JP2017138462A5 - - Google Patents
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- JP2017138462A5 JP2017138462A5 JP2016018906A JP2016018906A JP2017138462A5 JP 2017138462 A5 JP2017138462 A5 JP 2017138462A5 JP 2016018906 A JP2016018906 A JP 2016018906A JP 2016018906 A JP2016018906 A JP 2016018906A JP 2017138462 A5 JP2017138462 A5 JP 2017138462A5
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- 239000002245 particle Substances 0.000 claims description 36
- 229920001558 organosilicon polymer Polymers 0.000 claims description 12
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N silicon Chemical group [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims description 9
- 101710021191 ICP34.5 Proteins 0.000 claims description 7
- 238000004458 analytical method Methods 0.000 claims description 3
- 125000004432 carbon atoms Chemical group C* 0.000 claims description 3
- 125000004430 oxygen atoms Chemical group O* 0.000 claims description 3
- 239000000523 sample Substances 0.000 claims description 3
- 239000002344 surface layer Substances 0.000 claims description 3
- CZMRCDWAGMRECN-UGDNZRGBSA-N D-sucrose Chemical compound O[C@H]1[C@H](O)[C@@H](CO)O[C@@]1(CO)O[C@@H]1[C@H](O)[C@@H](O)[C@H](O)[C@@H](CO)O1 CZMRCDWAGMRECN-UGDNZRGBSA-N 0.000 claims description 2
- CZMRCDWAGMRECN-GDQSFJPYSA-N Sucrose Natural products O([C@@H]1[C@H](O)[C@@H](O)[C@H](O)[C@H](CO)O1)[C@@]1(CO)[C@H](O)[C@@H](O)[C@@H](CO)O1 CZMRCDWAGMRECN-GDQSFJPYSA-N 0.000 claims description 2
- 239000005720 sucrose Substances 0.000 claims description 2
- 125000000816 ethylene group Chemical group [H]C([H])([*:1])C([H])([H])[*:2] 0.000 claims 3
- 125000001570 methylene group Chemical group [H]C([H])([*:1])[*:2] 0.000 claims 3
- 125000000843 phenylene group Chemical group C1(=C(C=CC=C1)*)* 0.000 claims 3
- 229910052710 silicon Inorganic materials 0.000 claims 3
- WYURNTSHIVDZCO-UHFFFAOYSA-N tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 claims 2
- 238000005481 NMR spectroscopy Methods 0.000 claims 1
- 125000003668 acetyloxy group Chemical group [H]C([H])([H])C(=O)O[*] 0.000 claims 1
- 125000003545 alkoxy group Chemical group 0.000 claims 1
- 125000005843 halogen group Chemical group 0.000 claims 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims 1
- 150000003961 organosilicon compounds Chemical class 0.000 claims 1
- 229920000642 polymer Polymers 0.000 claims 1
- LIVNPJMFVYWSIS-UHFFFAOYSA-N silicon monoxide Inorganic materials [Si-]#[O+] LIVNPJMFVYWSIS-UHFFFAOYSA-N 0.000 claims 1
- 230000015572 biosynthetic process Effects 0.000 description 2
- 238000005755 formation reaction Methods 0.000 description 2
- 239000000853 adhesive Substances 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000007810 chemical reaction solvent Substances 0.000 description 1
- 239000010419 fine particle Substances 0.000 description 1
- 238000006460 hydrolysis reaction Methods 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 230000035484 reaction time Effects 0.000 description 1
Description
本発明者らは、前記課題を解決すべく鋭意検討を行った結果、以下のトナーを見出した。すなわち、本発明は、有機ケイ素重合体を含有する表面層を有するトナー粒子を含むトナーであって、
前記有機ケイ素重合体は、下記式（１）又は（２）で表される部分構造を有し、
前記トナー粒子の表面のＸ線光電子分光分析において、前記トナー粒子の表面の、炭素原子の濃度ｄＣ、酸素原子の濃度ｄＯ、及びケイ素原子の濃度ｄＳｉの合計を１００．０原子％としたときに、前記ケイ素原子の濃度ｄＳｉが、１．０原子％以上２２．２原子％以下であり、
