JP2017066191A - Molding material for light reflection bodies, light reflection body and light emitting device - Google Patents

Abstract

PROBLEM TO BE SOLVED: To provide a molding material for light reflection bodies that has excellent flowability and is molded to give a light reflection body having high thermal discoloration resistance.SOLUTION: A molding material for light reflection bodies according to the present invention comprises unsaturated polyester and filler. The unsaturated polyester comprises a compound comprising a fumaric acid residue, a 1,4- butanediol residue, and a trimethylol propane residue.SELECTED DRAWING: Figure 1

Description

  The present invention relates to a molding material for a light reflector suitable for producing a light reflector (reflector), a light reflector produced from the molding material for the light reflector, and a light emitting device provided with the light reflector. .

  Conventionally, it is known to use a light reflector (reflector) to reflect light emitted from a light emitting element such as a light emitting diode. As one of resins used for producing a light reflector, an unsaturated polyester resin is known. Unsaturated polyester resin is comprised from unsaturated polyester and crosslinking agents, such as styrene. Since the unsaturated polyester resin is a thermosetting resin, if it is used, there is an advantage that the heat discoloration of the light reflector is increased.

  For example, in Patent Document 1, an unsaturated polyester resin containing an unsaturated polyester, a copolymerizable monomer or multimer, and a thermoplastic resin, and an unsaturated polyester resin composition containing a white pigment are molded. To obtain an LED reflector. Further, Patent Document 1 includes a melt heating molding method such as an injection molding method, an injection compression molding method, or a transfer molding method as a molding method.

JP 2014-019747 A

  In the case of obtaining a light reflector by molding an unsaturated polyester resin composition, mass production of the light reflector can be expected at a low cost if a general transfer molding is adopted as a molding method of the thermosetting resin composition. . In order to have good moldability at the time of transfer molding, for example, higher fluidity is required for the unsaturated polyester resin composition than when an injection molding method is employed. The light reflector is required to have high heat discoloration in order to maintain high light reflectivity over a long period of time.

  However, an unsaturated polyester resin composition that has a good fluidity suitable for transfer molding and that can obtain a light reflector having high heat discoloration has not been obtained. Although Patent Document 1 describes not only an injection molding method but also a transfer molding method as a molding method, the molding method employed in the examples in Patent Document 1 is only the injection molding method. Patent Document 1 does not disclose the use of an unsaturated polyester resin to obtain a light reflector having high heat discoloration by a transfer molding method.

  The present invention has been made in view of the above points, and a molding material for a light reflector, which has excellent fluidity and can obtain a light reflector having high heat discoloration by molding, It aims at providing the light reflector manufactured from the molding material for light reflectors, and a light-emitting device provided with this light reflector.

  The molding material for light reflectors according to the present invention contains an unsaturated polyester and a filler, and the unsaturated polyester comprises a fumaric acid residue, a 1,4-butanediol residue, and a trimethylolpropane residue. It is characterized by containing a compound.

  The light reflector according to the present invention includes a cured product of the molding material for light reflector.

  The light-emitting device according to the present invention includes the light reflector and a light-emitting element.

  According to the present invention, it is possible to obtain a molding material for a light reflector that has an excellent fluidity and can obtain a light reflector having high heat discoloration by being molded.

  According to the present invention, a light reflector having high heat discoloration can be obtained.

  ADVANTAGE OF THE INVENTION According to this invention, a light-emitting device provided with the light reflector which has high heat-resistant discoloration property can be obtained.

It is sectional drawing which shows a light-emitting device provided with the light reflector in one Embodiment of this invention. It is a top view which shows the light-emitting device shown in FIG. It is a top view which shows the molded object obtained when manufacturing a light reflector by a MAP construction method.

  The light reflector molding material according to the present embodiment (hereinafter referred to as a molding material) is used for manufacturing the light reflector 1. This molding material contains an unsaturated polyester and a filler. The molding material may further contain a crosslinking agent.

  In this embodiment, a filler is a component which consists of at least 1 type among a white pigment, an inorganic filler, and a fibrous filler. The filler preferably contains at least a white pigment. The white pigment in this embodiment is white and is a pigment having a refractive index of 1.5 or more. The refractive index of the resin is usually around 1.5, and the difference between the refractive index of the white pigment and the refractive index of the resin is preferably large.

  In this embodiment, unsaturated polyester contains the compound (henceforth 1st unsaturated polyester) provided with a fumaric acid residue, a 1, 4- butanediol residue, and a trimethylol propane residue.

  The first unsaturated polyester is synthesized, for example, by dehydrating and condensing raw material monomers containing fumaric acid, 1,4-butanediol and trimethylolpropane.

  Since the first unsaturated polyester has the above-described configuration, the viscosity at the time of melting of the first unsaturated polyester is reduced. Therefore, the flowability at the time of molding of the molding material containing the first unsaturated polyester is increased, and the moldability when the molding material is molded by the transfer molding method is improved. In addition, the first unsaturated polyester can have a melting point suitable for transfer molding and have high crystallinity by including the above-described configuration. Further, since the first unsaturated polyester has high reactivity, it is difficult for unreacted components to remain in the molded product obtained by thermosetting the molding material. For this reason, the heat-resistant discoloration property of the light reflector 1 produced from the molding material is improved. Thereby, the high light reflectivity of the light reflector 1 is easily maintained over a long period of time.

  The first unsaturated polyester preferably has crystallinity. That is, the first unsaturated polyester is preferably a crystalline unsaturated polyester. When the first unsaturated polyester has crystallinity, the storage stability of the molding material increases. That is, the molding material has high stability at a temperature below the melting point of the first unsaturated polyester. Furthermore, good moldability can be obtained by improving the fluidity of the molding material during molding. Moreover, when the 1st unsaturated polyester has crystallinity, while being able to raise the light reflectivity of the light reflector 1, the persistence of a high light reflectivity can also be raised.

  In the present embodiment, the crystalline unsaturated polyester is an unsaturated polyester having crystallinity, having a melting point lower than room temperature, a solid at room temperature, and a liquid having a low viscosity above the melting point. . The first unsaturated polyester has crystallinity, for example, when the first unsaturated polyester is heated and melted and then cooled to room temperature at a rate of −10 ° C./min. Confirmed by occurring. In addition, this crystallinity is observed using a polarizing microscope that polarization characteristics occur when the first unsaturated polyester is heated and melted and then cooled to room temperature at a rate of −10 ° C./min. Is also confirmed. Such confirmation of crystallinity is performed, for example, using a microscope cooling and heating stage manufactured by Linkam.

  The glass transition temperature of the first unsaturated polyester is preferably in the range of 30 to 50 ° C. Moreover, it is preferable that melting | fusing point of a 1st unsaturated polyester exists in the range of 70-100 degreeC.

  When the glass transition temperature of the first unsaturated polyester is 30 ° C. or higher, the storage stability of the molding material is particularly high. That is, for example, when the molding material is pulverized into particles and stored, it is possible to prevent the molding material particles from fusing together at a high temperature such as in summer. In addition, it is not preferable that the glass transition temperature is higher than 50 ° C. because the melting point of the first unsaturated polyester may be excessively increased accordingly. The glass transition temperature of the first unsaturated polyester can be easily adjusted by adjusting the composition ratio and molecular weight of the constituent components.

