JP2017501166A - 繊維材料を整形するための方法及びそのための処理組成物 - Google Patents
繊維材料を整形するための方法及びそのための処理組成物 Download PDFInfo
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- JP2017501166A JP2017501166A JP2016540567A JP2016540567A JP2017501166A JP 2017501166 A JP2017501166 A JP 2017501166A JP 2016540567 A JP2016540567 A JP 2016540567A JP 2016540567 A JP2016540567 A JP 2016540567A JP 2017501166 A JP2017501166 A JP 2017501166A
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- Prior art keywords
- hydroxyquinoline
- fiber material
- treatment composition
- acid
- iodo
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- 239000000203 mixture Substances 0.000 title claims abstract description 128
- 239000002657 fibrous material Substances 0.000 title claims abstract description 84
- 238000011282 treatment Methods 0.000 title claims abstract description 77
- 238000000034 method Methods 0.000 title claims abstract description 58
- 238000007493 shaping process Methods 0.000 title claims abstract description 22
- 239000011941 photocatalyst Substances 0.000 claims abstract description 38
- 239000002253 acid Substances 0.000 claims abstract description 29
- 230000005670 electromagnetic radiation Effects 0.000 claims abstract description 27
- 239000012190 activator Substances 0.000 claims abstract description 24
- 125000002915 carbonyl group Chemical group [*:2]C([*:1])=O 0.000 claims abstract description 21
- 239000000835 fiber Substances 0.000 claims description 25
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 claims description 21
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 15
- 239000005725 8-Hydroxyquinoline Substances 0.000 claims description 11
- 229960003540 oxyquinoline Drugs 0.000 claims description 11
- QSJXEFYPDANLFS-UHFFFAOYSA-N Diacetyl Chemical compound CC(=O)C(C)=O QSJXEFYPDANLFS-UHFFFAOYSA-N 0.000 claims description 10
- 238000010438 heat treatment Methods 0.000 claims description 9
- OJVAMHKKJGICOG-UHFFFAOYSA-N 2,5-hexanedione Chemical compound CC(=O)CCC(C)=O OJVAMHKKJGICOG-UHFFFAOYSA-N 0.000 claims description 8
- JOOXCMJARBKPKM-UHFFFAOYSA-N 4-oxopentanoic acid Chemical compound CC(=O)CCC(O)=O JOOXCMJARBKPKM-UHFFFAOYSA-N 0.000 claims description 8
- 150000001875 compounds Chemical class 0.000 claims description 7
- 150000001241 acetals Chemical class 0.000 claims description 6
- 150000001299 aldehydes Chemical class 0.000 claims description 5
- 150000001491 aromatic compounds Chemical class 0.000 claims description 5
- 150000002148 esters Chemical class 0.000 claims description 5
- 150000002373 hemiacetals Chemical class 0.000 claims description 5
- MVXVYAKCVDQRLW-UHFFFAOYSA-N 1h-pyrrolo[2,3-b]pyridine Chemical compound C1=CN=C2NC=CC2=C1 MVXVYAKCVDQRLW-UHFFFAOYSA-N 0.000 claims description 4
- VTERBIYJBWDXDT-UHFFFAOYSA-N 2-hydroxybutanedial Chemical compound O=CC(O)CC=O VTERBIYJBWDXDT-UHFFFAOYSA-N 0.000 claims description 4
- 150000001408 amides Chemical class 0.000 claims description 4
- 150000004649 carbonic acid derivatives Chemical class 0.000 claims description 4
- LEQAOMBKQFMDFZ-UHFFFAOYSA-N glyoxal Chemical compound O=CC=O LEQAOMBKQFMDFZ-UHFFFAOYSA-N 0.000 claims description 4