前記トナー粒子の走査型プローブ顕微鏡で測定される粗さ曲線において、ＪＩＳ Ｂ０６０１：２００１に基づいて測定される算術平均粗さＲａ（ｎｍ）が、１０ｎｍ以上３００ｎｍ以下であり、
前記Ｒａの標準偏差をσＲａ（ｎｍ）としたとき、σＲａ／Ｒａが、０．６０以下であり、
前記粗さ曲線において、前記トナー粒子のＪＩＳ Ｂ０６０１：２００１に基づいて測定される粗さ曲線要素の平均長さＲＳｍ（ｎｍ）が、２０ｎｍ以上５００ｎｍ以下であり、
前記ＲＳｍの標準偏差をσＲＳｍ（ｎｍ）としたとき、σＲＳｍ／ＲＳｍが、０．６０以下である
ことを特徴とするトナーである。
As a result of intensive studies to solve the above problems, the present inventors have found the following toner. That is, the present invention is a toner comprising toner particles having a surface layer containing an organosilicon polymer,
The organosilicon polymer has a partial structure represented by the following formula (1) or (2):
In X-ray photoelectron spectroscopic analysis of the surface of the toner particles, wherein the surface of the toner particles, the concentration of carbon atoms dC, the concentration of oxygen atoms dO, and the total concentration dSi of the silicon atoms when the 100.0 atomic% , the concentration dSi of the silicon atoms is at 22.2 atomic% or less 1.0 atomic% or more,
In the roughness curve measured with a scanning probe microscope of the toner particles, JIS B0601: Arithmetic Average Roughness Ra (nm) measured on the basis of 2001, is a 10nm or more 300nm or less,
When the standard deviation of the Ra and σRa (nm), σRa / Ra is, is 0.60 or less,
In the roughness curve, the toner particles JIS B0601: average length of roughness curve element to be measured on the basis of the 2001 RSm (nm) is, is at 20nm or more 500nm or less,
When the standard deviation of the RSm and σRSm (nm), σRSm / RSm is a toner which is characterized in that 0.60 or less.
以下、本発明を詳細に説明する。本発明のトナーは、有機ケイ素重合体を含有する表面層を有するトナー粒子を含むトナーであって、前記有機ケイ素重合体は、下記式（１）又は（２）で表される部分構造を有し、
前記トナー粒子の表面のＸ線光電子分光分析において、前記トナー粒子の面の、炭素原子の濃度ｄＣ、酸素原子の濃度ｄＯ、及びケイ素原子の濃度ｄＳｉの合計を１００．０原子％としたときに、前記ケイ素原子の濃度ｄＳｉが、１．０原子％以上２２．２原子％以下であり、
前記トナー粒子の走査型プローブ顕微鏡で測定される粗さ曲線において、ＪＩＳ Ｂ０６０１：２００１に基づいて測定される算術平均粗さＲａ（ｎｍ）が、１０ｎｍ以上３００ｎｍ以下であり、
前記Ｒａの標準偏差をσＲａ（ｎｍ）としたとき、σＲａ／Ｒａが、０．６０以下であり、
前記粗さ曲線において、前記トナー粒子のＪＩＳ Ｂ０６０１：２００１に基づいて測定される粗さ曲線要素の平均長さＲＳｍ（ｎｍ）が、２０ｎｍ以上５００ｎｍ以下であり、
前記ＲＳｍの標準偏差をσＲＳｍ（ｎｍ）としたとき、σＲＳｍ／ＲＳｍが、０．６０以下であることを特徴とする。
Hereinafter, the present invention will be described in detail. The toner of the present invention is a toner including toner particles having a surface layer containing an organosilicon polymer, and the organosilicon polymer has a partial structure represented by the following formula (1) or (2). And
In X-ray photoelectron spectroscopic analysis of the surface of the toner particles, the surface of the toner particles, the concentration of carbon atoms dC, the concentration of oxygen atoms dO, and the total concentration dSi of the silicon atoms when the 100.0 atomic% , the concentration dSi of the silicon atoms is at 22.2 atomic% or less 1.0 atomic% or more,
In the roughness curve measured with a scanning probe microscope of the toner particles, JIS B0601: Arithmetic Average Roughness Ra (nm) measured on the basis of 2001, is a 10nm or more 300nm or less,
When the standard deviation of the Ra and σRa (nm), σRa / Ra is, is 0.60 or less,
In the roughness curve, the toner particles JIS B0601: average length of roughness curve element to be measured on the basis of the 2001 RSm (nm) is, is at 20nm or more 500nm or less,
When the standard deviation of the RSm and σRSm (nm), σRSm / RSm, characterized in that it is 0.60 or less.