  When the melting point of the first unsaturated polyester is 100 ° C. or less, it becomes easy to melt the first unsaturated polyester without proceeding the curing reaction during the heat-kneading for preparing the molding material. For this reason, the molding material which does not contain hardened | cured material is prepared easily. Moreover, the fall of the light reflectivity of the light reflector 1 is suppressed because melting | fusing point of a 1st unsaturated polyester is 70 degreeC or more. The reason is presumed as follows. When the molding material is pulverized by the pulverizer, the first unsaturated polyester is melted by heat generated by the pulverizer or frictional heat, that is, the molding material is partially melted. When the molding material partially melted collides with a metal part such as a rotor blade in the pulverizer, the molding material easily rubs in contact with the metal part. If it does so, hard components, such as a white pigment in a molding material, an inorganic filler, and a metal part will rub against each other, metal powder will arise from a metal part, and this will become easy to mix in a molding material. It is considered that this metal powder causes a decrease in the light reflectance of the light reflector 1. However, when the melting point of the first unsaturated polyester is 70 ° C. or higher, the first unsaturated polyester is difficult to melt when the molding material is pulverized by the pulverizer. In this case, when the molding material collides with a metal part such as a rotor blade, the molding material is easily crushed quickly, and therefore, the friction between the molding material and the metal part is less likely to occur. For this reason, it becomes difficult for metal powder to mix in a molding material, and, thereby, the fall of the light reflectivity of the light reflector 1 is suppressed.

  Furthermore, the first unsaturated polyester having a melting point in the range of 70 to 100 ° C. can impart particularly excellent fluidity to the molding material when the molding material is molded. Even when it is molded by the molding method, the moldability is improved.

  The melting point of the first unsaturated polyester is a temperature at which a peak of heat of fusion appears when differential scanning calorimetry (DSC) is performed while raising the temperature of the first unsaturated polyester.

  The iodine value of the first unsaturated polyester is preferably in the range of 70 to 120. When the iodine value is 70 or more, the glass transition temperature of the light reflector 1 becomes particularly high, and when the iodine value is 120 or less, the reactivity of the light reflector 1 becomes low and the strength of the light reflector 1 becomes particularly high. . More preferably, the iodine value is in the range of 80 to 110.

  The iodine value of the first unsaturated polyester can be easily adjusted by adjusting the ratio of fumaric acid residues in the first unsaturated polyester, for example.

  The ICI viscosity (high shear viscosity) at 150 ° C. of the first unsaturated polyester is preferably within the range of 0.1 to 5 Pa · s, and within the range of 0.5 to 3 Pa · s. Particularly preferred. In this case, moderate fluidity is imparted to the molding material at the time of molding, the moldability becomes particularly good, and the generation of burrs is effectively suppressed. The ICI viscosity of the first unsaturated polyester is easily adjusted by appropriately adjusting the composition of the first unsaturated polyester.

  The structure of the first unsaturated polyester will be described in more detail.

  The first unsaturated polyester comprises a polybasic acid residue and a polyol residue.

  The molar ratio of the polybasic acid residue to the polyol residue in the first unsaturated polyester is, for example, in the range of 1: 1.1 to 1: 1.3. That is, the first unsaturated polyester is synthesized, for example, by a dehydration condensation reaction of polybasic acids and polyols at a molar ratio of 1: 1.1 to 1: 1.3.

  In this embodiment, the polybasic acid residue contains a fumaric acid residue. For this reason, the first unsaturated polyester has good reactivity. For this reason, the remaining of unreacted components when the molding material is thermoset is reduced, and the heat discoloration of the light reflector 1 is particularly improved.

  The percentage ratio of fumaric acid residues to all polybasic acid residues in the first unsaturated polyester is preferably 50 mol% or more. In this case, the heat discoloration property of the light reflector 1 is particularly increased by increasing the proportion of fumaric acid residues that do not include an aromatic ring in the first unsaturated polyester. The percentage of fumaric acid residues is more preferably in the range of 50 to 70 mol%, and even more preferably in the range of 55 to 65 mol%.

  The polybasic acid residue in the first unsaturated polyester may contain only a fumaric acid residue or may contain a fumaric acid residue and other groups.

  In particular, the polybasic acid residue preferably contains a fumaric acid residue and a terephthalic acid residue. In this case, the toughness of the light reflector 1 is improved. In addition, since the first unsaturated polyester has an aromatic ring, particularly when the crosslinking agent also has an aromatic ring, the compatibility of the first unsaturated polyester and the crosslinking agent is improved, so that the light reflector 1 Improved characteristics. The percentage of terephthalic acid residues to all polybasic acid residues in the first unsaturated polyester is preferably 50 mol% or less. The percentage of terephthalic acid is more preferably in the range of 25 to 50 mol%, and even more preferably in the range of 30 to 40.

  The polybasic acid residue is selected from the group consisting of a maleic acid residue, a citraconic acid residue, a mesaconic acid residue, an itaconic acid residue, a tetrahydrophthalic acid residue, a methyltetrahydrophthalic acid residue, and a glutaconic acid residue One or more unsaturated polybasic acid residues may be further contained.

  Polybasic acid residues are phthalic acid residue, 1,4-cyclohexanedicarboxylic acid residue, isophthalic acid residue, succinic acid residue, adipic acid residue, sebacic acid residue, azelaic acid residue, endo One or more saturated polybasic acid residues selected from the group consisting of a methylenetetrahydrophthalic acid residue, a heptic acid residue, and a tetrabromophthalic acid residue may be contained. In this case, the heat discoloration of the light reflector 1 is particularly improved.

  The polyol residue contains 1,4-butanediol residue and trimethylolpropane residue as described above. Thus, since the polyol residue has not only 1,4-butanediol residue but also trimethylolpropane residue, the crystallinity of the first unsaturated polyester is improved and the viscosity is reduced. The moldability of is improved.

  The total percentage of 1,4-butanediol residues and trimethylolpropane residues to all polyol residues in the first unsaturated polyester is preferably 80 mol% or more. This percentage may be 100 mol%. If this percentage is 80 mol% or more, crystallization of the cured product is promoted when the molding material is cured, and thus the dimensional stability of the light reflector 1 is increased.

  The percentage of 1,4-butanediol residues to all polyol residues in the first unsaturated polyester is preferably in the range of 70 to 96 mol%. When the percentage is 70 mol% or more, the viscosity of the molding material at the time of molding is particularly reduced. Moreover, when this percentage is 96 mol% or less, good moldability at the time of molding can be secured. It is particularly preferred if the percentage of 1,4-butanediol residues to all polyol residues is in the range of 75-95 mol%.

  The percentage of trimethylolpropane residues to all polyol residues in the first unsaturated polyester is preferably in the range of 10-25 mol%. In this case, the crystallinity of the first unsaturated polyester can be moderately suppressed. Further, when the percentage of trimethylolpropane residue is within the above range, the compatibility between the first unsaturated polyester and the crosslinking agent in the molding material is improved, and thus characteristics such as uniformity of the light reflector 1 are obtained. Will improve. This is considered to be because the crystallinity of the first unsaturated polyester is moderately lowered as described above due to the trimethylolpropane residue. It is particularly preferred if the percentage of trimethylolpropane residues relative to all polyol residues is in the range of 15-20 mol%.

  The polyol residue in the first unsaturated polyester may comprise a 1,2-propanediol residue. In this case, an improvement in fluidity of the molding material can be expected by reducing the viscosity during molding. The percentage of 1,2-propanediol residues to all polyol residues in the first unsaturated polyester is preferably in the range of 0-30 mol%. In this case, the resin strength of the light reflector 1 is improved. More preferably, the percentage of 1,2-propanediol residues is in the range of 1 to 25 mol%.

