JP2016067296A - Packed beverage including milk substitute composition - Google Patents

Packed beverage including milk substitute composition Download PDF

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JP2016067296A
JP2016067296A JP2014201177A JP2014201177A JP2016067296A JP 2016067296 A JP2016067296 A JP 2016067296A JP 2014201177 A JP2014201177 A JP 2014201177A JP 2014201177 A JP2014201177 A JP 2014201177A JP 2016067296 A JP2016067296 A JP 2016067296A
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milk
beverage
fat
vegetable oil
weight
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JP6474984B2 (en
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沙織 後藤
Saori Goto
沙織 後藤
亜季 松浦
Aki Matsuura
亜季 松浦
槙佑 長野
Shinsuke Nagano
槙佑 長野
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Kirin Beverage Corp
Kirin Brewery Co Ltd
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Kirin Brewery Co Ltd
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Abstract

PROBLEM TO BE SOLVED: To provide a packed beverage or a milk substitute composition, which has excellent milk-like natural taste and flavor while suppressing a milk fat-derived degradation odor generated by long-term storage of the packed beverage or the milk substitute composition.SOLUTION: Provided is a milk substitute composition in which a vegetable oil and fat and a specific amino acid and the like (or a specific free amino acid) are added or included in a specific weight ratio range. Also provided is a packed beverage in which a vegetable oil and fat and a specific amino acid and the like (or a specific free amino acid) are added or included in a specific weight ratio range, and an amount of the vegetable oil and fat added or included is a certain amount or more.SELECTED DRAWING: None

Description

本発明は、容器詰飲料又は乳代替組成物の長期保存により発生する乳脂肪由来の劣化臭が抑制されつつ、牛乳様の自然な味覚及び風味に優れた容器詰飲料又は乳代替組成物に関する。より詳しくは、植物油脂と特定のアミノ酸又はその塩(以下、「特定のアミノ酸等」とも表示する。)とを併用することによって、容器詰飲料又は乳代替組成物の長期保存により発生する乳脂肪由来の劣化臭を抑制しつつ、牛乳様の自然な味覚及び風味が付与された容器詰飲料又は乳代替組成物に関する。   The present invention relates to a packaged beverage or milk substitute composition excellent in milk-like natural taste and flavor while suppressing deterioration odor derived from milk fat generated by long-term storage of the packaged beverage or milk substitute composition. More specifically, milk fat generated by long-term storage of a packaged beverage or a milk substitute composition by using vegetable oil and fat together with a specific amino acid or a salt thereof (hereinafter also referred to as “specific amino acid etc.”). The present invention relates to a packaged beverage or a milk substitute composition to which a milk-like natural taste and flavor are imparted while suppressing a deterioration odor derived from the origin.

近年、嗜好性の多様化から、各種飲料が容器詰飲料として提供されている。中でも、乳入りコーヒー飲料や乳入り紅茶飲料などは、旧来より消費者に愛用されてきた嗜好性の高い飲料である。しかし、これらの容器詰乳入り飲料においては、含有される乳の乳脂肪や乳タンパク質が長期保存により酸化され易く、劣化臭(酸敗臭、オフフレーバーとも呼ばれる)が生じるという問題がある。   In recent years, various beverages have been provided as packaged beverages due to diversification of palatability. Among them, milk-containing coffee drinks and milk-containing tea drinks are drinks with high palatability that have been favored by consumers for a long time. However, these bottled milk-containing beverages have a problem that the milk fat and milk protein contained therein are easily oxidized by long-term storage, and a deteriorated odor (also referred to as an acid odor or off-flavor) occurs.

このような乳成分入り容器詰飲料における劣化臭を抑制する技術としていくつかの方法が開示されている。別の成分を添加することによって、その劣化臭を抑制する技術として、例えば、特開2004−248555号公報(特許文献1)には、発酵乳飲料において生じる特有の風味劣化を改善するために、カルシウム塩や、トレハロースを添加して、発酵乳飲料の酸臭味をマスキングする方法が、特開2008−86216号公報(特許文献2)には、乳飲料において、加熱又は光に曝される条件下において、乳成分の劣化を抑制するために乳飲料にトコフェロール及びルチンを含有させる方法が、特表2011−512798号公報(特許文献3)には、乳飲料にカテキン含有成分を添加することにより、乳脂肪の光酸化を防止して乳脂肪の酸敗を抑制し、乳飲料中の酸敗臭などの異臭を防止する方法が開示されている。   Several methods have been disclosed as techniques for suppressing the deterioration odor in such containered beverages containing milk components. As a technique for suppressing the deterioration odor by adding another component, for example, in JP 2004-248555 A (Patent Document 1), in order to improve the characteristic flavor deterioration that occurs in fermented milk beverages, Japanese Patent Application Laid-Open No. 2008-86216 (Patent Document 2) discloses a method for masking the acid odor of fermented milk beverages by adding calcium salt or trehalose. Below, in order to suppress the deterioration of milk components, a method of containing tocopherol and rutin in milk beverages is disclosed in JP 2011-512798 A (Patent Document 3) by adding a catechin-containing component to milk beverages. In addition, a method for preventing photooxidation of milk fat to suppress the rancidity of milk fat and preventing off-flavors such as rancidity in milk beverages is disclosed.

また、前述の劣化臭を、乳成分の一部又は全部を乳代替物に置換すること等によって抑制する技術として、例えば、特開平9−37713号公報(特許文献4)には、(A)炭素数10以下の脂肪酸の合計量が牛乳のそれの80重量%以下である脂肪分(例えば植物性脂肪)、および(B)無脂乳固形分、とを乳代替成分として用いることにより、乳風味飲料における牛乳(乳脂肪)由来の劣化臭を減少する方法が、国際公開第2012/124615号パンフレット(特許文献5)には、無脂乳固形分及び脂肪分を含んでなる飲料において、前述の脂肪分の70質量%以上を、特定の植物油脂(ヤシ油、ヒマワリ油及びそれらの混合物)とすることによって、乳脂肪などの乳成分の光劣化による飲料のオフフレーバーを抑制する方法が開示されている。また、例えば、国際公開2011/108633号パンフレット(特許文献6)には、コーヒーホワイトナーにおいて、タンパク質脱アミド酵素による処理が施されたカゼイン含有乳タンパク質溶液と、植物油脂とを用いることにより、合成乳化剤を用いずとも保存安定性、飲料への分散性を向上させ、合成乳化剤特有のエグ味、苦味による飲料の風味、味、食感の低下を低減する方法が開示されている。   In addition, as a technique for suppressing the above-mentioned deterioration odor by substituting a part or all of milk components with a milk substitute, for example, JP-A-9-37713 (Patent Document 4) includes (A) By using fats (for example, vegetable fat) in which the total amount of fatty acids having 10 or less carbon atoms is 80% by weight or less of that of milk, and (B) non-fat milk solids as milk substitute components, A method for reducing the deterioration odor derived from milk (milk fat) in flavored drinks is disclosed in International Publication No. 2012/124615 (Patent Document 5), in beverages comprising non-fat milk solids and fats. Disclosed is a method for suppressing off-flavor of beverages due to photodegradation of milk components such as milk fat by using 70% by mass or more of the fat content of the vegetable oil as specific vegetable oils (coconut oil, sunflower oil and mixtures thereof) It has been. In addition, for example, in International Publication 2011/108633 pamphlet (Patent Document 6), a coffee whitener uses a casein-containing milk protein solution that has been treated with a protein deamidase, and a vegetable oil. Disclosed is a method for improving storage stability and dispersibility in beverages without using an emulsifier, and reducing the flavor, taste, and texture of the beverage due to the taste and bitterness unique to synthetic emulsifiers.

このような、乳成分の一部又は全部を乳代替物に置換する方法は、長期保存による乳の劣化臭の主な原因となり得る乳脂肪の使用量を低減する方法であるため、その劣化臭の抑制という効果は得ることができた。しかし、このような従来の乳代替物は、牛乳様の味覚及び風味(乳感)を有してはいるものの、その程度は必ずしも十分ではなく、また、粉臭や、加熱乳原料に由来する異質な乳感が感じられるなど、特にその乳感の自然さ(牛乳本来の自然な乳感)という点で不十分であるという問題があった。   Such a method of replacing a part or all of milk components with a milk substitute is a method for reducing the amount of milk fat used, which can be a major cause of milk deterioration odor due to long-term storage. It was possible to obtain the effect of suppressing the above. However, although such a conventional milk substitute has a milk-like taste and flavor (milky feeling), the degree thereof is not always sufficient, and is derived from a powdery odor and a heated milk raw material. There was a problem that it was insufficient particularly in terms of the naturalness of the milky feeling (natural natural milky feeling of milk), such as the feeling of an unusual milky feeling.

