JP2016124277A5 - - Google Patents

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JP2016124277A5
JP2016124277A5 JP2015002613A JP2015002613A JP2016124277A5 JP 2016124277 A5 JP2016124277 A5 JP 2016124277A5 JP 2015002613 A JP2015002613 A JP 2015002613A JP 2015002613 A JP2015002613 A JP 2015002613A JP 2016124277 A5 JP2016124277 A5 JP 2016124277A5
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image recording
recording method
general formula
resin
ink
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JP2015002613A
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JP2016124277A (en
JP6472250B2 (en
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顔料及びアニオン性樹脂粒子を含有するインクを記録媒体に付与する工程と、前記インク中の前記顔料又は前記アニオン性樹脂粒子の分散状態を不安定化させる液体組成物を、前記インクを付与する領域と少なくとも一部で重なるように前記記録媒体に付与する工程と、を有する画像記録方法であって、
前記インクが、更に、下記一般式（１）で表されるユニットを有する樹脂、及び、下記一般式（２）で表されるユニットを有する樹脂から選択される少なくとも１種の樹脂Ｘを含有することを特徴とする画像記録方法。

（一般式（１）において、Ｒ１は水素原子又はメチル基を表し、Ｒ２は水素原子又は有機基を表す。）

（一般式（２）において、Ｒ１、Ｒ２及びＲ３はそれぞれ独立に水素原子又は有機基を表し、Ｘは単結合又は結合鎖を表し、Ｙは下記一般式（３）で表される構造又はアルキレンオキシ基を表す。）

（一般式（３）において、Ｒ４、Ｒ５及びＲ６はそれぞれ独立に水素原子又は有機基を表す。） A step of applying the ink containing the pigment and the anionic resin particles to the recording medium, and a region where the ink is applied to the liquid composition that destabilizes the dispersion state of the pigment or the anionic resin particles in the ink And applying to the recording medium so as to at least partially overlap with the image recording method,
The ink further contains at least one resin X selected from a resin having a unit represented by the following general formula (1) and a resin having a unit represented by the following general formula (2). An image recording method.

(In General Formula (1), R 1 represents a hydrogen atom or a methyl group, and R 2 represents a hydrogen atom or an organic group.)

(In General Formula (2), R 1 , R 2 and R 3 each independently represent a hydrogen atom or an organic group, X represents a single bond or a bond chain, and Y is represented by the following General Formula (3). Represents a structure or an alkyleneoxy group.)

(In general formula (3), R 4 , R 5 and R 6 each independently represents a hydrogen atom or an organic group.) インク全質量を基準とした、前記樹脂Ｘの含有量が、０．１質量％以上である請求項１に記載の画像記録方法。   The image recording method according to claim 1, wherein the content of the resin X is 0.1% by mass or more based on the total mass of the ink. インク全質量を基準とした、前記樹脂Ｘの含有量が、０．２質量％以上３．０質量％以下である請求項１に記載の画像記録方法。The image recording method according to claim 1, wherein the content of the resin X is 0.2% by mass or more and 3.0% by mass or less based on the total mass of the ink. インク全質量を基準とした、前記アニオン性樹脂粒子の含有量が、前記樹脂Ｘの含有量に対して、質量比率で１．５倍以上５０．０倍以下である請求項１乃至３の何れか１項に記載の画像記録方法。 The total mass of the ink as a reference, the content of the anionic resin particles, relative to the content of the resin X, any of claims 1 to 3 or less 50.0 × 1.5 times or more in mass ratio the image recording method according to any one of claims. 前記液体組成物は、多価金属イオン及び有機酸から選択される少なくとも１種を含有する請求項１乃至４の何れか１項に記載の画像記録方法。The image recording method according to claim 1, wherein the liquid composition contains at least one selected from polyvalent metal ions and organic acids. 前記記録媒体が中間転写体である請求項１乃至５の何れか１項に記載の画像記録方法。The image recording method according to claim 1, wherein the recording medium is an intermediate transfer member. 請求項１乃至６の何れか１項に記載の画像記録方法に用いることを特徴とするインク。 An ink for use in the image recording method according to any one of claims 1 to 6 . 顔料及びアニオン性樹脂粒子を含有するインクを記録媒体に付与する工程と、前記インク中の前記顔料又は前記アニオン性樹脂粒子の分散状態を不安定化させる液体組成物を、前記インクを付与する領域と少なくとも一部で重なるように前記記録媒体に付与する工程と、を有する画像記録方法であって、
前記液体組成物が、下記一般式（１）で表されるユニットを有する樹脂、及び、下記一般式（２）で表されるユニットを有する樹脂から選択される少なくとも１種の樹脂Ｘを含有することを特徴とする画像記録方法。

