JP2017179577A - Method for operating melting-refining furnace and melting-refining furnace - Google Patents

Method for operating melting-refining furnace and melting-refining furnace Download PDF

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JP2017179577A
JP2017179577A JP2016073577A JP2016073577A JP2017179577A JP 2017179577 A JP2017179577 A JP 2017179577A JP 2016073577 A JP2016073577 A JP 2016073577A JP 2016073577 A JP2016073577 A JP 2016073577A JP 2017179577 A JP2017179577 A JP 2017179577A
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melting
furnace
iron source
cold iron
burner
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JP6393291B2 (en
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義之 萩原
Yoshiyuki Hagiwara
義之 萩原
康之 山本
Yasuyuki Yamamoto
康之 山本
尚樹 清野
Naoki Kiyono
尚樹 清野
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Taiyo Nippon Sanso Corp
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    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P10/00Technologies related to metal processing
    • Y02P10/20Recycling

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  • Refinement Of Pig-Iron, Manufacture Of Cast Iron, And Steel Manufacture Other Than In Revolving Furnaces (AREA)
  • Vertical, Hearth, Or Arc Furnaces (AREA)
  • Furnace Charging Or Discharging (AREA)
  • Treatment Of Steel In Its Molten State (AREA)

Abstract

PROBLEM TO BE SOLVED: To provide a method for operating a melting-refining furnace, upon the operation of a melting-refining furnace for a cold iron source using oxygen burner(s)-lance(s), improving the efficiency.SOLUTION: Provided is a method for operating a melting-refining furnace where, in a furnace equipped with a through hole provided so as to pass through a furnace wall, one or more burners provided in the through hole and one or more lances installed in a combustion supporting fluid feed hole provided at the part upper than the through hole for a burner, operation is performed in such a manner that the introduction amount of oxygen lies in a range calculated from the volume of the furnace in a melting step.SELECTED DRAWING: Figure 1

Description

本発明は、酸素バーナとランスとを用いた冷鉄源の溶解・精錬炉の操業方法と溶解・精錬炉に関する。   The present invention relates to a method for operating a melting and refining furnace for a cold iron source using an oxygen burner and a lance, and a melting and refining furnace.

酸素を含む支燃性流体(酸素、空気、酸素富化空気等)と燃料とを燃焼させて被加熱物を加熱するバーナは、様々な生産プロセスで用いられている。例えば、電気炉における製鋼プロセスでは、鉄屑等の原料を電気炉内で加熱し、溶融させる際に、原料にコールドスポットといわれる低温部位が生じ、この部分において原料が溶融しにくくなる事がある。そのような場合に、特許文献1に開示されているようなバーナを併用することによって、原料の加熱効率を高め、原料溶融の為の電力使用量を低減し、溶融コストを削減することが出来る。   Burners that heat an object to be heated by burning a combustion-supporting fluid (oxygen, air, oxygen-enriched air, etc.) containing oxygen and fuel are used in various production processes. For example, in a steelmaking process in an electric furnace, when a raw material such as iron scrap is heated and melted in the electric furnace, a low temperature region called a cold spot is generated in the raw material, and the raw material may be difficult to melt in this part. . In such a case, the combined use of a burner as disclosed in Patent Document 1 can increase the heating efficiency of the raw material, reduce the amount of power used for melting the raw material, and reduce the melting cost. .

また、支燃性流体によって原料の一部を酸化、溶融させ、切断を促し、原料に対する加熱効率をさらに高める事が出来る。さらには、支燃性流体の供給によって、未燃焼流体(一酸化炭素等)の燃焼を促進する事も可能である。   In addition, a part of the raw material can be oxidized and melted by the combustion-supporting fluid to promote cutting, and the heating efficiency of the raw material can be further increased. Furthermore, it is possible to promote combustion of an unburned fluid (such as carbon monoxide) by supplying a combustion-supporting fluid.

例えば、特許文献2には、支燃性流体による二次燃焼時の加熱効率を高めるために、予め高温に予熱した酸素ガスを利用する発明が開示されている。   For example, Patent Document 2 discloses an invention that uses oxygen gas preheated to a high temperature in advance in order to increase the heating efficiency during secondary combustion with a combustion-supporting fluid.

