JP2017128542A - Cleansing cosmetic - Google Patents

Abstract

PROBLEM TO BE SOLVED: To provide a cleansing cosmetic having high cleansing properties and little irritation to the eyes, skin, or the like.SOLUTION: There is provided a cleansing cosmetic which is not washed away after use, in which the cleansing cosmetic comprises a polyoxyethylene fatty acid glyceryl as (A) component, a polyoxyethylene sorbitan fatty acid ester and/or a polyglyceryl fatty acid ester as (B) component, a polyoxyethylene polyoxypropylene alkyl ether as (C) component and a polyhydric alcohol as (D) component and the (B) component has an HLB value of 8 to 17. The (A) component preferably is polyoxyethylene (caprylic acid/capric acid) glyceryl.SELECTED DRAWING: None

Description

  The present invention relates to a cleansing cosmetic.

  2. Description of the Related Art Conventionally, cleansing cosmetics for removing oily dirt such as makeup such as foundation and lipstick attached to the skin are known.

  In addition to high cleansing properties (cleaning properties), cleansing cosmetics are required to have good usability and low irritation.

  As such a cleansing cosmetic, a lotion-type cleansing cosmetic that is not washed away is known (see, for example, Patent Document 1).

  However, although the cosmetic for cleansing of patent document 1 has the irritation | stimulation to eyes, skin, etc. suppressed, it did not fully provide the cleansing property.

  Further, for the purpose of improving cleansing properties, cleansing cosmetics using ionic surfactants are known (see, for example, Patent Document 2).

  However, the cleansing cosmetic of Patent Document 2 is not sufficient, although a slight improvement in cleansing properties is seen. Further, it was not sufficient from the viewpoint of irritation to eyes and skin.

JP 2010-70521 A JP 2014-201561 A

  An object of the present invention is to provide a cleansing cosmetic material having high cleansing properties and less irritation to eyes and skin.

Such an object is achieved by the present inventions (1) to (5) below.
(1) A cleansing cosmetic that does not wash away after use,
(A) Polyoxyethylene fatty acid glyceryl as a component;
(B) Polyoxyethylene sorbitan fatty acid ester and / or polyglycerin fatty acid ester as component,
(C) Polyoxyethylene polyoxypropylene alkyl ether as component,
(D) a polyhydric alcohol as a component,
A cleansing cosmetic, wherein the component (B) has an HLB value of 8 to 17.

  (2) The cleansing cosmetic according to (1), wherein the component (A) is polyoxyethylene (capric acid / caprylic acid) glyceryl.

  (3) The cleansing cosmetic according to (1) or (2), wherein the component (D) is at least one selected from the group consisting of propylene glycol, propanediol, and dipropylene glycol.

  (4) The cleansing makeup according to any one of (1) to (3), wherein the total amount of the component (A), the component (B), and the component (C) is 7% by mass or less. Fee.

  (5) The HLB value of the component (A) is a, the HLB value of the component (B) is b, the HLB value of the component (C) is c, and the blending amount of the component (A) is l [mass%]. When the blending amount of the component (B) is m [mass%], the blending amount of the component (C) is n [mass%], and the blending amount of the component (D) is o [mass%], 1 Cleansing according to any one of the above (1) to (4) satisfying the relationship of 2 ≦ [(a−12) × l + (b−12) × m + (c−12) × n] / o ≦ 12 Cosmetics.

  ADVANTAGE OF THE INVENTION According to this invention, the cosmetics for cleansing which have high cleansing property and there is little irritation | stimulation to eyes, skin, etc. can be provided.

Hereinafter, preferred embodiments of the cleansing cosmetic of the present invention will be described in detail.
In addition, the cleansing cosmetic material in the present specification may be in any form, and may be, for example, a liquid, a cream, or an emulsion.

  The cleansing cosmetic composition of the present invention is used for the purpose of removing oily and dirt such as makeup such as foundation and lipstick attached to the skin.

  Further, the cleansing cosmetic of the present invention does not need to be washed away after use. The polyoxyethylene fatty acid glyceryl as the component (A) and the polyoxyethylene sorbitan fatty acid ester as the component (B) and / or Or a polyglycerin fatty acid ester, a polyoxyethylene polyoxypropylene alkyl ether as the component (C), and a polyhydric alcohol as the component (D), and the HLB value of the component (B) is 8 to 17 It is characterized by being.

  By having such characteristics, oily and dirt such as makeup such as foundation and lipstick attached to the skin can be easily removed. Moreover, irritation | stimulation to eyes, skin, etc. can be suppressed effectively. Moreover, the cosmetics for cleansing with a favorable feeling of use can be provided.

Hereinafter, each component will be described in detail.
[(A) component]
The cleansing cosmetic composition of the present invention contains polyoxyethylene fatty acid glyceryl as the component (A). (A) A component is a component which contributes to the improvement of cleansing (cleaning) property.

