JP2016175397A - Resin joined body, method for producing resin joined body, and structure for vehicle - Google Patents

Resin joined body, method for producing resin joined body, and structure for vehicle Download PDF

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JP2016175397A
JP2016175397A JP2015149530A JP2015149530A JP2016175397A JP 2016175397 A JP2016175397 A JP 2016175397A JP 2015149530 A JP2015149530 A JP 2015149530A JP 2015149530 A JP2015149530 A JP 2015149530A JP 2016175397 A JP2016175397 A JP 2016175397A
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molded body
thermoplastic resin
resin molded
thermosetting resin
thermosetting
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JP6341156B2 (en
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吉宏 岩野
Yoshihiro Iwano
吉宏 岩野
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Toyota Motor Corp
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Toyota Motor Corp
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Priority to KR1020160027031A priority Critical patent/KR20160112950A/en
Priority to US15/065,461 priority patent/US10105898B2/en
Priority to EP16160273.5A priority patent/EP3069851A1/en
Priority to CN201610153599.1A priority patent/CN105984119B/en
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  • Lining Or Joining Of Plastics Or The Like (AREA)
  • Moulding By Coating Moulds (AREA)
  • Mechanical Engineering (AREA)
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Abstract

PROBLEM TO BE SOLVED: To provide a resin joined body formed by joining a thermoplastic resin molding and a thermosetting resin molding.SOLUTION: A resin joined body 10 is joined by fusing a thermoplastic resin molding 20, and a thermoplastic resin part 30 of a thermosetting resin molding 40, with the thermoplastic resin part 30 provided so as to be exposed on a part of the surface of the thermosetting resin molding 40. The thermoplastic resin part 30 has an anchor part embedded in the thermosetting resin molding 40, a joining part which is exposed on a part of the surface of the thermosetting resin molding 40 and is fused to the thermoplastic resin molding 20, and a connection part which connects the anchor part and the joining part. The joining part is fused to the thermoplastic resin molding 20.SELECTED DRAWING: Figure 1

Description

本発明は、樹脂接合体、樹脂接合体の製造方法及び車両用構造体に関する。   The present invention relates to a resin bonded body, a method for manufacturing a resin bonded body, and a vehicle structure.

次世代の車両用車体には、樹脂製部品の採用の拡大が予想されている。そのため、樹脂製部品同士の接合方法の確立が急務となっている。   The use of plastic parts is expected to expand in the next-generation vehicle body. Therefore, establishment of the joining method of resin parts is an urgent task.

繊維強化熱可塑性樹脂同士を接合するため、繊維強化熱可塑性樹脂の間に配置した熱可塑性樹脂シートを介して繊維強化熱可塑性樹脂同士を接合する接合方法が開示されている(例えば、特許文献1参照。)。   In order to join fiber reinforced thermoplastic resins, a joining method is disclosed in which fiber reinforced thermoplastic resins are joined via a thermoplastic resin sheet disposed between fiber reinforced thermoplastic resins (for example, Patent Document 1). reference.).

また、熱硬化性樹脂硬化物を用いた樹脂製部品と熱可塑性樹脂を用いた樹脂製部品との接合には、接着剤を用いた接合又はリベット等の締結部材を用いた固定が一般的である。   Also, for joining a resin part using a cured thermosetting resin and a resin part using a thermoplastic resin, bonding using an adhesive or fixing using a fastening member such as a rivet is generally used. is there.

なお、熱硬化性樹脂と熱可塑性樹脂とを含む繊維強化複合材料板については知られている(例えば、特許文献2参照。)。   In addition, the fiber reinforced composite material board containing a thermosetting resin and a thermoplastic resin is known (for example, refer patent document 2).

さらに、繊維強化樹脂Aの表面の一部に、樹脂Bからなる樹脂体を予め接合して樹脂体一体化予備成形体を形成し、該樹脂体一体化予備成形体を型内に配置して、前記樹脂Bと同一樹脂によるインサート成形を行う複合成形体の製造方法が開示されている(例えば、特許文献3参照。)。   Further, a resin body made of resin B is bonded in advance to a part of the surface of the fiber reinforced resin A to form a resin body integrated preform, and the resin body integrated preform is placed in a mold. A method for producing a composite molded body in which insert molding is performed using the same resin as the resin B is disclosed (for example, see Patent Document 3).

特開2014−076565号公報JP 2014-077655 A 特開2008−230238号公報JP 2008-230238 A 特開2013−028159号公報JP 2013-028159 A

しかし、特許文献1に記載の技術は、可塑性を示す熱可塑性樹脂同士の接合に用いられるものであり、熱可塑性樹脂と既に硬化反応が完了して可塑化しにくい熱硬化性樹脂硬化物との接合には適用できない。また、熱硬化性樹脂硬化物を用いた樹脂製部品と熱可塑性樹脂を用いた樹脂製部品との接合に接着剤又はリベット等の締結部材を用いると、質量又はコストの増加の一因となり、望ましくない。特に、接着剤を用いて熱可塑性樹脂と熱硬化性樹脂硬化物とを接合した場合、接着剤の強度で接合部の強度が決定されるため、樹脂製部品自身の材料強度を生かすことができない場合がある。さらには、特許文献2に記載の技術は熱可塑性樹脂と未だ未硬化の熱硬化性樹脂とを用いた繊維強化複合材料板の製造に適用されるものであり、既に硬化反応が完了している熱硬化性樹脂硬化物と熱可塑性樹脂との接合には適用できない。また、特許文献3に記載の技術は樹脂製部品の接合を目的とするものではない。   However, the technique described in Patent Document 1 is used for joining thermoplastic resins exhibiting plasticity, and joining of a thermoplastic resin and a cured thermosetting resin that has already undergone a curing reaction and is difficult to plasticize. Not applicable to In addition, if a fastening member such as an adhesive or a rivet is used to join a resin part using a thermosetting resin cured product and a resin part using a thermoplastic resin, it contributes to an increase in mass or cost. Not desirable. In particular, when a thermoplastic resin and a thermosetting resin cured product are bonded using an adhesive, the strength of the bonding portion is determined by the strength of the adhesive, and thus the material strength of the resin part itself cannot be utilized. There is a case. Furthermore, the technique described in Patent Document 2 is applied to the production of a fiber-reinforced composite material plate using a thermoplastic resin and an uncured thermosetting resin, and the curing reaction has already been completed. It cannot be applied to the joining of a cured thermosetting resin and a thermoplastic resin. Further, the technique described in Patent Document 3 is not intended for joining resin parts.

本発明は、上記従来の問題点に鑑みてなされたものであり、熱可塑性樹脂成形体と熱硬化性樹脂成形体とが接着剤又はリベット等の締結部材を用いることなく接合された樹脂接合体及びその製造方法並びにこの樹脂接合体を有する車両用構造体を提供することを目的とする。   The present invention has been made in view of the above-described conventional problems, and is a resin bonded body in which a thermoplastic resin molded body and a thermosetting resin molded body are bonded without using a fastening member such as an adhesive or a rivet. It is another object of the present invention to provide a vehicle structure having the resin bonded body and a manufacturing method thereof.

請求項1に記載の樹脂接合体は、熱可塑性樹脂成形体と、表面の一部に露出して設けられた熱可塑性樹脂部を有する熱硬化性樹脂成形体の前記熱可塑性樹脂部と、が溶着により接合したものである。   The resin joined body according to claim 1 includes a thermoplastic resin molded body, and the thermoplastic resin portion of the thermosetting resin molded body having a thermoplastic resin portion that is exposed and provided on a part of the surface. Joined by welding.

上記構成によれば、熱可塑性樹脂成形体と熱硬化性樹脂成形体とが、熱硬化性樹脂成形体の表面の一部に露出して設けられた熱可塑性樹脂部を介して溶着により接合している。そのため、接着剤又はリベット等の締結部材を用いることなく熱可塑性樹脂成形体と熱硬化性樹脂成形体とが接合された樹脂接合体が得られる。   According to the above configuration, the thermoplastic resin molded body and the thermosetting resin molded body are bonded by welding via the thermoplastic resin portion provided exposed on a part of the surface of the thermosetting resin molded body. ing. Therefore, a resin joined body in which the thermoplastic resin molded body and the thermosetting resin molded body are joined without using a fastening member such as an adhesive or a rivet is obtained.

請求項2に記載の樹脂接合体は、請求項1に記載の構成において、熱可塑性樹脂部が、熱硬化性樹脂成形体に埋設されたアンカー部と、熱硬化性樹脂成形体の表面の一部に露出し熱可塑性樹脂成形体と溶着される接合部と、アンカー部と接合部とを連結する連結部とを有し、接合部が熱可塑性樹脂成形体と溶着しているものである。   According to a second aspect of the present invention, there is provided the resin bonded body according to the first aspect, wherein the thermoplastic resin portion includes an anchor portion embedded in the thermosetting resin molded body and a surface of the thermosetting resin molded body. And a joining portion that is exposed to the thermoplastic resin molded body and is joined to the anchor portion and the joining portion, and the joining portion is welded to the thermoplastic resin molded body.