特許4050195号公報Japanese Patent No. 4050195 特開2000-337776号公報JP 2000-337776 A

このような操業においては、バーナによる原料の補助溶融が溶融コストの削減を目的としていることから、電気炉内に吹き込む支燃性流体の消費量をできる限り少なくし、且つ、歩留まり向上のための原料の過酸化抑制も要望されている。 本発明は、上記事情に鑑みてなされたものであり、バーナとランスを用いた冷鉄源の溶解・精錬炉の操業あるいは精錬の際に、その効率を向上させることにある。 In such an operation, since the auxiliary melting of the raw material by the burner is aimed at reducing the melting cost, the consumption of the combustion-supporting fluid blown into the electric furnace is minimized and the yield is improved. There is also a demand for suppression of peroxidation of raw materials. The present invention has been made in view of the above circumstances, and is to improve the efficiency of a cold iron source melting / smelting furnace operation or refining using a burner and a lance.

上記課題を解決するための本発明の溶解・精錬方法は、電気炉を用いて冷鉄源を溶解精錬する方法であって、前記電気炉の上部から冷鉄源を投入する第1工程と、電気炉の中心部に設けた電極に通電して冷鉄源を主溶解させる第2工程と電気炉の炉壁に設けたバーナによって冷鉄源を補助溶解する第3工程と、前記バーナより上部の位置の前記炉壁に設けた酸素噴出孔に設置したランスから、水平方向より下方に向けて酸素を噴出させ、当該酸素と前記冷鉄源の溶解時に発生する一酸化炭素及びもしくは水素とを反応させる第4工程とからなる溶解工程、及び前記冷鉄源の溶解により生じた溶鉱中に酸素を導入することで不純物を取り除く精錬工程とからなる。
前記第4工程は、第3工程の開始と同時もしくはその直後から開始され精錬工程の開始とともに終了し、前記炉の容積V(m)と導入する酸素量Q(Nm/h)との関係をV/Q=0.1〜0.8の範囲とすることを特徴とする冷鉄源の溶解精錬方法である。
The melting and refining method of the present invention for solving the above problems is a method of melting and refining a cold iron source using an electric furnace, the first step of charging the cold iron source from the upper part of the electric furnace, A second step in which the cold iron source is mainly melted by energizing an electrode provided in the center of the electric furnace, a third step in which the cold iron source is auxiliary melted by a burner provided in the furnace wall of the electric furnace, and an upper portion from the burner. From the lance installed in the oxygen ejection hole provided in the furnace wall at the position of the above, oxygen is ejected downward from the horizontal direction, and the oxygen and carbon monoxide and / or hydrogen generated when the cold iron source is dissolved It comprises a melting step consisting of a fourth step to be reacted, and a refining step of removing impurities by introducing oxygen into the molten ore generated by melting the cold iron source.
The fourth step starts at the same time as or immediately after the start of the third step and ends with the start of the refining step. The furnace volume V (m 3 ) and the amount of oxygen Q (Nm 3 / h) to be introduced A cold iron source melting and refining method characterized in that the relationship is in the range of V / Q = 0.1 to 0.8.

また、本発明の溶解・精錬炉は、上記溶解製錬方法を実施するための炉であって、前記炉は上部に冷鉄源を導入するための開口部を有した電気炉であり、該電気炉は、その中心部に冷鉄源を溶解するための電極と、その炉壁に冷鉄源を補助溶解するためのバーナと、前記炉壁に前記バーナより上部の位置に酸素を導入するためのランスと、前記ランスに一定量の酸素を供給するための酸素流量調整機構とを有し、前記バーナ及び前記ランスの前記炉壁への取付け位置が以下の範囲にあることを特徴とする冷鉄源の溶解・製錬炉である。
溶湯面からバーナ先端部までの距離L<溶湯面からランス先端部までの距離L
バーナの中心軸と水平面とが成す角度α≧ランスの中心軸と水平面とが成す角度β
バーナの中心軸と水平面とが成す角度α>0°
ランスの中心軸と水平面とが成す角度β≧0°
The melting / smelting furnace of the present invention is a furnace for carrying out the melting and smelting method, wherein the furnace is an electric furnace having an opening for introducing a cold iron source at an upper portion thereof, The electric furnace has an electrode for melting a cold iron source at the center thereof, a burner for auxiliary melting of the cold iron source at the furnace wall, and oxygen is introduced into the furnace wall at a position above the burner. And an oxygen flow rate adjusting mechanism for supplying a constant amount of oxygen to the lance, and the mounting positions of the burner and the lance on the furnace wall are in the following ranges. It is a melting and smelting furnace for cold iron sources.
Distance L 1 from the molten metal surface to the tip of the burner <Distance L 2 from the molten metal surface to the tip of the lance
Angle α between burner center axis and horizontal plane ≧ Angle β between lance central axis and horizontal plane
Angle α> 0 ° between the central axis of the burner and the horizontal plane
The angle between the central axis of the lance and the horizontal plane β ≧ 0 °

前記酸素流量調整機構は、流量調節弁、流量指示器、圧力計、圧力調節弁からなることを特徴とする冷鉄源の溶解・製錬炉である。 The oxygen flow rate adjustment mechanism is a cold iron source melting / smelting furnace comprising a flow rate control valve, a flow rate indicator, a pressure gauge, and a pressure control valve.