  Specific examples of the polyoxyethylene fatty acid glyceryl include, for example, glyceryl polyoxyethylene caprylate, polyoxyethylene (capric / caprylic acid) glyceryl, polyoxyethylene glyceryl laurate, polyoxyethylene tallow fatty acid glyceryl, polyoxy Ethylene coconut oil fatty acid glycerin, polyoxyethylene mono coconut oil fatty acid glyceryl, etc. are mentioned, Among these, it can use 1 type or in combination of 2 or more types.

  Among these, it is preferable to use polyoxyethylene (capric acid / caprylic acid) glyceryl as the component (A). Thereby, irritation to eyes and skin can be more effectively suppressed. Moreover, cleansing property can be made higher.

  Although the HLB value of (A) component is not specifically limited, It is preferable that it is 12-19.5, and it is more preferable that it is 13-15. Thereby, cleansing property can be made higher. In addition, irritation to eyes and skin can be more effectively suppressed.

  The amount of component (A) is preferably 0.5 to 7.0% by mass, more preferably 1.0 to 4.0% by mass. Thereby, the usability | use_condition of the cosmetics for cleansing can be improved more. Moreover, cleansing property can be made higher while suppressing irritation to eyes and skin.

[Component (B)]
The cleansing cosmetic composition of the present invention contains polyoxyethylene sorbitan fatty acid ester and / or polyglycerin fatty acid ester as component (B). Moreover, the HLB value of (B) component is 8-17.

  Such polyoxyethylene sorbitan fatty acid ester and polyglycerin fatty acid ester are components that have higher cleansing properties and gentle irritation to eyes and skin.

  Examples of the polyoxyethylene sorbitan fatty acid ester include polyoxyethylene sorbitan monooleate (20E.O.), polyoxyethylene sorbitan monooleate (6E.O.), and polyoxyethylene sorbitan monolaurate (6E.O.O.). ), Polyoxyethylene sorbite tetraoleate (40E.O.), polyoxyethylene sorbite tetraoleate (30E.O.), polyoxyethylene sorbitan monostearate (6E.O.), polyoxyethylene sorbitan monolaurate (20E.O.), polyoxyethylene sorbitan monopalmitate (20E.O.), polyoxyethylene sorbitan monostearate (20E.O.), polyoxyethylene sorbitan tristearate (20E.O.), Examples thereof include polyoxyethylene sorbitan (20E.O.) lyoleate, polyoxyethylene sorbitan triisostearate (160E.O.), polyoxyethylene sorbite tetraoleate (60E.O.), etc. Among these, 1 Species or a combination of two or more can be used.

  Examples of the polyglyceryl fatty acid ester include polyglyceryl-6 myristate, polyglyceryl-10 laurate, polyglyceryl-10 linoleate, polyglyceryl laurate-4, polyglyceryl-4 oleate, polyglyceryl-4 isostearate, polyglyceryl laurate -6, Polyglyceryl-6 stearate, Polyglyceryl-6 isostearate, Polyglyceryl-6 oleate, Polyglyceryl-10 myristate, Polyglyceryl-10 oleate, Polyglyceryl-10 palmitate, Polyglyceryl-10 stearate, Polyglyceryl-10 distearate , Polyglyceryl-10 diisostearate, polyglyceryl-10 tristearate, polyglyceryl-10 isostearate, etc. Among these may be used alone or in combination.

  The HLB value of the component (B) as described above is 8 to 17, but more preferably 9 to 16. Thereby, the effect of this invention can be made more remarkable.

  (B) It is preferable that the compounding quantity of a component is 0.3-6.0 mass%, and it is more preferable that it is 0.5-4.0 mass%. Thereby, the irritation to eyes, skin, etc. can be suppressed more efficiently. Moreover, the usability of the cleansing cosmetic can be further improved.

[Component (C)]
The cleansing cosmetic composition of the present invention contains polyoxyethylene polyoxypropylene alkyl ether as the component (C). Polyoxyethylene polyoxypropylene alkyl ether is a component having a function of moisturizing the skin in addition to improving cleansing properties.

