JP2016174590A - Delayed coagulant for soybean curd using thickening polysaccharide and manufacturing method thereof - Google Patents

Delayed coagulant for soybean curd using thickening polysaccharide and manufacturing method thereof Download PDF

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JP2016174590A
JP2016174590A JP2015078037A JP2015078037A JP2016174590A JP 2016174590 A JP2016174590 A JP 2016174590A JP 2015078037 A JP2015078037 A JP 2015078037A JP 2015078037 A JP2015078037 A JP 2015078037A JP 2016174590 A JP2016174590 A JP 2016174590A
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coagulant
magnesium chloride
delayed
tofu
bitterness
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民男 小林
Tamio Kobayashi
民男 小林
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BIITEIN KENKYUSHO KK
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Abstract

PROBLEM TO BE SOLVED: To provide a coagulant easy to dispersion mix high temperature soybean curd mainly containing magnesium chloride with high temperature soybean curd without using oil and fat or an emulsifier and capable of achieving a solidification treatment with delayed effect property.SOLUTION: There is provided a delayed coagulant for soybean curd adding moderate viscosity obtained by mixing (a) bittern (a solution of magnesium chloride or crude sea water magnesium chloride) and (b) thickening polysaccharides. There is provided a delayed coagulant for soybean curd, by adding and dissolving two kinds of thickening polysaccharides which are psyllium seed gum of 0.01 o 0.5 wt.% and dielane gum of 0.01 to 0.3 wt.% based on the bittern. There is provided a manufacturing method of the delayed coagulant for soybean curd having proper viscosity for delayed solidification treatment and a gelation reaction by properly dissolving and mixing the bittern and two kids of thickening polysaccharides.SELECTED DRAWING: None

Description

本発明は、苦り(塩化マグネシウム又は粗製海水塩化マグネシウム溶液)を主成分とした凝固剤を豆乳に添加して、豆腐を製造する豆腐用凝固剤の製造方法に関するものであり、豆乳への分散混合が容易で、凝固反応が充分遅延性(遅延作用効果)を発揮する凝固剤を開発することで、滑らかで弾力性に優れ、風味も良好となる豆腐のできる凝固剤の製造方法を提供するものである。The present invention relates to a method for producing a coagulant for tofu by adding a coagulant based on bitterness (magnesium chloride or a crude seawater magnesium chloride solution) to soy milk, and producing the tofu. Dispersion in soy milk Provided is a method for producing a coagulant capable of producing tofu that is easy to mix and has a smooth coagulation reaction that exhibits a sufficient delay (effect of delaying action), which is smooth, excellent in elasticity and good in flavor. Is.

豆腐用凝固剤の苦り(塩化マグネシウム又は粗製海水塩化マグネシウム溶液)を用いて、特に高温豆乳から豆腐を作る場合、その凝固反応が速く、均質で安定した豆腐を作ることは至って困難であった。
そこで速効性の凝固反応を生ずる主成分の塩化マグネシウムの含有量の比率低下させ、遅延性凝固剤の硫酸カルシウム、硫酸マグネシウム等との複合剤としたりして使用していた。しかし、それは遅効性凝固剤が増えれば増えるほど、風味ある豆腐とはならないものであった。
特に、最近開発されたもので、塩化マグネシウム又は粗製海水塩化マグネシュウム水溶液を油脂及び多量の、多種類の乳化剤を添加させて乳化させ、塩化マグネシウムをコーテングしたり、更には、塩化マグネシウムをグリセリン脂肪酸エステル等に分散させ、多段階及び多様な加工を加え、ペースト状に近いものとして、本来の苦りとは全く似つかわしくない物性をもったものとなっている。
この様に、油脂及び乳化剤等を使用して、凝固反応を遅効性にさせることによって上記の問題を解決した乳化凝固剤が市販されている。
しかし、これは本来の苦り(塩化マグネシュウム又は粗製海水塩化マグネシュウム溶液)とはかけ離れたもので、苦りから作られた豆腐とは味も物性も離反したもので、大豆の風味も味もほとんど感じられないものであるばかりか、油脂、乳化剤の味がする。そして、これは余分なカロリーの摂取にもつながり、更には豆腐消費者の種々なる食品添加物使用の嫌悪意識にも答えていない。
Especially when making tofu from high-temperature soymilk using the bitterness of the coagulant for tofu (magnesium chloride or crude seawater magnesium chloride solution), it was extremely difficult to make a homogeneous and stable tofu with a fast coagulation reaction. .
Therefore, the ratio of the content of the main component magnesium chloride that causes a fast-acting coagulation reaction is reduced and used as a composite agent with a delayed coagulant such as calcium sulfate or magnesium sulfate. However, the more the slow-acting coagulant, the less the flavored tofu.
In particular, recently developed, magnesium chloride or crude seawater magnesium chloride aqueous solution is emulsified with fat and a large amount of various emulsifiers added to coat magnesium chloride, and magnesium chloride is glycerin fatty acid ester. As a paste-like material, it has physical properties that do not resemble the original bitterness.
Thus, the emulsification coagulant which solved the above-mentioned problem by making oil coagulation reaction slow action using fats and oils, an emulsifier, etc. is marketed.
However, this is far from the original bitterness (magnesium chloride or crude seawater magnesium chloride solution), and the tofu made from bitterness is far from the taste and physical properties, and the taste and taste of soybeans are almost the same. Not only can it be felt, it tastes like fats and oils and emulsifiers. And this leads to excessive calorie intake, and furthermore, it does not answer tofu consumers' disgust of using various food additives.

