JP2016168002A - Novel water-in-oil type emulsified grease composition for filling/topping - Google Patents

Novel water-in-oil type emulsified grease composition for filling/topping Download PDF

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JP2016168002A
JP2016168002A JP2015049535A JP2015049535A JP2016168002A JP 2016168002 A JP2016168002 A JP 2016168002A JP 2015049535 A JP2015049535 A JP 2015049535A JP 2015049535 A JP2015049535 A JP 2015049535A JP 2016168002 A JP2016168002 A JP 2016168002A
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fat
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JP6507738B2 (en
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立志 田中
Tateshi Tanaka
立志 田中
敬宏 遠藤
Keiko Endo
敬宏 遠藤
真子 石黒
Masako Ishiguro
真子 石黒
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Kaneka Corp
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Abstract

PROBLEM TO BE SOLVED: To provide: a water-in-oil type emulsified grease composition for filling/topping that has a rich milk flavor and a richness; and a food product that has a filling or topping of said water-in-oil type emulsified grease composition provided therein.SOLUTION: Provided is a water-in-oil type emulsified grease composition for filling/topping containing, within the entire water-in-oil type emulsified grease composition, a grease from 40 to 97 wt.%, non-fat milk solid content of 0.3 to 5 wt.% (dry weight), a fermentation seasoning obtained from grain and/or seafood as a raw-material and kelp extract in total by 0.05 to 0.5 wt.% (dry weight) and water content by 2 to 40 wt.%, and in which the fermentation seasoning/kelp extracts (dry weight ratio) is 95/5 to 15/85.SELECTED DRAWING: None

Description

本発明は、豊かな乳風味とコクを有するフィリング・トッピング用油中水型乳化油脂組成物及びその油中水型乳化油脂組成物をフィリング又はトッピングしてなる食品に関する。   TECHNICAL FIELD The present invention relates to a water-in-oil emulsified oil / fat composition for filling and topping having a rich milk flavor and richness, and a food obtained by filling or topping the water-in-oil emulsified oil / fat composition.

マーガリン等の油中水型乳化油脂組成物は、バターとは異なり主に植物性油脂を使用するため、健康面や価格面で優れているものの、バターのような独特の風味やコクを有しない。このため、フレーバーを添加して香り付けすることが一般的であるが、香りが不自然であったり、後味の広がりに欠けたり、加熱後の風味持続が劣るなどの問題がある。   Margarine and other water-in-oil emulsified fats and oils composition uses mainly vegetable oils and fats, unlike butter, so it is excellent in health and price, but does not have a unique flavor or richness like butter. . For this reason, it is common to add flavor and scent, but there are problems such as unnatural scent, lack of aftertaste, and poor flavor persistence after heating.

一方、醤油、魚醤などの液状調味料や野菜・果物等のジュースをバターやマーガリンに混合することで豊かな味を付与した新規スプレッドの製造方法(特許文献1)、充分な発酵の行われていないパンの発酵不足と小麦粉特有の粉っぽい風味を改善するために、コンブより抽出した風味成分と油脂とをあらかじめ混合した組成物を添加するパンの製造方法(特許文献2)が開示されている。しかしながら、何れもパンや菓子などのフィリング・トッピングに用いる油中水型乳化油脂組成物ではなく、醤油、魚醤、味噌等の発酵調味料もしくは昆布エキスの片方のみを使用しており、また目的が違うことからそれらの添加量も多く、従ってフィリング・トッピング用油中水型乳化油脂組成物に豊かな乳風味とコクを付与する効果についての示唆も全くない。   On the other hand, a liquid spread seasoning such as soy sauce and fish soy and juice such as vegetables and fruits are mixed with butter and margarine to produce a new spread (Patent Document 1), and sufficient fermentation is performed. In order to improve the lack of bread fermentation and the flour-like flavor peculiar to wheat flour, a method for producing bread (Patent Document 2) is disclosed, in which a composition in which a flavor component extracted from a kombu and fats and oils are mixed in advance is added. ing. However, they are not water-in-oil emulsified oils and fats used for filling and topping of bread and confectionery, but only fermented seasonings such as soy sauce, fish soy, miso or kelp extract are used. However, there is no suggestion about the effect of imparting a rich milk flavor and richness to the water-in-oil emulsified oil composition for filling and topping.

特開2012−110282号公報JP 2012-110282 A 特開平2−249445号公報JP-A-2-249445

本発明の目的は、豊かな乳風味とコクを有するフィリング・トッピング用油中水型乳化油脂組成物及びその油中水型乳化油脂組成物をフィリング又はトッピングしてなる食品を提供することである。   An object of the present invention is to provide a water-in-oil emulsified oil / fat composition for filling and topping having a rich milk flavor and richness, and a food obtained by filling or topping the water-in-oil emulsified oil / fat composition. .

本発明者らは上記課題を解決するために鋭意研究を重ねた結果、油脂、無脂乳固形分、穀類を原料とする発酵調味料及び/又は魚介類を原料とする発酵調味料、昆布エキス及び水分をそれぞれ特定量含有する油中水型乳化油脂組成物が、豊かな乳風味とコクを有することを見出し、本発明を完成するに至った。   As a result of intensive studies to solve the above-mentioned problems, the present inventors have found that a fermented seasoning made from fats and oils, non-fat milk solids, cereals and / or a fermented seasoning made from seafood, and kombu extract And a water-in-oil emulsified oil / fat composition containing specific amounts of water and water each have a rich milk flavor and richness, and the present invention has been completed.

即ち、本発明の第一は、油中水型乳化油脂組成物全体中、油脂40〜97重量%、無脂乳固形分0.3〜5重量%(乾燥重量)、穀類及び/又は魚介類を原料とする発酵調味料及び昆布エキスを合計で0.05〜0.5重量%(乾燥重量)及び水分2〜40重量%を含有し、発酵調味料/昆布エキス(乾燥重量比)が95/5〜15/85であるフィリング・トッピング用油中水型乳化油脂組成物に関する。好ましい実施態様は、発酵調味料が、魚醤、醤油、味噌、オイスターソースからなる群から選ばれる少なくとも1種である上記記載のフィリング・トッピング用油中水型乳化油脂組成物に関する。より好ましくは、油中水型乳化油脂組成物全体中、糖類(乳糖を除く)を0.2〜40重量%(乾燥重量)含有する上記記載のフィリング・トッピング用油中水型乳化油脂組成物、更に好ましくは、油脂全体中、乳脂肪を0.1〜30重量%含有する上記記載のフィリング・トッピング用油中水型乳化油脂組成物、特に好ましくは、油脂全体中、パーム系油脂のエステル交換油の分別液状部であり且つヨウ素価が35〜62の油脂を10〜70重量%含有する上記記載のフィリング・トッピング用油中水型乳化油脂組成物、極めて好ましくは、パーム系油脂のエステル交換油の分別液状部であり且つヨウ素価が35〜62の油脂が、SSSを2〜13重量%含有し、SSUとSUSを合計で34〜54重量%含有し、(SSUとSUSの合計含量)/(SSS含量)の重量比率が4〜20且つ(SSU含量)/(SUS含量)の重量比率が1以上である上記記載のフィリング・トッピング用油中水型乳化油脂組成物[SSS:トリ飽和脂肪酸グリセリド、SSU:1,2−ジ飽和脂肪酸−3−モノ不飽和脂肪酸グリセリド(光学異性体を含む)、SUS:1,3−ジ飽和脂肪酸−2−モノ不飽和脂肪酸グリセリド]、最も好ましくは、穀類及び/又は魚介類を原料とする発酵調味料及び昆布エキスが、水相部に含まれる上記記載のフィリング・トッピング用油中水型乳化油脂組成物、に関する。本発明の第二は、上記記載のフィリング・トッピング用油中水型乳化油脂組成物を、フィリング又はトッピングしてなる食品に関する。   That is, the first aspect of the present invention is that the entire oil-in-water emulsified oil / fat composition contains 40 to 97% by weight of oil and fat, 0.3 to 5% by weight (dry weight) of nonfat milk solids, cereals and / or seafood. Contains a total of 0.05 to 0.5% by weight (dry weight) and 2 to 40% by weight of water, and the fermented seasoning / konbu extract (dry weight ratio) is 95. It is related with the water-in-oil type emulsified oil-fat composition for filling topping which is / 5-15 / 85. A preferred embodiment relates to the above water-in-oil emulsified oil / fat composition for filling and topping, wherein the fermented seasoning is at least one selected from the group consisting of fish sauce, soy sauce, miso, and oyster sauce. More preferably, the water-in-oil emulsified fat / oil composition for filling and topping as described above containing 0.2 to 40% by weight (dry weight) of saccharides (excluding lactose) in the whole water-in-oil emulsified fat / oil composition. More preferably, the water-in-oil emulsified oil / fat composition for filling and topping as described above containing 0.1 to 30% by weight of milk fat in the whole oil and fat, particularly preferably the ester of palm oil and fat in the whole oil and fat. The water-in-oil emulsified oil / fat composition for filling and topping as described above, which is a fractionated liquid part of the exchange oil and contains 10 to 70% by weight of fats and oils having an iodine value of 35 to 62, and most preferably esters of palm fats and oils Oils and fats that are fractionated liquid parts of the exchange oil and have an iodine value of 35 to 62 contain 2 to 13% by weight of SSS, and 34 to 54% by weight of SSU and SUS in total (total of SSU and SUS The above-described water-in-oil emulsified oil / fat composition for filling and topping [SSS: wherein the weight ratio of (amount) / (SSS content) is 4 to 20 and the weight ratio of (SSU content) / (SUS content) is 1 or more. Trisaturated fatty acid glyceride, SSU: 1,2-disaturated fatty acid-3-monounsaturated fatty acid glyceride (including optical isomers), SUS: 1,3-disaturated fatty acid-2-monounsaturated fatty acid glyceride], most Preferably, the water-in-oil emulsified oil / fat composition for filling and topping as described above, wherein a fermented seasoning and kelp extract made from cereals and / or fishery products are contained in an aqueous phase. The second of the present invention relates to a food product obtained by filling or topping the above-described water-in-oil emulsified oil / fat composition for filling and topping.