  Examples of the polyoxyethylene polyoxypropylene alkyl ether include polyoxyethylene polyoxypropylene glycol (10E.O.) (2PO), polyoxyethylene polyoxypropylene glycol (10E.O.) (30PO). .), Polyoxyethylene polyoxypropylene glycol (10E.O.) (65P.O.), polyoxyethylene polyoxypropylene glycol (10E.O.) (70P.O.), polyoxyethylene polyoxypropylene glycol (12E.O.) (35P.O.), polyoxyethylene polyoxypropylene glycol (150E.O.) (30P.O.), polyoxyethylene polyoxypropylene glycol (150E.O.) (35P.O.) .), Polyoxyethylene Reoxypropylene glycol (160E.O.) (30P.O.), polyoxyethylene polyoxypropylene glycol (160E.O.) (31P.O.), polyoxyethylene polyoxypropylene glycol (16E.O.) (17 PO), polyoxyethylene polyoxypropylene glycol (16 EO) (30 PO), polyoxyethylene polyoxypropylene glycol (190 EO) (60 PO), polyoxyethylene Polyoxypropylene glycol (19E.O.) (21P.O.), polyoxyethylene polyoxypropylene glycol (1E.O.) (2P.O.), polyoxyethylene polyoxypropylene glycol (200E.O.) (40 PO), polyoxyethylene polio Cypropylene glycol (200E.O.) (70P.O.), polyoxyethylene polyoxypropylene glycol (20E.O.) (20P.O.), polyoxyethylene polyoxypropylene glycol (20E.O.) ( 60 P.O.), polyoxyethylene polyoxypropylene glycol (20E.O.) (65P.O.), polyoxyethylene polyoxypropylene glycol (20E.O.) (9P.O.), polyoxyethylene poly Oxypropylene glycol (22E.O.) (16P.O.), polyoxyethylene polyoxypropylene glycol (22E.O.) (21P.O.), polyoxyethylene polyoxypropylene glycol (22E.O.) ( 25 PO), polyoxyethylene polyoxypropylene Glycol (23E. O. ) (17 P.O.), polyoxyethylene polyoxypropylene glycol (23E.O.) (21 P.O.), polyoxyethylene polyoxypropylene glycol (240E.O.) (60 P.O.), polyoxy Ethylene polyoxypropylene glycol (25E.O.) (30P.O.), polyoxyethylene polyoxypropylene glycol (26E.O.) (30P.O.), polyoxyethylene polyoxypropylene glycol (26E.O.) ) (31 PO), polyoxyethylene polyoxypropylene glycol (28 EO) (30 PO), polyoxyethylene polyoxypropylene glycol (300 EO) (55 PO), polyoxy Ethylene polyoxypropylene glycol (30E.O.) (3 PO), polyoxyethylene polyoxypropylene glycol (30E.O.) (35P.O.), polyoxyethylene polyoxypropylene glycol (30E.O.) (55P.O.), polyoxyethylene poly Oxypropylene glycol (35E.O.) (40P.O.), polyoxyethylene polyoxypropylene glycol (38E.O.) (30P.O.), polyoxyethylene polyoxypropylene glycol (3E.O.) ( 17 P.O.), polyoxyethylene polyoxypropylene glycol (40E.O.) (54P.O.), polyoxyethylene polyoxypropylene glycol (48E.O.) (35P.O.), polyoxyethylene poly Oxypropylene glycol (4E.O.) (2P.O.), PO Oxyethylene polyoxypropylene glycol (50 EO) (40 PO), polyoxyethylene polyoxypropylene glycol (5 EO) (30 PO), polyoxyethylene polyoxypropylene glycol (5 EO) .) (35 P.O.), polyoxyethylene polyoxypropylene glycol (6E.O.) (2P.O.), polyoxyethylene polyoxypropylene glycol (6E.O.) (30 P.O.), poly Oxyethylene polyoxypropylene glycol (7E.O.) (50P.O.), polyoxyethylene polyoxypropylene glycol (8E.O.) (17P.O.), polyoxyethylene polyoxypropylene glycol (8E.O.) .) (55PO), polyoxyethylene polyoxyp Lopylene glyceryl ether (24E. O. ) (24PO), polyoxyethylene polyoxypropylene stearyl ether, polyoxyethylene polyoxypropylene stearyl ether (34EO) (23PO), polyoxyethylene polyoxypropylene cetyl ether, polyoxyethylene Polyoxypropylene cetyl ether (10E.O.) (1P.O.), polyoxyethylene polyoxypropylene cetyl ether (10E.O.) (2P.O.), polyoxyethylene polyoxypropylene cetyl ether (10E.O.) O.) (4P.O.), polyoxyethylene polyoxypropylene cetyl ether (10E.O.) (8P.O.), polyoxyethylene polyoxypropylene cetyl ether (1E.O.) (1P.O.). ), Polyoxyethylene polyoxy Propylene cetyl ether (1E.O.) (2P.O.), polyoxyethylene polyoxypropylene cetyl ether (1E.O.) (4P.O.), polyoxyethylene polyoxypropylene cetyl ether (1E.O.) ) (8P.O.), polyoxyethylene polyoxypropylene cetyl ether (20E.O.) (1P.O.), polyoxyethylene polyoxypropylene cetyl ether (20E.O.) (2P.O.), Polyoxyethylene polyoxypropylene cetyl ether (20E.O.) (4P.O.), polyoxyethylene polyoxypropylene cetyl ether (20E.O.) (8P.O.), polyoxyethylene polyoxypropylene cetyl ether (5E.O.) (1P.O.), polyoxyethylene polyoxy Lopylene cetyl ether (5E.O.) (2P.O.), polyoxyethylene polyoxypropylene cetyl ether (5E.O.) (4P.O.), polyoxyethylene polyoxypropylene cetyl ether (5E.O.) (8PO), polyoxyethylene polyoxypropylene butyl ether, polyoxyethylene polyoxypropylene butyl ether (10E.O.) (7PO), polyoxyethylene polyoxypropylene butyl ether (12E.O.) ( 12P.O.), polyoxyethylene polyoxypropylene butyl ether (17E.O.) (17P.O.), polyoxyethylene polyoxypropylene butyl ether (20E.O.) (15P.O.), polyoxyethylene poly Oxypropylene butyl ether ( 2E. O. ) (2P.O.), polyoxyethylene polyoxypropylene butyl ether (30E.O.) (30P.O.), polyoxyethylene polyoxypropylene butyl ether (35E.O.) (28P.O.), polyoxy Ethylene polyoxypropylene butyl ether (36E.O.) (36P.O.), polyoxyethylene polyoxypropylene butyl ether (37E.O.) (38P.O.), polyoxyethylene polyoxypropylene butyl ether (45E.O.) ) (33 P.O.), polyoxyethylene polyoxypropylene butyl ether (4E.O.) (4P.O.), polyoxyethylene polyoxypropylene butyl ether (5E.O.) (5P.O.), polyoxy Ethylene polyoxypropylene butyl ether ( E.O.) (10P.O.), And the like, among these, can be used alone or in combination.

