JP2017201401A5 - - Google Patents

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JP2017201401A5
JP2017201401A5 JP2017107435A JP2017107435A JP2017201401A5 JP 2017201401 A5 JP2017201401 A5 JP 2017201401A5 JP 2017107435 A JP2017107435 A JP 2017107435A JP 2017107435 A JP2017107435 A JP 2017107435A JP 2017201401 A5 JP2017201401 A5 JP 2017201401A5
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adhesive layer
polarizing film
pressure
sensitive adhesive
hydroxyl group
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JP2017107435A
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JP2017201401A (en
JP6797077B2 (en
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Claims (18)

偏光子、アンカーコート層および粘着剤層を、この順で有する粘着剤層付偏光フィルムであって、
前記アンカーコート層は、水系樹脂およびヒドロキシル基と反応可能な第一級のアルコールを分子末端に少なくとも一つ有する化合物(a)を含有する水系樹脂組成物から形成されたものであり、
前記粘着剤層は、ヒドロキシル基を有するベースポリマー、およびメルカプト基含有シランカップリング剤を含有する粘着剤組成物から形成されたものであることを特徴とする粘着剤層付偏光フィルム。
A polarizing film with a pressure-sensitive adhesive layer having a polarizer, an anchor coat layer and a pressure-sensitive adhesive layer in this order,
The anchor coat layer is formed from an aqueous resin composition containing an aqueous resin and a compound (a) having at least one primary alcohol capable of reacting with a hydroxyl group at the molecular end;
The said adhesive layer is formed from the adhesive composition containing the base polymer which has a hydroxyl group, and a mercapto group containing silane coupling agent, The polarizing film with an adhesive layer characterized by the above-mentioned.
前記水系樹脂が、ポリビニルアルコール系樹脂、ポリウレタン系樹脂、エポキシ系樹脂およびオキサゾリン基含有ポリマーから選ばれるいずれ少なくとも1つであることを特徴とする請求項1記載の粘着剤層付偏光フィルム。   2. The polarizing film with a pressure-sensitive adhesive layer according to claim 1, wherein the aqueous resin is at least one selected from a polyvinyl alcohol resin, a polyurethane resin, an epoxy resin, and an oxazoline group-containing polymer. 前記水系樹脂が、ポリビニルアルコール系樹脂であることを特徴とする請求項2記載の粘着剤層付偏光フィルム。   The polarizing film with an adhesive layer according to claim 2, wherein the aqueous resin is a polyvinyl alcohol resin. 前記ポリビニルアルコール系樹脂は、ケン化度が96モル%以上、平均重合度が2000以上であることを特徴とする請求項3のいずれかに記載の粘着剤層付偏光フィルム。   4. The polarizing film with a pressure-sensitive adhesive layer according to claim 3, wherein the polyvinyl alcohol-based resin has a saponification degree of 96 mol% or more and an average polymerization degree of 2000 or more. 前記水系樹脂組成物は、前記水系樹脂100重量部に対して、前記化合物(a)を0.2〜20重量部含有することを特徴とする請求項1〜4のいずれかに記載の粘着剤層付偏光フィルム。   The pressure-sensitive adhesive according to any one of claims 1 to 4, wherein the water-based resin composition contains 0.2 to 20 parts by weight of the compound (a) with respect to 100 parts by weight of the water-based resin. Layered polarizing film. 前記アンカーコート層は、厚みが0.05μm以上6μm以下であることを特徴とする請求項1〜のいずれかに記載の粘着剤層付偏光フィルム。 The anchor coat layer, a polarizing film pressure-sensitive adhesive layer according to any one of claims 1 to 5, wherein the thickness is 0.05μm or more 6μm or less. 前記ヒドロキシル基を有するベースポリマーが、ヒドロキシル基を有する(メタ)アクリル系ポリマーであることを特徴とする請求項1〜のいずれかに記載の粘着剤層付偏光フィルム。 Wherein the base polymer having a hydroxyl group has a hydroxyl group-containing (meth) attached polarizing film adhesive layer according to any one of claims 1 to 6, characterized in that an acrylic polymer. 前記粘着剤組成物は、前記ヒドロキシル基を有するベースポリマー100重量部に対して、前記メルカプト基含有シランカップリング剤を0.01〜5重量部含有することを特徴とする請求項1〜のいずれかに記載の粘着剤層付偏光フィルム。 The pressure-sensitive adhesive composition, with respect to 100 parts by weight of the base polymer having a hydroxyl group, according to claim 1-7 where the mercapto group-containing silane coupling agent, characterized in that it contains 0.01 to 5 parts by weight The polarizing film with an adhesive layer in any one. 