  The polyol residue may further contain groups other than 1,4-butanediol residue, 1,2-propanediol residue, and trimethylolpropane residue. For example, the polyol residue is an ethylene glycol residue, 1,3-propanediol residue, 1,4-butanediol residue, 1,3-butanediol residue, 1,5-pentanediol residue, propylene glycol residue. Group, diethylene glycol residue, triethylene glycol residue, dipropylene glycol residue, hydrogenated bisphenol A residue, bisphenol A propylene oxide compound residue, dibromoneopentyl glycol residue, 1,6-hexanediol residue, It can contain at least one group selected from the group consisting of neopentyl glycol residues and cyclohexane 1,4-dimethanol residues.

  The polyol residue is selected from the group consisting of ethylene glycol residue, 1,3-propanediol residue, 1,4-butanediol residue, 1,5-pentanediol residue and cyclohexanedimethanol residue It is also preferable to contain the above groups. In this case, the heat discoloration of the light reflector 1 is particularly improved.

  The acid value of the first unsaturated polyester is preferably in the range of 15 to 35 mg-KOH / g, and more preferably in the range of 20 to 30 mg-KOH / g.

  The first unsaturated polyester is synthesized, for example, by subjecting a raw material monomer containing polybasic acids and polyols to a dehydration condensation reaction. In this case, the first unsaturated polyester has a polybasic acid residue derived from polybasic acids and a polyol residue derived from polyols. In this raw material monomer, the polybasic acids contain fumaric acid and terephthalic acid, and the polyol contains 1,4-butanediol, 1,2-propanediol, and trimethylolpropane.

  In the present embodiment, the reactivity of the first unsaturated polyester is low at room temperature, and therefore the storage stability of the molding material containing the first unsaturated polyester is high.

  Moreover, in this embodiment, the high adhesiveness of the hardened | cured material of a molding material and a metal is obtained because a molding material contains the 1st unsaturated polyester. For this reason, when the metal lead 2 is attached to the light reflector 1 produced from the molding material (see FIG. 1), high adhesion between the light reflector 1 and the lead 2 is obtained.

  It is particularly preferable that the unsaturated polyester in the molding material contains only the first unsaturated polyester. Further, the unsaturated polyester contains the first unsaturated polyester, and further does not have one or more groups of fumaric acid residue, 1,4-butanediol residue, and trimethylolpropane residue (first compound) A second unsaturated polyester) may also be included. However, the percentage of the first unsaturated polyester relative to the whole unsaturated polyester is preferably 40% by mass or more, and more preferably 95% by mass or more.

  It is preferable that the weight average molecular weight of a 1st unsaturated polyester exists in the range of 6000-10000. In this embodiment, it is possible to achieve the glass transition temperature, iodine value, and ICI viscosity at 150 ° C. of the first unsaturated polyester within this range. The weight average molecular weight is measured by GPC (gel permeation chromatography).

  The crosslinking agent is a component that builds a crosslinked structure between the chains of the unsaturated polyester by reacting with the unsaturated polyester.

  Examples of the crosslinking agent include vinyl polymerizable monomers such as styrene, vinyl toluene, divinyl benzene, α-methyl styrene, methyl methacrylate, and vinyl acetate; diallyl phthalate, isodiallyl phthalate, triallyl cyanurate, diallyl tetrabromophthalate, Methacrylate-based and acrylate-based polymerizable monomers such as phenoxyethyl acrylate, 2-hydroxyethyl acrylate, 1,6-hexanediol diacrylate; and prepolymers obtained by polymerizing one or more compounds among these polymerizable monomers; One or more compounds selected from the group consisting of can be contained.

  In particular, the crosslinking agent preferably contains a compound having a boiling point of 150 ° C. or higher. In this case, volatilization of the crosslinking agent from the molding material is suppressed. For this reason, generation | occurrence | production of the odor from a molding material is suppressed and a working environment is improved. Further, the stability of the composition of the molding material is increased. In particular, as the compound having a boiling point of 150 ° C. or higher, the crosslinking agent contains one or more compounds selected from the group consisting of diallyl phthalate, isodiallyl phthalate, diethylene glycol diacrylate, and polymers of these compounds, preferable. The polymer is a polymer of at least one compound selected from the group consisting of diallyl phthalate, isodiallyl phthalate and diethylene glycol diacrylate. In this case, volatilization of the crosslinking agent from the molding material is suppressed. For this reason, generation | occurrence | production of the odor from a molding material is suppressed and a working environment is improved. Further, the stability of the composition of the molding material is increased. In addition, the difference between the melting point of the first unsaturated polyester and the softening point of the cross-linking agent is reduced, so that a highly uniform molding material can be easily obtained by heating and kneading. Furthermore, the glass transition point of the light reflector 1 becomes high, and the heat discoloration of the light reflector 1 becomes high. The compound having a boiling point of 150 ° C. or higher includes a compound that does not boil at normal pressure and has a thermal decomposition temperature of 150 ° C. or higher.

  It is also preferred that the crosslinking agent contains at least one compound of diallyl phthalate monomer and triallyl cyanurate. In this case, not only the effect due to the high boiling point is obtained, but also mold contamination is suppressed when molding is performed by a mold molding method such as a transfer molding method.

  The percentage of the crosslinking agent relative to the total amount of unsaturated polyester and crosslinking agent is particularly preferably within the range of 2 to 15% by mass. When the percentage is 2% by mass or more, the glass transition point of the light reflector 1 is particularly high, and when the percentage is 15% by mass or less, the heat discoloration of the light reflector 1 is particularly high.

  The molding material may contain a curing catalyst. In this case, the reaction between the unsaturated polyester and the crosslinking agent is promoted, and the crosslinked structure is efficiently constructed. For this reason, the moldability of the molding material and the shape stability of the light reflector 1 are improved. The curing catalyst can contain, for example, one or more compounds selected from the group consisting of a curing accelerator and a polymerization initiator.

  The polymerization initiator can contain, for example, a heat decomposition type organic peroxide. Examples of the organic peroxide include 2,5-dimethyl-2,5- (t-butylperoxy) hexane, tert-butyl (3,5,5-trimethylhexanoyl) peroxide, 1,4-bis [(t- Butylperoxy) isopropyl] benzene, t-butylperoxy-2-ethylhexyl monocarbonate, 1,1-di (t-hexylperoxy) cyclohexane, 1,1-di (t-butylperoxy) -3,3 , 5-trimethylcyclohexane, t-butylperoxyoctate, benzoyl peroxide, methyl ethyl ketone peroxide, acetylacetone peroxide, t-butylperoxybenzoate, and dicumyl peroxide Can be contained.

  Commercial products of organic peroxides are provided by NOF Corporation, Kayaku Akzo Corporation, Yoshitomi Arkema Corporation and others. The organic peroxide is appropriately selected in consideration of, for example, being less likely to generate odor due to decomposition products during molding, and further suppressing the generation of unsaturated bonds during molding and suppressing the reduction in heat discoloration. . The organic peroxide and the inorganic filler may be masterbatched. In this case, the organic peroxide can be favorably dispersed in the molding material.

  In particular, the polymerization initiator preferably contains an organic peroxide having a 10-hour half-life temperature of 100 ° C. or higher. Specifically, the polymerization initiator preferably contains dicumyl peroxide. When the polymerization initiator contains such an organic peroxide, a decrease in reflectance over time of the light reflector 1 is further suppressed.