- UXZFQZANDVDGMM-UHFFFAOYSA-N iodoquinol Chemical compound C1=CN=C2C(O)=C(I)C=C(I)C2=C1 UXZFQZANDVDGMM-UHFFFAOYSA-N 0.000 claims description 4
- 150000002576 ketones Chemical group 0.000 claims description 4
- CQRYARSYNCAZFO-UHFFFAOYSA-N salicyl alcohol Chemical compound OCC1=CC=CC=C1O CQRYARSYNCAZFO-UHFFFAOYSA-N 0.000 claims description 4
- ZDASUJMDVPTNTF-UHFFFAOYSA-N 5,7-dibromo-8-quinolinol Chemical compound C1=CN=C2C(O)=C(Br)C=C(Br)C2=C1 ZDASUJMDVPTNTF-UHFFFAOYSA-N 0.000 claims description 3
- SUQZNPQQZDQDPJ-UHFFFAOYSA-N 5-iodoquinolin-8-ol Chemical compound C1=CN=C2C(O)=CC=C(I)C2=C1 SUQZNPQQZDQDPJ-UHFFFAOYSA-N 0.000 claims description 3
- 102000011782 Keratins Human genes 0.000 claims description 3
- 108010076876 Keratins Proteins 0.000 claims description 3
- 150000001266 acyl halides Chemical class 0.000 claims description 3
- CTQMJYWDVABFRZ-UHFFFAOYSA-N cloxiquine Chemical compound C1=CN=C2C(O)=CC=C(Cl)C2=C1 CTQMJYWDVABFRZ-UHFFFAOYSA-N 0.000 claims description 3
- WSFSSNUMVMOOMR-NJFSPNSNSA-N methanone Chemical compound O=[14CH2] WSFSSNUMVMOOMR-NJFSPNSNSA-N 0.000 claims description 3
- MCJGNVYPOGVAJF-UHFFFAOYSA-N quinolin-8-ol Chemical group C1=CN=C2C(O)=CC=CC2=C1 MCJGNVYPOGVAJF-UHFFFAOYSA-N 0.000 claims description 3
- NEUADDTXPYTNKT-UHFFFAOYSA-N (8-hydroxyquinolin-5-yl) thiocyanate Chemical compound C1=CN=C2C(O)=CC=C(SC#N)C2=C1 NEUADDTXPYTNKT-UHFFFAOYSA-N 0.000 claims description 2
- GOXNUYXRIQJIEF-UHFFFAOYSA-N 3-(2-hydroxyethyl)-1,3-oxazolidin-2-one Chemical group OCCN1CCOC1=O GOXNUYXRIQJIEF-UHFFFAOYSA-N 0.000 claims description 2
- XBHJTSIYYWRJFQ-MDZDMXLPSA-N 3-[(e)-2-phenylethenyl]phenol Chemical compound OC1=CC=CC(\C=C\C=2C=CC=CC=2)=C1 XBHJTSIYYWRJFQ-MDZDMXLPSA-N 0.000 claims description 2
- UNUZFXMRJIKULJ-UHFFFAOYSA-N 5-bromo-7-chloroquinolin-8-ol Chemical compound C1=CN=C2C(O)=C(Cl)C=C(Br)C2=C1 UNUZFXMRJIKULJ-UHFFFAOYSA-N 0.000 claims description 2
- IMYWOQVNTHOMNH-UHFFFAOYSA-N 5-bromo-7-iodoquinolin-8-ol Chemical compound C1=CN=C2C(O)=C(I)C=C(Br)C2=C1 IMYWOQVNTHOMNH-UHFFFAOYSA-N 0.000 claims description 2
- WIIUANWSGSTCLG-UHFFFAOYSA-N 5-bromoquinolin-8-ol Chemical compound C1=CN=C2C(O)=CC=C(Br)C2=C1 WIIUANWSGSTCLG-UHFFFAOYSA-N 0.000 claims description 2
- RXOMAZJOFNMVRA-UHFFFAOYSA-N 5-fluoro-7-iodoquinolin-8-ol Chemical compound C1=CN=C2C(O)=C(I)C=C(F)C2=C1 RXOMAZJOFNMVRA-UHFFFAOYSA-N 0.000 claims description 2
- YHXLEKUJMPEQAJ-UHFFFAOYSA-N 5-fluoroquinolin-8-ol Chemical compound C1=CN=C2C(O)=CC=C(F)C2=C1 YHXLEKUJMPEQAJ-UHFFFAOYSA-N 0.000 claims description 2
- BSQTUYCOTSTNLF-UHFFFAOYSA-N 6-hydroxynaphthalene-1-carbonitrile Chemical compound N#CC1=CC=CC2=CC(O)=CC=C21 BSQTUYCOTSTNLF-UHFFFAOYSA-N 0.000 claims description 2
- IYVMXMJAYLDUHH-UHFFFAOYSA-N 7-bromo-5-fluoroquinolin-8-ol Chemical compound C1=CN=C2C(O)=C(Br)C=C(F)C2=C1 IYVMXMJAYLDUHH-UHFFFAOYSA-N 0.000 claims description 2
- ICKPMTNGWVNOGC-UHFFFAOYSA-N 7-bromoquinolin-8-ol Chemical compound C1=CN=C2C(O)=C(Br)C=CC2=C1 ICKPMTNGWVNOGC-UHFFFAOYSA-N 0.000 claims description 2
- ZDYCNXPCDNJWCW-UHFFFAOYSA-N 7-chloro-5-fluoroquinolin-8-ol Chemical compound C1=CN=C2C(O)=C(Cl)C=C(F)C2=C1 ZDYCNXPCDNJWCW-UHFFFAOYSA-N 0.000 claims description 2
