JP2016190995A - Inkjet recording ink - Google Patents

Abstract

PROBLEM TO BE SOLVED: To provide an aqueous inkjet yellow ink that gives sharp image qualities with good color developability and fewer voids on a substrate and excellent ethanol resistance, and has stable continuous discharge performance, and an aqueous inkjet ink set comprising the above aqueous inkjet yellow ink.SOLUTION: The aqueous inkjet yellow ink comprises water, a water-soluble solvent, a pigment, and a binder resin. The pigment comprises C. I. Pigment Yellow 14; the binder resin has an acid value of 100 or less and a weight average molecular weight of 30000 or less; and the ink has a surface tension of 20 to 35 mN/m.SELECTED DRAWING: None

Description

The present invention provides a water-based inkjet yellow ink that has good color developability, clear image quality with few white spots on the substrate, excellent ethanol resistance, and stable continuous ejection performance, and The present invention relates to an aqueous inkjet ink set containing an aqueous inkjet yellow ink.

The ink jet recording method is a printing method in which printing is performed by causing a droplet of an ink composition to fly and adhere to a recording medium such as paper. This method has a feature that a high-resolution and high-quality image can be printed at a high speed with a relatively inexpensive apparatus.

Also in industrial applications, use as an output machine for digital printing is expected due to improvements in inkjet technology, and water-based inks are required from the viewpoint of environment and cost.
The appearance of water-based pigment ink is strongly demanded from the aspect of light resistance.

Needless to say, the color developability and color reproducibility of the ink-jet printed material are important, and various studies have been made so far to improve the color developability and color reproducibility. For example, Patent Documents 1 and 2 propose that an image expressing good color reproducibility can be formed by using an ink set in which special color inks are combined in addition to process inks.

However, in these printing systems, an ink jet head for special colors is additionally required, resulting in an increase in apparatus size and cost. Therefore, it is preferable that the above problem can be solved by using only process colors without using special color inks.

Of the process colors, yellow is involved in the development of red, which is a mixed color with magenta, and green, which is a mixed color with cyan, and plays an important role in the development and expansion of the color reproducibility. Conventionally, in an inkjet yellow ink, C.I. I. Pigment
Yellow 74, 120 and 150 were used as yellow pigments. On the other hand, in Patent Document 4, C.I. I. There are reports on inkjet yellow inks using Pigment Yellow 180, 185 and the like.

However, each of the pigments has a problem that it is inferior in color developability. Therefore, when these pigments are used, it is necessary to increase the pigment concentration in the ink, but at the same time, the amount of solid components in the ink is increased, so that the viscosity of the ink also increases. On the other hand, in order to develop the characteristics of inkjet ink, that is, to maintain and improve ink ejection performance and printing characteristics, it is necessary to keep the viscosity of the ink within a suitable range. The amount of ingredients that affect the characteristics of the must be reduced.

As described above, a water-based inkjet yellow ink capable of obtaining a printed matter excellent in color developability with only a process color while having properties necessary for an inkjet ink such as ejection performance has not yet been found.

International Publication No. 1999/005230 Pamphlet JP 2009-173853 A JP 2006-283017 A Japanese Patent Laid-Open No. 11-172180

The object of the present invention is to provide a good color developability and a clear image quality with few white spots on the substrate, and
An object of the present invention is to provide a water-based inkjet yellow ink having excellent ethanol resistance and a stable continuous ejection performance, and a water-based inkjet ink set containing the water-based inkjet yellow ink.

That is, the present invention is an aqueous inkjet yellow ink containing water, a water-soluble solvent, a pigment, and a binder resin,
The pigment is C.I. I. Pigment Yellow14,
The binder resin has an acid value of 100 or less and a weight average molecular weight of 30000 or less,
The present invention relates to a water-based inkjet yellow ink characterized in that the surface tension of the ink is 20 to 35 mN / m.

