JP2016171777A - Production method of dried fish - Google Patents

Production method of dried fish Download PDF

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JP2016171777A
JP2016171777A JP2015053700A JP2015053700A JP2016171777A JP 2016171777 A JP2016171777 A JP 2016171777A JP 2015053700 A JP2015053700 A JP 2015053700A JP 2015053700 A JP2015053700 A JP 2015053700A JP 2016171777 A JP2016171777 A JP 2016171777A
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fish
drying
smoke
smoking
dried
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仁 朝田
Hitoshi Asada
仁 朝田
拓 浅山
Taku Asayama
拓 浅山
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Yamaki Co Ltd
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Yamaki Co Ltd
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Abstract

PROBLEM TO BE SOLVED: To develop a production method of dried fish in which drying and smoking are separated in the production method of the dried fish, and besides it is performed in a short time while performing smoking control, and thereby an aroma quality of the dried fish is maintained and the reduction of harmful components such as benzopyrene is possible, and the dried fish of high quality is provided.SOLUTION: When producing dried fish, the smoking/drying process of a conventional dried fish production method is completely separated into drying and smoking, and it is performed in a short time while controlling the smoking after the drying, and thereby the occurrence of harmful components such as benzopyrene is reduced while maintaining an original aroma quality of the dried fish. Specifically, the shaped and boil-ripened fish is subjected to hot-air drying until vitrified at the moisture content of 18% or less, and the fish after the drying is deposited of a smoking component in a short time by a commercial electronic smoke device. The smoking is generated by subjecting a plant material to incomplete combustion or thermal decomposition at 400°C or less, and furthermore the air flow of the smoking is controlled in the ratio of 0.01-0.03 m/second to a smoking chamber of approximately 0.3 m. Also, a high voltage of 10-15 kV is applied to the smoking to electrify the smoking, and thereby the adhesion to the dried/shaped fish is facilitated in a short time. According to the method of the present invention, the original aroma quality of the dried fish can be maintained, and the harmful components such as the benzopyrene can be reduced.SELECTED DRAWING: None

Description

本発明は、鰹節、宗田鰹節、さば節、あじ節などの魚節類の製造方法に関し、乾燥と燻煙を完全に分離し、乾燥方法と燻煙方法を制御することによって、魚節本来の好ましい燻香・スモークの風味を付与したうえで、ベンツピレン等の有害成分を安定的に低減することが可能な魚節類の製造方法に関する。   The present invention relates to a method for producing fish buns such as bonito, soda bonito, mackerel buns, and horse mackerel. By completely controlling the drying method and the smoking method, The present invention relates to a method for producing fish clauses capable of stably reducing harmful components such as benzpyrene after imparting a preferable savory and smoked flavor.

鰹節、宗田鰹節、さば節、あじ節などの魚節類は、料理に使う「だし」の風味原料として日本では古くから製造されてきている。これら魚節の従来からの一般的な製造方法は、魚の頭と内臓を取り除いて整形し、煮熟した後、焙乾あるいは燻乾と呼ばれる乾燥と燻付けを同時に行う工程により、魚を乾燥しながらナラ、クヌギなどの薪を燃やすことで燻煙を発生させ、独特の燻香を付与していく。この焙乾とあん蒸を7〜10日間繰り返して荒節ができあがる。この荒節の表面を削ったものが裸節で、裸節にカビ付けして日乾、カビ付けを繰り返したものが枯節である(非特許文献1参照)。   Fish buns such as bonito, soda bonito, mackerel buns, and hydrangea have long been produced in Japan as ingredients for flavoring “dashi” used in cooking. The conventional method for producing these fish sections is to remove the fish head and internal organs, shape and boil it, and then dry the fish by a process of drying and brazing at the same time called roasting or drying. While burning firewood such as oak and kunugi, smoke is generated and a unique musk is added. This roasting and fumigation is repeated for 7 to 10 days, resulting in rough knots. A material obtained by shaving the surface of the rough knot is a bare knot.

この魚節類の従来の製造工程における焙乾の目的は、魚を乾燥するとともに、ハム、ソーセージ、ベーコン、チーズなどの燻製食品と同様に独特の風味を付与するものであるが、燻煙にはきわめて多くの成分が含まれている。そのため、魚節を含めた燻製食品では燻煙成分と食品成分が焙乾工程中に成分変化を起こし、多環芳香族炭化水素類を生成する。この多環芳香族炭化水素類の中には、発がん性物質として知られているベンツピレンやジベンツアントラセンがあり、前記の燻製食品の中でも特にかつお節を始めとした魚節類には、ベンツピレンを始めとする多環芳香族炭化水素類の含有量が多い(非特許文献2参照)。   The purpose of roasting in the conventional manufacturing process of fish buns is to dry the fish and give it a unique flavor similar to smoked foods such as ham, sausage, bacon and cheese. Contains very many ingredients. For this reason, in smoked foods including fish sections, smoke components and food components undergo component changes during the roasting process, producing polycyclic aromatic hydrocarbons. Among these polycyclic aromatic hydrocarbons are benzpyrene and dibenzanthracene, which are known as carcinogens. Among the smoked foods mentioned above, especially bonito and other fish bonito include benzpyrene. The content of polycyclic aromatic hydrocarbons is large (see Non-Patent Document 2).

特に、従来の焙乾では薪あるいは木材を破砕したチップ等を完全、不完全燃焼あるいは熱分解することで燻煙を発生させるが、この燃焼、熱分解温度が425℃以上になるとベンツピレン等の有害成分が発生することも知られている(非特許文献3参照)。   In particular, conventional roasting generates smoke by completely or incompletely burning or thermally decomposing chips or crushed wood chips. However, if the combustion and thermal decomposition temperature exceeds 425 ° C, harmful substances such as benzpyrene are generated. It is also known that components are generated (see Non-Patent Document 3).

この魚節類にベンツピレンを始めとする多環芳香族炭化水素類の含有量が多い原因は、数ある燻製食品の中でも魚節類はハム、ソーセージ、ベーコンなどに比べて焙乾時間が著しく長く、さらには乾燥で飛散させるべき水分量が多いために、魚節に特異的に多環芳香族炭化水素類が増加しやすくなる。特にこの魚節類の製造工程では、焙乾工程における長時間の乾燥、燻付けによって魚体の水分を約20%以下まで乾燥させるが、乾燥時間が数日間と著しく長いために必然的に燻煙時間も長くなり、燻煙成分と魚体中成分の反応の時間も長くなりベンツピレンなどの多環芳香族炭化水素類の生成が多くなる。   The reason for the high content of benzopyrene and other polycyclic aromatic hydrocarbons in this fish bun is that among the many smoked foods, fish buns have a significantly longer drying time than ham, sausage, bacon, etc. In addition, since the amount of moisture to be scattered by drying is large, polycyclic aromatic hydrocarbons are likely to increase specifically in fish sections. In particular, in the manufacturing process of this fish clause, the moisture of the fish body is dried to about 20% or less by prolonged drying and brazing in the roasting process. The time becomes longer, the reaction time of the smoke component and the components in the fish body becomes longer, and the production of polycyclic aromatic hydrocarbons such as benzpyrene increases.