- JBTWPGVHNYETNF-UHFFFAOYSA-N 7-chloro-5-iodoquinolin-8-ol Chemical compound C1=CN=C2C(O)=C(Cl)C=C(I)C2=C1 JBTWPGVHNYETNF-UHFFFAOYSA-N 0.000 claims description 2
- LDCRHJNNQVTBNY-UHFFFAOYSA-N 7-fluoroquinolin-8-ol Chemical compound C1=CN=C2C(O)=C(F)C=CC2=C1 LDCRHJNNQVTBNY-UHFFFAOYSA-N 0.000 claims description 2
- UDGWTXRLMHXQKB-UHFFFAOYSA-N 7-hydroxynaphthalene-1-carbonitrile Chemical compound C1=CC=C(C#N)C2=CC(O)=CC=C21 UDGWTXRLMHXQKB-UHFFFAOYSA-N 0.000 claims description 2
- NFBPHZSDBOVNAL-UHFFFAOYSA-N 7-hydroxynaphthalene-2-carbonitrile Chemical compound C1=CC(C#N)=CC2=CC(O)=CC=C21 NFBPHZSDBOVNAL-UHFFFAOYSA-N 0.000 claims description 2
- AXKOGJAAENJJFI-UHFFFAOYSA-N 7-iodoquinolin-8-ol Chemical compound C1=CN=C2C(O)=C(I)C=CC2=C1 AXKOGJAAENJJFI-UHFFFAOYSA-N 0.000 claims description 2
- FJKUOCCQEBLPNX-UHFFFAOYSA-N 8-hydroxyquinoline N-oxide Chemical compound C1=C[N+]([O-])=C2C(O)=CC=CC2=C1 FJKUOCCQEBLPNX-UHFFFAOYSA-N 0.000 claims description 2
- 229920003043 Cellulose fiber Polymers 0.000 claims description 2
- QCDFBFJGMNKBDO-UHFFFAOYSA-N Clioquinol Chemical compound C1=CN=C2C(O)=C(I)C=C(Cl)C2=C1 QCDFBFJGMNKBDO-UHFFFAOYSA-N 0.000 claims description 2
- ZNZYKNKBJPZETN-WELNAUFTSA-N Dialdehyde 11678 Chemical compound N1C2=CC=CC=C2C2=C1[C@H](C[C@H](/C(=C/O)C(=O)OC)[C@@H](C=C)C=O)NCC2 ZNZYKNKBJPZETN-WELNAUFTSA-N 0.000 claims description 2
- WDFKMLRRRCGAKS-UHFFFAOYSA-N chloroxine Chemical compound C1=CN=C2C(O)=C(Cl)C=C(Cl)C2=C1 WDFKMLRRRCGAKS-UHFFFAOYSA-N 0.000 claims description 2
- 229940040102 levulinic acid Drugs 0.000 claims description 2
- HKUHOPQRJKPJCJ-UHFFFAOYSA-N pelargonidin Natural products OC1=Cc2c(O)cc(O)cc2OC1c1ccc(O)cc1 HKUHOPQRJKPJCJ-UHFFFAOYSA-N 0.000 claims description 2
- 235000006251 pelargonidin Nutrition 0.000 claims description 2
- GYESAYHWISMZOK-UHFFFAOYSA-N quinolin-5-ol Chemical compound C1=CC=C2C(O)=CC=CC2=N1 GYESAYHWISMZOK-UHFFFAOYSA-N 0.000 claims description 2
- OVYWMEWYEJLIER-UHFFFAOYSA-N quinolin-6-ol Chemical compound N1=CC=CC2=CC(O)=CC=C21 OVYWMEWYEJLIER-UHFFFAOYSA-N 0.000 claims description 2
- XCRPPAPDRUBKRJ-UHFFFAOYSA-N quinolin-7-ol Chemical compound C1=CC=NC2=CC(O)=CC=C21 XCRPPAPDRUBKRJ-UHFFFAOYSA-N 0.000 claims description 2
- MRUMAIRJPMUAPZ-UHFFFAOYSA-N quinolin-8-ol;sulfuric acid Chemical compound OS(O)(=O)=O.C1=CN=C2C(O)=CC=CC2=C1 MRUMAIRJPMUAPZ-UHFFFAOYSA-N 0.000 claims description 2
- 229920002994 synthetic fiber Polymers 0.000 claims description 2
- 239000012209 synthetic fiber Substances 0.000 claims description 2
- SMWDFEZZVXVKRB-UHFFFAOYSA-N Quinoline Chemical compound N1=CC=CC2=CC=CC=C21 SMWDFEZZVXVKRB-UHFFFAOYSA-N 0.000 claims 2
- UVEUKHPGKVTSOB-UHFFFAOYSA-N 5-iodo-1h-quinolin-2-one Chemical compound N1C(=O)C=CC2=C1C=CC=C2I UVEUKHPGKVTSOB-UHFFFAOYSA-N 0.000 claims 1
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- KTNLYTNKBOKXRW-UHFFFAOYSA-N phenyliodanium Chemical compound [IH+]C1=CC=CC=C1 KTNLYTNKBOKXRW-UHFFFAOYSA-N 0.000 description 1
- 125000003170 phenylsulfonyl group Chemical group C1(=CC=CC=C1)S(=O)(=O)* 0.000 description 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 1