In the present invention, the pigment is 2 to 5% by weight based on the whole ink,
The present invention relates to the water-based inkjet yellow ink, wherein the binder resin is 1 to 10% by weight based on the whole ink.

In the present invention, the water-soluble solvent is an alkanediol having 3 to 6 carbon atoms and 6 to 8 carbon atoms.
The water-based inkjet yellow ink according to claim 1, comprising at least one of the following diethylene glycol monoalkyl ethers.

The present invention also relates to a water-based inkjet ink set comprising the water-based inkjet yellow ink, the water-based inkjet magenta ink, and the water-based inkjet cyan ink.

In the present invention, the water-based inkjet magenta ink contains water, a water-soluble solvent, a pigment, and a binder resin.
The pigment is C.I. I. Pigment Red 122, 147, 150, 269, and C.I. I. Including at least one selected from Pigment Violet 19,
Water-based inkjet cyan ink contains water, water-soluble solvent, pigment, binder resin,
The pigment is C.I. I. Pigment Blue 15: 3, and C.I. I. Pigment
It is related with the said water-based inkjet ink set characterized by including at least 1 sort (s) chosen from Blue15: 4.

Further, according to the present invention, the pigment contained in the aqueous inkjet magenta ink is 3 to 6% by weight based on the entire aqueous inkjet magenta ink, and the pigment contained in the aqueous inkjet cyan ink is 2% based on the entire aqueous inkjet cyan ink. The water-based inkjet ink set is characterized by being 5 to 6% by weight.

The present invention also relates to a recording method for performing printing by an ink jet method using the aqueous ink jet ink set.

  Moreover, this invention relates to the printed matter printed on the base material by the said recording method.

By using the water-based inkjet yellow ink of the present invention, good color developability, clear image quality with few white spots on the substrate, excellent ethanol resistance, and stable continuous ejection performance are obtained. A water-based inkjet yellow ink and a water-based inkjet ink set containing the water-based inkjet yellow ink could be provided.

  Hereinafter, the present invention will be described with reference to preferred embodiments.

The present invention has been intensively studied to provide a water-based ink that has good color developability, clear image quality with few white spots on the substrate, and excellent ethanol resistance, and has stable continuous ejection performance. As a result, C.I. I. Pigment Yellow 14 pigment, and
The present invention was found by finding that the above problems can be solved by including a binder resin having an acid value of 100 or less and a weight average molecular weight of 30000 or less and setting the surface tension of the ink to 20 to 35 mN / m. It is a thing.

The reason why excellent ethanol resistance and continuous discharge properties can be obtained by including the above-mentioned acid value and molecular weight binder resin is not clear, but if the acid value is large, the binder resin easily dissolves in ethanol, so ethanol resistance is obtained. In addition, when the weight average molecular weight is large, it is considered that the pigment dispersion is easily broken and the continuous discharge property is deteriorated.

The reason why the above-described surface tension is set to obtain a clear image quality with continuous dischargeability and less white spots on the substrate is not clear, but the following may be considered. If the surface tension of the ink-jet ink is not 20 mN / m or more, the ejection property is deteriorated, and the continuous ejection property is remarkably deteriorated. On the other hand, when it exceeds 35 mN / m, it becomes difficult for the dots to spread on the base material, and the print quality deteriorates. Therefore, it is considered that the surface tension needs to be 20 mN / m or more and 35 mN / m or less.

  The main components of the present invention are described below.

(C.I. Pigment Yellow 14)
In the present invention, C.I. I. The blending amount of Pigment Yellow 14 is determined based on color development, ejection / printing characteristics, and the like. As described above, the C.I.
I. Pigment Yellow 14 has better color developability than conventionally used pigments, and can reduce the blending amount accordingly. C. in the ink of the present invention. I. Pigmen
The preferred blending amount of t Yellow 14 is 2 to 5% by weight with respect to the total amount of ink. If it is less than 2% by weight, the printing density is slightly inferior, and if it exceeds 5% by weight, the continuous ejection property is deteriorated.