ところで、各種アミノ酸は、食品添加物として使用されており、調味料や栄養強化剤として用いられている。アミノ酸の飲食品への添加のその他の目的として、例えば特開2008−178396号公報(特許文献7)には、高濃度の非重合体カテキン類に、アミノ酸と甘味料とを一定量配合した上で、非重合体カテキン類中のガレート体率を調整し、更にそのpHを特定範囲にすることにより、飲料本来の風味を保持し、かつ甘味料を含有するにもかかわらず長期の保存に優れた容器詰飲料を得る方法が開示されている。また、特許第5406050号公報(特許文献8)には、遊離アミノ酸として、バリン又はフェニルアラニンを含む疎水性アミノ酸、リジンを含む塩基性アミノ酸、及びグルタミン酸を含む酸性アミノ酸を含有させ、しかも、全遊離アミノ酸中、上記疎水性アミノ酸の含有量を30〜60質量%とし、上記塩基性アミノ酸の含有量を35〜65質量%とし、上記酸性アミノ酸の含有量を1〜20質量%とし、上記塩基性アミノ酸中、リジンの含有量を75〜100質量%とし、上記酸性アミノ酸中、グルタミン酸の含有量を80〜100質量%とすることにより、飲食品のコク味を強化するコク味強化剤を得る方法が開示されている。しかし、植物油脂と特定のアミノ酸等とを併用することによって、容器詰飲料又は乳代替組成物の長期保存により発生する乳脂肪由来の劣化臭を抑制しつつ、牛乳様の自然な味覚及び風味が付与された容器詰飲料や乳代替組成物が得られることはこれまでに報告されていない。   By the way, various amino acids are used as food additives and are used as seasonings and nutrient enhancers. As another purpose of adding amino acids to foods and drinks, for example, Japanese Patent Application Laid-Open No. 2008-178396 (Patent Document 7) contains a high concentration of non-polymer catechins and a certain amount of amino acids and sweeteners. By adjusting the percentage of gallate body in non-polymer catechins and further adjusting the pH to a specific range, it maintains the original flavor of the beverage and is excellent for long-term storage despite containing a sweetener. A method for obtaining a packaged beverage is disclosed. Japanese Patent No. 5406050 (Patent Document 8) contains, as free amino acids, a hydrophobic amino acid containing valine or phenylalanine, a basic amino acid containing lysine, and an acidic amino acid containing glutamic acid. Among them, the content of the hydrophobic amino acid is 30 to 60% by mass, the content of the basic amino acid is 35 to 65% by mass, the content of the acidic amino acid is 1 to 20% by mass, and the basic amino acid is Among them, a method of obtaining a rich taste enhancer that enhances the rich taste of food and drink by setting the content of lysine to 75 to 100% by mass and the content of glutamic acid in the acidic amino acid to 80 to 100% by mass. It is disclosed. However, by using vegetable oils and fats together with specific amino acids, etc., the milk-like natural taste and flavor can be reduced while suppressing the deterioration odor derived from milk fat caused by long-term storage of container-packed beverages or milk substitute compositions. It has not been reported so far that a given packaged beverage or milk replacement composition can be obtained.

特開2004−248555号公報JP 2004-248555 A 特開2008−86216号公報JP 2008-86216 A 特表2011−512798号公報Special table 2011-512798 gazette 特開平9−37713号公報JP-A-9-37713 国際公開第2012/124615号パンフレットInternational Publication No. 2012/124615 Pamphlet 国際公開2011/108633号パンフレットInternational publication 2011/108633 pamphlet 特開2008−178396号公報JP 2008-178396 A 特許第5406050号公報Japanese Patent No. 5406050

本発明の課題は、容器詰飲料又は乳代替組成物の長期保存により発生する乳脂肪由来の劣化臭が抑制されつつ、牛乳様の自然な味覚及び風味に優れた容器詰飲料又は乳代替組成物を提供することにある。   An object of the present invention is to provide a containerized beverage or milk substitute composition excellent in natural taste and flavor of milk while suppressing deterioration odor derived from milk fat generated by long-term storage of the packaged beverage or milk substitute composition. Is to provide.

牛乳は、水分と乳脂肪分と無脂乳固形分からなる。無脂乳固形分は、主として炭水化物(主に乳糖)や乳タンパク質からなり、微量成分としてミネラル(主にカルシウム)やビタミンを含んでいる。背景技術で述べたように、長期保存により発生する牛乳由来の劣化臭を抑制するために、劣化臭の主な原因である乳脂肪の少なくとも一部を植物油脂で代替し、乳脂肪以外の乳成分として脱脂粉乳等の無脂乳固形分や、カゼイン等の乳タンパク質を添加する方法は既に知られていた。しかし、そのような従来の乳代替物は、牛乳様の味覚及び風味(乳感)を有してはいるものの、その程度は必ずしも十分ではなく、また、粉臭や、加熱乳原料に由来する異質な乳感が感じられるなど、特にその乳感の自然さ(牛乳本来の自然な乳感)という点で不十分であり、容器詰飲料に用いても牛乳様の自然な味覚及び風味が十分に得られないという問題があった。   Milk is composed of moisture, milk fat and non-fat milk solids. Non-fat milk solids are mainly composed of carbohydrates (mainly lactose) and milk proteins, and contain minerals (mainly calcium) and vitamins as trace components. As described in the background art, in order to suppress the deterioration odor derived from milk caused by long-term storage, at least part of the milk fat that is the main cause of the deterioration odor is replaced with vegetable oils and fats other than milk fat. Methods for adding non-fat milk solids such as skim milk powder and milk proteins such as casein as ingredients have already been known. However, although such conventional milk substitutes have a milk-like taste and flavor (milky feeling), the degree thereof is not always sufficient, and is derived from powdered odors and heated milk raw materials. It is not enough in terms of the naturalness of the milky feeling (natural milky feeling inherent in milk), such as the feeling of extraordinary milkiness, and the milk-like natural taste and flavor are sufficient even when used in packaged beverages. There was a problem that could not be obtained.

このような問題に鑑み、本発明者らは、上記課題を解決するために、容器詰飲料又は乳代替組成物の長期保存により発生する乳脂肪由来の劣化臭を抑制しつつ、牛乳様の自然な味覚及び風味に優れた容器詰飲料又は乳代替組成物を製造する方法について鋭意検討する中で、乳代替組成物を含有若しくは添加する容器詰飲料の製造、又は、乳代替組成物の製造に際して、植物油脂と特定のアミノ酸等(又は特定の遊離アミノ酸)とを特定の範囲内の重量比率で添加又は含有させることによって、容器詰飲料又は乳代替組成物の長期保存により発生する乳脂肪由来の劣化臭を抑制しつつ、牛乳様の自然な味覚及び風味に優れた容器詰飲料又は乳代替組成物を得ることができることを見出し、本発明を完成するに至った。また、乳代替組成物を含有する若しくは添加された容器詰飲料に関してより詳しくは、かかる容器詰飲料の製造に際して、植物油脂と特定のアミノ酸等(又は特定の遊離アミノ酸)とを特定の範囲内の重量比率で添加又は含有させ、かつ、前述の植物油脂の添加量又は含有量を一定以上とすることによって、容器詰飲料の長期保存により発生する乳脂肪由来の劣化臭を抑制しつつ、牛乳様の自然な味覚及び風味に優れており、しかも、異味(塩味及び脂っぽさ)が抑制された容器詰飲料を得ることができることを見出し、本発明を完成するに至った。   In view of such problems, the present inventors have solved a milk-like nature while suppressing the deterioration odor derived from milk fat generated by long-term storage of a container-packed beverage or a milk substitute composition in order to solve the above problems. In the production of a packaged beverage containing or adding a milk replacer composition, or in the manufacture of a milk replacer composition, while intensively studying a method for producing a packaged beverage or a milk replacer composition excellent in taste and flavor It is derived from milk fat generated by long-term storage of a packaged beverage or a milk substitute composition by adding or containing vegetable fats and oils and specific amino acids (or specific free amino acids) at a weight ratio within a specific range. The present inventors have found that it is possible to obtain a packaged beverage or milk substitute composition excellent in milk-like natural taste and flavor while suppressing the deterioration odor, and have completed the present invention. Further, in more detail regarding the packaged beverage containing or added to the milk replacement composition, the vegetable oil and fat, the specific amino acid, etc. (or the specific free amino acid) are within a specific range in the production of the packaged beverage. Milk-like while suppressing deterioration odor derived from milk fat generated by long-term storage of container-packed beverages by adding or containing them in a weight ratio and making the amount or content of the above-mentioned vegetable fats or fats a certain level or more The present invention has been completed by finding that it is possible to obtain a packaged beverage that is excellent in the natural taste and flavor, and that has a different taste (salt taste and greasy).

なお、乳には、本発明で用いるような単量体のアミノ酸(遊離アミノ酸)は、含まれていない(検出限界以下)。もともと乳には含まれていない単量体のアミノ酸を植物油脂と組み合わせることによって、牛乳様の自然な味覚及び風味を得るという本発明の思想は、乳成分の一部を類似成分で代替するという従来の乳代替物の思想とは根本的に異なるものである。また、もともと乳には含まれていない単量体のアミノ酸を植物油脂と組み合わせることによって、牛乳様の自然な味覚及び風味に優れた容器詰飲料が得られるということは、当業者にとって、きわめて意外であった。   Milk does not contain monomeric amino acids (free amino acids) as used in the present invention (below the detection limit). The idea of the present invention to obtain a milk-like natural taste and flavor by combining a monomeric amino acid originally not contained in milk with vegetable oil is to replace a part of the milk component with a similar component. This is fundamentally different from the concept of conventional milk substitutes. In addition, it is extremely surprising for those skilled in the art that by combining a monomeric amino acid originally not contained in milk with a vegetable oil, a packaged beverage excellent in milk-like natural taste and flavor can be obtained. Met.

