possible form, but preferably at least one pesticide is isotianil, sedaxane, penflufen, azole fungicide , Especially tebuconazole, ipconazole, propiconazole or diphenoconazole, strobilurins, especially trifloxystrobin, azoxystrobin or picoxystrobin, penthiopyrad, metalaxyl, fludioxonil, thiazinyl, fipronil, fulvendiamide, chlorantranilip Roll, cyantraniliprole, imidacloprid, thiacloprid, thiamethoxam, clothianidin, spinosad, ethiprole or mixtures thereof, preferably isotianil and tri Loki cysts Robin, Isotianil and penflufen, are selected from a combination of penflufen and trifloxystrobin or Isotianil and acetamiprid. Particularly preferred is isotianil. Because these pesticides are compatible with rice-specific diseases and pests, and effectively prevent washing of these substances from seeds coated with the copolymer of the present invention, the present invention of rice seeds Particularly preferred for coating by.

  The seed coating may further comprise at least one colorant, surfactant, organic solvent and / or additional polymer or copolymer. Adding colorants such as red, green, blue, etc. makes it obvious to everyone that they are treating rice seeds, so there is a greater risk of unintentionally using coated rice for food purposes There is an advantage of lowering. In addition, the colorant can indicate that the coating remains on the seed surface during soaking and incubation. It is believed that the colorant can be selected, for example, not only by its color, but also by its bleeding behavior from the coating as long as it is similar to the pesticide used in the coating. Thus, the applicator can actually see that the coating has not actually been washed off. In this context, colorants can be used as a semi-quantitative criterion for bleeding behavior, for example by comparing the color of the seed before and after soaking using a color table showing the relationship between color and pesticide content. Spectroscopy can also be used for color intensity before and after immersion. Furthermore, the colorant can also show the appearance of the coating with respect to the uniformity of the coating across all seeds or between all seeds.

  The colorant used can be of visible color or a UV dye. If an inorganic colorant is used, it can simultaneously serve as a trace element source.

  The coating can have any possible structure or layer order. According to one preferred embodiment, the copolymer and pesticide are mixed before application to the seed, but in particular the coated rice seed is then treated with a further pesticide, preferably an insecticide. The pesticide mixed with the copolymer is preferably a fungicide.

  Alternatively, the copolymer and pesticide can be applied sequentially to the seed, but preferably the seed is first coated with one pesticide and then coated with the copolymer.

  The application rate of the copolymer can be varied within a wide range. The application rate is, for example, 0.001 to 2.5% by weight, in particular 0.01 to 1.25% by weight, preferably 0.025 to 1% by weight, based on the untreated seed weight.

  The application amount of the pesticide depends mainly on the required dose and can be adjusted by a person skilled in the art. In one example, the application rate of the pesticide is 0.001 to 5% by weight, in particular 0.01 to 2.5% by weight, preferably 0.05 to 1% by weight, based on the untreated seed weight. . Non-limiting examples of specific fungicides include isothianyl application rates from 0.05 to 2% by weight, in particular from 0.1 to 1% by weight, The application rate of Robin can be selected from 0.01 to 1% by weight, in particular from 0.05 to 0.5% by weight, each of which is relative to the untreated seed weight.

  The pesticide is in any usable form or formulation, to name a few, for example, solids such as (hydrated) powders, water-soluble formulations, liquid formulations, applicable liquids, aqueous suspensions, dispersions or It can be used as an emulsion or a microcapsule preparation. The formulation can be obtained by known methods, for example by mixing the pesticide with a developing agent, ie a liquid or solid diluent or carrier, and optionally with a surfactant, ie an emulsifier and / or a dispersant. In that case, water can be used as a developing agent and an organic solvent can be used as an auxiliary solvent, for example.

  In the present invention, an aqueous suspension of an agrochemical is preferable from the viewpoint of workability. As aqueous suspensions, in addition to agricultural chemicals, water, surfactants, liquid diluents (organic solvents) and polymer resins, especially acrylic resins ((co) polymer resins consisting of alkyl acrylates and / or alkyl methacrylates) ) Is particularly preferred from the viewpoint of sustained effect.