特に、こうした魚節類の多環芳香族炭化水素類の含有量は、鰹節の削り節ではベンツピレンとして4.4〜39ppb(平均19ppb)(質量に基づく)であり、かつお荒節の表面削り粉に含まれるベンツピレン含有量は、99〜140ppb(平均120ppb)となっており加工食品の中でも魚節関係には、特に多環芳香族炭化水素類が多い。(非特許文献4参照)
そのため、魚節類を含めた燻製食品において、製造工程中で生成する多環芳香族炭化水素類を低減させる試みは様々に行われてきている。この魚節を含めた燻製食品におけるベンツピレンなどの多環芳香族炭化水素類の低減の基本的な考え方としては、以下のようになる。
In particular, the content of polycyclic aromatic hydrocarbons in these fish knots is 4.4-39 ppb (average 19 ppb) (based on mass) as benzpyrene in the knots of bonito, and in the surface shavings of rough knots. The content of benzpyrene contained is 99 to 140 ppb (average 120 ppb), and among processed foods, there are many polycyclic aromatic hydrocarbons especially in relation to fish sections. (See Non-Patent Document 4)
Therefore, various attempts have been made to reduce polycyclic aromatic hydrocarbons produced during the manufacturing process in smoked foods including fish buns. The basic idea for reducing polycyclic aromatic hydrocarbons such as benzpyrene in smoked foods including fish sections is as follows.

まず、焙乾の時間を短くする。すなわち、乾燥と燻煙を同時に行う焙乾時間が長いことが、多環芳香族炭化水素類の生成を増加させることになるためである。特に、燻煙時間を短くすることが燻煙成分と魚体中成分の反応を減少させ、多環芳香族炭化水素類の生成を抑制することにつながる。さらに、乾燥と燻煙の工程を分けることで、燻煙の時間を短くすることもできる。
次に、この燻煙工程における薪の燃焼温度あるいは熱分解温度を多環芳香族炭化水素類の発生しにくい425℃以下にする。この燃焼、熱分解温度さらには燻煙の発生温度、燻煙自身の温度を制御することで、多環芳香族炭化水素を生成しにくくすることになる。さらに、燻煙工程においては燻煙が魚節に物理的に付着しないようにする方法も考えられる。こうした基本的な考えを基にして、魚節などの燻製食品の多環芳香族炭化水素類を低減する様々な技術が紹介されている。
First, the drying time is shortened. That is, it is because the long drying time which performs drying and smoke at the same time will increase the production of polycyclic aromatic hydrocarbons. In particular, shortening the soot time reduces the reaction between the soot component and the components in the fish body, leading to the suppression of the production of polycyclic aromatic hydrocarbons. Furthermore, the time of soot can be shortened by separating the processes of drying and soot.
Next, the combustion temperature or thermal decomposition temperature of the soot in this soot process is set to 425 ° C. or less where polycyclic aromatic hydrocarbons are hardly generated. By controlling the combustion, thermal decomposition temperature, the soot generation temperature, and the temperature of the soot itself, it becomes difficult to produce polycyclic aromatic hydrocarbons. Further, in the soot process, a method for preventing soot from physically adhering to the fish section is also conceivable. Based on these basic ideas, various technologies for reducing polycyclic aromatic hydrocarbons in smoked foods such as fish salmon have been introduced.

この多環芳香族炭化水素類を低減させる魚節の製造方法としては、植物原料を燃焼、不完全燃焼又は熱分解して燻煙を発生させる工程と、その燻煙を2次加熱装置により加熱する工程とを含み、さらにその加熱温度が300℃以上、800℃未満である製造方法が提案されている(特許文献1参照)。
この製造方法によれば、燻煙を2次加熱装置により300℃から800℃の間で制御し、魚節の熱風乾燥も乾燥開始時の140℃以上から終了時の120℃未満と連続あるいは段階的低下を行い、さらには燻煙雰囲気を25℃以上100℃以下で風速0.5m/秒での制御によって、魚節に含まれるベンツピレンが20ppb以下に低減できるとされている。
As a method for producing fish salmon that reduces the polycyclic aromatic hydrocarbons, a process of generating soot by burning, incomplete combustion or thermal decomposition of plant raw materials, and heating the soot with a secondary heating device And a heating method whose temperature is 300 ° C. or higher and lower than 800 ° C. has been proposed (see Patent Document 1).
According to this manufacturing method, the smoke is controlled between 300 ° C. and 800 ° C. by the secondary heating device, and the hot air drying of the fish knot is continuously or stepwise from 140 ° C. or more at the start of drying to less than 120 ° C. at the end In addition, it is said that benzpyrene contained in fish sections can be reduced to 20 ppb or less by controlling the smoke atmosphere at 25 ° C. to 100 ° C. and a wind speed of 0.5 m / sec.

また、他には魚節用原料魚を煮熟する工程と、煮熟済み節用原料魚に対し燻煙を接触させる工程とを含み、その燻煙が燻材から煙が発生する温度以上425℃未満の温度範囲により燻材を不完全燃焼させて、かつその煮熟済み節用原料魚に対し燻煙を接触させる工程が、煮熟済み節用原料魚を不織布により覆ってから実施され、煮熟済み節用原料魚を乾燥する工程後に、この節用原料魚に対して5kV〜15kVの直流または交流電圧を印加しつつ、425℃未満の温度範囲により、燻材を不完全燃焼させて発生させた燻煙を接触させる魚節の製造方法も提案されている(特許文献2参照)。
この魚節の製造方法では、ベンツピレンの含有量を10ppb以下にまで低減できるとされている。
In addition, the process includes a step of simmering the fish for raw fish and a step for bringing smoked smoke into contact with the savory raw fish for seasoning, and the smoke is higher than the temperature at which smoke is generated from the firewood and less than 425 ° C. The process of incompletely burning the firewood in the temperature range and bringing the smoked smoked raw material fish into contact with the smoked fish is carried out after the cooked raw fish is covered with a non-woven fabric. After the step of drying the raw fish, smoke generated by incomplete combustion of the firewood in a temperature range of less than 425 ° C. while applying a DC or AC voltage of 5 kV to 15 kV to the raw fish for saving A method for producing fish clauses to be contacted has also been proposed (see Patent Document 2).
In this method for producing fish salmon, the content of benzpyrene can be reduced to 10 ppb or less.

さらに、多環芳香族炭化水素類を低減させる魚節の製造方法としては、煮熟した魚を遠赤外線照射による加熱で従来の焙乾時間に比べて比較的短い時間で乾燥した裸節、もしくは煮熟後の魚を焙乾した後に遠赤外線照射で乾燥を実施した荒節の製造方法がある。これらは焙乾および乾燥の時間が従来方法よりも短いことでベンツピレン含有量が少ないとされている(特許文献3参照)。   Furthermore, as a method for producing fish buns that reduce polycyclic aromatic hydrocarbons, naked bonito dried in a relatively short time compared to conventional roasting time by heating by irradiating far-infrared fish, or There is a method for producing rough knots in which dried fish are dried by irradiation with far-infrared rays after roasting the fish after cooking. These are said to have a low benzpyrene content because the drying and drying times are shorter than those of conventional methods (see Patent Document 3).

この遠赤外線による乾燥方法では、従来、一般的に行われている魚節の焙乾工程の時間が数日間であることを考えると、実施例では48〜96時間と短い乾燥あるいは焙乾時間であるために、燻煙成分と魚体中成分の反応の時間が短くなり、従来の魚節の製法よりもベンツピレンの生成は減少すると考えられる。   In this drying method using far-infrared rays, considering the fact that the time for the conventional drying process of fish buns is several days, in the examples, the drying time is as short as 48 to 96 hours or the drying time. For this reason, the reaction time between the smoke component and the components in the fish body is shortened, and it is considered that the production of benzpyrene is reduced as compared with the conventional method for producing fish sections.