When the yellow ink of the present invention is used as an ink set, the ink set is
In addition to the yellow ink described above, at least magenta ink and cyan ink can be included, and further black ink can be included.
Further, a light color ink for reducing image graininess such as light cyan ink, light magenta ink, gray ink, and light gray ink can also be included.

On the other hand, C.I. I. By including a pigment having poor solvent resistance such as Pigment Yellow 74 and a solvent having high hydrophobicity, continuous discharge properties are deteriorated. The reason is not clear, but it is believed that a pigment having poor solvent resistance in a hydrophobic solvent repeatedly dissolves and precipitates, resulting in dispersion destruction of the pigment. Moreover, even if a hydrophobic solvent is not used, the ink coating film has an adverse effect that the coating film is peeled off by wiping with ethanol.

(Other pigments)
In the present invention, in order to improve color reproducibility in a printed matter, particularly in the red region, it is particularly preferable to select a suitable component as a constituent component of magenta ink. Examples of magenta pigments that can be used in the present invention include C.I. I. Pigment Red5, 7, 12,
22, 23, 31, 48 (Ca), 48 (Mn), 49, 52, 53, 57 (Ca), 5
7: 1, 112, 122; quinacridone solid solution, 146, 147, 150, 238, 26
9, C.I. I. Pigment Violet 19 etc. are mentioned. In the present invention, when used together with the yellow ink as an ink set, C.I. I. Pigment Red 147, 150, 269 are preferred. I. Pig
ment Red 150 is particularly preferably used. Examples of pigments that are excellent in color reproducibility in the blue region while maintaining color reproducibility in the red region by using with the yellow ink include C.I. I. Pigment Red122, C.I. I. Pigment Violet 19
Are preferred, and C.I. I. Pigment Red 122 is particularly preferably used.

The blending amount of the magenta pigment with respect to the total amount in the ink is preferably 3 to 6% by weight from the viewpoint of coloring power, ejection / printing characteristics, and the like. When the blending amount is 3% by weight or more, color development and color reproducibility during printing are easily exhibited sufficiently. When it is 6% by weight or less, the continuous discharge property is good.

Examples of cyan pigments that can be used in the present invention include C.I. I. Pigmen
t Blue 15: 3, 15: 4, 16, 22, C.I. I. Vat Blue 4, 6 etc. are mentioned. Among these pigments, C.I. I. Pigment Blue 15: 3, 15:
4 is preferably included.

The blending amount of the cyan pigment with respect to the total amount in the ink is preferably 2.5 to 6% by weight in terms of coloring power, ejection / printing characteristics, and the like. When the blending amount is 2.5% by weight or more, the color developability and color reproducibility during printing are sufficiently exhibited. When it is 6% by weight or less, the continuous discharge property is good.

Examples of the black pigment that can be used in the present invention include carbon black produced by a furnace method or a channel method. For example, these carbon blacks have a primary particle diameter of 11 to 40 mμm (nm) and a specific surface area by the BET method of 50 to 400 m ^2.
/ G, having a volatile content of 0.5 to 10% by weight, a pH value of 2 to 10, and the like are preferable. The following are mentioned as a commercial item which has such a characteristic. For example, no.
33, 40, 45, 52, 900, 2200B, 2300, MA7, MA8, MCF88
(Mitsubishi Chemical), RAVEN 1255 (Colombia), REGAL330R, 4
00R, 660R, MOGUL L (above, manufactured by Cabot), Nipex 160IQ, N
ipex 170IQ, Nipex 75, Printex 85, Printex 95,
There are Printex 90, Printex 35, Printex U (manufactured by Degussa) and the like, and any of them can be preferably used.