  Antifoaming agents, preservatives, thickeners, dispersants, antifreezing agents, and the like can be added to the agrochemical aqueous suspension as necessary. The preferred agrochemical content in the aqueous suspension composition is 1 to 50% by weight, in particular 5 to 40% by weight. The preferred surfactant content is 0.01 to 10% by weight, in particular 0.1 to 5% by weight. The preferred diluent content is 1 to 50% by weight, in particular 5 to 30% by weight. The preferred acrylic resin content is 0.1 to 20% by weight, in particular 1 to 10% by weight. For other points or components such as antifoams, preservatives and thickeners, the preferred total content is 0 to 10% by weight, in particular 0.1 to 5% by weight. A granular polymer resin is preferred as the polymer resin in the aqueous suspension composition, and those finely pulverized by pulverization or the like are particularly preferred.

Examples of liquid diluents or carriers include aromatic hydrocarbons (eg, xylene, toluene, alkylnaphthalene, etc.), chlorinated aromatic or chlorinated aliphatic hydrocarbons (eg, chlorobenzenes, ethylene chloride, chloride) Methylene etc.), aliphatic hydrocarbons [eg cyclohexane etc., paraffins (eg mineral oil fraction etc.)], alcohols (eg glycols such as butanol, ethylene glycol, propylene glycol etc.) C _2-10 alcohols And their ethers, esters, etc.), ketones (eg, acetone, methyl ethyl ketone, methyl isobutyl ketone, cyclohexanone, etc.), strong polar solvents (eg, dimethylformamide, dimethyl sulfoxide, etc.), water and the like. .

  Examples of solid diluents include ground natural minerals (eg kaolin, clay, talc, chalk, quartz, attapul guide, montmorillonite or diatomaceous earth), ground synthetic minerals (eg bentonite, silicic acid, alumina, silicate, silica sand). Etc.). Examples of solid carriers for granules include crushed and fractionated rocks (eg calcite, marble, pumice, gabbro, dolomite, etc.), synthetic particles of inorganic or organic powders, organic substances (eg sawdust, Examples include coconuts, corn cobs, tobacco stems, etc.).

  Examples of surfactants include nonionic and anionic emulsifiers [eg, polyoxyethylene fatty acid esters, polyoxyethylene fatty acid alcohol ethers (eg, alkylaryl polyglycol ethers, alkyl sulfonates, alkyl sulfates, aryl sulfonic acids) Salt, etc.), tristyrylphenols and their ethoxylates], and albumin hydrolysates.

  Examples of the dispersant include lignin sulfite waste liquid and methylcellulose.

  Sticking agents can also be added to the formulation (powder, granules, emulsions), examples of which are carboxymethylcellulose, natural or synthetic polymers (eg gum arabic, polyvinyl alcohols, polyvinyl acetates). Etc.).

  Colorants can also be used in the formulation, examples of which are inorganic pigments (eg iron oxide, titanium oxide, Prussian blue, etc.) and organic dyes such as alizarin dyes, azo dyes or metal phthalocyanine dyes In addition, trace elements such as metal salts such as iron, manganese, boron, copper, cobalt, molybdenum, and zinc can be cited.

  There is no restriction | limiting in particular about the method of providing the coating agent of this invention to a rice seed. The composition of the coating agent can be a liquid formulation, but the pesticide can be a solid and the copolymer can be a liquid. In such cases, the pesticide can be applied to the seed surface by a powder coating method, followed by a liquid coating method on the copolymer. The coating agent can be applied in one step, but it can also be applied in two or more steps if a further coating layer is to be applied.

  As a powder coating method, for example, there is a method in which rice seeds and agricultural chemicals are placed in a rotary drum and the drums are rotated to uniformly coat rice seeds with agricultural chemicals. Examples of methods for spraying pesticides include: (1) a method of spraying pesticides, copolymers or a mixture of both directly onto rice seeds falling from a hopper using an appropriate nozzle, and (2) a vibrating guide plate from the hopper to a nursery. A method of spraying pesticides, copolymers or a mixture of both on rice seeds using a suitable nozzle when the rice seeds jump while passing on a plate, and (3) a drum through which rice seeds pass through a hopper and a nursery There is a method of spraying pesticides, copolymers or a mixture of both on rice seeds that are placed between boxes and pass through a drum.