すなわち、本発明は
(1)容器詰飲料であって、
(a)植物油脂、及び、(b)遊離アスパラギン酸、遊離グリシン及び遊離シトルリンからなる群から選択される1種又は2種以上の遊離アミノ酸を含有し、
前記飲料における前記植物油脂の含有量が、前記飲料全量に対して0.35重量%以上であり、かつ、
前記飲料における前記植物油脂の含有量に対する、前記飲料における前記遊離アミノ酸の合計含有量の重量比率が、1.5〜25%の範囲内であることを特徴とする、
長期保存による乳脂肪由来の劣化臭が抑制されつつ、牛乳様の自然な味覚及び風味に優れた容器詰飲料や、
(2)飲料における植物油脂の含有量に対する、飲料における遊離アミノ酸の合計含有量の重量比率が、3〜16%の範囲内であることを特徴とする上記(1)に記載の容器詰飲料や、
(3)飲料における植物油脂の含有量が、飲料全量に対して0.35〜2.5重量%の範囲内であることを特徴とする上記(1)又は(2)に記載の容器詰飲料に関する。
That is, the present invention is (1) a packaged beverage,
(A) vegetable oil and fat, and (b) one or more free amino acids selected from the group consisting of free aspartic acid, free glycine and free citrulline,
The content of the vegetable oil in the beverage is 0.35% by weight or more based on the total amount of the beverage, and
The weight ratio of the total content of the free amino acids in the beverage to the content of the vegetable oil in the beverage is in the range of 1.5 to 25%,
Bottled beverages with excellent milk-like natural taste and flavor while suppressing deterioration odor derived from milk fat due to long-term storage,
(2) The weight ratio of the total content of free amino acids in the beverage to the content of vegetable oil in the beverage is in the range of 3 to 16%, ,
(3) The packaged beverage according to (1) or (2) above, wherein the content of vegetable oil in the beverage is in the range of 0.35 to 2.5% by weight relative to the total amount of the beverage About.

また、本発明は、
(4)植物油脂を含有する乳代替組成物において、
アスパラギン酸塩、アスパラギン酸、グリシン、グリシン塩、シトルリン及びシトルリン塩からなる群から選択される1種又は2種以上のアミノ酸又はその塩が添加され、かつ、
前記乳代替組成物における前記植物油脂の添加量に対する、前記乳代替組成物における前記アミノ酸又はその塩の合計添加量の重量比率が、2〜30%の範囲内に調整されたことを特徴とする、長期保存による乳脂肪由来の劣化臭が抑制されつつ、牛乳様の自然な味覚及び風味に優れた乳代替組成物に関する。
The present invention also provides:
(4) In a milk substitute composition containing vegetable oils and fats,
One or more amino acids selected from the group consisting of aspartate, aspartate, glycine, glycine salt, citrulline and citrulline salt or a salt thereof are added; and
The weight ratio of the total addition amount of the amino acid or the salt thereof in the milk substitute composition to the addition amount of the vegetable oil or fat in the milk substitute composition is adjusted within a range of 2 to 30%. Furthermore, the present invention relates to a milk substitute composition excellent in milk-like natural taste and flavor while suppressing deterioration odor derived from milk fat due to long-term storage.

さらに、本発明は、
(5)容器詰飲料において、
(a)植物油脂、及び、(b)アスパラギン酸塩、アスパラギン酸、グリシン、グリシン塩、シトルリン及びシトルリン塩からなる群から選択される1種又は2種以上のアミノ酸又はその塩が添加され、
前記飲料における前記植物油脂の添加量が、前記飲料全量に対して0.35重量%以上であり、かつ、
前記飲料における前記植物油脂の添加量に対する、前記飲料における前記アミノ酸又はその塩の合計添加量の重量比率が、2〜30%の範囲内に調整されたことを特徴とする、
長期保存による乳脂肪由来の劣化臭が抑制されつつ、牛乳様の自然な味覚及び風味に優れた容器詰飲料や、
(6)容器詰飲料が、容器詰乳飲料又は容器詰乳入り飲料であることを特徴とする上記(1)〜(3)及び(5)のいずれかに記載の容器詰飲料に関する。
Furthermore, the present invention provides
(5) In packaged beverages,
(A) vegetable oil and fat, and (b) one or more amino acids selected from the group consisting of aspartate, aspartic acid, glycine, glycine salt, citrulline and citrulline salt or salts thereof are added,
The amount of the vegetable oil in the beverage is 0.35% by weight or more based on the total amount of the beverage, and
The weight ratio of the total addition amount of the amino acid or salt thereof in the beverage to the addition amount of the vegetable fat in the beverage is adjusted within a range of 2 to 30%,
Bottled beverages with excellent milk-like natural taste and flavor while suppressing deterioration odor derived from milk fat due to long-term storage,
(6) The packaged beverage according to any one of (1) to (3) and (5) above, wherein the packaged beverage is a packaged milk beverage or a packaged milk-containing beverage.

本発明は、容器詰飲料又は乳代替組成物の長期保存により発生する乳脂肪由来の劣化臭が抑制されつつ、牛乳様の自然な味覚及び風味に優れた容器詰飲料又は乳代替組成物を提供する。容器詰飲料に関してより詳しくは、容器詰飲料の長期保存により発生する乳脂肪由来の劣化臭を抑制しつつ、牛乳様の自然な味覚及び風味に優れており、しかも、異味(塩味及び脂っぽさ)が抑制された容器詰飲料を提供する。   The present invention provides a packaged beverage or milk substitute composition excellent in milk-like natural taste and flavor while suppressing deterioration odor derived from milk fat generated by long-term storage of the packaged beverage or milk substitute composition To do. More specifically regarding container-packed beverages, it has excellent milk-like natural taste and flavor while suppressing the deterioration odor derived from milk fat caused by long-term storage of container-packed beverages, and it also has a different taste (salt taste and greasy) The present invention provides a packaged beverage in which (a) is suppressed.

本発明は、
(I)植物油脂を含有する乳代替組成物において、
アスパラギン酸塩、アスパラギン酸、グリシン、グリシン塩、シトルリン及びシトルリン塩からなる群から選択される1種又は2種以上のアミノ酸又はその塩が添加され、かつ、
前記乳代替組成物における前記植物油脂の添加量(又は含有量)に対する、前記乳代替組成物における前記アミノ酸又はその塩の合計添加量の重量比率が、2〜30%の範囲内に調整されたことを特徴とする、
長期保存により発生する乳脂肪由来の劣化臭が抑制されつつ、牛乳様の自然な味覚及び風味に優れた乳代替組成物(以下、単に「本発明の乳代替組成物」とも表示する)、及びその製造方法:
(II)容器詰飲料であって、
(a)植物油脂、及び、(b)遊離アスパラギン酸、遊離グリシン及び遊離シトルリンからなる群から選択される1種又は2種以上の遊離アミノ酸を含有し、
前記飲料における前記植物油脂の含有量(又は添加量)が、前記飲料全量に対して0.35重量%以上であり、かつ、
前記飲料における前記植物油脂の含有量(又は添加量)に対する、前記飲料における前記遊離アミノ酸の合計含有量の重量比率が、1.5〜25%の範囲内であることを特徴とする、
長期保存による乳脂肪由来の劣化臭が抑制されつつ、牛乳様の自然な味覚及び風味に優れた容器詰飲料、及びその製造方法:及び、
(III)容器詰飲料において、
(a)植物油脂、及び、(b)アスパラギン酸塩、アスパラギン酸、グリシン、グリシン塩、シトルリン及びシトルリン塩からなる群から選択される1種又は2種以上のアミノ酸又はその塩が添加され、
前記飲料における前記植物油脂の添加量(又は含有量)が、前記飲料全量に対して0.35重量%以上であり、かつ、
前記飲料における前記植物油脂の添加量(又は含有量)に対する、前記飲料における前記アミノ酸又はその塩の合計添加量の重量比率が、2〜30%の範囲内に調整されたことを特徴とする、
長期保存による乳脂肪由来の劣化臭が抑制されつつ、牛乳様の自然な味覚及び風味に優れた容器詰飲料、及びその製造方法からなる。なお、本発明における特定の遊離アミノ酸には、特定の遊離アミノ酸のイオン(アミノ酸の塩に由来するものを含む)が含まれる。
The present invention
(I) In the milk substitute composition containing vegetable oil and fat,
One or more amino acids selected from the group consisting of aspartate, aspartate, glycine, glycine salt, citrulline and citrulline salt or a salt thereof are added; and
The weight ratio of the total added amount of the amino acid or the salt thereof in the milk replaceable composition to the added amount (or content) of the vegetable oil or fat in the milk replaceable composition was adjusted within a range of 2 to 30%. It is characterized by
A milk replacement composition excellent in the natural taste and flavor of milk (hereinafter also simply referred to as “the milk replacement composition of the present invention”) while suppressing the deterioration odor derived from milk fat generated by long-term storage, and Its manufacturing method:
(II) a packaged beverage,
(A) vegetable oil and fat, and (b) one or more free amino acids selected from the group consisting of free aspartic acid, free glycine and free citrulline,
The content (or addition amount) of the vegetable oil in the beverage is 0.35% by weight or more based on the total amount of the beverage, and
The weight ratio of the total content of the free amino acids in the beverage to the content (or addition amount) of the vegetable oil in the beverage is in the range of 1.5 to 25%,
A packaged beverage excellent in milk-like natural taste and flavor while suppressing deterioration odor derived from milk fat due to long-term storage, and a method for producing the same:
(III) In packaged beverages,
(A) vegetable oil and fat, and (b) one or more amino acids selected from the group consisting of aspartate, aspartic acid, glycine, glycine salt, citrulline and citrulline salt or salts thereof are added,
The amount (or content) of the vegetable oil / fat in the beverage is 0.35% by weight or more based on the total amount of the beverage, and
The weight ratio of the total addition amount of the amino acid or salt thereof in the beverage to the addition amount (or content) of the vegetable oil or fat in the beverage is adjusted within a range of 2 to 30%,
It consists of a packaged beverage excellent in milk-like natural taste and flavor, and a method for producing the same, while suppressing deterioration odor derived from milk fat due to long-term storage. The specific free amino acids in the present invention include specific free amino acid ions (including those derived from amino acid salts).

