JP2016202150A - Milk flavor imparting material - Google Patents

Milk flavor imparting material Download PDF

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JP2016202150A
JP2016202150A JP2015092132A JP2015092132A JP2016202150A JP 2016202150 A JP2016202150 A JP 2016202150A JP 2015092132 A JP2015092132 A JP 2015092132A JP 2015092132 A JP2015092132 A JP 2015092132A JP 2016202150 A JP2016202150 A JP 2016202150A
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milk
mass
flavor
parts
solid content
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JP6654359B2 (en
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茂木 和之
Kazuyuki Mogi
和之 茂木
宏輔 菊地
Kosuke Kikuchi
宏輔 菊地
憲司 池田
Kenji Ikeda
憲司 池田
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Adeka Corp
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Abstract

PROBLEM TO BE SOLVED: To provide a milk flavor imparting material substitutable for powdered milk especially for skim-milk, capable of imparting excellent milk flavor to food and drink.SOLUTION: A milk flavor imparting material contains (A) whey mineral and (B) lactic fermentation flavor material as much as 0.001-5 pts. mass (B) lactic fermentation flavor material in terms of a solid content to a 1 pt. mass solid content of (A) whey mineral, preferably, further contains (C) phospholipid as much as 0.0001-0.5 pt. mass to the 1 pt. mass solid content of (A) whey mineral, and further preferably, contains (D) saccharide as much as 0.5-40 pts. mass in terms of a solid content to the 1 pt. mass solid content of (A) whey mineral.SELECTED DRAWING: None

Description

本発明は、粉乳類、とくに脱脂粉乳を代替可能であり、飲食品に対し良好な乳風味を付与することのできる乳風味付与材に関する。   The present invention relates to a milk flavor imparting material that can replace powdered milk, particularly skim milk powder, and can impart a good milk flavor to foods and drinks.

牛乳は、優れた乳のコク味を有する、栄養面、風味面で非常に優れた食品であり、それ自体飲料として消費される以外に、各種飲食品の原材料として多量に消費されている。
しかし、牛乳の組成はその90%程度が水であり、乳風味の主体である無脂乳固形分含量は8〜10質量%と含有量が少ないため、飲食品に添加したり、食品加工用として使用する場合、付与できる乳風味は弱いという欠点がある。
Milk is a food that has an excellent milky taste and is excellent in terms of nutrition and flavor, and is consumed in a large amount as a raw material for various foods and drinks, in addition to being consumed as a beverage itself.
However, about 90% of the composition of milk is water, and the content of non-fat milk, which is the main component of milk flavor, is as low as 8 to 10% by mass. When used as, there is a disadvantage that the milk flavor that can be imparted is weak.

そのため、牛乳を粉末化した全粉乳や、無脂乳固形分を粉末化した脱脂粉乳、ホエイを粉末化したホエイパウダーなどの粉乳類を使用する。このような粉乳類を使用する方法であれば添加量を低く抑えることができ、飲食品の物性にはあまり影響が出ないため、これらの粉乳類は飲食品の原材料として広く利用されている。
また、これらの粉乳類は、分離・濃縮や粉末化の際に風味がやや変化しているため、飲食品に豊かな乳風味を付与することが難しいという問題がある。また、無脂乳固形分の主体である乳蛋白質も乳糖も、水溶性とはいえ溶解度が低いため、水に溶解しにくく、とくに飲料では、経日的に分離したり、沈殿したり、ザラが出たりする問題がある。さらに、乳蛋白質を多く含有する飲食品の製造時に加熱殺菌処理する場合や、乳蛋白質を多く含有する飲食品を加熱調理する場合には、乳蛋白質の変性や、アミノカルボニル反応による褐変、さらにはコゲを生じてしまうという問題もある。
Therefore, powdered milk such as whole milk powder obtained by powdering milk, skimmed milk powder obtained by powdering non-fat milk solids, and whey powder obtained by powdering whey is used. If such a method using powdered milk is used, the amount added can be kept low, and the physical properties of the food and drink are not significantly affected. Therefore, these milk powders are widely used as raw materials for food and drink.
In addition, these milk powders have a problem that it is difficult to impart a rich milk flavor to foods and drinks because the flavor is slightly changed during separation, concentration and powdering. In addition, milk protein and lactose, which are the main components of non-fat milk solids, are water-soluble but have low solubility, so they are difficult to dissolve in water. Especially in beverages, they are separated or precipitated over time. There is a problem that comes out. Furthermore, when sterilizing by heating during the production of foods and drinks containing a lot of milk protein, or when cooking foods and drinks containing a lot of milk protein, the milk protein is denatured, browned by an aminocarbonyl reaction, There is also a problem of causing kogation.

そこで、これらの粉乳類の添加量は一定量以下に制限されることになるが、その場合であっても豊かな乳風味が要求される場合がある。
また、これらの粉乳類、とくにもっとも一般的で安価な脱脂粉乳は乳製品全体の需給関係により生産量が定まるため流通量が一定ではなく、需給の逼迫により品薄状態となる場合が多く、その場合、コストアップにつながるといった課題がある。また、原料生乳の産地や牛の肥育環境によって品質がばらつきやすいという問題もある。
そのため、飲食品において、粉乳類を使用せずに、豊かな乳風味を付与する方法、すなわち、飲食品に乳風味を付与する方法が各種研究され、提案されている。
Therefore, the amount of addition of these milk powders is limited to a certain amount or less, but even in that case, a rich milk flavor may be required.
In addition, these milk powders, especially the most common and cheap skimmed milk powder, the production volume is determined by the supply-demand relationship of the entire dairy product, so the distribution volume is not constant, and in many cases it becomes in short supply due to tight supply and demand. There is a problem that leads to cost increase. Another problem is that the quality is likely to vary depending on the raw milk production area and the cattle fattening environment.
Therefore, various researches and proposals have been made on methods for imparting a rich milk flavor without using powdered milk in foods and beverages, that is, methods for imparting milk flavor to foods and beverages.

まず、一般的には香料が使用される。しかし、香料はたしかに乳風味は付与されるが、味に厚みがないため、トップの乳風味が強すぎる反面、乳風味に伸びが感じられず豊かな乳風味にならないという問題があった。
そのため、天然の食品素材を使用した乳風味付与材が考案された。例えば、ペプチドとカルボニル化合物とのアミノ−カルボニル反応物(例えば特許文献1参照)、アルカリ処理したビール酵母の乾燥物(例えば特許文献2参照)、スクラロース(例えば特許文献3参照)、コーン粉末と油脂との反応物(例えば特許文献4参照)などが提案されている。
しかし、これらの素材は、実際には乳風味自体を付与しているのではなく、コク味を付与することにより乳風味を得ている。そのため、乳蛋白質を含有しない飲食品の場合は、コク味は付与されるが、乳風味は付与されないという問題があった。また、乳蛋白質含量がある程度の量がある飲食品の場合であっても、乳風味以外の成分の風味をも同様に増強してしまい、乳風味が付与されたように感じられない、という問題があった。
First, a fragrance is generally used. However, although the flavor is certainly imparted with a milk flavor, since the taste is not thick, the top milk flavor is too strong. On the other hand, there is a problem that the milk flavor is not stretched and does not become a rich milk flavor.
Therefore, a milk flavor imparting material using a natural food material has been devised. For example, an amino-carbonyl reaction product of a peptide and a carbonyl compound (see, for example, Patent Document 1), a dried product of alkali-treated brewer's yeast (see, for example, Patent Document 2), sucralose (see, for example, Patent Document 3), corn powder and fats and oils (For example, see Patent Document 4) and the like have been proposed.
However, these materials do not actually impart the milk flavor itself, but obtain a milk flavor by imparting a rich taste. Therefore, in the case of the food / beverage products which do not contain a milk protein, there existed a problem that a rich taste was provided but a milk flavor was not provided. In addition, even in the case of foods and drinks with a certain amount of milk protein content, the flavor of ingredients other than milk flavor is similarly enhanced, and it does not feel that milk flavor has been imparted was there.

一方、乳タンパク質以外で乳のこく味を凝縮した乳原料として乳清ミネラルが知られている。そしてこの乳清ミネラルを飲食品に対する乳風味の付与材として使用することが提案されている。(例えば特許文献5参照)
しかし、この乳清ミネラルには乳脂や乳タンパク質のもつ豊かな乳風味が含まれないため、飲食品に対し乳のコク味を付与することはできても、豊かな乳風味は付与されない、という問題があった。
On the other hand, whey mineral is known as a milk raw material that condenses the rich taste of milk other than milk protein. And it is proposed to use this whey mineral as a milk flavor imparting material for food and drink. (For example, see Patent Document 5)
However, because this whey mineral does not contain the rich milk flavor of milk fat and milk protein, even if it can give the rich taste of milk to food and drink, it does not give a rich milk flavor There was a problem.

特開2007−202492号公報JP 2007-202492 A 特開2010−057434号公報JP 2010-057434 A 特開2000−135055号公報JP 2000-135055 A 特開2000−004822号公報JP 2000-004822 A 特開2014−050337号公報JP 2014-050337 A

従って、本発明の目的は、粉乳類、とくに脱脂粉乳を代替可能であり、飲食品に対し良好な乳風味を付与することのできる乳風味付与材を提供することにある。   Accordingly, an object of the present invention is to provide a milk flavor imparting material that can replace milk powders, particularly skim milk powder, and can impart a good milk flavor to foods and drinks.

本発明者等は上記課題を解決すべく種々検討した結果、乳清ミネラルと発酵風味素材を特定比で配合し、好ましくはリン脂質や糖類を併用した組成物が上記問題を解決可能であることを見出した。   As a result of various studies to solve the above problems, the present inventors have formulated whey minerals and fermented flavor materials in a specific ratio, and preferably a composition using phospholipids and saccharides in combination can solve the above problems. I found.

すなわち本発明は、(A)乳清ミネラル、及び、(B)乳酸発酵風味素材を、(A)乳清ミネラルの固形分1質量部に対し、(B)乳酸発酵風味素材を固形分として0.001〜5質量部含有することを特徴とする乳風味付与材を提供するものである。   That is, the present invention provides (A) whey mineral and (B) lactic acid fermented flavor material with (B) lactic acid fermented flavor material as solid content with respect to 1 part by mass of solid content of (A) whey mineral. The milk flavor imparting material characterized by containing 0.001-5 mass parts.

本発明の乳風味付与材は、乳脂や乳蛋白質含量を極力減じたにも拘わらず、飲食品に添加すると、飲食品自体の風味や物性に影響を与えることなく、飲食品に豊かな厚みのある乳風味を付与することができるため、飲食品製造時に使用する粉乳類を代替可能である。   Although the milk flavor imparting material of the present invention has reduced the milk fat and milk protein content as much as possible, when added to food and drink, it does not affect the flavor and physical properties of the food and drink itself, and the food and drink has a rich thickness. Since a certain milk flavor can be provided, powdered milk used at the time of food-drinks manufacture can be substituted.

以下、本発明の乳風味付与材について好ましい実施形態に基づき詳述する。
まず、本発明で使用する乳清ミネラルについて詳述する。
乳清ミネラルとは、乳又はホエー(乳清)から、可能な限りタンパク質や乳糖を除去したものであり、そのため、高濃度に乳の灰分(ミネラル)を含有し、且つ、固形分に占める灰分の割合が極めて高いという特徴を有する。そして、そのミネラル組成は、原料となる乳やホエー中のミネラル組成に近い比率となる。
Hereinafter, the milk flavor imparting material of the present invention will be described in detail based on preferred embodiments.
First, the whey mineral used in the present invention will be described in detail.
Whey mineral is protein or lactose removed from milk or whey (whey) as much as possible. Therefore, it contains milk ash (mineral) at a high concentration and ash occupies solids. The ratio is extremely high. And the mineral composition becomes a ratio close | similar to the mineral composition in the milk and whey used as a raw material.

本発明で使用する乳清ミネラルとしては、食品加工用としての汎用性が高い乳風味付与材が得られることから、純度が高いこと、即ちタンパク質や乳糖等の不純物含量が低いことが好ましい。即ち、固形分に占める灰分含量が30質量%以上である乳清ミネラルを使用することが好ましく、固形分に占める灰分含量が50質量%以上である乳清ミネラルを使用することがより好ましい。尚、該灰分含量は高いほど好ましい。   As the whey mineral used in the present invention, since a milk flavor imparting material having high versatility for food processing can be obtained, it is preferable that the purity is high, that is, the content of impurities such as protein and lactose is low. That is, it is preferable to use a whey mineral having an ash content of 30% by mass or more in the solid content, and more preferably using a whey mineral having an ash content in the solid content of 50% by mass or more. The higher the ash content, the better.

また、本発明で使用する乳清ミネラルとしては、特に良好な乳風味を付与できること、及び、加熱工程を有する飲食品に使用した場合でも沈殿や濁りを生じない点で、固形分中のカルシウム含量が好ましくは2質量%未満、より好ましくは1質量%未満、更に好ましくは0.5質量%未満の乳清ミネラルを使用することが好ましい。尚、該カルシウム含量は低いほど好ましい。   In addition, as the whey mineral used in the present invention, the calcium content in the solid content can be imparted with a particularly good milk flavor and does not cause precipitation or turbidity even when used in food or drink having a heating step. Is preferably less than 2% by weight, more preferably less than 1% by weight, even more preferably less than 0.5% by weight of whey mineral. The lower the calcium content, the better.

牛乳から通常の製法で製造された乳清ミネラルは、固形分中のカルシウム含量が5質量%以上である。上記カルシウム含量が2質量%未満の乳清ミネラルは、乳又はホエーから、膜分離及び/又はイオン交換、更には冷却により、乳糖及びタンパク質を除去して乳清ミネラルを得る際に、あらかじめカルシウムを低減した乳を使用した酸性ホエーを用いる方法、或いは、甘性ホエーから乳清ミネラルを製造する際にカルシウムを除去する工程を挿入することで得ることができるが、工業的に実施する上での効率やコストの点で、甘性ホエーから乳清ミネラルを製造する際にある程度ミネラルを濃縮した後に、カルシウムを除去する工程を挿入することで得る方法を採ることが好ましい。ここで使用する脱カルシウムの方法としては、特に限定されず、調温保持による沈殿法等の公知の方法を採ることができる。   The whey mineral produced from cow's milk by a normal production method has a calcium content in the solid content of 5% by mass or more. The whey mineral having a calcium content of less than 2% by mass is preliminarily supplied with calcium when milk or whey is subjected to membrane separation and / or ion exchange and cooling to remove lactose and protein to obtain whey mineral. It can be obtained by inserting a method of using acidic whey using reduced milk, or by inserting a step of removing calcium when producing whey minerals from sweet whey. From the viewpoint of efficiency and cost, it is preferable to adopt a method obtained by inserting a step of removing calcium after concentrating the mineral to some extent when producing whey mineral from sweet whey. The method of decalcification used here is not particularly limited, and a known method such as a precipitation method by maintaining a temperature can be employed.