本発明によると、バーナとランスとを用いた冷鉄源の溶解・精錬炉の操業あるいは精錬の際に、炉内に支燃性流体を適正な位置から適正量吹き込むことが可能となり、支燃性流体の消費量を必要最低限とすることができるため、溶解効率も向上できる。   According to the present invention, when operating or refining a cold iron source using a burner and a lance, it is possible to inject an appropriate amount of a supporting fluid from an appropriate position into the furnace. Since the consumption of the ionic fluid can be minimized, the dissolution efficiency can also be improved.

本発明に用いられる溶解・製錬炉の模式図である。It is a schematic diagram of the melting and smelting furnace used in the present invention. 本発明に用いられる溶解・製錬炉の上蓋を取り外し、冷鉄源を導入する際の模式図である。It is a schematic diagram at the time of removing the upper cover of the melting / smelting furnace used in the present invention and introducing a cold iron source. 電気炉側面からのバーナとランスの配置を示した模式図である。It is the schematic diagram which showed arrangement | positioning of the burner and lance from the electric furnace side surface. 電気炉上部からのバーナの配置を示した模式図である。It is the schematic diagram which showed arrangement | positioning of the burner from an electric furnace upper part. 実施形態におけるランス機能を有するバーナ(バーナ・ランス)の模式図である。It is a schematic diagram of the burner (burner lance) which has a lance function in embodiment. ランスから炉内に供給する酸素の流量制御機構の模式図である。It is a schematic diagram of the flow control mechanism of oxygen supplied from the lance into the furnace. 溶解・精錬炉からの排ガス中の一酸化炭素及び水素の発生量と、炉容積V/導入酸素量Qの関係を表した図である。It is a figure showing the relationship between the generation amount of carbon monoxide and hydrogen in the exhaust gas from the melting / smelting furnace and the furnace volume V 1 / the introduced oxygen amount Q. 溶解・精錬炉からの排ガス中の一酸化炭素と水素の発生量と、炉容積V/導入酸素量Qの関係を表した図である。It is a figure showing the relationship between the generation amount of carbon monoxide and hydrogen in the exhaust gas from the melting / smelting furnace, and the furnace volume V 2 / introduced oxygen amount Q.

本発明の一実施形態を説明する。本発明に用いられる冷鉄源の溶解・製錬炉を図1に示す。図1に示した溶解・製錬炉1は、その中心部に電極4を有する電気炉である。電気炉1は上部が開口可能な円筒形であり、炉の開口部を塞ぐ炉蓋3を有している。電極4は、各炉によって1本の場合と3本の場合があるが、本実施形態においては電極が1本の場合を示している。 An embodiment of the present invention will be described. A cold iron source melting and smelting furnace used in the present invention is shown in FIG. The melting / smelting furnace 1 shown in FIG. 1 is an electric furnace having an electrode 4 at the center thereof. The electric furnace 1 has a cylindrical shape whose upper part can be opened, and has a furnace lid 3 that closes the opening of the furnace. Although there are cases where there are one electrode and three electrodes 4 depending on each furnace, in the present embodiment, a case where there is one electrode is shown.

電気炉1内に冷鉄源を投入する際には、例えば、図2に示すように電極を抜き、炉蓋を外してから、炉体2上部の開口部より冷鉄源を投入する。 When the cold iron source is put into the electric furnace 1, for example, as shown in FIG. 2, the electrode is pulled out, the furnace cover is removed, and then the cold iron source is put in through the opening at the top of the furnace body 2.