  Although the HLB value of (C) component is not specifically limited, It is preferable that it is 4-18, and it is more preferable that it is 8-17. Thereby, cleansing property can be made higher. In addition, irritation to eyes and skin can be more effectively suppressed.

  (C) It is preferable that the compounding quantity of a component is 0.05-3.0 mass%, and it is more preferable that it is 0.1-1.5 mass%. Thereby, the usability | use_condition of the cosmetics for cleansing can be improved more. In addition, irritation to eyes and skin can be more efficiently suppressed.

  The total amount of the component (A), the component (B) and the component (C) described above is preferably 7.0% by mass or less, and more preferably 3.0 to 6.0% by mass. . Thereby, the irritation to eyes and skin can be suppressed more effectively.

[(D) component]
The cleansing cosmetic composition of the present invention contains a polyhydric alcohol as the component (D).

  Polyhydric alcohol is a component that contributes to moisturizing the skin and has a function of reducing irritation to eyes and skin. The polyhydric alcohol is also a component that contributes to the stability of the cleansing cosmetic.

  The component (D) is not particularly limited as long as it is a polyhydric alcohol, but among the polyhydric alcohols, it is preferable to use at least one selected from the group consisting of propylene glycol, propanediol, and dipropylene glycol. Thereby, the irritation to eyes, skin, etc. can be relieved more effectively.

  (D) It is preferable that the compounding quantity of a component is 0.3-6.0 mass%, and it is more preferable that it is 1.0-4.0 mass%. Thereby, the usability | use_condition of the cosmetics for cleansing can be improved more. In addition, irritation to eyes and skin can be more efficiently suppressed.

  As described above, the HLB value of the component (A) is a, the HLB value of the component (B) is b, the HLB value of the component (C) is c, and the blending amount of the component (A) is l [mass%]. When the blending amount of the component (B) is m [mass%], the blending amount of the component (C) is n [mass%], and the blending amount of the component (D) is o [mass%], 1 It is preferable that the relationship of 2 ≦ [(a−12) × l + (b−12) × m + (c−12) × n] / o ≦ 12 is satisfied. By satisfying such a relationship, the balance between high cleansing properties and low irritation properties can be improved.

[Other ingredients]
In addition to the above ingredients, the cleansing cosmetic composition of the present invention can be blended with base ingredients and medicinal ingredients that are usually used according to the purpose and dosage form.

  Examples of such base ingredients and medicinal ingredients include amino acids, vitamins, minerals and synthetic oils, animal and vegetable oils, waxes, fatty acids, alcohols, ester oils, polymer compounds, animal and plant extracts, solvents, anti-inflammatory agents, antiseptics Agents, ultraviolet light inhibitors, sequestering agents, antioxidants, pH adjusters, dyes / pigments, powders, film forming agents, fragrances, and the like, and can be blended within a range that does not impair the effects of the present invention. Specific examples thereof are given below.

(amino acid)
The cleansing cosmetic composition of the present invention may contain amino acids.

  As amino acids, for example, L-alanine, L-arginine, L-aspartic acid, L-glutamine, L-asparagine, L-cysteine, L-serine, L-tyrosine, L-proline, pyrrolidone carboxylate, glycine , Valine, leucine, isoleucine, threonine, methionine, phenylalanine, tryptophan, lysine, cystine, hydroxyproline, hydroxylysine, ornithine, histidine, γ-aminobutyric acid, ε-aminocaproic acid, etc. Two or more kinds can be used in combination. Among these, it is particularly preferable to use glycine.

(Vitamins)
The cleansing cosmetic composition of the present invention may contain vitamins.