本発明に従えば、豊かな乳風味とコクを有するフィリング・トッピング用油中水型乳化油脂組成物及びその油中水型乳化油脂組成物をフィリング又はトッピングしてなる食品を提供することができる。   According to the present invention, it is possible to provide a water-in-oil emulsified oil / fat composition for filling and topping having a rich milk flavor and richness, and a food obtained by filling or topping the water-in-oil emulsified oil / fat composition. .

以下、本発明につき、さらに詳細に説明する。本発明のフィリング・トッピング用油中水型乳化油脂組成物は、油脂、無脂乳固形分、穀類及び/又は魚介類を原料とする発酵調味料及び昆布エキス、及び水をそれぞれ特定量含有することを特徴とする。   Hereinafter, the present invention will be described in more detail. The water-in-oil emulsified oil / fat composition for filling and topping of the present invention contains a specific amount of each of a fermented seasoning and kelp extract made from fats and oils, non-fat milk solids, cereals and / or seafood, and water. It is characterized by that.

前記油中水型乳化油脂組成物中の油脂は、従来フィリング・トッピング用油中水型乳化油脂組成物に使用されるいかなる油脂を使用してもよく、例えば、パーム油、パーム核油、ヤシ油、亜麻仁油、桐油、サフラワー油、かや油、胡桃油、芥子油、向日葵油、綿実油、菜種油、コーン油、大豆油、辛子油、カポック油、米糠油、胡麻油、落花生油、オリーブ油、椿油、茶油、ひまし油、葡萄油、カカオ脂、シア脂、サル脂、コクム脂、ボルネオ脂等の植物性油脂や、魚油、鯨油、牛脂、乳脂、豚脂、鶏油、卵黄油、羊油等の動物性油脂が挙げられ、また、これらの油脂をエステル交換したものや、硬化、分別したもの等、通常食用に供されるすべての油脂類からなる群より選ばれる少なくとも1種を使用することができる。前記油脂の含有量は、前記油中水型乳化油脂組成物全体中40〜97重量%が好ましく、45〜95重量%がより好ましく、48〜90重量%が更に好ましく、50〜80重量%が特に好ましい。前記油脂の含有量が40重量%より少ないと、フィリング・トッピング用油中水型乳化油脂組成物としての好ましい物性を得ることができない場合がある。また含有量が97重量%を超えると、好ましい風味を付与するに十分な水溶性風味素材を添加することができない場合がある。   The oil / fat in the water-in-oil emulsified oil / fat composition may be any oil / fat conventionally used in water-in-oil emulsified oil / fat compositions for filling and topping, such as palm oil, palm kernel oil, palm Oil, linseed oil, tung oil, safflower oil, pod oil, walnut oil, coconut oil, sunflower oil, cottonseed oil, rapeseed oil, corn oil, soybean oil, pepper oil, kapok oil, rice bran oil, sesame oil, peanut oil, olive oil, Plant oil such as coconut oil, tea oil, castor oil, coconut oil, cacao butter, shea butter, monkey butter, kokum buta, borneo, etc., fish oil, whale oil, beef tallow, milk fat, pork tallow, chicken oil, egg yolk oil, sheep oil Animal fats and oils such as these are used, and at least one selected from the group consisting of all fats and oils that are usually used for food, such as those obtained by transesterification, hardening, and fractionation, is used. be able to. The content of the oil / fat is preferably 40 to 97% by weight, more preferably 45 to 95% by weight, still more preferably 48 to 90% by weight, and more preferably 50 to 80% by weight in the entire water-in-oil emulsified oil / fat composition. Particularly preferred. When the content of the oil or fat is less than 40% by weight, it may be impossible to obtain preferable physical properties as a water-in-oil emulsified oil or fat composition for filling and topping. Moreover, when content exceeds 97 weight%, water-soluble flavor raw material sufficient to provide a preferable flavor may not be added.

また前記油中水型乳化油脂組成物には、豊かな乳風味とコクを付与する観点から、乳脂肪を含有していることが好ましく、乳脂肪の含有量は前記油中水型乳化油脂組成物に含まれる油脂全体中0.1〜30重量%が好ましく、0.5〜20重量%がより好ましく、0.7〜10重量%が更に好ましく、1〜7重量%が特に好ましい。前記乳脂肪の含有量が0.1重量%より少ないと、豊かな乳風味とコクの付与効果が得られにくい場合があり、30重量%を超えると、効果が頭打ちになったり、価格が高くなる場合がある。乳脂肪とは、牛乳由来の脂質を言い、バター、発酵バター、生乳、牛乳、特別牛乳、濃縮乳、クリーム、発酵クリーム、加糖練乳、無糖練乳、チーズ、全脂粉乳、バターミルク、バターミルクパウダー及びこれらを酸、酵素、加熱処理したものや分別したものなどが例示でき、これらの群より選ばれる少なくとも1種が用いられる。   The water-in-oil emulsified oil / fat composition preferably contains milk fat from the viewpoint of imparting rich milk flavor and richness, and the content of milk fat is the water-in-oil emulsified oil / fat composition. 0.1-30 weight% is preferable in the whole fats and oils contained in a thing, 0.5-20 weight% is more preferable, 0.7-10 weight% is still more preferable, 1-7 weight% is especially preferable. When the content of the milk fat is less than 0.1% by weight, it may be difficult to obtain a rich milk flavor and richness. When it exceeds 30% by weight, the effect reaches a peak or the price is high. There is a case. Milk fat means fat derived from milk, butter, fermented butter, raw milk, milk, special milk, concentrated milk, cream, fermented cream, sweetened condensed milk, cheese, whole milk powder, buttermilk, buttermilk Examples thereof include powders and acids, enzymes, heat-treated and fractionated powders, and at least one selected from these groups is used.

さらに前記油中水型乳化油脂組成物には、豊かな乳風味とコクを増強する観点から、パーム系油脂のランダムエステル交換油の分別液状部であり且つヨウ素価が35〜62の油脂を含有していることが好ましい。また該ヨウ素価は、37〜58がより好ましく、40〜55が更に好ましい。前記分別液状部のヨウ素価が35より低いと、硬すぎて可塑性が不足しクリーミング性が悪くなったり、食感が悪くなる場合があり、また62より高いと、軟らかすぎて保型性が劣る場合がある。   Furthermore, the water-in-oil type emulsified oil / fat composition contains a fat and oil having a iodine value of 35 to 62, which is a fractionated liquid part of a random transesterified oil of palm oil and fat, from the viewpoint of enhancing a rich milk flavor and richness. It is preferable. The iodine value is more preferably 37 to 58, still more preferably 40 to 55. If the iodine value of the fractionated liquid part is lower than 35, it may be too hard and the plasticity will be insufficient, and the creaming property may be deteriorated or the texture may be deteriorated, and if it is higher than 62, it is too soft and the shape retention property is poor. There is a case.