電気炉1には、炉壁2Aを貫通するように設けられた貫通孔5Aがあり、貫通孔5Aにはバーナ3が設置されている。炉壁2Aには、貫通孔5Aより上部に、炉壁2Aを貫通するように支燃性流体貫通孔6Aが設けられている。支燃性流体貫通孔6Aには、炉内に支燃性流体(酸素)を導入するためにランス6が設置されている。バーナ5は貫通孔5Aから、ランス6は支燃性流体貫通孔6Aから、炉底2Bに向けて挿入し、固定する。 The electric furnace 1 has a through hole 5A provided so as to penetrate the furnace wall 2A, and a burner 3 is installed in the through hole 5A. The furnace wall 2A is provided with a combustion-supporting fluid through hole 6A above the through hole 5A so as to penetrate the furnace wall 2A. A lance 6 is installed in the combustion-supporting fluid through hole 6A in order to introduce a combustion-supporting fluid (oxygen) into the furnace. The burner 5 is inserted from the through-hole 5A, and the lance 6 is inserted from the combustion-supporting fluid through-hole 6A toward the furnace bottom 2B and fixed.

図3は電気炉側面からのバーナとランスの配置を示した図である。ランス6の炉壁2Aへの設置位置は、バーナ5より上部とする。すなわち、バーナ5の高さ位置(バーナ先端部と溶湯面との距離)をL、ランス6の高さ位置(ランス先端部と溶湯面との距離)をL2としたとき、L1<L2となるように、バーナ5とランス6を設置する(図3左図)。ここで溶湯面とは、冷鉄源を溶解したのち、溶鋼で形成される溶湯の上面を意味する。 FIG. 3 is a view showing the arrangement of burners and lances from the side of the electric furnace. The installation position of the lance 6 on the furnace wall 2 </ b> A is above the burner 5. That is, when L 1 is the height position of the burner 5 (distance between the burner tip and the molten metal surface) and L 2 is the height position of the lance 6 (distance between the lance tip and the molten metal surface), L 1 < The burner 5 and the lance 6 are installed so as to be L 2 (the left figure in FIG. 3). Here, the molten metal surface means the upper surface of the molten metal formed from molten steel after melting the cold iron source.

バーナ5の設置方向が、バーナ5の中心軸と水平方向とでなす角度をαとしたとき、90°>α>0°となるように固定する(図3右図)。より好ましくは60°<α<45°とする。また、ランスの設置方向は、ランス6の中心軸と水平方向とでなす角度をβとしたとき、α≧β≧0°となるように固定する(図3右図)。すなわち、ランス6からの支燃性流体の噴出方向は、バーナ5による火炎が形成される方向と同一の角度以上とする。ランス6の向きをこのように設定することで、バーナ5を燃焼させた際の未燃ガス(主に一酸化炭素、水素)を、ランス6からの支燃性ガスにより、効率よく燃焼させることができる。 The installation direction of the burner 5 is fixed so that 90 °> α> 0 °, where α is the angle formed by the central axis of the burner 5 and the horizontal direction (right diagram in FIG. 3). More preferably, 60 ° <α <45 °. In addition, the installation direction of the lance is fixed so that α ≧ β ≧ 0 °, where β is an angle formed between the central axis of the lance 6 and the horizontal direction (the right diagram in FIG. 3). That is, the ejection direction of the combustion-supporting fluid from the lance 6 is set to the same angle or more as the direction in which the flame by the burner 5 is formed. By setting the direction of the lance 6 in this way, the unburned gas (mainly carbon monoxide and hydrogen) when the burner 5 is burned can be efficiently burned by the combustion-supporting gas from the lance 6. Can do.

図4は電気炉上部からのバーナ5の配置を示した図である。図4には3本のバーナを設置した例を示している。バーナ5の火炎形成方向は、炉内において電極4による冷鉄源の加熱が不十分な場所を加熱できる方向に向ける。また、電極4に損傷を与えないように、バーナ5は、火炎が電極に直接当たらない方向となるように設置することが望ましい。 FIG. 4 is a view showing the arrangement of the burner 5 from the upper part of the electric furnace. FIG. 4 shows an example in which three burners are installed. The flame formation direction of the burner 5 is directed to a direction in which a place where the heating of the cold iron source by the electrode 4 is insufficient in the furnace can be heated. In order not to damage the electrode 4, it is desirable to install the burner 5 so that the flame does not directly hit the electrode.