「塩辛・くさや・かつお節」、藤井建夫 著、恒星社厚生閣、p.100−103“Salty, Kusaya, Katsuo-bushi”, written by Takeo Fujii, Hoshiseisha Koseikaku, p. 100-103 「くん製食品」、太田静行 著、恒星社厚生閣、p.178−179“Kunsei Foods”, written by Ota Shizuyuki, Hoshiseisha Koseikaku, p. 178-179 「スモーク食品」、太田静行、他、恒星社厚生閣、p.139−143“Smoked Food”, Shizuyuki Ota, et al., Hoshiseisha Koseikaku, p. 139-143 「有害化学物質含有実態調査結果データ集(平成23〜24年度)」、農林水産省、p.83〜90“Hazardous chemical substance content survey results data collection (2011-2012)”, Ministry of Agriculture, Forestry and Fisheries, p. 83-90 「かつお節」、和田俊 著、幸書房、p.33−35“Katsuo-bushi”, Shun Wada, Koshobo, p. 33-35

特許第5195423号公報Japanese Patent No. 5195423 特開2011−250735号公報JP 2011-250735 A 特開2002−058420号公報JP 2002-058420 A

魚節のように薪や木材チップを燃焼させて、乾燥と燻付けを同時に行う場合は、燻香・スモーク風味が付与されつつ乾燥による水分低減でそれらの濃縮も平行して発生するという現象となる。この現象が有害成分のベンツピレンの生成と濃縮にもつながっていることは明白である。すなわち、従来からの伝統的な魚節の製造方法自体が燻香・スモーク風味の付与とともに、ベンツピレン含有量が高濃度になる原因でもある。このことは、魚節への燻香・スモーク風味の付与とベンツピレン含有量の増加は比例していることを示している。   When burning salmon and wood chips like fish buns and drying and brazing at the same time, a concentration of musk and smoked flavor is added, and moisture concentration due to drying also occurs in parallel. Become. It is clear that this phenomenon also leads to the formation and concentration of the harmful component benzpyrene. In other words, the traditional traditional method for producing fish buns itself is not only the addition of musk and smoked flavor, but also the cause of the high concentration of benzpyrene. This indicates that the aroma and smoke flavor imparted to the fish section is proportional to the increase in benzpyrene content.

さらに、魚節の生産者は焼津市や枕崎市などの地域に集中するとともに、資本力の乏しい個人事業者、中小企業が多いことも特徴である。このことは、魚節への燻香・スモーク風味付与とベンツピレン含有量増加の課題に対して過大な設備投資による解決では、実質的な産業上の有効性に結びつかないことを意味している。   In addition, fish salmon producers are concentrated in areas such as Yaizu City and Makurazaki City, and are characterized by a large number of private businesses and small and medium-sized enterprises with limited capital. This means that the solution by excessive capital investment to the problem of imparting the aroma and smoke flavor to the fish section and increasing the content of benzpyrene does not lead to substantial industrial effectiveness.

そのため、従来からの魚節製造方法を大きく変えることなく、特許文献1、2、3などのようにまず薪や木材チップを不完全燃焼させて燃焼方法、燃焼温度を変えて燻煙の発生温度、発生方法を制御することが試みられている。この方法ではベンツピレン含有量は、薪や木材チップの燃焼方法、燃焼温度を制御しない場合に比べると若干の低減効果はあるが、制御方法が困難であることと薪の不完全燃焼によって燻香・スモーク風味までが変わってしまい品質的な差異も生まれてしまうことになる。   Therefore, without significantly changing the traditional fish bun manufacturing method, as in Patent Documents 1, 2, 3, etc., first, incompletely burning firewood and wood chips, changing the combustion method, the combustion temperature, and the generation temperature of soot Attempts have been made to control the generation method. In this method, the content of benzpyrene is slightly reduced compared to the method of burning soot and wood chips, and the case where the combustion temperature is not controlled, but the control method is difficult and the incomplete combustion of soot causes incense and The smoked flavor will change, resulting in quality differences.

そこで、さらに特許文献1のように燻煙生成の温度、燻煙自身の温度、さらには乾燥時間とその温度を制御することにまで踏み込んで、ベンツピレンの生成を抑制し、先に挙げた多環芳香族炭化水素類の低減の基本的な考え方において、燻煙発生温度と燻煙自身の温度を設備機械あるいは装置によって制御する方法が考えられた。この設備機械と方法は、非常に理想的な設備機械あるいは装置での製造方法であるが、その分、それらの設備機械、装置は高額なものにならざるをえない。
実際に、日本における鰹節を含めた魚節の生産者の多くが個人事業体であり、企業体として資本力を持った魚節の生産者が限られてくることを鑑みると、資本力のあるごく一部の生産者しか活用できない限定的な製造方法であると言える。
Therefore, as described in Patent Document 1, the temperature of soot generation, the temperature of the soot itself, and further the control of the drying time and its temperature are suppressed to suppress the generation of benzpyrene, and the polycyclic ring mentioned above In the basic idea of reducing aromatic hydrocarbons, a method of controlling the soot generation temperature and the temperature of soot itself with an equipment machine or device has been considered. Although this equipment machine and method is a manufacturing method using a very ideal equipment machine or apparatus, the equipment machine and apparatus are inevitably expensive.
In fact, most of the fish salmon producers, including bonito in Japan, are private entities, and given the limited number of fish salmon producers with capital as a corporate entity, they have capital It can be said that this is a limited manufacturing method that can be used by only a few producers.

また、特許文献2のように燻煙の発生温度範囲を425℃未満にし、さらに煮熟済み節用原料魚を不織布で覆うことで物理的に燻煙の接触を減らす方法もある。特に、煮熟済み節用原料魚に対して5kV〜15kVの電圧を印加することで燻煙との接触時間をより短時間で行う考え方でもある。   Moreover, there exists a method of reducing the contact of smoke so that the generation temperature range of smoke is less than 425 degreeC like patent document 2, and also the cooked raw material fish for knots is covered with a nonwoven fabric. In particular, it is also an idea of applying a voltage of 5 kV to 15 kV to the boiled and seasoned raw material fish so that the contact time with the smoke is shorter.

この方法は、燻煙における薪の燃焼、不完全燃焼または熱分解の温度を425℃未満に制御するために、密閉容器内への吹込み空気量の調整による炎の肉眼観察と熱電対での温度測定によって行っており、実際の制御方法としてはかなりの熟練を要する必要があるとともに、その再現性にも課題が残る。さらに、焙乾は煮熟した魚を個々に不織布で包装してから行うために、実際の魚節の製造においては膨大な手間がかかり生産性が大きく低減し、産業上の有効性にも疑問が残る。また、その出来上がった魚節はベンツピレンを含めた多環芳香族炭化水素類だけでなく、燻製食品に関係の深い風味成分であるグアヤコール、フェノール、メチルフルフラール等の燻煙成分までも付着が少なくなり、燻製食品としての魚節の官能評価イメージとは大きくかけ離れてしまっている課題がある。   In this method, in order to control the temperature of soot burning, incomplete combustion, or thermal decomposition in soot to less than 425 ° C, the flame is visually observed and the thermocouple is adjusted by adjusting the amount of air blown into the sealed container. It is performed by temperature measurement, and it is necessary to have considerable skill as an actual control method, and a problem remains in its reproducibility. Furthermore, since roasting is performed after each boiled fish is individually wrapped in a non-woven fabric, it takes a lot of time and effort to manufacture actual fish buns, greatly reducing productivity, and questioning industrial effectiveness. Remains. In addition, not only polycyclic aromatic hydrocarbons including benzpyrene, but also smoke components such as guaiacol, phenol, and methylfurfural, which are flavor components deeply related to smoked foods, are reduced in the finished fish sections. There is a problem that is far from the sensory evaluation image of fish bun as smoked food.