上記構成によれば、熱硬化性樹脂成形体の表面の一部に露出し熱可塑性樹脂成形体と溶着される接合部が、連結部を介して熱硬化性樹脂成形体に埋設されたアンカー部と連結されている。そのため、熱可塑性樹脂部の熱硬化性樹脂成形体からの剥離強度が向上し、熱可塑性樹脂成形体と熱可塑性樹脂部とを溶着して熱可塑性樹脂成形体と熱硬化性樹脂成形体とを接合した場合に、熱可塑性樹脂成形体と熱硬化性樹脂成形体との接合強度が向上する。   According to the said structure, the anchor part by which the junction part exposed to a part of surface of a thermosetting resin molded object and welded with a thermoplastic resin molded object was embed | buried under the thermosetting resin molded object via the connection part. It is connected with. Therefore, the peeling strength of the thermoplastic resin part from the thermosetting resin molded body is improved, and the thermoplastic resin molded body and the thermoplastic resin part are welded to form the thermoplastic resin molded body and the thermosetting resin molded body. When bonded, the bonding strength between the thermoplastic resin molded body and the thermosetting resin molded body is improved.

請求項3に記載の樹脂接合体は、請求項1又は請求項2に記載の構成において、熱可塑性樹脂成形体が、繊維を含むものである。   The resin bonded body according to claim 3 is the structure according to claim 1 or 2, wherein the thermoplastic resin molded body includes fibers.

上記構成によれば、熱可塑性樹脂成形体が繊維を含むため、熱可塑性樹脂成形体と熱可塑性樹脂部とが溶着により接合した状態で、熱可塑性樹脂成形体に含まれる繊維が熱可塑性樹脂部に進入する。そのため、熱可塑性樹脂部を介した熱可塑性樹脂成形体と熱硬化性樹脂成形体との接合強度が向上する。   According to the above configuration, since the thermoplastic resin molded body includes fibers, the fibers contained in the thermoplastic resin molded body are in a state where the thermoplastic resin molded body and the thermoplastic resin portion are joined by welding. Enter. Therefore, the joint strength between the thermoplastic resin molded body and the thermosetting resin molded body through the thermoplastic resin portion is improved.

請求項4に記載の樹脂接合体は、請求項1〜請求項3のいずれか1項に記載の構成において、熱可塑性樹脂部が、繊維を含むものである。   The resin joined body according to claim 4 is the structure according to any one of claims 1 to 3, wherein the thermoplastic resin portion includes fibers.

上記構成によれば、熱硬化性樹脂成形体の表面の一部に露出して設けられた熱可塑性樹脂部が繊維を含むため、熱可塑性樹脂成形体と熱可塑性樹脂部とが溶着により接合した状態で、熱可塑性樹脂部に含まれる繊維が熱可塑性樹脂成形体に進入する。そのため、熱可塑性樹脂部を介した熱可塑性樹脂成形体と熱硬化性樹脂成形体との接合強度が向上する。   According to the above configuration, since the thermoplastic resin portion exposed and provided on a part of the surface of the thermosetting resin molded body contains fibers, the thermoplastic resin molded body and the thermoplastic resin portion are joined by welding. In the state, the fibers contained in the thermoplastic resin portion enter the thermoplastic resin molded body. Therefore, the joint strength between the thermoplastic resin molded body and the thermosetting resin molded body through the thermoplastic resin portion is improved.

請求項5に記載の樹脂接合体は、請求項1〜請求項4のいずれか1項に記載の構成において、熱硬化性樹脂成形体が、熱可塑性樹脂部を二つ以上有するものである。   The resin joined body according to claim 5 is the structure according to any one of claims 1 to 4, wherein the thermosetting resin molded body has two or more thermoplastic resin portions.

上記構成によれば、熱可塑性樹脂成形体と熱硬化性樹脂成形体との接合箇所が二箇所以上とされるため、熱可塑性樹脂成形体と熱硬化性樹脂成形体との接合強度が向上する。   According to the said structure, since the joining location of a thermoplastic resin molded object and a thermosetting resin molded object is made into two or more places, the joining strength of a thermoplastic resin molded object and a thermosetting resin molded object improves. .

請求項6に記載の樹脂接合体の製造方法は、熱可塑性樹脂成形体を準備する工程と、表面の一部に露出して設けられた熱可塑性樹脂部を有する熱硬化性樹脂成形体を準備する工程と、熱可塑性樹脂成形体と熱可塑性樹脂部とを溶着して、熱可塑性樹脂成形体と熱硬化性樹脂成形体とを接合する工程と、を有する。   The method for producing a resin joined body according to claim 6 provides a step of preparing a thermoplastic resin molded body, and a thermosetting resin molded body having a thermoplastic resin portion exposed to a part of the surface. And a step of welding the thermoplastic resin molded body and the thermoplastic resin portion to join the thermoplastic resin molded body and the thermosetting resin molded body.

上記構成によれば、熱可塑性樹脂成形体と熱硬化性樹脂成形体とが、熱硬化性樹脂成形体の表面の一部に露出して設けられた熱可塑性樹脂部を介して溶着により接合される。そのため、熱可塑性樹脂成形体と熱硬化性樹脂成形体とを接着剤又はリベット等の締結部材を用いることなく接合することができる。   According to the above configuration, the thermoplastic resin molded body and the thermosetting resin molded body are joined by welding via the thermoplastic resin portion provided exposed on a part of the surface of the thermosetting resin molded body. The Therefore, the thermoplastic resin molded body and the thermosetting resin molded body can be joined without using a fastening member such as an adhesive or a rivet.

請求項7に記載の樹脂接合体の製造方法は、請求項6に記載の構成において、熱可塑性樹脂成形体が、繊維を含むものである。   According to a seventh aspect of the present invention, there is provided the method for producing a resin bonded body according to the sixth aspect, wherein the thermoplastic resin molded body includes fibers.

上記構成によれば、熱可塑性樹脂成形体が繊維を含むため、熱可塑性樹脂成形体と熱可塑性樹脂部とを溶着により接合するときに、熱可塑性樹脂成形体に含まれる繊維が熱可塑性樹脂部に進入する。そのため、熱可塑性樹脂部を介した熱可塑性樹脂成形体と熱硬化性樹脂成形体との接合強度が向上する。   According to the above configuration, since the thermoplastic resin molded body includes fibers, when the thermoplastic resin molded body and the thermoplastic resin portion are joined by welding, the fibers contained in the thermoplastic resin molded body are the thermoplastic resin portion. Enter. Therefore, the joint strength between the thermoplastic resin molded body and the thermosetting resin molded body through the thermoplastic resin portion is improved.

請求項8に記載の樹脂接合体の製造方法は、請求項6又は請求項7に記載の構成において、熱可塑性樹脂部が、繊維を含むものである。   The method for producing a resin bonded body according to claim 8 is the structure according to claim 6 or 7, wherein the thermoplastic resin portion includes fibers.

上記構成によれば、熱硬化性樹脂成形体の表面の一部に露出して設けられた熱可塑性樹脂部が繊維を含むため、熱可塑性樹脂成形体と熱可塑性樹脂部とを溶着により接合するときに、熱可塑性樹脂部に含まれる繊維が熱可塑性樹脂成形体に進入する。そのため、熱可塑性樹脂部を介した熱可塑性樹脂成形体と熱硬化性樹脂成形体との接合強度が向上する。   According to the above configuration, since the thermoplastic resin portion exposed and provided on a part of the surface of the thermosetting resin molded body contains fibers, the thermoplastic resin molded body and the thermoplastic resin portion are joined by welding. Sometimes, fibers contained in the thermoplastic resin portion enter the thermoplastic resin molded body. Therefore, the joint strength between the thermoplastic resin molded body and the thermosetting resin molded body through the thermoplastic resin portion is improved.

請求項9に記載の樹脂接合体の製造方法は、請求項6〜請求項8のいずれか1項に記載の構成において、熱硬化性樹脂成形体が、熱可塑性樹脂部を二つ以上有するものである。   The method for producing a resin bonded body according to claim 9 is the structure according to any one of claims 6 to 8, wherein the thermosetting resin molded body has two or more thermoplastic resin portions. It is.

上記構成によれば、熱可塑性樹脂成形体と熱硬化性樹脂成形体との接合箇所が二箇所以上とされるため、熱可塑性樹脂成形体と熱硬化性樹脂成形体との接合強度が向上する。   According to the said structure, since the joining location of a thermoplastic resin molded object and a thermosetting resin molded object is made into two or more places, the joining strength of a thermoplastic resin molded object and a thermosetting resin molded object improves. .

請求項10に記載の樹脂接合体の製造方法は、請求項6〜請求項9のいずれか1項に記載の構成において、熱可塑性樹脂部が、熱硬化性樹脂成形体に埋設されたアンカー部と、熱硬化性樹脂成形体の表面の一部に露出し熱可塑性樹脂成形体と溶着される接合部と、アンカー部と接合部とを連結する連結部とを有するものである。   The method for producing a resin joined body according to claim 10 is the anchor portion in which the thermoplastic resin portion is embedded in the thermosetting resin molded body in the configuration according to any one of claims 6 to 9. And a joining portion that is exposed on a part of the surface of the thermosetting resin molding and is welded to the thermoplastic resin molding, and a connecting portion that connects the anchor portion and the joining portion.

