JP2016183081A5 - - Google Patents

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JP2016183081A5
JP2016183081A5 JP2015064930A JP2015064930A JP2016183081A5 JP 2016183081 A5 JP2016183081 A5 JP 2016183081A5 JP 2015064930 A JP2015064930 A JP 2015064930A JP 2015064930 A JP2015064930 A JP 2015064930A JP 2016183081 A5 JP2016183081 A5 JP 2016183081A5
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phase
silicon carbide
sintered body
conductive
high resistance
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JP2015064930A
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JP2016183081A (en
JP6291446B2 (en
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ドーパントとして窒素を含む炭化珪素の相である導電性相を含む焼結体において、少なくとも前記導電性相の外側に、前記導電性相における窒素の平均濃度より窒素の濃度が低い炭化珪素の相である高抵抗相を形成することにより、酸化に伴う比抵抗値の変化が前記高抵抗相のない焼結体に比べて小さい焼結体を製造すると共に、
焼結体におけるβ型炭化珪素の割合により、比抵抗値の温度依存性を異ならせた焼結体を製造する
ことを特徴とする導電性炭化珪素質焼結体の製造方法。
In a sintered body including a conductive phase that is a phase of silicon carbide containing nitrogen as a dopant, at least outside the conductive phase, a silicon carbide phase having a nitrogen concentration lower than the average concentration of nitrogen in the conductive phase. By forming a certain high resistance phase, while producing a sintered body in which the change in specific resistance value due to oxidation is smaller than that of the sintered body without the high resistance phase,
A method for producing a conductive silicon carbide-based sintered body, comprising producing a sintered body having a temperature dependence of specific resistance value varied depending on a ratio of β-type silicon carbide in the sintered body.
前記導電性相の外側の前記高抵抗相は、前記導電性相を含む焼結体を、実質的に窒素ガスを含まない非酸化性雰囲気で加熱する高抵抗相形成工程により形成する
ことを特徴とする請求項1に記載の導電性炭化珪素質焼結体の製造方法。
The high resistance phase outside the conductive phase is formed by a high resistance phase forming step of heating a sintered body containing the conductive phase in a non-oxidizing atmosphere substantially free of nitrogen gas. The method for producing a conductive silicon carbide sintered body according to claim 1.
前記導電性相を含む焼結体は、珪素源及び炭素源から炭化珪素を反応生成させる反応焼成工程を経て得るものであり、
焼結体におけるβ型炭化珪素の割合は、前記反応焼成工程の焼成温度によって変化させる
ことを特徴とする請求項1または請求項2に記載の導電性炭化珪素質焼結体の製造方法。
The sintered body containing the conductive phase is obtained through a reaction firing step in which silicon carbide is reacted and generated from a silicon source and a carbon source,
The method for producing a conductive silicon carbide based sintered body according to claim 1 or 2, wherein a ratio of β-type silicon carbide in the sintered body is changed depending on a firing temperature in the reaction firing step.
前記高抵抗相形成工程では、β型炭化珪素の一部をα型炭化珪素に転移させて前記高抵抗相を形成する
ことを特徴とする請求項2に記載の導電性炭化珪素質焼結体の製造方法。
3. The conductive silicon carbide based sintered body according to claim 2, wherein in the high resistance phase forming step, part of β-type silicon carbide is transferred to α-type silicon carbide to form the high resistance phase. 4. Manufacturing method.
ドーパントとして窒素を含む炭化珪素の相である導電性相を含む焼結体であり、
少なくとも前記導電性相の外側に、前記導電性相における窒素の平均濃度より窒素の濃度が低い炭化珪素の相である高抵抗相が形成されており、
炭化珪素におけるβ型炭化珪素の割合は、前記高抵抗相より前記導電性相の方が大きい
ことを特徴とする導電性炭化珪素質焼結体。
It is a sintered body containing a conductive phase that is a phase of silicon carbide containing nitrogen as a dopant,
A high resistance phase, which is a silicon carbide phase having a nitrogen concentration lower than the average concentration of nitrogen in the conductive phase, is formed at least outside the conductive phase,
The conductive silicon carbide based sintered body characterized in that the ratio of β-type silicon carbide in silicon carbide is larger in the conductive phase than in the high resistance phase.
JP2015064930A 2015-03-26 2015-03-26 Method for producing conductive silicon carbide sintered body Active JP6291446B2 (en)

Priority Applications (1)

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JP2015064930A JP6291446B2 (en) 2015-03-26 2015-03-26 Method for producing conductive silicon carbide sintered body

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Application Number Priority Date Filing Date Title
JP2015064930A JP6291446B2 (en) 2015-03-26 2015-03-26 Method for producing conductive silicon carbide sintered body

Publications (3)

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JP2016183081A JP2016183081A (en) 2016-10-20
JP2016183081A5 true JP2016183081A5 (en) 2017-02-09
JP6291446B2 JP6291446B2 (en) 2018-03-14

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JP2015064930A Active JP6291446B2 (en) 2015-03-26 2015-03-26 Method for producing conductive silicon carbide sintered body

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Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP6778644B2 (en) * 2017-03-29 2020-11-04 東京窯業株式会社 Manufacturing method of conductive silicon carbide sintered body and conductive silicon carbide sintered body
JP7213607B2 (en) * 2018-03-28 2023-01-27 東京窯業株式会社 Manufacturing method of conductive silicon carbide sintered body and conductive silicon carbide sintered body

Family Cites Families (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP3476153B2 (en) * 1993-08-12 2003-12-10 東海高熱工業株式会社 Conductive silicon carbide ceramic material
JPH0789764A (en) * 1993-09-21 1995-04-04 Tokai Konetsu Kogyo Co Ltd Silicon carbide heating element
JPH0812462A (en) * 1994-06-22 1996-01-16 Denki Kagaku Kogyo Kk Electroconductive ceramic, its production and use
JPH0826827A (en) * 1994-07-15 1996-01-30 Denki Kagaku Kogyo Kk Electrically conductive reactional silicon carbide sintered compact, its production and use
JP3681780B2 (en) * 1995-02-08 2005-08-10 東京窯業株式会社 Porous conductive silicon carbide sintered body, its production method and use
JP3691536B2 (en) * 1995-02-08 2005-09-07 東京窯業株式会社 Method for producing porous conductive silicon carbide sintered body
KR100620493B1 (en) * 1998-08-07 2006-09-05 가부시키가이샤 브리지스톤 Silicon carbide sinter and process for producing the same

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