上記乳清ミネラルは、流動状、ペースト状、粉末状等、どのような形態であっても使用可能である。
なお本発明においては上記乳清ミネラルが流動状、ペースト状など固形以外の性状である場合は、その固形分を乳清ミネラルとして扱うものとする。
The whey mineral can be used in any form such as fluid, paste or powder.
In the present invention, when the whey mineral has a non-solid property such as fluid or paste, the solid content is treated as whey mineral.

次に、本発明で使用する、乳酸発酵風味素材について説明する。
上記乳酸発酵風味素材とは、乳酸菌が資化可能な基質を乳酸発酵して得られた風味素材であるが、その基質としては良好な乳風味が得られる点で乳原料を使用することが好ましい。該乳原料としては、牛乳、濃縮乳、練乳、ホエイ、クリーム、バター、バタークリーム、クリームチーズ、ナチュラルチーズ、プロセスチーズ等の乳や乳製品をはじめ、脱脂粉乳、全粉乳、ホエイパウダーなどの粉乳類や、脱脂乳などの乳糖を含有する乳製品も使用可能である。
Next, the lactic acid fermentation flavor material used by this invention is demonstrated.
The lactic acid fermentation flavor material is a flavor material obtained by lactic acid fermentation of a substrate that can be assimilated by lactic acid bacteria. As the substrate, it is preferable to use a milk raw material in terms of obtaining a good milk flavor. . The milk ingredients include milk, concentrated milk, condensed milk, whey, cream, butter, butter cream, cream cheese, natural cheese, processed cheese, and other milk products and dairy products as well as skim milk powder, whole milk powder, whey powder, etc. And dairy products containing lactose such as skim milk can also be used.

なお、本発明では上記乳酸発酵風味素材として、乳酸発酵を利用した市販の飲食品や風味素材、たとえばクリームチーズ、ナチュラルチーズ、プロセスチーズ、ヨーグルト、発酵乳飲料、製パン用発酵種等を使用することもできる。
また、本発明では、上記乳酸発酵風味素材は、基質や発酵条件の異なる2種以上の乳酸発酵風味素材を用いてもよい。
In the present invention, as the lactic acid fermentation flavor material, commercially available foods and beverages and flavor materials utilizing lactic acid fermentation, such as cream cheese, natural cheese, process cheese, yogurt, fermented milk beverage, fermented seeds for bread making, etc. are used. You can also
In the present invention, as the lactic acid fermentation flavor material, two or more lactic acid fermentation flavor materials having different substrates and fermentation conditions may be used.

以下、上記乳酸発酵風味素材の製造方法について、乳酸菌が資化可能な基質として乳原料を使用した場合の好ましい実施態様について詳述する。   Hereinafter, the preferred embodiment when the milk raw material is used as a substrate that can be assimilated by lactic acid bacteria will be described in detail with respect to the method for producing a lactic acid fermentation flavor material.

上記乳酸発酵風味素材を得るためには、まず乳酸菌が資化可能な基質、好ましくは乳原料を含有するミックス液を調製する。   In order to obtain the lactic acid fermentation flavor material, first, a mixed solution containing a substrate capable of assimilating lactic acid bacteria, preferably a milk raw material is prepared.

具体的には、牛乳、濃縮乳、ホエイ、クリーム、バター、クリームチーズ、ナチュラルチーズ、プロセスチーズ等の水分を多く含有する乳や乳製品、あるいは水に、脱脂粉乳、全粉乳、ホエイパウダーなどの粉乳類や、乳蛋白質、乳糖、バターなどの乳原料を添加し、水分含量が好ましくは20〜95質量%、より好ましくは70〜90質量%となるように調整して乳原料を含有するミックス液とする。また、該乳原料を含有するミックス液は、食用油脂を添加した水中油型乳化物としてもよいが、良好な風味バランスの乳酸発酵風味素材を得るため、本発明では、ミックス液は油脂含量を好ましくは10質量%以下、より好ましくは5質量%以下とする。   Specifically, milk, milk products containing a lot of water such as milk, concentrated milk, whey, cream, butter, cream cheese, natural cheese, processed cheese, or water, skimmed milk powder, whole milk powder, whey powder, etc. Milk mix containing milk ingredients by adding milk ingredients such as powdered milk, milk protein, lactose, butter, etc., and adjusting the water content to preferably 20-95% by mass, more preferably 70-90% by mass Use liquid. In addition, the mix liquid containing the milk raw material may be an oil-in-water emulsion to which edible oils and fats are added, but in order to obtain a lactic acid fermentation flavor material with a good flavor balance, in the present invention, the mix liquid has a fat content. Preferably it is 10 mass% or less, More preferably, you may be 5 mass% or less.

ミックス液は、風味が強化された乳酸発酵風味素材を安定して製造可能な点で、上記乳原料の含量が無脂乳固形分として2〜50質量%であることが好ましく、5〜20質量%であることが更に好ましい。
また、ミックス液は、風味が強化された乳酸発酵風味素材が得られる点で、遊離脂肪酸を好ましくは0.01〜0.2質量%、より好ましくは0.02〜0.1質量%含有することが好ましい。0.01質量%を下回ると遊離脂肪酸を含有することによる風味強化の効果が得にくく、0.2質量%を上回ると乳酸発酵風味素材に脂肪酸臭が残存し、好ましくない。ミックス液中の遊離脂肪酸含量を上記範囲とするためには、遊離脂肪酸含量の高い乳原料を使用する方法や、別途遊離脂肪酸や遊離脂肪酸含量の高い原材料を添加する方法、さらには油脂を含有するミックス液をリパーゼ等の脂質分解酵素で分解する方法などが挙げられるが、本発明では良好な風味の乳酸発酵風味素材が安定して製造可能であることから、バター分解物、バターオイル分解物、クリーム分解物、チーズ分解物などの遊離脂肪酸含量の高い乳原料を使用する方法であることが好ましく、特に好ましくはバター分解物を使用する。
It is preferable that the content of the said milk raw material is 2-50 mass% as non-fat milk solid content by the point which can manufacture stably the lactic-acid-fermentation flavor raw material with which the flavor was reinforced, and 5-20 mass%. % Is more preferable.
In addition, the mixed solution preferably contains 0.01 to 0.2% by mass of free fatty acid, more preferably 0.02 to 0.1% by mass in terms of obtaining a lactic acid fermentation flavor material with enhanced flavor. It is preferable. If it is less than 0.01% by mass, it is difficult to obtain the effect of flavor enhancement by containing free fatty acids, and if it exceeds 0.2% by mass, a fatty acid odor remains in the lactic acid fermentation flavor material, which is not preferable. In order to make the free fatty acid content in the mix liquid within the above range, a method using a milk raw material with a high free fatty acid content, a method of adding a free fatty acid or a raw material with a high free fatty acid content separately, and further containing fats and oils Examples include a method of decomposing a mixed solution with a lipolytic enzyme such as lipase.In the present invention, since a lactic acid fermentation flavor material having a good flavor can be stably produced, butter decomposition products, butter oil decomposition products, A method using a milk raw material having a high free fatty acid content such as a cream decomposed product or a cheese decomposed product is preferable, and a butter decomposed product is particularly preferably used.

次に、必要に応じて、この乳原料を含有するミックス液を加熱する。加熱する温度は、好ましくは35〜75℃である。更に、必要に応じて均質化を行なう。均質化を行なうための均質化機としては、例えば、ケトル型チーズ乳化釜、ステファンミキサーの様な高速せん断乳化釜、スタティックミキサー、インラインミキサー、ホモゲナイザー、コロイドミル、ディスパーミル等が挙げられ、好ましくは1〜200MPaの均質化圧力にて均質化を行なう。   Next, the mix liquid containing this milk raw material is heated as needed. The heating temperature is preferably 35 to 75 ° C. Further, homogenization is performed as necessary. Examples of the homogenizer for homogenization include a kettle type cheese emulsification pot, a high-speed shear emulsification pot such as a stefan mixer, a static mixer, an in-line mixer, a homogenizer, a colloid mill, a disper mill, etc. Homogenization is performed at a homogenization pressure of 1 to 200 MPa.

均質化後、必要に応じて、加熱殺菌を行なう。該加熱殺菌の方法としては、インジェクション式、インフュージョン式、マイクロ波、ジュール加熱式等の直接加熱方式、又は、バッチ式、プレート式、チューブラー式、掻き取り式等の間接加熱方式があり、UHT、HTST、LTLT等の50〜160℃、好ましくは55〜100℃の加熱処理を行なえば良い。   After homogenization, heat sterilization is performed as necessary. As the method of heat sterilization, there is a direct heating method such as an injection method, an infusion method, a microwave, a Joule heating method, or an indirect heating method such as a batch method, a plate method, a tubular method, a scraping method, Heat treatment at 50 to 160 ° C., preferably 55 to 100 ° C., such as UHT, HTST, and LTLT may be performed.

このようにして調製された乳原料を含有するミックス液に乳酸菌を添加して、乳酸発酵を行なう。   Lactic acid bacteria are added to the mix solution containing the milk raw material thus prepared, and lactic acid fermentation is performed.

なお、本発明で使用する乳酸菌としては特に制限されるものではないが、Lactococcus lactis subsp. lactis、Lactococcus lactis subsp. cremoris、Lactococcus lactis subsp. lactis var. diacetylactis、Lactobacillus casei subsp. casei、Lactobacillus acidophilus、Lactobacillus delbrueckii subsp. delbrueckii、Lactobacillus delbrueckii subsp. bulgaricus、Lactobacillus delbrueckii subsp. lactis、Lactobacillus jugurti、Lactobacillus helveticus、Lactobacillus kefyr、Lactobacillus plantarum、Lactobacillus rhamnosus、Streptococcus thermophilus、Leuconostoc mesenteroides、Leuconostoc mesenteroides subsp. cremoris 、Bifidobacterium longum、Bifidobacterium bifidum、Bifidobacterium infantis、Bifidobacterium breve等が挙げられ、これらを単独で用いることもでき、又は二種以上を組み合わせて用いることもできる。
また、これらの乳酸菌は、乳酸菌を含む発酵乳の形態で使用することも可能である。また、更に、乳酸発酵風味素材の風味を向上させる目的で、Candida kefyr、Kluyveromyces marxianus var. marxianus、Saccharomyces unisporus、Saccharomyces florentinus等の酵母を含むスターターを使用してもよい。
The lactic acid bacteria used in the present invention are not particularly limited, but Lactococcus lactis subsp. Lactis, Lactococcus lactis subsp. Cremoris, Lactococcus lactis subsp. Lactis var. Diacetylactis, Lactobacillus casei subsp. Casei, Lactobacillus acidophilus, Lactobacillus delbrueckii subsp. delbrueckii, Lactobacillus delbrueckii subsp.bulgaricus, Lactobacillus delbrueckii subsp. lactis, Lactobacillus jugurti, Lactobacillus helveticus, Lactobacillus kefyr, Lactobacillus plantarum, Lactobacillus rhamnosus, Streptusocenteric Bifidobacterium infantis, Bifidobacterium breve etc. are mentioned, These can also be used independently or can also be used in combination of 2 or more type.
Moreover, these lactic acid bacteria can also be used in the form of fermented milk containing lactic acid bacteria. Furthermore, for the purpose of improving the flavor of the lactic acid fermentation flavor material, starters containing yeasts such as Candida kefyr, Kluyveromyces marxianus var. Marxianus, Saccharomyces unisporus, Saccharomyces florentinus may be used.

ここで本発明では、より良好な香味を有する乳酸発酵風味素材が得られる点で、Lactococcus lactis subsp. lactis var. diacetylactis、Lactobacillus helveticus、Leuconostoc mesenteroides、Leuconostoc mesenteroides subsp. cremorisのうちの1種、又は2種以上を用いることが好ましく、より好ましくは、Lactococcus lactis subsp. lactis var. diacetylactisと、Leuconostoc mesenteroides subsp. cremorisの2種を併用するか、または、Lactobacillus helveticusと、Leuconostoc mesenteroidesの2種を併用する。   Here, in the present invention, one of Lactococcus lactis subsp. Lactis var. Diacetylactis, Lactobacillus helveticus, Leuconostoc mesenteroides, Leuconostoc mesenteroides subsp. Cremoris, or 2 in that a lactic acid fermentation flavor material having a better flavor can be obtained. It is preferable to use two or more species, and more preferably, Lactococcus lactis subsp. Lactis var. Diacetylactis and Leuconostoc mesenteroides subsp. Cremoris are used in combination, or Lactobacillus helveticus and Leuconostoc mesenteroides are used in combination.

乳酸菌の添加量は、後述するpHの乳酸発酵風味素材を効率よく得る観点から、ミックス液100質量部に対して、乾燥質量で0.001質量部以上0.2質量部以下であることが好ましく、0.004質量部以上0.05質量部以下であることがより好ましい。   The addition amount of lactic acid bacteria is preferably 0.001 part by mass or more and 0.2 part by mass or less in terms of dry mass with respect to 100 parts by mass of the mixed solution from the viewpoint of efficiently obtaining a lactic acid fermentation flavor material having a pH described later. More preferably, it is 0.004 parts by mass or more and 0.05 parts by mass or less.

また、乳酸発酵の条件は、温度については、使用される各乳酸菌に好適な発酵温度(例えば20〜40℃)を適宜選択すればよい。
乳酸発酵時間は基質濃度や乳酸菌の添加量等に応じ適宜選択可能であるが、好ましくは、乳酸発酵後のpHの値が4〜6、より好ましくは4.0〜5.5、更に好ましくは4.2〜5.2、最も好ましくは4.3〜4.8となる時間とする。
なお、上記乳酸発酵時は静置状態であってもよいが、好ましくは攪拌をおこなう。好ましい攪拌条件は、1分間に5〜50回転、より好ましくは10〜30回転である。
Moreover, what is necessary is just to select suitably the fermentation temperature (for example, 20-40 degreeC) suitable for each lactic acid bacteria used about the conditions of lactic acid fermentation about temperature.
The lactic acid fermentation time can be appropriately selected according to the substrate concentration, the amount of lactic acid bacteria added, etc., but preferably the pH value after lactic acid fermentation is 4 to 6, more preferably 4.0 to 5.5, and still more preferably. The time is 4.2 to 5.2, and most preferably 4.3 to 4.8.
In addition, although it may be in a stationary state at the time of the lactic acid fermentation, it is preferably stirred. Preferable stirring conditions are 5 to 50 rotations per minute, more preferably 10 to 30 rotations.