  The percentage ratio of the organic peroxide to the total amount of unsaturated polyester and crosslinking agent in the molding material is preferably in the range of 1 to 3% by mass. When the percentage is 1% by mass or more, the curing reaction of the molding material can be effectively promoted. Moreover, it can suppress that shaping | molding time is shortened too much that this percentage is 3 mass% or less, and defects, such as a blurring, occur in the light reflector 1.

  The molding material may contain a polymerization inhibitor. Polymerization inhibitors include, for example, hydroquinone, monomethyl ether hydroquinone, toluhydroquinone, di-t-4-methylphenol, monomethyl ether hydroquinone, phenothiazine, t-butylcatechol, quinones such as parabenzoquinone, pyrogallol, 2,6-di- t-butyl-p-cresol, 2,2-methylene-bis- (4-methyl-6-tert-butylphenol), 1,1,3-tris- (2-methyl-4-hydroxy-5-tert-butyl) One or more compounds selected from the group consisting of phenolic compounds such as phenyl) butane can be contained.

  The molding material may contain only an unsaturated polyester resin as a thermosetting resin, but may further contain other thermosetting resins such as an epoxy resin. However, the percentage of the unsaturated polyester resin to the total thermosetting resin is preferably 50% by mass or more.

  In particular, the filler preferably contains a white pigment. The white pigment imparts light reflectivity to the light reflector 1 formed from the molding material. The white pigment is, for example, from the group consisting of titanium oxide, barium titanate, strontium titanate, aluminum oxide, magnesium oxide, zinc oxide, zinc sulfide, barium sulfate, magnesium carbonate, barium carbonate and lead white (ie basic lead carbonate). One or more selected materials may be included.

  In particular, the white pigment preferably contains one or more materials selected from the group consisting of titanium oxide, barium titanate, barium sulfate, zinc oxide, and zinc sulfide. When the white pigment contains zinc oxide, the thermal conductivity of the light reflector 1 is particularly high, which is preferable. It is also preferable that the white pigment contains aluminum oxide having a high thermal conductivity.

  When the white pigment contains titanium oxide, the titanium oxide can contain one or more materials selected from, for example, anatase type titanium oxide, rutile type titanium oxide, and brucite type titanium oxide. In particular, since rutile type titanium oxide is excellent in thermal stability, it is preferable that the titanium oxide contains rutile type titanium oxide.

  The surface of the white pigment may be surface-treated with a fatty acid, a coupling agent or the like. In this case, aggregation, oil absorption and the like of the white pigment are suppressed, and the filling property of the white pigment in the molding material is increased.

  The average particle size of the white pigment is preferably 2.0 μm or less. The average particle size is preferably 0.01 μm or more. This average particle size is also preferably in the range of 0.03 to 1.0 μm, preferably in the range of 0.1 to 0.7 μm, and in the range of 0.2 to 0.5 μm. It is also preferable. The average particle diameter of the white pigment is measured by a laser diffraction scattering method.

  The percentage of white pigment in the molding material is preferably in the range of 15 to 40% by weight. In this case, the heat-reflecting property of the light reflector 1 is particularly high, and the light reflectivity of the light reflector 1 is particularly high.

  The filler may further contain an inorganic filler other than the white pigment. In this case, the light reflectivity of the light reflector 1 is further increased, and the shape stability of the light reflector 1 is further increased. Further, the inorganic filler can increase the thermal conductivity of the light reflector 1. Thereby, discoloration, deterioration, etc. due to heat of the light reflector 1 are further suppressed.

  The inorganic filler can contain, for example, one or more materials selected from the group consisting of silica, calcium carbonate, calcium hydroxide, aluminum hydroxide, aluminum nitride, alumina, silicon nitride, boron nitride, and mica.

  The inorganic filler may contain a white extender pigment. In the present embodiment, the white extender pigment is a pigment that is white and has a refractive index of less than 1.5. When the molding material contains a white extender, the light reflectivity of the light reflector 1 is particularly high. The white extender pigment can contain, for example, at least one material selected from the group consisting of calcium carbonate, barium sulfate, and aluminum hydroxide.

  In particular, the inorganic filler preferably contains silica. In this case, the light reflectivity of the light reflector 1 is further increased, and the shape stability of the light reflector 1 is further increased. Silica can contain, for example, one or more materials selected from fused silica powder, spherical silica powder, crushed silica powder, and crystalline silica powder. In particular, the silica preferably contains fused silica.

  It is also preferable that the inorganic filler contains a thermally conductive inorganic filler. In this case, the thermal conductivity of the light reflector 1 is particularly high, and therefore, discoloration, deterioration, etc. due to heat of the light reflector 1 are further suppressed. The thermally conductive inorganic filler can contain one or more materials selected from the group consisting of crystalline silica, alumina, silicon nitride, boron nitride, aluminum nitride, and the like.

  The thermally conductive inorganic filler preferably contains a metal-containing filler, and particularly preferably contains an aluminum-containing filler. The aluminum-containing filler can contain, for example, aluminum hydroxide. Since aluminum hydroxide has a Mohs hardness of 3, there is an advantage that coloring due to sliding with a kneader during kneading is suppressed.

  The inorganic filler may be surface-treated with a fatty acid, a coupling agent or the like. In this case, aggregation, oil absorption and the like of the inorganic filler are suppressed, the filling property of the inorganic filler in the molding material is increased, and the moisture resistance reliability of the light reflector 1 is increased.

  The percentage of hollow particles to the molding material is preferably in the range of 5 to 15% by mass. When the percentage of the hollow particles is 5% by mass or more, the ultraviolet resistance of the light reflector 1 is particularly improved. Moreover, when the percentage of the hollow particles is 15% by mass or less, an increase in the viscosity of the molding material can be suppressed during molding. More preferably, the percentage of the hollow particles is in the range of 5 to 10% by mass. When the percentage of the hollow particles is 10% by mass or less, an increase in the viscosity of the molding material can be particularly suppressed during molding.

  The hollow particles are preferably surface-treated with one or more materials selected from the group consisting of calcium carbonate, zinc oxide and talc. That is, the hollow particles are preferably coated with one or more materials selected from the group consisting of calcium carbonate, zinc oxide and talc. In this case, the whiteness of the light reflector 1 is improved and the ultraviolet resistance of the light reflector 1 is also improved. One of the possible reasons is that the hollow particles are surface-treated, so that the dispersibility of the hollow particles in the molding material and the light reflector 1 is improved.

  A preferred specific example of the hollow particles is product number S60-HS (hollow glass beads) manufactured by Sumitomo 3M Limited.

  The average particle size of the inorganic filler is preferably 100 μm or less. In this case, the moldability of the molding material is particularly good, and the heat discoloration resistance and moisture resistance of the light reflector 1 are particularly high. This average particle size is preferably 0.1 μm or more. In this case, the handleability of the molding material is improved. The average particle size of the inorganic filler is more preferably 80 μm or less, and further preferably 50 μm or less. The average particle size of the inorganic filler is more preferably 0.3 μm or more. Furthermore, when the average particle size of the inorganic filler is in the range of 8 to 20 μm, the injection moldability of the molding material is particularly good. The average particle size of the inorganic filler is measured by a laser diffraction scattering method.

  The percentage of the inorganic filler relative to the total thermosetting resin in the molding material is preferably 40% by mass or more. In this case, the shape stability of the light reflector 1 is particularly high. The percentage of the inorganic filler is preferably 300% by mass or less. In this case, the moldability of the molding material is particularly high. It is particularly preferable if the percentage of the inorganic filler is in the range of 50 to 250% by mass.