  Examples of vitamins include retinol, retinoic acid, vitamin A oil, retinol acetate, retinol palmitate, hydrogenated retinol, β-carotene, lycopene, astaxanthin, lutein, cryptoxanthine, pyridoxine hydrochloride, pyridoxine dicaprylate, biotin, nicotine Acid, nicotinamide, benzyl nicotinate, riboflavin, folic acid, calcium pantothenate, D-pantothenyl alcohol, pantothenyl ethyl ether, ascorbic acid, ascorbyl palmitate, L-ascorbyl magnesium phosphate, ascorbyl tetra-2-hexyldecanoate, L-ascorbic acid 2-glucoside, ascorbyl-2-phosphate sodium palmitate, ascorbyl ethyl, ergocalciferol, dl-α-tocophero , Dl-α-tocopherol acetate, natural vitamin E, ubiquinone, carnitine, α-lipoic acid, vitamin P (hesperidin, methyl hesperidin, rutin), and the like. Among these, one or a combination of two or more Can be used. Among these, by including at least one selected from the group consisting of dl-α-tocopherol, dl-α-tocopherol acetate, and natural vitamin E, the above effect can be made more remarkable.

(Mineral / Synthetic oil)
Examples of the mineral / synthetic oil include liquid paraffin, liquid isoparaffin, petrolatum, paraffin, ceresin, microstalin wax, α-olefin oligomer, polyethylene, polybutene, and synthetic squalane. A combination of the above can be used.

(Animal and vegetable oil)
As animal and vegetable oils, for example, squalane, olive oil, camellia oil, wheat germ oil, jojoba oil, avocado oil, carrot oil, shea fat, liquid shea fat, palm oil, palm kernel oil, hydrogenated oil, horse oil, lanolins Egg yolk oil, clove oil, rosehip oil, lavender oil, peppermint oil, spearmint oil, rosemary oil, macadamia nut oil, apricot oil, safflower oil, safflower oil (2), sunflower oil, sunflower oil (2), Medu home oil, almond oil, sesame oil, sesame oil, borage oil, cacao butter, rice bran oil, rice germ oil, fennel oil, orange oil, chamomile oil, cucumber oil, kukui nut oil, soybean oil, tea tree oil, corn oil, Rapeseed oil, persic oil, castor oil, cottonseed oil, peanut oil, turtle oil, mink oil, Arganian spinosa kernel oil, clay Bare vicinica seed oil, almond oil, peach seed oil, grape seed oil, emu oil, mink oil, Asa seed oil, flaxseed oil, sasanqua oil, owl, coconut oil, evening primrose oil, pistachio seed oil, mango butter, etc. Among them, one kind or a combination of two or more kinds can be used.

(Wax)
Examples of the waxes include jojoba oil, beeswax, carnauba wax, rice bran wax, whale wax, lanolin, liquid lanolin, reduced lanolin, hard lanolin, candelilla wax, montan wax, shellac, orange luffy oil, etc. One kind or a combination of two or more kinds can be used.

(fatty acid)
Examples of fatty acids include lauric acid, myristic acid, palmitic acid, stearic acid, oleic acid, isostearic acid, behenic acid, linoleic acid, linolenic acid, docosahexaenoic acid, eicosapentaenoic acid, 12-hydroxystearic acid, undecylenic acid, lanolin Examples include natural fatty acids such as fatty acids, synthetic fatty acids such as isononanoic acid, caproic acid, 2-ethylbutanoic acid, isopentanoic acid, 2-methylpentanoic acid, and isopentanoic acid. Can be used.

(alcohol)
Examples of the alcohol include ethanol, isopropanol, butyl alcohol, benzyl alcohol, lauryl alcohol, myristyl alcohol, cetanol, cetostearyl alcohol, stearyl alcohol, isostearyl alcohol, oleyl alcohol, hexyl decanol, behenyl alcohol, octyldodecanol, lanolin alcohol, cholesterol , Phytosterol, 2-hexyldecanol, 2-octyldodecanol, batyl alcohol, and the like. Among these, one kind or two or more kinds can be used in combination.