特許文献3では、煮熟した魚の燻乾工程を乾燥と燻付けに分けて、さらに遠赤外線照射による加熱で比較的短い時間で乾燥させるか、もしく焙乾した後に遠赤外線照射で乾燥を実施している。この遠赤外線による乾燥方法では、従来、一般的に行われている魚節の焙乾工程の時間が数日間であることを考えると、48〜96時間と短い乾燥あるいは焙乾時間であるが、それでも2〜4日間であり、農林水産省の「有害化学物質含有実態調査結果データ集(平成23〜24年度)」で示されているようにベンツピレン含有量としては20〜50ppbは存在すると考えられる。特に、特許文献での実施例においては、官能的な風味に遜色がないことから、燻煙成分の付着は従来の焙乾方法と同様に多いと推定できる。   In Patent Document 3, the drying process of boiled fish is divided into drying and brazing, and further drying is carried out in a relatively short time by heating by far-infrared irradiation, or drying is carried out by far-infrared irradiation after roasting. doing. In this drying method using far infrared rays, considering the fact that the time of the conventional roasting process for fish clauses is several days, it is a short drying or drying time of 48 to 96 hours, It is still 2 to 4 days, and it is considered that 20-50 ppb is present as benzpyrene content as shown in the Ministry of Agriculture, Forestry and Fisheries Ministry of Agriculture, Forestry and Fisheries “Results of Survey on Contained Chemical Substances (2011-2012)” . In particular, in the examples in the patent literature, since the sensory flavor is not inferior, it can be presumed that the smoke component adheres as much as in the conventional roasting method.

以上のように、従来の製法においては、魚節本来の燻香・スモークの風味を維持しつつ、有害成分のベンツピレン含有量を10ppb程度に低減させることは非常に困難である。もちろん、魚節の生産性や生産コストを顧みなければ燻香・スモークの風味とベツンピレンの低減は可能であるが産業上の有効性を欠いてしまう。   As described above, in the conventional production method, it is very difficult to reduce the content of benzpyrene, which is a harmful component, to about 10 ppb while maintaining the original flavor and smoked taste of fish. Of course, if the productivity and production cost of fish buns are not taken into consideration, the flavor of bean and smoke and betsunpyrene can be reduced, but they lack industrial effectiveness.

本発明の更なる目的は、上記の課題に鑑み、魚節本来の好ましい燻香・スモークの風味を付与したうえで、ベンツピレン等の有害成分を安定的に低減するとともに、それらの生産性を著しく損なわないことが可能な魚節類の製造方法を提供することである。   A further object of the present invention is to take into account the above-mentioned problems, and to add a desirable flavor of smoked scent and smoke, and to reduce harmful components such as benzpyrene in a stable manner and to significantly increase their productivity. It is an object of the present invention to provide a method for producing fish clauses that can be kept intact.

本発明者らは、これらの課題を解決すべく研究した結果、魚節の製法における焙乾工程を乾燥工程と燻付け工程とに完全に分けて乾燥のみを先に行い、その後、燻付けを制御された条件下において短時間で行うことを可能にした。特に、乾燥は魚節の原料である魚のタンパク質がガラス化するまで行い、燻付けは市販の燻製食品用の電子スモーク装置を利用し、その条件を詳細設定することによって短時間で燻香・スモーク風味を付与できることを見出した。   As a result of studying to solve these problems, the inventors of the present invention completely divided the roasting process in the method for producing fish salmon into a drying process and a brazing process, and then performed only the drying process, and then performed the brazing process. It was possible to carry out in a short time under controlled conditions. In particular, drying is performed until the fish protein, which is the raw material of the fish section, is vitrified, and the brazing is performed using a commercially available electronic smoke device for smoked foods, and the conditions are set in detail to shorten the time. It has been found that flavor can be imparted.

即ち、本発明は、
原料魚を整形、煮熟後に熱風乾燥で乾燥とあん蒸を繰り返す乾燥工程と、植物原料を燃焼、不完全燃焼又は熱分解して燻煙を発生させて燻煙成分を魚乾燥品に付着又は接触させる燻付け工程の2段階からなり、前記燻付け工程が、乾燥整形魚もしくは燻煙に直流または交流電圧を印加しつつ、短時間で燻煙成分を乾燥整形魚に付着させることで、出来上がった魚節が燻香・スモーク香を有し、かつベンツピレン含有量が5.0ppb(質量に基づく)以下となることを特徴とする魚節の製造方法に関する。
That is, the present invention
Shaping raw fish, drying and simmering with hot air drying after ripening, and burning, incomplete combustion or pyrolysis of plant raw materials to generate smoke and attach smoke components to dried fish It consists of two stages of the brazing process to contact, and the brazing process is completed by applying a direct current or alternating current voltage to the dry shaped fish or smoke, and attaching the smoke component to the dry shaped fish in a short time The present invention relates to a method for producing a fish clause, characterized in that the fish clause has musk and smoked incense and has a benzpyrene content of 5.0 ppb (based on mass) or less.

また本発明の好ましい態様は、
前記魚乾燥品に対して燻煙成分を付着又は接触させる工程が、原料魚を整形、煮熟後に熱風乾燥で乾燥・あん蒸を繰り返す乾燥工程後に実施され、その後、植物原料を400℃以下で不完全燃焼又は熱分解して燻煙を発生させて、その発生した燻煙を約0.3mのドラム式燻煙室に対して0.01〜0.03m/秒の比率となるように低速で送風するとともに、燻煙成分の乾燥整形魚への付着、接触が、乾燥整形魚に10〜15kVの直流または交流電圧を印加しつつ、20〜30℃の雰囲気下で180分以上240分以内で行われる上記の魚節の製造方法に関する。
A preferred embodiment of the present invention is
The step of attaching or contacting the smoke component to the dried fish product is carried out after the drying step of shaping, boiling and ripening the raw material fish and repeating drying and fumigation. Incomplete combustion or thermal decomposition generates soot, and the generated soot has a ratio of 0.01 to 0.03 m 3 / sec with respect to a drum type soot chamber of about 0.3 m 3. The smoke component is attached to and contacted with the dried shaped fish while applying a DC or AC voltage of 10 to 15 kV to the dried shaped fish for 180 minutes or more in an atmosphere of 20 to 30 ° C. for 240 minutes or more. The present invention relates to a method for producing the above-mentioned fish section performed within minutes.

また、本発明の別の好ましい態様は、
前記乾燥・あん蒸の乾燥工程での乾燥が熱風乾燥であり、整形、煮熟した水分含量が55〜70%(平均64%)(質量に基づく)の魚が乾燥工程後に水分含量18%以下となり、魚内部のタンパク質がガラス化するように、乾燥時間とあん蒸を繰り返して行われることからなる、上記いずれかの魚節の製造方法に関する。
Another preferred embodiment of the present invention is as follows.
The drying in the drying / aeration drying process is hot-air drying, and the water content of 55-70% (average 64%) (based on mass) of the shaped and boiled water is 18% or less after the drying process. Thus, the present invention relates to a method for producing any of the above fish clauses, which is performed by repeating drying time and fumigation so that the protein inside the fish is vitrified.

