JP2017043703A5 - - Google Patents
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- JP2017043703A5 JP2017043703A5 JP2015167541A JP2015167541A JP2017043703A5 JP 2017043703 A5 JP2017043703 A5 JP 2017043703A5 JP 2015167541 A JP2015167541 A JP 2015167541A JP 2015167541 A JP2015167541 A JP 2015167541A JP 2017043703 A5 JP2017043703 A5 JP 2017043703A5
- Authority
- JP
- Japan
- Prior art keywords
- resin composition
- curable resin
- ultraviolet curable
- acrylate monomer
- aliphatic
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- 239000000178 monomer Substances 0.000 claims description 16
- NIXOWILDQLNWCW-UHFFFAOYSA-M acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 claims description 13
- 239000011342 resin composition Substances 0.000 claims description 11
- 125000001931 aliphatic group Chemical group 0.000 claims description 7
- 230000001588 bifunctional Effects 0.000 claims description 6
- 239000004721 Polyphenylene oxide Substances 0.000 claims description 5
- 229920000570 polyether Polymers 0.000 claims description 5
- 210000002356 Skeleton Anatomy 0.000 claims description 4
- 125000003118 aryl group Chemical group 0.000 claims description 4
- CERQOIWHTDAKMF-UHFFFAOYSA-M methacrylate Chemical compound CC(=C)C([O-])=O CERQOIWHTDAKMF-UHFFFAOYSA-M 0.000 claims description 4
- 239000004925 Acrylic resin Substances 0.000 claims description 3
- 239000000203 mixture Substances 0.000 claims description 3
- 239000003999 initiator Substances 0.000 claims description 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims 4
- JOYRKODLDBILNP-UHFFFAOYSA-N ethyl urethane Chemical compound CCOC(N)=O JOYRKODLDBILNP-UHFFFAOYSA-N 0.000 claims 2
- 239000002202 Polyethylene glycol Substances 0.000 claims 1
- 125000000524 functional group Chemical group 0.000 claims 1
- LYCAIKOWRPUZTN-UHFFFAOYSA-N glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims 1
- 229920001223 polyethylene glycol Polymers 0.000 claims 1
- -1 polytetramethylene Polymers 0.000 claims 1
- UHESRSKEBRADOO-UHFFFAOYSA-N ethyl carbamate;prop-2-enoic acid Chemical compound OC(=O)C=C.CCOC(N)=O UHESRSKEBRADOO-UHFFFAOYSA-N 0.000 description 4
- 239000011347 resin Substances 0.000 description 3
- 229920005989 resin Polymers 0.000 description 3
- 230000000052 comparative effect Effects 0.000 description 2
- 229920001296 polysiloxane Polymers 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- ZFSLODLOARCGLH-UHFFFAOYSA-N Cyanuric acid Chemical compound OC1=NC(O)=NC(O)=N1 ZFSLODLOARCGLH-UHFFFAOYSA-N 0.000 description 1
- QCXXDZUWBAHYPA-UHFFFAOYSA-N OC(=O)C=C.OC(=O)C=C.OC(=O)C=C.O=C1NC(=O)NC(=O)N1 Chemical class OC(=O)C=C.OC(=O)C=C.OC(=O)C=C.O=C1NC(=O)NC(=O)N1 QCXXDZUWBAHYPA-UHFFFAOYSA-N 0.000 description 1
- GKZPEYIPJQHPNC-UHFFFAOYSA-N OC(=O)C=C.OC(=O)C=C.OC(=O)C=C.OC(=O)C=C.OC(=O)C=C.OC(=O)C=C.OCC(CO)(CO)CO Chemical compound OC(=O)C=C.OC(=O)C=C.OC(=O)C=C.OC(=O)C=C.OC(=O)C=C.OC(=O)C=C.OCC(CO)(CO)CO GKZPEYIPJQHPNC-UHFFFAOYSA-N 0.000 description 1
- 229940105570 Ornex Drugs 0.000 description 1
- 239000005062 Polybutadiene Substances 0.000 description 1
- KNSXNCFKSZZHEA-UHFFFAOYSA-N [3-prop-2-enoyloxy-2,2-bis(prop-2-enoyloxymethyl)propyl] prop-2-enoate Chemical compound C=CC(=O)OCC(COC(=O)C=C)(COC(=O)C=C)COC(=O)C=C KNSXNCFKSZZHEA-UHFFFAOYSA-N 0.000 description 1
- 239000006096 absorbing agent Substances 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 239000002518 antifoaming agent Substances 0.000 description 1
- 230000003078 antioxidant Effects 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- MHCLJIVVJQQNKQ-UHFFFAOYSA-N ethyl carbamate;2-methylprop-2-enoic acid Chemical compound CCOC(N)=O.CC(=C)C(O)=O MHCLJIVVJQQNKQ-UHFFFAOYSA-N 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 230000001771 impaired Effects 0.000 description 1
- 239000004611 light stabiliser Substances 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- YNAVUWVOSKDBBP-UHFFFAOYSA-N morpholine Chemical compound C1COCCN1 YNAVUWVOSKDBBP-UHFFFAOYSA-N 0.000 description 1