1.(本発明(I)の乳代替組成物)
長期保存により発生する乳脂肪由来の劣化臭が抑制されつつ、牛乳様の自然な味覚及び風味に優れた本発明の乳代替組成物は、植物油脂を含有する乳代替組成物において、アスパラギン酸塩、アスパラギン酸、グリシン、グリシン塩、シトルリン及びシトルリン塩からなる群から選択される1種又は2種以上のアミノ酸又はその塩が添加され、かつ、前記乳代替組成物における前記植物油脂の添加量(又は含有量)に対する、前記乳代替組成物における前記アミノ酸又はその塩の合計添加量の重量比率が、2〜30%の範囲内に調整されたものである限り特に制限されない。
1. (Milk replacement composition of the present invention (I))
The milk substitute composition of the present invention, which is superior in milk-like natural taste and flavor while suppressing the deterioration odor derived from milk fat generated by long-term storage, is an aspartate in a milk substitute composition containing vegetable oils and fats. , One or more amino acids selected from the group consisting of aspartic acid, glycine, glycine salt, citrulline and citrulline or salts thereof are added, and the amount of the vegetable oil or fat added in the milk substitute composition ( Or the content) is not particularly limited as long as the weight ratio of the total addition amount of the amino acid or salt thereof in the milk substitute composition is adjusted within the range of 2 to 30%.

<本発明に用いる特定のアミノ酸等>
本発明に用いる特定のアミノ酸等としては、アスパラギン酸塩、アスパラギン酸、グリシン、グリシン塩、シトルリン及びシトルリン塩からなる群から選択される1種又は2種以上である限り特に制限されないが、牛乳様の自然な味覚及び風味により優れた乳代替組成物又は容器詰飲料を得る観点から、アスパラギン酸塩、アスパラギン酸、グリシン、シトルリンからなる群から選択される1種又は2種以上であることが好ましく、アスパラギン酸塩、グリシン、シトルリンからなる群から選択される1種又は2種以上であることがより好ましく、アスパラギン酸ナトリウム、グリシン、シトルリンからなる群から選択される1種又は2種以上であることがさらに好ましく、アスパラギン酸ナトリウムが特に好ましい。また、本発明において2種以上の特定のアミノ酸等を併用する場合、牛乳様の自然な味覚及び風味により優れた乳代替組成物又は容器詰飲料を得る観点から、特定のアミノ酸等のうち少なくとも1種は、アスパラギン酸塩又はアスパラギン酸であることが好ましく、アスパラギン酸塩であることがより好ましく、アスパラギン酸ナトリウムであることがさらに好ましい。本発明において2種以上の特定のアミノ酸等を併用する場合、牛乳様の自然な味覚及び風味により優れた乳代替組成物又は容器詰飲料を得る観点から、乳代替組成物又は容器詰飲料における、特定のアミノ酸等の添加量に対するアスパラギン酸ナトリウムの添加量の重量比率が好ましくは30%以上、より好ましくは50%以上、さらに好ましくは70%以上である態様を好適に挙げることができる。また、乳代替組成物又は容器詰飲料中の総アミノ酸(ただし単量体のアミノ酸に限る)の含有量に対する、特定のアミノ酸等の合計含有量の重量比率(%)は特に制限されないが、牛乳様の自然な味覚及び風味により優れた乳代替組成物又は容器詰飲料を得る観点から、30%以上であることが好ましく、50%以上であることがより好ましく、70%以上であることがさらに好ましい。
<Specific amino acids used in the present invention>
The specific amino acid used in the present invention is not particularly limited as long as it is one or more selected from the group consisting of aspartate, aspartate, glycine, glycine salt, citrulline and citrulline salt, but milk-like From the viewpoint of obtaining a milk substitute composition or a container-packed beverage that is superior in its natural taste and flavor, it is preferably one or more selected from the group consisting of aspartate, aspartic acid, glycine, and citrulline. More preferably, one or more selected from the group consisting of aspartate, glycine and citrulline, and one or more selected from the group consisting of sodium aspartate, glycine and citrulline More preferably, sodium aspartate is particularly preferable. Moreover, when using together 2 or more types of specific amino acids etc. in this invention, from a viewpoint of obtaining the milk substitute composition or container-packed drink which was excellent with the natural taste and flavor of milk-like, at least 1 of specific amino acids etc. The species is preferably aspartate or aspartate, more preferably aspartate, and even more preferably sodium aspartate. In the case of using two or more kinds of specific amino acids or the like in the present invention, from the viewpoint of obtaining a milk replacement composition or a container-packed beverage that is superior to a milk-like natural taste and flavor, An embodiment in which the weight ratio of the added amount of sodium aspartate to the added amount of the specific amino acid is preferably 30% or more, more preferably 50% or more, and further preferably 70% or more can be mentioned. In addition, the weight ratio (%) of the total content of specific amino acids to the content of total amino acids (but not limited to monomeric amino acids) in the milk substitute composition or packaged beverage is not particularly limited, but milk From the viewpoint of obtaining a milk substitute composition or a container-packed beverage that is more excellent in such natural taste and flavor, it is preferably 30% or more, more preferably 50% or more, and further preferably 70% or more. preferable.

なお、本発明に用いる特定のアミノ酸等は、単量体(モノマー)のアミノ酸又はその塩を意味し、ペプチドやタンパク質等の多量体(ポリマー)のアミノ酸は含まない。なお、本発明に用いる特定のアミノ酸等としては、かかるアミノ酸等の精製品(例えば、かかるアミノ酸等の合計含有量が90重量%以上のもの)が好ましいが、本発明の効果が得られる限り、本発明に用いる特定のアミノ酸等の含有物であってもよい。かかる含有物としては、本発明に用いる特定のアミノ酸等の合計含有量が、1重量%以上、好ましくは3重量%以上、より好ましくは10重量%以上、さらに好ましくは30重量%以上、より好ましくは50重量%以上さらに好ましくは80重量%以上のものを好適に挙げることができる。   The specific amino acid or the like used in the present invention means a monomeric amino acid or a salt thereof, and does not include a multimeric amino acid such as a peptide or protein. In addition, as a specific amino acid etc. used for this invention, refined products, such as this amino acid (For example, the total content of such an amino acid etc. is 90 weight% or more), but as long as the effect of this invention is acquired, It may be a substance such as a specific amino acid used in the present invention. As such a content, the total content of specific amino acids and the like used in the present invention is 1% by weight or more, preferably 3% by weight or more, more preferably 10% by weight or more, still more preferably 30% by weight or more, more preferably Suitable examples include those having a weight of 50% by weight or more, more preferably 80% by weight or more.

上記のアミノ酸の塩としては、薬理学的に許容されるものであれば特に制限されない。アミノ酸におけるカルボキシル基等の酸性基に対しては、ナトリウム、カリウム等のアルカリ金属との塩、カルシウム、マグネシウム等のアルカリ土類金属との塩、アンモニウム塩、アルミニウム塩、亜鉛塩、トリエチルアミン、エタノールアミン、モルホリン、ピロリジン、ピペリジン、ピペラジン、ジシクロへキシルアミン等の有機アミンとの塩が挙げられ、中でも、ナトリウム、カリウム等のアルカリ金属との塩や、カルシウム、マグネシウム等のアルカリ土類金属との塩が好ましく挙げられ、中でも、ナトリウム、カリウム等のアルカリ金属との塩がより好ましく挙げられ、中でもナトリウムとの塩がさらに好ましく挙げられる。また、アミノ酸における塩基性基に対しては、塩酸、硫酸、リン酸、硝酸、臭化水素酸などの無機酸との塩、酢酸、クエン酸、安息香酸、マレイン酸、フマル酸、酒石酸、コハク酸、タンニン酸、酪酸、ヒベンズ酸、パモ酸、エナント酸、デカン酸、テオクル酸、サリチル酸、乳酸、シュウ酸、マンデル酸、リンゴ酸等の有機カルボン酸との塩、メタンスルホン酸、ベンゼンスルホン酸、p−トルエンスルホン酸等の有機スルホン酸との塩が挙げられる。   The amino acid salt is not particularly limited as long as it is pharmacologically acceptable. For acidic groups such as carboxyl groups in amino acids, salts with alkali metals such as sodium and potassium, salts with alkaline earth metals such as calcium and magnesium, ammonium salts, aluminum salts, zinc salts, triethylamine, ethanolamine And salts with organic amines such as morpholine, pyrrolidine, piperidine, piperazine and dicyclohexylamine. Among them, salts with alkali metals such as sodium and potassium, and salts with alkaline earth metals such as calcium and magnesium. Among them, preferred are salts with alkali metals such as sodium and potassium, and more preferred are salts with sodium. For basic groups in amino acids, salts with inorganic acids such as hydrochloric acid, sulfuric acid, phosphoric acid, nitric acid, hydrobromic acid, acetic acid, citric acid, benzoic acid, maleic acid, fumaric acid, tartaric acid, succinic acid Acid, tannic acid, butyric acid, hybenzic acid, pamoic acid, enanthic acid, decanoic acid, teocric acid, salicylic acid, lactic acid, oxalic acid, mandelic acid, salt with organic carboxylic acid such as malic acid, methanesulfonic acid, benzenesulfonic acid And salts with organic sulfonic acids such as p-toluenesulfonic acid.