(Ester oil)
Examples of ester oils include glyceryl tricaprylate, glyceryl tri-2-ethylhexanoate, isononyl isononanoate, ethylene glycol dioctanoate, glyceryl tri (caprylate / caprate), isopropyl myristate, butyl myristate, isopropyl palmitate, stearin Ethyl acetate, butyl stearate, ethyl oleate, ethyl linoleate, isopropyl linoleate, cetyl caprylate, decyl myristate, hexyl laurate, myristyl myristate, cetyl myristate, cetyl palmitate, stearyl stearate, oleyl oleate , Decyl oleate, cetyl ricinoleate, isostearyl laurate, isotridecyl myristate, isocetyl myristate, isostearyl myristate 2-octyldodecyl myristate, ethylhexyl palmitate, isocetyl palmitate, ethylhexyl stearate, isocetyl stearate, isodecyl oleate, 2-octyldodecyl oleate, 2-octyldodecyl ricinoleate, ethyl isostearate, isopropyl isostearate, octane Cetyl acid, cetostearyl octoate, stearyl octoate, hexyl isostearate, ethylene glycol dioleate, propylene glycol dicaprate, propylene glycol di (capryl / caprate), propylene glycol dioleate, neopentyl glycol dicaprate, di-2- Neopentyl glycol ethylhexanoate, glyceryl triundecylate, glyceryl triisopalmitate, Glyceryl isostearate, trimethylolpropane tri-2-ethylhexanoate, trimethylolpropane triisostearate, pentaerythritol tetra2-ethylhexanoate, pentaerythritol tetramyristate, pentaerythritol tetraisostearate, 2-octyldodecyl neopentanoate, octane Isocetyl acid, isostearyl octoate, ethylhexyl isopearate, 2-hexyldecyl neodecanoate, 2-octyldodecyl neodecanoate, ethylhexyl isopalmitate, isocetyl isostearate, isostearyl isostearate, 2-octyldodecyl isostearate, lauryl lactate, Myristyl lactate, cetyl lactate, 2-octyldodecyl lactate, triethyl citrate, acetyl citrate Rutriethyl, acetyl tributyl citrate, tri-2-ethylhexyl citrate, triisocetyl citrate, tri-2-octyldodecyl citrate, diisostearyl malate, 2-ethylhexyl hydroxystearate, dioctyl succinate, diisopropyl adipate, diisobutyl adipate Dioctyl adipate, diethyl sebacate, diisopropyl sebacate, dioctyl sebacate, dibutyl octyl sebacate, cholesteryl isostearate, cholesteryl hydroxystearate, cholesteryl oleate, dihydrocholesteryl oleate, phytosteryl isostearate, oleic acid Phytosteryl, hexyldecyl dimethyloctanoate, cetyl lactate, diethyl phthalate, phthalic acid Butyl, dialkyl carbonate, and the like, among these, can be used alone or in combination.

(Polymer compound)
Examples of the polymer compound include sodium alginate, carrageenan, agar, far celerin, guar gum, quince seed, konjac mannan, tamarind gum, tara gum, dextrin, starch, locust bean gum, gum arabic, gati gum, caraya gum, tragacanth gum, arabinogalactan , Pectin, quince, wheat protein, soy protein, albumin, casein, gelatin, chitosan, hyaluronic acid, curdlan, xanthan gum, gellan gum, cyclodextrin, dextran, pullulan, hyaluronic acid, synthetic sodium silicate / magnesium, crystalline cellulose, methylcellulose , Ethylcellulose, hydroxyethylcellulose, hydroxypropylcellulose, hydroxypropylmethylcellulose Loin, carboxymethylcellulose, cationized cellulose, cationized guar gum, hydroxypropylated guar gum, carboxyvinyl polymer, acrylic acid / alkyl methacrylate copolymer, polyacrylic acid amide, sodium polyacrylate, polyethyleneimine, highly polymerized polyethylene glycol, Polyvinyl alcohol, polyvinyl pyrrolidone, etc. are mentioned, Among these, it can be used 1 type or in combination of 2 or more types.

(Animal and plant extracts)
Examples of animal and plant extracts include cattle or pigs, horse-derived placenta extract, elastin and its degradation product (hydrolyzed elastin) or derivatives thereof, cow or pig, fish-derived collagen and its degradation product (hydrolyzed collagen). Or derivatives thereof (hydrolyzed collagen ethyl, N- [2-hydroxy-3- (trimethylammonio) propyl chloride] hydrolyzed collagen, N- [2-hydroxy-3- (stearyldimethylammonio) propyl] hydrochloride Degraded collagen, N- [2-hydroxy-3- (coconut oil alkyldimethylammonio) propyl] hydrolyzed collagen, N- [2-hydroxy-3- (lauryldimethylammonio) propyl chloride hydrolyzed collagen), Silk and its degradation products (hydrolyzed silk) or their Conductor (N- [2-hydroxy-3- (trimethylammonio) propyl chloride) hydrolyzed silk fluid, N- [2-hydroxy-3- (stearyldimethylammonio) propyl chloride] hydrolyzed silk, N- [chloride chloride 2-hydroxy-3- (coconut oil alkyldimethylammonio) propyl] hydrolyzed silk solution, N- [2-hydroxy-3- (lauryldimethylammonio) propyl] hydrolyzed silk chloride), conchiolin and its degradation products ( Hydrolyzed conchiolin solution) or derivatives thereof (N- [2-hydroxy-3- (trimethylammonio) propyl chloride) hydrolyzed conchiolin solution), yeast extract, aloe extract, chamomile extract, comfrey extract, peonies extract, perilla extract , Ginger extract, ginger root extract, sage extract, Kumbu extract, Senkyu extract, Sakuhakuhi extract, Soybean fermented extract, Clove extract, Chimpi extract, Pepper extract, Toki extract, Spruce extract, Dokudami extract, Carrot extract, Garlic extract, Loofah extract, Hamamelis water, Hikikoshi extract, Hop extract, Maronier extract, Peach leaf extract, Yukinoshita extract, Eucalyptus extract, Yuzu extract, Melissa extract, Artemisia extract, Yokuinin extract, Novara extract, Rosemary extract, Royal jelly extract, Seaweed extract (1), Seaweed extract (2), Seaweed extract (3), Seaweed extract (4), rice bran fermented extract, and the like, and among these, one kind or two or more kinds can be used in combination.