本実施形態におけるバーナの構成を示す断面模式図を図5に示す。図5に記載のバーナは、ランス機能を有するバーナ(バーナ・ランス)である。本実施形態における酸素バーナ・ランス6の中央には、酸素を含んだ支燃性流体を供給する支燃性流体供給管18が設けられており、その外周には、燃料流体を供給する燃料流体供給管19が設けられ、さらに、その外周に支燃性流体供給管20が、同心円状に設けられている。支燃性流体供給管20の外周には、還流式水冷ジャケット21が設けられている。 FIG. 5 shows a schematic cross-sectional view showing the configuration of the burner in the present embodiment. The burner described in FIG. 5 is a burner having a lance function (burner lance). A combustion support fluid supply pipe 18 that supplies a support fluid containing oxygen is provided at the center of the oxygen burner lance 6 in the present embodiment, and a fuel fluid that supplies fuel fluid is provided on the outer periphery thereof. A supply pipe 19 is provided, and a combustion-supporting fluid supply pipe 20 is provided concentrically on the outer periphery thereof. A reflux type water cooling jacket 21 is provided on the outer periphery of the combustion-supporting fluid supply pipe 20.

なお、支燃性流体供給管20を設けず、燃料流体供給管19の外周に還流式水冷ジャケット21を設けても良いが、支燃性流体供給管20を設けた場合には、支燃性流体供給管18と20の酸素流量比を調整することにより、火炎長の調整が可能となる。   In addition, the reflux-type water cooling jacket 21 may be provided on the outer periphery of the fuel fluid supply pipe 19 without providing the fuel support fluid supply pipe 20, but when the fuel support fluid supply pipe 20 is provided, the fuel support property is improved. The flame length can be adjusted by adjusting the oxygen flow rate ratio between the fluid supply pipes 18 and 20.

支燃性流体供給管18は、基端側18Aから先端側18Bにかけて、一定の内径を有する太径部18aと、太径部18aよりも内径が小さいスロート部18bと、スロート部18bから先端側18Bに向けて内径が徐々に大きくなる広がり部18cと、ほぼ一定の内径を有する直動部18dを有する。   The combustion-supporting fluid supply pipe 18 includes a large-diameter portion 18a having a constant inner diameter, a throat portion 18b having a smaller inner diameter than the large-diameter portion 18a, and a distal-end side from the throat portion 18b. An expanded portion 18c having an inner diameter gradually increasing toward 18B and a linear motion portion 18d having a substantially constant inner diameter are provided.

本実施形態におけるバーナ・ランス(バーナ5)を設置した炉壁2Aの上部には、二次燃焼用の酸素を含んだ支燃性流体を炉内に導入するランス6を設置するための支燃性流体供給孔6Aを設けている。
ランス6は、酸素を含む支燃性流体を供給する支燃性流体供給管の外周に、還流式水冷ジャケットを設けておくことが望ましい。水冷ジャケットを有するランスであれば、炉壁が耐火物壁であっても、水冷壁であっても設置が可能である。
In the upper part of the furnace wall 2A where the burner lance (burner 5) is installed in the present embodiment, a combustion support for installing a lance 6 for introducing a combustion supporting fluid containing oxygen for secondary combustion into the furnace. A functional fluid supply hole 6A is provided.
The lance 6 is desirably provided with a reflux water cooling jacket on the outer periphery of a combustion-supporting fluid supply pipe for supplying a combustion-supporting fluid containing oxygen. A lance having a water cooling jacket can be installed regardless of whether the furnace wall is a refractory wall or a water cooling wall.

図6には、ランス6に酸素を供給するための酸素流量調整機構の構成を示している。酸素流量調整機構は、酸素供給側から圧力調節弁10、圧力計11、流量指示器12、流量調節弁13からなる。 FIG. 6 shows a configuration of an oxygen flow rate adjusting mechanism for supplying oxygen to the lance 6. The oxygen flow rate adjusting mechanism includes a pressure control valve 10, a pressure gauge 11, a flow rate indicator 12, and a flow rate control valve 13 from the oxygen supply side.