本発明に用いるアミノ酸等は、市販されているものを用いることができる。   As the amino acid and the like used in the present invention, those commercially available can be used.

<植物油脂>
本発明に用いる植物油脂としては、特に制限されないが、JAS規格に規定されている食用植物油脂などの、食品に通常使用されるものを用いることができ、例えば、ヤシ油(ココナッツ油)、パーム核油、パーム油、ナタネ油、綿実油、コーン油、ヒマワリ油、大豆油、及び、それらを硬化又は分別したものからなる群から選択される1種又は2種以上の植物油脂が挙げられ、牛乳様の自然な味覚及び風味により優れた乳代替組成物又は容器詰飲料を得る観点から、ヤシ油、パーム油、及び、それらを硬化又は分別したものからなる群から選択される1種又は2種以上の植物油脂が好ましく挙げられる。中でも、常温、特に20〜30℃付近で液状の脂肪は、オイルオフ(脂肪分離)を起こし難い利点があるため、好適に使用される。なお、本発明に用いる植物油脂としては、植物油脂の精製品であることが好ましいが、本発明の効果が得られる限り、植物油脂の含有物であってもよい。かかる含有物としては、植物油脂を30重量%以上、好ましくは50重量%以上、より好ましくは80重量%以上のものを好適に挙げることができる。
<Vegetable oils and fats>
Although it does not restrict | limit especially as vegetable oil and fat used for this invention, What is normally used for foodstuffs, such as edible vegetable oil and fat prescribed | regulated to JAS specification, can be used, for example, palm oil (coconut oil), palm 1 or 2 or more types of vegetable oils and fats selected from the group consisting of kernel oil, palm oil, rapeseed oil, cottonseed oil, corn oil, sunflower oil, soybean oil, and those obtained by curing or separating them, and milk 1 or 2 types selected from the group consisting of coconut oil, palm oil, and those obtained by curing or fractionating them, from the viewpoint of obtaining a milk substitute composition or a container-packed beverage superior in natural taste and flavor The above vegetable oils and fats are preferably mentioned. Among these, liquid fat at room temperature, particularly around 20 to 30 ° C., is advantageously used because it has the advantage of hardly causing oil-off (fat separation). The vegetable oil used in the present invention is preferably a refined vegetable oil, but may be a vegetable oil-containing material as long as the effects of the present invention are obtained. Suitable examples of such inclusions include vegetable oils and fats having a content of 30% by weight or more, preferably 50% by weight or more, and more preferably 80% by weight or more.

本発明に用いる植物油脂は、市販のものを用いることができる。   Commercial vegetable oils and fats used in the present invention can be used.

本発明の乳代替組成物における特定のアミノ酸等や植物油脂の使用量としては、特に制限されないが、乳代替組成物における植物油脂の添加量(又は含有量)に対する、乳代替組成物における特定のアミノ酸等の合計添加量の重量比率は2〜30%の範囲内に調整されている。好適な該重量比率としては、牛乳様のより自然な味覚及び風味を得る観点、及び、該乳代替組成物を飲料に添加した際の飲料における乳感と異味とのバランスの観点から、好ましくは2.3〜28%の範囲内、より好ましくは4〜22%の範囲内、さらに好ましくは4.7〜19%の範囲内を挙げることができる。   The amount of specific amino acids and the like used in the milk substitute composition of the present invention and the amount of vegetable oil / fat are not particularly limited, but the specific amount in the milk substitute composition relative to the amount (or content) of the vegetable oil / fat in the milk substitute composition is not limited. The weight ratio of the total addition amount of amino acids and the like is adjusted within a range of 2 to 30%. The preferred weight ratio is preferably from the viewpoint of obtaining a more natural taste and flavor like milk, and from the viewpoint of the balance between the milky feeling and the taste in the beverage when the milk replacement composition is added to the beverage. Within the range of 2.3 to 28%, more preferably within the range of 4 to 22%, and even more preferably within the range of 4.7 to 19%.

本発明の乳代替組成物における植物油脂の使用量としては、前述したように特に制限されないが、乳代替組成物全量に対して例えば20〜95重量%の範囲内、好ましくは30〜80重量%の範囲内を挙げることができる。また、本発明の乳代替組成物における特定のアミノ酸等の使用量も特に制限されないが、乳代替組成物全量に対して例えば、0.4〜28.5重量%の範囲内、好ましくは、0.6〜24重量%の範囲内を挙げることができる。   The amount of vegetable oil / fat used in the milk substitute composition of the present invention is not particularly limited as described above, but it is, for example, in the range of 20 to 95% by weight, preferably 30 to 80% by weight, based on the total amount of the milk substitute composition. Can be included in the range. Further, the amount of specific amino acids and the like used in the milk replacer composition of the present invention is not particularly limited, but is within the range of, for example, 0.4 to 28.5% by weight, preferably 0, relative to the total amount of the milk replacer composition. In the range of 6 to 24% by weight.

本発明の乳代替組成物においては、植物油脂及び特定のアミノ酸等の他に、乳代替組成物の製造に際して通常用いられている添加成分を、本発明の効果を損なわない範囲で添加することができる。かかる添加成分としては、水、糖類、甘味料、酸味料、ビタミン類、ミネラル類、香料、有機酸、有機塩基、乳化剤、増粘剤、酸化防止剤、pH調整剤等が挙げられる。   In the milk substitute composition of the present invention, in addition to vegetable fats and oils and specific amino acids, additives that are usually used in the production of the milk replaceable composition may be added within a range that does not impair the effects of the present invention. it can. Examples of such additive components include water, sugars, sweeteners, acidulants, vitamins, minerals, fragrances, organic acids, organic bases, emulsifiers, thickeners, antioxidants, pH adjusters, and the like.

本発明の乳代替組成物においては、本発明の効果を損なわない範囲で、その他の添加成分として、乳原料を添加することができる。かかる乳原料としては、牛乳、低脂肪牛乳、無脂肪牛乳、全粉乳、脱脂粉乳、ホエイ、カゼイン等が挙げられる。ただし、乳原料を添加する場合であっても、長期保存による乳脂肪由来の劣化臭をより抑制しつつ、牛乳様の自然な味覚及び風味がより優れた乳代替組成物を得る観点から、これら乳原料の添加量は、添加した乳原料に含まれる乳脂肪及び無脂乳固形分の合計重量(乾燥重量)が、添加した植物油脂及び特定のアミノ酸等の合計重量よりも少ないことが好ましく、前記乾燥重量が、植物油脂及び特定のアミノ酸等の合計重量に対して80重量%以下であることがより好ましく、60重量%以下であることがさらに好ましい。   In the milk substitute composition of the present invention, a milk raw material can be added as another additive component as long as the effects of the present invention are not impaired. Examples of the milk raw material include milk, low-fat milk, non-fat milk, whole milk powder, skimmed milk powder, whey, casein and the like. However, even in the case of adding milk raw materials, from the viewpoint of obtaining a milk substitute composition with more excellent milk-like natural taste and flavor while further suppressing deterioration odor derived from milk fat due to long-term storage The addition amount of the milk raw material is preferably such that the total weight (dry weight) of milk fat and nonfat milk solids contained in the added milk raw material is smaller than the total weight of the added vegetable oil and specific amino acids, The dry weight is more preferably 80% by weight or less, and still more preferably 60% by weight or less, based on the total weight of the vegetable oil and the specific amino acid.

本発明の乳代替組成物は、その製造に際して、特定のアミノ酸等を添加すること、及び、乳代替組成物における植物油脂の添加量(又は含有量)に対する、乳代替組成物における特定のアミノ酸等の合計添加量の重量比率を2〜30%の範囲内に調整すること以外は、従来公知の乳代替組成物の製造方法にしたがって製造することができる。例えば、特定のアミノ酸等、植物油脂、及び、必要に応じて前述の添加成分を混合して攪拌する工程により製造することができる。上記重量比率の調整は、特定のアミノ酸等及び植物油脂の使用量を適宜調整することによって、行うことができる。   The milk replaceable composition of the present invention includes a specific amino acid and the like in the milk replaceable composition with respect to the addition amount (or content) of the vegetable oil and fat in the milk replaceable composition in the production thereof. It can manufacture in accordance with the conventionally well-known manufacturing method of a milk substitute composition except adjusting the weight ratio of the total addition amount in the range of 2-30%. For example, it can be produced by a step of mixing and stirring a specific amino acid or the like, vegetable oil and fat, and, if necessary, the above-mentioned additive components. Adjustment of the said weight ratio can be performed by adjusting the usage-amount of a specific amino acid etc. and vegetable fats and oils suitably.

本発明の乳代替組成物の使用方法としては特に制限されないが、例えば、容器詰飲料の製造の際に原料液に添加させ又は含有させて用いることができる。このように使用することにより、長期保存による乳脂肪由来の劣化臭が抑制されつつ、牛乳様の自然な味覚及び風味に優れた容器詰飲料(好ましくは、乳風味を有する容器詰飲料)を得ることができる。   Although it does not restrict | limit especially as a usage method of the milk substitute composition of this invention, For example, it can be used by making it add or contain to a raw material liquid in the case of manufacture of a container-packed drink. By using in this way, a packaged beverage excellent in milk-like natural taste and flavor (preferably a packaged beverage having a milk flavor) is obtained while suppressing deterioration odor derived from milk fat due to long-term storage. be able to.