前記パーム系油脂のエステル交換油の分別液状部の含有量は、前記油中水型乳化油脂組成物に含まれる油脂全体中10〜70重量%が好ましく、20〜60重量%がより好ましく、30〜50重量%が更に好ましい。前記分別液状部の含有量が10重量%より少ないと、豊かな乳風味とコクの増強効果が得られにくい場合がある。り、また70重量%を超えると、効果が頭打ちになったり、フィリング・トッピング用油中水型乳化油脂組成物としての好ましい物性が損なわれる場合がある。   The content of the fractionated liquid part of the transesterified oil of the palm-based fat / oil is preferably 10 to 70% by weight, more preferably 20 to 60% by weight, based on the whole fat / oil contained in the water-in-oil emulsified oil / fat composition. More preferred is ˜50% by weight. When the content of the fractionated liquid part is less than 10% by weight, it may be difficult to obtain a rich milk flavor and a rich enhancement effect. On the other hand, if it exceeds 70% by weight, the effect may reach its peak, or preferable physical properties as a water-in-oil emulsified oil / fat composition for filling and topping may be impaired.

パーム系油脂のランダムエステル交換方法としては、「ナトリウムメチラートなどのアルカリ触媒などを用いた化学法」や「リパーゼを用いた酵素法」など、一般的に食用油脂に適用することができる方法が挙げられる。なお、本発明におけるランダムエステル交換方法としては、「化学法」もしくは「トリグリセリドの2位にもある程度の反応性があるリパーゼ、例えば、Thermomyces属由来のリパーゼなどを用いる酵素法」を利用することが好ましい。   Random transesterification methods for palm fats and oils include methods that can be generally applied to edible fats and oils, such as “chemical methods using alkali catalysts such as sodium methylate” and “enzymatic methods using lipase”. Can be mentioned. As the random transesterification method in the present invention, it is possible to use “chemical method” or “enzymatic method using a lipase having a certain degree of reactivity at the 2-position of triglyceride, for example, a lipase derived from the genus Thermomyces”. preferable.

前記エステル交換に供するパーム系油脂のヨウ素価は30〜58が好ましく、その範囲であれば、最終的に得られる油脂のヨウ素価を35〜62に調整し易い。前記エステル交換に供するパーム系油脂としては、例えば、そのまま使用する場合、パーム油、パームステアリン、パーム中融点部、パームオレインが挙げられ、そのまま使用しない場合でも、ヨウ素価が30〜58の範囲外にあるパームダブルオレイン、パームスーパーオレイン、パームトップオレイン、パームハードステアリンなどのパーム系油脂と他のパーム系油脂を混合してヨウ素価30〜58に調整しても良い。   The iodine value of palm-based fats and oils subjected to transesterification is preferably 30 to 58, and if within this range, the iodine value of the finally obtained fats and oils can be easily adjusted to 35 to 62. Examples of the palm-based fats and oils to be used for the transesterification include palm oil, palm stearin, palm middle melting point, and palm olein when used as they are, and even when not used as they are, the iodine value is outside the range of 30 to 58. Palm oils such as palm double olein, palm super olein, palm top olein, and palm hard stearin may be mixed with other palm oils to adjust the iodine value to 30-58.

前記エステル交換後の分別方法としては、食用油脂に一般的に適用される方法が挙げられ、例えば、パーム系油脂のエステル交換油を温調しながら攪拌して結晶を析出させた後、その油脂を加圧圧搾装置に導入して圧搾して液状部を得る。具体的には、パーム系油脂のランダムエステル交換油を5〜48時間、分別に供するエステル交換油脂の融点よりも2〜14℃低い温度で温調しながら攪拌して結晶を析出させ、その油脂を加圧圧搾装置に導入し、前記温度を維持しながら0.5〜5MPaで圧搾すると、容易にヨウ素価が35〜62の液状部が得られて好ましい。   Examples of the separation method after the transesterification include a method generally applied to edible fats and oils. For example, after the transesterified oil of palm-based fats and oils is stirred to precipitate crystals, the fats and oils are mixed. Is introduced into a pressure squeezing device and squeezed to obtain a liquid part. Specifically, a random transesterified oil of palm oil / fat is stirred for 5 to 48 hours while stirring at a temperature 2-14 ° C. lower than the melting point of the transesterified oil / fat to precipitate crystals, and the oil / fat Is preferably squeezed at 0.5 to 5 MPa while maintaining the temperature, and a liquid part having an iodine value of 35 to 62 is easily obtained.

更に前記パーム系油脂のエステル交換油の分別液状部であり且つヨウ素価が35〜62の油脂は、SSSを2〜13重量%含有し、SSUとSUSを合計で34〜54重量%含有し、(SSUとSUSの合計含量)/(SSS含量)の重量比率が4〜20且つ(SSU含量)/(SUS含量)の重量比率が1以上であることが好ましい。   Furthermore, the oil and fat which is a liquid separation part of the transesterified oil of the palm oil and has an iodine value of 35 to 62 contains 2 to 13% by weight of SSS, and 34 to 54% by weight of SSU and SUS in total. It is preferable that the weight ratio of (total content of SSU and SUS) / (SSS content) is 4 to 20 and the weight ratio of (SSU content) / (SUS content) is 1 or more.

前記SSS含量は、2重量%未満であると保型性が悪くなる場合があり、13重量%を超えると口溶けが悪くなる場合がある。また前記SSUとSUSの合計含量は、34重量%未満では結晶速度が遅く経時変化が大きくなる場合があり、54重量%を超えると硬くなり可塑性が悪くなる場合がある。   When the SSS content is less than 2% by weight, the shape retention may be deteriorated, and when it exceeds 13% by weight, the meltability in the mouth may be deteriorated. If the total content of SSU and SUS is less than 34% by weight, the crystallization speed may be slow and the change with time may be large. If it exceeds 54% by weight, it may become hard and plasticity may be deteriorated.

また(SSUとSUSの合計含量)/(SSS含量)の重量比率は、4より小さいとSSSが多く口溶けが悪くなるか、もしくはSSS、SSU、SUSの合計量が少ないために結晶速度の遅い軟質の油脂となる場合があり、20より大きくなると、結晶核となるSSSが相対的に少ないために粗大結晶となり物性が悪化する場合がある。   Also, the weight ratio of (total content of SSU and SUS) / (SSS content) is less than 4, so SSS is too much to melt into the mouth, or the total amount of SSS, SSU, and SUS is small, so the softness of the crystal speed is slow. If it is larger than 20, the SSS that is a crystal nucleus is relatively small, so that it becomes coarse crystals and physical properties may deteriorate.

前記(SSU含量)/(SUS含量)の重量比率は1未満であると、SSUに対してSUSが多くなり結晶速度が遅く経時的に物性変化が大きくなり好ましくない場合がある。   When the weight ratio of (SSU content) / (SUS content) is less than 1, SUS increases with respect to SSU, the crystal speed is slow, and physical properties change with time.

上記記載のパーム系油脂を原料とし、上記記載のエステル交換方法及びエステル交換後の分別方法に従えば、多大な試行錯誤をすることなく前記分別液状部のトリグリセリド組成を得ることができる。   By using the palm oil and fat described above as a raw material and following the transesterification method and the fractionation method after the transesterification described above, the triglyceride composition of the fractionated liquid part can be obtained without much trial and error.

本発明におけるSSS含量、SSU含量、SUS含量は「AOCS Official Method Ce 5c−93」に準拠してHPLCにより分析できる。また、SSU/SUS比率は、HPLCを用いて硝酸銀カラムにより分析できる。分析条件は「Journal of the American Oil Chemists Society,68,289−293,1991」記載の方法に準拠して分析できる。更に、ヨウ素価は、日本油化学会制定、基準油脂分析試験法2.3.4.1−1996」に準拠して測定できる。   The SSS content, SSU content, and SUS content in the present invention can be analyzed by HPLC in accordance with “AOCS Official Method Ce 5c-93”. The SSU / SUS ratio can be analyzed by a silver nitrate column using HPLC. The analysis conditions can be analyzed according to the method described in “Journal of the American Oil Chemistry Society, 68, 289-293, 1991”. Further, the iodine value can be measured according to the establishment of Japan Oil Chemists' Society, Standard Oil Analysis Test Method 2.3.4.1-1996 ”.