このようにして得られる乳酸発酵風味素材の固形分含量としては、5〜20質量%であることが好ましく、10〜15質量%であることがより好ましい。またこの乳酸発酵風味素材の糖類含量としては、2〜15質量%であることが好ましく、3〜10質量%であることがより好ましい。またこのようにして得られる乳酸発酵風味素材のリン脂質含量としては0.01〜1質量%であることが好ましく、0.02〜0.5質量%であることがより好ましい。   The solid content of the lactic acid fermentation flavor material thus obtained is preferably 5 to 20% by mass, and more preferably 10 to 15% by mass. Moreover, as a saccharide content of this lactic-acid fermentation flavor raw material, it is preferable that it is 2-15 mass%, and it is more preferable that it is 3-10 mass%. Moreover, it is preferable that it is 0.01-1 mass% as a phospholipid content of the lactic acid fermentation flavor material obtained in this way, and it is more preferable that it is 0.02-0.5 mass%.

本発明の乳風味付与材は上記乳清ミネラル及び乳酸発酵風味素材を、(A)乳清ミネラルの固形分1質量部に対し、(B)乳酸発酵風味素材を固形分として0.001〜5質量部、好ましくは0.01〜2質量部、より好ましくは0.05〜0.8質量部含有する。
ここで、(A)乳清ミネラルの固形分1質量部に対する(B)乳酸発酵風味素材の含有量が固形分として0.001質量部未満であると本発明の効果が得られず、5質量部を超えると酸味により風味が悪化してしまう。
The milk flavor imparting material of the present invention is the above-mentioned whey mineral and lactic acid fermented flavor material with 0.001 to 5 (B) lactic acid fermented flavor material as solid content with respect to 1 part by mass of the solid content of whey mineral (A). Part by mass, preferably 0.01 to 2 parts by mass, more preferably 0.05 to 0.8 parts by mass.
Here, the effect of the present invention cannot be obtained when the content of the (B) lactic acid fermentation flavor material is less than 0.001 part by mass as the solid content with respect to 1 part by mass of the solid content of (A) whey mineral, and 5 mass. If it exceeds the part, the flavor deteriorates due to acidity.

本発明の乳風味付与材は上記乳清ミネラル及び乳酸発酵風味素材に加え、さらに(C)リン脂質を(A)乳清ミネラルの固形分1質量部に対し、0.0001〜0.5質量部、好ましくは0.0005〜0.1質量部、より好ましくは0.001〜0.05質量部含有するものであることが、より乳のコク味が高くなる点、及び、乳清ミネラルによってイオン強度が高くなり、乳酸発酵風味素材の分散性が損なわれたり凝集物が発生することを防止できる点、さらには、乳風味付与材添加時の飲食品、あるいは飲食品の生地への分散性が高まる点で好ましい。   The milk flavor imparting material of the present invention is added to the whey mineral and the lactic acid fermentation flavor material, and (C) phospholipid is 0.0001 to 0.5 mass based on 1 part by mass of the solid content of (A) whey mineral. Parts, preferably 0.0005 to 0.1 parts by mass, more preferably 0.001 to 0.05 parts by mass, depending on the point that the richness of milk becomes higher and whey minerals It is possible to prevent the dispersibility of the lactic acid fermented flavor material from being impaired or the formation of aggregates due to the increase in ionic strength. Is preferable in terms of increasing

ここで、(A)乳清ミネラルの固形分1質量部に対する(C)リン脂質の含有量が0.0001質量部未満であると本発明の効果が得られず、0.5質量部を超えるとリン脂質特有の苦味が出るため、風味が悪化してしまうことがある。
なお、上記(C)リン脂質含量には、(B)乳酸発酵風味素材や下記のその他の成分に含まれるリン脂質についても算入する。
Here, the effect of the present invention cannot be obtained when the content of (C) phospholipid is less than 0.0001 part by mass with respect to 1 part by mass of the solid content of (A) whey mineral, and exceeds 0.5 part by mass. Because of the bitterness peculiar to phospholipids, the flavor may deteriorate.
The (C) phospholipid content also includes phospholipids contained in the (B) lactic acid fermentation flavor material and other components described below.

本発明で使用するリン脂質は、特に限定されるものではなく、食品に使用できるリン脂質であればどのようなリン脂質でも構わない。上記リン脂質としては、例えば、スティンゴミエリン等のスフィンゴリン脂質や、ホスファチジルコリン、ホスファチジルエタノールアミン、ホスファチジルセリン、ホスファチジルイノシトール、ホスファチジルグリセロール、ホスファチジン酸等のジアシルグリセロリン脂質を使用することができ、さらに上記リン脂質に対し、ホスホリパーゼ等により酵素処理を行い、乳化力を向上させたリゾリン脂質、上記リン脂質や上記リゾリン脂質を含有する食品素材を使用することができる。本発明ではリン脂質としてこれらの中から選ばれた1種または2種以上を用いることができる。
本発明の乳風味付与材では、上記のリン脂質そのものよりも、上記のリン脂質を含有する食品素材を用いる方が好ましい。このリン脂質を含有する食品素材としては、卵黄、大豆、牛乳、ヤギ乳、ヒツジ乳、馬乳、人乳等の乳があげられるが、風味と食感の面から乳由来のリン脂質を含有する食品素材を用いるのが好ましく、牛乳由来のリン脂質を含有する食品素材を用いるのがさらに好ましい。
The phospholipid used in the present invention is not particularly limited, and any phospholipid may be used as long as it can be used in foods. Examples of the phospholipid include sphingophospholipids such as stingomyelin, and diacylglycerophospholipids such as phosphatidylcholine, phosphatidylethanolamine, phosphatidylserine, phosphatidylinositol, phosphatidylglycerol, and phosphatidic acid. On the other hand, it is possible to use lysophospholipids that have been subjected to enzyme treatment with phospholipase or the like to improve emulsifying power, and food materials containing the phospholipids or lysophospholipids. In this invention, 1 type, or 2 or more types selected from these can be used as a phospholipid.
In the milk flavor imparting material of the present invention, it is preferable to use a food material containing the above phospholipid rather than the above phospholipid itself. Examples of food materials containing this phospholipid include egg yolk, soybean, cow's milk, goat milk, sheep milk, horse milk, human milk, etc., but contain milk-derived phospholipids in terms of flavor and texture. It is preferable to use a food material to be used, and it is more preferable to use a food material containing a phospholipid derived from milk.

上記乳由来のリン脂質を含有する食品素材を使用する場合は、固形分中のリン脂質の含量が該固形分を基準として0.5質量%以上であることが好ましく、より好ましくは2質量%以上、さらに好ましくは3質量%以上、最も好ましくは4〜40質量%である食品素材を使用することが好ましい。   When using the foodstuff containing the said milk-derived phospholipid, it is preferable that the content of the phospholipid in solid content is 0.5 mass% or more on the basis of the solid content, more preferably 2 mass%. As described above, it is preferable to use a food material of 3% by mass or more, and most preferably 4 to 40% by mass.

また、上記のリン脂質を含有する食品素材は、液体状でも、粉末状でも、濃縮物でも構わない。但し、溶剤を用いて乳由来の固形分中のリン脂質の含量が2質量%以上となるように濃縮した食品素材は、風味上の問題から本発明において用いないのが好ましい。
上記乳由来のリン脂質を含有する食品素材の固形分中のリン脂質の定量方法は、例えば以下のような方法にて測定することができる。但し、抽出方法等については乳由来のリン脂質を含有する食品素材の形態等によって適正な方法が異なるためこの定量方法に限定されるものではない。
The food material containing the phospholipid may be liquid, powder, or concentrate. However, it is preferable not to use in the present invention a food material concentrated using a solvent so that the content of phospholipid in the solid content derived from milk is 2% by mass or more, because of a problem in flavor.
The method for quantifying the phospholipid in the solid content of the food material containing the milk-derived phospholipid can be measured, for example, by the following method. However, the extraction method and the like are not limited to this quantification method because an appropriate method varies depending on the form of the food material containing milk-derived phospholipid.

まず、乳由来のリン脂質を含有する食品素材の脂質をFolch法を用いて抽出する。次いで、抽出した脂質溶液を湿式分解法(日本薬学会編、衛生試験法・注解2000 2.1食品成分試験法に記載の湿式分解法に準じる)にて分解した後、モリブデンブルー吸光度法(日本薬学会編、衛生試験法・注解2000 2.1食品成分試験法に記載のリンのモリブデン酸による定量に準じる)によりリン量を求める。求められたリン量から以下の計算式を用いて乳由来のリン脂質を含有する食品素材の固形分100g中のリン脂質の含量(g)を求める。   First, the lipid of the food material containing milk-derived phospholipid is extracted using the Folch method. Next, the extracted lipid solution was decomposed by a wet decomposition method (according to the wet decomposition method described in the Japan Pharmaceutical Association, Sanitary Test Method, Note 2000 2.1 Food Component Test Method), and then the molybdenum blue absorbance method (Japan Pharmaceutical Association). Chapter 2. Hygiene Test Method / Comment 2000 2.1 According to the determination of phosphorus with molybdic acid described in 2.1 Food Composition Test Method), determine the phosphorus content. The content (g) of phospholipid in 100 g of a solid content of a food material containing milk-derived phospholipid is obtained from the obtained amount of phosphorus using the following formula.

リン脂質(g/100g)=〔リン量(マイクロg)/乳原料採取量(g)〕×(25.4)×(0.1/1000)   Phospholipid (g / 100 g) = [phosphorus amount (microg) / milk raw material collection amount (g)] × (25.4) × (0.1 / 1000)

上記の乳由来の固形分中のリン脂質の含有量が0.5質量%以上である食品素材としては、例えば、クリームからバターを製造する際に生じる水相成分(バターミルク)や、クリームまたはバターからバターオイルを製造する際に生じる水相成分があげられる。
上記のクリームからバターを製造する際に生じる水相成分は、乳由来の固形分中のリン脂質の含有量が、通常0.5〜1.5質量%程度である。一方、クリームまたはバターからバターオイルを製造する際に生じる水相成分は、その製法の違いにより組成が大きく異なるが、乳由来の固形分中のリン脂質の含有量が、大凡2〜15質量%であり、多量のリン脂質を含有している。
As a food material in which the content of phospholipid in the solid content derived from milk is 0.5% by mass or more, for example, an aqueous phase component (buttermilk) produced when producing butter from cream, cream or Examples include an aqueous phase component generated when producing butter oil from butter.
As for the aqueous phase component produced when producing butter from the above cream, the content of phospholipid in the solid content derived from milk is usually about 0.5 to 1.5% by mass. On the other hand, the composition of the aqueous phase component produced when producing butter oil from cream or butter varies greatly depending on the production method, but the content of phospholipid in the solid content derived from milk is about 2 to 15% by mass. It contains a large amount of phospholipid.

すなわち本発明では、上記の乳由来の固形分中のリン脂質の含有量が0.5質量%以上である食品素材として、クリームからバターを製造する際に生じる水相成分、及び/又は、クリームまたはバターからバターオイルを製造する際に生じる水相成分を使用することが好ましく、より好ましくはクリームまたはバターからバターオイルを製造する際に生じる水相成分を使用する。   That is, in the present invention, as a food material in which the content of phospholipid in the milk-derived solid content is 0.5% by mass or more, an aqueous phase component produced when producing butter from cream, and / or cream Alternatively, it is preferable to use an aqueous phase component generated when producing butter oil from butter, and more preferably, an aqueous phase component generated when producing butter oil from cream or butter is used.

次に上記のクリームからバターを製造する際に生じる水相成分の製造方法について説明する。
クリームからバターを製造する際に生じる水相成分の製造方法は、例えば以下の通りである。まず、牛乳を遠心分離して得られる脂肪濃度30〜40質量%のクリームをプレートで加温し、遠心分離機によってクリームの脂肪濃度を70〜95質量%まで高める。次いで乳化破壊機で脂肪球を破壊して凝集させ、バター粒を形成させる工程でバターの副産物として発生するものである。
Next, the manufacturing method of the water phase component produced when manufacturing butter from said cream is demonstrated.
A method for producing an aqueous phase component produced when producing butter from cream is, for example, as follows. First, a cream having a fat concentration of 30 to 40% by mass obtained by centrifuging milk is heated on a plate, and the fat concentration of the cream is increased to 70 to 95% by mass using a centrifuge. Next, the fat globule is broken and aggregated by an emulsion breaker, and is produced as a by-product of butter in a process of forming butter granules.

クリームからバターオイルを製造する際に生じる水相成分の製造方法は、例えば以下の通りである。まず、牛乳を遠心分離して得られる脂肪濃度30〜40質量%のクリームをプレートで加温し、遠心分離機によってクリームの脂肪濃度を70〜95質量%まで高める。次いで乳化破壊機で乳化を破壊し、再び遠心分離機で処理することによってバターオイルが得られる。本発明で用いられる上記水相成分は、最後の遠心分離の工程でバターオイルの副産物として発生するものである。   A method for producing an aqueous phase component produced when producing butter oil from cream is, for example, as follows. First, a cream having a fat concentration of 30 to 40% by mass obtained by centrifuging milk is heated on a plate, and the fat concentration of the cream is increased to 70 to 95% by mass using a centrifuge. The butter oil is then obtained by breaking the emulsification with an emulsification breaker and processing again with a centrifuge. The aqueous phase component used in the present invention is generated as a by-product of butter oil in the final centrifugation step.

一方、バターからバターオイルを製造する際に生じる水相成分の製造方法は、例えば以下の通りである。まずバターを溶解機で溶解し熱交換機で加温する。これを遠心分離機で分離することによってバターオイルが得られる。本発明で用いられる上記水相成分は、最後の遠心分離の工程でバターオイルの副産物として発生するものである。該バターオイルの製造に用いられるバターとしては、通常のものが用いられる。   On the other hand, the manufacturing method of the water phase component produced when manufacturing butter oil from butter is as follows, for example. First, the butter is melted with a dissolver and heated with a heat exchanger. Butter oil is obtained by separating this with a centrifuge. The aqueous phase component used in the present invention is generated as a by-product of butter oil in the final centrifugation step. As the butter used for producing the butter oil, ordinary ones are used.

また、本発明においては、乳由来の固形分中のリン脂質の含有量が0.5質量%以上であれば、上記水相成分をそのまま用いてもよく、また噴霧乾燥、濃縮、冷凍などの処理を施したものを用いてもよい。   In the present invention, if the content of phospholipid in the milk-derived solid content is 0.5% by mass or more, the aqueous phase component may be used as it is, and spray drying, concentration, freezing, etc. You may use what gave the process.

また、本発明では、上記の乳由来の固形分中のリン脂質の含量が0.5質量%以上である食品素材のリン脂質の一部または全部をそのままリゾ化してもよく、また濃縮した後にリゾ化してもよい。またさらに得られたリゾ化物をさらに濃縮、あるいは、噴霧乾燥処理等を施してもよい。   In the present invention, part or all of the phospholipid of the food material having a phospholipid content of 0.5% by mass or more in the solid content derived from milk may be lysed as it is, or after concentration. It may be lysed. Further, the obtained lysed product may be further concentrated or spray-dried.