上記構成によれば、熱硬化性樹脂成形体の表面の一部に露出し熱可塑性樹脂成形体と溶着される接合部が、連結部を介して熱硬化性樹脂成形体に埋設されたアンカー部と連結されている。そのため、熱可塑性樹脂部の熱硬化性樹脂成形体からの剥離強度が向上し、熱可塑性樹脂成形体と熱可塑性樹脂部とを溶着して熱可塑性樹脂成形体と熱硬化性樹脂成形体とを接合した場合に、熱可塑性樹脂成形体と熱硬化性樹脂成形体との接合強度が向上する。   According to the said structure, the anchor part by which the junction part exposed to a part of surface of a thermosetting resin molded object and welded with a thermoplastic resin molded object was embed | buried under the thermosetting resin molded object via the connection part. It is connected with. Therefore, the peeling strength of the thermoplastic resin part from the thermosetting resin molded body is improved, and the thermoplastic resin molded body and the thermoplastic resin part are welded to form the thermoplastic resin molded body and the thermosetting resin molded body. When bonded, the bonding strength between the thermoplastic resin molded body and the thermosetting resin molded body is improved.

請求項11に記載の樹脂接合体の製造方法は、請求項6〜請求項9のいずれか1項に記載の構成において、熱可塑性樹脂部が、熱硬化性樹脂成形体に埋設されたアンカー部と、アンカー部から熱硬化性樹脂成形体の表面に向けて表面から突出するように設けられた突出部とを有するものである。   The method for producing a resin bonded body according to claim 11 is the anchor portion in which the thermoplastic resin portion is embedded in the thermosetting resin molded body in the configuration according to any one of claims 6 to 9. And a protruding portion provided so as to protrude from the surface toward the surface of the thermosetting resin molded body from the anchor portion.

上記構成によれば、突出部が、熱硬化性樹脂成形体に埋設されたアンカー部から熱硬化性樹脂成形体の表面に向けて前記表面から突出するように設けられている。そのため、熱可塑性樹脂成形体と熱可塑性樹脂部とを溶着して熱可塑性樹脂成形体と熱硬化性樹脂成形体とを接合するときに、突出部の先端が熱可塑性樹脂成形体と接触する。突出部の先端が熱可塑性樹脂成形体と接触した状態で熱可塑性樹脂成形体と熱可塑性樹脂部とを溶着すると、突出部の先端が発熱しやすいため発熱効率が向上し、作業性及び溶着性が向上する。さらに、熱可塑性樹脂部が、熱硬化性樹脂成形体に埋設されたアンカー部を有するため、熱可塑性樹脂部の熱硬化性樹脂成形体からの剥離強度が向上し、熱可塑性樹脂成形体と熱可塑性樹脂部とを溶着して熱可塑性樹脂成形体と熱硬化性樹脂成形体とを接合した場合に、熱可塑性樹脂成形体と熱硬化性樹脂成形体との接合強度が向上する。   According to the said structure, the protrusion part is provided so that it may protrude from the said surface toward the surface of a thermosetting resin molding from the anchor part embed | buried in the thermosetting resin molding. Therefore, when the thermoplastic resin molded body and the thermoplastic resin portion are welded to join the thermoplastic resin molded body and the thermosetting resin molded body, the tip of the protrusion comes into contact with the thermoplastic resin molded body. If the thermoplastic resin molded body and the thermoplastic resin part are welded in a state where the tip of the protruding part is in contact with the thermoplastic resin molded body, the tip of the protruding part easily generates heat, so the heat generation efficiency is improved and workability and weldability are improved. Will improve. Furthermore, since the thermoplastic resin portion has an anchor portion embedded in the thermosetting resin molded body, the peel strength of the thermoplastic resin portion from the thermosetting resin molded body is improved, and the thermoplastic resin molded body and the When the thermoplastic resin molded body and the thermosetting resin molded body are bonded to each other by welding the plastic resin portion, the bonding strength between the thermoplastic resin molded body and the thermosetting resin molded body is improved.

請求項12に記載の樹脂接合体の製造方法は、請求項6〜請求項11のいずれか1項に記載の構成において、熱硬化性樹脂成形体の表面の熱可塑性樹脂部の露出した部分の周囲に、溝部が設けられているものである。   The method for producing a resin bonded body according to claim 12 is the structure according to any one of claims 6 to 11, wherein the exposed portion of the thermoplastic resin portion of the surface of the thermosetting resin molded body is exposed. A groove is provided around the periphery.

上記構成によれば、熱硬化性樹脂成形体の表面の熱可塑性樹脂部の露出した部分の周囲に溝部が設けられることで、熱可塑性樹脂成形体と熱可塑性樹脂部とを溶着して熱可塑性樹脂成形体と熱硬化性樹脂成形体とを接合するときに生ずるバリの少なくとも一部が溝部に充填される。そのため、熱可塑性樹脂成形体と熱硬化性樹脂成形体とが接合した箇所に生ずるバリの発生量が軽減され、より強固な溶着が可能となる。   According to the above configuration, the groove portion is provided around the exposed portion of the thermoplastic resin portion on the surface of the thermosetting resin molded body, so that the thermoplastic resin molded body and the thermoplastic resin portion are welded and are thermoplastic. At least a part of a burr generated when the resin molded body and the thermosetting resin molded body are joined is filled in the groove. Therefore, the amount of burrs generated at the location where the thermoplastic resin molded body and the thermosetting resin molded body are joined is reduced, and a stronger welding is possible.

請求項13に記載の車両用構造体は、請求項1〜請求項5のいずれか1項に記載の樹脂接合体を有するものである。   A vehicle structure according to a thirteenth aspect includes the resin joined body according to any one of the first to fifth aspects.

上記構成によれば、熱可塑性樹脂成形体と熱硬化性樹脂成形体とが、熱硬化性樹脂成形体の表面の一部に露出して設けられた熱可塑性樹脂部を介して溶着により接合されるため、接着剤又はリベット等の締結部材を用いることなく熱可塑性樹脂成形体と熱硬化性樹脂成形体とが接合された樹脂接合体を有する車両用構造体が得られる。   According to the above configuration, the thermoplastic resin molded body and the thermosetting resin molded body are joined by welding via the thermoplastic resin portion provided exposed on a part of the surface of the thermosetting resin molded body. Therefore, a vehicle structure having a resin joined body in which a thermoplastic resin molded body and a thermosetting resin molded body are joined without using a fastening member such as an adhesive or a rivet is obtained.

本発明によれば、熱可塑性樹脂成形体と熱硬化性樹脂成形体とが接着剤又はリベット等の締結部材を用いることなく接合された樹脂接合体及びその製造方法並びにこの樹脂接合体を有する車両用構造体が提供される。   According to the present invention, a resin bonded body in which a thermoplastic resin molded body and a thermosetting resin molded body are bonded without using a fastening member such as an adhesive or a rivet, a manufacturing method thereof, and a vehicle having the resin bonded body. A structure is provided.

本実施形態に係る樹脂接合体の一例を示す断面図である。It is sectional drawing which shows an example of the resin bonded body which concerns on this embodiment. 第1実施形態に係る樹脂接合体の製造方法を説明するための断面図である。It is sectional drawing for demonstrating the manufacturing method of the resin conjugate | zygote which concerns on 1st Embodiment. 第1実施形態に係る樹脂接合体の製造方法の変形例を説明するための断面図である。It is sectional drawing for demonstrating the modification of the manufacturing method of the resin joined body which concerns on 1st Embodiment. 第2実施形態に係る樹脂接合体の製造方法を説明するための断面図である。It is sectional drawing for demonstrating the manufacturing method of the resin joined body which concerns on 2nd Embodiment. 第2実施形態に係る樹脂接合体の製造方法の変形例を説明するための断面図である。It is sectional drawing for demonstrating the modification of the manufacturing method of the resin joined body which concerns on 2nd Embodiment. 第3実施形態に係る樹脂接合体の製造方法を説明するための断面図である。It is sectional drawing for demonstrating the manufacturing method of the resin joined body which concerns on 3rd Embodiment. 第4実施形態に係る樹脂接合体の製造方法を説明するための断面図である。It is sectional drawing for demonstrating the manufacturing method of the resin conjugate | zygote which concerns on 4th Embodiment.

以下、本発明の樹脂接合体、樹脂接合体の製造方法及び車両用構造体の実施形態について詳細に説明する。   Hereinafter, embodiments of the resin joined body, the method for producing the resin joined body, and the vehicle structure of the present invention will be described in detail.

<樹脂接合体及びその製造方法>
樹脂接合体の実施形態について、図面を参照して説明する。
図1は、本実施形態に係る樹脂接合体の一例を示す断面図である。図1において、熱可塑性樹脂成形体20は、表面の一部に露出して設けられた熱可塑性樹脂部30を有する熱硬化性樹脂成形体40の熱可塑性樹脂部30と、溶着により接合して樹脂接合体10を構成している。
<Resin bonded body and manufacturing method thereof>
An embodiment of a resin bonded body will be described with reference to the drawings.
FIG. 1 is a cross-sectional view showing an example of a resin joined body according to the present embodiment. In FIG. 1, a thermoplastic resin molded body 20 is joined by welding to a thermoplastic resin portion 30 of a thermosetting resin molded body 40 having a thermoplastic resin portion 30 provided to be exposed on a part of the surface. The resin joined body 10 is configured.