(solvent)
Examples of the solvent include purified water, normal water, isopropanol, benzyl alcohol, and the like. Among these, one kind or a combination of two or more kinds can be used.

(Anti-inflammatory agent)
Examples of the anti-inflammatory agent include glycyrrhizic acid, dipotassium glycyrrhizinate, monoammonium glycyrrhizinate, glycyrrhetinic acid, stearyl glycyrrhetinate, guaiazulene, sodium guaiazulenesulfonate, allantoin, and ε-aminocaproic acid. Alternatively, two or more kinds can be used in combination.

(Preservative)
Examples of the preservatives include methyl paraben, ethyl paraben, propyl paraben, butyl paraben, isobutyl paraben, phenoxyethanol, bisabolol, hinokitiol, benzoic acid, sodium benzoate, salicylic acid, sodium salicylate, sorbic acid, potassium sorbate, undecylenic acid, and pionein. , L-menthol, d-camphor, isopropylmethylphenol, benzethonium chloride, alkyldiaminoethylglycine hydrochloride, and the like. Among these, one kind or two or more kinds can be used in combination.

(UV protection agent)
Examples of UV inhibitors include paraaminobenzoic acid, ethyl paraaminobenzoate, glyceryl paraaminobenzoate, 2-ethylhexyl paradimethylaminobenzoate, oxybenzone, dihydroxybenzophenone, dihydroxydimethoxybenzophenone, sodium dihydroxydimethoxybenzophenone sulfonate, hydroxymethoxybenzophenone Examples thereof include sodium sulfonate, octyl salicylate, 4-tert-butyl-4′-methoxy-dibenzoylmethane, ferulic acid, titanium oxide, fine particle titanium oxide, zinc oxide, and fine particle zinc oxide. Two or more kinds can be used in combination.

(Metal sequestering agent)
Examples of the sequestering agent include edetic acid, edetate, trisodium ethylenediaminehydroxyethyl triacetate, diethylenetriaminepentaacetic acid, pentasodium diethylenetriaminepentaacetate, ethylenediaminetetrakis (2-hydroxyisopropyl) dioleate, hydroxyethanediphosphone. An acid solution, hydroxyethane diphosphonic acid tetrasodium solution, a phytic acid, etc. are mentioned, Among these, it can use 1 type or in combination of 2 or more types.

(Antioxidant)
Examples of the antioxidant include dibutylhydroxytoluene, butylhydroxyanisole, erythorbic acid, propyl gallate, d-δ-tocopherol, etc. Among these, one or a combination of two or more can be used. .

(PH adjuster)
Examples of the pH adjuster include citric acid, glycolic acid, malic acid, tartaric acid, lactic acid, succinic acid, phosphoric acid and salts thereof. Among these, one or a combination of two or more may be used. it can.

(Pigment)
Examples of organic pigments include azo pigments and phthalocyanine pigments, and laked ones are also used. Examples of the organic pigment include red pigment 201, red 202, red 205, red 226, red 228, orange 203, orange 204, blue 404, yellow 401 and the like, red 3 , Red 104, red 106, orange 205, yellow 4, yellow 5, green 3, blue 1, etc., zirconium, barium or aluminum lakes, etc., inorganic silica, anhydrous silicic acid, magnesium silicate , Talc, kaolin, bentonite, mica, mica titanium, bismuth oxychloride, zirconium oxide, magnesium oxide, zinc oxide, titanium oxide, calcium carbonate, magnesium carbonate, yellow iron oxide, bengara, black iron oxide, gunjo, chromium oxide, water Examples include chromium oxide, carbon black, calamine, cerium oxide, barium sulfate iron oxide, and bitumen. It is.

(Other)
Urea, ellagic acid, yeast (yeast extract (1), yeast extract (2), yeast extract (3)) and its degradation products (hydrolyzing yeast), potato starch, talc, corn starch, seawater dried product, seawater dried product Powder (2), ethylene glycol fatty acid ester, mica, distearic acid, ethylene glycol distearate, glycol stearate, sodium cocoamphoacetate, polyethylene glycol 600, iron oxide, titanium oxide, mica with titanium oxide or iron oxide Pearling agents such as coated ones

  Although the cleansing cosmetic of the present invention has been described above, the present invention is not limited to this.

Next, specific examples of the present invention will be described.
(Examples 1-8, Comparative Examples 1-6)
Using the components and blending amounts shown in Table 1, a cleansing cosmetic (lotion) was produced according to the above.