上記のような溶解・製錬炉1を用いて冷鉄源を溶解精錬する方法を示す。まず、図2に示すように、電極4と炉蓋3を取り外した炉体2の上部開口部から冷鉄源を投入する(第1工程)。次に、溶解・製錬炉1の中心部の所定の位置まで電極4を下げ、炉蓋3で炉体2の上部を覆う。そして電極4に通電して、冷鉄源を溶解する(第2工程)。
冷鉄源の溶解が始まり、溶湯が炉底2Bに溜まり始めたら、溶解・製錬炉1の炉壁2Aに設けた複数のバーナ5によって冷鉄源を補助溶解する(第3工程)。
そして、第3工程の開始と同時、もしくはその直後より、炉壁2Aに設けた支燃性流体供給孔6Aに設置したランス6から酸素を噴出させ、冷鉄源の溶解時に発生する一酸化炭素及びもしくは水素とを反応させる(第4工程)。
この第1工程から第4工程までが溶解工程となる。
A method of melting and refining a cold iron source using the melting / smelting furnace 1 as described above will be described. First, as shown in FIG. 2, a cold iron source is supplied from the upper opening of the furnace body 2 from which the electrode 4 and the furnace lid 3 are removed (first step). Next, the electrode 4 is lowered to a predetermined position in the center of the melting / smelting furnace 1, and the upper part of the furnace body 2 is covered with the furnace lid 3. And it supplies with electricity to the electrode 4 and melt | dissolves a cold iron source (2nd process).
When the melting of the cold iron source begins and the molten metal begins to accumulate in the furnace bottom 2B, the cold iron source is auxiliary melted by a plurality of burners 5 provided on the furnace wall 2A of the melting / smelting furnace 1 (third step).
At the same time as the start of the third step or immediately after that, oxygen is spouted from the lance 6 installed in the combustion-supporting fluid supply hole 6A provided in the furnace wall 2A, and carbon monoxide generated when the cold iron source is dissolved. And / or reacting with hydrogen (fourth step).
The first step to the fourth step are dissolution steps.

ここで、第4工程におけるランス6からの酸素供給量は、溶解・製錬炉1の容積から決定できる。すなわち、溶解・製錬炉1の容積がV(m3)であった場合、第4工程における酸素の導入量Q(Nm3/h)を、V/Q=0.1〜0.8の範囲となるようにする。ここで、炉容積Vとは、冷鉄源が投入される前の炉体2の内容積である。 Here, the amount of oxygen supplied from the lance 6 in the fourth step can be determined from the volume of the melting / smelting furnace 1. That is, when the volume of the melting / smelting furnace 1 is V (m 3 ), the oxygen introduction amount Q (Nm 3 / h) in the fourth step is V / Q = 0.1 to 0.8. Try to be in range. Here, the furnace volume V is the internal volume of the furnace body 2 before the cold iron source is charged.

溶解工程において冷鉄源がほぼ溶解し、炉底に溶解した溶鋼が溶湯として溜まったら、バーナ・ランス(バーナ5)への燃料供給を停止してランスモードに切り替え、溶湯中に酸素を導入して不純物を取り除く。これが精錬工程となる。 When the cold iron source is almost melted in the melting process and the molten steel is melted in the furnace bottom, the fuel supply to the burner lance (burner 5) is stopped and the lance mode is switched to introduce oxygen into the molten metal. To remove impurities. This is the refining process.

炉体の内容積がV(m)である溶解・精錬炉において、上記の溶解工程(第1工程〜第4工程)を実施した。溶解・製錬炉の排ガス出口には、排ガス分析装置と排ガス流量測定装置(図示せず)を設け、第3工程において、ランスから炉内に酸素ガスを導入する際に、排ガス中の一酸化炭素と水素(CO、H)の含有量を測定できるようにした。 In the melting and refining furnace in which the internal volume of the furnace body is V 1 (m 3 ), the melting process (the first process to the fourth process) was performed. At the exhaust gas outlet of the melting and smelting furnace, an exhaust gas analyzer and an exhaust gas flow rate measuring device (not shown) are provided, and in the third step, when oxygen gas is introduced from the lance into the furnace, monoxide in the exhaust gas The contents of carbon and hydrogen (CO, H 2 ) can be measured.

第3工程において、ランス6から炉内に導入する酸素量Q(Nm/h)を、酸素流量調整機構を用いて変化させ、溶解・精錬炉からの排ガス中の一酸化炭素と水素の含有量を測定した。その結果を図7に示す。
図7の横軸はV/Qである。縦軸は、冷鉄源を溶解して得られた鉄1tあたりの一酸化炭素と水素(CO、H)の発生量(Nm/t)である。
/Qが0.1〜0.8のとき、導入する酸素量が多くなるにつれてCOとHの発生量が減じているのが確認された。しかしながら、V/Qが0.8以上になってしまうと、COとHの濃度がほとんど変わらない。すなわち、導入する酸素量が不足していることを示しており、十分に二次燃焼が行われていないことが判る。また、0.1以下では酸素の導入量を増加させても、COとHの発生量に大きな変化が無いことが確認された。
In the third step, the oxygen amount Q (Nm 3 / h) introduced into the furnace from the lance 6 is changed using an oxygen flow rate adjusting mechanism, so that carbon monoxide and hydrogen are contained in the exhaust gas from the melting and refining furnace. The amount was measured. The result is shown in FIG.
The horizontal axis in FIG. 7 is V 1 / Q. The vertical axis represents the generation amount (Nm 3 / t) of carbon monoxide and hydrogen (CO, H 2 ) per 1 t of iron obtained by dissolving the cold iron source.
When V 1 / Q was 0.1 to 0.8, it was confirmed that the amount of CO and H 2 generated decreased as the amount of oxygen introduced increased. However, when V 1 / Q becomes 0.8 or more, the concentrations of CO and H 2 hardly change. That is, it indicates that the amount of oxygen to be introduced is insufficient, and it is understood that secondary combustion is not sufficiently performed. It was also confirmed that when the amount of oxygen introduced was increased below 0.1, there was no significant change in the amount of CO and H 2 generated.