- 239000011574 phosphorus Substances 0.000 description 1
- 229910000073 phosphorus hydride Inorganic materials 0.000 description 1
- 239000000906 photoactive agent Substances 0.000 description 1
- 238000007146 photocatalysis Methods 0.000 description 1
- 238000013032 photocatalytic reaction Methods 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 239000004926 polymethyl methacrylate Substances 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 229920001296 polysiloxane Polymers 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 150000003141 primary amines Chemical class 0.000 description 1
- 150000003856 quaternary ammonium compounds Chemical class 0.000 description 1
- 235000005875 quercetin Nutrition 0.000 description 1
- 229960001285 quercetin Drugs 0.000 description 1
- 239000002964 rayon Substances 0.000 description 1
- 239000012429 reaction media Substances 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- AZJPTIGZZTZIDR-UHFFFAOYSA-L rose bengal Chemical compound [K+].[K+].[O-]C(=O)C1=C(Cl)C(Cl)=C(Cl)C(Cl)=C1C1=C2C=C(I)C(=O)C(I)=C2OC2=C(I)C([O-])=C(I)C=C21 AZJPTIGZZTZIDR-UHFFFAOYSA-L 0.000 description 1
- 229940081623 rose bengal Drugs 0.000 description 1
- 229930187593 rose bengal Natural products 0.000 description 1
- STRXNPAVPKGJQR-UHFFFAOYSA-N rose bengal A Natural products O1C(=O)C(C(=CC=C2Cl)Cl)=C2C21C1=CC(I)=C(O)C(I)=C1OC1=C(I)C(O)=C(I)C=C21 STRXNPAVPKGJQR-UHFFFAOYSA-N 0.000 description 1
- 210000004761 scalp Anatomy 0.000 description 1
- 150000003335 secondary amines Chemical class 0.000 description 1
- 238000004088 simulation Methods 0.000 description 1
- WXMKPNITSTVMEF-UHFFFAOYSA-M sodium benzoate Chemical compound [Na+].[O-]C(=O)C1=CC=CC=C1 WXMKPNITSTVMEF-UHFFFAOYSA-M 0.000 description 1
- 235000010234 sodium benzoate Nutrition 0.000 description 1
- 239000004299 sodium benzoate Substances 0.000 description 1
- 241000894007 species Species 0.000 description 1
- 238000001228 spectrum Methods 0.000 description 1
- 235000019698 starch Nutrition 0.000 description 1
- 239000008107 starch Substances 0.000 description 1
- LYPVBFXTKUJYDL-UHFFFAOYSA-N sulfanium;trifluoromethanesulfonate Chemical compound [SH3+].[O-]S(=O)(=O)C(F)(F)F LYPVBFXTKUJYDL-UHFFFAOYSA-N 0.000 description 1
- 125000000475 sulfinyl group Chemical group [*:2]S([*:1])=O 0.000 description 1
- 125000001273 sulfonato group Chemical group [O-]S(*)(=O)=O 0.000 description 1
- RWSOTUBLDIXVET-UHFFFAOYSA-O sulfonium Chemical compound [SH3+] RWSOTUBLDIXVET-UHFFFAOYSA-O 0.000 description 1
- 150000003462 sulfoxides Chemical class 0.000 description 1
- 125000004434 sulfur atom Chemical group 0.000 description 1
- 230000001629 suppression Effects 0.000 description 1
- 230000008685 targeting Effects 0.000 description 1
- 230000002123 temporal effect Effects 0.000 description 1
- 150000003512 tertiary amines Chemical class 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 125000000101 thioether group Chemical group 0.000 description 1
- 150000003568 thioethers Chemical class 0.000 description 1
- 150000003573 thiols Chemical class 0.000 description 1