  As a method of spraying pesticides, copolymers or a mixture of both on rice seeds on a small scale, place rice seeds in a rotary machine such as a mortar mixer and put a predetermined dose of pesticides, copolymers or a mixture of both in a suitable sprayer The method of spraying uniformly can also be used. And furthermore, put the rice seeds in a plastic bag or a suitable container having a volume of 2 to 3 times the volume of rice seeds, add the pesticide, copolymer or a mixture of both, then close it (in the case of plastic bags, The bag is filled with air to inflate the bag and then the bag inlet is closed), shaken and stirred to spread the pesticide, copolymer or a mixture of both inside the container or bag. it can.

  When spraying large quantities of rice seeds, it is possible to install a spray nozzle in the middle of the means of transportation leading to a seeding machine for a nursery box that sprays pesticides, copolymers or a mixture of both. Thereafter, a mixing step and an appropriate drying step can be performed.

A further embodiment of the invention is a rice seed treatment, wherein the treatment comprises an ethylene-vinyl acetate copolymer and at least one pesticide.

  Rice seed treatments can have the modifications described above with respect to the methods of the invention without exception.

  Yet another embodiment of the present invention is a coated rice seed that is at least partially coated with the rice seed treating agent of the present invention.

  As described above, the coating of the present invention protects seeds from disease and pests with little effect on germination rate. Therefore, typical production of rice seeds known to the applicator including water soaking and incubation prior to sowing can be maintained. Preferably, the coated rice seeds of the present invention are of the same variety and plant age after immersion of the rice seeds in water at 25 ° C. and subsequent incubation of the soaked rice seeds at 7 ° C. for 144 hours (6 days). Compared to treated rice seeds, it shows an average germination rate reduction of 0 to 10%, preferably 0 to 5%. The seed immersion is performed, for example, by spreading 30 seeds on a tissue paper and spraying 50 mL of water on the paper. Next, the paper is wound up, placed in a sealed jar, and exposed to the above temperature and humidity conditions in a dark place, for example, in a refrigerator. The germination test is performed under the test conditions described above and the evaluation is performed by counting at least 30 randomly selected seeds. This test is performed on at least three samples immersed and incubated in different containers to calculate the average germination rate.

  Furthermore, coated rice seeds can be stored with little reduction of germination rate and / or reduced activity of pesticides over several months.

  The coated rice seeds of the present invention can be soaked in water with little loss of pesticides due to washing off or bleeding. Therefore, in a preferred embodiment of the present invention, the coated rice seed is 5% by weight or less compared to the total weight of the pesticide in the coating agent when immersed in water for 24 hours at 25 ° C. Is 3% by weight or less. Shows the release rate of pesticides. The pesticide is particularly selected from fungicides.

Another embodiment of the present invention is a method for protecting germinating seedlings of rice plants against fungal diseases and / or pests before planting, comprising:
a. Immersing the coated rice seed according to the invention in water, especially at least for 12 hours, preferably at a temperature of 10 to 40 ° C., more preferably at 20 to 30 ° C., and b. Optionally, incubating the soaked rice seeds for at least 36 hours, in particular for at least 72 hours,
Optionally, at least one further pesticide is applied to the rice seeds during soaking and / or incubation, wherein said further pesticide is in particular an insecticide, preferably thiamethoxam, imidacloprid, clothianidin or mixtures thereof. With this method it is possible to adjust the protection profile to the actual requirements, for example when the danger of insect pests is significant. For example, rice seeds can be sown after soaking in a nursery box (eg having a size of 60 cm × 30 cm × 3 cm) or after an appropriate incubation step. However, it is also within the scope of the present invention that rice seeds are sown directly to the field after soaking for cultivation or sown to a field nursery system for subsequent transplantation.