前記粘着剤組成物が、架橋剤を含有することを特徴とする請求項1〜のいずれかに記載の粘着剤層付偏光フィルム。 The said adhesive composition contains a crosslinking agent, The polarizing film with an adhesive layer in any one of Claims 1-8 characterized by the above-mentioned. 前記架橋剤が、ヒドロキシル基と反応しない架橋剤(b)を含有することを特徴とする請求項記載の粘着剤層付偏光フィルム。 The polarizing film with a pressure-sensitive adhesive layer according to claim 9 , wherein the crosslinking agent contains a crosslinking agent (b) that does not react with a hydroxyl group. 前記ヒドロキシル基と反応しない架橋剤(b)が、過酸化物であることを特徴とする請求項10記載の粘着剤層付偏光フィルム。 The polarizing film with an adhesive layer according to claim 10, wherein the crosslinking agent (b) that does not react with the hydroxyl group is a peroxide. 前記ヒドロキシル基と反応しない架橋剤(b)を、前記ヒドロキシル基を有するベースポリマー100重量部に対して、0.01〜2重量部含有することを特徴とする請求項10または11記載の粘着剤層付偏光フィルム。 The pressure-sensitive adhesive according to claim 10 or 11 , comprising 0.01 to 2 parts by weight of the crosslinking agent (b) that does not react with the hydroxyl group, based on 100 parts by weight of the base polymer having the hydroxyl group. Layered polarizing film. 前記偏光子は、厚みが15μm以下であることを特徴とする請求項1〜12のいずれかに記載の粘着剤層付偏光フィルム。 The polarizer is a polarizing film with an adhesive layer according to any one of claims 1 to 12, wherein the thickness is 15μm or less. 前記偏光子は、単体透過率T及び偏光度Pによって表される光学特性が、下記式、
P>−(100.929T−42.4−1)×100(ただし、T<42.3)、及び、
P≧99.9(ただし、T≧42.3)、の条件を満足するように構成されたことを特徴とする請求項1〜13のいずれかに記載の粘着剤層付偏光フィルム。
The polarizer has an optical characteristic represented by the following formula:
P> − (10 0.929T-42.4 −1) × 100 (where T <42.3), and
P ≧ 99.9 (However, T ≧ 42.3), polarizing film pressure-sensitive adhesive layer according to any one of claims 1 to 13, characterized in that it is configured so as to satisfy the condition.
前記偏光子の少なくとも片側に保護フィルムを有することを特徴とする請求項1〜14のいずれかに記載の粘着剤層付偏光フィルム。 Polarizing film pressure-sensitive adhesive layer according to any one of claims 1 to 14, characterized in that it has a protective film on at least one side of the polarizer. 前記粘着剤層には、セパレータが積層されていることを特徴とする請求項1〜15のいずれかに記載の粘着剤層付偏光フィルム。 The polarizing film with an adhesive layer according to any one of claims 1 to 15 , wherein a separator is laminated on the adhesive layer. 請求項1〜16のいずれかに記載の粘着剤層付偏光フィルムの製造方法であって、
偏光子上に、水系樹脂およびヒドロキシル基と反応可能な第一級のアルコールを分子末端に少なくとも一つ有する化合物(a)を含有する水系樹脂組成物を塗工し、次いで、乾燥して、アンカーコート層を形成する工程と、
前記アンカーコート層上に、ヒドロキシル基を有するベースポリマー、およびメルカプト基含有シランカップリング剤を含有する粘着剤組成物から粘着剤層を形成する工程、
を有することを特徴とする粘着剤層付偏光フィルムの製造方法。
A method of manufacturing a polarizing film with an adhesive layer according to any one of claims 1-16,
On the polarizer, an aqueous resin composition containing a water-based resin and a compound (a) having at least one primary alcohol capable of reacting with a hydroxyl group at the molecular end is coated, then dried, and anchored. Forming a coat layer;
Forming a pressure-sensitive adhesive layer on the anchor coat layer from a pressure-sensitive adhesive composition containing a base polymer having a hydroxyl group and a mercapto group-containing silane coupling agent;
The manufacturing method of the polarizing film with an adhesive layer characterized by having.
請求項1〜16のいずれかに記載の粘着剤層付偏光フィルムを有する画像表示装置。
An image display device having the polarizing film pressure-sensitive adhesive layer according to any one of claims 1-16.
JP2017107435A 2015-09-30 2017-05-31 Polarizing film with adhesive layer, its manufacturing method, and image display device Active JP6797077B2 (en)

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