（一般式（１）において、Ｒ１は水素原子又はメチル基を表し、Ｒ２は水素原子又は有機基を表す。）

（一般式（２）において、Ｒ１、Ｒ２及びＲ３はそれぞれ独立に水素原子又は有機基を表し、Ｘは単結合又は結合鎖を表し、Ｙは下記一般式（３）で表される構造又はアルキレンオキシ基を表す。）

（一般式（３）において、Ｒ４、Ｒ５及びＲ６はそれぞれ独立に水素原子又は有機基を表す。） A step of applying the ink containing the pigment and the anionic resin particles to the recording medium, and a region where the ink is applied to the liquid composition that destabilizes the dispersion state of the pigment or the anionic resin particles in the ink And applying to the recording medium so as to at least partially overlap with the image recording method,
The liquid composition contains at least one resin X selected from a resin having a unit represented by the following general formula (1) and a resin having a unit represented by the following general formula (2). An image recording method.

(In General Formula (1), R 1 represents a hydrogen atom or a methyl group, and R 2 represents a hydrogen atom or an organic group.)

(In General Formula (2), R 1 , R 2 and R 3 each independently represent a hydrogen atom or an organic group, X represents a single bond or a bond chain, and Y is represented by the following General Formula (3). Represents a structure or an alkyleneoxy group.)

(In general formula (3), R 4 , R 5 and R 6 each independently represents a hydrogen atom or an organic group.) 液体組成物全質量を基準とした、前記樹脂Ｘの含有量が、２．０質量％以上である請求項８に記載の画像記録方法。 The image recording method according to claim 8 , wherein the content of the resin X is 2.0% by mass or more based on the total mass of the liquid composition. 液体組成物全質量を基準とした、前記樹脂Ｘの含有量が、５．０質量％以上４０．０質量％以下である請求項８に記載の画像記録方法。The image recording method according to claim 8, wherein the content of the resin X is 5.0% by mass or more and 40.0% by mass or less based on the total mass of the liquid composition. 液体組成物は、多価金属イオン及び有機酸から選択される少なくとも１種を含有する請求項８乃至１０の何れか１項に記載の画像記録方法。The image recording method according to claim 8, wherein the liquid composition contains at least one selected from polyvalent metal ions and organic acids. 前記記録媒体が中間転写体である請求項８乃至１１の何れか１項に記載の画像記録方法。The image recording method according to claim 8, wherein the recording medium is an intermediate transfer member. 請求項８乃至１２の何れか１項に記載の画像記録方法に用いることを特徴とする液体組成物。 A liquid composition for use in the image recording method according to any one of claims 8 to 12 . アニオン性樹脂粒子を含有するクリアインクを記録媒体に付与する工程と、前記クリアインク中の前記アニオン性樹脂粒子の分散状態を不安定化させる液体組成物を、前記クリアインクを付与する領域と少なくとも一部で重なるように前記記録媒体に付与する工程と、を有する画像記録方法であって、
前記クリアインクが、更に、下記一般式（１）で表されるユニットを有する樹脂、及び、下記一般式（２）で表されるユニットを有する樹脂から選択される少なくとも１種の樹脂Ｘを含有することを特徴とする画像記録方法。

（一般式（１）において、Ｒ１は水素原子又はメチル基を表し、Ｒ２は水素原子又は有機基を表す。）

（一般式（２）において、Ｒ１、Ｒ２及びＲ３はそれぞれ独立に水素原子又は有機基を表し、Ｘは単結合又は結合鎖を表し、Ｙは下記一般式（３）で表される構造又はアルキレンオキシ基を表す。）