2.(本発明(II)の容器詰飲料)
長期保存による乳脂肪由来の劣化臭が抑制されつつ、牛乳様の自然な味覚及び風味に優れた本発明(II)の容器詰飲料は、容器詰飲料であって、
(a)植物油脂、及び、(b)遊離アスパラギン酸、遊離グリシン及び遊離シトルリンからなる群から選択される1種又は2種以上の遊離アミノ酸(以下、「特定の遊離アミノ酸」とも表示する。)を含有し、
前記飲料における前記植物油脂の含有量(又は添加量)が、前記飲料全量に対して0.35重量%以上であり、かつ、
前記飲料における前記植物油脂の含有量(又は添加量)に対する、前記飲料における前記遊離アミノ酸の合計含有量の重量比率が、1.5〜25%の範囲内であるものである限り特に制限されない。
2. (Packaged beverage of the present invention (II))
The bottled beverage of the present invention (II) excellent in milk-like natural taste and flavor while suppressing deterioration odor derived from milk fat due to long-term storage is a bottled beverage,
(A) vegetable oil and fat, and (b) one or more free amino acids selected from the group consisting of free aspartic acid, free glycine and free citrulline (hereinafter also referred to as “specific free amino acids”). Containing
The content (or addition amount) of the vegetable oil in the beverage is 0.35% by weight or more based on the total amount of the beverage, and
There is no particular limitation as long as the weight ratio of the total content of the free amino acids in the beverage to the content (or addition amount) of the vegetable oil in the beverage is in the range of 1.5 to 25%.

本発明(II)の容器詰飲料が含有する特定の遊離アミノ酸としては、遊離アスパラギン酸、遊離グリシン及び遊離シトルリンからなる群から選択される1種又は2種以上の遊離アミノ酸である限り特に制限されないが、牛乳様の自然な味覚及び風味により優れた乳代替組成物又は容器詰飲料を得る観点から、遊離アスパラギン酸が好ましい。また、本発明において2種以上の特定の遊離アミノ酸を併用する場合、牛乳様の自然な味覚及び風味により優れた乳代替組成物又は容器詰飲料を得る観点から、特定の遊離アミノ酸のうち少なくとも1種は、遊離アスパラギン酸であることが好ましい。本発明において2種以上の特定の遊離アミノ酸を併用する場合、牛乳様の自然な味覚及び風味により優れた容器詰飲料を得る観点から、容器詰飲料における、特定の遊離アミノ酸の含有量に対する遊離アスパラギン酸の含有量の重量比率が好ましくは30%以上、より好ましくは50%以上、さらに好ましくは70%以上である態様を好適に挙げることができる。また、本発明(II)の容器詰飲料中の総遊離アミノ酸含有量に対する、特定の遊離アミノ酸の合計含有量の重量比率(%)は特に制限されないが、牛乳様の自然な味覚及び風味により優れた乳代替組成物又は容器詰飲料を得る観点から、30%以上であることが好ましく、50%以上であることがより好ましく、70%以上であることがさらに好ましい。   The specific free amino acid contained in the packaged beverage of the present invention (II) is not particularly limited as long as it is one or more free amino acids selected from the group consisting of free aspartic acid, free glycine and free citrulline. However, free aspartic acid is preferable from the viewpoint of obtaining a milk substitute composition or a packaged beverage that is superior in milk-like natural taste and flavor. Moreover, when using together 2 or more types of specific free amino acids in this invention, from a viewpoint of obtaining the milk substitute composition or the container-packed drink which was excellent by the natural taste and flavor of milk-like, at least 1 of specific free amino acids. The species is preferably free aspartic acid. In the present invention, when two or more kinds of specific free amino acids are used in combination, free asparagine with respect to the content of the specific free amino acid in the packaged beverage from the viewpoint of obtaining a packaged beverage excellent in milk-like natural taste and flavor. An embodiment in which the weight ratio of the acid content is preferably 30% or more, more preferably 50% or more, and still more preferably 70% or more can be mentioned. Further, the weight ratio (%) of the total content of specific free amino acids to the total free amino acid content in the packaged beverage of the present invention (II) is not particularly limited, but is superior to the natural taste and flavor of milk. From the viewpoint of obtaining a milk substitute composition or a packaged beverage, it is preferably 30% or more, more preferably 50% or more, and further preferably 70% or more.

本発明(II)の容器詰飲料における植物油脂の含有量(又は添加量)としては、前記飲料全量に対して0.35重量%以上である限り特に制限されないが、より優れた乳感を得る観点から、好ましくは0.358重量%以上、より好ましくは0.53重量%以上、さらに好ましくは0.537重量%以上、より好ましくは0.7重量%以上、特に好ましくは0.716重量%以上とすることが好適である。また、かかる植物油脂の含有量(又は添加量)の上限としては、異味である脂っぽさが過度とならないような観点から、前記飲料全量に対して好ましくは2.5重量%以下、より好ましくは2.3重量%以下、さらに好ましくは2.2重量%以下、より好ましくは2.15重量%以下、さらに好ましくは2重量%以下、特に好ましくは1.79重量%以下とすることが好適である。なお、列挙されている下限値と上限値のすべての組合せがこの記載に含まれているものとするが、より優れた乳感を得つつ、異味である脂っぽさが過度とならないような観点から、本発明(II)の容器詰飲料における植物油脂の含有量(又は添加量)が前記飲料全量に対して好ましくは0.35〜2.5重量%の範囲内、より好ましくは約0.358〜2.5重量%の範囲内、さらに好ましくは0.53〜2.3重量%の範囲内、より好ましくは0.7〜2.2重量%(より好ましくは0.716〜2.15重量%)の範囲内、さらに好ましくは0.7〜2重量%(特に好ましくは0.716〜1.79重量%)の範囲内とすることが好適である。   The content (or addition amount) of the vegetable oil and fat in the container-packed beverage of the present invention (II) is not particularly limited as long as it is 0.35% by weight or more with respect to the total amount of the beverage, but a better milk feeling is obtained. From the viewpoint, it is preferably 0.358% by weight or more, more preferably 0.53% by weight or more, further preferably 0.537% by weight or more, more preferably 0.7% by weight or more, and particularly preferably 0.716% by weight. The above is preferable. Moreover, as an upper limit of content (or addition amount) of this vegetable oil and fat, from a viewpoint that the fat taste which is unpleasant taste does not become excessive, Preferably it is 2.5 weight% or less with respect to the said drink whole quantity, More It is preferably 2.3% by weight or less, more preferably 2.2% by weight or less, more preferably 2.15% by weight or less, further preferably 2% by weight or less, and particularly preferably 1.79% by weight or less. Is preferred. It should be noted that all the combinations of the lower limit value and the upper limit value listed are included in this description, but the greasy taste that does not become excessive is obtained while obtaining a better milk feeling. From the viewpoint, the content (or addition amount) of the vegetable oil / fat in the packaged beverage of the present invention (II) is preferably in the range of 0.35 to 2.5% by weight, more preferably about 0, relative to the total amount of the beverage. Within the range of 358 to 2.5% by weight, more preferably within the range of 0.53 to 2.3% by weight, more preferably 0.7 to 2.2% by weight (more preferably 0.716 to 2. 15 wt%), more preferably 0.7 to 2 wt% (particularly preferably 0.716 to 1.79 wt%).

本発明(II)の容器詰飲料における植物油脂の含有量は、公知の方法により測定することができる。かかる方法としては、エーテル抽出法、クロロホルム・メタノール混液抽出法、ゲルベル法、酸分解法、レーゼゴットリーブ法などを挙げることができる。   The vegetable oil content in the packaged beverage of the present invention (II) can be measured by a known method. Examples of such a method include an ether extraction method, a chloroform / methanol mixed solution extraction method, a gel bell method, an acid decomposition method, and a Rosette Gottlieb method.

本発明(II)の容器詰飲料において、飲料における植物油脂の含有量(又は添加量)に対する、飲料における特定の遊離アミノ酸の合計含有量の重量比率は、1.5〜25%の範囲内である限り特に制限されないが、より優れた乳感を得つつ、異味である塩味が過度とならないような観点から、好ましくは1.7〜23%の範囲内、より好ましくは1.7〜21.1%の範囲内、さらに好ましくは約3〜16%の範囲内、より好ましくは3.5〜14.1%の範囲内、さらに好ましくは7〜14.1%の範囲内、より好ましくは9〜14.1%の範囲内、特に好ましくは9.6〜14.1%の範囲内とすることが好適である。   In the container-packed beverage of the present invention (II), the weight ratio of the total content of specific free amino acids in the beverage to the content (or addition amount) of vegetable oils and fats in the beverage is within a range of 1.5 to 25%. Although it does not restrict | limit as much as possible, From a viewpoint that the salty taste which is unpleasant taste is acquired, obtaining a more excellent milky feeling, Preferably it exists in the range of 1.7-23%, More preferably, it is 1.7-21. Within the range of 1%, more preferably within the range of about 3-16%, more preferably within the range of 3.5-14.1%, even more preferably within the range of 7-14.1%, more preferably 9 It is preferable that the content be in the range of ˜14.1%, particularly preferably in the range of 9.6 to 14.1%.