- JOXIMZWYDAKGHI-UHFFFAOYSA-N toluene-4-sulfonic acid Chemical compound CC1=CC=C(S(O)(=O)=O)C=C1 JOXIMZWYDAKGHI-UHFFFAOYSA-N 0.000 description 1
- 230000001988 toxicity Effects 0.000 description 1
- 231100000419 toxicity Toxicity 0.000 description 1
- 125000005409 triarylsulfonium group Chemical group 0.000 description 1
- AANIRNIRVXARSN-UHFFFAOYSA-M trifluoromethanesulfonate;trimethylsulfanium Chemical compound C[S+](C)C.[O-]S(=O)(=O)C(F)(F)F AANIRNIRVXARSN-UHFFFAOYSA-M 0.000 description 1
- HHMQUQRJNPTPAJ-UHFFFAOYSA-M trifluoromethanesulfonate;tris(4-tert-butylphenyl)sulfanium Chemical compound [O-]S(=O)(=O)C(F)(F)F.C1=CC(C(C)(C)C)=CC=C1[S+](C=1C=CC(=CC=1)C(C)(C)C)C1=CC=C(C(C)(C)C)C=C1 HHMQUQRJNPTPAJ-UHFFFAOYSA-M 0.000 description 1
- 125000001889 triflyl group Chemical group FC(F)(F)S(*)(=O)=O 0.000 description 1
- LZTRCELOJRDYMQ-UHFFFAOYSA-N triphenylmethanol Chemical class C=1C=CC=CC=1C(C=1C=CC=CC=1)(O)C1=CC=CC=C1 LZTRCELOJRDYMQ-UHFFFAOYSA-N 0.000 description 1
- WLOQLWBIJZDHET-UHFFFAOYSA-N triphenylsulfonium Chemical compound C1=CC=CC=C1[S+](C=1C=CC=CC=1)C1=CC=CC=C1 WLOQLWBIJZDHET-UHFFFAOYSA-N 0.000 description 1
- 239000012953 triphenylsulfonium Substances 0.000 description 1
- ZMOJTPABCOWEOS-UHFFFAOYSA-N tris(4-tert-butylphenyl)sulfanium Chemical compound C1=CC(C(C)(C)C)=CC=C1[S+](C=1C=CC(=CC=1)C(C)(C)C)C1=CC=C(C(C)(C)C)C=C1 ZMOJTPABCOWEOS-UHFFFAOYSA-N 0.000 description 1
- 239000000341 volatile oil Substances 0.000 description 1
- 239000002025 wood fiber Substances 0.000 description 1
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Abstract
Description
本発明の処理組成物は、活性剤及び光触媒を含む。処理組成物は任意で、キャリアを更に含む。本発明の目的のために、処理組成物は、使用前に連続して希釈される濃縮組成物、及び使用できる状態である希釈組成物を包含する。
本発明の活性剤は、酸でないカルボニル又は酸でないカルボニルの等価物を含む。酸でないカルボニルとしては、一般に、官能基の一部として、少なくとも1つのカルボニル基を有する有機化学種であって、この官能基はカルボン酸ではない有機化学種が挙げられる。カルボン酸部分のより高い極性は、特に、酸が共役塩基の形態にあり、正の電荷を運搬するpHにおいて、繊維材料内への拡散を制限すると考えられる。本明細書で記載される酸でないカルボニルは、極性がより低く、いずれのpHでも形式電荷を運搬しない。酸でないカルボニルは、酸でないカルボニルと比較して、より容易に繊維材料に浸透すると考えられる。酸でないカルボニル官能基の非限定例としては、ケトン、エステル、アルデヒド、アミド、ハロゲン化アシル、及びカルボネートが挙げられる。酸でないカルボニルの等価物としては、アセタール、ヘミアセタール、ケタール、及びヘミケタールが挙げられる。
R−C(=O)−R
(式中、RはC1〜C32アルキル、C1〜C32置換アルキル、C5〜C32又はC6〜C32アリール、C5〜C32又はC6〜C32置換アリール、C6〜C32アルキルアリール、C6〜C32置換アルキルアリール、C1〜C32ヒドロキシ、C1〜C32アルコキシ、C1〜C32置換アルコキシ、C1〜C32アルキルアミノ、及びC1〜C32置換アルキルアミノからなる群から独立して選択され、Rは、P、N、S、B及びOからなる群から選択される少なくとも1つのヘテロ原子を更に含んでもよい)として描写され得る。
R−C(=O)−O−R
(式中、RはC1〜C32アルキル、C1〜C32置換アルキル、C5〜C32又はC6〜C32アリール、C5〜C32又はC6〜C32置換アリール、C6〜C32アルキルアリール、C6〜C32置換アルキルアリール、C1〜C32ヒドロキシ、C1〜C32アルコキシ、C1〜C32置換アルコキシ、C1〜C32アルキルアミノ、及びC1〜C32置換アルキルアミノからなる群から独立して選択され、Rは、P、N、S、B及びOからなる群から選択される少なくとも1つのヘテロ原子を更に含んでもよい)として描写され得る。
R−C(=O)−H
(式中、RはC1〜C32アルキル、C1〜C32置換アルキル、C5〜C32又はC6〜C32アリール、C5〜C32又はC6〜C32置換アリール、C6〜C32アルキルアリール、C6〜C32置換アルキルアリール、C1〜C32ヒドロキシ、C1〜C32アルコキシ、C1〜C32置換アルコキシ、C1〜C32アルキルアミノ、及びC1〜C32置換アルキルアミノからなる群から選択され、Rは、P、N、S、B及びOからなる群から選択される少なくとも1つのヘテロ原子を更に含んでもよい)として描写され得る。
R−C(=O)−N−R’R”
(式中、RはC1〜C32アルキル、C1〜C32置換アルキル、C5〜C32又はC6〜C32アリール、C5〜C32又はC6〜C32置換アリール、C6〜C32アルキルアリール、C6〜C32置換アルキルアリール、C1〜C32ヒドロキシ、C1〜C32アルコキシ、C1〜C32置換アルコキシ、C1〜C32アルキルアミノ、及びC1〜C32置換アルキルアミノからなる群から選択され、Rは、P、N、S、B及びOからなる群から選択される少なくとも1つのヘテロ原子を更に含んでもよく;