上記乳由来の固形分中のリン脂質の含量が0.5質量%以上である食品素材中の、リン脂質をリゾ化するにはホスホリパーゼAで処理すればよい。ホスホリパーゼAは、リン脂質分子のグリセロール部分と脂肪酸残基とを結びつけている結合を切断し、この脂肪酸残基を水酸基で置き換える作用を有する酵素である。ホスホリパーゼA2の場合、リン脂質分子のグリセロール部分の2位の脂肪酸残基が選択的に切り離される。ホスホリパーゼAは作用する部位の違いによってA1、A2に分かれるが、A2が好ましい。   In order to lyze the phospholipid in the food material having a phospholipid content of 0.5% by mass or more in the milk-derived solid content, it may be treated with phospholipase A. Phospholipase A is an enzyme having an action of cleaving a bond connecting a glycerol part of a phospholipid molecule and a fatty acid residue and replacing the fatty acid residue with a hydroxyl group. In the case of phospholipase A2, the fatty acid residue at position 2 of the glycerol part of the phospholipid molecule is selectively cleaved. Phospholipase A is divided into A1 and A2 depending on the site of action, but A2 is preferred.

また、本発明の乳風味付与材は、リン脂質として上記の乳由来の固形分中のリン脂質の含量が0.5質量%以上である食品素材を用いる場合、該食品素材を固形分として、好ましくは0.1〜8質量%、さらに好ましくは0.5〜7質量%、最も好ましくは1〜4質量%含有するのがよい。   In addition, the milk flavor imparting material of the present invention, when using a food material having a phospholipid content of 0.5 mass% or more in the solid content derived from milk as the phospholipid, the food material as a solid content, Preferably it is 0.1-8 mass%, More preferably, it is 0.5-7 mass%, Most preferably, it is good to contain 1-4 mass%.

本発明の乳風味付与材は、さらに(D)糖類を(A)乳清ミネラルの固形分1質量部に対し、固形分として0.5〜40質量部含有するものであることが、糖類を含有しない飲食品に対して添加した場合であっても十分な乳風味付与効果が得られること、及び、より粉乳類、とくに脱脂粉乳使用時の風味に近い飲食品が得られる点で好ましい。
ここで、(A)乳清ミネラルの固形分1質量部に対する(D)糖類の含有量が固形分として0.5質量部未満であると糖類を添加することによるプラスの効果が得にくく、40質量部を超えると甘味が強すぎて、風味バランスを損なってしまうことがある。
なお、上記(D)糖類含量には、(B)乳酸発酵風味素材、上記リン脂質を含有する食品素材、さらには下記のその他の成分に含まれる糖類についても算入する。
The milk flavor imparting material of the present invention further comprises (D) a saccharide in an amount of 0.5 to 40 parts by mass as a solid relative to 1 part by mass of the solid content of (A) whey mineral. Even if it is a case where it adds with respect to the food / beverage products which do not contain, sufficient milk flavor provision effect is acquired, and the food / beverage products near the flavor at the time of using powdered milk, especially skim milk powder are preferable.
Here, it is difficult to obtain a positive effect by adding the saccharide when (A) the content of the saccharide with respect to 1 part by mass of the whey mineral is less than 0.5 parts by mass as the solid content. If it exceeds the mass part, the sweetness is too strong and the flavor balance may be impaired.
The (D) saccharide content includes (B) a lactic acid fermentation flavor material, a food material containing the phospholipid, and saccharides contained in the following other components.

本発明で使用することができる糖類としては、乳糖をはじめ、ブドウ糖、果糖、ショ糖、麦芽糖、酵素糖化水飴、還元澱粉糖化物、還元水飴、異性化液糖、ショ糖結合水飴、還元糖、還元パラチノース、ソルビトール、還元乳糖、L-アラビノース、トレハロース、キシロース、キシリトール、マルチトール、エリスリトール、マンニトール、フラクトオリゴ糖、大豆オリゴ糖、ガラクトオリゴ糖、乳果オリゴ糖、キシロオリゴ糖、ラフィノース、ラクチュロース、パラチノース、パラチノースオリゴ糖等の糖類や糖アルコール等が挙げられる。これらの糖類は、単独で用いることもでき、又は二種以上を組み合わせて用いることもできる。   Saccharides that can be used in the present invention include lactose, glucose, fructose, sucrose, maltose, enzyme saccharified starch syrup, reduced starch saccharified product, reduced starch syrup, isomerized liquid sugar, sucrose-bound starch syrup, reducing sugar, Reduced palatinose, sorbitol, reduced lactose, L-arabinose, trehalose, xylose, xylitol, maltitol, erythritol, mannitol, fructooligosaccharide, soybean oligosaccharide, galactooligosaccharide, dairy oligosaccharide, xylooligosaccharide, raffinose, lactulose, palatinose, palatinose Examples thereof include sugars such as oligosaccharides and sugar alcohols. These saccharides can be used alone or in combination of two or more.

本発明では、粉乳類、特に脱脂粉乳を使用した場合とほとんど同等の風味を求める場合は、上記糖類の中でも、乳糖を使用することが好ましい。   In the present invention, it is preferable to use lactose among the above saccharides in the case of obtaining almost the same flavor as when powdered milk, particularly skim milk powder is used.

なお、乳糖を使用する場合は、その好ましい含有量は、(A)乳清ミネラルの固形分1質量部に対し、固形分として0.5〜40質量部、好ましくは2〜25質量部、より好ましくは5〜15質量部である。   In addition, when using lactose, the preferable content is 0.5-40 mass parts as solid content with respect to 1 mass part of solid content of (A) whey mineral, Preferably it is 2-25 mass parts. Preferably it is 5-15 mass parts.

さらに、本発明では、粉乳類、特に脱脂粉乳を使用した場合とほとんど同等の風味であり、且つ、水溶性の高い乳風味付与材を求める場合は、上記糖類の中でも、ガラクトオリゴ糖を使用することが好ましい。   Furthermore, in the present invention, galactooligosaccharide is used among the above saccharides when a milk flavor imparting material having almost the same flavor as when milk powder, particularly skim milk powder is used, and having a high water solubility is obtained. Is preferred.

なお、ガラクトオリゴ糖を使用する場合は、その好ましい含有量は、(A)乳清ミネラルの固形分1質量部に対し、固形分として0.5〜40質量部、好ましくは2〜25質量部、より好ましくは5〜15質量部である。   In addition, when using galactooligosaccharide, the preferable content is 0.5-40 mass parts as solid content with respect to 1 mass part of solid content of (A) whey mineral, Preferably it is 2-25 mass parts, More preferably, it is 5-15 mass parts.

また、本発明では、加熱殺菌時等の加熱工程を有する飲食品に使用する乳風味付与材を求める場合は、加熱工程の際の褐変が抑制される点で、還元澱粉糖化物、還元水飴、還元パラチノース、ソルビトール、還元乳糖、キシリトール、マルチトール、エリスリトール、マンニトール、パラチノース、パラチノースオリゴ糖等の糖アルコールを使用することが好ましい。   Moreover, in this invention, when calculating | requiring the milk flavor imparting material used for the food / beverage products which have heating processes, such as the time of heat sterilization, at the point by which the browning in the case of a heating process is suppressed, reduced starch saccharified material, reduced starch syrup, It is preferable to use sugar alcohols such as reduced palatinose, sorbitol, reduced lactose, xylitol, maltitol, erythritol, mannitol, palatinose, palatinose oligosaccharide.

なお、糖アルコールを使用する場合は、その好ましい含有量は、(A)乳清ミネラルの固形分1質量部に対し、固形分として0.5〜40質量部、好ましくは1.8〜25質量部、より好ましくは4.5〜15質量部である。   In addition, when using sugar alcohol, the preferable content is 0.5-40 mass parts as solid content with respect to 1 mass part of solid content of (A) whey mineral, Preferably it is 1.8-25 mass. Part, more preferably 4.5 to 15 parts by mass.

なお、上記糖類の好ましい含有量は、使用する糖類の甘味度を考慮して決定し、糖類を2種以上組み合わせて使用する場合の好ましい含有量はその使用量の比に応じて決定することが好ましい。   The preferable content of the saccharide is determined in consideration of the sweetness of the saccharide to be used, and the preferable content when two or more saccharides are used in combination is determined according to the ratio of the amounts used. preferable.

本発明の乳風味付与材の油脂の含量は、特に制限はないが、飲食品への添加時の分散性や呈味性の点、さらには乳風味付与効果が阻害されるおそれがある点で、好ましくは20質量%以下、より好ましくは10質量%以下、さらに好ましくは5質量%以下、最も好ましくは実質的に含有しないことが好ましい。   The content of fats and oils of the milk flavor imparting material of the present invention is not particularly limited, but in terms of dispersibility and taste at the time of addition to foods and beverages, and further, the milk flavor imparting effect may be impaired. Preferably, it is 20 mass% or less, More preferably, it is 10 mass% or less, More preferably, it is 5 mass% or less, Most preferably, it is preferable not to contain substantially.

なお、ここで、「油脂を実質的に含有しない」とは、レーゼゴットリーブ法で測定した場合、1.0質量%以下、好ましくは0.8質量%以下となる含量である。   Here, “substantially does not contain fats and oils” is a content that is 1.0% by mass or less, preferably 0.8% by mass or less, as measured by the Rosette Gottlieb method.

本発明の乳風味付与材は、本発明の効果を阻害しない限りにおいて、上記(A)、(B)、(C)及び(D)以外のその他の成分を使用することができる。該その他の成分としては、例えば、アルギン酸、アルギン酸塩、ペクチン、LMペクチン、HMペクチン、海藻抽出物、海藻エキス、寒天、グルコマンナン、ローカストビーンガム、グアーガム、ジェランガム、タラガントガム、キサンタンガム、カラギーナン、カードラン、タマリンドシードガム、カラヤガム、タラガム、トラガントガム、アラビアガム、カシアガム、メチルセルロース、カルボキシメチルセルロース、ポリデキストロース等のゲル化剤や安定剤、グリセリン脂肪酸エステル、グリセリン酢酸脂肪酸エステル、グリセリン乳酸脂肪酸エステル、グリセリンコハク酸脂肪酸エステル、グリセリンジアセチル酒石酸脂肪酸エステル、ソルビタン脂肪酸エステル、ショ糖脂肪酸エステル、ショ糖酢酸イソ酪酸エステル、ポリグリセリン脂肪酸エステル、ポリグリセリン縮合リシノレイン酸エステル、プロピレングリコール脂肪酸エステル、ステアロイル乳酸カルシウム、ステアロイル乳酸ナトリウム、ポリオキシエチレンソルビタン脂肪酸エステル等の乳化剤、金属イオン封鎖剤、食塩、岩塩等の塩味剤、アセスルファムカリウム、スクラロース、ステビア、アスパルテーム、サッカリン、ネオテーム、甘草、羅漢果、グリチルリチン、グリチルリチン酸塩、ジヒドロカルコン、ソーマチン、モネリン等の高甘味度甘味料、無機塩、有機酸塩、ジグリセライド、植物ステロール、植物ステロールエステル、直鎖デキストリン・分枝デキストリン・環状デキストリン・難消化性デキストリン等のデキストリン類、水、アルコール、プロピレングリコール、食用油脂、蛋白質、着香料、苦味料、調味料等の呈味成分、着色料、保存料、酸化防止剤、pH調整剤、強化剤、酵素、を配合してもよい。   The milk flavor imparting material of the present invention can use other components other than the above (A), (B), (C) and (D) as long as the effects of the present invention are not impaired. Examples of the other components include alginic acid, alginate, pectin, LM pectin, HM pectin, seaweed extract, seaweed extract, agar, glucomannan, locust bean gum, guar gum, gellan gum, tarragant gum, xanthan gum, carrageenan, curdlan , Tamarind seed gum, karaya gum, tara gum, tragacanth gum, gum arabic, cassia gum, methylcellulose, carboxymethylcellulose, polydextrose and other gelling agents and stabilizers, glycerin fatty acid ester, glycerin acetic acid fatty acid ester, glycerin lactate fatty acid ester, glycerin succinic acid fatty acid Ester, glycerin diacetyl tartaric acid fatty acid ester, sorbitan fatty acid ester, sucrose fatty acid ester, sucrose acetate isobutyric acid ester, polyglyceride Phosphoric fatty acid ester, polyglycerin condensed ricinoleic acid ester, propylene glycol fatty acid ester, stearoyl calcium lactate, sodium stearoyl lactate, emulsifier such as polyoxyethylene sorbitan fatty acid ester, sequestering agent, salt, salt salt and rock salt, acesulfame potassium, High-sweetness sweeteners such as sucralose, stevia, aspartame, saccharin, neotame, licorice, rahan fruit, glycyrrhizin, glycyrrhizinate, dihydrochalcone, thaumatin, monelin, inorganic salts, organic acid salts, diglycerides, plant sterols, plant sterol esters, Dextrins such as linear dextrin, branched dextrin, cyclic dextrin, indigestible dextrin, water, alcohol, propylene glycol, edible oil and fat, protein , Flavoring agents, bittering agent, taste components of seasonings, coloring agents, preservatives, antioxidants, pH modifiers, reinforcing agents, enzymes, may be incorporated.

なお、本発明では、上記その他の原料は乳風味付与材の固形分中、固形分として80質量%以下とすることが好ましく、より好ましくは50質量%以下とする。   In addition, in this invention, it is preferable that the said other raw material shall be 80 mass% or less as solid content in solid content of a milk flavor imparting material, More preferably, it shall be 50 mass% or less.

また本発明の乳風味付与材の、乳清ミネラル及び乳酸発酵風味素材の各固形分の合計した含有量は、本発明の乳風味付与材の固形分中、好ましくは1〜100質量%、より好ましくは10〜95質量%、さらに好ましくは10〜60質量%、最も好ましくは10〜20質量%である。1質量%以上であることは本発明の効果が明確に得られるという観点から好ましい。   Moreover, the total content of each solid content of the whey mineral and lactic acid fermentation flavor material of the milk flavor imparting material of the present invention is preferably 1 to 100% by mass in the solid content of the milk flavor imparting material of the present invention. Preferably it is 10-95 mass%, More preferably, it is 10-60 mass%, Most preferably, it is 10-20 mass%. The content of 1% by mass or more is preferable from the viewpoint that the effects of the present invention can be clearly obtained.

本発明の乳風味付与材の形態としては、特に制限されず、固形、顆粒状、粉末状、ペースト状、流動状、液状などのいずれの形態であってもよいが、粉末状又は液状であることが好ましい。   The form of the milk flavor imparting material of the present invention is not particularly limited, and may be any form such as solid, granule, powder, paste, fluid, and liquid, but is powdery or liquid. It is preferable.