  Basically, there is no restriction on the soaking method of rice seeds. In the above method for protecting germinated seedlings, sufficient temperature for rice seeds is obtained at an integrated temperature of 60 to 140 ° C./day (eg, 13 to 14 ° C. for 7 to 10 days) It is preferable to absorb water. Incubation can be performed, for example, at 20 to 40 ° C., preferably 25 to 35 ° C. after immersion for at least 24 hours, preferably at least 72 or 132 hours.

  The method of seeding rice seeds in a nursery box, covering with soil, later generating rice seedlings, planting seedlings in paddy fields, and growing rice after transplanting is not particularly limited, and generally known methods can be employed. For example, after covering the seeds with soil, each nursery box is placed in a nursery cabinet, the seeds are germinated, and then the nursery box is moved to the nursery ridge for further growth. It is only necessary to transplant seedlings generated by using a tiller or the like to a paddy field. There is no restriction | limiting also about the growth method of the rice after transplanting to a paddy field, and a rice can be grown according to a conventional method.

  The coating agents of the present invention typically allow longer lasting protection compared to seeds directly coated with individual pesticides and can reduce the amount of pesticide required. For example, in the method according to the invention for protecting germinating seedlings of rice plants, disease and / or pest protection can still be observed for more than 50 days, especially for more than 60 days, from immersion and incubation seed transplantation. Typical diseases that provide protection are caused by filamentous fungi and / or microorganisms. Diseases in particular are rice blast disease (due to Pyrcularia oryzae), rice brown spot disease or rice head blight (due to Cochliobolus miyabeanus), rice blight (Rhizotonia ii). caused by solani), white leaf blight of rice (caused by Xanthomonas oryzae pv. oryzae), bacterial blast blight of rice (Burkholderia glumae) or combinations of these Selected from.

  In a further embodiment of the method for protecting germinating seedlings of the present invention, the pests are, in particular, rice weevil (Lissorhoptrus oryzophylus), rice dwarf oyster (Ourema oryzae kuwayama), Delphidae et rice leaf miner), Parnara guttata (rice skipper), Nanaga aenscens Moore, Canaphalocis medusaris, Cyprus medusaris Stenchaetothrips biformis) (a rice thrips) or animal pests combinations thereof.

  The invention is further illustrated based on the following examples.

Substances used:
Agrochemical formulation:
As an agrochemical, an aqueous preparation containing isotianil (200 g / L) and trifloxystrobin (80 g / L) was used. The formulation had a total water content of about 60% by weight and further contained a mixture of 2.5% by weight of red pigment and further additives such as antifoams, thickeners. This is further referred to below as “agrochemical formulation”.

Copolymer:
As the copolymer, an unplasticized aqueous copolymer dispersion was used.

Atlox ™ 1656: a product from Croda Crop Care, an unplasticized aqueous copolymer dispersion based on the following monomers: Monomer A
CAS No. 108-05-4, vinyl acetate _{C 4 H 6 O 2, AcO} -CH = CH 2
35-50%
Monomer B
CAS number 103-11-7, 2-ethylhexyl acrylate C ₁₁ H ₂₀ O ₂

25 to 55% soft (meth) acrylic acid monomer Monomer C
CAS No. 74-85-1, ethylene CH ₂ = CH ₂
5 to 25%.

  The percentile of monomers A + B + C is 100% in total.

  Furthermore, the copolymer itself does not contain acrylic acid, but the product does so because it can be added as part of the synthesis.

Monomer D
CAS number 79-10-7, acrylic acid C ₃ H ₄ O ₂

  Present from 0 to 5% in total product, ie copolymer dispersion.

  With acrylic acid first, the polymerization reaction can be initiated. This acrylic acid does not form part of the copolymer, but remains in the product, so it exists as a different acrylic acid polymer than the monomer and copolymer.

  The copolymer dispersion has a solids content of approximately 59 to 61% by weight (DIN EN ISO 3251; 30 minutes; 130 ° C.).

  The polymer produced has a Tg of -30 ° C. The dispersion contains neither plasticizer nor alkylphenol ethoxylate.

  Brookfield viscosity (DIN EN ISO2555; RVT; spindle number 4; 20 rpm, 25 ° C.)-lower limit-2,000 mPa · s, upper limit-mPa · s 10,000 mPa · s.

  pH value (DIN ISO976; 1: 1 with water)-lower limit -4.5, upper limit -6.5.