R’及びR”は、−H、C1〜C32アルキル、C1〜C32置換アルキル、C5〜C32又はC6〜C32アリール、C5〜C32又はC6〜C32置換アリール、C6〜C32アルキルアリール、C6〜C32置換アルキルアリール、C1〜C32ヒドロキシ、C1〜C32アルコキシ、C1〜C32置換アルコキシ、C1〜C32アルキルアミノ、及びC1〜C32置換アルキルアミノ、−OH、−NH2、及び=NHからなる群から独立して選択される)として描写され得る。
R−C(=O)−X
(式中、RはC1〜C32アルキル、C1〜C32置換アルキル、C5〜C32又はC6〜C32アリール、C5〜C32又はC6〜C32置換アリール、C6〜C32アルキルアリール、C6〜C32置換アルキルアリール、C1〜C32ヒドロキシ、C1〜C32アルコキシ、C1〜C32置換アルコキシ、C1〜C32アルキルアミノ、及びC1〜C32置換アルキルアミノからなる群から選択され、Rは、P、N、S、B及びOからなる群から選択される少なくとも1つのヘテロ原子を更に含んでもよく;
XはF、Cl、Br、及びIからなる群から選択される)として描写され得る。
R−O−C(=O)−O−R
(式中、RはC1〜C32アルキル、C1〜C32置換アルキル、C5〜C32又はC6〜C32アリール、C5〜C32又はC6〜C32置換アリール、C6〜C32アルキルアリール、C6〜C32置換アルキルアリール、C1〜C32ヒドロキシ、C1〜C32アルコキシ、C1〜C32置換アルコキシ、C1〜C32アルキルアミノ、及びC1〜C32置換アルキルアミノからなる群から選択され、Rは、P、N、S、B及びOからなる群から選択される少なくとも1つのヘテロ原子を更に含んでもよい)として描写され得る。本発明のカルボネートは、好ましくは環状でない。
R’及びR”は、−H、C1〜C32アルキル、C1〜C32置換アルキル、C5〜C32又はC6〜C32アリール、C5〜C32又はC6〜C32置換アリール、C6〜C32アルキルアリール、C6〜C32置換アルキルアリール、C1〜C32ヒドロキシ、C1〜C32アルコキシ、C1〜C32置換アルコキシ、C1〜C32アルキルアミノ、及びC1〜C32置換アルキルアミノからなる群から独立して選択され;R’及びR”は、両方が水素原子ではない)として描写され得る。当業者であれば、ヘミアセタールは、含まれるR’及びR”のうちの少なくとも1つが水素原子であることを理解するであろう。
R’及びR”は、−H、C1〜C32アルキル、C1〜C32置換アルキル、C5〜C32又はC6〜C32アリール、C5〜C32又はC6〜C32置換アリール、C6〜C32アルキルアリール、C6〜C32置換アルキルアリール、C1〜C32ヒドロキシ、C1〜C32アルコキシ、C1〜C32置換アルコキシ、C1〜C32アルキルアミノ、及びC1〜C32置換アルキルアミノからなる群から独立して選択され;R’及びR”は、両方が水素原子ではない)として描写され得る。当業者であれば、ヘミケタールは、含まれるR’及びR”のうちの少なくとも1つが水素原子であることを理解するであろう。
光触媒は、電磁放射線に曝露した際に減少(又は増加)するpKa(又はpKb)値を有する任意の光酸若しくは光塩基(又はこれらの複合体)であり得る。電磁放射線は、pKa又はpKbがそれぞれ減少又は増加する任意の好適な波長の電磁放射線であってもよく、好ましくは約300nm〜約750nmの範囲にある。例えば、電磁放射線は、周辺光(ambient light)、日光、白熱光、蛍光、LED光、レーザー光、太陽光、及びこれらに類するものであり得る。電磁放射線は、電磁スペクトルに沿った任意の分類に属してもよいが、好ましくは可視光である。当業者には、光の適切な波長(単一又は複数)は、用いられる1つ以上の光触媒の固有性に依存することが容易に明らかであろう。
ヒドロキシフラボン及びその誘導体;好ましくは、ヒドロキシルフラボン、ジヒドロキシフラボン、トリヒドロキシフラボン、テトラヒドロキシフラボン;より好ましくは、3−ヒドロキシフラボン、7−ヒドロキシフラボン、5,7−ヒドロキシフラボン、4’,5,7−トリヒドロキシフラボン、及びクエルセチン;
ヒドロキシルトリアリールメタン、好ましくは、FD&Cグリーン3;
アントシアニジン及びアントシアニン;好ましくは、シアニジン、マルビジン、パラルゴニジン(palargonidin)、及びアントシアニンを含有する抽出物、例えばニワトコ(elderberry)、ブルーベリー、クランベリー、ビルベリー、赤キャベツ、サトウモロコシ、クロイチゴ(blackberry)、クロスグリ(black current)、サクランボ、赤及び黒のラズベリーを挙げてもよい。
本明細書に記載される組成物は、任意で、及び好ましくは、キャリアを更に含み、このキャリアは、活性剤、光触媒、及び任意の他の成分を運搬(carry)し、分散し、又は溶解して、処理組成物の製造及び/又は繊維材料上への処理組成物の塗布を促進するのに適する。キャリアは、溶媒、乳化剤、界面活性剤、又はその他の分散剤のうちの1つ以上を含んでもよい。キャリアは更に、生理学的に許容可能なキャリアであってもよい。好適なキャリアの特性は、少なくとも部分的には、組成物の他の成分及び改質される基材の特性に依存する。
本明細書に記載される処理組成物及び方法は、任意で様々な成分を含んでもよく、この成分は、処理組成物の性質に依存するであろう。処理組成物は、好ましくはコンシューマ製品組成物であり、より好ましくは、パーソナルケア製品組成物又は家庭用ケア組成物である。例えば、様々な態様では、本明細書に記載される処理組成物及び方法は、界面活性剤、乳化剤、酸化剤、還元剤、pH調整剤、皮膚軟化剤、湿潤剤、タンパク質、ペプチド、アミノ酸、添加ポリマー、つや出し剤、油及び/若しくは脂肪酸、潤滑剤、金属イオン封鎖剤/キレート剤、帯電防止剤、レオロジー調整剤、感触改良剤(feel agents)、充填剤、染料、防腐剤、香料、その他の機能性成分、又はこれらの組み合わせを含んでもよい。特定の任意の成分は、CTFA International Cosmetic Ingredient Dictionary、第10版、2004、及びMcCutcheon、Detergents and Emulsifiers、North American Edition(1986)に見出だされ得る。当業者には、利用される特定の任意成分が、少なくとも部分的には、組成物及び方法の特定の用途に依存することが容易に明らかである。
液体洗濯洗剤、例えば米国特許出願公開第2012/0324653号明細書に詳細に記載されるもの;
粒状洗濯洗剤、例えば米国特許第7,605,116号に詳細に記載されるもの;
単位用量(unit dose)洗濯洗剤、例えば国際公開第2013/039964号パンフレット、国際公開第2006/057905号パンフレット、国際公開第2006/130647号パンフレットに詳細に記載されるもの;
液体布地柔軟剤、例えば米国特許第7,135,451号、米国特許第6,369,025号及び米国特許第6,492,322号に詳細に記載されるもの;
乾燥機添加布地柔軟シート、例えば米国特許第6,787,510号に詳細に記載されるもの;
布地処理スプレー、例えば米国特許第5,939,060号、国際公開第01/88076号パンフレット、米国特許出願公開第2009/0038083号明細書、及び米国特許第6,573,233号に詳細に記載されるもの;