また本発明の乳風味付与材がペースト状、固形、顆粒状、粉末状のいずれかの形態である場合、乳清ミネラル、乳酸発酵風味素材、リン脂質及び糖類の4成分の合計した含有量は、本発明の乳風味付与材中、固形分として、好ましくは0.5〜100質量%、より好ましくは10〜100質量%、さらに好ましくは20〜100質量%、最も好ましくは60〜100質量%である。
この範囲内とすることにより、粉乳類、とくに脱脂粉乳の代替として一般的に使用することができる。
Moreover, when the milk flavor imparting material of the present invention is in the form of paste, solid, granule or powder, the total content of the four components of whey mineral, lactic acid fermentation flavor material, phospholipid and saccharide is In the milk flavor imparting material of the present invention, the solid content is preferably 0.5 to 100% by mass, more preferably 10 to 100% by mass, further preferably 20 to 100% by mass, and most preferably 60 to 100% by mass. It is.
By setting it within this range, it can be generally used as an alternative to milk powder, particularly skim milk powder.

尚、本発明の乳風味付与材が流動状又は液状の形態である場合、乳清ミネラル、乳酸発酵風味素材、リン脂質及び糖類の4成分の合計した含有量は、本発明の乳風味付与材中、固形分として、好ましくは0.5〜20質量%、より好ましくは3.5〜10質量%である。   In addition, when the milk flavor imparting material of the present invention is in a fluid or liquid form, the total content of the four components of whey mineral, lactic acid fermentation flavor material, phospholipid and saccharide is the milk flavor imparting material of the present invention. The solid content is preferably 0.5 to 20% by mass, more preferably 3.5 to 10% by mass.

この範囲内とすることにより、粉乳類の水溶液として使用するかのように、溶解度を考慮することなく、粉乳類、とくに脱脂粉乳の代替として便利に使用することができる。   By setting it within this range, it can be conveniently used as an alternative to powdered milk, particularly skim milk powder, without considering solubility as if it is used as an aqueous solution of milk powder.

本発明の乳風味付与材は、乳風味を必要とする様々な飲食品に適用可能である。そして、本発明の乳風味付与材は、その形態がペースト状、固形、顆粒状、粉末状のいずれかである場合は粉乳類の代替として直接的に粉乳類、とくに脱脂粉乳の代替として、本発明の乳風味付与材の形態がペースト状、流動状、液状のいずれかである場合はその水分を考慮の上で粉乳類、とくに脱脂粉乳の代替として使用することができる。   The milk flavor imparting material of the present invention can be applied to various foods and drinks that require milk flavor. And when the form of the milk flavor imparting material of the present invention is any of paste, solid, granule and powder, it is directly used as an alternative to powdered milk, especially as an alternative to skim milk powder. When the milk flavor imparting material of the invention is in the form of paste, fluid or liquid, it can be used as an alternative to powdered milk, particularly skim milk in consideration of its moisture.

上記飲食品の具体例としては、例えばカフェオレ・ミルクティー・抹茶ミルク・ミルクココア・アイスミルクココア・ホットチョコレート・乳酸菌飲料・炭酸入り乳酸菌飲料・発酵乳飲料・ドリンクヨーグルト・無脂肪乳・低脂肪乳・いちごミルク・果汁飲料・果実飲料・カルーアミルク・ベイリーズミルク等の各種飲料、カスタードクリーム・フラワーペースト・ホワイトクリーム・バタークリーム等のクリーム類、シチュー・カレー・ホワイトソース・グラタン等のクリーム状食品、コーンスープ・クラムチャウダー等のスープ類、アイスクリーム、アイスミルク、ラクトアイス・ゼリー・杏仁豆腐・ババロア・ムース・プリン等のデザート類、マーガリン類、マヨネーズ・ドレッシング等のドレッシング類、チーズ様食品、パン類、ドーナツ類・キャラメル・キャンディー・チョコレート・ビスケット・クッキー・スポンジケーキ・バターケーキ等の菓子類・ハム・ソーセージその他加工食品を挙げることができる。   Specific examples of the food and drink include, for example, cafe au lait, milk tea, matcha milk, milk cocoa, iced milk cocoa, hot chocolate, lactic acid bacteria beverage, carbonated lactic acid bacteria beverage, fermented milk beverage, drink yogurt, non-fat milk, and low fat. Various beverages such as milk, strawberry milk, fruit juice beverages, fruit beverages, kahlua milk, Baileys milk, creams such as custard cream, flower paste, white cream, butter cream, creamy foods such as stew, curry, white sauce, gratin , Soups such as corn soup and crumb chowder, ice cream, ice milk, desserts such as lacto ice, jelly, apricot tofu, bavaroa, mousse and pudding, dressings such as margarines, mayonnaise and dressing, cheese-like food, bread Kind Mention may be made of confectionery, ham, sausages and other processed foods in the summer class, caramel candy, chocolate, biscuits, cookies, sponge cake, butter cake and the like.

上記飲食品における、本発明の乳風味付与材の添加量は、特に限定されず、使用する飲食品や、求める乳風味の強さに応じて適宜決定されるが、飲食品100質量部に対し、乳清ミネラル及び乳酸発酵風味素材の合計した固形分の含有量として好ましくは0.05〜20質量部、より好ましくは0.2〜10質量部、さらに好ましくは0.3〜5質量部となる量である。0.2質量部未満、又は、20質量部を超えると、乳風味付与効果が認められ難く、また20質量部を超えると、乳清ミネラルの苦味が感じられるおそれがある。   The addition amount of the milk flavor imparting material of the present invention in the above food and drink is not particularly limited and is appropriately determined according to the food and drink to be used and the strength of the milk flavor to be sought. The total solid content of the whey mineral and the lactic acid fermentation flavor material is preferably 0.05 to 20 parts by mass, more preferably 0.2 to 10 parts by mass, and still more preferably 0.3 to 5 parts by mass. Is the amount. If it is less than 0.2 parts by mass or exceeds 20 parts by mass, the effect of imparting milk flavor is hardly recognized, and if it exceeds 20 parts by mass, the bitter taste of whey minerals may be felt.

また、本発明の乳風味付与材が糖類を含有しないものである場合は、飲食品の糖類含量が少ない場合には、その効果が十分に発揮できない場合があるため、飲食品に含まれる糖類の含有量と、添加する風味付与材に含まれる乳清ミネラルの比が、乳清ミネラルの固形分1質量部に対し、飲食品に含まれる糖類が、固形分として0.5質量部以上、好ましくは2質量部以上、より好ましくは5質量部以上であることが好ましい。   Moreover, when the milk flavor imparting material of the present invention does not contain saccharides, when the saccharide content of the food or drink is low, the effect may not be sufficiently exhibited. The ratio of the whey mineral contained in the content and the flavor-imparting material added is 1 part by mass of the solid content of the whey mineral, and the saccharide contained in the food or drink is preferably 0.5 parts by mass or more as the solid content. Is preferably 2 parts by mass or more, more preferably 5 parts by mass or more.

次に、本発明の飲食品について述べる。
本発明の飲食品は、上記本発明の乳風味付与材を添加して得られた飲食品であり、粉乳類、とくに脱脂粉乳の使用量が少ない場合、さらには粉乳類を含有しない場合であっても、飲食品に豊かな厚みのある乳風味を付与されているという特徴を有するものである。
飲食品における上記本発明の乳風味付与材の添加方法はとくに制限されず、飲食品の製造時、加工時、調理時、飲食時等に、飲食品またはその素材に混合、散布、噴霧、溶解等任意の手段により行なわれる。
なお、本発明の飲食品における上記本発明の乳風味付与材の添加量は、上述のとおりである。
Next, the food / beverage products of this invention are described.
The food / beverage product of the present invention is a food / beverage product obtained by adding the milk flavor imparting material of the present invention described above, and it is a case where the amount of powdered milk, particularly skim milk powder is small, or even when it does not contain powdered milk. However, it has the characteristic that the milk flavor with rich thickness is provided to food-drinks.
The method for adding the milk flavor imparting material of the present invention in foods and drinks is not particularly limited, and is mixed, sprayed, sprayed, dissolved in foods and drinks or their materials during the production, processing, cooking, and food and drink production. Or any other means.
In addition, the addition amount of the said milk flavor imparting material of the said invention in the food / beverage products of this invention is as above-mentioned.

次に、本発明の飲食品の乳風味付与方法について述べる。
本発明の飲食品の乳風味付与方法は、上記本発明の乳風味付与材を飲食品に添加するものであり、粉乳類、とくに脱脂粉乳の使用量が少ない場合、さらには粉乳類を含有しない場合であっても、飲食品に豊かな厚みのある乳風味を付与するものである。
本発明の乳風味付与材を飲食品に添加する方法、及び、添加量については上述のとおりである。
Next, the milk flavor imparting method for food and drink according to the present invention will be described.
The method for imparting milk flavor of foods and beverages according to the present invention is to add the above-mentioned milk flavor imparting material of the present invention to foods and beverages. When the amount of powdered milk, particularly skim milk powder is small, it does not contain powdered milk. Even if it is a case, a rich and thick milk flavor is given to food and drink.
The method of adding the milk flavor imparting material of the present invention to food and drink and the amount added are as described above.

以下に本発明の実施例を挙げるが、本発明は以下の実施例によって限定されるものではない。   Examples of the present invention will be given below, but the present invention is not limited to the following examples.

<乳清ミネラルの製造>
チーズを製造する際に副産物として得られる甘性ホエーをナノ濾過膜分離した後、さらに逆浸透濾過膜分離により固形分が20質量%となるまで濃縮し、次いで、80℃、20分の加熱処理をして生じた沈殿を遠心分離して除去し、これをさらにエバポレーターで濃縮し、スプレードライ法により、固形分98質量%の乳清ミネラルAを得た。得られた乳清ミネラルAの固形分中のカルシウム含量は0.4質量%であった。
<Manufacture of whey minerals>
After the sweet whey obtained as a by-product when producing cheese is subjected to nanofiltration membrane separation, it is further concentrated by reverse osmosis filtration membrane separation until the solid content becomes 20% by mass, and then heat treatment at 80 ° C. for 20 minutes The resulting precipitate was removed by centrifugation, further concentrated by an evaporator, and whey mineral A having a solid content of 98% by mass was obtained by spray drying. The calcium content in the solid content of the obtained whey mineral A was 0.4% by mass.

<乳酸発酵風味素材Aの調製>
脱脂粉乳(リン脂質含量0.3質量%未満)10質量部、ホエイパウダー(リン脂質含量0.2質量%未満)2質量部及び水82.99質量部を混合し、55℃に加熱し、ケミコロイド社製シャーロットコロイドミルにてクリアランス0.2mm、回転数3500rpmにて均質化し、プレート式熱交換器にて80℃で3分間加熱殺菌後、プレート式熱交換器にて30℃に冷却し、無脂乳固形分が12質量%、遊離脂肪酸含量が0.01質量%未満であるミックス液を調製した。この乳原料を含有するミックス液にLactococcus lactis subsp. lactis var. diacetylactis及びLeuconostoc mesenteroides subsp. Cremorisの2種から成る乳酸菌スターター0.01質量部を加え、30℃で15回転/分で攪拌しながら5時間発酵した。ここで、リン脂質として、クリームからバターオイルを製造する際に生じる水相成分の濃縮物(リン脂質含量3.7質量%、蛋白質含量12質量%、無脂乳固形分33.4質量%、乳由来の固形分38質量%、乳由来の固形分中のリン脂質含量9.8質量%)5質量部を添加し、更に第2乳酸発酵工程として、30℃で10回転/分で攪拌しながら7時間発酵し、固形分12質量%、リン脂質を0.2質量%、糖類を5質量%含有し、pHが4.71である乳酸発酵風味素材Aを得た。
<Preparation of lactic acid fermentation flavor material A>
Skim milk powder (phospholipid content less than 0.3% by weight) 10 parts by weight, whey powder (phospholipid content less than 0.2% by weight) 2 parts by weight and water 82.99 parts by weight, heated to 55 ° C., Homogenized at a clearance of 0.2 mm and a rotation speed of 3500 rpm in a Charlotte colloid mill manufactured by Chemi-Colloid Co., Ltd., sterilized by heating at 80 ° C. for 3 minutes in a plate heat exchanger, cooled to 30 ° C. in a plate heat exchanger, A mix solution having a non-fat milk solid content of 12% by mass and a free fatty acid content of less than 0.01% by mass was prepared. 0.01 parts by mass of a lactic acid bacteria starter composed of two species of Lactococcus lactis subsp. Lactis var. Diacetylactis and Leuconostoc mesenteroides subsp. Cremoris is added to the mixed solution containing the milk ingredients, and the mixture is stirred at 30 ° C. at 15 rpm. Fermented for hours. Here, as a phospholipid, a concentrate of an aqueous phase component produced when producing butter oil from cream (phospholipid content 3.7 mass%, protein content 12 mass%, non-fat milk solid content 33.4 mass%, 5 parts by weight of milk-derived solid content 38% by weight and phospholipid content 9.8% by weight in milk-derived solid content), and in the second lactic acid fermentation step, the mixture was stirred at 30 ° C. at 10 rpm. While fermenting for 7 hours, a lactic acid fermentation flavor material A containing 12% by mass of solids, 0.2% by mass of phospholipids, 5% by mass of saccharides, and having a pH of 4.71 was obtained.

<乳酸発酵風味素材Bの調製>
脱脂粉乳(リン脂質含量0.3質量%未満)4.5質量部、ホエイパウダー(リン脂質含量0.2質量%未満)3.5質量部、トータルミルクプロテイン1質量部(リン脂質含量0.1質量%未満)、無塩バター(リン脂質含量0.5質量%未満)4質量部、バター分解物(デリシャンバターテイストHB−2、大洋香料株式会社製)0.2質量部、及び水86.78質量部を混合し、55℃に加熱し、ケミコロイド社製シャーロットコロイドミルにてクリアランス0.2mm、回転数3500rpmにて均質化し、プレート式熱交換器にて80℃で3分間加熱殺菌後、プレート式熱交換器にて30℃に冷却し、無脂乳固形分が9質量%、遊離脂肪酸含量が0.035質量%であるミックス液を調製した。この乳原料を含有するミックス液にLactobacillus helveticus及びLeuconostoc mesenteroidesの乳酸菌スターター各0.01質量部を加え、30℃で15回転/分で攪拌しながら12時間発酵し、固形分13質量%、リン脂質を0.05質量%未満、糖類を6質量%含有し、pHが4.54である乳酸発酵風味素材Bを得た。
<Preparation of lactic acid fermentation flavor material B>
Nonfat dry milk (phospholipid content less than 0.3% by weight) 4.5 parts by weight, whey powder (phospholipid content less than 0.2% by weight) 3.5 parts by weight, total milk protein 1 part by weight (phospholipid content 0. Less than 1% by mass), 4 parts by mass of unsalted butter (phospholipid content less than 0.5% by mass), butter degradation products (Delician Butter Taste HB-2, manufactured by Taiyo Inc.), and water 86.78 parts by mass are mixed, heated to 55 ° C., homogenized at a clearance of 0.2 mm and a rotational speed of 3500 rpm using a chemi-colloid Charlotte colloid mill, and sterilized by heating at 80 ° C. for 3 minutes in a plate heat exchanger. Then, it cooled at 30 degreeC with the plate-type heat exchanger, and prepared the mix liquid whose non-fat milk solid content is 9 mass% and free fatty acid content is 0.035 mass%. Add 0.01 parts by weight each of Lactobacillus helveticus and Leuconostoc mesenteroides lactic acid bacteria starter to the mixed solution containing this milk raw material, and ferment for 12 hours with stirring at 30 rev / min at 30 ° C., solid content 13% by mass, phospholipid The lactic acid fermentation flavor raw material B which contains less than 0.05 mass%, 6 mass% saccharides, and pH is 4.54 was obtained.