本発明に係るトナー粒子は、ＪＩＳ Ｂ０６０１：２００１に基づいて測定される粗さ曲線要素の平均長さをＲＳｍ１とし、前記トナー粒子をスクロース溶液中で遠心分離にかけて、前記トナー粒子の表面への付着力が小さい粒子を分離除去したトナー粒子の、粗さ曲線要素の平均長さをＲＳｍ２としたとき、ＲＳｍ２／ＲＳｍ１が、１．２０以下であることが好ましい。 The toner particles according to the present invention have an average length of a roughness curve element measured based on JIS B0601: 2001, RSm1, and the toner particles are centrifuged in a sucrose solution to attach the toner particles to the surface of the toner particles. when the toner particles where the particles-adhesive strength is less separated was removed, and the average length of roughness curve element and RSM2, RSM2 / RSm1 is preferably 1.20 or less.
通常、トナー表面の粒子が一部外れた状態であるＲＳｍ２の値は、ＲＳｍ１に比べて大きくなる。ＲＳｍ２／ＲＳｍ１が大きいほど、トナー粒子表面の粒子がはがれやすく、トナーの転写性が変化しやすいことを示す。本発明のトナー粒子は、このＲＳｍ２／ＲＳｍ１が、１．２０以下であることが好ましく、１．１０以下であることがより好ましい。ＲＳｍ２／ＲＳｍ１が、１．２０以下であることにより、トナー粒子表面への付着力が小さい粒子の割合が少なく、耐久を通した転写性の変化がさらに小さいトナーを提供することができる。また、ＲＳｍ２／ＲＳｍ１が、１．１０以下であることにより、トナー粒子表面への付着力が小さい粒子の割合を１０％以下とさらに少なくすることができ、転写性の変化が小さくなるだけでなく、広範な環境下や厳しい使用条件下においても、優れた耐久性を有するトナーを得ることができる。ＲＳｍ２／ＲＳｍ１は、有機ケイ素重合体形成時におけるトナー粒子の製造方法、有機ケイ素重合体形成時の加水分解、重合時の反応温度、反応時間、反応溶媒及びｐＨ等を調整することによって、前記範囲に制御することができる。また、有機ケイ素重合体の含有量によっても制御することができる。さらに、トナー粒子表面に凹凸を形成させる工程における、前記有機ケイ素重合体と凹凸形成用微粒子の添加タイミング等を調整することによっても制御可能である。 Normally, the value of RSm2, which is a state in which some particles on the toner surface are removed, is larger than RSm1. As RSm2 / RSm1 is larger, particles on the surface of the toner particles are more easily peeled off, and the toner transferability is more likely to change. The toner particles of the present invention preferably have an RSm2 / RSm1 of 1.20 or less, more preferably 1.10 or less. RSM2 / RSm1 is, by 1.20 or less, the ratio of particles adhesion is less on the toner particle surfaces is small, it is possible to provide a toner smaller transfer of the change through the durability. Further, RSM2 / RSm1 is, by 1.10 or less, the ratio of particles adhesion is less on the toner particle surfaces can be further reduced to 10% or less, not only the transfer of the change is small In addition, a toner having excellent durability can be obtained even under a wide range of environments and severe use conditions. RSm2 / RSm1 is the above-mentioned range by adjusting the method for producing toner particles during the formation of the organosilicon polymer, the hydrolysis during the formation of the organosilicon polymer, the reaction temperature during the polymerization, the reaction time, the reaction solvent and the pH Can be controlled. It can also be controlled by the content of the organosilicon polymer. Further, it can be controlled by adjusting the addition timing of the organosilicon polymer and the fine particles for forming irregularities in the step of forming irregularities on the surface of the toner particles.