上記とは異なる溶解・精錬炉(炉体の内容積V)において、同様の試験を実施した。結果を図8に示す。V/Qが0.1〜0.8のとき、ランス6からの酸素導入量に応じた一酸化炭素と水素の減少効果が見られた。すなわち、無駄のない酸素の適切な導入量はV/Qが0.1〜0.8の範囲にあるときである。 A similar test was conducted in a melting / smelting furnace (furnace volume V 2 ) different from the above. The results are shown in FIG. When V 2 / Q was 0.1 to 0.8, an effect of reducing carbon monoxide and hydrogen according to the amount of oxygen introduced from the lance 6 was observed. That is, an appropriate amount of oxygen introduced without waste is when V 2 / Q is in the range of 0.1 to 0.8.

本発明の溶解・精錬炉の操業方法及び溶解・精錬炉は、電気炉における冷鉄源の溶解への利用可能性がある。   The melting / smelting furnace operating method and melting / smelting furnace of the present invention can be used for melting a cold iron source in an electric furnace.

1・・・溶解・精錬炉(電気炉)、2・・・炉体、2A・・・炉壁、2B・・・炉底、3・・・炉蓋、4・・・電極、5・・・バーナ(バーナ・ランス)、5A・・・貫通孔、6・・・ランス、6A・・・支燃性流体供給孔、10・・・圧力調節弁、11・・・圧力計、12・・・流量指示器、13・・・流量調節弁、18・・・支燃性流体供給管、19・・・燃料流体供給管、20・・・支燃性流体供給管、21・・・還流式水冷ジャケット DESCRIPTION OF SYMBOLS 1 ... Melting / smelting furnace (electric furnace), 2 ... Furnace body, 2A ... Furnace wall, 2B ... Furnace bottom, 3 ... Furnace lid, 4 ... Electrode, 5 ... Burner (burner lance), 5A ... through hole, 6 ... lance, 6A ... flammable fluid supply hole, 10 ... pressure regulating valve, 11 ... pressure gauge, 12 ... -Flow indicator, 13 ... Flow control valve, 18 ... Fuel support fluid supply pipe, 19 ... Fuel fluid supply pipe, 20 ... Fuel support fluid supply pipe, 21 ... Reflux type Water cooling jacket

Claims (3)