熱可塑性樹脂成形体20を構成する熱可塑性樹脂は特に限定されるものではなく、目的に応じて公知の各種熱可塑性樹脂を使用可能である。本実施形態において用いられる熱可塑性樹脂としては、例えば、ポリカーボネート樹脂、ポリアミド(PA)樹脂、ポリウレタン(PU)樹脂、ポリ塩化ビニル樹脂、アクリロニトリル−ブタジエン−スチレン共重合体(ABS)樹脂及びポリプロピレン(PP)樹脂が挙げられる。これらの中でも、PA樹脂及びPP樹脂が好ましい。   The thermoplastic resin which comprises the thermoplastic resin molding 20 is not specifically limited, Various well-known thermoplastic resins can be used according to the objective. Examples of the thermoplastic resin used in this embodiment include polycarbonate resin, polyamide (PA) resin, polyurethane (PU) resin, polyvinyl chloride resin, acrylonitrile-butadiene-styrene copolymer (ABS) resin, and polypropylene (PP). ) Resin. Among these, PA resin and PP resin are preferable.

熱可塑性樹脂部30を構成する熱可塑性樹脂は特に限定されるものではなく、目的に応じて公知の各種熱可塑性樹脂を使用可能である。本実施形態において用いられる熱可塑性樹脂としては、例えば、ポリカーボネート樹脂、ポリアミド(PA)樹脂、ポリウレタン(PU)樹脂、ポリ塩化ビニル樹脂、アクリロニトリル−ブタジエン−スチレン共重合体(ABS)樹脂及びポリプロピレン(PP)樹脂が挙げられる。これらの中でも、PA樹脂及びPP樹脂が好ましい。   The thermoplastic resin constituting the thermoplastic resin portion 30 is not particularly limited, and various known thermoplastic resins can be used depending on the purpose. Examples of the thermoplastic resin used in this embodiment include polycarbonate resin, polyamide (PA) resin, polyurethane (PU) resin, polyvinyl chloride resin, acrylonitrile-butadiene-styrene copolymer (ABS) resin, and polypropylene (PP). ) Resin. Among these, PA resin and PP resin are preferable.

熱可塑性樹脂成形体20を構成する熱可塑性樹脂と熱可塑性樹脂部30を構成する熱可塑性樹脂とは、同一の種類でもよいし異なった種類であってもよい。本実施形態においては、熱可塑性樹脂成形体20を構成する熱可塑性樹脂と熱可塑性樹脂部30を構成する熱可塑性樹脂とは、同一の種類であることが好ましい。   The thermoplastic resin constituting the thermoplastic resin molded body 20 and the thermoplastic resin constituting the thermoplastic resin portion 30 may be of the same type or different types. In the present embodiment, the thermoplastic resin constituting the thermoplastic resin molded body 20 and the thermoplastic resin constituting the thermoplastic resin portion 30 are preferably the same type.

熱硬化性樹脂成形体40は、熱硬化性樹脂を熱硬化させた後の硬化物である。当該硬化物の形成に用いられる熱硬化性樹脂は特に限定されるものではなく、目的に応じて公知の各種熱硬化性樹脂を使用可能である。本実施形態において用いられる熱硬化性樹脂としては、例えば、ビニルエステル樹脂、不飽和ポリエステル樹脂、フェノール樹脂、エポキシ樹脂及びウレタン樹脂が挙げられる。これらの中でも、エポキシ樹脂が好ましい。   The thermosetting resin molded body 40 is a cured product after thermosetting the thermosetting resin. The thermosetting resin used for formation of the said hardened | cured material is not specifically limited, According to the objective, various well-known thermosetting resins can be used. Examples of the thermosetting resin used in the present embodiment include vinyl ester resins, unsaturated polyester resins, phenol resins, epoxy resins, and urethane resins. Among these, an epoxy resin is preferable.

熱可塑性樹脂成形体20の成形方法は特に限定されるものではなく、目的に応じて公知の各種成形方法を使用可能である。本実施形態において用いられる成形方法としては、例えば、射出成形、押出成形、吹込成形及び粉末成形が挙げられる。   The molding method of the thermoplastic resin molded body 20 is not particularly limited, and various known molding methods can be used depending on the purpose. Examples of the molding method used in the present embodiment include injection molding, extrusion molding, blow molding, and powder molding.

熱硬化性樹脂成形体40の成形方法としては特に限定されるものではなく、例えば、射出成形、押出成形、吹込成形、粉末成形、カレンダ成形、積層成形等により熱可塑性樹脂部30を成形し、成形された熱可塑性樹脂部30を用いてインサート成形等により熱可塑性樹脂部30が一体となった熱硬化性樹脂成形体40を成形することができる。   The molding method of the thermosetting resin molded body 40 is not particularly limited. For example, the thermoplastic resin portion 30 is molded by injection molding, extrusion molding, blow molding, powder molding, calendar molding, lamination molding, or the like. Using the molded thermoplastic resin portion 30, the thermosetting resin molded body 40 in which the thermoplastic resin portion 30 is integrated can be molded by insert molding or the like.

熱可塑性樹脂成形体20は、繊維を含んでいてもよい。熱可塑性樹脂成形体20に用いられる繊維の種類は特に限定されるものではなく、目的に応じて公知の各種繊維を使用可能である。熱可塑性樹脂成形体20に用いられる繊維の種類としては、例えば、アラミド繊維、セルロース繊維、ナイロン繊維、ビニロン繊維、ポリエステル繊維、ポリオレフィン繊維、レーヨン繊維等の樹脂繊維、炭素繊維、ガラス繊維、金属繊維などが挙げられる。これらの中でも、高い機械的強度を実現可能な炭素繊維が望ましい。   The thermoplastic resin molded body 20 may contain fibers. The kind of fiber used for the thermoplastic resin molding 20 is not particularly limited, and various known fibers can be used depending on the purpose. Examples of the types of fibers used in the thermoplastic resin molded body 20 include resin fibers such as aramid fibers, cellulose fibers, nylon fibers, vinylon fibers, polyester fibers, polyolefin fibers, rayon fibers, carbon fibers, glass fibers, and metal fibers. Etc. Among these, carbon fibers that can realize high mechanical strength are desirable.

熱可塑性樹脂部30は、繊維を含んでいてもよい。熱可塑性樹脂部30に用いられる繊維の種類は特に限定されるものではなく、目的に応じて公知の各種繊維を使用可能である。熱可塑性樹脂部30に用いられる繊維の種類としては、例えば、アラミド繊維、セルロース繊維、ナイロン繊維、ビニロン繊維、ポリエステル繊維、ポリオレフィン繊維、レーヨン繊維等の樹脂繊維、炭素繊維、ガラス繊維、金属繊維などが挙げられる。これらの中でも、高い機械的強度を実現可能な炭素繊維が望ましい。   The thermoplastic resin part 30 may contain fibers. The kind of fiber used for the thermoplastic resin part 30 is not specifically limited, According to the objective, various well-known fibers can be used. Examples of the types of fibers used for the thermoplastic resin portion 30 include resin fibers such as aramid fibers, cellulose fibers, nylon fibers, vinylon fibers, polyester fibers, polyolefin fibers, and rayon fibers, carbon fibers, glass fibers, and metal fibers. Is mentioned. Among these, carbon fibers that can realize high mechanical strength are desirable.

熱硬化性樹脂成形体40は、繊維を含んでいてもよい。熱硬化性樹脂成形体40に用いられる繊維の種類は特に限定されるものではなく、目的に応じて公知の各種繊維を使用可能である。熱硬化性樹脂成形体40に用いられる繊維の種類としては、例えば、アラミド繊維、セルロース繊維、ナイロン繊維、ビニロン繊維、ポリエステル繊維、ポリオレフィン繊維、レーヨン繊維等の樹脂繊維、炭素繊維、ガラス繊維、金属繊維などが挙げられる。これらの中でも、高い機械的強度を実現可能な炭素繊維が望ましい。   The thermosetting resin molded body 40 may contain fibers. The kind of fiber used for the thermosetting resin molding 40 is not particularly limited, and various known fibers can be used according to the purpose. Examples of the types of fibers used in the thermosetting resin molded body 40 include resin fibers such as aramid fibers, cellulose fibers, nylon fibers, vinylon fibers, polyester fibers, polyolefin fibers, and rayon fibers, carbon fibers, glass fibers, and metals. Examples include fibers. Among these, carbon fibers that can realize high mechanical strength are desirable.

本実施形態において用いられる繊維の状態は特に限定されるものではなく、目的に応じて公知の状態の繊維を使用可能である。本実施形態において用いられる繊維の状態としては、例えば、織布及び不織布が挙げられる。   The state of the fiber used in the present embodiment is not particularly limited, and a fiber in a known state can be used depending on the purpose. Examples of the state of the fiber used in the present embodiment include a woven fabric and a non-woven fabric.