ヘアシャンプー、例えば米国特許出願公開第2013/0080279号明細書に詳細に記載されるもの;
ヘアコンディショナー、例えば米国特許第8,017,108号に詳細に記載されるもの;
ヘアスタイリング組成物、例えば米国特許出願公開第2009/0061004号明細書及び欧州特許第2570192号に詳細に記載されるもの;
マスカラ組成物を含む化粧品、例えば米国特許出願公開第2012/0114585号明細書に詳細に記載されるものが挙げられる。
本発明は更に、繊維材料を整形するための方法であって、活性剤及び光触媒を含む処理組成物を準備する工程と、処理組成物を繊維材料に塗布して、処理された繊維材料を形成する工程と、処理された繊維材料を機械的に整形する工程と、処理された繊維材料を電磁放射線に曝露する工程と、を含む方法を包含する。好適な処理組成物としては、本明細書でここまでに記載された処理組成物が挙げられる。処理組成物を繊維材料に塗布する工程、及び繊維材料を機械的に整形する工程は、いずれの順番でも実施できることに注意すべきである。
本発明の方法は、用具を利用して、機械的に繊維材料を整形し、電磁放射線を供給し、及び/又は熱を供給できる。繊維材料の機械的整形に関して、用具は任意の器具、装置、又は付属器官(appendage)であってもよく、その使用によって、繊維材料は整形され得る。例えば、用具はヘアストレート器具であってもよい。ヘアストレート器具は、光源及び/又は加熱要素を含んでもよい。好適なヘアストレート器具は、「APPLIANCE FOR SHAPING FIBROUS MATERIAL」、R.P.Washingtonら、米国特許出願番号第__/___,___号(代理人事件番号CM4017FPQ)に詳細に記載されている。このような器具は、電磁放射線を供給する光源及び加熱要素を含む。この種の器具は、機械的に繊維材料を整形し、電磁放射線を供給し、かつ熱を供給するために使用され得る(例えばオールインワンの器具)。
本発明は更に、活性剤及び光触媒を含む処理組成物と、繊維材料を機械的に整形し、電磁放射線を供給し、及び/又は熱を供給するための器具と、を含むキットに関する。本発明のキットでの使用に適する処理組成物及び器具は、本明細書でここまでに記載されている。
2 Rohm & Haasから入手可能なAcusol 823
3 Momentive Performance Materials Inc.から入手可能なエポキシアミノシランコポリマー
4 実施例Eは固体の処理組成物であり、丸括弧内の重量パーセント値は、固体組成物が水に溶解した後の量を表す。
毛髪を真っ直ぐにする有効性は、下記のテスト方法を使用して評価される。隆起の低い(low lift)天然カールヘアのヘアピース(switch)を用いる。これらを、Pantene浄化シャンプー(clarifying shampoo)で洗髪して、毛髪が清潔な状態にあり、最終結果に影響し得る残留物がないことを確実にする。その後、ヘアピースをすすぐ。過剰の水は、ヘアピースを絞ることによって、毛髪から除去される。ヘアピースを、暗室内で予め調製され、pH10に緩衝された本発明の処理組成物で処理する。処理組成物の成分を、スピナープレート(spinner plate)上で30分間混合する。処理組成物を、琥珀色の瓶、又は絶縁テープ(electrical tape)で覆われた瓶内に保管し、処理組成物に光が確実に接近しないようにする。毛髪1g当たり0.25gの処理組成物を用いる。処理組成物を、毛髪上に30分間残す。対照として、処理組成物をヘアピースに塗布しないことを除き、正確に同じようにヘアピースを処理する。対照のヘアピースを、湿った状態で30分間静置する。この時間の後、毛髪をブロー乾燥させ、ブラッシングする。その後、ハイブリッドの光及び熱を発するストレートアイロンを8回通し、ヘアピースを機械的に真っ直ぐにする。その後、ヘアピースを撮像(image)する。その後、耐久性の模擬実験をするために、ヘアピースに1回の洗浄及び乾燥サイクルを与える。1回の洗浄及び乾燥サイクルは、Hairtritionシャンプー(ZotosのHairtrition Color Protectのスルフェートを含まないシャンプー)での洗髪、すすぎ、及びその後の高温の箱(hot box)内での乾燥を伴う。乾燥すると、ヘアピースを再度撮像する。その後、ヘアピースに更に4回の洗浄及び乾燥サイクルを与える。乾燥すると、ヘアピースを再度撮像する。専門の採点者が、ヘアピースの画像に0〜10の等級でスコアを与える。等級は、標準の等級であり、4〜5個のカールの節(node)を有するカールした毛髪はスコア0であり、非常に真っ直ぐな毛髪は10であるとして設定される。したがって、ヘアピースは毛髪の通常の状態と比較される。専門の採点者は、一貫した方法で、ストレートからカールまでの毛髪の構成の測定/等級付けについて訓練されているので、信頼できる。
下記のテスト方法を利用して、本発明の処理組成物について、布地のしわの出現を減少する能力を評価する。ワイシャツを、Land’s End Companyから、Men’s Regular Long Sleeve Button−down Solid Pinpoint Shirtとして、ラージサイズで得る(品番245195)。従来の自動洗濯/乾燥機でワイシャツを洗浄し、すすぎ、かつ乾燥させ、処理の前に、乾燥機の底部に静置する。
Claims (16)
- 繊維材料を整形するための方法であって、
(a)
(i)酸でないカルボニル又は酸でないカルボニルの等価物を含む活性剤と、
(ii)光触媒と、
を含む処理組成物を準備する工程と、
(b)前記処理組成物を繊維材料に塗布して、処理された繊維材料を形成する工程と、
(c)前記処理された繊維材料を機械的に整形する工程と、
(d)前記処理された繊維材料を電磁放射線に曝露する工程と、
を含む、方法。 - 前記活性剤は、分子量が1000g/mol未満、好ましくは500g/mol未満、より好ましくは300g/mol未満である、請求項1に記載の方法。
- 前記電磁放射線は、波長が300nm〜750nmである、請求項1又は2に記載の方法。
- 前記光触媒が光酸であり、好ましくはヒドロキシル置換芳香族化合物である、請求項1〜3のいずれか一項に記載の方法。
- 前記繊維材料を機械的に整形する工程が、用具、好ましくは、白熱灯、蛍光灯、LED光、レーザー光、太陽光、及びこれらの組み合わせからなる群から選択される光源を含む用具を使用することを含む、請求項1〜4のいずれか一項に記載の方法。