特開2008−154526JP 2008-154526 A 特開2008−61542JP2008-61542 特開2008−295381JP2008-295381 特開2010−94066JP 2010-94066 特開2011−45366JP2011-45366 特開2011−155918JP2011-155918A 特開2011−130760JP2011-130760 特開2011−45366JP2011-45366 特開2014−117160JP 2014-117160 A

前述したように、塩化マグネシュウム、粗製海水塩化マグネシュウムに、油脂、乳化剤を使用して造る乳化凝固剤においては、凝固剤の乳化物を豆乳中に細かく混合分散させる為、大きな分散剪断力を必要としていた。そしてグリセリン脂肪酸エステル等合成系の乳化剤を使用した場合は豆腐の風味は感じられなく、合成系乳化剤特有の風味が在るとする指摘もあり、品質面での改善が望まれていた。As mentioned above, in the emulsion coagulant made by using fats and oils and emulsifiers in magnesium chloride and crude seawater magnesium chloride, a large dispersion shear force is required to finely mix and disperse the emulsion of the coagulant in soy milk. It was. When a synthetic emulsifier such as glycerin fatty acid ester is used, the taste of tofu is not felt, and there is an indication that there is a flavor peculiar to the synthetic emulsifier, and improvement in quality has been desired.

豆腐は、伝統食品として今まで、広く愛用されてきた食品の一つである。従来の豆腐製造は大豆から分離した豆乳に、苦り、塩化マグネシウム、硫酸カルシム、グルコノデーターラクトン(GDL)等の凝固剤を単独又は混合して凝固させて後、これを熟成させる方法が採られてきた。
その中で、品質面で優れた苦り(塩化マグネシュウム、粗製海水塩化マグネシュウム)が使われて来た経緯がある。これは苦りの主成分である塩化マグネシュウムによって、大豆の風味を生かした、にがり特有の物性を演出することで知られているものである。
Tofu is one of the foods that has been widely used as a traditional food. Conventional tofu production is a method in which soy milk separated from soybeans is bittered and coagulated with a coagulant such as magnesium chloride, calcium sulfate, gluconodata lactone (GDL) alone or mixed, and then aged. Has been.
Among them, there is a background that bitterness superior in quality (magnesium chloride, crude seawater magnesium chloride) has been used. This is known to produce physical properties peculiar to bittern, utilizing the flavor of soybeans, with magnesium chloride, which is the main component of bitterness.