Claims (6)
前記有機ケイ素重合体は、下記式（１）又は（２）で表される部分構造を有し、
前記トナー粒子の表面のＸ線光電子分光分析において、前記トナー粒子の表面の、炭素原子の濃度ｄＣ、酸素原子の濃度ｄＯ、及びケイ素原子の濃度ｄＳｉの合計を１００．０原子％としたときに、前記ケイ素原子の濃度ｄＳｉが、１．０原子％以上２２．２原子％以下であり、
前記トナー粒子の走査型プローブ顕微鏡で測定される粗さ曲線において、ＪＩＳ Ｂ０６０１：２００１に基づいて測定される算術平均粗さＲａ（ｎｍ）が、１０ｎｍ以上３００ｎｍ以下であり、
前記Ｒａの標準偏差をσＲａ（ｎｍ）としたとき、σＲａ／Ｒａが、０．６０以下であり、
前記粗さ曲線において、前記トナー粒子のＪＩＳ Ｂ０６０１：２００１に基づいて測定される粗さ曲線要素の平均長さＲＳｍ（ｎｍ）が、２０ｎｍ以上５００ｎｍ以下であり、
前記ＲＳｍの標準偏差をσＲＳｍ（ｎｍ）としたとき、σＲＳｍ／ＲＳｍが、０．６０以下である
ことを特徴とするトナー。
The organosilicon polymer has a partial structure represented by the following formula (1) or (2):
In X-ray photoelectron spectroscopic analysis of the surface of the toner particles, wherein the surface of the toner particles, the concentration of carbon atoms dC, the concentration of oxygen atoms dO, and the total concentration dSi of the silicon atoms when the 100.0 atomic% , the concentration dSi of the silicon atoms is at 22.2 atomic% or less 1.0 atomic% or more,
In the roughness curve measured with a scanning probe microscope of the toner particles, JIS B0601: Arithmetic Average Roughness Ra (nm) measured on the basis of 2001, is a 10nm or more 300nm or less,
When the standard deviation of the Ra and σRa (nm), σRa / Ra is, is 0.60 or less,
In the roughness curve, the toner particles JIS B0601: average length of roughness curve element to be measured on the basis of the 2001 RSm (nm) is, is at 20nm or more 500nm or less,
When the standard deviation of the RSm and σRSm (nm), the toner, wherein the ShigumaRSm / RSm is 0.60 or less.