<乳風味付与材の製造>
〔実施例1〜11〕
上記乳清ミネラルA、上記乳酸発酵風味素材A、市販プレーンヨーグルト(ブルガリアヨーグルト:株式会社明治製)、ヨーグルトパウダー(ヨーグルトパウダーYP−A:森永乳業(株)製)、製パン用乳酸発酵風味素材(ポルテTZ−10: MCフードスペシャリティーズ株式会社製)、 クリームからバターオイルを製造する際に生じる水相成分の粉末化品、クリームからバターオイルを製造する際に生じる水相成分の濃縮物、高純度リン脂質(レシオンP:理研ビタミン製)、乳糖、還元水あめ(PO−500:三菱商事フードテック)、ガラクトオリゴ糖(オリゴメイト55N:ヤクルト薬品工業)、及び、水を使用し、表1の配合にしたがって、本発明の乳風味付与材A〜Kを製造した。
<Manufacture of milk flavoring material>
[Examples 1 to 11]
Whey mineral A, lactic acid fermentation flavor material A, commercially available plain yogurt (Bulgaria yogurt: manufactured by Meiji Co., Ltd.), yogurt powder (yogurt powder YP-A: Morinaga Milk Industry Co., Ltd.), lactic acid fermentation flavor material for baking (Porte TZ-10: manufactured by MC Food Specialties Co., Ltd.), powdered product of aqueous phase component produced when producing butter oil from cream, concentrate of aqueous phase component produced when producing butter oil from cream, Using high-purity phospholipid (Resion P: manufactured by Riken Vitamin), lactose, reduced water candy (PO-500: Mitsubishi Corporation Foodtech), galactooligosaccharide (Oligomate 55N: Yakult Pharmaceutical Co., Ltd.) and water, According to the formulation, milk flavor imparting materials A to K of the present invention were produced.

Figure 2016202150
Figure 2016202150

なお製造方法については、実施例1〜3及び実施例8〜11については全原料を溶解・混合する方法によったが、実施例4〜7については下記の製造方法によって製造した。
実施例4については、ハイスピードバキュームドライヤFS-VDGS-10J(アーステクニカ)を使用して、乳酸発酵風味素材以外の原料を混合し、続いて乳酸発酵風味素材を添加・混合し、その後、45℃、減圧下で乾燥し、固形分含量98.0質量%の粉末状の乳風味付与材Dを得た。
実施例5については、ハイスピードバキュームドライヤFS-VDGS-10J(アーステクニカ)を使用して、乳酸発酵風味素材以外の原料を混合し、続いて乳酸発酵風味素材及び乳素材(濃縮物)を添加・混合し、その後、45℃、減圧下で乾燥し、固形分含量97.8質量%の粉末状の乳風味付与材Eを得た。
In addition, about the manufacturing method, although it was based on the method of melt | dissolving and mixing all the raw materials about Examples 1-3 and Examples 8-11, it manufactured by the following manufacturing method about Examples 4-7.
For Example 4, using a high-speed vacuum dryer FS-VDGS-10J (Earth Technica), ingredients other than the lactic acid fermentation flavor material were mixed, and then the lactic acid fermentation flavor material was added and mixed. The powder was dried under reduced pressure at 0 ° C. to obtain a powdery milk flavor imparting material D having a solid content of 98.0% by mass.
For Example 5, using high-speed vacuum dryer FS-VDGS-10J (Earth Technica), mix ingredients other than lactic acid fermentation flavor material, then add lactic acid fermentation flavor material and milk material (concentrate) -After mixing, it dried under reduced pressure at 45 degreeC, and the powdery milk flavor imparting material E with a solid content of 97.8 mass% was obtained.

実施例6については、乳糖以外の原料(24質量部)を水100質量部に分散し、この分散液をスプレードライヤーで乾燥した。該粉末全量(14.8質量部)に対し、85質量部の乳糖を粉体混合機で混合し、固形分含量99.8質量%の粉末状の乳風味付与材Fを得た。   For Example 6, raw materials other than lactose (24 parts by mass) were dispersed in 100 parts by mass of water, and this dispersion was dried with a spray dryer. With respect to the total amount of the powder (14.8 parts by mass), 85 parts by mass of lactose was mixed with a powder mixer to obtain a powdery milk flavor imparting material F having a solid content of 99.8% by mass.

実施例7については、全原料を溶解・混合後、UHT殺菌を行ない、液状の乳風味付与材Gを得た。
得られた乳風味付与材A〜Kの、(A)乳清ミネラルの固形分1質量部に対する(B)乳酸発酵風味素材の固形分含有量、(A)乳清ミネラルの固形分1質量部に対する(C)リン脂質の含有量、及び、(A)乳清ミネラルの固形分1質量部に対する(D)糖類の固形分含有量については表2に記載した。
また、得られた乳風味付与材A〜Kの、乳清ミネラル、乳酸発酵風味素材、リン脂質及び糖類の4成分の合計した固形分含有量については表3に記載した。
About Example 7, after melt | dissolving and mixing all the raw materials, UHT sterilization was performed and the liquid milk flavor imparting material G was obtained.
(B) Solid content of lactic acid fermentation flavor material with respect to (A) 1 part by weight of solid content of whey mineral, (A) 1 part by weight of solid content of whey mineral Table 2 shows the (C) phospholipid content and (D) saccharide solid content of 1 part by mass of (A) whey mineral solid content.
In addition, the total solid content of the four components of whey minerals, lactic acid fermentation flavor materials, phospholipids and sugars of the obtained milk flavor imparting materials A to K is shown in Table 3.

得られた乳風味付与材A〜Kは下記の「乳風味評価試験」を行った。   The obtained milk flavor imparting materials A to K were subjected to the following “milk flavor evaluation test”.

Figure 2016202150
Figure 2016202150

Figure 2016202150
Figure 2016202150

<乳風味評価試験1>
乳風味付与材A〜F及びH〜Jについて炭水化物濃度が4.8質量%になるように表4に記載の配合にしたがって水に溶解し、水溶液とし、乳風味評価試験に供した。
一方、脱脂粉乳の9質量%水溶液を用意し、上記乳風味付与材の水溶液と、トップの乳風味、乳風味の伸び、苦み及びえぐ味、の3点について1〜7点の7段階評価(脱脂粉乳9質量%水溶液を4点としたときの強弱を、最も強い場合を7点、最も弱い場合を1点として点数化)を行い、10名のパネラーの平均点を表5に記載した。
表5の結果から、本発明の乳風味付与材A〜F及びH〜Jは、脱脂粉乳と同等の風味のプロフィールを有しながら、苦みやえぐ味が軽減されていることがわかる。
<Milk flavor evaluation test 1>
The milk flavor imparting materials A to F and H to J were dissolved in water in accordance with the formulation described in Table 4 so that the carbohydrate concentration was 4.8% by mass to obtain an aqueous solution, which was subjected to a milk flavor evaluation test.
On the other hand, a 9% by weight aqueous solution of skim milk powder is prepared, and a seven-step evaluation of 1 to 7 points is performed on the three points of the aqueous solution of the milk flavor imparting material and the top milk flavor, milk flavor elongation, bitterness and gummy taste ( The strength when the non-fat dry milk 9 mass% aqueous solution was 4 points was scored with 7 points for the strongest case and 1 point for the weakest case, and the average points of 10 panelists are shown in Table 5.
From the results in Table 5, it can be seen that the milk flavor imparting materials A to F and H to J of the present invention have a flavor profile equivalent to that of skim milk powder, while the bitterness and gummy taste are reduced.

Figure 2016202150
Figure 2016202150

Figure 2016202150
Figure 2016202150

<乳風味付与試験1(カフェオレ)>
〔実施例12〕
市販レギュラーコーヒー40gをお湯620gで抽出したものをコーヒー抽出液とした。このコーヒー抽出液370質量部に砂糖35質量部、牛乳40質量部、乳風味付与材G1.5質量部、水50質量部を混合し、カフェオレAを作成した。
<Milk flavor imparting test 1 (cafe au lait)>
Example 12
A coffee extract was obtained by extracting 40 g of commercial regular coffee with 620 g of hot water. Café Ale A was prepared by mixing 370 parts by mass of this coffee extract with 35 parts by mass of sugar, 40 parts by mass of milk, 1.5 parts by mass of milk flavoring material G, and 50 parts by mass of water.

〔比較例1〕
市販レギュラーコーヒー40gをお湯620gで抽出したものをコーヒー抽出液とした。このコーヒー抽出液370質量部に砂糖35質量部、牛乳40質量部、脱脂粉乳6質量部、水49質量部を混合し、カフェオレBを作成した。
対照として、上記コーヒー抽出液370質量部に砂糖35質量部、牛乳95質量部を混合して得られたカフェオレCを用意し、上記実施例12で得られたカフェオレAと比較例1で得られたカフェオレBの風味の比較を行ったところ、比較例1のカフェオレBは、牛乳のみを使用した対照のカフェオレCに比べ、乳脂量が少なく、カロリーを低減したものであるが、コクが無く、粉臭のするものであった。一方、実施例12のカフェオレAは、比較例1のカフェオレBと比べ、炭水化物量が少ないため、さらに低カロリーとなっているにもかかわらず、牛乳のみを使用した対照のカフェオレCに近いコクがあり、異味のない、豊かな厚みのある乳風味を付与されていた。
[Comparative Example 1]
A coffee extract was obtained by extracting 40 g of commercial regular coffee with 620 g of hot water. Caffe oleau B was prepared by mixing 370 parts by mass of this coffee extract with 35 parts by mass of sugar, 40 parts by mass of milk, 6 parts by mass of skim milk powder, and 49 parts by mass of water.
As a control, café au lait C obtained by mixing 370 parts by mass of the coffee extract with 35 parts by mass of sugar and 95 parts by mass of milk was prepared, and the café olea A obtained in Example 12 and Comparative Example 1 were used. When the flavors of the obtained cafe au lait B were compared, the cafe au lait B of Comparative Example 1 had less milk fat and reduced calories compared to the control cafe oleo C using only milk. There was no richness and a powdery odor. On the other hand, the cafe au lait A of Example 12 has a lower amount of carbohydrates than the café oleo B of Comparative Example 1, and thus, even though the calorie is lower, the control cafe oleo C using only milk is used. It had a near body and was given a rich and thick milk flavor without any taste.

〔実施例13〕
乳風味付与材G1.5質量部に代えて乳風味付与材K1.5質量部に変更した以外は実施例12と同様の配合・製法でカフェオレDを作成し、実施例12と同様にカフェオレB及びカフェオレCとの風味の比較を行ったところ、カフェオレDは、比較例1のカフェオレBと比べ、炭水化物量が少ないため、さらに低カロリーとなっているにもかかわらず、牛乳のみを使用した対照のカフェオレCに近いコクがあり、異味のない、豊かな厚みのある乳風味を付与されていた。
Example 13
Café au lait D was prepared by the same composition and production method as Example 12 except that the milk flavor imparting material G was changed to 1.5 parts by mass instead of the milk flavor imparting material G 1.5 parts by mass. When the flavors of Ole B and Caffe Ole C were compared, Caffe Ole D had a lower amount of carbohydrate than Café Ole B of Comparative Example 1 and therefore, even though it had a lower calorie, milk. There was a richness close to that of the control cafe au lait C, which had a rich and thick flavor without taste.

<乳風味付与試験2(ミルクチョコレート)>
〔実施例14〕
カカオマス90質量部、砂糖164質量部、全粉乳50質量部、脱脂粉乳10質量部、乳風味付与材D20質量部、難消化性デキストリン13質量部、ココアバター125質量部、ハードバター25質量部、レシチン2.5質量部、香料1質量部 の配合で、常法によりミルクチョコレートAを得た。
<Milk flavor imparting test 2 (milk chocolate)>
Example 14
90 parts by weight of cacao, 164 parts by weight of sugar, 50 parts by weight of whole milk powder, 10 parts by weight of skim milk powder, 20 parts by weight of milk flavoring material D, 13 parts by weight of indigestible dextrin, 125 parts by weight of cocoa butter, 25 parts by weight of hard butter, Milk chocolate A was obtained by a conventional method with 2.5 parts by mass of lecithin and 1 part by mass of fragrance.

〔比較例2〕
カカオマス90質量部、砂糖164質量部、全粉乳50質量部、脱脂粉乳43質量部、ココアバター125質量部、ハードバター25質量部、レシチン2.5質量部、香料1質量部の配合で、常法により比較用のミルクチョコレートBを得た。
上記2種のミルクチョコレートの風味の比較を行ったところ、両者はほぼ同等の強さの厚みのある乳風味であったが、実施例14で得られたミルクチョコレートAの方が豊かな乳風味が感じられた。
[Comparative Example 2]
A blend of 90 parts by weight of cacao, 164 parts by weight of sugar, 50 parts by weight of whole milk powder, 43 parts by weight of skim milk powder, 125 parts by weight of cocoa butter, 25 parts by weight of hard butter, 2.5 parts by weight of lecithin, and 1 part by weight of flavor. Milk milk B for comparison was obtained by the method.
When the flavors of the above-mentioned two types of milk chocolate were compared, both had a thick milk flavor with almost the same strength, but the milk chocolate A obtained in Example 14 had a richer milk flavor. Was felt.

<乳風味付与試験3(マーガリン)>
〔実施例15〕
パームスーパーオレインのランダムエステル交換油脂95質量部及びパームステアリン5質量部を均一に混合した混合油脂72.47質量部に、グリセリン脂肪酸エステル3質量部、60%トコフェロール0.01質量部を、添加、混合、溶解した油相を60℃に保温した。一方、水20.89質量部に、乳風味付与材E2.43質量部、食塩1質量部、香料0.2質量部を、添加、溶解した水相を油相に添加し、予備乳化液とし、90℃1分蒸気を用いて殺菌処理したのち、コンビネーターを用いて急冷可塑化を行い、マーガリンAを得た。
<Milk flavor imparting test 3 (margarine)>
Example 15
To 72.47 parts by mass of mixed fats and oils uniformly mixed with 95 parts by mass of random transesterified fat and oil of palm super olein and 5 parts by mass of palm stearin, 3 parts by mass of glycerin fatty acid ester, 0.01 parts by mass of 60% tocopherol, The mixed and dissolved oil phase was kept at 60 ° C. On the other hand, to the 20.89 parts by mass of water, 2.43 parts by mass of the milk flavor imparting material E, 1 part by mass of salt, and 0.2 parts by mass of the fragrance are added and the dissolved aqueous phase is added to the oil phase to obtain a preliminary emulsion. After sterilizing using steam at 90 ° C. for 1 minute, quenching plasticization was performed using a combinator to obtain margarine A.

