JP2017100435A5 - - Google Patents

Claims (13)

The first hard coat, the second hard coat, and the transparent resin sheet layer in order from the surface side,
The first hard coat is
(A) Polyfunctional (meth) acrylate 100 parts by mass;
(B) Water repellent 0.01 to 7 parts by mass; and (C) Silane coupling agent 0.01 to 10 parts by mass;
Consisting of a paint containing no inorganic particles;
The second hard coat is
(A) Polyfunctional (meth) acrylate 100 parts by mass; and (D) 50 to 300 parts by mass of inorganic fine particles having an average particle diameter of 1 to 300 nm;
Made of paint containing;
The transparent resin sheet has a thickness of 0.2 mm or more;
Transparent resin laminate.
The transparent resin laminate according to claim 1, wherein the (C) silane coupling agent includes one or more selected from the group consisting of a silane coupling agent having an amino group and a silane coupling agent having a mercapto group. body.
The transparent resin laminate according to claim 1, wherein the water repellent (B) includes a (meth) acryloyl group-containing fluoropolyether water repellent.
The transparent resin laminate according to any one of claims 1 to 3, wherein the coating material forming the second hard coat further comprises (E) a leveling agent in an amount of 0.01 to 1 part by mass.
The hard coat laminated film according to claim 1, wherein the (D) inorganic fine particles having an average particle size of 1 to 300 nm include silica fine particles.
The first hard coat, the second hard coat, and the transparent resin sheet layer in order from the surface side,
The first hard coat is made of a coating containing no inorganic particles;
The second hard coat is made of a coating containing inorganic particles;
The transparent resin sheet has a thickness of 0.2 mm or more;
A transparent resin laminate satisfying the following (A) to (C).
(A) Total light transmittance is 80% or more.
(B) Haze 5% or less.
(C) Yellowness index: 3 or less.
The first hard coat, the second hard coat, and the transparent resin sheet layer in order from the surface side,
The first hard coat is made of a coating containing no inorganic particles;
The second hard coat is made of a coating containing inorganic particles;
The transparent resin sheet has a thickness of 0.2 mm or more;
A transparent resin laminate satisfying the following (d) and (e).
(D) The water contact angle on the surface of the first hard coat is 100 degrees or more.
(E) The water contact angle after 20,000 cotton swabs on the first hard coat surface is 100 degrees or more.
The transparent resin laminate according to claim 6 or 7, wherein the first hard coat comprises a paint containing a water repellent and no inorganic particles.
Furthermore, the transparent resin laminated body of any one of Claims 6-8 which satisfy | fills the following (f):
(F) The pencil hardness of the first hard coat surface is 5H or more.
The transparent resin laminate according to claim 9, wherein the first hard coat surface has a pencil hardness of 7H or more.
The thickness of the said 1st hard coat is 0.5-5 micrometers, The transparent resin laminated body of any one of Claims 1-10.
The transparent resin product according to claim 1, wherein the second hard coat has a thickness of 5 to 30 μm.
An article comprising the transparent resin laminate according to any one of claims 1 to 12 .