- 229940113083 morpholine Drugs 0.000 description 1
- 239000003504 photosensitizing agent Substances 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 239000004014 plasticizer Substances 0.000 description 1
- 229920002857 polybutadiene Polymers 0.000 description 1
- 229920000515 polycarbonate Polymers 0.000 description 1
- 239000004417 polycarbonate Substances 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- DVQHRBFGRZHMSR-NWBUNABESA-N sodium;methyl 2,2-dimethyl-4,6-dioxo-5-[(E)-N-prop-2-enoxy-C-propylcarbonimidoyl]cyclohexane-1-carboxylate Chemical compound [Na+].C=CCO\N=C(/CCC)[C-]1C(=O)CC(C)(C)C(C(=O)OC)C1=O DVQHRBFGRZHMSR-NWBUNABESA-N 0.000 description 1
- 239000002562 thickening agent Substances 0.000 description 1
Description
請求項１の発明は、ブローチや小物などのアクセサリーを自作するために使用する紫外線硬化樹脂組成物であって、ポリエーテル骨格の数平均分子量が１，０００〜７，０００である２官能のウレタン（メタ）アクリレート樹脂（Ａ）と、単官能メタクリレートモノマーまたは芳香族アクリレートモノマーまたは極性基を持たない脂肪族アクリレートモノマー（Ｂ）と、光重合開始剤（Ｃ）と、を含む紫外線硬化樹脂組成物であって、（Ａ）成分の含有量が全組成物１００重量部に対し５０〜９５重量部である紫外線硬化樹脂組成物を提供する。
The invention of claim 1 is an ultraviolet curable resin composition used for making accessories such as brooches and accessories , and has a polyether skeleton having a number average molecular weight of 1,000 to 7,000. UV curable resin composition comprising (meth) acrylate resin (A), monofunctional methacrylate monomer, aromatic acrylate monomer, aliphatic acrylate monomer having no polar group (B), and photopolymerization initiator (C) And the ultraviolet curable resin composition whose content of (A) component is 50-95 weight part with respect to 100 weight part of all compositions is provided.
本発明の紫外線硬化樹脂組成物には、性能を損なわない範囲で、必要により粘着付与剤、可塑剤、酸化防止剤顔料、染料、光安定剤、光増感剤、消泡剤、増粘剤、紫外線吸収剤、及び濡れ性調整剤等の各種添加剤が含まれていても良い。
In the ultraviolet curable resin composition of the present invention, a tackifier, a plasticizer, an antioxidant pigment, a dye, a light stabilizer, a photosensitizer, an antifoaming agent, and a thickening agent are added as necessary, as long as the performance is not impaired. In addition, various additives such as an ultraviolet absorber and a wettability adjusting agent may be contained.
比較例１〜１２
実施例で用いた材料の他、ポリエーテル系ウレタンアクリレートのＳＵＡ−０１５（亜細亜工業製、Ｍｎ１７，０００、２官能）、ポリブタジエン系ウレタンメタクリレートのＴＥ−２０００（日本曹達製、Ｍｎ３，１００、２官能）、ポリエステル系ウレタンアクリレートのＵＡ−１２２Ｐ（新中村化学工業製、Ｍｎ１，３００、２官能）、ポリカーボネート系ウレタンアクリレートのＵＮ−９０００ＰＥＰ（根上工業製、Ｍｎ３，６００、２官能）、イソシアヌレート系ウレタンアクリレートのＲＵＡ−０４９Ｘ（亜細亜工業製、Ｍｎ１，５００、３官能）、脂肪族ウレタンアクリレートのＥＢＥＣＲＹＬ８２５４（ダイセルオルネクス製、Ｍｎ１，５００、６官能）を、その他６官能アクリレートモノマーのＤＰＨＡ（日本化薬製、ジペンタエリスリトールヘキサアクリレート）、４官能アクリレートモノマーのライトアクリレートＰＥ−４Ａ（共栄社化学製、ペンタエリスリトールテトラアクリレート）、３官能アクリレートモノマーのＦＡ−７３１ＡＴ（日立化成製、エトキシ化イソシアヌル酸トリアクリレート）、単官能アクリレートモノマーのＡＣＭＯ（ＫＪケミカルズ製、アクリルモルフォリン）を用い、表１記載の配合にて比較例１〜１２の樹脂組成物を調製した。
Comparative Examples 1-12
In addition to the materials used in the examples, polyether urethane acrylate SUA-015 (manufactured by Asia, Mn 17,000, bifunctional), polybutadiene urethane methacrylate TE-2000 (manufactured by Nippon Soda, Mn 3,100, bifunctional) ), Polyester-based urethane acrylate UA-122P (Shin-Nakamura Chemical Co., Ltd., Mn1,300, bifunctional), polycarbonate-based urethane acrylate UN-9000PEP (Negami Kogyo Co., Ltd., Mn3,600, bifunctional), isocyanurate-based urethane Acrylic RUA-049X (manufactured by Asia, Mn1,500, trifunctional), aliphatic urethane acrylate EBECRYL8254 (manufactured by Daicel Ornex, Mn1,500, hexafunctional), DPHA (Nippon Kayaku Co., Ltd.) Made Pentaerythritol hexaacrylate), 4-functional acrylate monomer light acrylate PE-4A (Kyoeisha Chemical, pentaerythritol tetraacrylate), trifunctional acrylate monomer FA-731AT (Hitachi Chemical Co., Ltd., ethoxylated isocyanuric acid triacrylate), monofunctional Resin compositions of Comparative Examples 1 to 12 were prepared using the acrylate monomer ACMO (manufactured by KJ Chemicals, acrylic morpholine) with the formulation shown in Table 1.