  Particle size in dispersion-lower limit-0.2 [mu] m, upper limit-2.0 [mu] m, Nd: YVO4 laser (Millenie II) and bialkali photocathode 4517 type (Fa. Measurement by laser-aerosol spectroscopy using Burle (calculated in the range of 80 nm to 550 nm).

  Minimum film forming temperature (MFFT) (DIN ISO 2115) -0 ° C.

Experiment:
Preparation of seed treatment formulation:
The following invention and comparative seed treatment formulations were prepared.

  In order to obtain a seed treatment formulation, the polymer dispersion was added to a 60 mL jar and an agrochemical formulation was added. The mixture was high shear mixed with IKA Ultra Turrax for 2 minutes at 9500 rpm before use and then rotated for 30 minutes.

Seed treatment In order to make coated rice seeds, 1.00 g of seed treatment formulation was added to 50.0 g of rice seeds in a baffled flask and rotated at room temperature for 30 minutes to uniformly spread the coating on the whole seed surface. . The application rate is equivalent to 20 g / kg dry rice seed on a liquid seed treatment formulation basis. “Dry” in that context means that the seed has a residual water content typical of rice seed, for example, 14% by weight or less. Since the seed treatment preparation is very strong in red, a uniform coating can be observed with the naked eye. Furthermore, the flask surface has little red color, which indicates that the seed treatment formulation adheres more strongly to the seed than to the glass. Thereafter, the seeds were spread on a flat plate and dried at room temperature for 1 day.

HPLC measurement of pesticide release in wash-off water To determine the adhesion of pesticides to rice seeds, coated dry seeds were immersed in water and incubation preparations, which is a typical method prior to sowing. During this procedure, a sample of immersion water was taken at a fixed time point and analyzed by HPLC for its content with respect to isotianil and trifloxystrobin.

  The concentration corresponding to the theoretical maximum release (100% by weight) was calculated to be 720 μg / mL and 288 μg / mL for isotianil and trifloxystrobin, respectively, and the release rate of these substances was related to these quantities.

  Examples 1 and 2 and Comparative Example 3 of the present invention containing the copolymer dispersion showed the following isotianil and trifloxystrobin release after 48 hours.

Example 1: 0.2 wt% isotianil; 0.8 wt% trifloxystrobin Example 2: 0.6 wt% isotianil; 1.3 wt% trifloxystrobin Example 3: 6.5 wt% isotianil 11.8% by weight trifloxystrobin.

  A comparison between Examples 1 and 2 shows that by reducing the copolymer concentration by 50% by weight, isotianil release increased from 0.3% to 0.6% after 48 hours and trifloxystrobin release was 48 hours. Later it increased from 1.0 to 1.3%, indicating that it corresponds to an increase in total active ingredient concentration from 5.3 to 8.0 μg / mL.

Germination test A germination test was also performed. Spread 30-40 amounts of rice seeds on tissue paper and spray 50 mL of water on the paper. The paper is then wound and placed in a sealed jar and exposed to 7 ° C. and about 55% relative humidity. Incubation is carried out for 144 hours (6 days) and the seeds are macroscopically germinated stages “no germination”, “slight germination (buds or roots <1 cm)”, “roots only (buds 5 mm)” and “sturdy roots and buds” Into groups.

The percent germination results from the test on triplicate samples for each candidate are summarized in Table 3 below.

  The percentage of seeds germinated in stages 1 to 3 in all treated seed batches was similar to the untreated control. Germination in all batches of stage 4 treated seeds was slightly lower compared to the untreated control (sample 1). However, the experiment shows that no significant difference can be observed by comparing Examples 1 and 2 of the present invention with Comparative Example 3.

CONCLUSION Two inventive examples (Examples 1 and 2) and one comparative example (Example 3) show that the inventive coating (i) has no adverse effect on germination, and (ii) It is robust and has improved wash-off resistance. The seed coating formulation of the present invention is stable, can be easily applied to the seed surface, and has little residue on the mixing machine parts.