前記無脂乳固形分の原料は、例えば、牛乳、クリーム、脱脂乳、バターミルク、脱脂粉乳、全脂粉乳、バターミルクパウダー、ホエー蛋白質、カゼイン蛋白質、乳清ミネラル、加糖練乳、無糖練乳、チーズ等が挙げられ、中でも脱脂乳、脱脂粉乳、バターミルク及びバターミルクパウダーが好ましく、特にバターミルクパウダーが好ましい。前記無脂乳固形分の含有量は、前記油中水型乳化油脂組成物全体中、乾燥重量で0.3〜5重量%が好ましく、0.5〜4重量%がより好ましく、1〜3重量部が更に好ましく、1.2〜2.5重量%が特に好ましい。前記無脂乳固形分の含有量が0.3重量部より少ないと豊かな乳風味とコクが感じられない場合があり、5重量%より多いと製造時に離水し安定的に生産することが困難となる場合がある。   The non-fat milk solid content is, for example, milk, cream, skim milk, butter milk, skim milk powder, whole milk powder, butter milk powder, whey protein, casein protein, whey mineral, sweetened condensed milk, sugar-free condensed milk, Cheese etc. are mentioned, Nonfat milk, skim milk powder, buttermilk, and buttermilk powder are especially preferable, and buttermilk powder is especially preferable. The content of the non-fat milk solid content is preferably 0.3 to 5% by weight, more preferably 0.5 to 4% by weight in terms of dry weight in the entire water-in-oil emulsified oil / fat composition. Part by weight is more preferable, and 1.2 to 2.5% by weight is particularly preferable. If the content of the non-fat milk solid content is less than 0.3 parts by weight, the rich milk flavor and richness may not be felt. If the content is more than 5% by weight, it is difficult to produce water stably during production. It may become.

前記穀類及び/又は魚介類を原料とする発酵調味料は、穀類又は魚介類の原料を自己消化及び/又は酵素を添加して、蛋白質などを分解して製造される調味料を意味し、例えば味噌、醤油、みりん、豆板醤、甜麺醤、魚醤、オイスターソースなどが挙げられ、これらのうち魚醤、醤油、味噌、オイスターソースからなる群から選ばれる少なくとも1種を使用することが好ましい。   The fermented seasoning using cereals and / or seafood as a raw material means a seasoning produced by self-digesting cereals or seafood raw materials and / or adding enzymes to decompose proteins and the like, for example, Examples include miso, soy sauce, mirin, bean plate soy, crab noodle soy, fish soy, and oyster sauce. Among these, it is preferable to use at least one selected from the group consisting of fish soy, soy sauce, miso, and oyster sauce.

前記昆布エキスは、昆布原藻、もしくはその乾燥品を水抽出、アルコール抽出又はアルカリ抽出して得られる抽出液、該抽出液の濃縮液、あるいは該抽出液を粉末化したものを意味し、更に塩、糖、アミノ酸、有機酸、核酸等で調味されていてもよく、一般に市販されている昆布エキス等を用いることができる。上記において、抽出前に前記昆布原藻、もしくはその乾燥品を切断し、砂等の異物を取り除いておくことが好ましい。   The kombu extract means an extract obtained by water extraction, alcohol extraction or alkali extraction of kombu original algae or a dried product thereof, a concentrated solution of the extract, or a powdered extract. It may be seasoned with a salt, sugar, amino acid, organic acid, nucleic acid or the like, and a commercially available kelp extract or the like can be used. In the above, it is preferable to cut off the kombu algae or a dried product thereof to remove foreign substances such as sand before extraction.

前記穀類及び/又は魚介類を原料とする発酵調味料と前記昆布エキスの合計含有量(乾燥重量)は、前記油中水型乳化油脂組成物全体中、0.05〜0.5重量部が好ましく、0.08〜0.4重量部がより好ましく、0.1〜0.3重量部が更に好ましく、0.12〜0.2重量部が特に好ましい。前記発酵調味料と前記昆布エキスの合計含有量が0.05重量部より少ないと、豊かな乳風味とコクを付与する効果が得られない場合があり、0.5重量部より多いと発酵調味料や昆布エキスの風味が感じられる場合がある。   The total content (dry weight) of the fermented seasoning made from the cereal and / or seafood and the kelp extract is 0.05 to 0.5 parts by weight in the entire water-in-oil emulsified fat composition. Preferably, 0.08-0.4 weight part is more preferable, 0.1-0.3 weight part is still more preferable, 0.12-0.2 weight part is especially preferable. If the total content of the fermented seasoning and the kelp extract is less than 0.05 parts by weight, the effect of imparting a rich milk flavor and richness may not be obtained. The flavor of the ingredients and kelp extract may be felt.

また、前記において発酵調味料/昆布エキス(乾燥重量比)は95/5〜15/85が好ましく、90/10〜20/80がより好ましく、85/15〜40/60が更に好ましく、80/20〜55/45が特に好ましい。前記重量比が95/5より大きいと、後味の乳風味が弱く感じられる場合があり、また15/85より小さいと、先味の乳風味が弱く感じられる場合がある。   In the above, the fermented seasoning / kombu extract (dry weight ratio) is preferably 95/5 to 15/85, more preferably 90/10 to 20/80, still more preferably 85/15 to 40/60, and 80 / 20-55 / 45 is particularly preferred. If the weight ratio is greater than 95/5, the aftertaste of milk may be felt weak, and if it is less than 15/85, the taste of the taste of taste may be felt weak.

また、前記において(発酵調味料)/(昆布エキス)/(無脂乳固形分)の比率は、乾燥重量で、(2〜25)/(0.8〜7)/(70〜97)が好ましい。   In the above, the ratio of (fermented seasoning) / (kombu extract) / (non-fat milk solids) is (2-25) / (0.8-7) / (70-97) in terms of dry weight. preferable.

前記水分は、前記油中水型乳化油脂組成物中、2〜40重量%が好ましく、3〜35重量%がより好ましく、4〜30重量%が更に好ましく、5〜20重量%が特に好ましい。水分の含有量が2重量%より少ないと豊かな乳風味とコクが弱く感じられる場合があり、40重量%より多いと豊かな乳風味とコクが感じられなかったり、乳化が不安定になって製造時に離水して安定的に生産することが困難となる場合がある。   The water content is preferably 2 to 40% by weight, more preferably 3 to 35% by weight, still more preferably 4 to 30% by weight, and particularly preferably 5 to 20% by weight in the water-in-oil emulsified oil / fat composition. If the water content is less than 2% by weight, the rich milk flavor and richness may be felt weak, and if it is more than 40% by weight, the rich milk flavor and richness will not be felt, or the emulsification will become unstable. It may be difficult to produce water stably during production.

さらに前記油中水型乳化油脂組成物には、豊かな乳風味とコクを増強する観点から、糖類(乳糖を除く)を含有していることが好ましい。前記糖類としては、砂糖、果糖、ブドウ糖、水飴、還元水飴、はちみつ、異性化糖、転化糖、オリゴ糖(イソマルトオリゴ糖、還元キシロオリゴ糖、還元ゲンチオオリゴ糖、キシロオリゴ糖、ゲンチチオオリゴ糖、ニゲロオリゴ糖、テアンデオリゴ糖、大豆オリゴ糖等)、トレハロース、糖アルコール(マルチトール、エリスリトール、ソルビトール、パラチニット、キシリトール、ラクチトール等)、砂糖結合水飴等を挙げることができ、粉糖でも液糖でも構わない。また糖類の代わりに甘味成分を用いることができ、例えばアスパルテーム、アセスルファムカリウム、スクラロース、アリテーム、ネオテーム、カンゾウ抽出物(グリチルリチン)、サッカリン、サッカリンナトリウム、ステビア抽出物、ステビア粉末等などが挙げられ、これらの群より選ばれる少なくとも1種を使用することもできる。   Further, the water-in-oil emulsified oil / fat composition preferably contains sugars (excluding lactose) from the viewpoint of enhancing the rich milk flavor and richness. Examples of the saccharide include sugar, fructose, glucose, starch syrup, reduced starch syrup, honey, isomerized sugar, invert sugar, oligosaccharide (isomalto-oligosaccharide, reduced xylo-oligosaccharide, reduced gentio-oligosaccharide, xylo-oligosaccharide, gentio-thio-oligosaccharide, and nigerooligosaccharide. , Theande-oligosaccharide, soybean oligosaccharide, etc.), trehalose, sugar alcohol (maltitol, erythritol, sorbitol, palatinit, xylitol, lactitol, etc.), sugar-bound starch syrup, etc., and may be powdered sugar or liquid sugar. Sweeteners can be used instead of saccharides, and examples include aspartame, acesulfame potassium, sucralose, aritem, neotame, licorice extract (glycyrrhizin), saccharin, saccharin sodium, stevia extract, stevia powder, etc. At least one selected from the group can also be used.