Ｒｆ−ＳｉＯRf-SiO ３／２3/2 （４） (4)
（式（４）において、Ｒｆは、下記式（ｉｉｉ）又は（ｉｖ）で表される部分構造を示す。）(In the formula (4), Rf represents a partial structure represented by the following formula (iii) or (iv).)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2016018906A JP6643121B2 (en) | 2016-02-03 | 2016-02-03 | toner |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2016018906A JP6643121B2 (en) | 2016-02-03 | 2016-02-03 | toner |
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| Publication Number | Publication Date |
|---|---|
| JP2017138462A JP2017138462A (en) | 2017-08-10 |
| JP2017138462A5 true JP2017138462A5 (en) | 2019-03-14 |
| JP6643121B2 JP6643121B2 (en) | 2020-02-12 |
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| JP2016018906A Active JP6643121B2 (en) | 2016-02-03 | 2016-02-03 | toner |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP7427550B2 (en) | 2019-07-25 | 2024-02-05 | キヤノン株式会社 | Process cartridges and electrophotographic equipment |
Families Citing this family (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US9733583B2 (en) * | 2015-04-08 | 2017-08-15 | Canon Kabushiki Kaisha | Toner |
| JP7163574B2 (en) * | 2017-11-17 | 2022-11-01 | コニカミノルタ株式会社 | Image forming method and toner set |
| JP7027180B2 (en) * | 2018-01-26 | 2022-03-01 | キヤノン株式会社 | toner |
| JP7261086B2 (en) * | 2018-05-31 | 2023-04-19 | キヤノン株式会社 | Process cartridges and electrophotographic equipment |
| JP7338011B2 (en) * | 2018-07-17 | 2023-09-04 | キヤノン株式会社 | Toner and toner manufacturing method |
| JP7130479B2 (en) | 2018-07-17 | 2022-09-05 | キヤノン株式会社 | toner |
| JP7080756B2 (en) | 2018-07-17 | 2022-06-06 | キヤノン株式会社 | Image forming device |
| JP7250487B2 (en) * | 2018-11-14 | 2023-04-03 | キヤノン株式会社 | Process cartridge and image forming apparatus |
| JP7321811B2 (en) * | 2019-07-25 | 2023-08-07 | キヤノン株式会社 | image forming device |
| JP7409168B2 (en) | 2020-03-09 | 2024-01-09 | 富士フイルムビジネスイノベーション株式会社 | Pressure-responsive particles, cartridge, apparatus for producing printed matter, method for producing printed matter, printed matter, sheet for producing printed matter, and method for producing sheet for producing printed matter |
| JP7458915B2 (en) | 2020-06-25 | 2024-04-01 | キヤノン株式会社 | toner |
| JP2022066092A (en) | 2020-10-16 | 2022-04-28 | キヤノン株式会社 | toner |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| JP3405036B2 (en) * | 1996-01-19 | 2003-05-12 | 富士ゼロックス株式会社 | Electrostatic toner and method for producing the same |
| JP2003345055A (en) * | 2002-05-29 | 2003-12-03 | Fuji Xerox Co Ltd | Electrostatic charge image developing toner and electrostatic charge image developing developer |
| JP6061671B2 (en) * | 2012-12-28 | 2017-01-18 | キヤノン株式会社 | toner |
| US20150037720A1 (en) * | 2013-07-31 | 2015-02-05 | Canon Kabushiki Kaisha | Magnetic toner |
| US9785077B2 (en) * | 2013-10-09 | 2017-10-10 | Canon Kabushiki Kaisha | Toner |
| JP6300631B2 (en) * | 2014-05-14 | 2018-03-28 | キヤノン株式会社 | Toner particle manufacturing method and toner manufacturing method |
| JP6316115B2 (en) * | 2014-06-26 | 2018-04-25 | キヤノン株式会社 | toner |
| JP6327972B2 (en) * | 2014-06-27 | 2018-05-23 | キヤノン株式会社 | toner |
| JP6366382B2 (en) * | 2014-06-27 | 2018-08-01 | キヤノン株式会社 | Toner production method |
| JP6366381B2 (en) * | 2014-06-27 | 2018-08-01 | キヤノン株式会社 | Toner production method |
| JP6316117B2 (en) * | 2014-06-27 | 2018-04-25 | キヤノン株式会社 | toner |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP7427550B2 (en) | 2019-07-25 | 2024-02-05 | キヤノン株式会社 | Process cartridges and electrophotographic equipment |
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