Claims (28)

  A method for preparing a coated rice seed, wherein the seed coating agent is applied at least partially to the surface of a dried rice seed, the seed coating agent comprising at least an ethylene-vinyl acetate copolymer and at least one pesticide. And how to. The copolymer is at least the following monomer:
a. Vinyl acetate,
b. (Meth) acrylic acid monomer of the following general formula (I):

(Wherein R is a saturated or unsaturated organic group having at least 3 carbon atoms, R ′ is hydrogen or a methyl group), and c. The process according to claim 1, which is produced by reacting ethylene. The copolymer is at least:
a. 35 to 50% by weight vinyl acetate, in particular 38 to 48% by weight, preferably 40 to 45% by weight;
b. (Meth) acrylic acid monomer of the general formula (I) 25 to 55% by weight, in particular 30 to 50% by weight, preferably 35 to 45% by weight;
c. 5 to 25% by weight of ethylene, in particular 10 to 25% by weight, preferably 15 to 23% by weight; and d. 0 to 5% by weight of acrylic acid, in particular 0.1 to 4.5% by weight, preferably 0.5 to 4.0% by weight
The method according to claim 2, produced from   The substituent R has 4 to 15 carbon atoms, in particular 5 to 10, preferably n-butyl, n-pentyl, n-hexyl, cyclohexyl, isoheptyl, n-nonyl, n-decyl, isohexyl , Isobornyl, 2-ethyloctyl, isooctyl, 2-ethylhexyl, tetrahydrofurfuryl, ethoxyethoxyethyl, phenoxyethyl, cyclic trimethylpropane formal, 3,3,5-trimethylcyclohexyl, t-butylcyclohexyl and / or t-butyl 4. The method according to claim 2 or 3, which is selected.   The method according to any one of claims 1 to 4, wherein the copolymer is an ethylene-acrylic acid-2-ethylhexyl-vinyl acetate copolymer.   Glass transition temperature Tg-60 to 20 measured by dynamic differential scanning calorimetry according to the definition of Tg as the midpoint temperature using DIN 53765 at a heating rate of 20 K / min and tangent method and nitrogen as inert gas. The method according to any one of claims 1 to 5, wherein the method has a temperature of T and the Tg is particularly -10 ° C or less, preferably -20 ° C or less.   The method according to any one of claims 1 to 6, wherein the copolymer is applied to the seed in the form of a dispersion, in particular in the form of an aqueous dispersion, and the rice seed is dried after the coating agent is applied. .   The dispersion has a Brookfield viscosity of 1000 to 30,000 mPa · s, in particular 1,500 to 20,000 mPa · s as measured by DIN EN ISO 2555, RVT, spindle number 4 at 20 rpm and 25 ° C., preferably 2, The method according to claim 7, having a viscosity of 000 to 10,000 mPa · s.   9. The dispersion according to claim 7, wherein the dispersion has a solids content of 30 to 80% by weight, in particular 50 to 70% by weight, preferably 55 to 65% by weight, measured according to DIN EN ISO3251 at 130 ° C. for 30 minutes. The method described.   10. The dispersion according to claim 7, wherein the dispersion has a pH value of 4 to 7, in particular 4.5 to 6.5, measured according to DIN ISO 976 in a 1: 1 mixture with water. Method.   11. A method according to any one of claims 7 to 10, wherein the dispersion has an average particle size d50 of 0.1 to 5 [mu] m, in particular 0.2 to 2.0 [mu] m.   The method according to any one of claims 7 to 11, wherein the dispersion has a minimum film formation temperature of 0 ° C measured according to DIN ISO 2115.   The method according to any one of claims 7 to 12, wherein the dispersion contains little plasticizer and / or nonionic detergent, in particular little alkylphenol ethoxylate.   The pesticides are insecticides, fungicides, bactericides, viricides, acaricides, molluscicides, nematicides, egg killers, repellents, rodenticides, herbicides, safeners, fertilizers, 14. A method according to any one of claims 1 to 13 selected from the group comprising biological agents, or mixtures thereof. At least one pesticide is isotianil, sedaxane, penflufen, an azole fungicide, in particular tebuconazole, ipconazole, propiconazole or difenoconazole, strobilurins, in particular trifloxystrobin, azoxystrobin or picoxystrobin, penthiopyrad , Metalaxyl, fludioxonil, thiazinyl, fipronil, fulvendiamide, chlorantraniliprole, cyantraniliprole, imidacloprid, thiacloprid, thiamethoxam, clothianidin, spinosad, ethiprole or mixtures thereof, preferably a. Isotianil and trifloxystrobin,