前記糖類の含有量は、油中水型乳化油脂組成物全体中0.2〜40重量%が好ましく、より好ましくは1〜35重量%、さらに好ましくは5〜32重量%である。前記糖類の含有量が0.2重量%より少ないと良好な風味の増強効果が得られない場合があり、40重量%より多いと甘味が強く感じられる場合がある。なお前記糖類は、該油中水型乳化油脂組成物の製造時に添加しても、できた該油中水型乳化油脂組成物に後合わせしても構わない。   The content of the saccharide is preferably 0.2 to 40% by weight, more preferably 1 to 35% by weight, and still more preferably 5 to 32% by weight in the entire water-in-oil emulsified fat composition. When the saccharide content is less than 0.2% by weight, a good flavor enhancing effect may not be obtained, and when it is more than 40% by weight, sweetness may be felt strongly. The saccharide may be added during the production of the water-in-oil emulsified oil / fat composition or may be added to the water-in-oil emulsified oil / fat composition thus produced.

本発明の油中水型乳化油脂組成物においては、前記記載の原材料の他に、必要に応じて、例えば、乳化剤、増粘安定剤、β−カロテン、カラメル、紅麹色素等の着色料、トコフェロール、茶抽出物(カテキン等)、ルチン等の酸化防止剤、小麦蛋白や大豆蛋白といった植物蛋白、卵及び各種卵加工品、香料、乳製品、調味料、pH調整剤、食品保存料、果実、果汁、コーヒー、ナッツペースト、香辛料、ココアマス、ココアパウダー、穀類、豆類、野菜類、肉類、魚介類等の食品素材や食品添加物などを添加することもできる。   In the water-in-oil emulsified oil / fat composition of the present invention, in addition to the raw materials described above, if necessary, for example, a colorant such as an emulsifier, a thickening stabilizer, β-carotene, caramel, red yeast rice pigment, Tocopherols, tea extracts (catechins, etc.), antioxidants such as rutin, plant proteins such as wheat protein and soy protein, eggs and various processed eggs, flavorings, dairy products, seasonings, pH adjusters, food preservatives, fruits Food materials such as fruit juice, coffee, nut paste, spices, cocoa mass, cocoa powder, cereals, beans, vegetables, meats, and seafood, and food additives can also be added.

前記乳化剤としては、ポリグリセリン脂肪酸エステル、ショ糖脂肪酸エステル、ソルビタン脂肪酸エステル、ポリソルベート、縮合リシノレイン脂肪酸エステル、グリセリン脂肪酸エステル等の合成乳化剤や、大豆レシチン、卵黄レシチン、大豆リゾレシチン、卵黄リゾレシチン、酵素処理卵黄、サポニン、植物ステロール類、乳脂肪球皮膜等の合成乳化剤でない乳化剤が挙げられ、これらの群より選ばれる少なくとも1種を使用すればよい。前記乳化剤の配合量は、油中水型乳化油脂組成物全体中0.01〜5重量%であることが好ましく、0.05〜2重量%であることがより好ましく、0.1〜1重量%であることが更に好ましい。0.01重量%より少ないと、乳化剤の効果が得られない場合があり、5重量%より多いと乳化剤の苦味が感じられる場合がある。   Examples of the emulsifier include synthetic emulsifiers such as polyglycerin fatty acid ester, sucrose fatty acid ester, sorbitan fatty acid ester, polysorbate, condensed ricinolein fatty acid ester, glycerin fatty acid ester, soybean lecithin, egg yolk lecithin, soybean lysolecithin, egg yolk lysolecithin, enzyme-treated egg yolk , Saponins, plant sterols, emulsifiers that are not synthetic emulsifiers such as milk fat globule membrane, and at least one selected from these groups may be used. The blending amount of the emulsifier is preferably 0.01 to 5% by weight, more preferably 0.05 to 2% by weight, and more preferably 0.1 to 1% by weight in the entire water-in-oil emulsified oil / fat composition. % Is more preferable. If it is less than 0.01% by weight, the effect of the emulsifier may not be obtained, and if it is more than 5% by weight, the bitterness of the emulsifier may be felt.

前記増粘安定剤としては、グアーガム、ローカストビーンガム、カラギーナン、アラビアガム、アルギン酸類、ペクチン、キサンタンガム、プルラン、タマリンドシードガム、サイリウムシードガム、結晶セルロース、カルボキシメチルセルロース、メチルセルロース、寒天、グルコマンナン、ゼラチン、澱粉、化工澱粉等が挙げられる。   Examples of the thickening stabilizer include guar gum, locust bean gum, carrageenan, gum arabic, alginic acid, pectin, xanthan gum, pullulan, tamarind seed gum, psyllium seed gum, crystalline cellulose, carboxymethylcellulose, methylcellulose, agar, glucomannan, gelatin , Starch, modified starch and the like.

なお、前記その他の成分の含有量は、好ましくは油中水型乳化油脂組成物全体中10重量%以下、より好ましくは5重量%以下である。   The content of the other components is preferably 10% by weight or less, more preferably 5% by weight or less, based on the entire water-in-oil emulsified oil / fat composition.

本発明のフィリング・トッピング用油中水型乳化油脂組成物の製造方法は、通常のフィリング・トッピング用油中水型油脂組成物と同様の方法で実施でき、以下に例示する。まず、50〜80℃に加温溶解した油脂に油溶性原料を混合して油相部を得る。一方、50〜70℃の温水に、前記穀類及び/又は魚介類を原料とする発酵調味料、昆布エキス、無脂乳固形分などの水系原料を攪拌溶解して水相部を得る。前記油相部に前記水相部を添加し、予備乳化した乳化液を、冷却し、結晶化させることで製造することができる。   The method for producing a water-in-oil emulsified oil / fat composition for filling and topping of the present invention can be carried out in the same manner as a normal water-in-oil type oil / fat composition for filling and topping, and is exemplified below. First, an oil-soluble raw material is mixed with fats and oils heated and dissolved at 50 to 80 ° C. to obtain an oil phase part. On the other hand, aqueous ingredients such as fermented seasoning, kelp extract, and non-fat milk solids made from the cereals and / or fishery products are stirred and dissolved in hot water at 50 to 70 ° C. to obtain an aqueous phase. The aqueous phase part is added to the oil phase part, and the pre-emulsified emulsion is cooled and crystallized.

本発明のフィリング・トッピング用油中水型乳化油脂組成物は、例えば、食パン、菓子パン、クロワッサン、デニッシュ等のパン類、クッキー、ビスケット、ケーキ、パイ等の焼き菓子類等にフィリング又はトッピングして使用することができる。   The water-in-oil emulsified oil / fat composition for filling and topping of the present invention is filled or topped with, for example, bread such as bread, confectionery bread, croissant, Danish, baked confectionery such as cookies, biscuits, cakes and pies. Can be used.

以下に実施例を示し、本発明をより具体的に説明するが、本発明はこれらの実施例に何ら限定されるものではない。なお、実施例において「部」や「%」は重量基準である。   EXAMPLES Hereinafter, the present invention will be described more specifically with reference to examples. However, the present invention is not limited to these examples. In the examples, “parts” and “%” are based on weight.

<SSS含量及びSSUとSUSの合計含量の測定>
実施例・比較例における各トリグリセリド含量は、「AOCS Official Method Ce 5c−93」に準拠して、高速液体クロマトグラフィー(HPLC)を用いてODSカラムにより分析した。
<Measurement of SSS content and total content of SSU and SUS>
Each triglyceride content in Examples and Comparative Examples was analyzed with an ODS column using high performance liquid chromatography (HPLC) according to “AOCS Official Method Ce 5c-93”.