溶解・製錬炉を用いて冷鉄源を溶解精錬する方法であって、
前記溶解・製錬炉の上部から冷鉄源を投入する第1工程と、
前記溶解・製錬炉の中心部に設けた電極に通電して冷鉄源を主溶解させる第2工程と
前記溶解・製錬炉の炉壁に設けたバーナによって冷鉄源を補助溶解する第3工程と、
前記炉壁に前記バーナより上部の位置に設けた支燃性流体噴出孔からランスを用い、水平方向より下方に向けて支燃性流体を噴出させ、当該支燃性流体と前記冷鉄源の溶解時に発生する一酸化炭素及びもしくは水素とを反応させる第4工程とからなる溶解工程、及び
前記冷鉄源の溶解により生じた溶鉱中に酸素を導入することで不純物を取り除く精錬工程とからなり、
前記第4工程は、前記第3工程の開始と同時もしくはその直後から開始され、精錬工程の開始とともに終了し、前記炉の炉体容積がV(m3)であった場合に、前記第4工程における支燃性流体が酸素であったときの酸素導入量Q(Nm3/h)をV/Q=0.1〜0.8の範囲とすることを特徴とする冷鉄源の溶解精錬方法。
A method for melting and refining a cold iron source using a melting and smelting furnace,
A first step of charging a cold iron source from the upper part of the melting / smelting furnace;
A second step of energizing an electrode provided at the center of the melting / smelting furnace to mainly melt the cold iron source and a second step of auxiliary melting of the cold iron source by a burner provided on the furnace wall of the melting / smelting furnace. 3 steps,
Using a lance from a combustion-supporting fluid jet hole provided at a position above the burner on the furnace wall, the support-supporting fluid and the cold iron source are ejected from the horizontal direction downward. A melting step comprising a fourth step of reacting carbon monoxide and / or hydrogen generated during melting, and a refining step of removing impurities by introducing oxygen into the ore produced by melting the cold iron source Become
The fourth step starts at the same time as or immediately after the start of the third step, ends with the start of the refining step, and when the furnace body volume of the furnace is V (m 3 ), Melting and refining a cold iron source characterized in that the oxygen introduction amount Q (Nm 3 / h) when the combustion supporting fluid in the process is oxygen is in the range of V / Q = 0.1 to 0.8 Method.
冷鉄源の溶解・製錬を行うための炉であって、
前記炉は上部に冷鉄源を導入するための開口部を有した電気炉であり、
該電気炉は、その中心部に冷鉄源を溶解するための電極と、
その炉壁に冷鉄源を補助溶解するためのバーナと、
前記炉壁に前記バーナより上部の位置に酸素を導入するためのランスと、
前記ランスに一定量の酸素を供給するための酸素流量調整機構とを有し、
前記バーナ及び前記ランスの前記炉壁への取付け位置が以下の範囲にあることを特徴とする冷鉄源の溶解・製錬炉。
溶湯面からバーナ先端部までの距離L<溶湯面からランス先端部までの距離L
バーナの中心軸と水平面とが成す角度α≧ランスの中心軸と水平面とが成す角度β
バーナの中心軸と水平面とが成す角度90°>α>0°
ランスの中心軸と水平面とが成す角度β≧0°
A furnace for melting and smelting a cold iron source,
The furnace is an electric furnace having an opening for introducing a cold iron source in the upper part,
The electric furnace has an electrode for melting a cold iron source at the center thereof,
A burner for auxiliary melting of the cold iron source in the furnace wall;
A lance for introducing oxygen into the furnace wall at a position above the burner;
An oxygen flow rate adjusting mechanism for supplying a constant amount of oxygen to the lance,
The cold iron source melting / smelting furnace, wherein the burner and the lance are attached to the furnace wall in the following ranges.
Distance L 1 from the molten metal surface to the tip of the burner <Distance L 2 from the molten metal surface to the tip of the lance
Angle α between burner center axis and horizontal plane ≧ Angle β between lance central axis and horizontal plane
Angle 90 °>α> 0 ° formed by the central axis of the burner and the horizontal plane
The angle between the central axis of the lance and the horizontal plane β ≧ 0 °
前記酸素流量調整機構は、流量調節弁、流量指示器、圧力計、圧力調節弁からなることを特徴とする請求項2記載の冷鉄源の溶解・製錬炉。


The melting / smelting furnace for a cold iron source according to claim 2, wherein the oxygen flow rate adjusting mechanism comprises a flow rate control valve, a flow rate indicator, a pressure gauge, and a pressure control valve.


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JP2008039362A (en) * 2006-08-10 2008-02-21 Taiyo Nippon Sanso Corp Burner, combustion method of powder combustibles, and melting and refining method of cold iron source
JP2011509394A (en) * 2008-01-08 2011-03-24 レール・リキード−ソシエテ・アノニム・プール・レテュード・エ・レクスプロワタシオン・デ・プロセデ・ジョルジュ・クロード Combined burner and lance for electric arc furnace

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH11293326A (en) * 1998-04-09 1999-10-26 Daido Steel Co Ltd Operation of electric arc furnace
US6229838B1 (en) * 1999-05-07 2001-05-08 L'air Liquide, Societe Anonyme Pour L'etude Et L'exploitation Des Procedes Georges Claude Electric arc furnace for the production of steel and method of operating this furnace
JP2008039362A (en) * 2006-08-10 2008-02-21 Taiyo Nippon Sanso Corp Burner, combustion method of powder combustibles, and melting and refining method of cold iron source
JP2011509394A (en) * 2008-01-08 2011-03-24 レール・リキード−ソシエテ・アノニム・プール・レテュード・エ・レクスプロワタシオン・デ・プロセデ・ジョルジュ・クロード Combined burner and lance for electric arc furnace

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