JP2017149994A5 - - Google Patents

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JP2017149994A5
JP2017149994A5 JP2017114636A JP2017114636A JP2017149994A5 JP 2017149994 A5 JP2017149994 A5 JP 2017149994A5 JP 2017114636 A JP2017114636 A JP 2017114636A JP 2017114636 A JP2017114636 A JP 2017114636A JP 2017149994 A5 JP2017149994 A5 JP 2017149994A5
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Prior art keywords
acrylate
methacrylate
norbornyl
methacrylic acid
resin composition
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JP2017114636A
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JP2017149994A (en
JP6447665B2 (en
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Claims (6)

２種類以上の単量体及び重合開始剤を含む単量体混合物を重合反応させる樹脂組成物の製造方法であって、
前記単量体の１種として、エポキシ基含有モノマを含み、
他の前記単量体が、アクリル酸エステル類、メタクリル酸エステル類及び脂環式類アクリル酸からなる群より選ばれる少なくとも１種を含み、
ただし前記単量体は、アクリロニトリルを含まず、
前記重合反応が懸濁重合法を用いて行われ、単量体、重合開始剤及び水を加えて得られた分散液に、加熱撹拌しながら、前記エポキシ基含有モノマを連続添加又は間隔を空けて何回かに分けての添加を行う工程を備える、樹脂組成物の製造方法。 A method for producing a resin composition in which a monomer mixture containing two or more types of monomers and a polymerization initiator is subjected to a polymerization reaction,
As one of the monomers, an epoxy group-containing monomer is included,
The other monomer includes at least one selected from the group consisting of acrylic acid esters, methacrylic acid esters, and alicyclic acrylic acids,
However, the monomer does not contain acrylonitrile,
The polymerization reaction is performed using a suspension polymerization method, and the epoxy group-containing monomer is continuously added to the dispersion obtained by adding a monomer, a polymerization initiator, and water with stirring, or at intervals. A method for producing a resin composition, comprising a step of performing addition in several times. 前記アクリル酸エステル類が、アクリル酸ｎ−プロピル、アクリル酸ｉ−プロピル、アクリル酸ｉ−ブチル、アクリル酸ｔ−ブチル、アクリル酸ペンチル、アクリル酸ｎ−ヘキシル、アクリル酸２−エチルヘキシル、アクリル酸ｎ−オクチル、アクリル酸ドデシル、アクリル酸オクタデシル、アクリル酸ブトキシエチル、アクリル酸フェニル、アクリル酸ベンジル及びアクリル酸ナフチルからなる群より選ばれる少なくとも１種を含む、請求項１に記載の樹脂組成物の製造方法。 The acrylic acid esters, A acrylic acid n- propyl, acrylate i- propyl, i- butyl A acrylic acid, butyl t- acrylate, pentyl acrylate, n- hexyl, 2-ethylhexyl acrylate, acrylic 2. The resin composition according to claim 1, comprising at least one selected from the group consisting of n-octyl acid, dodecyl acrylate, octadecyl acrylate, butoxyethyl acrylate, phenyl acrylate, benzyl acrylate, and naphthyl acrylate. Manufacturing method. 前記メタクリル酸エステル類が、メタクリル酸メチル、メタクリル酸ｎ−プロピル、メタクリル酸ｉ−プロピル、メタクリル酸ｎ−ブチル、メタクリル酸ｉ−ブチル、メタクリル酸ｔ−ブチル、メタクリル酸ペンチル、メタクリル酸ｎ−ヘキシル、メタクリル酸ｎ−オクチル、メタクリル酸ドデシル、メタクリル酸オクタデシル、メタクリル酸ブトキシエチル、メタクリル酸フェニル及びメタクリル酸ナフチルからなる群より選ばれる少なくとも１種を含む、請求項１又は２に記載の樹脂組成物の製造方法。 The methacrylic acid esters, methyl methacrylate, main methacrylic acid n- propyl methacrylate i- propyl, n- butyl methacrylate, i- butyl methacrylate, t- butyl methacrylate, pentyl methacrylate, n- hexyl, main methacrylic acid n- octyl, dodecyl methacrylate, octadecyl methacrylate, butoxyethyl methacrylate, containing at least one selected from the group consisting of phenyl methacrylate and methacrylic acid naphthyl, resin according to claim 1 or 2 A method for producing the composition. 前記脂環式類アクリル酸が、アクリル酸シクロペンチル、アクリル酸メチルシクロヘキシル、アクリル酸トリメチルシクロヘキシル、アクリル酸ノルボルニル、アクリル酸ノルボルニルメチル、アクリル酸フェニルノルボルニル、アクリル酸シアノノルボルニル、アクリル酸イソボルニル、アクリル酸ボルニル、アクリル酸メンチル、アクリル酸フェンチル、アクリル酸アダマンチル、アクリル酸ジメチルアダマンチル、アクリル酸トリシクロ〔５．２．１．０２，６〕デカ−４−メチル、アクリル酸シクロデシル、メタクリル酸シクロペンチル、メタクリル酸シクロヘキシル、メタクリル酸メチルシクロヘキシル、メタクリル酸トリメチルシクロヘキシル、メタクリル酸ノルボルニル、メタクリル酸ノルボルニルメチル、メタクリル酸シアノノルボルニル、メタクリル酸フェニルノルボルニル、メタクリル酸イソボルニル、メタクリル酸ボルニル、メタクリル酸メンチル、メタクリル酸フェンチル、メタクリル酸アダマンチル、メタクリル酸ジメチルアダマンチル、メタクリル酸トリシクロ〔５．２．１．０２，６〕デカ−４−メチル及びメタクリル酸シクロデシルからなる群より選ばれる少なくとも１種を含む、請求項１〜３のいずれか一項に記載の樹脂組成物の製造方法。 The alicyclic compounds acrylate, cyclopentyl acrylate, A acrylic acid methyl cyclohexyl, acrylate trimethylcyclohexyl, norbornyl acrylate, norbornyl, phenyl norbornyl acrylate, cyano norbornyl acrylate, isobornyl, bornyl acrylate, menthyl acrylate, fenchyl acrylate, adamantyl acrylate, dimethyl adamantyl, A acrylic acid tricyclo [5.2.1.0 2,6] dec-4-methyl, cyclodecyl acrylate, Cyclopentyl methacrylate, cyclohexyl methacrylate, methyl cyclohexyl methacrylate, trimethyl cyclohexyl methacrylate, norbornyl methacrylate, norbornyl methyl methacrylate, methacrylic acid Nonoruboruniru, phenyl methacrylate norbornyl, isobornyl methacrylate, bornyl methacrylate, menthyl, fenchyl methacrylate, adamantyl methacrylate, dimethyladamantyl, main methacrylic acid tricyclo [5.2.1.0 2,6] The manufacturing method of the resin composition as described in any one of Claims 1-3 containing at least 1 sort (s) chosen from the group which consists of deca-4-methyl and cyclodecyl methacrylate. 前記エポキシ基含有モノマが（メタ）アクリル酸グリシジルである、請求項１〜４のいずれか一項に記載の樹脂組成物の製造方法。   The manufacturing method of the resin composition as described in any one of Claims 1-4 whose said epoxy-group-containing monomer is glycidyl (meth) acrylate. 前記重合開始剤がラジカル重合開始剤であり、前記重合反応が、リビングラジカル重合ではないラジカル重合である、請求項１〜５のいずれか一項に記載の樹脂組成物の製造方法。   The method for producing a resin composition according to any one of claims 1 to 5, wherein the polymerization initiator is a radical polymerization initiator, and the polymerization reaction is radical polymerization that is not living radical polymerization.
JP2017114636A 2017-06-09 2017-06-09 Method for producing resin composition Active JP6447665B2 (en)