(Binder resin)
As the binder resin, a resin having a hydrophobic component and a hydrophilic component in a certain balance is designed and used. In this case, the hydrophilic component is ionic, and more preferably anionic. In particular, those that are rendered water-soluble by neutralizing anionic substances with a volatile base component are preferred. The binder resin of the present invention is a resin having a carboxyl group or a sulfonic acid group as an acidic group and having an acid value of 100 or less. An acid value of 50 or less can be particularly preferably used. When the acid value exceeds 100, since the binder resin is easily dissolved in ethanol, sufficient ethanol resistance cannot be obtained. In addition, the dispersion of the pigment is easily destroyed, and the continuous discharge property is also deteriorated.

The acid value is the number of milligrams of potassium hydroxide required to neutralize acidic components contained in 1 g of resin.

Examples of such resins include acrylic resins, styrene-acrylic resins, acrylonitrile-acrylic resins, vinyl acetate-acrylic resins, polyurethane resins, and polyester resins.

Hydrophobic monomers that serve as the hydrophobic component of the binder resin include acrylic acid esters (n-butyl acrylate, 2-ethylhexyl acrylate, 2-hydroxyethyl acrylate, etc.), methacrylic acid esters (ethyl methacrylate, butyl methacrylate). , Glycidyl methacrylate, etc.), styrene and the like.

Examples of the hydrophilic monomer serving as the hydrophilic component of the binder resin include acrylic acid, methacrylic acid, acrylamide, and the like, and those having an acidic group such as acrylic acid are preferably neutralized with a base after polymerization. Can do.

The molecular weight of the binder resin is preferably 30000 or less in terms of weight average molecular weight. When the weight average molecular weight exceeds 30000, the continuous ejection property is deteriorated.

The weight average molecular weight of the resin in the present invention can be measured by a conventional method. The measurement method of the weight average molecular weight of the resin in the present invention is as follows, and the weight average molecular weight is TSK.
GPC (manufactured by Tosoh Corporation, HLC) equipped with an RI detector using a gel column (Tosoh Corporation)
The weight average molecular weight in terms of polystyrene measured using THF as a developing solvent at −8120 GPC).

The acidic group derived from the acidic monomer of the binder resin is preferably neutralized partially or completely with a base component. As the neutralizing base in this case, an alkali metal-containing base such as sodium hydroxide or potassium hydroxide, or an amine (ammonia, alkanolamine, alkylamine, etc. can be used) can be used. In particular, neutralization with amines having a boiling point of less than 200 ° C. is particularly preferable from the viewpoint of improving image durability.

In order to obtain the object of the present invention, the addition amount of the binder resin is 0.1 to 15% by weight.
It is preferably used in an amount of 1 to 10% by weight.

If it is less than 0.1% by weight, sufficient resistance cannot be obtained. Further, the optimum continuous discharge property is 10% by weight or less, and the addition of more than 15% by weight deteriorates the continuous discharge property.

(Water-soluble solvent)
The organic solvent used in the present invention is preferably one having an affinity for water. In particular, alkanediol solvents and glycol ether solvents are preferred.