〔比較例3〕
水を20.89質量部から19.32質量部に変更し、さらに乳風味付与材E2.43質量部に代えて脱脂粉乳4質量部に変更した以外は実施例15の配合・製法と同様にして、比較用のマーガリンBを得た。
上記2種のマーガリンの風味の比較を行ったところ、両者はほぼ同等の強さの厚みのある乳風味であったが、実施例15で得られたマーガリンAの方が豊かな乳風味が感じられた。
[Comparative Example 3]
Except for changing the water from 20.89 parts by mass to 19.32 parts by mass and further changing to 4 parts by mass of skim milk powder instead of 2.43 parts by mass of the milk flavor imparting material E, the same procedure as in Example 15 was repeated. Thus, margarine B for comparison was obtained.
When the flavors of the above-mentioned two types of margarine were compared, both had a thick milk flavor with almost the same strength, but the margarine A obtained in Example 15 felt a richer milk flavor. It was.

<乳風味付与試験4(プルマン型食パン)>
〔実施例16〕
強力粉(イーグル:日本製粉製)70質量部、生イースト2質量部、イーストフード0.1質量部及び水40質量部をミキサーボウルに投入し、フックを使用し、低速で2分、中速で2分混合し、中種生地を得た。捏ね上げ温度は24℃であった。この中種生地を生地ボックスに入れ、温度28℃、相対湿度85%の恒温室で、4時間中種発酵を行なった。終点温度は29℃であった。この中種発酵の終了した生地を再びミキサーボウルに投入し、本捏ね工程として更に、強力粉(イーグル:日本製粉製)30質量部、上白糖5質量部、乳風味付与材H22.2質量部、食塩1.5質量部及び水5質量部を添加し、低速で3分、中速で3分本捏ミキシングした。ここで、ショートニング8質量部を投入し、フックを使用し、低速で3分、中速で3分、高速で1分ミキシングを行ない、食パン生地を得た。得られた食パン生地の捏ね上げ温度は28℃であった。ここで、フロアタイムを20分とった後、230gに分割・丸目を行なった。次いで、ベンチタイムを20分とった後、 モルダー成形し、6本をU字にして3斤型プルマン型に入れ、38℃、相対湿度85%で50分ホイロをとった後、200℃に設定した固定窯に入れ40分焼成して、プルマン型食パンAを得た。
<Milk flavor imparting test 4 (Pullman type bread)>
Example 16
Powerful flour (Eagle: made in Japan) 70 parts by weight, fresh yeast 2 parts by weight, yeast food 0.1 part by weight and water 40 parts by weight are put into a mixer bowl, using a hook, low speed for 2 minutes, medium speed Mix for 2 minutes to obtain a medium seed dough. The kneading temperature was 24 ° C. This medium seed dough was put in a dough box and subjected to seed fermentation for 4 hours in a thermostatic chamber at a temperature of 28 ° C. and a relative humidity of 85%. The end point temperature was 29 ° C. The medium-type fermented dough is again put into the mixer bowl, and as a main kneading process, 30 parts by weight of strong flour (Eagle: made in Japan), 5 parts by weight of white sucrose, 22.2 parts by weight of milk flavoring material H, 1.5 parts by mass of sodium chloride and 5 parts by mass of water were added, and the mixture was mixed for 3 minutes at low speed and 3 minutes at medium speed. Here, 8 parts by weight of shortening was added, and using a hook, mixing was performed for 3 minutes at low speed, 3 minutes at medium speed, and 1 minute at high speed to obtain bread dough. The kneading temperature of the resulting bread dough was 28 ° C. Here, after taking the floor time of 20 minutes, 230 g was divided and rounded. Next, after taking a bench time of 20 minutes, mold it, mold 6 pieces into a U-shaped Pullman mold, take a proof at 38 ° C and relative humidity of 85% for 50 minutes, and then set it to 200 ° C. In a fixed kiln and baked for 40 minutes to obtain a pullman-type bread B.

〔比較例4〕
乳風味付与材H22.2質量部を脱脂粉乳2質量部に変更し、さらに、本捏ね工程の水5質量部を27質量部に変更した以外は実施例16の配合・製法にしたがって、比較用のプルマン型食パンBを得た。
上記2種のプルマン型食パンの風味の比較を行ったところ、両者はほぼ同等の強さの厚みのある乳風味であったが、実施例16で得られたプルマン型食パンAの方が豊かな乳風味が感じられた。
[Comparative Example 4]
For comparison, according to the formulation and production method of Example 16, except that 22.2 parts by mass of the milk flavor imparting material H is changed to 2 parts by mass of skim milk powder and 5 parts by mass of water in the main kneading process is changed to 27 parts by mass. Pullman type bread B was obtained.
When the flavors of the above-mentioned two kinds of pullman bread were compared, both had a milk flavor with almost the same strength, but the pullman bread A obtained in Example 16 was richer. Milk flavor was felt.

<乳風味付与試験5(加糖練乳)>
〔実施例17〕
乳風味付与材K8.5質量部、グラニュー糖44質量部、乳糖11質量部、水18質量部を70℃まで加温して混合、溶解した後、生クリーム(乳脂45%品)を18.5質量部加えて混合し、常温まで冷やし、加糖練乳風味の組成物Aを得た。(該組成物の乳脂含量8.4%、炭水化物56%、うちショ糖44%であった)
<Milk flavor imparting test 5 (sweetened condensed milk)>
Example 17
The milk flavor imparting material K8.5 parts by mass, granulated sugar 44 parts by mass, lactose 11 parts by mass and water 18 parts by mass were heated to 70 ° C., mixed and dissolved, and then fresh cream (milk fat 45% product) was added to 18. 5 parts by mass was added and mixed, and cooled to room temperature to obtain a sweetened condensed milk flavored composition A. (The milk fat content of the composition was 8.4%, carbohydrate was 56%, of which sucrose was 44%)

〔比較例5〕
実施例17の配合のうち、乳風味付与材K 8.5質量部、乳糖11質量部に替えて脱脂粉乳22質量部とし、また生クリーム(乳脂45%品)の配合量を18.3質量部としたた以外、実施例16と同様の方法で比較用の加糖練乳風味の組成物Bを得た。(該組成物の乳脂含量8.4%、炭水化物56%、うちショ糖44%であった。)
いちご30gを軽く潰し、実施例17で得られた加糖練乳風味の組成物A及び比較例5の加糖練乳風味の組成物Bをそれぞれ5gかけ、和えるように混合し、デザートを作成し、風味の比較を行ったところ、両者はほぼ同等の強さの厚みのある練乳風味であったが、実施例17で得られた加糖練乳風味の組成物Aを使用したデザートの方が豊かな練乳風味が感じられた。
[Comparative Example 5]
Among the blends of Example 17, the milk flavor imparting material K is 8.5 parts by mass, the lactose is replaced by 11 parts by mass, and the skim milk powder is 22 parts by mass, and the blending amount of the fresh cream (milk fat 45% product) is 18.3 masses. A comparative sweetened condensed milk-flavored composition B was obtained in the same manner as in Example 16 except that the composition B was used. (The milk fat content of the composition was 8.4%, carbohydrate was 56%, of which sucrose was 44%.)
30 g of strawberry is lightly crushed, and 5 g of each of the sweetened condensed milk flavor composition A obtained in Example 17 and the sweetened condensed milk flavor composition B of Comparative Example 5 are added to each other and mixed so as to soften to make a dessert. When the comparison was made, both had a thick condensed milk flavor with almost the same strength, but the dessert using the sweetened condensed milk flavor composition A obtained in Example 17 had a rich condensed milk flavor. I felt it.

<乳風味付与試験6(ファットスプレッド)>
〔実施例18〕
パーム油45質量部、レシチン0.5質量部、ショ糖脂肪酸エステル0.5質量部、香料0.1質量部を混合し油相とする。一方、水4.35質量部、水あめ(糖分70質量%、水分30質量%)35質量部、20%加糖卵黄3.5質量部、グリシンを主剤とする日持ち向上製剤1.4質量部、ポリグリセリン脂肪酸エステル0.1質量部、実施例17で得た加糖練乳風味の組成物A8.5質量部、脱脂粉乳1質量部、食塩0.05質量部を混合し水相とする。この油相と水相とを混合、乳化し、急冷可塑化してファットスプレッドAを得た。
<Milk flavor imparting test 6 (Fat spread)>
Example 18
Palm oil 45 mass parts, lecithin 0.5 mass part, sucrose fatty acid ester 0.5 mass part, and fragrance | flavor 0.1 mass part are mixed, and it is set as an oil phase. On the other hand, 4.35 parts by weight of water, 35 parts by weight of syrup (sugar content 70% by weight, water 30% by weight), 20% sweetened egg yolk 3.5 parts by weight, 1.4 parts by weight of a shelf-life improvement preparation based on glycine, poly 0.1 parts by mass of glycerin fatty acid ester, 8.5 parts by mass of the sweetened condensed milk flavor composition A obtained in Example 17, 1 part by mass of skim milk powder, and 0.05 parts by mass of sodium chloride are mixed to obtain an aqueous phase. Fat phase A was obtained by mixing and emulsifying the oil phase and aqueous phase, followed by rapid plasticization.

〔比較例6〕
実施例18記載の配合のうち、加糖練乳風味の組成物Aに替えて比較例6で得た加糖練乳風味の組成物Bとした以外、実施例18と同様の方法で比較用のファットスプレッドBを得た。
実施例18及び比較例6で得られたファットスプレッド0.5gをそれぞれ1cmの厚さにスライスしたバケット(約10g)に塗布し、風味を評価したところ、両者はほぼ同等の強さの厚みのある乳風味であったが、実施例18で得られたファットスプレッドAの方が豊かな練乳風味が感じられた。
[Comparative Example 6]
Fat spread B for comparison in the same manner as in Example 18 except that the composition B described in Example 18 was replaced with the sweetened condensed milk-flavored composition A and the sweetened condensed milk-flavored composition B was obtained in Comparative Example 6. Got.
The fat spread 0.5 g obtained in Example 18 and Comparative Example 6 was applied to a bucket (about 10 g) sliced to a thickness of 1 cm, and the flavor was evaluated. Although it had a certain milk flavor, the fat spread A obtained in Example 18 felt a rich condensed milk flavor.

<乳風味付与試験7(ホイップクリーム)>
〔実施例19〕
パーム核油2.5質量部、パーム核ステアリン2.5質量部、バターオイル30質量部を65℃に加温溶解し、油相とした。一方、乳風味付与材E 2質量部、ショ糖脂肪酸エステル0.2質量部、高粘度キサンタンガム0.04質量部、水55.76質量部を混合し、65℃に加温溶解し、水相とした。上記水相と上記油相を混合、乳化して、予備乳化物を調製し、3MPaの圧力で均質化した後、VTIS殺菌機(アルファラバル社製UHT殺菌機)で140℃、4秒間殺菌し、再度5MPaの圧力で均質化後5℃まで冷却した。その後、冷蔵庫で24時間エージングを行い、ホイップクリームAを得た。
<Milk flavor imparting test 7 (whipped cream)>
Example 19
Palm kernel oil 2.5 parts by mass, palm kernel stearin 2.5 parts by mass and butter oil 30 parts by mass were heated and dissolved at 65 ° C. to obtain an oil phase. On the other hand, 2 parts by mass of milk flavoring material E, 0.2 parts by mass of sucrose fatty acid ester, 0.04 parts by mass of high-viscosity xanthan gum, and 55.76 parts by mass of water are mixed and dissolved by heating at 65 ° C. It was. The aqueous phase and the oil phase are mixed and emulsified to prepare a preliminary emulsion, homogenized at a pressure of 3 MPa, and then sterilized at 140 ° C. for 4 seconds with a VTIS sterilizer (UHT sterilizer manufactured by Alfa Laval). The mixture was homogenized again at a pressure of 5 MPa and then cooled to 5 ° C. Thereafter, aging was performed in the refrigerator for 24 hours to obtain whipped cream A.

〔比較例7〕
実施例19記載の原料のうち、乳風味付与材E2質量部に替えて脱脂粉乳3.2質量部とした以外、実施例19と同様にして比較用のホイップクリームBを得た。
実施例19及び比較例7で得られたホイップクリームをそれぞれホイップしてホイップドクリームとし、風味を評価したところ、両者はほぼ同等の強さの厚みのある乳風味であったが、実施例19で得られたホイップクリームAから得られたホイップドクリームの方が豊かな乳風味が感じられた。
[Comparative Example 7]
Of the raw materials described in Example 19, a whipped cream B for comparison was obtained in the same manner as in Example 19 except that 3.2 parts by mass of skim milk powder was used instead of the milk flavor imparting material E2.
When the whipped creams obtained in Example 19 and Comparative Example 7 were whipped to make whipped creams and the flavor was evaluated, both were milk flavors with a thickness of almost the same strength. The whipped cream obtained from the whipped cream A obtained in step 1 felt a richer milk flavor.

<乳風味付与試験8(ケーキドーナツ)>
〔実施例20〕
薄力粉100質量部、ベーキングパウダー1質量部、乾燥全卵15質量部、粉糖15質量部、乳風味付与材E5質量部を粉体混合機によって混合し、ケーキドーナツプレミックス粉を調製した。このプレミックス粉136質量部に対し、水67質量部を添加、混合し、ケーキドーナツ生地を得た。このケーキドーナツ生地をドーナツ成型した後、160℃の油で揚げ、ケーキドーナツAを得た。
<Milk flavor imparting test 8 (cake donut)>
Example 20
A cake donut premix powder was prepared by mixing 100 parts by weight of flour, 1 part by weight of baking powder, 15 parts by weight of dried whole eggs, 15 parts by weight of powdered sugar, and 5 parts by weight of milk flavor imparting material E using a powder mixer. With respect to 136 parts by mass of this premix powder, 67 parts by mass of water was added and mixed to obtain a cake donut dough. This cake donut dough was formed into donuts and then fried in oil at 160 ° C. to obtain cake donut A.

〔比較例8〕
実施例20記載の原料のうち、乳風味付与材E5質量部に替えて脱脂粉乳8質量部とした以外、実施例20と同様にして比較用のケーキドーナツBを得た。
実施例20及び比較例8で得られたケーキドーナツの風味を評価したところ、両者はほぼ同等の強さの厚みのある乳風味であったが、実施例20で得られたケーキドーナツAの方が豊かな乳風味が感じられた。
[Comparative Example 8]
Of the raw materials described in Example 20, a cake donut B for comparison was obtained in the same manner as in Example 20 except that the milk flavor imparting material E was changed to 5 parts by mass and replaced with 8 parts by mass of skim milk powder.
When the flavors of the cake donuts obtained in Example 20 and Comparative Example 8 were evaluated, both had a thick milk flavor with almost the same strength, but the cake donut A obtained in Example 20 was the same. A rich milk flavor was felt.