  The percentage of the white pigment relative to the whole filler is preferably 30% by mass or more. In this case, the light reflectivity of the light reflector 1 is particularly high. This percentage is preferably 95% by mass or less. This percentage is more preferably in the range of 35 to 90% by mass, and still more preferably in the range of 40 to 85% by mass.

  The percentage of the filler relative to the total thermosetting resin in the molding material is preferably 500% by mass or less. In this case, the fluidity of the molding material becomes particularly high during molding. The percentage of the filler is preferably 100% by mass or more. In this case, the light reflectivity of the light reflector 1 is particularly high. The percentage of the filler is more preferably in the range of 100 to 400% by mass, and further preferably in the range of 200 to 300% by mass.

  The filler may contain a fibrous filler or may not contain a fibrous filler.

  The fibrous filler means a filler having a ratio value (L / D) of 10 to 20 in the ratio of the average fiber length (L) and the average fiber diameter (D). The average fiber length and the average fiber diameter of the fibrous filler are arithmetic average values of the fiber length and the fiber diameter obtained by image processing of the microscopic image of the fibrous filler, respectively.

  When the filler does not contain a fibrous filler, the fluidity of the molding material becomes very high during molding. In this case, even if the molding material is molded by a mold array package (MAP) method, excellent moldability can be obtained. The mold array package method is a method for obtaining a plurality of products by first forming a single molded body at a time and then cutting the molded body into a predetermined size.

  On the other hand, when the filler contains a fibrous filler, curing shrinkage of the molding material is suppressed during molding, the strength of the light reflector 1 is increased, and the dimensional stability of the light reflector 1 is further increased. Moreover, when producing the light reflector 1 integrated with the lead frame by insert molding or the like, warpage of the light reflector 1 due to molding shrinkage of the runner portion is suppressed.

  The percentage of the fibrous filler to the total thermosetting resin in the molding material is preferably in the range of 10 to 200% by mass. In this case, curing shrinkage of the molding material is particularly suppressed during molding, and the strength of the light reflector 1 is particularly high. The percentage of the fibrous filler is more preferably in the range of 20 to 100% by mass, and further preferably in the range of 30 to 80% by mass.

  Even when the filler contains a fibrous filler, if the amount of filler in the molding material and the amount of fibrous filler are set appropriately, the fluidity of the molding material becomes very high during molding. Even if the molding material is molded by the MAP method, excellent moldability can be obtained. In this case, the percentage of the filler is preferably 50 to 70% by volume with respect to the whole molding material, and the percentage of the fibrous filler is preferably within the range of 5 to 20% by volume with respect to the whole molding material.

  The fibrous filler can contain, for example, a fibrous filler used for FRP (Fiber Reinforced Plastics) such as BMC (Bulk Molding Compound) and SMC (Sheet Molding Compound). .

  The average fiber diameter of the fibrous filler is preferably in the range of 6 to 12 μm, and more preferably in the range of 6 to 8 μm. In this case, the strength of the light reflector 1 is particularly high. The average fiber length of the fibrous filler is preferably in the range of 100 to 300 μm, and more preferably in the range of 150 to 250 μm. In this case, the strength of the light reflector 1 is particularly improved and the light reflectance thereof is also particularly improved. The average fiber diameter and the average fiber length of the fibrous filler are arithmetic average values of the fiber diameter and the fiber length obtained by image processing of electron micrographs of the fibers in the fibrous filler, respectively.

  The fibrous filler is, for example, one or more materials selected from glass fibers, vinylon fibers, aramid fibers, polyester fibers, wollastonite, potassium titanate whiskers, carbonate whiskers such as calcium carbonate, and hydrotalcite. Can be contained. In particular, it is preferable that the fibrous filler contains glass fibers.

  The glass fibers are, for example, E glass (non-alkali glass for electricity), C glass (alkali glass for chemistry), A glass (acid-resistant glass), S glass (high-strength glass) using silicate glass and borosilicate glass as raw materials. 1) or more of materials selected from the group consisting of glass fibers. The glass fiber may be a long fiber (roving) or a short fiber (chopped strand). The glass fiber may be subjected to a surface treatment. In particular, the glass fiber is in the range of 3 to 6 mm in length after the E glass fiber having a fiber diameter of 10 to 15 μm is converged with a sizing agent such as vinyl acetate and subsequently surface-treated with a silane coupling agent. It is preferable to contain chopped strands cut into pieces.

  In particular, the average fiber diameter of the glass fibers is preferably in the range of 6 to 12 μm, and more preferably in the range of 6 to 8 μm. In this case, the strength of the light reflector 1 is particularly high.

  The average fiber length of the glass fibers is preferably in the range of 100 to 300 μm, and more preferably in the range of 150 to 250 μm. In this case, the strength of the light reflector 1 is particularly improved and the light reflectance thereof is also particularly improved. When the average fiber length is 100 μm or less, the glass fiber and the metal slide at the time of kneading or injection molding, so that the light reflectance of the light reflector 1 may be reduced. The average fiber diameter and the average fiber length of the fibers are arithmetic average values of the fiber diameter and the fiber length obtained by image processing of electron micrographs of the fibers, respectively.

  Even if the average fiber length of the glass fiber before blending into the molding material is not within the range of 100 to 300 μm, the average fiber length of the glass fiber in the molding material and the light reflector 1 is within the range of 100 to 300 μm. I just need it. For example, even if glass fibers having a fiber length of about 3 mm are used, the average fiber length of the glass fibers in the molding material is within the range of 100 to 300 μm as a result of stress applied to the glass fibers by kneading in the manufacturing process of the molding material. It may be.

  More specific examples of glass fibers include a chopped strand having a diameter of 13 μm and a length of 3 to 5 mm, a chopped strand having a diameter of 6 μm and a length of 3 to 5 mm, and an average fiber length of 250 μm and a diameter of 250 μm. Milled fibers that are ˜600 μm.

  It is also preferable that the maximum fiber length of the glass fiber is 300 μm or less. In this case, when the molding material is molded by a mold molding method such as a transfer molding method, the molding material is less likely to be clogged with a gate or the like, thereby further suppressing unfilled defects. In particular, when a small light reflector 1 is produced in order to reflect light from the light emitting element 3 such as a light emitting diode, the gate diameter is reduced. The

  It is also preferable that the cross section of the glass fiber has an irregular shape. The irregular shape refers to a shape other than a circle, for example, a shape having an aspect ratio larger than 1, such as an eyebrows shape or an oval shape. The aspect ratio of the cross section is preferably 1.5 or more. As such a glass fiber, for example, a modified cross-section chopped strand manufactured by Nittobo Co., Ltd. may be mentioned. When the glass fiber having such an irregular cross section is used, the strength of the light reflector 1 is improved. Moreover, by suppressing the curvature of the light reflector 1, the flatness of the light reflector 1 is increased, and thus the light reflectance is further improved.

  It is also preferable that the fibrous filler is treated with an aliphatic urethane-based sizing agent. In this case, the fibrous filler is bundled with the aliphatic urethane-based sizing agent, and the adhesiveness between the molding material and the resin in the light reflector 1 and the fibrous filler is increased. Thereby, the dispersibility of the fibrous filler in the molding material and in the light reflector 1 is improved. Therefore, the fibrous filler can effectively improve the mechanical strength of the light reflector 1, and the fibrous filler is less likely to hinder the light reflectivity of the light reflector 1. As a result, the light filler The high strength and high light reflectivity of the reflector 1 are ensured. Furthermore, since the aliphatic urethane-based sizing agent has few sites that cause yellowing, such as unsaturated groups, it is difficult to cause yellowing, and thus the light reflectivity of the light reflector 1 is less likely to deteriorate over time.