熱可塑性樹脂部30の構成は特に限定されるものではない。図1に示すようなシート状とされていてもよいし、熱硬化性樹脂成形体に埋設されたアンカー部と、熱硬化性樹脂成形体の表面の一部に露出し熱可塑性樹脂成形体20と溶着される接合部と、アンカー部と接合部とを連結する連結部とを有し、接合部が熱可塑性樹脂成形体20と溶着している構成としてもよい。熱可塑性樹脂部30の構成をアンカー部と接合部と連結部とを有する構成とすることにより、熱可塑性樹脂部30が熱硬化性樹脂成形体40から脱離しにくい。そのため、熱可塑性樹脂部30の熱硬化性樹脂成形体40からの剥離強度が向上し、熱可塑性樹脂成形体20と熱硬化性樹脂成形体40との接合強度が向上する。   The configuration of the thermoplastic resin portion 30 is not particularly limited. The sheet may be in the form of a sheet as shown in FIG. 1, the anchor portion embedded in the thermosetting resin molding, and a portion of the surface of the thermosetting resin molding that is exposed to the thermoplastic resin molding 20. It is good also as a structure which has the junction part welded and the connection part which connects an anchor part and a junction part, and the junction part is welded with the thermoplastic resin molded object 20. FIG. By configuring the thermoplastic resin portion 30 to have an anchor portion, a joint portion, and a connecting portion, the thermoplastic resin portion 30 is unlikely to be detached from the thermosetting resin molded body 40. Therefore, the peel strength of the thermoplastic resin part 30 from the thermosetting resin molded body 40 is improved, and the bonding strength between the thermoplastic resin molded body 20 and the thermosetting resin molded body 40 is improved.

本実施形態に係る樹脂接合体においては、熱硬化性樹脂成形体40に設けられる熱可塑性樹脂部30の数は特に限定されない。図1では熱硬化性樹脂成形体40に設けられる熱可塑性樹脂部30の数は一つとされているが、二つ以上であってもよく、必要とされる熱可塑性樹脂成形体20と熱硬化性樹脂成形体40との接合強度に合わせて熱可塑性樹脂部30の数を選択することができる。   In the resin joined body according to the present embodiment, the number of the thermoplastic resin portions 30 provided in the thermosetting resin molded body 40 is not particularly limited. In FIG. 1, the number of the thermoplastic resin portions 30 provided in the thermosetting resin molded body 40 is one, but it may be two or more, and the required thermoplastic resin molded body 20 and thermosetting. The number of thermoplastic resin portions 30 can be selected in accordance with the bonding strength with the thermoplastic resin molded body 40.

熱可塑性樹脂と繊維とを複合化させて熱可塑性樹脂成形体20又は熱可塑性樹脂部30を得る方法については、特に限定されるものではなく、目的に応じて公知の各種方法を使用可能である。例えば、繊維に熱可塑性樹脂の溶液または融液を含浸させ、必要に応じて乾燥してシート状に成型する方法、及び、繊維と熱可塑性樹脂フィルムとを交互に積層した後に加熱加圧成形する方法が挙げられる。
熱硬化性樹脂と繊維とを複合化させて熱硬化性樹脂成形体40を得る方法についても、特に限定されるものではなく、目的に応じて公知の各種方法を使用可能である。熱硬化性樹脂成形体40の製造には、熱硬化性樹脂と繊維とを複合化させたプリプレグを用いてもよい。
The method for obtaining the thermoplastic resin molded body 20 or the thermoplastic resin portion 30 by combining the thermoplastic resin and the fiber is not particularly limited, and various known methods can be used depending on the purpose. . For example, a method in which a fiber is impregnated with a solution or melt of a thermoplastic resin, and if necessary, is dried and molded into a sheet, and a fiber and a thermoplastic resin film are alternately laminated and then heated and pressed. A method is mentioned.
The method for obtaining the thermosetting resin molded body 40 by combining the thermosetting resin and the fiber is not particularly limited, and various known methods can be used depending on the purpose. For the production of the thermosetting resin molded body 40, a prepreg in which a thermosetting resin and a fiber are combined may be used.

次に、樹脂接合体の製造方法の実施形態について、図面を参照して説明する。なお、以下において、樹脂接合体の実施形態と同一の部材には同一の符号を付し、重複した説明を省略することがある。また、各図における部材の大きさは概念的なものであり、部材間の大きさの相対的な関係はこれに限定されない。   Next, an embodiment of a method for producing a resin joined body will be described with reference to the drawings. In addition, below, the same code | symbol may be attached | subjected to the member same as embodiment of a resin joined body, and the overlapping description may be abbreviate | omitted. Moreover, the magnitude | size of the member in each figure is notional, The relative relationship of the magnitude | size between members is not limited to this.

図2は、第1実施形態に係る樹脂接合体の製造方法を説明するための断面図である。第1実施形態に係る樹脂接合体の製造方法においては、熱可塑性樹脂成形体20と、表面の一部に露出して設けられた熱可塑性樹脂部30を有する熱硬化性樹脂成形体40とが準備される。熱可塑性樹脂成形体20及び熱硬化性樹脂成形体40を準備する方法は特に限定されるものではなく、後述の、熱可塑性樹脂成形体20と熱硬化性樹脂成形体40とを接合する工程を実施する者が自身で作製してもよいし、熱可塑性樹脂成形体20及び熱硬化性樹脂成形体40を購入等により入手してもよい。熱可塑性樹脂成形体20及び熱硬化性樹脂成形体40を作製するために用いられる材料、方法等は上述の通りである。   FIG. 2 is a cross-sectional view for explaining the method of manufacturing the resin joined body according to the first embodiment. In the method for producing a resin joined body according to the first embodiment, a thermoplastic resin molded body 20 and a thermosetting resin molded body 40 having a thermoplastic resin portion 30 provided to be exposed on a part of the surface are provided. Be prepared. The method for preparing the thermoplastic resin molded body 20 and the thermosetting resin molded body 40 is not particularly limited, and a process of joining the thermoplastic resin molded body 20 and the thermosetting resin molded body 40 described later is performed. The practitioner may make the product himself or may obtain the thermoplastic resin molded body 20 and the thermosetting resin molded body 40 by purchase or the like. The materials, methods, and the like used for producing the thermoplastic resin molded body 20 and the thermosetting resin molded body 40 are as described above.

図2において、熱硬化性樹脂成形体40の表面の一部に露出して設けられた熱可塑性樹脂部30の形状は、シート状とされている。   In FIG. 2, the shape of the thermoplastic resin part 30 exposed and provided in a part of surface of the thermosetting resin molding 40 is a sheet form.

第1実施形態に係る樹脂接合体の製造方法においては、熱可塑性樹脂成形体20と熱可塑性樹脂部30とを溶着して、熱可塑性樹脂成形体20と熱硬化性樹脂成形体40とを接合することで樹脂接合体10が製造される。   In the method for manufacturing a resin joined body according to the first embodiment, the thermoplastic resin molded body 20 and the thermoplastic resin portion 30 are welded to join the thermoplastic resin molded body 20 and the thermosetting resin molded body 40 together. By doing so, the resin bonded body 10 is manufactured.

熱可塑性樹脂成形体20と熱可塑性樹脂部30とを溶着させて熱可塑性樹脂成形体20と熱硬化性樹脂成形体40とを接合する方法としては特に限定されるものではなく、公知の各種溶着方法を使用可能である。本実施形態において用いることのできる溶着方法としては、例えば、超音波溶着、振動溶着、誘導溶着、高周波溶着、レーザー溶着、熱溶着及びスピン溶着が挙げられる。これらの中でも、超音波溶着及び振動溶着が好ましい。   The method of joining the thermoplastic resin molded body 20 and the thermosetting resin molded body 40 by welding the thermoplastic resin molded body 20 and the thermoplastic resin portion 30 is not particularly limited, and various known welds are used. The method can be used. Examples of the welding method that can be used in the present embodiment include ultrasonic welding, vibration welding, induction welding, high frequency welding, laser welding, thermal welding, and spin welding. Among these, ultrasonic welding and vibration welding are preferable.

溶着方法として振動溶着を用いることにより、樹脂接合体の強度がより向上する。一方、溶着方法として超音波溶着を用いることにより、接合される熱可塑性樹脂成形体及び熱硬化性樹脂成形体の設計及び構造の自由度が高くなる。   By using vibration welding as the welding method, the strength of the resin bonded body is further improved. On the other hand, the use of ultrasonic welding as the welding method increases the degree of freedom in design and structure of the thermoplastic resin molded body and the thermosetting resin molded body to be joined.

振動溶着は、溶着させる熱可塑性樹脂成形体及び熱硬化性樹脂成形体に対してプレス機等を用いて荷重をかけた状態で、熱可塑性樹脂成形体及び熱硬化性樹脂成形体の一方を熱可塑性樹脂成形体及び熱硬化性樹脂成形体の接触面に対して水平方向に振動させ、それによって発生する摩擦熱を利用して溶着する方法である。   In vibration welding, one of the thermoplastic resin molded body and the thermosetting resin molded body is heated while a load is applied to the thermoplastic resin molded body and the thermosetting resin molded body to be welded using a press machine or the like. In this method, the plastic resin molded body and the thermosetting resin molded body are vibrated in the horizontal direction with respect to the contact surfaces, and welding is performed using frictional heat generated thereby.