These compounds include 1,2-hexanediol, 1,2-pentanediol,
, 2-butanediol, 1,3-butanediol, 3-methyl-1,3-butanediol, 3-methoxy-1-butanol, 3-methoxy-3-methylbutanol, 2-methyl-
1,3-propanediol, 2,2-dimethyl-1,3-propanediol, 1,2-propanediol, 1,3-propanediol, ethylene glycol, glycerin, ethylene glycol-2-ethylhexyl ether, diethylene glycol monobutyl ether , Diethylene glycol monohexyl ether, dipropylene glycol monopropyl ether, dipropylene glycol monobutyl ether, tripropylene glycol monomethyl ether, diethylene glycol methyl butyl ether, triethylene glycol methyl butyl ether, tripropylene glycol dimethyl ether, ethylene glycol monoethyl ether, ethylene glycol monobutyl ether , Diethylene glycol monomethyl ether, polyethylene Glycol monoethyl ether, diethylene glycol monopropyl ether, diethylene glycol monopentyl ether, triethylene glycol monomethyl ether, triethylene glycol monoethyl ether, triethylene glycol monopropyl ether, tetraethylene glycol monomethyl ether, dipropylene glycol monomethyl ether, diethylene glycol dimethyl ether, Triethylene glycol dimethyl ether, tetraethylene glycol dimethyl ether, diethylene glycol diethyl ether, triethylene glycol diethyl ether, tetraethylene glycol diethyl ether, diethylene glycol methyl ethyl ether, triethylene glycol methyl ethyl ether, tetraethyl Glycol methyl ethyl ether, tetraethylene glycol butyl ether, propylene glycol dimethyl ether. Among them, alkanediol having 3 to 6 carbon atoms and diethylene glycol monoalkyl ether having 6 to 8 carbon atoms are preferable, and more preferably diethylene glycol monoethyl ether, diethylene glycol monobutyl ether, 1,2-butanediol, and 1,2-hexanediol. is there. These water-soluble solvents are preferably used because they have a small dispersion failure of the pigment and are excellent in wettability on paper.

The content of the water-soluble solvent in the ink is generally in the range of 2 to 60% by weight, more preferably in the range of 2 to 50% by weight based on the total mass of the ink.

(Surfactant)
In the ink for ink jet recording of the present invention, a surfactant can be used for the purpose of adjusting the surface tension and ensuring the wettability on the low absorption substrate. As surfactant, acetylene type,
Various materials are known for various applications such as silicon, acrylic and fluorine. From the viewpoint of securing a surface tension of ink of 20 mN / m or more and obtaining excellent continuous ejection during high-speed printing. It is particularly preferable to use an acrylic or silicon surfactant. When a fluorosurfactant is used, the surface tension calculated by the measurement method described above tends to decrease, and the continuous ejection stability may be impaired when printing at high speed. On the other hand, if the surface tension exceeds 35 mN / m, the wettability to the substrate is poor, white streaks are generated, and clear image quality cannot be obtained. The surfactant content is 0.05 to 5% by weight based on the total weight of the ink.
Is preferred. If it exceeds 5% by weight, the surface tension of the ink is lowered, and the continuous ejection stability when printing at high speed is deteriorated.

(Dispersant)
When these pigments are used, it is preferable to use them dispersed in an ink medium in order to maintain long-term storage stability of the ink. As a method for dispersing the pigment, there are a method in which the pigment is surface-modified by oxidation treatment or the like and the pigment is dispersed without a dispersant, and a method in which the pigment is dispersed using a surfactant or resin as a dispersant. In order to obtain a more stable ink, it is preferable to disperse the pigment using a dispersion resin.

Examples of the pigment dispersion resin include an acrylic resin, a styrene acrylic resin, a maleic acid resin, a styrene maleic resin, an α-olefin maleic resin, a urethane resin, and an ester resin. From the viewpoint of stabilizing the pigment dispersion, it is preferable to use an acrylic resin or a styrene acrylic resin.

The weight average molecular weight of the pigment-dispersed resin is preferably 5,000 to 100,000. When the weight average molecular weight is 5000 or less, the dispersion stability may decrease, and the weight average molecular weight 1000
If it is 00 or more, the ejection may be affected. More preferably, the weight average molecular weight is 10,000 to
It is 50000, More preferably, it is a weight average molecular weight 15000-30000.

The ratio of the pigment to the pigment dispersion resin is preferably 1/1 to 100/1. When the ratio of the pigment dispersion resin is larger than 1/1, the viscosity of the ink tends to increase. Also, 100 /
If it is less than 1, the dispersibility is lowered, and the stability may be lowered. The ratio of the pigment to the pigment dispersion resin is more preferably 2/1 to 50/1, and further preferably 2/1 to 20/1.

(water)
The water is not general water containing various ions, but ion-exchanged water (deionized water)
Is preferably used. The content of water in the ink is generally in the range of 10 to 90% by weight, more preferably in the range of 30 to 80% by weight, based on the total mass of the ink.