本発明のさらに別の好ましい態様は、
前記熱風乾燥条件で、乾燥温度が90〜100℃の範囲で熱風乾燥を8時間以内行い、その後一晩あん蒸した後再度乾燥温度を90〜100℃で3〜8時間熱風乾燥し、魚の水分含量が18%以下で魚内部のタンパク質をガラス化させる前記の魚節の製造方法にも関する。
Yet another preferred embodiment of the present invention is
Under the hot air drying conditions, hot air drying is performed within a range of 90 to 100 ° C. within 8 hours, followed by fumigation overnight, and then drying again at 90 to 100 ° C. for 3 to 8 hours to dry the fish moisture. The present invention also relates to the above-mentioned method for producing fish clauses, wherein the content of the fish is 18% or less and the protein inside the fish is vitrified.

本発明の要点は、木材などの植物原料を燃焼、不完全燃焼して発生した燻煙で、乾燥と燻付けを同時に行う従来の魚節の製法の燻乾工程を、乾燥工程と燻付け工程の2つの別工程に完全に分けることである。そのため、魚節の原料である魚の乾燥条件を詳細に設定し、その魚のタンパク質をガラス化させることが第1のポイントである。   The gist of the present invention is that the drying process and the brazing process are the same as the drying process of the conventional method for producing fish salmon that is dried and brazed at the same time with smoke generated by burning or incomplete combustion of plant materials such as wood. It is to divide completely into two separate processes. Therefore, the first point is to set the drying conditions of the fish, which is the raw material of the fish section, in detail, and to vitrify the protein of the fish.

特に、本発明の魚節の製造方法は、魚節原料として煮熟した魚を、その水分含量が18%以下になるように所定の時間熱風乾燥して、魚タンパクをガラス化させる。ここで、当該熱風温度は90〜100℃の範囲とし、乾燥時間は乾燥開始から8時間行い、その後一晩(12〜15時間)あん蒸した後、さらに同温度で4時間乾燥させるサイクルで行うことが好ましい。乾燥温度範囲を90〜100℃にするのは、これ以上乾燥温度が高くなると魚表面だけが急速に乾燥し、表面が硬化することで魚内部まで均一に水分蒸発せずに、乾燥時間が長くなり、水分含量が18%まで低下しない。そのために、乾燥時間も乾燥、あん蒸、再乾燥のサイクルで行うことで短時間で行えるようにする。また、乾燥温度がこれよりも低くなっても乾燥時間は長くなる。乾燥時間が長くなると煮熟された魚中の脂質酸化が著しくなり、風味を劣化させるためである。   In particular, in the method for producing fish bun according to the present invention, fish protein boiled as a fish bun raw material is dried with hot air for a predetermined time so that its moisture content is 18% or less, and the fish protein is vitrified. Here, the hot air temperature is in the range of 90 to 100 ° C., and the drying time is 8 hours from the start of drying, and then is fumigated overnight (12 to 15 hours) and then dried at the same temperature for 4 hours. It is preferable. The reason for setting the drying temperature range to 90 to 100 ° C. is that when the drying temperature is higher than this, only the fish surface is dried rapidly, and the surface hardens so that the water does not evaporate uniformly to the inside of the fish and the drying time is long. The water content does not drop to 18%. Therefore, the drying time can be shortened by performing the cycle of drying, fumigation and re-drying. Further, even if the drying temperature is lower than this, the drying time becomes longer. This is because when the drying time is long, lipid oxidation in the boiled fish becomes remarkable and the flavor is deteriorated.

本発明の第2のポイントは、魚節原料として煮熟、乾燥、ガラス化させた魚を、熱を加えることなく短時間で燻付けする工程である。そのために新たな設備、装置を設計、開発することなく市販の電子スモーク装置を用いることで、多大な設備投資のない燻付け工程を得ることができる。この電子スモーク装置は、肉製品、卵などの燻製食品に効率よく燻付けするために既に市販、汎用されている。この装置を用いて、燻付け条件を設定することにより、魚節に好ましい燻香、スモーク香風味を付与するとともに、熱を加えることなく短時間での燻煙によりベンツピレンの発生を抑える目的がある。   The second point of the present invention is a step of brazing fish that has been boiled, dried and vitrified as a fish clause material in a short time without applying heat. Therefore, a brazing process without much capital investment can be obtained by using a commercially available electronic smoke device without designing and developing new facilities and devices. This electronic smoke device has already been put on the market and widely used in order to efficiently apply it to smoked foods such as meat products and eggs. By using this device, it is possible to impart a favorable aroma and smoked scent to the fish section by setting the conditions for culling and to suppress the occurrence of benzpyrene by smoking in a short time without applying heat. .

この燻付け工程で使用する電子スモーク装置は、市販されているもので燻煙発生装置と燻製装置からなり、燻煙発生装置には、燻煙材として木片チップやスモークチップが利用できる。この燻煙発生装置で木材チップなどを連続供給しながら温度制御できるプレートヒーターで加熱し、燻煙を発生させる。さらに発生した燻煙を燻製したい食品を入れたドラム式の燻製装置に送り込み、燻付けをする。この燻製装置には電極線が付いており、燻付け時に高電圧を発生させて燻煙をマイナスに帯電し、イオン化された燻煙のマイナス粒子が静電気で食品に吸い寄せられることで、低温、短時間で燻付けすることができる。   The electronic smoke device used in this brazing process is a commercially available product, and is composed of a smoke generation device and a smoke production device. In the smoke generation device, wood chip or smoke chip can be used as the smoke material. This smoke generator is heated by a plate heater that can control the temperature while continuously supplying wood chips and the like, thereby generating smoke. Furthermore, the smoke generated is sent to a drum type smoker containing foods to be smoked and brazed. This smoker has an electrode wire, which generates a high voltage at the time of soldering to negatively charge the smoke, and the negative particles of the ionized smoke are attracted to food by static electricity. Can be brazed in time.

この電子スモーク装置で制御できるのが、木片チップやスモークチップを加熱するプレートヒーターの温度とチップの供給量、燻煙を供給する送風量、燻付けする食品自体の供給量、電極線の電圧である。プレートヒーターの温度は360℃程度にすると、チップの燃焼、熱分解温度が425℃以下になりベンツピレンの発生を抑えられる。さらに、チップの供給量を制御することで発生する燻煙の量を調整し、発生した燻煙を排気する排気ファンの稼働時間を制御することで燻煙の滞留・排出時間を制御でき燻付け状態やその時間も間接的に調整できることになる。こうして、チップの燃焼、熱分解温度だけでなく、燻付けする時の燻煙量や燻付け時間の制御によって好ましい燻香、スモーク香の種類や質をコントロールしながら付与できるとともに、従来の魚節の燻乾工程で生成していた有害成分のベンツピレンの発生を低減させることができる。   This electronic smoke device can be controlled by the temperature of the plate heater that heats the wood chip and smoke chip, the supply amount of the chip, the amount of blown air that supplies smoke, the supply amount of food to be brazed, and the voltage of the electrode wire is there. When the temperature of the plate heater is about 360 ° C., the combustion and thermal decomposition temperature of the chip becomes 425 ° C. or less, and the generation of benzpyrene can be suppressed. In addition, the amount of smoke generated can be adjusted by controlling the amount of chips supplied, and the operation time of the exhaust fan that exhausts the generated smoke can be controlled to control the residence and discharge time of the smoke. The state and its time can also be adjusted indirectly. In this way, not only the burning and pyrolysis temperature of the chip, but also the preferred type and quality of smoked and smoked scents can be controlled by controlling the amount and time of smoking during simmering. The generation of benzpyrene, which is a harmful component generated in the lyophilization process, can be reduced.