<乳風味付与試験9(ミルクティー)>
〔実施例21〕
市販の紅茶葉30質量部に対し、熱水900質量部で抽出したものを紅茶抽出液とした。この紅茶抽出液70質量部に砂糖5.5質量部、乳風味付与材K0.25質量部、乳糖0.52質量部、水23.73質量部を加え、ミルクティーAを作成した。
<Milk flavor imparting test 9 (milk tea)>
Example 21
What extracted with 900 mass parts of hot water with respect to 30 mass parts of commercially available black tea leaves was made into the black tea extract. Milk tea A was prepared by adding 5.5 parts by weight of sugar, 0.25 parts by weight of a milk flavor imparting material, 0.52 parts by weight of lactose, and 23.73 parts by weight of water to 70 parts by weight of this black tea extract.

〔比較例9〕
実施例21記載の原料のうち、乳風味付与材K及び乳糖に替えて脱脂粉乳1質量部とし、また実施例21記載の水23.73質量部を23.5質量部とした以外、実施例21と同様にして比較用のミルクティーBを作成した。
実施例21及び比較例9で得られたミルクティーの風味を評価したところ、両者はほぼ同等の強さの厚みのある乳風味であったが、実施例21で得られたミルクティーAの方が豊かな乳風味が感じられた。
[Comparative Example 9]
Of the raw materials described in Example 21, the milk flavor-imparting material K and lactose were replaced with 1 part by mass of skim milk powder, and 23.73 parts by mass of water described in Example 21 was 23.5 parts by mass. A milk tea B for comparison was prepared in the same manner as in No. 21.
When the flavors of the milk teas obtained in Example 21 and Comparative Example 9 were evaluated, the milk teas obtained in Example 21 were almost the same in strength and thickness. A rich milk flavor was felt.

<乳風味付与試験10(アイスクリーム)>
〔実施例22〕
卵黄90質量部にグラニュー糖68質量部を加え、白くなるまでしっかり撹拌した後、牛乳50質量部、乳風味付与材B50質量部、水50質量部を添加してさらに撹拌した。弱火で少しとろみがつくまで加熱後、氷水で冷却したのち、バニラエッセンス0.05質量部を加えた。さらに、攪拌しながら予めホイッパーで8分立てに泡立てた純生クリーム150質量部を少しずつ添加し、市販アイスクリーマー(Panasonic製 BH-941P)を使用し、冷凍庫で攪拌し(−18℃、3時間)アイスクリームAを作成した。
<Milk flavor imparting test 10 (ice cream)>
[Example 22]
After adding 68 parts by mass of granulated sugar to 90 parts by mass of egg yolk and stirring well until white, 50 parts by mass of milk, 50 parts by mass of milk flavoring material B, and 50 parts by mass of water were added and further agitated. After heating until it thickened slightly with low heat, after cooling with ice water, 0.05 parts by weight of vanilla essence was added. Furthermore, 150 parts by mass of pure fresh cream that had been whipped with a whipper in advance for 8 minutes was added little by little while stirring, and a commercially available ice creamer (BH-941P made by Panasonic) was used and stirred in a freezer (−18 ° C., 3 hours) ) Ice cream A was prepared.

〔比較例10〕
実施例22記載の原料のうち、牛乳50質量部、乳風味付与材B50質量部、水50質量部に替えて牛乳150質量部とした以外、実施例22と同様にして比較用のアイスクリームBを作成した。
上記2種のアイスクリームの風味の比較を行ったところ、実施例22で得られたアイスクリームAは比較例10で得られたアイスクリームBに比べ、濃厚で豊かで厚みのある乳風味が感じられる良好なものであった。
[Comparative Example 10]
Ice cream B for comparison in the same manner as in Example 22 except that 50 parts by mass of milk, 50 parts by mass of milk flavor imparting material B, and 50 parts by mass of water were used instead of the ingredients described in Example 22. It was created.
When the flavors of the above two types of ice cream were compared, the ice cream A obtained in Example 22 felt a richer, richer and thicker milk flavor than the ice cream B obtained in Comparative Example 10. It was a good one.

<乳風味付与試験11(乳性炭酸飲料)>
〔実施例23〕
市販の乳性炭酸飲料(スコールホワイト:南日本酪農共同株式会社製)(糖類含量12質量%)100質量部に乳風味付与材G0.5質量部を加えて良く混合し、乳性炭酸飲料Aとした。
<Milk flavor imparting test 11 (dairy carbonated drink)>
Example 23
Milky carbonated beverage A (Scol white: manufactured by Minami Nihon Dairy Kyokai Co., Ltd.) (sugar content 12% by mass) 100 parts by mass of milk flavoring material G0.5 part by mass and mixed well. It was.

〔比較例11〕
実施例23で使用した市販の乳性炭酸飲料をそのまま比較用の乳性炭酸飲料Bとした。
上記2種の乳性炭酸飲料の風味の比較を行ったところ、実施例23で得られた乳性炭酸飲料Aは比較例11の乳性炭酸飲料Bに比べ、濃厚で、豊かで厚みのある乳風味が感じられる良好なものであった。
[Comparative Example 11]
The commercially available dairy carbonated drink used in Example 23 was used as the dairy carbonated drink B for comparison.
When the flavors of the two types of dairy carbonated drinks were compared, the dairy carbonated drink A obtained in Example 23 was thicker, richer and thicker than the dairy carbonated drink B of Comparative Example 11. The milk flavor was good.

<乳風味付与試験12(カスタードクリーム)>
〔実施例24〕
卵黄80質量部とグラニュー糖20質量部をよくすり混ぜ、さらに薄力粉15質量部を加え、実施例17で得た加糖練乳風味の組成物Aを加え、十分に混合した。粘性が出てくるまで加熱しながら混合を続け、加熱を停止した後、バニラエッセンス0.2質量部を加え、混合した後、冷却し、カスタードクリームAを作成した。
<Milk flavor imparting test 12 (custard cream)>
Example 24
80 parts by weight of egg yolk and 20 parts by weight of granulated sugar were thoroughly mixed, 15 parts by weight of flour was added, and the sweetened condensed milk flavor composition A obtained in Example 17 was added and mixed well. Mixing was continued while heating until viscosity appeared, and after heating was stopped, 0.2 part by weight of vanilla essence was added, mixed, and then cooled to prepare custard cream A.

〔比較例12〕
実施例24の配合のうち、加糖練乳風味の組成物Aに替えて比較例5で得られた加糖練乳風味の組成物Bとした以外、同様にして比較用のカスタードクリームBを作成した。
上記2種のカスタードクリームの風味の比較を行ったところ、両者はほぼ同等の強さの厚みのある乳風味であったが、実施例24で得られたカスタードクリームAの方が豊かな乳風味が感じられた。
[Comparative Example 12]
A custard cream B for comparison was prepared in the same manner as in the composition of Example 24, except that the composition B had a sweetened condensed milk flavor obtained in Comparative Example 5 instead of the sweetened condensed milk flavor composition A.
When the flavors of the above two types of custard cream were compared, both had a milk flavor with a thickness of about the same strength, but the custard cream A obtained in Example 24 had a richer milk flavor. Was felt.

<乳風味付与試験13(ミルクキャンディー)>
〔実施例25〕
グラニュー糖170質量部、水飴300質量部、水100質量部を鍋に入れて加熱し、粘度が出たところで乳風味付与材A180質量部を添加しよく混合した。ある程度冷えたところで棒状に伸ばし、適当な大きさに切り、粉糖をまぶしながら手で丸め、ミルクキャンディーAを得た。
<Milk flavor imparting test 13 (milk candy)>
Example 25
170 parts by weight of granulated sugar, 300 parts by weight of starch syrup, and 100 parts by weight of water were placed in a pan and heated. When it was cooled to some extent, it was stretched into a rod shape, cut into an appropriate size, and rounded by hand while sprinkled with powdered sugar to obtain milk candy A.

〔比較例14〕
実施例25の配合のうち、乳風味付与材A180質量部に替えて脱脂粉乳300質量部とした以外、実施例25と同様にして比較用のミルクキャンディーBを得た。
上記2種のミルクキャンディーの風味の比較を行ったところ、両者はほぼ同等の強さの厚みのある乳風味であったが、実施例25で得られたミルクキャンディーAの方が豊かな乳風味が感じられた。
[Comparative Example 14]
A milk candy B for comparison was obtained in the same manner as in Example 25 except that, in the formulation of Example 25, the milk flavor imparting material A was changed to 180 parts by mass and replaced with 300 parts by mass of skim milk powder.
When the flavors of the above-mentioned two types of milk candy were compared with each other, both had a milk flavor with a thickness of almost the same strength, but the milk candy A obtained in Example 25 was richer in milk flavor. Was felt.

<乳風味付与試験14(ホワイトソース)>
〔実施例26〕
バター55質量部を鍋に入れて弱火で溶かし、小麦粉50質量部を3回に分けて入れ、良く混合した。次いで、40℃の水380質量、乳風味付与材F30質量部を加え、良く混合した。そのまま弱火で加温を続け、とろみが出たところで、塩0.2質量部、こしょう0.3質量部、コンソメ5.5質量部を混合し、ホワイトソースAを作成した。
<Milk flavor imparting test 14 (white sauce)>
Example 26
55 parts by weight of butter was put in a pan and melted on low heat, and 50 parts by weight of flour was added in three portions and mixed well. Next, 380 masses of water at 40 ° C. and 30 mass parts of milk flavor imparting material F were added and mixed well. Heating was continued with low heat as it was, and when thickening occurred, 0.2 parts by weight of salt, 0.3 parts by weight of pepper and 5.5 parts by weight of consomme were mixed to prepare white sauce A.

〔比較例15〕
実施例26の配合のうち、乳風味付与材F30質量部に替えて脱脂粉乳50質量部とした以外、実施例26と同様にして比較用のホワイトソースBを作成した。
上記2種のホワイトソースの風味の比較を行ったところ、両者はほぼ同等の強度の厚みのある乳風味であったが、実施例26で得られたホワイトソースAの方が豊かな乳風味が感じられた。
[Comparative Example 15]
A white sauce B for comparison was prepared in the same manner as in Example 26 except that the milk flavor imparting material F30 parts by mass was replaced with 50 parts by mass of skim milk powder in the formulation of Example 26.
When the flavors of the above two types of white sauce were compared, both had a milk flavor with a thickness of almost the same strength, but the white sauce A obtained in Example 26 had a richer milk flavor. I felt it.

<乳風味付与試験15(カルーアミルク)>
〔実施例27〕
市販カルーア30質量部と牛乳40質量部、乳風味付与材J3質量部、水47質量部を混合し、カルーアミルクAを作成した。
<Milk flavor imparting test 15 (Kahlua milk)>
Example 27
Kalua milk A was prepared by mixing 30 parts by mass of commercially available kahlua, 40 parts by mass of milk, 3 parts by mass of milk flavor imparting material J, and 47 parts by mass of water.

〔比較例16〕
実施例27の配合のうち、乳風味付与材J3質量部に替えて脱脂粉乳5質量部、水45質量部とした以外、実施例27と同様にして比較用のカルーアミルクBを作成した。
上記2種のカルーアミルクの風味の比較を行ったところ、両者はほぼ同等の強さの厚みのある乳風味であったが、実施例27で得られたカルーアミルクAの方が豊かな乳風味が感じられた。
[Comparative Example 16]
In the blending of Example 27, a comparative kalua milk B was prepared in the same manner as in Example 27 except that 5 parts by mass of skim milk powder and 45 parts by mass of water were used instead of the milk flavor imparting material J3 parts by mass.
When the flavors of the above two types of kahlua milks were compared, both of them had a thick milk flavor with almost the same strength, but kahlua milk A obtained in Example 27 had a richer milk flavor. Was felt.

Claims (9)

(A)乳清ミネラル、及び、(B)乳酸発酵風味素材を、(A)乳清ミネラルの固形分1質量部に対し、(B)乳酸発酵風味素材を固形分として0.001〜5質量部含有することを特徴とする乳風味付与材。 (A) Whey mineral and (B) Lactic acid fermentation flavor material with respect to 1 mass part of solid content of (A) Whey mineral, (B) Lactic acid fermentation flavor material as solid content 0.001-5 mass Milk flavor imparting material characterized by containing a part. さらに(C)リン脂質を、(A)乳清ミネラルの固形分1質量部に対し、0.0001〜0.5質量部含有することを特徴とする請求項1記載の乳風味付与材。   Furthermore, 0.0001-0.5 mass part of (C) phospholipid is contained with respect to 1 mass part of solid content of (A) whey mineral, The milk flavor imparting material of Claim 1 characterized by the above-mentioned. 上記(C)リン脂質として、固形分中のリン脂質含量が該固形分を基準として0.5質量%以上である乳原料を使用したことを特徴とする請求項2記載の乳風味付与材。   The milk flavor-imparting material according to claim 2, wherein a milk raw material having a phospholipid content in the solid content of 0.5% by mass or more based on the solid content is used as the (C) phospholipid. さらに(D)糖類を、(A)乳清ミネラルの固形分1質量部に対し、固形分として0.5〜40質量部含有することを特徴とする請求項1〜3のいずれか一項に記載の乳風味付与材。   Furthermore, (D) saccharide | sugar is contained 0.5-40 mass parts as solid content with respect to 1 mass part of solid content of (A) whey mineral, The any one of Claims 1-3 characterized by the above-mentioned. The milk flavor imparting material described. 上記(D)糖類として、乳糖、ガラクトオリゴ糖、及び、糖アルコールのうちの1種または2種以上を使用したことを特徴とする請求項4記載の乳風味付与材。   The milk flavor imparting material according to claim 4, wherein one or more of lactose, galactooligosaccharide, and sugar alcohol is used as the saccharide (D). 油脂を実質的に含有しないことを特徴とする請求項1〜5のいずれか一項に記載の乳風味付与材。   Oil and fat are not substantially contained, The milk flavor imparting material as described in any one of Claims 1-5 characterized by the above-mentioned. 脱脂粉乳代替用であることを特徴とする請求項1〜6のいずれか一項に記載の乳風味付与材。   The milk flavor-imparting material according to any one of claims 1 to 6, wherein the milk flavor-imparting material is used for replacing skim milk powder. 請求項1〜7のいずれか一項に記載の乳風味付与材を使用した飲食品。   Food / beverage products using the milk | flavor flavor imparting material as described in any one of Claims 1-7. 請求項1〜7のいずれか一項に記載の乳風味付与材を、脱脂粉乳の代替として使用することを特徴とする乳風味付与材の使用方法。   The milk flavor imparting material according to any one of claims 1 to 7, wherein the milk flavor imparting material is used as an alternative to skim milk powder.
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