<SSU含量/SUS含量の重量比率の分析>
SSU含量/SUS含量の重量比率の分析は、HPLCを用いて硝酸銀カラムにより分析した。分析条件は、「Journal of the American Oil Chemists Society,68,289−293,1991」に記載の方法に基づいて実施した。
<Analysis of weight ratio of SSU content / SUS content>
The weight ratio of SSU content / SUS content was analyzed with a silver nitrate column using HPLC. The analysis conditions were based on the method described in “Journal of the American Oil Chemistry Society, 68, 289-293, 1991”.

<ヨウ素価の測定>
ヨウ素価は、「日本油化学会制定、基準油脂分析試験法2.3.4.1−1996」に従い測定した。
<Measurement of iodine value>
The iodine value was measured according to “Establishment of Japan Oil Chemistry Society, Standard Oil Analysis Test Method 2.3.4.1-1996”.

<官能評価方法>
実施例・比較例で得られたトッピング用マーガリンの官能評価は、20℃で3時間温調後のものを、訓練された10名(男性5人、女性5人)のパネラーにより、以下の基準により実施し、それらの平均点を評価値とした。
(乳の風味)
5点:乳の風味が非常に強く、大変好ましい。
4点:乳の風味が強く、好ましい。
3点:乳の風味がやや強く、やや好ましい。
2点:乳の風味が弱く、もの足りない。
1点:乳の風味が感じられない。
(乳のコク)
5点:乳のコクが非常に強く、大変好ましい。
4点:乳のコクが強く、好ましい。
3点:乳のコクがやや強く、やや好ましい。
2点:乳のコクが弱く、もの足りない。
1点:乳のコクが感じられない。
<Sensory evaluation method>
The sensory evaluation of the margarine for toppings obtained in the examples and comparative examples was conducted by adjusting the temperature of the margarine for 3 hours at 20 ° C. for 3 hours by using 10 trained panelists (5 men and 5 women). The average score was taken as the evaluation value.
(Milk flavor)
5 points: The flavor of milk is very strong and very preferable.
4 points: The flavor of milk is strong and preferable.
3 points: Slightly strong and slightly preferred flavor of milk.
2 points: The flavor of milk is weak and unsatisfactory.
1 point: The flavor of milk is not felt.
(Body of milk)
5 points: The body of milk is very strong and very preferable.
4 points: The body of milk is strong and preferable.
3 points: The body of milk is slightly strong and slightly preferable.
2 points: The body of milk is weak and unsatisfactory.
1 point: The body of milk is not felt.

(製造例1) エステル交換油脂Aの作製
パーム核オレイン(ヨウ素価25、株式会社カネカ製)30重量部、パームステアリン(ヨウ素価32.5、株式会社カネカ製)47重量部、パーム油の極度硬化油(ヨウ素価1、株式会社カネカ製)23重量部を混合し、90℃、真空下で脱水を行った。そこへナトリウムメチラート0.30重量部を加え、90℃、窒素気流下で30分間ランダムエステル交換反応を行い、水を加えて反応停止後、水洗した。次に、活性白土3.0重量部を加え、減圧下で攪拌して20分後に全量濾過してエステル交換油脂Aを得た。
(Production Example 1) Production of transesterified fat / oil A 30 parts by weight of palm kernel olein (iodine value 25, manufactured by Kaneka Corporation), 47 parts by weight of palm stearin (iodine value 32.5, manufactured by Kaneka Corporation), extreme of palm oil 23 parts by weight of hardened oil (iodine value 1, manufactured by Kaneka Corporation) was mixed and dehydrated at 90 ° C. under vacuum. Thereto was added 0.30 part by weight of sodium methylate, and a random transesterification reaction was carried out at 90 ° C. under a nitrogen stream for 30 minutes. Water was added to stop the reaction, and the mixture was washed with water. Next, 3.0 parts by weight of activated clay was added, stirred under reduced pressure, and after 20 minutes, the whole amount was filtered to obtain a transesterified fat A.

(製造例2) エステル交換油脂Bの作製
パーム核オレイン(ヨウ素価25、株式会社カネカ製)26重量部、パーム油(ヨウ素価52、株式会社カネカ製)69重量部、パームステアリン(ヨウ素価32.5、株式会社カネカ製)5重量部を混合し、90℃、真空下で脱水を行った。そこへナトリウムメチラート0.30重量部を加え、90℃、窒素気流下で30分間ランダムエステル交換反応を行い、水を加えて反応停止後、水洗した。次に、活性白土3.0重量部を加え、減圧下で攪拌して20分後に全量濾過してエステル交換油脂Bを得た。
(Production Example 2) Production of transesterified oil and fat B Palm kernel olein (iodine value 25, manufactured by Kaneka Corporation) 26 parts by weight, palm oil (iodine value 52, manufactured by Kaneka Corporation) 69 parts by weight, palm stearin (iodine value 32) 0.5, manufactured by Kaneka Corporation) was mixed and dehydrated at 90 ° C. under vacuum. Thereto was added 0.30 part by weight of sodium methylate, and a random transesterification reaction was carried out at 90 ° C. under a nitrogen stream for 30 minutes. Water was added to stop the reaction, and the mixture was washed with water. Next, 3.0 parts by weight of activated clay was added, stirred under reduced pressure, and after 20 minutes, the whole amount was filtered to obtain a transesterified oil and fat B.

(製造例3) エステル交換油脂Cの作製
精製牛脂(株式会社カネカ製)90重量部、極度硬化ハイエルシン菜種油(ヨウ素価1、株式会社カネカ製)10重量部を混合し、90℃、真空下で脱水を行った。そこへナトリウムメチラート0.30重量部を加え、90℃、窒素気流下で30分間ランダムエステル交換反応を行い、水を加えて反応停止後、水洗した。次に、活性白土3.0重量部を加え、減圧下で攪拌して20分後に全量濾過してエステル交換油脂Cを得た。
(Production Example 3) Production of transesterified fat / oil C 90 parts by weight of refined beef tallow (manufactured by Kaneka Co., Ltd.) and 10 parts by weight of extremely hardened Hyelsin rapeseed oil (iodine value 1, manufactured by Kaneka Co., Ltd.) are mixed, and 90 ° C. under vacuum. Dehydration was performed. Thereto was added 0.30 part by weight of sodium methylate, and a random transesterification reaction was carried out at 90 ° C. under a nitrogen stream for 30 minutes. Water was added to stop the reaction, and the mixture was washed with water. Next, 3.0 parts by weight of activated clay was added, stirred under reduced pressure, and after 20 minutes, the whole amount was filtered to obtain a transesterified oil C.

(製造例4) エステル交換油脂Dの作製
パームスーパーオレイン(ヨウ素価65、株式会社カネカ製)100重量部を90℃、真空下で脱水を行った。そこへナトリウムメチラート0.30重量部を加え、90℃、窒素気流下で30分間ランダムエステル交換反応を行い、水を加えて反応停止後、水洗した。次に、活性白土3.0重量部を加え、減圧下で攪拌して20分後に全量濾過してエステル交換油脂Cを得た。
(Production Example 4) Production of transesterified oil and fat D 100 parts by weight of palm super olein (iodine value 65, manufactured by Kaneka Corporation) was dehydrated at 90 ° C under vacuum. Thereto was added 0.30 part by weight of sodium methylate, and a random transesterification reaction was carried out at 90 ° C. under a nitrogen stream for 30 minutes. Water was added to stop the reaction, and the mixture was washed with water. Next, 3.0 parts by weight of activated clay was added, stirred under reduced pressure, and after 20 minutes, the whole amount was filtered to obtain a transesterified oil C.

(製造例5) パーム系油脂のエステル交換油の分別液状部の作製
脱酸処理されたパームステアリン(ヨウ素価35、株式会社カネカ製)100重量部を500Paの減圧下90℃に加熱し、0.2重量部のナトリウムメチラートを加えて30分攪拌してランダムエステル交換し、水洗した後、500Paの減圧下、90℃で2重量部の白土を加えて脱色した。脱色後の油脂を、70℃に加熱して完全に溶解し、46℃で攪拌しながら24時間晶析した。晶析後3.0MPaでフィルタープレスして液状部を得た。得られた液状部を240℃、200Paの条件で1時間脱臭してヨウ素価43のエステル交換分別油脂を得た。
(Production Example 5) Preparation of fractionated liquid part of transesterified oil of palm oil and fat 100 parts by weight of deoxidized palm stearin (iodine value 35, manufactured by Kaneka Corporation) was heated to 90 ° C under reduced pressure of 500 Pa, 0 Then, 2 parts by weight of sodium methylate was added and stirred for 30 minutes for random transesterification, washed with water, and decolorized by adding 2 parts by weight of white clay at 90 ° C. under reduced pressure of 500 Pa. The oil and fat after decolorization was heated to 70 ° C. and completely dissolved, and crystallized for 24 hours while stirring at 46 ° C. After crystallization, filter pressing was performed at 3.0 MPa to obtain a liquid part. The obtained liquid part was deodorized for 1 hour under the conditions of 240 ° C. and 200 Pa to obtain a transesterified fractionated oil having an iodine value of 43.