  It is preferable that the fibrous filler is first treated with an aminosilane coupling agent and then treated with an aliphatic urethane sizing agent. In this case, the adhesion of the aliphatic urethane sizing agent to the fibrous filler is increased.

  Examples of the aminosilane coupling agent include γ-aminopropyltriethoxysilane, N-β- (aminoethyl) -γ-aminopropyltrimethoxysilane, N-β- (aminoethyl) -N′-β- (aminoethyl). One or more compounds selected from the group consisting of -γ-aminopropyltriethoxysilane and γ-anilinopropyltrimethoxysilane can be contained. The percentage of aminosilane coupling agent is preferably 0.3% by mass or less, more preferably 0.2% by mass or less, based on the fibrous filler.

  The aliphatic urethane sizing agent can include an isocyanate residue and a polyol residue. The aliphatic urethane-based sizing agent is obtained by reacting an isocyanate compound that induces an isocyanate residue, a polyol compound that induces a polyol residue, and, if necessary, an additive selected from a chain extender and a crosslinking agent.

  In particular, the isocyanate residue in the aliphatic urethane sizing agent is an isophorone diisocyanate residue, hexamethylene diisocyanate residue, isophorone diisocyanate residue, methylenebis (4,1-cyclohexylene) diisocyanate residue, 1,3-bis ( Isocyanatomethyl) cyclohexane residue, norbornane diisocyanate residue and metaxylylene diisocyanate residue, containing at least one group selected from the group consisting of polycaprolactone It is preferable to contain one or more groups selected from the group consisting of polyols, polybutadiene polyols and polycarbonate polyols. In this case, since the yellowing of the aliphatic urethane-based sizing agent is particularly suppressed, yellowing due to light and heat of the light reflector 1 and a decrease in reflectance are particularly suppressed.

  The aliphatic urethane sizing agent comprises at least one of an aliphatic diisocyanate residue and an alicyclic diisocyanate residue, and a polyester polyol residue, and the polyester polyol residue is an aliphatic polybasic acid residue. It is also preferable to provide at least one of the alicyclic polybasic acid residues and an aliphatic polyhydric alcohol residue. In this case, since the yellowing of the aliphatic urethane-based sizing agent is particularly suppressed, yellowing due to light and heat of the light reflector 1 and a decrease in reflectance are particularly suppressed.

  The aliphatic urethane-based sizing agent comprises at least one group of isophorone diisocyanate residue and hexane-1,6-diisocyanate residue and a polyester polyol residue, and the polyester polyol residue is a neopentyl glycol residue. It is also preferable to provide at least one group of propylene glycol residues and at least one group of adipic acid residues and phthalic acid residues. In this case, since the yellowing of the aliphatic urethane-based sizing agent is particularly suppressed, yellowing due to light and heat of the light reflector 1 and a decrease in reflectance are particularly suppressed. In particular, the isocyanate residue in the aliphatic urethane sizing agent is composed of an isophorone diisocyanate residue and a hexane-1,6-diisocyanate residue, and the polyester polyol residue in the aliphatic urethane sizing agent is a neopentyl glycol residue, It preferably consists of a propylene glycol residue, an adipic acid residue and a phthalic acid residue.

  The percentage of the aliphatic urethane-based sizing agent with respect to the fibrous filler is not particularly limited, but is preferably in the range of 0.05 to 0.4% by mass, and in the range of 0.05 to 0.29% by mass. If it is more preferable.

  Moreover, it is preferable that the percentage of the fibrous filler with respect to the whole molding material exists in the range of 3-20 mass%, and it is still more preferable if it exists in the range of 5-15 mass%. In these cases, the bending strength of the light reflector 1 is particularly improved. Furthermore, in these cases, the material shrinkage rate can be reduced. That is, the occurrence of cracks in the light reflector 1 is suppressed in a temperature cycle test or the like. In particular, when the light reflector 1 is produced from the molding material by the MAP method, it is preferable that the percentage of the fibrous filler with respect to the entire molding material is in the range of 5 to 20% by volume.

  The percentage of the filler relative to the whole molding material is preferably in the range of 20 to 90% by mass. In this range, excellent fluidity of the molding material is ensured during molding. In particular, when the light reflector 1 is produced from the molding material by the MAP method, the percentage of the filler relative to the entire molding material is preferably in the range of 50 to 70% by volume. Moreover, when producing one light reflector 1 per cavity by molding the molding material by the transfer molding method instead of the MAP method, the percentage of the filler relative to the entire molding material is 50 to 90% by mass. It is preferable that it is in the range of 60 to 85% by mass.

  The molding material preferably contains an antioxidant. In this case, the discoloration of the light reflector 1 is further suppressed, and the light reflectivity of the light reflector 1 is not easily lowered over time. The antioxidant can contain, for example, one or more compounds selected from the group consisting of phenolic antioxidants and phosphorus antioxidants. The antioxidant preferably does not contain a compound that produces a chromophore.

  It is particularly preferred that the molding material contains a phosphorus-based antioxidant. In this case, yellowing at the time of processing and yellowing over time of the light reflector 1 are further suppressed, and thereby a decrease in light reflectance of the light reflector 1 is further suppressed. In particular, when the molding material contains triglycidyl isocyanurate and further contains a phosphorus-based antioxidant, a decrease in the light reflectance of the light reflector 1 is greatly suppressed.

  Phosphorous antioxidants are, for example, 9,10-dihydro-9-oxa-10-phosphaphenanthrene-10-oxide, 3,9-bis (2,6-di-tert-butyl-4-methylphenoxy)- Selected from the group consisting of 2,4,8,10-tetraoxa-3,9-diphosphaspiro [5.5] undecane, bis (nonylphenyl) pentaerythritol-di-phosphite and distearyl pentaerythritol-di-phosphite One or more compounds may be contained. The percentage of phosphorus-based antioxidant in the molding material is preferably in the range of 0.1 to 0.5% by mass.

  It is also preferable that the molding material contains a sulfur-based antioxidant. Specific examples of the sulfur-based antioxidant include Adeka Stab AAO-412S manufactured by ADEKA Corporation. The percentage of sulfur-based antioxidant in the molding material is preferably 0.5% by mass or less, and more preferably in the range of 0.01 to 0.5% by mass.

  The molding material may contain a release agent. The release agent can contain, for example, one or more materials selected from the group consisting of commonly used fatty acid waxes, fatty acid metal salt waxes, and mineral waxes. In particular, the release agent preferably contains a fatty acid wax or a fatty acid metal salt wax that is excellent in heat discoloration.

  The release agent preferably contains at least one material selected from the group consisting of stearic acid, zinc stearate, aluminum stearate, and calcium stearate.

  The amount of the release agent with respect to 100 parts by mass of the thermosetting resin is preferably in the range of 1 to 15 parts by mass. In this case, the good releasability of the light reflector 1 and the excellent appearance of the light reflector 1 are compatible at the time of molding, and the light reflectivity of the light reflector 1 is particularly high.

  The molding material may contain appropriate additives such as a colorant, a thickener, a flame retardant, and a flexibility imparting agent in addition to the above components.