飲料における特定の遊離アミノ酸の含有量(重量%)の測定方法としては、ポストカラム法や、プレカラム法などの公知の方法を適用することができる。上記のポストカラム法とは、イオン交換クロマトグラフィーで遊離アミノ酸を分離した後に、ニンヒドリン又はo−フタルアルデヒド(OPA)で誘導体化して検出、測定する方法である。また、上記のプレカラム法とは、遊離アミノ酸を以下の化合物1〜6のいずれかで誘導体化した後に、逆相液体クロマトグラフィーで分離して検出、測定する方法である。
化合物1:o−フタルアルデヒド(OPA)
化合物2:フェニルイソチオシアネート(PITC)
化合物3:6−アミノキノリル−N−ヒドロキシスクシンイミジルカルバメイト(AQC)
化合物4:(ジメチルアミノ)アゾベンゼンスルホニルクロリド(DABS−Cl)
化合物5:9−フルオレニルメチルクロロギ酸(FMOC−Cl)
化合物6:7−フルオロ−4−ニトロベンゾ−2−オキサ−1,3−ジアゾール(NBD−F)
なお、飲料における特定の遊離アミノ酸の含有量(重量%)の測定は、一般財団法人 日本食品分析センター等の外部機関に委託して行うこともできる。
As a method for measuring the content (% by weight) of a specific free amino acid in a beverage, a known method such as a post-column method or a pre-column method can be applied. The post column method is a method in which free amino acids are separated by ion exchange chromatography and then derivatized with ninhydrin or o-phthalaldehyde (OPA) for detection and measurement. The pre-column method is a method in which a free amino acid is derivatized with any of the following compounds 1 to 6 and then separated and detected and measured by reverse phase liquid chromatography.
Compound 1: o-phthalaldehyde (OPA)
Compound 2: Phenyl isothiocyanate (PITC)
Compound 3: 6-aminoquinolyl-N-hydroxysuccinimidyl carbamate (AQC)
Compound 4: (Dimethylamino) azobenzenesulfonyl chloride (DABS-Cl)
Compound 5: 9-fluorenylmethyl chloroformate (FMOC-Cl)
Compound 6: 7-fluoro-4-nitrobenzo-2-oxa-1,3-diazole (NBD-F)
In addition, measurement of content (weight%) of the specific free amino acid in a drink can also be consigned to outside organizations, such as Japan Food Research Center.

本発明(II)や後述の本発明(III)の容器詰飲料においては、植物油脂及び特定のアミノ酸等及び水の他に、容器詰飲料の製造に際して通常用いられている添加成分を、本発明の効果を損なわない範囲で添加することができる。かかる添加成分としては、糖類、甘味料、酸味料、ビタミン類、ミネラル類、香料、有機酸、有機塩基、乳化剤、増粘剤、酸化防止剤、pH調整剤の他、コーヒー、ココア、紅茶、緑茶、果汁、野菜汁などの食品素材、植物等の天然物やその抽出物、精製物、濃縮物、加工物等が挙げられる。なお、本発明の容器詰飲料に用いるアミノ酸等がナトリウムを含んでいる場合は、塩味を抑制する観点から、本発明の容器詰飲料におけるナトリウムイオン濃度を、0.05重量%以下とすることが好ましい。また、本発明の乳代替組成物に用いるアミノ酸等がナトリウムを含んでいる場合、該乳代替組成物におけるナトリウムイオン濃度は、該乳代替組成物が飲食される際の状態(例えば希釈されて容器詰飲料に用いられる場合はその容器詰飲料)において塩味を抑制する観点から、該乳代替組成物が飲食される際の状態おけるナトリウムイオン濃度が0.05重量%以下となるような濃度とすることが好ましい。   In the packaged beverages of the present invention (II) and the later-described present invention (III), in addition to vegetable oils and fats, specific amino acids, etc. and water, the additive components usually used in the production of packaged beverages are used in the present invention. It is possible to add in the range which does not impair the effect. Such additive components include sugars, sweeteners, acidulants, vitamins, minerals, fragrances, organic acids, organic bases, emulsifiers, thickeners, antioxidants, pH adjusters, coffee, cocoa, tea, Examples include food materials such as green tea, fruit juice, vegetable juice, natural products such as plants, extracts, purified products, concentrates, processed products, and the like. In addition, when the amino acid etc. which are used for the container-packed drink of this invention contain sodium, the sodium ion density | concentration in the container-packed drink of this invention shall be 0.05 weight% or less from a viewpoint of suppressing salty taste. preferable. Moreover, when the amino acid etc. which are used for the milk substitute composition of this invention contain sodium, the sodium ion concentration in this milk substitute composition is the state at the time of this milk replaceable composition being consumed (for example, diluted and container In the case of being used in a stuffed beverage, the concentration in which the sodium ion concentration in the state when the milk replacement composition is eaten or consumed is 0.05% by weight or less from the viewpoint of suppressing salty taste in the packaged beverage) It is preferable.

本発明(II)や後述の本発明(III)の容器詰飲料においては、本発明の効果を損なわない範囲で、その他の添加成分として、乳原料を添加することができる。かかる乳原料としては、牛乳、低脂肪牛乳、無脂肪牛乳、全粉乳、脱脂粉乳、ホエイ、カゼイン等が挙げられる。ただし、乳原料を添加する場合であっても、長期保存による乳脂肪由来の劣化臭をより抑制しつつ、牛乳様の自然な味覚及び風味がより優れた容器詰飲料を得る観点から、これら乳原料の添加量は、添加した乳原料に含まれる乳脂肪及び無脂乳固形分の合計重量(乾燥重量)が、添加した植物油脂及び特定のアミノ酸等(又は特定の遊離アミノ酸)の合計重量よりも少ないことが好ましく、前記乾燥重量が、植物油脂及び特定のアミノ酸等(又は特定の遊離アミノ酸)の合計重量に対して80重量%以下であることがより好ましく、60重量%以下であることがさらに好ましい。   In the container-packed beverages of the present invention (II) and the later-described present invention (III), milk raw materials can be added as other additive components as long as the effects of the present invention are not impaired. Examples of the milk raw material include milk, low-fat milk, non-fat milk, whole milk powder, skimmed milk powder, whey, casein and the like. However, even in the case of adding milk raw materials, from the viewpoint of obtaining a packaged beverage with more excellent milk-like natural taste and flavor while further suppressing deterioration odor derived from milk fat due to long-term storage, these milks The total amount (dry weight) of milk fat and non-fat milk solids contained in the added milk raw material is greater than the total weight of the added vegetable oil and specific amino acids (or specific free amino acids). The dry weight is preferably 80% by weight or less, more preferably 60% by weight or less, based on the total weight of the vegetable oil and fat and the specific amino acid (or specific free amino acid). Further preferred.

本発明(II)の容器詰飲料は、その製造に際して、
(a)植物油脂、及び、(b)遊離アスパラギン酸、遊離グリシン及び遊離シトルリンからなる群から選択される1種又は2種以上の遊離アミノ酸を含有させ、
飲料における植物油脂の含有量(又は添加量)を、飲料全量に対して0.35重量%以上とし、かつ、
飲料における植物油脂の含有量(又は添加量)に対する、飲料における前記遊離アミノ酸の合計含有量の重量比率を、1.5〜25%の範囲内とすること以外は、従来公知の、乳風味を有する容器詰飲料等の容器詰飲料の製造方法にしたがって製造することができる。例えば、水に、植物油脂、特定のアミノ酸等、及び、必要に応じて前述の添加成分を添加して攪拌し、飲料原液を調製する。そして、必要に応じて、飲料原液についてpHの調整及び/又は加熱殺菌をしてから冷却した後、容器に充填して、殺菌する工程により製造することができる。なお、添加した特定のアミノ酸等の全部又は一部は、飲料中において特定の遊離アミノ酸として存在する。
In the production of the packaged beverage of the present invention (II),
(A) vegetable oil and fat, and (b) one or more free amino acids selected from the group consisting of free aspartic acid, free glycine and free citrulline,
The content (or addition amount) of vegetable oil in the beverage is 0.35% by weight or more based on the total amount of the beverage, and
Conventionally known milk flavor except that the weight ratio of the total content of the free amino acids in the beverage to the content (or addition amount) of the vegetable oil in the beverage is within the range of 1.5 to 25%. It can manufacture according to the manufacturing method of container-packed drinks, such as a container-packed drink. For example, a vegetable oil and fat, a specific amino acid, and the like, and, if necessary, the aforementioned additive components are added to water and stirred to prepare a beverage stock solution. And if necessary, after adjusting the pH and / or heat sterilization of the beverage stock solution and then cooling, it can be manufactured by a process of filling the container and sterilizing it. In addition, all or part of the added specific amino acid or the like is present as a specific free amino acid in the beverage.

本発明(II)の容器詰飲料の製造に際して、上記重量比率を所定の範囲内にする方法としては、特に制限されないが、特定のアミノ酸等及び植物油脂の使用量を適宜調整することによって、行うことができる。   In the production of the packaged beverage of the present invention (II), the method for bringing the weight ratio within the predetermined range is not particularly limited, but is performed by appropriately adjusting the amount of specific amino acids and vegetable oils and fats used. be able to.