(Other ingredients)
In addition to the above-described components, the ink of the present invention can be appropriately added with additives such as an antifoaming agent and an antiseptic agent in order to obtain an ink having desired physical properties as required. As an example of the addition amount of these additives, 0.01 to 10% by weight is preferable with respect to the total weight of the ink.

(Ink preparation method)
Examples of the method for preparing the ink of the present invention comprising the components described above include the following methods, but the present invention is not limited to these. First, a pigment is added to an aqueous medium in which at least a pigment dispersant and water are mixed, and after mixing and stirring, dispersion processing is performed using a dispersion means described later, and centrifugation is performed as necessary. To obtain a desired pigment dispersion. Next, if necessary, a water-soluble organic solvent or an appropriately selected additive component as listed above is added to this pigment dispersion, and the mixture is stirred and filtered as necessary to obtain the ink of the present invention. And

Since the ink of the present invention is for inkjet recording, it is preferable to use a pigment having an optimum particle size distribution. That is, in order to enable the ink containing pigment particles to be suitably used in the ink jet recording method, from the demands such as nozzle clogging resistance,
It is preferable to use a pigment having an optimum particle size distribution. Examples of a method for obtaining a pigment having a desired particle size distribution include the following methods. Reduce the size of the grinding media of the disperser as mentioned above, increase the filling rate of the grinding media, increase the processing time, classify with a filter or centrifuge after grinding, etc. There are methods such as a combination of these methods.

(Recording method)
As a method for printing the ink for inkjet recording of the present invention, it is preferable to print while heating the printing substrate, or to heat the surface of the printed material after printing. The surface temperature of the base material when heating is preferably 40 to 90 ° C, more preferably 50 to 70 ° C.

Hereinafter, the present invention will be described more specifically with reference to examples and comparative examples. In the following description, “parts” and “%” are “parts by weight” and “% by weight” unless otherwise specified.
Represents.

(Production example of pigment dispersion resin)
Into a reaction vessel equipped with a gas introduction tube, a thermometer, a condenser, and a stirrer, butanol 93.4
Parts were charged and replaced with nitrogen gas. The inside of the reaction vessel was heated to 110 ° C., and a mixture of 30 parts of lauryl methacrylate as a polymerization monomer, 40 parts of styrene, 30 parts of acrylic acid and 6 parts of V-601 (manufactured by Wako Pure Chemical Industries) as a polymerization initiator for 2 hours. Over the course of the polymerization reaction. After completion of dropping, the reaction was further carried out at 110 ° C. for 3 hours, and then V-601 (manufactured by Wako Pure Chemical Industries) 0.6
Then, the reaction was further continued at 110 ° C. for 1 hour to obtain a dispersion resin A solution. further,
After cooling to room temperature, 37.1 parts of dimethylaminoethanol was added for neutralization, and 100 parts of water was added to make it aqueous. Then, it heated to 100 degreeC or more, butanol was azeotroped with water, butanol was distilled off, and it adjusted so that solid content might be 50%. As a result, an aqueous solution having a solid content of 50% of the pigment dispersion resin 1 was obtained.

(Manufacture of pigment dispersion)
20 parts of pigment, 42.9 parts of an aqueous pigment dispersion resin solution and 37.1 parts of water were charged into a mayonnaise bottle, predispersed with a disper, and filled with 1800 g of zirconia beads having a diameter of 0.5 mm as a dispersion medium This dispersion was performed for 2 hours using a 6 L dyno mill to obtain a dispersion.

(Binder resin production example)
Monomer used, 40 parts lauryl methacrylate, 45 parts styrene, 1 acrylic acid
Except for 5 parts, synthesis and neutralization were carried out in the same manner as in the pigment-dispersed resin 1 to obtain a binder resin.
The acid value and molecular weight of each binder resin were adjusted with the amount of acrylic acid and V-601.