一方、超音波溶着は、超音波発振器によって電気エネルギーを振動エネルギーに変換し、この振動エネルギーを接触させた状態の熱可塑性樹脂成形体及び熱硬化性樹脂成形体の接触面に付与することで当該接触面に発生した摩擦熱を利用して溶着する方法である。   On the other hand, in ultrasonic welding, the electrical energy is converted into vibration energy by an ultrasonic oscillator, and the vibration energy is applied to the contact surfaces of the thermoplastic resin molded body and the thermosetting resin molded body in contact with each other. This is a method of welding using frictional heat generated on the contact surface.

第1実施形態に係る樹脂接合体の製造方法においては、熱硬化性樹脂成形体40に設けられる熱可塑性樹脂部30の数は特に限定されない。図2では熱硬化性樹脂成形体40に設けられる熱可塑性樹脂部30の数は一つとされているが、二つ以上であってもよく、必要とされる熱可塑性樹脂成形体20と熱硬化性樹脂成形体40との接合強度に合わせて熱可塑性樹脂部30の数を選択することができる。   In the method for manufacturing a resin joined body according to the first embodiment, the number of thermoplastic resin portions 30 provided in the thermosetting resin molded body 40 is not particularly limited. In FIG. 2, the number of the thermoplastic resin portions 30 provided in the thermosetting resin molded body 40 is one, but it may be two or more, and the required thermoplastic resin molded body 20 and thermosetting. The number of thermoplastic resin portions 30 can be selected in accordance with the bonding strength with the thermoplastic resin molded body 40.

また、熱硬化性樹脂成形体40に設けられる熱可塑性樹脂部30の数を二つ以上とすることで、熱可塑性樹脂成形体20と熱可塑性樹脂部30とを溶着する際に生ずるバリ(熱可塑性樹脂成形体20と熱硬化性樹脂成形体40とを溶着により接合する際に生ずる余剰の熱可塑性樹脂)が熱硬化性樹脂成形体40と熱可塑性樹脂成形体20との間に介在し、熱可塑性樹脂成形体20と熱硬化性樹脂成形体40との接合強度がより向上する。   Further, by setting the number of the thermoplastic resin portions 30 provided in the thermosetting resin molded body 40 to two or more, burrs (heat) generated when the thermoplastic resin molded body 20 and the thermoplastic resin portion 30 are welded. Surplus thermoplastic resin generated when the thermoplastic resin molded body 20 and the thermosetting resin molded body 40 are joined by welding) is interposed between the thermosetting resin molded body 40 and the thermoplastic resin molded body 20, The bonding strength between the thermoplastic resin molded body 20 and the thermosetting resin molded body 40 is further improved.

図3は、第1実施形態に係る樹脂接合体の製造方法の変形例を説明するための断面図である。図3に示すように、熱可塑性樹脂部30は、熱硬化性樹脂成形体40の表面から突出するように設けられていてもよい。   Drawing 3 is a sectional view for explaining the modification of the manufacturing method of the resin joined object concerning a 1st embodiment. As shown in FIG. 3, the thermoplastic resin portion 30 may be provided so as to protrude from the surface of the thermosetting resin molded body 40.

図4は、第2実施形態に係る樹脂接合体の製造方法を説明するための断面図である。第2実施形態に係る樹脂接合体の製造方法においては、熱可塑性樹脂部30が、熱硬化性樹脂成形体40に埋設されたアンカー部32と、熱硬化性樹脂成形体40の表面の一部に露出し熱可塑性樹脂成形体20と溶着される接合部34と、アンカー部32と接合部34とを連結する連結部36とを有する構成とされている。   FIG. 4 is a cross-sectional view for explaining the method of manufacturing the resin joined body according to the second embodiment. In the method for manufacturing a resin joined body according to the second embodiment, the thermoplastic resin portion 30 includes an anchor portion 32 embedded in the thermosetting resin molded body 40 and a part of the surface of the thermosetting resin molded body 40. It is set as the structure which has the connection part 36 which connects the anchor part 32 and the junction part 34 which are exposed to the thermoplastic resin molded object 20, and is joined to the anchor part 32.

第2実施形態に係る樹脂接合体の製造方法においては、接合部34が連結部36を介して熱硬化性樹脂成形体40に埋設されたアンカー部32と連結されているため、熱可塑性樹脂部30が熱硬化性樹脂成形体40から脱離しにくい。そのため、熱可塑性樹脂部30の熱硬化性樹脂成形体40からの剥離強度が向上し、熱可塑性樹脂成形体20と熱硬化性樹脂成形体40との接合強度が向上する。   In the method for manufacturing a resin bonded body according to the second embodiment, since the bonded portion 34 is connected to the anchor portion 32 embedded in the thermosetting resin molded body 40 via the connecting portion 36, the thermoplastic resin portion. 30 is not easily detached from the thermosetting resin molded body 40. Therefore, the peel strength of the thermoplastic resin part 30 from the thermosetting resin molded body 40 is improved, and the bonding strength between the thermoplastic resin molded body 20 and the thermosetting resin molded body 40 is improved.

第2実施形態に係る樹脂接合体の製造方法における溶着方法としては、超音波溶着及び振動溶着が好ましく、振動溶着がより好ましい。   As a welding method in the method of manufacturing a resin joined body according to the second embodiment, ultrasonic welding and vibration welding are preferable, and vibration welding is more preferable.

第2実施形態に係る樹脂接合体の製造方法においては、熱硬化性樹脂成形体40に設けられる熱可塑性樹脂部30の数は特に限定されない。図4では熱硬化性樹脂成形体40に設けられる熱可塑性樹脂部30の数は一つとされているが、二つ以上であってもよく、必要とされる熱可塑性樹脂成形体20と熱硬化性樹脂成形体40との接合強度に合わせて熱可塑性樹脂部30の数を選択することができる。   In the method for manufacturing a resin joined body according to the second embodiment, the number of thermoplastic resin portions 30 provided in the thermosetting resin molded body 40 is not particularly limited. In FIG. 4, the number of the thermoplastic resin portions 30 provided in the thermosetting resin molded body 40 is one, but it may be two or more, and the required thermoplastic resin molded body 20 and thermosetting. The number of thermoplastic resin portions 30 can be selected in accordance with the bonding strength with the thermoplastic resin molded body 40.

また、熱硬化性樹脂成形体40に設けられる熱可塑性樹脂部30の数を二つ以上とすることで、熱可塑性樹脂成形体20と熱可塑性樹脂部30とを溶着する際に生ずるバリが熱硬化性樹脂成形体40と熱可塑性樹脂成形体20との間に介在し、熱可塑性樹脂成形体20と熱硬化性樹脂成形体40との接合強度がより向上する。   Further, by setting the number of the thermoplastic resin portions 30 provided in the thermosetting resin molded body 40 to two or more, burrs generated when the thermoplastic resin molded body 20 and the thermoplastic resin portion 30 are welded are heated. It is interposed between the curable resin molded body 40 and the thermoplastic resin molded body 20, and the bonding strength between the thermoplastic resin molded body 20 and the thermosetting resin molded body 40 is further improved.

図5は、第2実施形態に係る樹脂接合体の製造方法の変形例を説明するための断面図である。図5に示すように、熱可塑性樹脂部30における接合部34は、熱硬化性樹脂成形体40の表面から突出するように設けられていてもよい。   FIG. 5 is a cross-sectional view for explaining a modification of the method for producing a resin joined body according to the second embodiment. As shown in FIG. 5, the joining portion 34 in the thermoplastic resin portion 30 may be provided so as to protrude from the surface of the thermosetting resin molded body 40.

図6は、第3実施形態に係る樹脂接合体の製造方法を説明するための断面図である。第3実施形態に係る樹脂接合体の製造方法においては、熱可塑性樹脂部30が、熱硬化性樹脂成形体40に埋設されたアンカー部32と、アンカー部32から熱硬化性樹脂成形体40の表面に向けて表面から突出するように設けられた突出部38とを有する構成とされている。   FIG. 6 is a cross-sectional view for explaining the method of manufacturing the resin joined body according to the third embodiment. In the method of manufacturing the resin joined body according to the third embodiment, the thermoplastic resin portion 30 includes an anchor portion 32 embedded in the thermosetting resin molded body 40, and the thermosetting resin molded body 40 from the anchor portion 32. It is set as the structure which has the protrusion part 38 provided so that it might protrude from the surface toward the surface.

そのため、熱可塑性樹脂成形体20と熱可塑性樹脂部30とを溶着して熱可塑性樹脂成形体20と熱硬化性樹脂成形体40とを接合するときには、突出部38の先端が熱可塑性樹脂成形体20と接触する。突出部38の先端が熱可塑性樹脂成形体20と接触した状態で、例えば振動溶着を実施すると、突出部38の先端が摩擦により発熱しやすいため発熱効率が向上し、突出部38と熱可塑性樹脂成形体20とが容易に接合される。そのため、作業性及び溶着性が向上する。   Therefore, when the thermoplastic resin molded body 20 and the thermoplastic resin portion 30 are welded to join the thermoplastic resin molded body 20 and the thermosetting resin molded body 40, the tip of the protruding portion 38 is the thermoplastic resin molded body. 20 is contacted. When, for example, vibration welding is performed in a state where the tip of the protruding portion 38 is in contact with the thermoplastic resin molded body 20, the tip of the protruding portion 38 is likely to generate heat due to friction, so that the heat generation efficiency is improved. The molded body 20 is easily joined. Therefore, workability and weldability are improved.