豆腐の凝固剤には遅効性凝固剤と速効性凝固剤があり、遅効性凝固剤は、高温豆乳(75〜95℃)に添加した際、豆乳蛋白質との凝固反応速度が遅く、約5秒〜60秒以内に凝固反応するもので、硫酸カルシウム、GDL等がそれにあたる。
この様な遅効性凝固剤はその反応速度が遅い為に、保水性は良い豆腐となり得るが、風味の良い豆腐とはならないという短所があった。
The tofu coagulant has a slow-acting coagulant and a fast-acting coagulant. When added to high-temperature soymilk (75-95 ° C.), the slow-acting coagulant has a slow coagulation reaction rate with soy milk protein, about 5 seconds. Coagulation reaction occurs within -60 seconds, and calcium sulfate, GDL and the like correspond to it.
Since such a slow-acting coagulant has a slow reaction rate, the water retention can be good tofu, but there is a disadvantage that it does not become a savory tofu.

速効性凝固剤は高温豆乳(75℃〜95℃)に添加した際、約1〜2秒に凝固反応を始める反応速度の速い凝固剤で、苦り、塩化マグネシウム、粗製海水塩化マグネシウム、塩化カルシウム等がこれにあたる。
塩化マグネシウムを主成分とする苦り、塩化マグネシュウム、粗製海水塩化マグネシュウムは豆腐の風味をよくする長所がある。
又最近では本剤のマグネシウム成分がミネラル成分と認識され評価されてきている。
The fast-acting coagulant is a coagulant with a high reaction rate that starts a coagulation reaction in about 1-2 seconds when added to high-temperature soymilk (75 ° C to 95 ° C). Bitter, magnesium chloride, crude seawater magnesium chloride, calcium chloride Etc. correspond to this.
Bitterness mainly composed of magnesium chloride, magnesium chloride, and crude seawater magnesium chloride have the advantage of improving the flavor of tofu.
Recently, the magnesium component of this drug has been recognized and evaluated as a mineral component.

しかし、この様な速効性凝固剤を使用して豆腐を作る場合、凝固反応が著しく速く、出来あがった豆腐は保水性、弾力性、食感、歩留まり等で劣るものとなり易い。
これを改善するために従前は、熟練された技術者が行っていたがそれも充分なものとは言えず、あらためて技術的解決が求められていた。
However, when such a fast-acting coagulant is used to produce tofu, the coagulation reaction is extremely fast, and the resulting tofu tends to be inferior in water retention, elasticity, texture, yield, and the like.
In order to improve this, a skilled engineer used to do this, but it was not enough, and a technical solution was required again.

本発明の課題は、油脂、乳化剤を使用しなで、塩化マグネシュウム主体の凝固剤が高温豆乳への分散混合が容易であって、且つ遅効性のある凝固反応を達成出来る凝固剤を開発し、本凝固剤による豆腐は、風味、保水性、弾力性、食感、歩留等が良好で、又豆腐製造が連続的に出来るようにする、凝固剤を造るという点にある。The object of the present invention is to develop a coagulant that can achieve a slow-acting coagulation reaction, in which the coagulant mainly composed of magnesium chloride is easy to disperse and mix in high-temperature soy milk, without using fats and oils and emulsifiers, The tofu produced by the present coagulant is excellent in flavor, water retention, elasticity, texture, yield and the like, and is in the point of producing a coagulant that enables continuous production of tofu.

上記課題を解決すべく、二種の増粘多糖類を溶解させて、それに塩化マグネシュウム又は粗製海水塩化マグネシュウムを加え、均質に混合溶解させて豆腐用凝固剤液を得る。当該凝固剤液を高温豆乳に添加、凝固反応させる場合でも、凝固反応は充分遅延化されていて、豆腐の内部組織も均質である豆腐用凝固剤を提供するものである。In order to solve the above problems, two kinds of thickening polysaccharides are dissolved, and magnesium chloride or crude seawater magnesium chloride is added thereto and mixed and dissolved homogeneously to obtain a coagulant solution for tofu. Even when the coagulant solution is added to a high-temperature soymilk to cause a coagulation reaction, the coagulation reaction is sufficiently delayed, and the coagulant for tofu is provided in which the internal structure of the tofu is homogeneous.

本発明の粘性を付与した遅延凝固剤を使用する事により、特別な技術を必要とすることなく、凝固が遅延化するために、豆腐の内層が均質となって、離水しないばかりか、
弾力性、保水性もある風味豊かな豆腐を作ることが出来る。
By using the delayed coagulant imparted with the viscosity of the present invention, coagulation is delayed without the need for special techniques.
Flavorful tofu with elasticity and water retention can be made.