（一般式（３）において、Ｒ４、Ｒ５及びＲ６はそれぞれ独立に水素原子又は有機基を表す。） A step of applying a clear ink containing anionic resin particles to a recording medium, and a liquid composition that destabilizes the dispersion state of the anionic resin particles in the clear ink, and at least a region to which the clear ink is applied Applying to the recording medium so as to partially overlap, an image recording method comprising:
The clear ink further contains at least one resin X selected from a resin having a unit represented by the following general formula (1) and a resin having a unit represented by the following general formula (2) And an image recording method.

(In General Formula (1), R 1 represents a hydrogen atom or a methyl group, and R 2 represents a hydrogen atom or an organic group.)

(In General Formula (2), R 1 , R 2 and R 3 each independently represent a hydrogen atom or an organic group, X represents a single bond or a bond chain, and Y is represented by the following General Formula (3). Represents a structure or an alkyleneoxy group.)

(In general formula (3), R 4 , R 5 and R 6 each independently represents a hydrogen atom or an organic group.) クリアインク全質量を基準とした、前記樹脂Ｘの含有量が、０．１質量％以上である請求項１４に記載の画像記録方法。The image recording method according to claim 14, wherein the content of the resin X is 0.1% by mass or more based on the total mass of the clear ink. クリアインク全質量を基準とした、前記樹脂Ｘの含有量が、０．２質量％以上３．０質量％以下である請求項１４に記載の画像記録方法。The image recording method according to claim 14, wherein the content of the resin X is 0.2% by mass or more and 3.0% by mass or less based on the total mass of the clear ink. クリアインク全質量を基準とした、前記アニオン性樹脂粒子の含有量が、前記樹脂Ｘの含有量に対して、質量比率で１．５倍以上５０．０倍以下である請求項１４乃至１６の何れか１項に記載の画像記録方法。The content of the anionic resin particles based on the total mass of the clear ink is 1.5 times or more and 50.0 times or less by mass ratio with respect to the content of the resin X. The image recording method according to claim 1. 前記液体組成物は、多価金属イオン及び有機酸から選択される少なくとも１種を含有する請求項１４乃至１７の何れか１項に記載の画像記録方法。The image recording method according to claim 14, wherein the liquid composition contains at least one selected from polyvalent metal ions and organic acids. 前記記録媒体が中間転写体である請求項１４乃至１８の何れか１項に記載の画像記録方法。The image recording method according to claim 14, wherein the recording medium is an intermediate transfer member.
JP2015002613A 2015-01-08 2015-01-08 Image recording method Active JP6472250B2 (en)

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JP2016124277A JP2016124277A (en) 2016-07-11
JP2016124277A5 true JP2016124277A5 (en) 2018-02-15
JP6472250B2 JP6472250B2 (en) 2019-02-20

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Family Cites Families (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2000336289A (en) * 1999-05-27 2000-12-05 Pentel Corp Ink for ink jet
JP5159008B2 (en) * 2001-07-19 2013-03-06 日本合成化学工業株式会社 Resin composition for recording sheet
JP3875081B2 (en) * 2001-11-19 2007-01-31 日本合成化学工業株式会社 Inkjet recording sheet
JP4694812B2 (en) * 2004-09-29 2011-06-08 日本合成化学工業株式会社 Recording medium
JP2007077383A (en) * 2005-03-31 2007-03-29 Seiko Epson Corp Water-based ink
JP2008163179A (en) * 2006-12-28 2008-07-17 Nippon Synthetic Chem Ind Co Ltd:The Resin composition and inkjet recording medium using the same
JP5484742B2 (en) * 2008-08-14 2014-05-07 富士フイルム株式会社 Inkjet recording liquid
JP2010065110A (en) * 2008-09-10 2010-03-25 Brother Ind Ltd Pigment ink for inkjet printing and evaluation method of pigment ink for inkjet printing
JP5813402B2 (en) * 2011-07-27 2015-11-17 日立マクセル株式会社 Water-based pigment ink for inkjet recording

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