本発明の製造方法によれば、魚節を製造するにおいて、乾燥と燻煙の工程を分けて乾燥し、ガラス化した魚乾燥整形品を、電子スモーク装置を用いて燻付け条件を詳細制御し短時間で行うことによって、従来法による鰹節と同等の燻香・スモークの風味を保持したまま、かつ有害成分のベンツピレン含有量を5.0ppb以下にできる魚節を得ることができる。
また、本発明の方法によれば、魚節本来の好ましい燻香・スモーク香をコントロールしながら付与し、さらに従来は何日もかかっていた魚節の製造期間に比べて非常に短い時間での生産が実現できるとともに、ベンツピレン等の有害成分を低減することも可能である。特に、本発明の方法によれば、魚節本来の燻香・スモーク香の強さ、質のコントロールと有害成分のベンツピレンの生成という矛盾する燻乾工程を経ることなく、それぞれの燻煙による成分変化を両立させることができる。
According to the production method of the present invention, in producing fish clauses, the dried and smoked steps are separated and dried, and the vitrified fish dry shaped article is controlled in detail using an electronic smoke device. By performing in a short time, it is possible to obtain a fish knot that can maintain the scent of smoked smoke and smoke that is equivalent to the koji knot by the conventional method, and can reduce the content of benzpyrene as a harmful component to 5.0 ppb or less.
In addition, according to the method of the present invention, it is imparted while controlling the preferred bonito and smoked incense inherent to fish buns, and in a very short time compared to the production period of fish buns that previously took days. Production can be realized and harmful components such as benzpyrene can be reduced. In particular, according to the method of the present invention, the components due to each smoke without passing through the contradictory drying process of strength, quality control and benzpyrene generation of harmful components, which are the original smoke and smoke flavors of the fish section It is possible to make changes compatible.

以下、本発明について詳細に説明する。   Hereinafter, the present invention will be described in detail.

本発明に関連する魚節の種類は、鰹節、宗田鰹節、さば節、あじ節、まぐろ節などであるが、本来は魚節類に限定されるものではなく、スモークサーモン、ハム、ソーセージ、ベーコン、卵などの畜肉燻製品などにも適用できる。中でも、水分含量が少なく、必然的に有害成分のベンツピレン含有量の多い魚節類に特に有効である。   The types of fish buns relevant to the present invention are bonito, soda bonito, mackerel buns, horse mackerel buns, tuna buns, etc., but are not originally limited to fish buns, smoked salmon, ham, sausage, bacon It can also be applied to livestock products such as eggs. Among them, it is particularly effective for fish buns having a low water content and a high content of benzpyrene, which is necessarily a harmful component.

本発明の方法で魚節類を製造するためには、原料となる魚の頭と内臓を取り除いて整形し、煮熟した後に乾燥する。この煮熟後の整形魚の水分含量はだいたい60〜70質量%であるから、これを15質量%以下にまで乾燥する。乾燥の熱源としては、燻煙を発生しない熱源であればよい。例えば、天日、電熱、赤外線、遠赤外線などで、送風ができるものであれば、乾燥時間が短くなるためにさらによい。また、乾燥温度は高いほど早く乾燥するが、煮熟整形魚の表面水分ばかり蒸発し、魚体内部から表面部への水分移行が起こりにくくなるため、乾燥温度は90〜100℃程度にし、あん蒸の時間を持つ方が乾燥が早くなり、魚体の酸化も抑えられる。ここでは、一般的な魚の干物などの乾燥に使われる熱風乾燥機を用いて実施した。さらに、乾燥時間を短くするために整形魚の寸法を小さくすることも効果的である。   In order to produce fish clauses by the method of the present invention, the head and internal organs of the fish as raw materials are removed, shaped, boiled and dried. Since the water content of the shaped fish after ripening is about 60 to 70% by mass, it is dried to 15% by mass or less. The heat source for drying may be a heat source that does not generate smoke. For example, if the air can be blown by sunlight, electric heat, infrared rays, far-infrared rays, etc., it is even better because the drying time is shortened. Also, the higher the drying temperature, the faster the drying, but only the surface moisture of the cooked and shaped fish evaporates, making it difficult for moisture to migrate from the inside of the fish body to the surface. Therefore, the drying temperature should be about 90-100 ° C. The longer the time, the faster the drying and the less oxidization of the fish. Here, a hot air dryer used for drying general fish dried fish was used. It is also effective to reduce the size of the shaped fish in order to shorten the drying time.

この熱風乾燥機を使用した整形魚の乾燥事例としては、熱風の温度を90〜100℃にして、送風しながら連続で8時間乾燥し、その後、乾燥していない魚内部の水分を内部から表面まで移行させるために一晩あん蒸させ、その後、熱風の温度を90〜100℃のままでさらに4時間乾燥する。この乾燥サイクルで整形魚の水分含量は約18%以下にまで減少し、同時に整形魚内部もほぼガラス化してくる。整形魚の水分含有量が18%以下になれば乾燥は終了し、燻付けに移る。   As an example of drying shaped fish using this hot air dryer, the temperature of the hot air is set to 90 to 100 ° C., and it is continuously dried for 8 hours while blowing air. Steam for overnight to transfer, then dry for an additional 4 hours with the hot air temperature at 90-100 ° C. During this drying cycle, the moisture content of the shaped fish is reduced to about 18% or less, and at the same time, the inside of the shaped fish is almost vitrified. When the moisture content of the shaped fish falls below 18%, the drying is finished and the process begins.

ほぼ内部がガラス化した乾燥整形魚ができれば、次に燻付け工程に入る。燻付け作業は、工業的に市販されている電子スモーク装置を利用する。例えば、株式会社北陽、日本ニューホランド株式会社、芝本産業株式会社などが取り扱う電子スモーク装置あるいは連続式燻製装置を用いる。本発明の実施例では、株式会社北陽製の連続燻煙発生装置とドラム式燻製装置を組合わせた電子スモーク装置を用いる。   If dry shaped fish with almost internal vitrification is produced, the next step is the brazing process. The brazing operation uses an electronic smoke device that is commercially available on the industry. For example, an electronic smoke device or a continuous smoking device handled by Hokuyo Co., Ltd., Nippon New Holland Co., Ltd., Shibamoto Sangyo Co., Ltd. or the like is used. In an embodiment of the present invention, an electronic smoke device in which a continuous smoke generator manufactured by Hokuyo Co., Ltd. and a drum-type smoke generator are combined is used.

これらの市販の電子スモーク装置で制御できるのが、木片チップやスモークチップを加熱するプレートヒーターの温度、チップの供給量、燻煙を供給する送風量(排気量)、燻付けする食品自体の供給量、電極線の電圧である。
燻煙の原材料は、一般的にスモーク食品に利用されているナラ、クヌギ、ブナ、サクラなどの木材であり、その形状に限定はないがチップやおが屑のように表面積が広い方が熱分解時の効率がよい。
These commercially available electronic smoke devices can be controlled by the temperature of the plate heater that heats the wood chips and smoke chips, the amount of chips supplied, the amount of air blown to supply smoke (displacement), and the supply of the food to be brazed. Quantity, voltage of the electrode wire.
The raw material for soot is wood such as oak, kunugi, beech, and cherry that are commonly used in smoked foods. The shape of the material is not limited, but the larger surface area, such as chips and sawdust, can be used during pyrolysis. Is efficient.