  The molding material may contain a thermoplastic resin. In this case, since shrinkage during molding is suppressed, the dimensional stability of the light reflector 1 is increased. The thermoplastic resin can contain, for example, one or more components selected from the group consisting of polystyrene, silicone elastomer, polyethylene, polypropylene, polyvinyl acetate, styrene butadiene rubber, acrylonitrile butadiene styrene rubber, and polymethyl methacrylate. For example, the thermoplastic resin is in the range of 0.5 to 20 parts by mass with respect to 100 parts by mass of the molding material.

  The molding material may be solid. In this case, the storage stability and handling properties of the molding material are increased. For example, the molding material may be granular or powdery. In particular, the molding material is preferably solid at 30 ° C. or lower. In this case, the molding material can be easily processed into a granular shape by pulverization, extrusion pellet processing, or the like. It is also preferred that the molding material has shape retention at 50 ° C. or lower. In this case, handling property of the molding material and workability when using the molding material are particularly improved.

  The molding material may be prepared without a solvent. In this case, a solid molding material can be easily obtained.

  In preparing the molding material, for example, the raw materials as described above are first blended at a predetermined ratio and mixed with a mixer such as a mixer or a blender to obtain a mixture. This mixture is kneaded by a kneader, an extruder or the like capable of being heated and pressurized. As the kneader, for example, a pressure kneader, a heat roll, an extruder, or the like is used. The heating temperature at the time of kneading is preferably in the range of 80 to 120 ° C. In this case, the uniformity of the molding material is increased by melting the first unsaturated polyester without curing. Subsequently, the bulk material of the mixture is pulverized and sized, or further granulated as necessary to obtain molding materials such as granules, powders, and pellets. At the time of pulverization, in the present embodiment, the first unsaturated polyester is difficult to melt, so that the light reflectance of the light reflector 1 is prevented from being lowered due to metal rubbing.

  The molding material which concerns on this embodiment can obtain high fluidity at the time of shaping | molding by containing 1st unsaturated polyester as above-mentioned. It is preferable that the spiral flow length in 170 degreeC of the molding material which concerns on this embodiment is 30 cm or more by containing 1st unsaturated polyester. By containing the first unsaturated polyester, it is also preferable that the torque of the curast meter at 170 ° C. of the molding material according to this embodiment is 1.96 N · m (20 kgf · cm) or more. In this case, the flowability of the molding material is particularly excellent, the molding material is easily molded by the transfer molding method, and the occurrence of burrs in the light reflector 1 is suppressed.

  When the filler does not contain a fibrous filler, the fluidity of the molding material becomes particularly high during molding. When the molding material contains the first unsaturated polyester and no fibrous filler, the spiral flow length at 170 ° C. of the molding material is 50 cm or more, and the torque of the curastometer at 170 ° C. is 1.96 N · m. It can be achieved that it is (20 kgf · cm) or more. In this case, the moldability particularly when the light reflector 1 is produced by the mold array package (MAP) method is improved.

  The light reflector 1 is obtained by molding and curing the molding material. As a molding method, an appropriate melt heating molding method such as an injection molding method, an injection compression molding method, or a transfer molding method can be applied. In particular, as described above, it is preferable to apply a transfer molding method that is inexpensive and easy to mass-produce. The molding conditions in the transfer molding method are, for example, a mold temperature of 150 to 195 ° C., preferably 170 to 180 ° C., a transfer pressure of 5 to 20 MPa, a curing time of 30 to 300 seconds, preferably 30. Within the range of ~ 180 seconds. A post-cure process may be performed as needed.

  1 and 2 show an example of a light emitting device 6 including the light reflector 1. The light emitting device 6 includes a light reflector 1, a metal lead 2, and a light emitting element 3. In this example, the light reflector 1 and the lead 2 are combined because the lead 2 is attached to the light reflector 1. Note that the structures of the light reflector 1 and the light emitting device 6 manufactured from the molding material according to this embodiment are not limited to this example.

  The lead 2 includes a first lead 21 and a second lead 22. The light reflector 1 includes a main body 12 that is overlaid on the lead 2, and an interposition part 11 that is interposed between the first lead 21 and the second lead 22. The body portion 12 is formed with a recess 13 that opens on the upper surface thereof. Each of the first lead 21 and the second lead 22 is exposed in the recess 13 at the bottom surface of the recess 13. An insulating member 5 is provided on the lower surface of the lead 2 so as to straddle the first lead 21 and the second lead 22. The member 5 includes the first lead 21 and the second lead 22. Suppresses the short circuit between.

  The light emitting element 3 is, for example, a light emitting diode, but is not limited thereto. The light emitting element 3 is mounted on the first lead 21 in the recess 13. Further, in the recess 13, the light emitting element 3 and the first lead 21 are electrically connected by the first wire 41, and the light emitting element 3 and the second lead 22 are connected by the second wire 42. Has been.

  The inner peripheral surface 14 of the recess 13 of the light reflector 1 is inclined so that the inner diameter of the recess 13 increases toward the opening side. For this reason, the light emitted from the light emitting element 3 is easily reflected by the inner peripheral surface 14 of the recess 13 in the light reflector 1, and as a result, the light extraction efficiency from the light emitting device 6 is increased.

  In the light emitting device 6, if necessary, the inside of the recess 13 may be sealed with a transparent resin, and the opening of the recess 13 may be covered with a transparent cover.

  The light reflector 1 to which such a metal lead 2 is attached is manufactured by, for example, an insert molding method. That is, for example, a lead frame including the lead 2 is disposed inside the transfer molding die, and in this state, the molding material is transfer molded in the transfer molding die, and the lead 2 is separated from the lead frame as necessary. A light reflector 1 is obtained.

  A method of manufacturing the light reflector 1 to which the metal lead 2 is attached by the MAP method will be described with reference to FIG. For example, first, a lead frame 20 including a plurality of leads 2 is prepared. The lead frame 20 is placed inside the transfer molding die, and in this state, the molding material is transfer molded in the transfer molding die. Thereby, the molded object 10 to which the lead frame 20 is attached is obtained. A plurality of light reflectors 1 are obtained by cutting the molded body 10 with a dicing saw or the like.

[Preparation of unsaturated polyester]
The raw material monomer having the composition shown in Table 1 below was put in a container, and the raw material monomer was reacted while purging the condensed water while raising the temperature while replacing the inside of the container with an inert gas. When the acid value of the product was confirmed to be in the range of 5-40 mg-KOH / g, the reaction was terminated. Thereby, a crystalline unsaturated polyester was obtained.

  Table 1 also shows the iodine value, melting point, ICI viscosity at 150 ° C., and weight average molecular weight of each unsaturated polyester. The melting point is a value measured while raising the temperature of unsaturated polyester by differential scanning calorimetry (DSC) at 10 ° C. per minute.

[Examples and Comparative Examples]
A resin component and a filler having the composition shown in the table below were prepared, and these were blended so that the ratio of the filler was a value shown in “Ratio of filler in molding material” in the table. The amounts of raw materials shown in the “resin component composition” column and “filler composition” column in the table are all expressed in parts by mass. These raw materials were uniformly mixed using a sigma blender and then kneaded with a hot roll heated to 100 ° C. to obtain a sheet-like kneaded product. The kneaded product was cooled, ground and sized. Thereby, a granular molding material was obtained.