- 前記光触媒が、8−ヒドロキシキノリン、8−ヒドロキシキノリンスルフェート、8−キノリノール−1−オキシド、5−ヒドロキシキノリン、6−ヒドロキシキノリン、7−ヒドロキシキノリン、5−ヨード−7−スルホ−8−ヒドロキシキノリン、5−フルオロ−8−ヒドロキシキノリン、5−フルオロ−7−クロロ−8−ヒドロキシキノリン、5−フルオロ−7−ブロモ−8−ヒドロキシキノリン、5−フルオロ−7−ヨード−8−ヒドロキシキノリン、7−フルオロ−8−ヒドロキシキノリン、5−クロロ−8−ヒドロキシキノリン、5,7−ジクロロ−8−ヒドロキシキノリン、5−クロロ−7−ブロノ−8−ヒドロキシキノリン、5−クロロ−7−ヨード−8−ヒドロキシキノリン、7−クロロ−8−ヒドロキシキノリン、5−ブロモ−8−ヒドロキシキノリン、5−ブロモ−7−クロロ−8−ヒドロキシキノリン、5,7−ジブロモ−8−ヒドロキシキノリン、5−ブロモ−7−ヨード−8−ヒドロキシキノリン、7−ブロモ−8−ヒドロキシキノリン、5−ヨード−8−ヒドロキシキノリン、5−ヨード−7−クロロ−8−ヒドロキシキノリン、5,7−ジヨード−8−ヒドロキシキノリン、7−ヨード−8−ヒドロキシキノリン、5−スルホン酸−8−ヒドロキシキノリン、7−スルホン酸−8−ヒドロキシキノリン、5−スルホン酸−7−ヨード−8−ヒドロキシキノリン、5−チオシアノ−8−ヒドロキシキノリン、5−クロロ−8−ヒドロキシキノリン、5−ブロモ−8−ヒドロキシキノリン、5,7−ジブロモ−8−ヒドロキシキノリン、5−ヨード−8−ヒドロキシキノリン、5,7−ジヨード−8−ヒドロキシキノリン、7−アザインドール、7−シアノ−2−ナフトール、8−シアノ−2−ナフトール、5−シアノ−2−ナフトール、1−ヒドロキシ−3,6,8−ピレントリスルホン酸、トランス−3−ヒドロキシスチルベン、2−ヒドロキシメチルフェノール、ペラルゴニジン、及びこれらの混合物からなる群から選択される、請求項1〜5のいずれか一項に記載の方法。
- 前記繊維材料が、ケラチン繊維、セルロース繊維、合成繊維、及びこれらの組み合わせからなる群から選択される、請求項1〜6のいずれか一項に記載の方法。
- 前記方法が、前記処理された繊維材料の温度を、40℃〜150℃の温度に上昇させる工程を更に含む、請求項1〜7のいずれか一項に記載の方法。
- 前記処理組成物が、ホルムアルデヒド、ホルムアルデヒドの誘導体、ホルマリン、及び加熱時にホルムアルデヒドを生じる任意の化合物を実質的に含まない、請求項1〜8のいずれか一項に記載の方法。
- 前記処理組成物が、キャリア、好ましくは水を更に含む、請求項1〜9のいずれか一項に記載の方法。
- 前記活性剤が、ケトン、エステル、アルデヒド、アミド、ハロゲン化アシル、カルボネート、アセタール、ヘミアセタール、ケタール、ヘミケタール、及びこれらの混合物からなる群から選択される、請求項1〜10のいずれか一項に記載の方法。
- 前記活性剤が、3−(2−ヒドロキシエチル)−2−オキサゾリジノン、ヘキサン−2,5−ジオン、ブタン−2,3−ジオン、エタンジアール、2−ヒドロキシ−ブタンジアール、4−オキソ−ペンタン酸、これらの異性体、これらの誘導体、及びこれらの混合物からなる群から選択される、請求項1〜11のいずれか一項に記載の方法。
- 前記活性剤が、アセトニルアセトン、2,3−ブタンジオン、ジアルデヒド、レブリン酸、及びこれらの混合物からなる群から選択される、請求項1〜11のいずれか一項に記載の方法。
- 前記処理組成物が、不透明なパッケージ内にパッケージ化される、請求項1〜13のいずれか一項に記載の方法。
- (a)酸でないカルボニル又は酸でないカルボニルの等価物を含む活性剤と、
(b)光触媒と、
を含む処理組成物の、繊維材料を整形するための使用。 - (a)
(i)酸でないカルボニル又は酸でないカルボニルの等価物を含む活性剤と、
(ii)光触媒と、
を含む、処理組成物と、
(b)繊維材料を機械的に整形し、電磁放射線を与え、及び/又は熱を与えるための器具と、
を含むキット。
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WO (1) | WO2015094788A1 (ja) |
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JP2017501161A (ja) * | 2013-12-19 | 2017-01-12 | ザ プロクター アンド ギャンブル カンパニー | −c(=o)−、−c(=o)−h、及び−c(=o)−o−からなる群から選択される官能基を含む活性剤を使用した、ケラチン繊維の成形 |
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EP3082736B1 (en) | 2013-12-19 | 2018-08-08 | The Procter and Gamble Company | Shaping keratin fibres using 2-hydroxypropane-1,2,3-tricarboxylic acid and/or 1,2,3,4-butanetetracarboxylic acid |
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MX2016007779A (es) | 2013-12-19 | 2016-09-07 | Procter & Gamble | Formacion de fibras de queratina mediante el uso de ester de carbonato. |
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WO2016100256A1 (en) | 2014-12-19 | 2016-06-23 | The Procter & Gamble Company | Shaping keratin fibres using arabinose and ethylene carbonate |
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JP6615916B2 (ja) * | 2015-06-18 | 2019-12-04 | ザ プロクター アンド ギャンブル カンパニー | 2−オキサゾリジノン化合物を使用したケラチン繊維の整形 |
EP3310325A1 (en) | 2015-06-18 | 2018-04-25 | The Procter and Gamble Company | Shaping keratin fibres using dialdehyde compounds |
IT202100016733A1 (it) | 2021-06-25 | 2022-12-25 | Beauty & Business S P A | Composizioni stiranti per capelli |
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Also Published As
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WO2015094788A1 (en) | 2015-06-25 |
MX2016008161A (es) | 2016-09-16 |
EP3082738A1 (en) | 2016-10-26 |
US20150174432A1 (en) | 2015-06-25 |
BR112016014146A2 (pt) | 2017-08-08 |
CN105873563A (zh) | 2016-08-17 |
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