燻煙の発生方法としては、燻煙発生装置内で木片のスモークチップを400℃以下のプレートヒーター上に乗せ加熱することで燻煙を発生させる。ここで400℃以下にするのは、スモークチップの熱分解によるベンツピレン等の多環芳香族炭化水素の発生を抑制するためである。さらに、燻煙室(本発明ではドラム式燻製装置の空間量約0.3mに)対して、この時のチップ供給量は750〜850g/時間とすることで発生する燻煙量を調整し、発生した燻煙は燻製室の空間量約0.3mに対して0.01〜0.03m/秒の比率となるように送風する。この風速は、一般的な鰹節製造での焙乾庫のような0.2〜0.5/秒の風速よりもさらに低速である。これは、燻付けする乾燥整形魚の水分がすでに18%以下になっているために、燻煙が乾燥整形魚に吸着しにくいために低速で燻煙を送って燻煙滞留時間を長くしている。そのため、ドラム式燻煙室の容積に対するこの燻煙送風時間の制御により、乾燥整形魚当たりの燻煙滞留時間を調整することになる。また同時に、ドラム式燻煙室内の電極線には10〜15kVの電圧を印加させて送風された燻煙を荷電させる。これも、18%以下の乾燥整形魚に燻煙が吸着しにくいために、電極線への電圧の印加によって乾燥整形魚もしくは燻煙のどちらかを帯電させ、燻煙が短時間で吸着しやすくするためである。また、この時の燻煙時間は限定しないが、燻付けする乾燥整形魚重量、寸法とドラム式燻煙室容積によって約30〜480分くらいで行う。乾燥整形魚の燻香・スモーク香が好ましい状態になれば終了である。 As a method for generating soot, smoke smoke is generated by placing a smoke chip of a piece of wood on a plate heater of 400 ° C. or less and heating it in a soot generator. The reason why the temperature is set to 400 ° C. or lower is to suppress the generation of polycyclic aromatic hydrocarbons such as benzpyrene due to thermal decomposition of the smoke chip. Furthermore, the amount of smoke generated is adjusted by setting the chip supply amount at this time to 750 to 850 g / hour for the smoke chamber (in the present invention, the space amount of the drum type smoker is about 0.3 m 3 ). The generated smoke is blown so as to have a ratio of 0.01 to 0.03 m 3 / sec with respect to the space amount of about 0.3 m 3 in the smoke room. This wind speed is even slower than the wind speed of 0.2 to 0.5 / sec as in the case of a roasting cabinet in general bonito manufacturing. This is because the moisture of the dry shaped fish to be brazed is already 18% or less, so the smoke smoke is difficult to adsorb to the dried shaped fish, so the smoke smoke is sent at a low speed and the smoke smoke residence time is lengthened. . Therefore, the smoke retention time per dry shaped fish is adjusted by controlling the smoke blowing time with respect to the volume of the drum smoke chamber. At the same time, a voltage of 10 to 15 kV is applied to the electrode wire in the drum type smoke chamber to charge the blown smoke. This is also because it is difficult for soot to be adsorbed to 18% or less of dry shaped fish, so it is easy to adsorb soot in a short time by charging either dry shaped fish or soot by applying voltage to the electrode wire. It is to do. Moreover, although the smoke time at this time is not limited, it takes about 30 to 480 minutes depending on the weight and size of the dry shaped fish to be brazed and the volume of the drum type smoke chamber. If the dried smoked fish has a favorable scent and smoked scent, the process is complete.

次に本発明の効果を具体的な実施例に基づいて説明する。実施例では、カツオ45kgを用いて整形、乾燥し、乾燥整形魚5kgを燻付けして鰹節を試作した。試作した鰹節は熟練したパネル14名での官能評価と、ベンツピレン含有量を測定した。   Next, the effects of the present invention will be described based on specific examples. In the examples, 45 kg of skipjack was shaped and dried, and 5 kg of dried shaped fish was brazed to make a bonito prototype. The prototype bonito was subjected to sensory evaluation by 14 skilled panels and the content of benzpyrene was measured.

原料となるカツオの頭と内臓を取り除いて整形し、煮熟した後に乾燥する。煮熟後の整形魚の水分含量はだいたい64%であった。煮熟魚約25kgを電熱による熱風乾燥機に入れ、乾燥温度を95℃に設定し8時間連続乾燥した、その後、一晩あん蒸し、さらに95℃で4時間乾燥した。乾燥終了後の乾燥整形魚は約5kgとなり、水分含有量は15〜18.5%となった。
次に、この乾燥整形魚を電子スモーク装置の0.283m容量のドラム式燻乾機に入れる。燻煙の発生方法としては、ナラのスモークチップを360℃のプレートヒーター上に乗せ、810g/時間の速度でチップを供給しながら加熱することで燻煙を発生させる。発生した燻煙は0.011m/秒でドラム式燻煙室に送風し、ドラム式燻煙室内の電極線には11kVの電圧を印加させて送風された燻煙を荷電させた。この時の燻煙時間は0、60、120、180、240分でそれぞれ行い、これらの完成した鰹節の水分含量、ベンツピレン含量を測定した。また、想定される香りの違いの概要を知るためにGC−MS測定も実施した。さらに、これら鰹節の香りを中心に官能評価した。
Remove the head and internal organs of bonito, which is the raw material, shape it, boil it, and dry it. The water content of the shaped fish after cooking was about 64%. About 25 kg of boiled and matured fish was put into a hot air dryer by electric heating, the drying temperature was set at 95 ° C. and dried continuously for 8 hours, then steamed overnight and further dried at 95 ° C. for 4 hours. The dried shaped fish after drying was about 5 kg, and the water content was 15 to 18.5%.
Next, the dried shaped fish is put into a 0.283 m 3 capacity drum-type paddy dryer of an electronic smoke device. As a method for generating soot, smoke smoke is generated by placing a smoke chip of oak on a plate heater at 360 ° C. and heating it while supplying the chip at a rate of 810 g / hour. The generated soot was blown to the drum type smoke chamber at 0.011 m 3 / sec, and a voltage of 11 kV was applied to the electrode wire in the drum type smoke chamber to charge the blown smoke. The smoke time at this time was 0, 60, 120, 180 and 240 minutes, respectively, and the water content and benzpyrene content of these finished bonito were measured. Moreover, in order to know the outline | summary of the difference of the assumed fragrance, GC-MS measurement was also implemented. Furthermore, sensory evaluation centered on the scent of these bonito.

鰹節の水分含量は、通常の減圧乾燥法で、ベンツピレンは高速液体クロマトグラフ(HPLC)法を用いて実施した。このHPLC法のベンツピレンの測定限界は、約1.0ppbである。できあがった鰹節の官能評価方法は、通常製法の薩摩産鰹節をコントロールとして、通常製法の焼津産鰹節、本発明法の全く燻付けしていない鰹乾燥整形魚と240分燻付けした鰹節をサンプルとした。これらの各魚節を沸騰水で抽出し、重量3.0%となるように水分補正した「だし」を用いて、14名のパネルで5点法で官能評価し、その平均点を算出した。官能点数は、通常製法の薩摩産鰹節の香りを基準品(3点)として、各サンプルの燻香の「強さ」、「好ましさ」を下記基準に従って評価した。
5点:基準品と比較して燻香が強い(燻香が好ましい)もの
4点:基準品と比較して燻香がやや強い(燻香がやや好ましい)もの
3点:基準品と比較して燻香の強さ(燻香の好ましさ)が同等のもの
2点:基準品と比較して燻香がやや弱い(燻香がやや好ましくない)もの
1点:基準品と比較して燻香が弱い(燻香が好ましくない)もの
The water content of bonito was measured by a normal vacuum drying method, and benzpyrene was measured by a high performance liquid chromatograph (HPLC) method. The measurement limit of benzpyrene in this HPLC method is about 1.0 ppb. The sensory evaluation method of the finished bonito was made using the normal production method of Satsuma bonito as a control, and the normal production method of Yaizu bonito, the dried dried fish of the present invention, and the dried bonito of 240 minutes. did. Each of these fish nodes was extracted with boiling water, and using a “dashi” that had been corrected for moisture to a weight of 3.0%, sensory evaluation was performed by a 14-point panel using a 5-point method, and the average score was calculated. . The number of sensory points was evaluated according to the following criteria for the “strength” and “preference” of musk in each sample, using the scent of Satsuma bonito in the normal production method as a reference product (3 points).
5 points: those with strong musk compared to the reference product (preferably musk) 4 points: those with slightly strong musk compared to the reference product (preferably musk) 3 points: compared with the reference product Equivalent strength of musk (preference for musk) 2 points: Slightly weak musk (comparable with musk) compared to standard product 1 point: Compared with standard product Smell is weak (must not be preferred)

できあがった鰹節の水分含有量、ベンツピレン含有量の分析結果を下記表1に示す。   The analysis results of the moisture content and benzpyrene content of the finished bonito are shown in Table 1 below.