(実施例1)油中水型乳化油脂組成物(トッピング用マーガリン)の作製
表1に示す配合に従い、油中水型乳化油脂組成物を作製した。即ち、エステル交換油脂A、エステル交換油脂B、エステル交換油脂C及び菜種油を70℃に加温・融解したところに、レシチン、グリセリン脂肪酸エステルおよび香料を混合して油相部を調製した。次に、60℃の温水に異性化液糖、マルトース水飴、加糖脱脂練乳、上白糖、脱脂粉乳、魚醤パウダー及び昆布エキスを撹拌混合して水相部を調製した。油相部に水相部を徐々に添加し、その後約60℃に温調し、プロペラミキサーにて攪拌混合し乳化液にした。その後、急冷捏和装置にて捏和して、出口温度を15℃としてトッピング用マーガリンを得た。
(Example 1) Preparation of water-in-oil emulsified oil / fat composition (margarine for topping) According to the formulation shown in Table 1, a water-in-oil emulsified oil / fat composition was prepared. That is, when the transesterified fat A, transesterified fat B, transesterified fat C, and rapeseed oil were heated and melted to 70 ° C., lecithin, glycerin fatty acid ester and fragrance were mixed to prepare an oil phase part. Next, isomerized liquid sugar, maltose starch syrup, sweetened defatted condensed milk, super white sugar, defatted powdered milk, fish soy powder and kelp extract were mixed with stirring in warm water at 60 ° C. to prepare an aqueous phase part. The aqueous phase portion was gradually added to the oil phase portion, then the temperature was adjusted to about 60 ° C., and the mixture was stirred and mixed with a propeller mixer to obtain an emulsion. Thereafter, the mixture was kneaded with a quenching kneader to obtain a margarine for topping at an outlet temperature of 15 ° C.

(実施例2〜4)油中水型乳化油脂組成物(トッピング用マーガリン)の作製
表1に示す配合に従い、魚醤パウダーの代わりに醤油、味噌又はオイスターソースを用い、水で全体量を調整した以外は実施例1と同様にしてトッピング用マーガリンを得た。
(Examples 2 to 4) Preparation of water-in-oil emulsified oil / fat composition (margarine for topping) According to the formulation shown in Table 1, soy sauce, miso or oyster sauce was used instead of fish soy powder, and the total amount was adjusted with water A margarine for topping was obtained in the same manner as in Example 1 except that.

(比較例1,2)油中水型乳化油脂組成物(トッピング用マーガリン)の作製
表1に示す配合に従い、魚醤パウダーと昆布エキスの配合比を変更し、水で全体量を調整した以外は実施例1と同様にしてトッピング用マーガリンを得た。
(Comparative Examples 1 and 2) Preparation of water-in-oil type emulsified oil / fat composition (margarine for topping) According to the formulation shown in Table 1, the mixing ratio of fish soy powder and kelp extract was changed, and the total amount was adjusted with water. Obtained margarine for topping in the same manner as in Example 1.

実施例1〜4、比較例1,2の油中水型乳化油脂組成物(トッピング用マーガリン)についての官能評価結果を表1に示す。   Table 1 shows the sensory evaluation results for the water-in-oil type emulsified oil / fat compositions of Examples 1 to 4 and Comparative Examples 1 and 2 (margarine for topping).

Figure 2016168002
Figure 2016168002

表1から明らかなように、発酵調味料と昆布エキスとを併用することで、トッピング用マーガリンに豊かな乳風味とコクが付与される。しかし、その配合比が本発明の範囲を外れると、トッピング用マーガリンの乳風味とコクが不足する。   As is apparent from Table 1, a rich milk flavor and richness are imparted to the margarine for topping by using the fermented seasoning and the kelp extract together. However, if the blending ratio is out of the range of the present invention, the milk flavor and richness of the margarine for topping are insufficient.

(実施例5〜7、比較例3,4)油中水型乳化油脂組成物(トッピング用マーガリン)の作製
表2に示す配合に従い、魚醤パウダーと昆布エキスの配合量を変更し、水で全体量を調整した以外は実施例1と同様にしてトッピング用マーガリンを得た。実施例5〜7、比較例3,4のトッピング用マーガリンについての官能評価結果を表2に示す。
(Examples 5 to 7, Comparative Examples 3 and 4) Preparation of water-in-oil emulsified oil / fat composition (margarine for topping) According to the formulation shown in Table 2, the blending amounts of fish soy powder and kelp extract were changed with water. A margarine for topping was obtained in the same manner as in Example 1 except that the total amount was adjusted. Table 2 shows the sensory evaluation results of the margarines for topping of Examples 5 to 7 and Comparative Examples 3 and 4.

Figure 2016168002
Figure 2016168002

表2から明らかなように、実施例のトッピング用マーガリンでは豊かな乳風味とコクが付与されている。しかし、発酵調味料と昆布エキスの含有量が本発明の範囲を外れると、トッピング用マーガリンの乳風味とコクが不足する。   As is clear from Table 2, the margarine for topping of the example has a rich milk flavor and richness. However, if the contents of the fermented seasoning and the kelp extract are outside the scope of the present invention, the milk flavor and richness of the margarine for topping are insufficient.

(実施例8〜10)油中水型乳化油脂組成物(トッピング用マーガリン)の作製
表3に示す配合に従い、脱脂粉乳の配合量を変更し、水で全体量を調整した以外は実施例1と同様にしてトッピング用マーガリンを得た。
(Examples 8 to 10) Preparation of water-in-oil type emulsified oil / fat composition (margarine for topping) According to the formulation shown in Table 3, the amount of skim milk powder was changed and the total amount was adjusted with water. In the same manner, margarine for topping was obtained.

(実施例11)油中水型乳化油脂組成物(トッピング用マーガリン)の作製
表3に示す配合に従い、脱脂粉乳の代わりにバターミルクパウダーを用い、水で全体量を調整した以外は実施例1と同様にしてトッピング用マーガリンを得た。
(Example 11) Preparation of water-in-oil type emulsified oil / fat composition (margarine for topping) Example 1 except that buttermilk powder was used instead of skim milk powder and the total amount was adjusted with water according to the formulation shown in Table 3. In the same manner, margarine for topping was obtained.

(比較例5)油中水型乳化油脂組成物(トッピング用マーガリン)の作製
表3に示す配合に従い、脱脂粉乳を配合せず、水で全体量を調整した以外は実施例1と同様にしてトッピング用マーガリンを得た。
(Comparative Example 5) Preparation of water-in-oil emulsified oil / fat composition (margarine for topping) According to the formulation shown in Table 3, the same procedure as in Example 1 was performed except that the skim milk powder was not blended and the total amount was adjusted with water. A margarine for topping was obtained.

実施例8〜11、比較例5のトッピング用マーガリンについての官能評価結果を、表3に示す。   Table 3 shows the sensory evaluation results of the margarines for toppings of Examples 8 to 11 and Comparative Example 5.

Figure 2016168002
Figure 2016168002

表3から明らかなように、実施例のトッピング用マーガリンでは豊かな乳風味とコクが付与されており、また無脂乳固形分の種類は、脱脂粉乳よりもバターミルクパウダーが豊かな乳風味とコクの点で好ましい。しかし、無脂乳固形分量が本発明の範囲を外れると、トッピング用マーガリン乳風味とコクが不足する。   As is apparent from Table 3, the margarine for topping of the example has a rich milk flavor and richness, and the type of non-fat milk solids is a milk flavor richer in buttermilk powder than skim milk powder. It is preferable in terms of richness. However, if the non-fat milk solid content is outside the scope of the present invention, the topping margarine milk flavor and richness are insufficient.