熱硬化性樹脂成形体40の熱可塑性樹脂成形体20との接合面と直交する方向から見たときの突出部38の面積は、熱硬化性樹脂成形体40の熱可塑性樹脂成形体20との接合面と直交する方向から見たときのアンカー部32の面積よりも小さいことが好ましい。突出部38の面積を小さくすることで、突出部38の先端が熱可塑性樹脂成形体20と接触した状態で、例えば振動溶着を実施する際に、突出部38と熱可塑性樹脂成形体20との接触圧力をより高くすることができ、発熱効率がより向上する。   The area of the protrusion 38 when viewed from the direction orthogonal to the joint surface of the thermosetting resin molded body 40 with the thermoplastic resin molded body 20 is the same as that of the thermoplastic resin molded body 20 of the thermosetting resin molded body 40. The area is preferably smaller than the area of the anchor portion 32 when viewed from a direction orthogonal to the joint surface. By reducing the area of the protruding portion 38, for example, when performing vibration welding in a state where the tip of the protruding portion 38 is in contact with the thermoplastic resin molded body 20, the protruding portion 38 and the thermoplastic resin molded body 20 The contact pressure can be further increased, and the heat generation efficiency is further improved.

さらに、熱可塑性樹脂部30が、熱硬化性樹脂成形体40に埋設されたアンカー部32を有するため、熱可塑性樹脂部30が熱硬化性樹脂成形体40から脱離しにくい。そのため、熱可塑性樹脂部30の熱硬化性樹脂成形体40からの剥離強度が向上し、熱可塑性樹脂成形体20と熱硬化性樹脂成形体40との接合強度が向上する。   Furthermore, since the thermoplastic resin part 30 has the anchor part 32 embedded in the thermosetting resin molded body 40, the thermoplastic resin part 30 is not easily detached from the thermosetting resin molded body 40. Therefore, the peel strength of the thermoplastic resin part 30 from the thermosetting resin molded body 40 is improved, and the bonding strength between the thermoplastic resin molded body 20 and the thermosetting resin molded body 40 is improved.

第3実施形態に係る樹脂接合体の製造方法においては、熱硬化性樹脂成形体40に設けられる熱可塑性樹脂部30の数は特に限定されない。図6では熱硬化性樹脂成形体40に設けられる熱可塑性樹脂部30の数は一つとされているが、二つ以上であってもよく、必要とされる熱可塑性樹脂成形体20と熱硬化性樹脂成形体40との接合強度に合わせて熱可塑性樹脂部30の数を選択することができる。   In the method for manufacturing a resin joined body according to the third embodiment, the number of thermoplastic resin portions 30 provided in the thermosetting resin molded body 40 is not particularly limited. In FIG. 6, the number of the thermoplastic resin portions 30 provided in the thermosetting resin molded body 40 is one, but it may be two or more, and the required thermoplastic resin molded body 20 and thermosetting. The number of thermoplastic resin portions 30 can be selected in accordance with the bonding strength with the thermoplastic resin molded body 40.

熱硬化性樹脂成形体40に設けられる熱可塑性樹脂部30の数を二つ以上とすることで、熱可塑性樹脂成形体20と熱可塑性樹脂部30とを溶着する際に生ずるバリが熱硬化性樹脂成形体40と熱可塑性樹脂成形体20との間に介在し、熱可塑性樹脂成形体20と熱硬化性樹脂成形体40との接合強度がより向上する。   By setting the number of the thermoplastic resin portions 30 provided in the thermosetting resin molded body 40 to two or more, burrs generated when welding the thermoplastic resin molded body 20 and the thermoplastic resin portion 30 are thermosetting. It is interposed between the resin molded body 40 and the thermoplastic resin molded body 20, and the bonding strength between the thermoplastic resin molded body 20 and the thermosetting resin molded body 40 is further improved.

第3実施形態に係る樹脂接合体の製造方法における溶着方法としては、振動溶着が好ましい。   As a welding method in the method for producing a resin joined body according to the third embodiment, vibration welding is preferable.

図7は、第4実施形態に係る樹脂接合体の製造方法を説明するための断面図である。第4実施形態に係る樹脂接合体の製造方法においては、熱硬化性樹脂成形体40の表面の熱可塑性樹脂部30の露出した部分の周囲に、溝部42が設けられた構成とされている。   FIG. 7 is a cross-sectional view for explaining the method of manufacturing the resin joined body according to the fourth embodiment. In the method for manufacturing a resin joined body according to the fourth embodiment, a groove portion 42 is provided around the exposed portion of the thermoplastic resin portion 30 on the surface of the thermosetting resin molded body 40.

溝部42の大きさは特に限定されるものではない。熱可塑性樹脂成形体20と熱可塑性樹脂部30とを溶着する際の、熱可塑性樹脂成形体20と熱硬化性樹脂成形体40との溶かし込み量から熱可塑性樹脂のバリの発生量を見積もり、バリの発生量に合わせて溝部42の体積を設定することで、発生したバリの大部分が溝部42に充填される。そのため、熱可塑性樹脂成形体20と熱硬化性樹脂成形体40とが接合した箇所に生ずるバリの発生量がより軽減されるため望ましい。   The size of the groove 42 is not particularly limited. When the thermoplastic resin molded body 20 and the thermoplastic resin portion 30 are welded, the amount of burrs generated from the thermoplastic resin is estimated from the amount of the thermoplastic resin molded body 20 and the thermosetting resin molded body 40 that is melted. By setting the volume of the groove 42 in accordance with the amount of burrs generated, most of the generated burrs are filled in the groove 42. Therefore, it is desirable because the amount of burrs generated at the place where the thermoplastic resin molded body 20 and the thermosetting resin molded body 40 are joined is further reduced.

第4実施形態に係る樹脂接合体の製造方法では、熱可塑性樹脂部30がアンカー部32と突出部38とを有する構成とされているが、熱可塑性樹脂部30の構成は特に限定されるものではない。   In the manufacturing method of the resin joined body according to the fourth embodiment, the thermoplastic resin portion 30 is configured to have the anchor portion 32 and the protruding portion 38, but the configuration of the thermoplastic resin portion 30 is particularly limited. is not.

<車両用構造体>
本実施形態に係る車両用構造体は、上述した本実施形態に係る樹脂接合体を有するものである。本実施形態に係る車両用構造体の種類は特に限定されるものではなく、例えば、サイドドア、フード、ルーフ、バックドア、ラゲージドア、バンパ及びクラッシュボックスが挙げられる。
<Vehicle structure>
The vehicle structure according to the present embodiment includes the resin joined body according to the present embodiment described above. The type of the vehicle structure according to the present embodiment is not particularly limited, and examples thereof include a side door, a hood, a roof, a back door, a luggage door, a bumper, and a crash box.

一般に、熱可塑性樹脂成形体に比較して熱硬化性樹脂成形体の方が表面平滑性に優れるため、例えば、本実施形態に係る樹脂接合体を用いて車両用構造体としてドアを形成する場合、樹脂接合体のうちの熱硬化性樹脂成形体でドアの表側が構成されることが好ましい。   In general, since the thermosetting resin molded body is superior in surface smoothness compared to the thermoplastic resin molded body, for example, when a door is formed as a vehicle structural body using the resin joined body according to the present embodiment It is preferable that the front side of the door is constituted by a thermosetting resin molded body of the resin joined body.

本実施形態に係る車両用構造体によれば、要求される特性に応じて部分毎に好適な樹脂材料を組み合わせて樹脂製の車両用構造体を構成することが可能となる。そのため、本実施形態に係る車両用構造体によれは、複数種の樹脂(マルチマテリアル)を併用する次世代の車両を実現可能となる。   According to the vehicle structure according to the present embodiment, a resin vehicle structure can be configured by combining suitable resin materials for each portion in accordance with required characteristics. Therefore, according to the vehicle structure according to the present embodiment, a next-generation vehicle that uses a plurality of types of resins (multi-materials) in combination can be realized.

以下、実施例に基づき、本実施形態をより具体的に説明するが、本実施形態は以下の実施例に限定されるものではない。   Hereinafter, the present embodiment will be described more specifically based on examples, but the present embodiment is not limited to the following examples.