Figure 2016171777
Figure 2016171777

第1表にあるように、従来製法の鰹節は26〜80ppb濃度のベンツピレン含有量であった。産地や製造者によって、燻乾時の薪の種類、燃焼温度、燻乾室容量、燻乾時間などが異なるためにベンツピレン含有量に違いがあると考えられるが、本発明法による鰹節ではベンツピレン含有量は測定限界に近い1.0〜2.0ppbとなった。このことは、本発明方法であれば、有害成分としてしられるベンツピレン含有量が極端に低減できることが確認された。   As shown in Table 1, the traditional method has a benzpyrene content of 26 to 80 ppb. Benzpyrene content is considered to vary depending on the production area and manufacturer due to differences in soot type, combustion temperature, drying chamber capacity, drying time, etc. The amount was 1.0 to 2.0 ppb close to the measurement limit. This confirms that the benzpyrene content, which is a harmful component, can be extremely reduced by the method of the present invention.

本発明方法がベンツピレン含有量の低減には有効であるが、本来の鰹節の品質となる香りについて、通常の鰹節との差異を官能評価で調べた結果を下記表2に示す。   Although the method of the present invention is effective in reducing the benzpyrene content, Table 2 below shows the results of the sensory evaluation of the scent that is the quality of the original bonito and the difference from the normal bonito.

Figure 2016171777
Figure 2016171777

第2表の官能評価の結果では、従来法の鰹節でも薩摩産と焼津産に香りの強さの違いが認められた。本発明法では、電子スモークによる燻付けが120分では香りが弱く、240分の燻付けであれば従来法での薩摩産鰹節と同等の香りの評価となった。この結果であれは、本発明法で240分燻付けした鰹節が、従来法の鰹節と品質が同等で、かつベンツピレンの含有量も少なくなることが確認された。   As a result of sensory evaluation in Table 2, the difference in fragrance strength between Satsuma and Yaizu was recognized even in the traditional bonito section. According to the method of the present invention, the scent was weak at 120 minutes with electronic smoke, and the scent was equivalent to that of the traditional Satsuma bonito when it was 240 minutes. Even if it was this result, it was confirmed that the bonito sprinkled with the method of the present invention for 240 minutes is equivalent in quality to the bonito of the conventional method and the content of benzpyrene is also reduced.

Claims (4)

原料魚を整形、煮熟後に熱風乾燥で乾燥とあん蒸を繰り返す乾燥工程と、植物原料を燃焼、不完全燃焼又は熱分解して燻煙を発生させて燻煙成分を魚乾燥品に付着又は接触させる燻付け工程の2段階からなり、前記燻付け工程が、乾燥整形魚もしくは燻煙に直流または交流電圧を印加しつつ、短時間で燻煙成分を乾燥整形魚に付着させることで、出来上がった魚節が燻香・スモーク香を有し、かつベンツピレン含有量が5.0ppb(質量に基づく)以下となることを特徴とする魚節の製造方法。   Shaping raw fish, drying and simmering with hot air drying after ripening, and burning, incomplete combustion or pyrolysis of plant raw materials to generate smoke and attach smoke components to dried fish It consists of two stages of the brazing process to contact, and the brazing process is completed by applying a direct current or alternating current voltage to the dry shaped fish or smoke, and attaching the smoke component to the dry shaped fish in a short time A method for producing a fish knot characterized in that the fish knot has musk and smoked aroma and the benzpyrene content is 5.0 ppb (based on mass) or less. 前記魚乾燥品に対して燻煙成分を付着又は接触させる工程が、原料魚を整形、煮熟後に熱風乾燥で乾燥・あん蒸を繰り返す乾燥工程後に実施され、その後、植物原料を400℃以下で不完全燃焼又は熱分解して燻煙を発生させて、その発生した燻煙を約0.3mのドラム式燻煙室に対して0.01〜0.03m/秒の比率となるように低速で送風するとともに、燻煙成分の乾燥整形魚への付着、接触が、乾燥整形魚に10〜15kVの直流または交流電圧を印加しつつ、20〜30℃の雰囲気下で180分以上240分以内で行われる請求項1に記載の魚節の製造方法。 The step of attaching or contacting the smoke component to the dried fish product is carried out after the drying step of shaping, boiling and ripening the raw material fish and repeating drying and fumigation. Incomplete combustion or thermal decomposition generates soot, and the generated soot has a ratio of 0.01 to 0.03 m 3 / sec with respect to a drum type soot chamber of about 0.3 m 3. The smoke component is attached to and contacted with the dried shaped fish while applying a DC or AC voltage of 10 to 15 kV to the dried shaped fish for 180 minutes or more in an atmosphere of 20 to 30 ° C. for 240 minutes or more. The method for producing a fish clause according to claim 1, which is performed within minutes. 前記乾燥・あん蒸の乾燥工程での乾燥が熱風乾燥であり、整形、煮熟した水分含量が55〜70%(平均64%)(質量に基づく)の魚が乾燥工程後に水分含量18%以下となり、魚内部のタンパク質がガラス化するように、乾燥時間とあん蒸を繰り返して行われることからなる請求項1〜2記載の魚節の製造方法。   The drying in the drying / aeration drying process is hot-air drying, and the water content of 55-70% (average 64%) (based on mass) of the shaped and boiled water is 18% or less after the drying process. The method for producing fish clauses according to claim 1 or 2, wherein the drying process and fumigation are repeated so that the protein inside the fish is vitrified. 前記熱風乾燥条件で、乾燥温度が90〜100℃の範囲で熱風乾燥を8時間以内行い、その後一晩あん蒸した後再度乾燥温度を90〜100℃で3〜8時間熱風乾燥し、魚の水分含量が18%以下で魚内部のタンパク質をガラス化させる請求項3記載の魚節の製造方法。   Under the hot air drying conditions, hot air drying is performed within a range of 90 to 100 ° C. within 8 hours, followed by fumigation overnight, and then drying again at 90 to 100 ° C. for 3 to 8 hours to dry the fish moisture. The method for producing a fish clause according to claim 3, wherein the protein in the fish is vitrified at a content of 18% or less.
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DE112017004404T5 (en) 2016-09-02 2019-05-23 Denso Corporation VEHICLE OPERATING SYSTEM AND COMPUTER PROGRAM
JP2020028221A (en) * 2018-08-20 2020-02-27 株式会社北陽 Food product smoking device and food product smoking method

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE112017004404T5 (en) 2016-09-02 2019-05-23 Denso Corporation VEHICLE OPERATING SYSTEM AND COMPUTER PROGRAM
JP2020028221A (en) * 2018-08-20 2020-02-27 株式会社北陽 Food product smoking device and food product smoking method

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