(Production example of printed matter)
Filled with ink obtained in an ink jet printer equipped with an ink jet head having a piezo element in an environment of 25 ° C., coated paper (OK Top Coat N, manufactured by Oji Paper Co., Ltd.)
Color chart image (ProfileMake made by X-rite) on a basis weight of 104.7 g / m ² )
r chart image “TC3.5 CMYK i1_iO”) was printed, and a printed matter for evaluation was created.

(Examples 1-17, Comparative Examples 1-9)
Dispersions were prepared as described above (production of pigment dispersions) with the pigments listed in Tables 1 and 2,
After mixing the raw materials as described in 1. with stirring with a disper until they are sufficiently uniform, they are filtered through 1 μm and 0.45 μm membrane filters to remove coarse particles that cause head clogging. An ink was prepared. Then, it printed as above-mentioned (manufacturing example of printed matter), and obtained printed matter.

(Examples 18 to 26, Comparative Examples 10 to 12)
A yellow pigment, a magenta pigment, and a cyan pigment described in Table 3 were prepared as described above (production of pigment dispersion), and the raw materials described in Table 2 were mixed while stirring with a disper. After stirring until sufficiently uniform, the mixture was filtered through 1 μm and 0.45 μm membrane filters to remove coarse particles causing the clogging of the head to prepare an ink. Then, it printed as above-mentioned (manufacturing example of printed matter), and obtained printed matter.

It shows below about the evaluation method of the ink obtained in the said Examples 1-26 and Comparative Examples 1-12.

(Evaluation 1: Density of printed matter)
A solid print portion of each color having a printing rate of 100% of the obtained printed matter for evaluation was measured with a densitometer (X-rite).
The density (optical density) was measured and evaluated using X-rite 938). The evaluation criteria are as follows, and 、 and ○ evaluations are practical areas.
A: Higher than the printing density of Comparative Example 7 (1.1 or higher)
○: equivalent to the printing density of Comparative Example 7 (1.0)
X: Lower than the printing density of Comparative Example 7 (less than 1.0)

(Evaluation 2: Solid filling)
Color unevenness and white stripes were visually evaluated in an image portion of the printed matter for evaluation obtained on the coated paper having a printing rate of 100%. The evaluation criteria are as follows, and ◎, ○, and Δ evaluations are practical areas.
A: No color unevenness, no white stripes B: No white stripes, but some color unevenness.
Δ: There are some color unevenness and white stripes.
X: There are many streaks.

(Evaluation 3: Continuous dischargeability)
An ink jet printer equipped with an ink jet head having a piezo element in an environment of 25 ° C. was filled with the ink obtained in Examples 1 to 17 and Comparative Examples 1 to 9, and coated paper (Oji Paper Co., Ltd. OK Top Coat) N, a basis weight of 104.7 g / m ² ) was continuously printed with a solid printing rate of 100%, and then a nozzle check pattern was printed to confirm the presence or absence of missing nozzles. The evaluation criteria are as follows, and ◎, ○, and Δ evaluations are practical areas.
◎: No nozzle omission even after printing for 1 hour or more ○: No nozzle omission even if printing for 10 minutes or more and less than 1 hour △: No nozzle omission even if printing for 1 minute or more and less than 10 minutes × Less than 1 minute Nozzle missing

(Evaluation 4: Ethanol resistance)
The solid printed part of each color having a printing rate of 100% of the obtained printed matter for evaluation was subjected to 5 reciprocal rubbing evaluations with a cotton swab moistened with ethanol. The evaluation criteria are as follows, and ◎, ○, and Δ evaluations are practical areas.
A: The coating film is not peeled off at all. ○: The coating film is peeled off slightly. Δ: The coating film is peeled off by about 1/3.