本発明に用いられる、塩化マグネシウム、粗製海水塩化マグネシウム、苦り、は海水から塩化カリウム及び塩化ナトリウム等を析出、分離して得られるものであれば良く、固形化されたものが望ましく、固形の塩化マグネシウム又は粗製海水塩化マグネシュウムであればよい。勿論液体の苦りでも差支えない。
更に、それにミネラルがバランス良く含有されていることが望ましい。
Magnesium chloride, crude seawater magnesium chloride, bitterness used in the present invention may be any one obtained by precipitating and separating potassium chloride, sodium chloride, etc. from seawater, preferably solidified, solid Magnesium chloride or crude seawater magnesium chloride may be used. Of course, the bitterness of the liquid is acceptable.
Further, it is desirable that minerals are contained in a balanced manner.

本凝固剤に用いられる増粘多糖類は、高分子多糖類で適当な粘性を持ち合わせなければならない。又それ自体ゲル化能も持ち合わせる特性をもっている多糖類が望ましい。
上記増粘多糖類とはサイリウムシードガムと並びに、ジュランガムである。
The thickening polysaccharide used in the present coagulant must be a high molecular weight polysaccharide with an appropriate viscosity. Moreover, the polysaccharide which has the characteristic which has gelling ability itself is desirable.
The thickening polysaccharide is psyllium seed gum and duran gum.

サイリウムシードガムは、植物の種子から採った天然植物ガムで、酸性ポリサッカライドと中性ポリサッカライドの混合物といわれている。粘性もある程度持ち合わせているが、
それ自体強いゲル化能力を持ち合わせている。
Psyllium seed gum is a natural plant gum taken from plant seeds, and is said to be a mixture of acidic and neutral polysaccharides. Although it has some viscosity,
It has a strong gelling ability.

ジュランガムは微生物の産生した多糖類で、粘性を適当に持ち合わせている。
直鎖状のヘテロ多糖類で、グルコース、グルクロン酸、グルコース、ラムノースの4糖の繰返し単位から構成されている。
それ自体強いゲル化能力も持ち合わせている。
Dulan gum is a polysaccharide produced by microorganisms and has an appropriate viscosity.
It is a linear heteropolysaccharide composed of repeating units of tetrasaccharides of glucose, glucuronic acid, glucose, and rhamnose.
It also has strong gelling ability.

本増粘多糖類二種は何れも溶解して使用する。両者とも溶解する際、“だま”になり易いので丁寧な溶解が必要である。完璧なる溶解を期すために、加熱して均質化を計る。
粘性が出れば良いというものではなく、適度な粘性で、苦りをコーテングすれば良い。
本コーティングは苦りと豆乳の速効反応を一次的に阻止し、程よい遅延効果が出れば良い。
そして、この増粘多糖類は豆腐の中に入り込むので、それ自体ゲル化しないと固まった豆腐がその後の時間経過で組織崩壊を起こす。
These two thickening polysaccharides are used after being dissolved. Careful dissolution is required because both tend to be “dull” when dissolved. Heat to homogenize for complete dissolution.
It doesn't mean that it should be viscous, but it should be coated with bitterness with moderate viscosity.
The coating should be able to prevent the bitterness and soymilk's fast-acting reaction temporarily and provide a moderate delay effect.
And since this thickening polysaccharide penetrates into tofu, if it does not gel by itself, then the tofu that has hardened will undergo tissue collapse over time.

増粘多糖類の苦りへの添加比率は固形物換算で0.4重量%以下であり、好ましくは0.15重量%で、そして、サイリュームシードガムとジュランガム比率は10:3が好ましい。The addition ratio of the thickening polysaccharide to bitterness is 0.4% by weight or less, preferably 0.15% by weight in terms of solid matter, and the ratio of silium seed gum to duran gum is preferably 10: 3.