  In Table 1, (caprylic acid / capric acid) PEG-6 glyceryl (polyoxyethylene (capric acid / caprylic acid) glyceryl, HLB value: 14) is A1, (caprylic acid / capric acid) PEG-8 glyceryl ( Polyoxyethylene (capric acid / caprylic acid) glyceryl, HLB value: 15) A2, coconut oil fatty acid PEG-7 glyceryl (polyoxyethylene coconut oil fatty acid glycerin, HLB value: 13) A3, polyoxyethylene monooleate Sorbitan (20E.O.) (HLB value: 15) is B1, monooleic acid polyoxyethylene sorbitan (6E.O.) (HLB value: 10) is B2, monolauric acid polyoxyethylene sorbitan (6E.O.) (HLB value: 13.3) is B3, polyoxyethylene sorbitol tetraoleate 40E.O.) (HLB value: 11.8) as B4, tetraoleic acid polyoxyethylene sorbite (30E.O.) (HLB value: 10.5) as B5, and polyoxyethylene sorbitan monostearate (6E.O.). O.) (HLB value: 9.6) B6, polyglyceryl laurate-10 (HLB value: 15.5) B7, polyglyceryl oleate-4 (HLB value: 6) B8, polyoxyethylene polyoxypropylene Cetyl ether (1E.O.) (4P.O.) (HLB value: 9.5) is C1, polyoxyethylene polyoxypropylene cetyl ether (20E.O.) (4P.O.) (HLB value: 16) .5) is C2, polyoxyethylene polyoxypropylene decyl ether (30E.O.) (2P.O.) (HLB value: 15) is C3, poly Alkoxy polyoxypropylene decyl ether (HLB value: 14) (20E.O.) (2P.O.) Are shown as C4.

  The value of [(a-12) × l + (b−12) × m + (c−12) × n] / o is indicated by X.

<Evaluation>
[Evaluation of cleansing power]
0.03 g of lipstick (trade name: Facio Airy Sturgeon, manufactured by Kose) was uniformly spread over the entire surface of commercially available white synthetic leather (urethane) 2 cm × 10 cm and dried in a desiccator at 25 ° C. for 2 hours. . Next, the cleansing cosmetic 0.5 mL obtained in each example and each comparative example was impregnated into 1.5 cm × 1.5 cm cotton, and using a friction tester (KES-SE, manufactured by Kato Tech Co., Ltd.), The sample-containing cotton was subjected to a load of 25 gf and reciprocated once on a synthetic leather at a stroke of 4 cm.

  In addition, evaluation evaluated according to the following evaluation criteria using (DELTA) E * which analyzed the removal rate of the lipstick in synthetic leather with the colorimeter.

<Evaluation criteria for removing makeup dirt (foundation)>
◎: ΔE * is 45 or more ○: ΔE * is 40 or more and less than 45 Δ: ΔE * is 35 or more and less than 40 ×: ΔE * is less than 35

[Irritation evaluation]
20 female evaluation panels with makeup were impregnated with cotton with the cleansing cosmetics obtained in each of the examples and comparative examples and used to actually wipe off the makeup. Sensory evaluation was performed according to the following evaluation criteria for “stimulation” and “ocular mucosal irritation”. The term “eye / skin irritation” refers to a temporary “feeling of tingling” or “tingling” that is felt on the eyes or skin from 5 minutes after cleansing.

<Evaluation criteria for eye and skin irritation>
◎: More than 16 out of 20 responded that there was no eye and skin irritation. ○: 11-15 out of 20 responded that there was no eye and skin irritation. No answer ×: 5 or less out of 20 responded that there was no eye or skin irritation. The results are shown in Table 1.

As is clear from Table 1, the cleansing cosmetic of the present invention was excellent in cleansing properties. Further, the cleansing cosmetic of the present invention was less irritating. On the other hand, in the comparative example, sufficient results were not obtained.
Moreover, the cosmetics for cleansing of each Example were excellent in the usability.

Claims (5)

A cleansing cosmetic that does not wash away after use,
(A) Polyoxyethylene fatty acid glyceryl as a component;
(B) Polyoxyethylene sorbitan fatty acid ester and / or polyglycerin fatty acid ester as component,
(C) Polyoxyethylene polyoxypropylene alkyl ether as component,
(D) a polyhydric alcohol as a component,
A cleansing cosmetic, wherein the component (B) has an HLB value of 8 to 17.   The cleansing cosmetic according to claim 1, wherein the component (A) is polyoxyethylene (capric acid / caprylic acid) glyceryl.   The cleansing cosmetic according to claim 1 or 2, wherein the component (D) is at least one selected from the group consisting of propylene glycol, propanediol, and dipropylene glycol.   The cleansing cosmetic according to any one of claims 1 to 3, wherein the total amount of the component (A), the component (B), and the component (C) is 7.0% by mass or less.   The HLB value of the component (A) is a, the HLB value of the component (B) is b, the HLB value of the component (C) is c, the blending amount of the component (A) is l [mass%], When the blending amount of component B) is m [mass%], the blending amount of component (C) is n [mass%], and the blending amount of component (D) is o [mass%], 1.2 ≦ The cleansing cosmetic composition according to any one of claims 1 to 4, which satisfies a relationship of [(a-12) × l + (b-12) × m + (c-12) × n] / o ≦ 12.