  The results of measuring the spiral flow length at 170 ° C. and the curastometer torque at 170 ° C. of the molding material are shown in Tables 2 to 5 below. In the measurement of spiral flow, a molding material was molded under the conditions of a molding die temperature of 170 ° C. and a molding pressure of 6.9 MPa using a spiral flow measurement mold in accordance with the standard of EMMI-1-66. The flow distance (cm) was determined. In measuring the torque of the curast meter, the molding material was heated at a temperature of 170 ° C., and the torque value at the time when 180 seconds had elapsed from the start of heating was obtained.

  In addition, the detail of the raw material shown in the table | surface below other than unsaturated polyester is as follows.

Crosslinking agent / diallyl phthalate monomer: manufactured by Daiso Co., Ltd., product name DUP monomer, molecular weight 246.3, viscosity at 30 ° C. 8.5 mPa · s, iodine value 202, liquid at room temperature, boiling point 290 ° C.
Triallyl cyanurate: manufactured by Nippon Kasei Co., Ltd., product name, molecular weight 249, viscosity 80 to 110 mPa / s (30 ° C.), melting point 27 ° C., boiling point 162 ° C. (2 mmHg).

Curing accelerator, 2,5-dimethyl-2,5- (t-butylperoxy) hexane.
-Dicumyl peroxide: NOF Corporation make.

Mold release agent / zinc stearate: Sakai Chemical Industry Co., Ltd., product name SZ-P.

Antioxidant / PEP-36: Phosphorous antioxidant, manufactured by ADEKA Corporation, product name ADK STAB PEP-36.
AO-60: hindered phenol antioxidant, manufactured by ADEKA Corporation, product name ADK STAB AO-60.
AO-412S: Sulfur-based antioxidant, manufactured by ADEKA Corporation, product name ADK STAB AAO-412S.

White pigment / titanium oxide: rutile titanium oxide, average particle size 0.4 μm, manufactured by Tyoxide Japan Co., Ltd., product name Tioxide RTC-30.

Inorganic filler / silica: fused silica, average particle size 25 μm, manufactured by Denki Kagaku Kogyo Co., Ltd., product name FB-820.
Hollow particles: Glass hollow particles, average particle size 30 μm, manufactured by Sumitomo 3M Limited, trade name Glass Bubbles, product number S60-HS.

Fibrous filler / glass fiber: Glass fiber with an average fiber length of 3 mm, average fiber diameter of 10.5 μm, moisture content of 0.02%, ignition loss of 0.28%, surface treatment with an aminosilane coupling agent and aliphatic urethane Processed product obtained by sequential surface treatment with a system sizing agent. In the aliphatic urethane-based sizing agent, the isocyanate residue is composed of 80 mol% or more of isophorone diisocyanate residue and 20 mol% or less of hexane-1,6-diisocyanate residue, the polyester polyol residue is neopentylglycol residue, It consists of propylene glycol residue, adipic acid residue and phthalic acid residue.

[Evaluation]
(Light reflectance)
1. Samples for evaluation were produced by transfer molding the initial molding material. The transfer molding conditions were a mold temperature of 170 ° C., a transfer pressure of 8 MPa, and a curing time of 90 seconds. The dimensions of the evaluation sample were 5 cm in diameter and 1 mm in thickness.

  The light reflectance at a wavelength of 460 nm of the sample for evaluation was measured using a spectrocolorimeter CM-3500d manufactured by Konica Minolta.

2. After the heat treatment The sample for evaluation was subjected to a heat treatment at 150 ° C. for 1000 hours, and then the light reflectance at a wavelength of 460 nm of the sample was measured.

3. After UV irradiation and heat treatment The sample for evaluation was subjected to heat treatment at 140 ° C. for 1000 hours while irradiating with UV light using a HID lamp (high pressure mercury lamp) as a light source. Subsequently, the light reflectance of the sample at a wavelength of 460 nm was measured.

4). After the high temperature and high humidity treatment The sample for evaluation was treated at 85 ° C. and 85% RH for 1000 hours, and then the light reflectance at a wavelength of 460 nm of the sample for evaluation was measured.

(Odor when molding)
An evaluation sample was produced under the same conditions as in the evaluation of the light reflectance. The odor of the environment around the mold at the time of molding was sensory evaluated. As a result, the case where a strong odor was felt was evaluated as “B”, and the case where it did not was evaluated as “A”.

(Storage stability)
The molding materials obtained in each of the examples and comparative examples were analyzed by differential scanning calorimetry (DSC) immediately after preparation, and the calorific value during heat generation was measured. Further, after storing the molding material at a temperature of 20 ° C. for one month, the calorific value of the molding material during heat generation was measured. As a result, the case where the calorific value of the molding material after storage was 80% or more of the calorific value of the molding material immediately after preparation was evaluated as “A”, and the case where it was less than 80% was evaluated as “B”.

(Single piece formability)
A sample for evaluation of a light reflector was produced by transfer molding a molding material using a transfer molding die having a cavity of 3 mm × 3 mm × 1 mm. The transfer molding conditions were a mold temperature of 170 ° C., a transfer pressure of 8 MPa, and a curing time of 90 seconds.

  2500 samples for evaluation were prepared and observed to check for unfilled defects. The number of samples for evaluation in which defects were recognized was counted, and the moldability was evaluated by this number.

(MAP method formability)
A collective mold for forming one cavity was prepared by arranging 196 cavities measuring 3 mm × 3 mm × 1 mm in a matrix of 14 rows and 14 columns. The molding material was transfer molded in a state where a copper lead frame was set in the batch molding die. The transfer molding conditions were a mold temperature of 170 ° C., a transfer pressure of 8 MPa, and a curing time of 90 seconds. 196 light reflectors were cut out from one molded body by cutting the molded body thus obtained with a dicing saw.

  In the evaluation, 1960 light reflectors were obtained as evaluation samples by molding 10 molded bodies. The sample for evaluation was observed and the presence or absence of the unfilling defect was confirmed. The number of samples for evaluation in which defects were recognized was counted, and the moldability was evaluated by this number.

1 light reflector 6 light emitting device

Claims (12)

Contains unsaturated polyester and filler,
The molding material for light reflectors in which the said unsaturated polyester contains the compound provided with a fumaric acid residue, a 1, 4- butanediol residue, and a trimethylol propane residue. The molding material for light reflectors of Claim 1 containing a crosslinking agent. The percentage of the 1,4-butanediol residue is in the range of 70 to 90 mol% and the percentage of the trimethylolpropane residue is in the range of 10 to 25 mol% with respect to all polyol residues in the compound. The molding material for light reflectors according to claim 1 or 2. The molding compound for light reflectors according to any one of claims 1 to 3, wherein the compound further comprises a 1,2-propanediol residue. The molding material for light reflectors according to claim 4, wherein a percentage of the 1,2-propanediol residue is within a range of 10 mol% or less with respect to all polyol residues in the compound. The molding material for light reflectors according to any one of claims 1 to 5, wherein the compound further contains a terephthalic acid residue. The molding compound for light reflectors according to any one of claims 1 to 6, wherein the compound has crystallinity. The molding material for light reflectors according to any one of claims 1 to 7, wherein the unsaturated polyester has a melting point in a range of 70 to 100 ° C. The molding compound for light reflectors according to any one of claims 1 to 8, wherein the iodine value of the compound is within a range of 70 to 120. The molding material for light reflectors as described in any one of Claim 1 to 9 whose ICI viscosity in 150 degreeC of the said compound exists in the range of 0.1-5 Pa.s. The light reflector containing the hardened | cured material of the molding material for light reflectors as described in any one of Claim 1 to 10. A light emitting device comprising the light reflector according to claim 11 and a light emitting element.