上記のように溶解した増粘多糖類溶液100重量に塩化マグネシウム又は粗製海水マグネシウムを約30g入れ溶解する。
溶解させた増粘多糖類と塩化マグネシュウム、粗製海水塩化マグネシュウムは均質に溶解させる。
その結果、粘性のある塩化マグネシュウム溶液又は粗製海水塩化マグネシュウム溶液が出来る。これが遅延苦りである。これを用いて、高温豆乳から、内層の荒れない、風味のある苦り豆腐を簡単に作ることが出来る。
About 100 g of magnesium chloride or crude magnesium seawater is dissolved in 100 weight parts of the thickened polysaccharide solution dissolved as described above.
The dissolved thickening polysaccharide, magnesium chloride, and crude seawater magnesium chloride are uniformly dissolved.
The result is a viscous magnesium chloride solution or a crude seawater magnesium chloride solution. This is a bitter delay. Using this, it is possible to easily make a bitter tofu with a flavor that does not roughen the inner layer from hot soymilk.

増粘多糖類液の作り方
清水1000ml用意し、増粘多糖類のサイリュームシードガム1.5g用意する。
又増粘多糖類のジュランガムは0.46g計量し、
両者を一緒に混合して溶解する。非常に“だま”になり易い性質を持っているので、良く撹拌しながら溶解する。
この溶解が不十分なれば、その効果を充分発揮できないので、加温して溶解の完全を期す。
How to make a thickening polysaccharide solution Prepare 1000 ml of fresh water and 1.5 g of silium seed gum of thickening polysaccharide.
Also, 0.46 g of thickening polysaccharide dulan gum is weighed,
Both are mixed together and dissolved. Because it has the property of being very “dull”, it dissolves with good stirring.
If this dissolution is inadequate, the effect cannot be fully exhibited, and heating is performed to ensure complete dissolution.

苦り液の作り方
この二増粘多糖類の完全なる溶解した液に、塩化マグネシュウム、又は粗製海水塩化マグネシュウムを32重量%になるように、又食塩を2.4重量%になるように計量し溶解する。4者が良く混ざるよう丁寧に撹拌溶解する。
完全溶解させたものは粘度が8.0mP・sなる遅延凝固苦りである。
How to make a bitter liquid To a solution in which the bi-thickened polysaccharide is completely dissolved, weigh magnesium chloride or crude seawater magnesium chloride to 32% by weight and salt to 2.4% by weight. Dissolve. Gently stir and dissolve so that the four can mix well.
What was completely dissolved is a delayed solidification bitterness with a viscosity of 8.0 mP · s.

出来上がった苦りは適当な遅延性をもったもので、高温豆乳に添加した際、豆乳蛋白との反応は16秒を要した。The finished bitterness had an appropriate delay, and when added to hot soymilk, the reaction with soymilk protein took 16 seconds.

木綿豆腐の製造
常法により型箱(350mm×360mm×150mm)を用意し、凝固桶に豆乳(Brix12.0、温度82℃)13Lを投入し、上記実施例1で得られた遅延苦りを125ml加え、16秒撹拌する。この凝固剤と豆乳の混合されたゾル状物質を20〜30分間静置するとゲル状物質となる。経過後、ゲル状となったものを型箱に移し、均し平均化する。次にプレスで脱水する。
出来上がったものが、木綿豆腐である。
定番の300gサイズ(105mm×70mm×45mm)に切り、水に約30分晒す。
これで豆腐工程は完了する。その後、パック詰め7℃以下で冷蔵保管して、試料とした。
A mold box (350 mm × 360 mm × 150 mm) is prepared by a conventional method of manufacturing cotton tofu, and 13 L of soy milk (Brix 12.0, temperature 82 ° C.) is put into the coagulated rice cake, and the delayed bitterness obtained in Example 1 above is applied. Add 125 ml and stir for 16 seconds. When this sol-like substance mixed with the coagulant and soy milk is allowed to stand for 20 to 30 minutes, it becomes a gel-like substance. After the lapse of time, the gel-like product is transferred to a mold box and averaged. Next, it dehydrates with a press.
The finished product is cotton tofu.
Cut into a standard 300g size (105mm x 70mm x 45mm) and expose to water for about 30 minutes.
This completes the tofu process. Thereafter, the sample was refrigerated at 7 ° C. or lower in a pack and used as a sample.