b. Isotianil and penflufen,
c. Penflufen and trifloxystrobin, or d. 15. A method according to any one of claims 1 to 14 selected from a combination of isotianil and acetamiprid.   16. A method according to any one of claims 1 to 15, wherein the seed coating agent further comprises at least one colorant, surfactant, organic solvent and / or further polymer or copolymer.   17. The copolymer according to any one of claims 1 to 16, wherein the copolymer and the pesticide are mixed and then applied to the seed, in particular the coated rice seed is then treated with a further pesticide, preferably an insecticide. Method.   17. A method according to any one of claims 1 to 16, wherein the copolymer and the pesticide are applied to the seed sequentially, preferably the seed is first coated with at least one pesticide and coated with the copolymer.   The application amount of the copolymer is 0.001 to 2.5% by weight, in particular 0.01 to 1.25% by weight, preferably 0.025 to 1% by weight, based on the weight of the untreated seeds. The method according to any one of 18 to 18.   The application amount of the pesticide is 0.001 to 5% by weight, in particular 0.01 to 2.5% by weight, preferably 0.05 to 1% by weight, based on the weight of untreated seeds. The method according to any one of the above. A coated rice seed that is at least partially coated with a rice seed treating agent, wherein the rice seed treating agent comprises:
a. An ethylene-vinyl acetate copolymer and b. Coated rice seed containing at least one pesticide.   The rice seeds are soaked in water at 25 ° C., and then the soaked rice seeds are incubated for 144 hours at 7 ° C. and 55% relative humidity before being compared to untreated rice seeds of the same variety and plant age. 22. Coated rice seed according to claim 21, exhibiting an average germination rate reduction of from 10%.   The release rate of the pesticide when the rice seed is immersed in water at 25 ° C. for 24 hours without stirring is 5% by weight or less, particularly 3% by weight or less, compared to the total weight of the pesticide in the coating agent. 23. Coated rice seed according to claim 21 or 22, wherein the pesticide is selected in particular from fungicides. A method for protecting germinating seedlings of rice plants against fungal diseases and / or pests before planting,
a. Soaking the coated rice seed according to any one of claims 21 to 23 in water, in particular for at least 12 hours; and b. Optionally incubating said soaked rice seeds for at least 36 hours, in particular at least 72 hours,
Optionally, at least one further pesticide is applied to the rice seed during soaking and / or incubation, wherein the further pesticide is in particular an insecticide, preferably thiamethoxam, imidacloprid, clothianidin or mixtures thereof.   25. The method of claim 24, wherein the disease and / or pest protection is still observed over 50 days after transplantation of the soaked and incubated seeds.   26. A method according to claim 24 or 25, wherein the disease is caused by filamentous fungi and / or microorganisms.   The disease may be rice potato disease (due to Pyricularia oryzae), rice brown spot disease or rice head blight (due to Cochliobolus miyabeanus), rice blight (Rhizoctonia i olanie). )), Rice leaf blight (caused by Xanthomonas oryzae pv. Oryzae), rice blast blight (caused by Burkholderia glumae) or a combination thereof 27. A method according to any one of claims 24 to 26, which is selected.   Said pests, particularly rice water weevil (Lissorhoptrus oryzophilus), Inedorooimushi (Oulema oryzae Kuwayama), Delphacidae (planthopper), green rice leafhopper (Nephotettix cincticeps), Inemigiwabae (Hydrellia griseola) (rice leaf miner), parnara guttata (Parnara guttata) (rice skipper ), Naranga aenescens Moore, Cnaphacrocus medinalis, Chilo supressalis, Tenchaetopris biform 28. The method according to any one of claims 24 to 27, which is an animal pest selected from is) (rice trips) or a combination thereof.