(実施例12)油中水型乳化油脂組成物(トッピング用マーガリン)の作製
表4に示す配合に従い、油脂として乳脂肪を加え、他の油脂の配合量を調整した以外は実施例11と同様にしてトッピング用マーガリンを得た。
(Example 12) Preparation of water-in-oil emulsified oil / fat composition (margarine for topping) According to the formulation shown in Table 4, milk fat was added as an oil and fat, and the amount of other oils and fats was adjusted. Thus, margarine for topping was obtained.

(実施例13)油中水型乳化油脂組成物(トッピング用マーガリン)の作製
表4に示す配合に従い、エステル交換油脂A、Bに代えてエステル交換油脂D及びパーム系油脂のエステル交換油の分別液状部(製造例5)を用い、他の油脂の配合量を調整した以外は実施例11と同様にしてトッピング用マーガリンを得た。
(Example 13) Preparation of water-in-oil type emulsified oil / fat composition (margarine for topping) According to the formulation shown in Table 4, transesterified oil / fat D, and transesterified oil of palm oil / fat instead of transesterified oil / fat A and B A margarine for topping was obtained in the same manner as in Example 11 except that the amount of other fats and oils was adjusted using the liquid part (Production Example 5).

(実施例14)油中水型乳化油脂組成物(トッピング用マーガリン)の作製
表4に示す配合に従い、エステル交換油脂A、Bに代えてエステル交換油脂D、パーム系油脂のエステル交換油の分別液状部(製造例5)及び乳脂肪を用い、他の油脂の配合量を調整した以外は実施例11と同様にしてトッピング用マーガリンを得た。
(Example 14) Preparation of water-in-oil type emulsified oil / fat composition (margarine for topping) According to the formulation shown in Table 4, transesterified fat / oil D instead of transesterified fat / oil A, separation of transesterified oil of palm oil / fat A margarine for topping was obtained in the same manner as in Example 11 except that the liquid part (Production Example 5) and milk fat were used and the amount of other fats and oils was adjusted.

実施例12〜14のトッピング用マーガリンについての官能評価結果を、表4に示す。   The sensory evaluation results for the margarines for toppings of Examples 12 to 14 are shown in Table 4.

Figure 2016168002
Figure 2016168002

表4から明らかなように、トッピング用マーガリンの油脂として乳脂肪やパーム系油脂のエステル交換油の分別液状部を用いることで、豊かな乳風味とコクを増強することができる。   As can be seen from Table 4, rich milk flavor and richness can be enhanced by using a fractionated liquid part of transesterified oil of milk fat or palm oil and fat as the fat and oil of margarine for topping.

Claims (8)

油中水型乳化油脂組成物全体中、油脂40〜97重量%、無脂乳固形分0.3〜5重量%(乾燥重量)、穀類及び/又は魚介類を原料とする発酵調味料及び昆布エキスを合計で0.05〜0.5重量%(乾燥重量)及び水分2〜40重量%を含有し、発酵調味料/昆布エキス(乾燥重量比)が95/5〜15/85であるフィリング・トッピング用油中水型乳化油脂組成物。 Fermented seasoning and kelp made from cereals and / or fishery products as raw materials in water-in-oil type emulsified oils and fats composition, fats and oils 40 to 97% by weight, non-fat milk solids 0.3 to 5% by weight (dry weight) Filling containing 0.05 to 0.5% by weight (dry weight) of extract and 2 to 40% by weight of moisture, and having a fermented seasoning / konbu extract (dry weight ratio) of 95/5 to 15/85 -A water-in-oil emulsified fat composition for topping. 発酵調味料が、魚醤、醤油、味噌、オイスターソースからなる群から選ばれる少なくとも1種である請求項1に記載のフィリング・トッピング用油中水型乳化油脂組成物。 The water-in-oil emulsified oil / fat composition for filling and topping according to claim 1, wherein the fermented seasoning is at least one selected from the group consisting of fish sauce, soy sauce, miso, and oyster sauce. 油中水型乳化油脂組成物全体中、糖類(乳糖を除く)を0.2〜40重量%(乾燥重量)含有する請求項1又は2に記載のフィリング・トッピング用油中水型乳化油脂組成物。 The water-in-oil emulsified fat / oil composition for filling and topping according to claim 1 or 2, comprising 0.2 to 40% by weight (dry weight) of sugars (excluding lactose) in the whole water-in-oil emulsified fat / oil composition. object. 油脂全体中、乳脂肪を0.1〜30重量%含有する請求項1〜3の何れかに記載のフィリング・トッピング用油中水型乳化油脂組成物。 The water-in-oil emulsified oil / fat composition for filling and topping according to any one of claims 1 to 3, wherein the fat / oil contains 0.1 to 30% by weight of milk fat. 油脂全体中、パーム系油脂のエステル交換油の分別液状部であり且つヨウ素価が35〜62の油脂を10〜70重量%含有する請求項1〜4の何れかに記載のフィリング・トッピング用油中水型乳化油脂組成物。 The oil for filling and topping according to any one of claims 1 to 4, which is a fractionated liquid part of a transesterified oil of palm-based fats and oils and contains 10 to 70% by weight of fats and oils having an iodine value of 35 to 62. A water-in-water emulsified oil / fat composition. パーム系油脂のエステル交換油の分別液状部であり且つヨウ素価が35〜62の油脂が、SSSを2〜13重量%含有し、SSUとSUSを合計で34〜54重量%含有し、(SSUとSUSの合計含量)/(SSS含量)の重量比率が4〜20且つ(SSU含量)/(SUS含量)の重量比率が1以上である請求項5に記載のフィリング・トッピング用油中水型乳化油脂組成物。
SSS:トリ飽和脂肪酸グリセリド
SSU:1,2−ジ飽和脂肪酸−3−モノ不飽和脂肪酸グリセリド(光学異性体を含む)
SUS:1,3−ジ飽和脂肪酸−2−モノ不飽和脂肪酸グリセリド
The oil-and-fat with a transesterified oil of palm-based oil and fat and having an iodine value of 35 to 62 contains 2 to 13% by weight of SSS, and contains 34 to 54% by weight of SSU and SUS in total (SSU The weight ratio of (SUS content) / (SSS content) is 4 to 20 and (SSU content) / (SUS content) is 1 or more in water-in-oil type for filling topping according to claim 5 An emulsified oil composition.
SSS: Trisaturated fatty acid glyceride SSU: 1,2-disaturated fatty acid-3-monounsaturated fatty acid glyceride (including optical isomers)
SUS: 1,3-disaturated fatty acid-2-monounsaturated fatty acid glyceride
穀類及び/又は魚介類を原料とする発酵調味料及び昆布エキスが、水相部に含まれる請求項1〜6の何れかに記載のフィリング・トッピング用油中水型乳化油脂組成物。 The water-in-oil emulsified oil / fat composition for filling and topping according to any one of claims 1 to 6, wherein a fermented seasoning and kelp extract made from cereals and / or seafood are contained in the aqueous phase. 請求項1〜7の何れかに記載のフィリング・トッピング用油中水型乳化油脂組成物を、フィリング又はトッピングしてなる食品。 A food obtained by filling or topping the water-in-oil emulsified oil / fat composition for filling and topping according to any one of claims 1 to 7.
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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2018171057A (en) * 2017-03-31 2018-11-08 株式会社カネカ Oil-and-fat composition for filling
WO2021177115A1 (en) * 2020-03-02 2021-09-10 ミヨシ油脂株式会社 Emulsified fat composition

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH10257851A (en) * 1997-03-18 1998-09-29 Asahi Denka Kogyo Kk Emulsified oil-and-fat composition and food using the composition
WO2012032945A1 (en) * 2010-09-10 2012-03-15 株式会社カネカ Method for producing tri-saturated fatty acid glyceride-containing fat compositions
JP2013233089A (en) * 2012-05-07 2013-11-21 Adeka Corp Flavor material and flavor improving oil-and-fat

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH10257851A (en) * 1997-03-18 1998-09-29 Asahi Denka Kogyo Kk Emulsified oil-and-fat composition and food using the composition
WO2012032945A1 (en) * 2010-09-10 2012-03-15 株式会社カネカ Method for producing tri-saturated fatty acid glyceride-containing fat compositions
JP2013233089A (en) * 2012-05-07 2013-11-21 Adeka Corp Flavor material and flavor improving oil-and-fat

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2018171057A (en) * 2017-03-31 2018-11-08 株式会社カネカ Oil-and-fat composition for filling
WO2021177115A1 (en) * 2020-03-02 2021-09-10 ミヨシ油脂株式会社 Emulsified fat composition

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