JP2016142758A5 - - Google Patents

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JP2016142758A5
JP2016142758A5 JP2015016035A JP2015016035A JP2016142758A5 JP 2016142758 A5 JP2016142758 A5 JP 2016142758A5 JP 2015016035 A JP2015016035 A JP 2015016035A JP 2015016035 A JP2015016035 A JP 2015016035A JP 2016142758 A5 JP2016142758 A5 JP 2016142758A5
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toner
less
fine particles
particles
organic
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JP2015016035A
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JP2016142758A (en
JP6478662B2 (en
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Claims (7)

結着樹脂を含有するコア、及び該コアの表面に形成されたポリエステル樹脂Aを含有するシェルを有するコアシェル構造のトナー粒子と、外添剤Aと、を有するトナーであって、
該ポリエステル樹脂Aの25℃、10000Hzにおける誘電正接が、0.0070以上0.0140以下であり、
該トナーが、前記結着樹脂100.0質量部に対して1.0質量部以上20.0質量部以下の該ポリエステル樹脂Aを含有し、
該外添剤Aが有機無機複合微粒子であり、
該有機無機複合微粒子は、有機樹脂粒子及び無機微粒子aを含有し、該無機微粒子a由来の凸部が表面に形成されるように、該有機樹脂粒子の表面に無機微粒子aが露出した粒子であり、
該有機無機複合微粒子の表面における無機微粒子aの存在率が、20%以上70%以下であることを特徴とするトナー。
A toner having a core-shell structure toner particle having a core containing a binder resin and a shell containing a polyester resin A formed on the surface of the core, and an external additive A,
The dielectric loss tangent of the polyester resin A at 25 ° C. and 10,000 Hz is 0.0070 or more and 0.0140 or less,
The toner contains 1.0 to 20.0 parts by mass of the polyester resin A with respect to 100.0 parts by mass of the binder resin.
The external additive A is organic-inorganic composite fine particles,
The organic-inorganic composite fine particles are particles in which the inorganic fine particles a are exposed on the surface of the organic resin particles so that convex portions derived from the inorganic fine particles a are formed on the surface. Yes,
A toner characterized in that the abundance of inorganic fine particles a on the surface of the organic / inorganic composite fine particles is 20% or more and 70% or less.
該ポリエステル樹脂Aは、式(1)で示されるイソソルビドユニットを、全モノマーユニットを基準として0.10mol%以上20.00mol%以下含有する請求項1に記載のトナー。
Figure 2016142758
2. The toner according to claim 1, wherein the polyester resin A contains 0.10 mol% or more and 20.00 mol% or less of an isosorbide unit represented by the formula (1) based on all monomer units.
Figure 2016142758
該ポリエステル樹脂Aの酸価が、0.5mgKOH/g以上25.0mgKOH/g以下である請求項1又は2に記載のトナー。   The toner according to claim 1, wherein the acid value of the polyester resin A is 0.5 mgKOH / g or more and 25.0 mgKOH / g or less. 該結着樹脂が、スチレンアクリル系樹脂である請求項1〜3のいずれか一項に記載のト
ナー。
The toner according to claim 1, wherein the binder resin is a styrene acrylic resin.
該トナー粒子が、懸濁重合トナー粒子である請求項1〜のいずれか一項に記載のトナー。 The toner particles The toner according to any one of claims 1 to 4, which is a suspension polymerization toner particles. 該有機無機複合粒子を倍率20万倍で測定したときの形状係数SF−2が、103以上120以下であり、
該有機無機複合粒子の個数平均粒径(A)が、50nm以上400nm以下である請求項1〜のいずれか一項に記載のトナー。
The shape factor SF-2 when the organic-inorganic composite particles are measured at a magnification of 200,000 times is 103 or more and 120 or less,
Organic number average particle diameter of the inorganic composite particles (A) The toner according to any one of claims 1 to 5, at 50nm or more 400nm or less.
該トナーが外添剤として無機微粒子bをさらに有し、
該無機微粒子bの個数平均粒径(B)が、5nm以上40nm以下であり、
該個数平均粒径(A)と該個数平均粒径(B)との比(A/B)が、1.5以上10.0以下である請求項に記載のトナー。
The toner further has inorganic fine particles b as an external additive,
The number average particle diameter (B) of the inorganic fine particles b is 5 nm or more and 40 nm or less,
The toner according to claim 6 , wherein a ratio (A / B) of the number average particle diameter (A) to the number average particle diameter (B) is 1.5 or more and 10.0 or less.
JP2015016035A 2015-01-29 2015-01-29 Toner and toner production method Active JP6478662B2 (en)

Priority Applications (1)

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JP2015016035A JP6478662B2 (en) 2015-01-29 2015-01-29 Toner and toner production method

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JP2015016035A JP6478662B2 (en) 2015-01-29 2015-01-29 Toner and toner production method

Publications (3)

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JP2016142758A JP2016142758A (en) 2016-08-08
JP2016142758A5 true JP2016142758A5 (en) 2018-03-15
JP6478662B2 JP6478662B2 (en) 2019-03-06

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Families Citing this family (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110998458A (en) * 2017-08-04 2020-04-10 佳能株式会社 Toner and image forming apparatus
JP2019032365A (en) * 2017-08-04 2019-02-28 キヤノン株式会社 toner
JP7091033B2 (en) * 2017-08-04 2022-06-27 キヤノン株式会社 toner
JP2019215511A (en) * 2018-06-11 2019-12-19 キヤノン株式会社 toner
DE102019132817B4 (en) * 2018-12-05 2022-09-29 Canon Kabushiki Kaisha toner
JP7281043B2 (en) * 2019-01-10 2023-05-25 京セラドキュメントソリューションズ株式会社 toner
JP7475916B2 (en) * 2020-03-24 2024-04-30 キヤノン株式会社 Toner and method for producing the same
JP2022166386A (en) 2021-04-21 2022-11-02 キヤノン株式会社 Toner and method for manufacturing toner
WO2023282886A1 (en) * 2021-07-06 2023-01-12 Hewlett-Packard Development Company, L.P. External additive for toner

Family Cites Families (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2006251400A (en) * 2005-03-10 2006-09-21 Fuji Xerox Co Ltd Image forming method and image forming apparatus
KR101296923B1 (en) * 2005-03-18 2013-08-14 바텔리 메모리얼 인스티튜트 Toner
JP4894876B2 (en) * 2009-03-25 2012-03-14 富士ゼロックス株式会社 Toner for developing electrostatic image, toner cartridge, process cartridge, and image forming apparatus
JP5539052B2 (en) * 2010-06-16 2014-07-02 キヤノン株式会社 toner
JP2012073304A (en) * 2010-09-28 2012-04-12 Tomoegawa Paper Co Ltd Electrophotographic toner
JP2013092748A (en) * 2011-10-26 2013-05-16 Cabot Corp Toner additives comprising composite particles
JP6107656B2 (en) * 2012-06-13 2017-04-05 三菱レイヨン株式会社 Polyester resin for toner, method for producing the same, and toner
EP2837970B8 (en) * 2013-07-31 2018-03-28 Canon Kabushiki Kaisha Toner
JP6410609B2 (en) * 2015-01-07 2018-10-24 キヤノン株式会社 toner
JP6541356B2 (en) * 2015-01-19 2019-07-10 キヤノン株式会社 toner

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