(試験片の準備)
熱硬化性樹脂として、東レ株式会社製CFRP(連続繊維プリプレグ材)3K綾材を用いた。熱可塑性樹脂として、東レ株式会社製CFRTP(ランダム材)を用いた。
・熱可塑性樹脂成形体の準備
熱可塑性樹脂を用いて長さ100mm、幅25mm、厚さ3mmの熱可塑性樹脂成形体を形成した。
・熱硬化性樹脂成形体の準備
熱可塑性樹脂を用いて長さ10mm、幅5mm、厚さ3mmの熱可塑性樹脂部を2つ形成した。この熱可塑性樹脂部の表面にコロナ放電処理を施した。
熱硬化性樹脂とこの熱可塑性樹脂部とを用い、熱硬化性樹脂成形体の硬化前の前駆体を形成し、オーブンで135℃で2時間加熱し、次いでオートクレーブで135℃、0.4MPaの条件で2時間加熱加圧し、熱硬化性樹脂成形体を得た。熱硬化性樹脂成形体の大きさは長さ100mm、幅25mm、厚さ3mmとした。熱硬化性樹脂成形体の端部には、2つの熱可塑性樹脂部がその長さ方向を熱硬化性樹脂成形体の長さ方向と平行に、5mmの間隔で配置した。熱可塑性樹脂部の熱硬化性樹脂成形体からの突出量は、1mmとした。
(Preparation of specimen)
As a thermosetting resin, CFRP (continuous fiber prepreg material) 3K twill material manufactured by Toray Industries, Inc. was used. CFRTP (random material) manufactured by Toray Industries, Inc. was used as the thermoplastic resin.
-Preparation of thermoplastic resin molded body A thermoplastic resin molded body having a length of 100 mm, a width of 25 mm, and a thickness of 3 mm was formed using a thermoplastic resin.
-Preparation of thermosetting resin molded body Two thermoplastic resin portions having a length of 10 mm, a width of 5 mm, and a thickness of 3 mm were formed using a thermoplastic resin. The surface of the thermoplastic resin portion was subjected to corona discharge treatment.
Using the thermosetting resin and this thermoplastic resin portion, a precursor before curing of the thermosetting resin molded body is formed, heated in an oven at 135 ° C. for 2 hours, and then in an autoclave at 135 ° C. and 0.4 MPa. It heat-pressed for 2 hours on conditions, and the thermosetting resin molding was obtained. The size of the thermosetting resin molding was 100 mm in length, 25 mm in width, and 3 mm in thickness. At the end of the thermosetting resin molded body, two thermoplastic resin portions were arranged at intervals of 5 mm with the length direction parallel to the length direction of the thermosetting resin molded body. The amount of protrusion of the thermoplastic resin portion from the thermosetting resin molding was 1 mm.

(振動溶着)
得られた熱可塑性樹脂成形体及び熱硬化性樹脂成形体を、25±2℃に管理された部屋で10日以上保管後、溶着試験に供した。
振動溶着機として、ブランソン MICRO PPL(日本エマソン株式会社)を用いた。
熱可塑性樹脂成形体と熱硬化性樹脂成形体の熱可塑性樹脂部とを接触させ、振動溶着を実施し、樹脂接合体を作製した。溶着条件としては、振動振幅を1.8mmとし、加圧を0.75MPaとし、溶け込み寸法を1.0mmとした。
(Vibration welding)
The obtained thermoplastic resin molded body and thermosetting resin molded body were stored for 10 days or more in a room controlled at 25 ± 2 ° C., and then subjected to a welding test.
Branson MICRO PPL (Nippon Emerson Corporation) was used as the vibration welder.
The thermoplastic resin molded body and the thermoplastic resin portion of the thermosetting resin molded body were brought into contact with each other, and vibration welding was performed to produce a resin joined body. As welding conditions, the vibration amplitude was 1.8 mm, the pressure was 0.75 MPa, and the penetration dimension was 1.0 mm.

(せん断強度測定)
株式会社島津製作所製 オートグラフ AG−X100KNを用い、せん断試験を実施したところ、せん断強度は21.9MPaであり、優れた接合強度を示すことがわかった。
(Shear strength measurement)
When a shear test was performed using Autograph AG-X100KN manufactured by Shimadzu Corporation, it was found that the shear strength was 21.9 MPa, indicating excellent bonding strength.

10 樹脂接合体
20 熱可塑性樹脂成形体
30 熱可塑性樹脂部
32 アンカー部
34 接合部
36 連結部
38 突出部
40 熱硬化性樹脂成形体
42 溝部
DESCRIPTION OF SYMBOLS 10 Resin joined body 20 Thermoplastic resin molded body 30 Thermoplastic resin part 32 Anchor part 34 Joint part 36 Connection part 38 Protrusion part 40 Thermosetting resin molded body 42 Groove part

Claims (13)

熱可塑性樹脂成形体と、表面の一部に露出して設けられた熱可塑性樹脂部を有する熱硬化性樹脂成形体の前記熱可塑性樹脂部と、が溶着により接合した樹脂接合体。   A resin joined body in which a thermoplastic resin molded body and the thermoplastic resin portion of a thermosetting resin molded body having a thermoplastic resin portion provided exposed on a part of the surface are joined by welding. 前記熱可塑性樹脂部は、前記熱硬化性樹脂成形体に埋設されたアンカー部と、前記熱硬化性樹脂成形体の表面の一部に露出し前記熱可塑性樹脂成形体と溶着される接合部と、前記アンカー部と前記接合部とを連結する連結部とを有し、前記接合部が前記熱可塑性樹脂成形体と溶着している請求項1に記載の樹脂接合体。   The thermoplastic resin portion includes an anchor portion embedded in the thermosetting resin molded body, a joint portion that is exposed to a part of the surface of the thermosetting resin molded body and is welded to the thermoplastic resin molded body. The resin joined body according to claim 1, further comprising: a connecting portion that connects the anchor portion and the joined portion, wherein the joined portion is welded to the thermoplastic resin molded body. 前記熱可塑性樹脂成形体が、繊維を含む請求項1又は請求項2に記載の樹脂接合体。   The resin joined body according to claim 1, wherein the thermoplastic resin molded body includes a fiber. 前記熱可塑性樹脂部が、繊維を含む請求項1〜請求項3のいずれか1項に記載の樹脂接合体。   The resin joined body according to any one of claims 1 to 3, wherein the thermoplastic resin portion includes fibers. 前記熱硬化性樹脂成形体が、前記熱可塑性樹脂部を二つ以上有する請求項1〜請求項4のいずれか1項に記載の樹脂接合体。   The resin joined body according to any one of claims 1 to 4, wherein the thermosetting resin molded body has two or more of the thermoplastic resin portions. 熱可塑性樹脂成形体を準備する工程と、
表面の一部に露出して設けられた熱可塑性樹脂部を有する熱硬化性樹脂成形体を準備する工程と、
前記熱可塑性樹脂成形体と前記熱可塑性樹脂部とを溶着して、前記熱可塑性樹脂成形体と前記熱硬化性樹脂成形体とを接合する工程と、
を有する樹脂接合体の製造方法。
Preparing a thermoplastic resin molded body;
A step of preparing a thermosetting resin molded body having a thermoplastic resin portion exposed and provided on a part of the surface;
Welding the thermoplastic resin molded body and the thermoplastic resin portion, and joining the thermoplastic resin molded body and the thermosetting resin molded body;
The manufacturing method of the resin joined body which has this.
前記熱可塑性樹脂成形体が、繊維を含む請求項6に記載の樹脂接合体の製造方法。   The method for producing a resin joined body according to claim 6, wherein the thermoplastic resin molded body includes fibers. 前記熱可塑性樹脂部が、繊維を含む請求項6又は請求項7に記載の樹脂接合体の製造方法。   The method for producing a resin joined body according to claim 6 or 7, wherein the thermoplastic resin portion includes fibers. 前記熱硬化性樹脂成形体が、前記熱可塑性樹脂部を二つ以上有する請求項6〜請求項8のいずれか1項に記載の樹脂接合体の製造方法。   The method for producing a resin joined body according to any one of claims 6 to 8, wherein the thermosetting resin molded body has two or more of the thermoplastic resin portions. 前記熱可塑性樹脂部が、前記熱硬化性樹脂成形体に埋設されたアンカー部と、前記熱硬化性樹脂成形体の表面の一部に露出し前記熱可塑性樹脂成形体と溶着される接合部と、前記アンカー部と前記接合部とを連結する連結部とを有する請求項6〜請求項9のいずれか1項に記載の樹脂接合体の製造方法。   The thermoplastic resin portion is an anchor portion embedded in the thermosetting resin molded body, and a joint portion exposed to a part of the surface of the thermosetting resin molded body and welded to the thermoplastic resin molded body. The manufacturing method of the resin joined body of any one of Claims 6-9 which has a connection part which connects the said anchor part and the said junction part. 前記熱可塑性樹脂部が、前記熱硬化性樹脂成形体に埋設されたアンカー部と、前記アンカー部から前記熱硬化性樹脂成形体の表面に向けて前記表面から突出するように設けられた突出部とを有する請求項6〜請求項9のいずれか1項に記載の樹脂接合体の製造方法。   The thermoplastic resin portion has an anchor portion embedded in the thermosetting resin molded body, and a protruding portion provided so as to protrude from the surface toward the surface of the thermosetting resin molded body from the anchor portion. The manufacturing method of the resin joined body of any one of Claims 6-9 which has these. 前記熱硬化性樹脂成形体の表面の前記熱可塑性樹脂部の露出した部分の周囲に、溝部が設けられている請求項6〜請求項11のいずれか1項に記載の樹脂接合体の製造方法。   The manufacturing method of the resin joined body of any one of Claims 6-11 in which the groove part is provided in the circumference | surroundings of the exposed part of the said thermoplastic resin part of the surface of the said thermosetting resin molding. . 請求項1〜請求項5のいずれか1項に記載の樹脂接合体を有する車両用構造体。   The vehicle structure which has the resin joined body of any one of Claims 1-5.
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