豆腐の評価Evaluation of tofu

上記により得られた豆腐の内部組織の状態を含めた官能評価を表1に示す。
次の評価に従って基準10人ノパネラーで評価を実施した。

Figure 2016174590
Figure 2016174590
Table 1 shows the sensory evaluation including the state of the internal structure of the tofu obtained as described above.
Evaluation was carried out with a standard 10 panelist according to the following evaluation.
Figure 2016174590
Figure 2016174590

表2より明らかなように、本発明の増粘多糖類を使用して、粘度を付加させた遅延苦りで、豆腐作る際、内層が均質で、大豆本来の風味を醸し、旨味、甘味の良好なものが得られた。As can be seen from Table 2, the thickening polysaccharide of the present invention is used to delay the bitterness to which viscosity is added, and when making tofu, the inner layer is homogeneous and brings the original flavor of soybeans, umami and sweetness. A good one was obtained.

本発明は豆腐の作るための凝固剤製造する産業において利用される。The present invention is utilized in the industry of producing a coagulant for making tofu.

Claims (6)

(a)苦り(塩化マグネシュウム又は粗製海水塩化マグネシュウムの溶液)(b)増粘多糖類溶液を混合して得られる適度な粘性を付加することを特徴とする豆腐用凝固剤。(A) Bitter (magnesium chloride or crude seawater magnesium chloride solution) (b) A coagulant for tofu characterized by adding an appropriate viscosity obtained by mixing a thickening polysaccharide solution. (b)二種類の増粘多糖類を適度な割合で均質に溶解し、増粘化を計り、(a)苦り(塩化マグネシュウム又は粗製海水マグネシュウムの溶液)と併せ混合してなることを特徴とする請求項1の豆腐用凝固剤。(B) Two types of thickening polysaccharides are homogeneously dissolved at an appropriate ratio, thickened, and (a) mixed with bitterness (magnesium chloride or crude seawater magnesium solution). The coagulant for tofu according to claim 1. 二種類の増粘多糖類はサイリュームシードガムであり、苦り対し0.01〜0.5重量%、並びに、ジエランガムで、0.01〜0.3重量%の範囲で添加溶解することを特徴とする請求項1記載の豆腐用凝固剤。Two types of thickening polysaccharides are silium seed gums, 0.01 to 0.5% by weight for bitterness, and dielan gum, which are added and dissolved in the range of 0.01 to 0.3% by weight. The coagulant for tofu according to claim 1. 苦り(塩化マグネシュウム又は粗製海水塩化マグネシュウムの溶液)と二種類の増粘多糖類は何れも良く溶解され、 混合されて、適性なる遅延凝固反応する粘度、並びにゲル化反応を有する特徴をもった請求項1記載の豆腐用凝固剤の製造方法。Bitterness (magnesium chloride or crude seawater magnesium chloride solution) and two types of thickening polysaccharides are both well dissolved, mixed, and have the characteristic of having a suitable delayed solidification reaction and gelling reaction A method for producing a coagulant for tofu according to claim 1. 適性なる遅延凝固反応する苦りの粘度は1〜100mPa・sで、且つ、チキソトロピー性を有する特徴をもった請求項1記載の豆腐用凝固剤の製造方法。The method for producing a coagulant for tofu according to claim 1, wherein the suitable bitterness of delayed coagulation reaction is 1 to 100 mPa · s and has thixotropic properties. 適性なる粘度とゲル化性を有しているので、75℃以上の高温豆乳に対して、遅延凝固することを特徴とする請求項1の豆腐用凝固剤の製造方法。The method for producing a coagulant for tofu according to claim 1, wherein the coagulant for tofu according to claim 1, wherein the coagulant is delayed-coagulated with respect to high-temperature soy milk of 75 ° C or higher because it has suitable viscosity and gelling property.
JP2015078037A 2015-03-20 2015-03-20 Delayed coagulant for soybean curd using thickening polysaccharide and manufacturing method thereof Pending JP2016174590A (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112772845A (en) * 2019-10-22 2021-05-11 南京农业大学 Preparation and application of bean curd liquid acid sustained-release coagulant

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112772845A (en) * 2019-10-22 2021-05-11 南京农业大学 Preparation and application of bean curd liquid acid sustained-release coagulant

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