硬化物の作製
紫外線硬化樹脂２ｇを直径２６ｍｍ、深さ１０ｍｍのシリコーン型に投入し、樹脂面より５ｃｍの高さから、市販品のブラックライト照射装置スーパーレジンＵＶクリスタルランプを用い、波長３６５ｎｍにおける照度２〜４ｍＷ／ｃｍ２の光量で５分間照射して硬化させた。その後シリコーン型から硬化物を取り出し、２３±２℃にて３０分放置して作製した。
Preparation of cured product 2 g of UV curable resin was put into a silicone mold with a diameter of 26 mm and a depth of 10 mm, and the illuminance at a wavelength of 365 nm using a commercially available black light irradiation device super resin UV crystal lamp from a height of 5 cm from the resin surface. It was cured by irradiation with a light amount of 2 to 4 mW / cm 2 for 5 minutes. Thereafter, the cured product was taken out from the silicone mold and left at 23 ± 2 ° C. for 30 minutes to prepare.
Claims (4)
The polyether skeleton of the bifunctional urethane (meth) acrylate resin (A) whose number average molecular weight of the polyether skeleton is 1,000 to 7,000 is polyethylene glycol ether or polytetramethylene glycol ether. The ultraviolet curable resin composition according to any one of 1 to 3.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2015167541A JP6335853B2 (en) | 2015-08-27 | 2015-08-27 | UV curable resin composition for handicrafts |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2015167541A JP6335853B2 (en) | 2015-08-27 | 2015-08-27 | UV curable resin composition for handicrafts |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2017043703A JP2017043703A (en) | 2017-03-02 |
| JP2017043703A5 true JP2017043703A5 (en) | 2017-10-12 |
| JP6335853B2 JP6335853B2 (en) | 2018-05-30 |
Family
ID=58212112
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2015167541A Active JP6335853B2 (en) | 2015-08-27 | 2015-08-27 | UV curable resin composition for handicrafts |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JP6335853B2 (en) |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP6910097B2 (en) * | 2017-02-07 | 2021-07-28 | アイカ工業株式会社 | High refractive index photocurable resin composition |
| JP7146557B2 (en) * | 2018-10-15 | 2022-10-04 | アイカ工業株式会社 | UV curable resin composition |
Family Cites Families (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH01156387A (en) * | 1987-12-14 | 1989-06-19 | Cemedine Co Ltd | Photocurable adhesive composition having water resistance |
| JP3127230B2 (en) * | 1994-06-21 | 2001-01-22 | 株式会社メイコー | Precious metal products casting method |
| JPH1149534A (en) * | 1997-04-22 | 1999-02-23 | Dsm Nv | Radiation curable composition for coated optical fiber |
| JP4250308B2 (en) * | 2000-05-01 | 2009-04-08 | Ｊｓｒ株式会社 | Liquid curable resin composition |
| JP2005290065A (en) * | 2004-03-31 | 2005-10-20 | Jsr Corp | Curable liquid resin composition |
| JP2006057025A (en) * | 2004-08-20 | 2006-03-02 | Sanyo Chem Ind Ltd | Active energy ray-curable urethane (meth)acrylate composition |
| JP5053145B2 (en) * | 2008-03-27 | 2012-10-17 | Ｊｓｒ株式会社 | Liquid curable resin composition |
| JP2011212344A (en) * | 2010-03-31 | 2011-10-27 | Aida Kagaku Kogyo Kk | Method for producing ornament, and ornament |
-
2015
- 2015-08-27 JP JP2015167541A patent/JP6335853B2/en active Active
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