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JP2015208744A Division JP6278023B2 (en) 2015-10-23 2015-10-23 Method for producing resin composition

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JP2017149994A JP2017149994A (en) 2017-08-31
JP2017149994A5 true JP2017149994A5 (en) 2017-11-02
JP6447665B2 JP6447665B2 (en) 2019-01-09

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR102377565B1 (en) * 2018-12-13 2022-03-21 주식회사 엘지화학 Acryl based copolymer, method for preparing the same and acryl based copolymer composition comprising the acryl based copolymer

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JPS61266418A (en) * 1985-05-20 1986-11-26 Sekisui Plastics Co Ltd Production of styrene copolymer
JPS6274909A (en) * 1985-09-30 1987-04-06 Dainippon Ink & Chem Inc Production of transparent heat-resistant copolymer
JP2004155810A (en) * 2002-11-01 2004-06-03 Hitachi Chem Co Ltd Pseudo-crosslinked resin composition, molding and optical part molded from the same, and method for producing the same resin composition
JP5391590B2 (en) * 2008-06-26 2014-01-15 日立化成株式会社 Method for producing acrylic copolymer
JP5298704B2 (en) * 2008-08-26 2013-09-25 日立化成株式会社 Acrylic resin composition
JP5768318B2 (en) * 2009-12-16 2015-08-26 東ソー株式会社 Vinyl chloride resin latex and method for producing the same

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