(Color reproducibility of printed matter)
The color chart part of the printed matter for evaluation obtained in Examples 18 to 26 and Comparative Examples 10 to 12,
Color measurement was performed using a spectrophotometer (i1 Pro manufactured by X-rite), and a color reproduction region in the L * a * b * color space was plotted and evaluated. However, the measurement conditions were a light source D50, a 2-degree field of view, and measurement optics of 45 ° / 0 °. Specified by Japan Color for Printing 2007
The evaluation was performed in comparison with the color reproduction region in the L * a * b * color space. The evaluation criteria are as follows, and 、 and ○ evaluations are practical areas.
A: Greatly exceeds the red reproduction region or blue reproduction region of Japan Color 2007.
○: Slightly exceeds the red color reproduction region or blue color reproduction region of Japan Color 2007.
×: Equivalent to the red reproduction region and the blue reproduction region of Japan Color 2007.

(Density of printed matter)
Using a spectrophotometer (i1 Pro manufactured by X-rite), the density (optical density) of the solid print portion of each color with a printing rate of 100% of the printed matter for evaluation obtained in Examples 18 to 26 and Comparative Examples 10 to 12 was used. ) Was measured and evaluated. The evaluation criteria are as follows, and 、 and ○ evaluations are practical areas.
A: Higher than the density of Japan Color 2007 (C / M / Y = 1.50 / 1.47 / 1.04).
○: Equivalent to the density of Japan Color 2007 (C / M / Y = 1.50 / 1.47 / 1.04).
X: Lower than the density of Japan Color 2007 (C / M / Y = 1.50 / 1.47 / 1.04).

  The results are shown in Tables 1-3.

Unlike the inks of Comparative Examples 1 to 9, the inks having the compositions of Examples 1 to 17 have good color developability and clear image quality with little white spots on the substrate, and excellent ethanol resistance.
Furthermore, it has been shown that stable continuous discharge performance can be obtained.
On the other hand, the ink sets having the compositions of Examples 18 to 26 are shown to obtain excellent color reproducibility and printing density, unlike the inks of Comparative Examples 10 to 12.

Claims (8)

A water-based inkjet yellow ink containing water, a water-soluble solvent, a pigment, and a binder resin,
The pigment is C.I. I. Pigment Yellow14,
The binder resin has an acid value of 100 or less and a weight average molecular weight of 30000 or less,
A water-based inkjet yellow ink, wherein the surface tension of the ink is 20 to 35 mN / m. The pigment is 2 to 5% by weight with respect to the total ink,
The binder resin is 1 to 10% by weight based on the whole ink.
The water-based inkjet yellow ink as described. The water-based inkjet yellow ink according to claim 1 or 2, wherein the water-soluble solvent contains at least one of an alkanediol having 3 to 6 carbon atoms and a diethylene glycol monoalkyl ether having 6 to 8 carbon atoms. An aqueous inkjet ink set comprising the aqueous inkjet yellow ink according to claim 1, an aqueous inkjet magenta ink, and an aqueous inkjet cyan ink. Water-based inkjet magenta ink contains water, water-soluble solvent, pigment, binder resin,
The pigment is C.I. I. Pigment Red 122, 147, 150, 269, and C.I. I. Including at least one selected from Pigment Violet 19,
Water-based inkjet cyan ink contains water, water-soluble solvent, pigment, binder resin,
The pigment is C.I. I. Pigment Blue 15: 3, and C.I. I. Pigment
The water-based inkjet ink set according to claim 4, comprising at least one selected from Blue 15: 4. The pigment contained in the aqueous inkjet magenta ink is 3 to 6% by weight with respect to the entire aqueous inkjet magenta ink, and the pigment contained in the aqueous inkjet cyan ink is 2.5 to 6% with respect to the entire aqueous inkjet cyan ink. The water-based inkjet ink set according to claim 5, wherein the water-based inkjet ink set is%.   The recording method which prints by an inkjet system using the water-based inkjet ink set in any one of Claims 4-6.   A printed matter printed on a substrate by the recording method according to claim 7.