3.(本発明(III)の容器詰飲料)
長期保存による乳脂肪由来の劣化臭が抑制されつつ、牛乳様の自然な味覚及び風味に優れた本発明(III)の容器詰飲料は、容器詰飲料において、
(a)植物油脂、及び、(b)アスパラギン酸塩、アスパラギン酸、グリシン、グリシン塩、シトルリン及びシトルリン塩からなる群から選択される1種又は2種以上のアミノ酸又はその塩が添加され、
前記飲料における前記植物油脂の添加量(又は含有量)が、前記飲料全量に対して0.35重量%以上であり、かつ、
前記飲料における前記植物油脂の添加量(又は含有量)に対する、前記飲料における前記アミノ酸又はその塩の合計添加量の重量比率が、2〜30%の範囲内に調整されたものである限り特に制限されない。
3. (Packaged beverage of the present invention (III))
The bottled beverage of the present invention (III) excellent in milk-like natural taste and flavor, while suppressing the deterioration odor derived from milk fat due to long-term storage,
(A) vegetable oil and fat, and (b) one or more amino acids selected from the group consisting of aspartate, aspartic acid, glycine, glycine salt, citrulline and citrulline salt or salts thereof are added,
The amount (or content) of the vegetable oil / fat in the beverage is 0.35% by weight or more based on the total amount of the beverage, and
As long as the weight ratio of the total addition amount of the amino acid or salt thereof in the beverage to the addition amount (or content) of the vegetable oil in the beverage is adjusted within a range of 2 to 30%, it is particularly limited. Not.

本発明(III)の容器詰飲料における植物油脂の添加量(又は含有量)としては、前記飲料全量に対して0.35重量%以上である限り特に制限されないが、より優れた乳感を得る観点から、好ましくは0.358重量%以上、より好ましくは0.53重量%以上、さらに好ましくは0.537重量%以上、より好ましくは0.7重量%以上、特に好ましくは0.716重量%以上とすることが好適である。また、かかる植物油脂の添加量(又は含有量)の上限としては、異味である脂っぽさが過度とならないような観点から、前記飲料全量に対して好ましくは2.5重量%以下、より好ましくは2.3重量%以下、さらに好ましくは2.2重量%以下、より好ましくは2.15重量%以下、さらに好ましくは2重量%以下、特に好ましくは1.79重量%以下とすることが好適である。なお、列挙されている下限値と上限値のすべての組合せがこの記載に含まれているものとするが、より優れた乳感を得つつ、異味である脂っぽさが過度とならないような観点から、本発明(III)の容器詰飲料における植物油脂の添加量(又は含有量)が前記飲料全量に対して好ましくは0.35〜2.5重量%の範囲内、より好ましくは約0.358〜2.5重量%の範囲内、さらに好ましくは0.53〜2.3重量%の範囲内、より好ましくは0.7〜2.2重量%(より好ましくは0.716〜2.15重量%)の範囲内、さらに好ましくは0.7〜2重量%(特に好ましくは0.716〜1.79重量%)の範囲内とすることが好適である。   The amount (or content) of the vegetable oil / fat in the packaged beverage of the present invention (III) is not particularly limited as long as it is 0.35% by weight or more based on the total amount of the beverage, but a better milk feeling is obtained. From the viewpoint, it is preferably 0.358% by weight or more, more preferably 0.53% by weight or more, further preferably 0.537% by weight or more, more preferably 0.7% by weight or more, and particularly preferably 0.716% by weight. The above is preferable. Moreover, as an upper limit of the addition amount (or content) of such vegetable oils and fats, from the viewpoint of not having an excessively greasy greasy taste, it is preferably 2.5% by weight or less, based on the total amount of the beverage. It is preferably 2.3% by weight or less, more preferably 2.2% by weight or less, more preferably 2.15% by weight or less, further preferably 2% by weight or less, and particularly preferably 1.79% by weight or less. Is preferred. It should be noted that all the combinations of the lower limit value and the upper limit value listed are included in this description, but the greasy taste that does not become excessive is obtained while obtaining a better milk feeling. From the viewpoint, the amount (or content) of vegetable oil / fat in the container-packed beverage of the present invention (III) is preferably in the range of 0.35 to 2.5% by weight, more preferably about 0, based on the total amount of the beverage. Within the range of 358 to 2.5% by weight, more preferably within the range of 0.53 to 2.3% by weight, more preferably 0.7 to 2.2% by weight (more preferably 0.716 to 2. 15 wt%), more preferably 0.7 to 2 wt% (particularly preferably 0.716 to 1.79 wt%).

本発明(III)の容器詰飲料において、飲料における植物油脂の添加量(又は含有量)に対する、飲料における特定のアミノ酸等の合計添加量の重量比率は、2〜30%の範囲内である限り特に制限されないが、より優れた乳感を得つつ、異味である塩味が過度とならないような観点から、好ましくは2.3〜28%の範囲内、より好ましくは約4〜22%の範囲内、さらに好ましくは4.7〜19%の範囲内、より好ましくは9.4〜19%の範囲内、さらに好ましくは10〜19%の範囲内、より好ましくは10.7〜19%の範囲内、さらに好ましくは11.5〜19%の範囲内、特に好ましくは12.7〜18.7%の範囲内とすることが好適である。   In the packaged beverage of the present invention (III), the weight ratio of the total addition amount of specific amino acids and the like in the beverage to the addition amount (or content) of the vegetable oil and fat in the beverage is within the range of 2 to 30%. Although it is not particularly limited, it is preferably within the range of 2.3 to 28%, more preferably within the range of about 4 to 22%, from the viewpoint of obtaining a superior milky feeling and not having an excessive salty taste. More preferably in the range of 4.7 to 19%, more preferably in the range of 9.4 to 19%, still more preferably in the range of 10 to 19%, more preferably in the range of 10.7 to 19%. More preferably, it is within the range of 11.5 to 19%, particularly preferably within the range of 12.7 to 18.7%.

本発明(III)の容器詰飲料は、その製造に際して、
(a)植物油脂、及び、(b)アスパラギン酸塩、アスパラギン酸、グリシン、グリシン塩、シトルリン及びシトルリン塩からなる群から選択される1種又は2種以上のアミノ酸又はその塩を添加し、
飲料における植物油脂の添加量(又は含有量)を、飲料全量に対して0.35重量%以上とし、かつ、
飲料における植物油脂の添加量(又は含有量)に対する、飲料における前記アミノ酸又はその塩の合計添加量の重量比率を、2〜30%の範囲内に調整すること以外は、従来公知の、乳風味を有する容器詰飲料等の容器詰飲料の製造方法にしたがって製造することができる。例えば、水に、植物油脂、特定のアミノ酸等、及び、必要に応じて前述の添加成分を添加して攪拌し、飲料原液を調製する。そして、必要に応じて、飲料原液についてpHの調整及び/又は加熱殺菌をしてから冷却した後、容器に充填して、殺菌する工程により製造することができる。
In the production of the packaged beverage of the present invention (III),
(A) vegetable oil and fat, and (b) one or more amino acids selected from the group consisting of aspartate, aspartic acid, glycine, glycine salt, citrulline and citrulline salt, or a salt thereof,
Addition amount (or content) of vegetable oil in the beverage is 0.35% by weight or more based on the total amount of the beverage, and
A conventionally known milk flavor except that the weight ratio of the total amount of the amino acid or salt thereof in the beverage to the amount (or content) of the vegetable oil in the beverage is adjusted within a range of 2 to 30%. Can be produced according to a method for producing a packaged beverage such as a packaged beverage. For example, a vegetable oil and fat, a specific amino acid, and the like, and, if necessary, the aforementioned additive components are added to water and stirred to prepare a beverage stock solution. And if necessary, after adjusting the pH and / or heat sterilization of the beverage stock solution and then cooling, it can be manufactured by a process of filling the container and sterilizing it.

本発明(III)の容器詰飲料の製造に際して、上記重量比率を所定の範囲内に調整する方法としては、特に制限されないが、特定のアミノ酸等及び植物油脂の使用量を適宜調整することによって、行うことができる。   In the production of the packaged beverage of the present invention (III), the method for adjusting the weight ratio within a predetermined range is not particularly limited, but by appropriately adjusting the amount of specific amino acids and vegetable oils and fats used, It can be carried out.

本発明(II)や本発明(III)の容器詰飲料に用いる容器としては特に制限されないが、ペットボトル、ポリプロピレンボトル、ポリ塩化ビニルボトル等の樹脂ボトル容器;ビン容器;缶容器;紙パック容器;ラミネートパック容器;等の容器が挙げられる。   Although it does not restrict | limit especially as a container used for the container-packed drink of this invention (II) or this invention (III), Resin bottle containers, such as a PET bottle, a polypropylene bottle, a polyvinyl chloride bottle; A bottle container; A can container; A paper pack container A laminate pack container; and the like.

本発明において「長期保存による乳脂肪由来の劣化臭が抑制された乳代替組成物又は容器詰飲料」とは、含有する油脂分のすべて又は90重量%以上が乳脂肪である乳代替組成物又は容器詰飲料と比較して、長期保存による乳脂肪由来の劣化臭が抑制された乳代替組成物又は容器詰飲料を意味し、好ましい態様としては、添加した乳原料に含まれる乳脂肪及び無脂乳固形分の合計重量(乾燥重量)が、添加した植物油脂及び特定のアミノ酸等(又は特定の遊離アミノ酸)の合計重量よりも多い乳代替組成物又は容器詰飲料と比較して、長期保存による乳脂肪由来の劣化臭が抑制された乳代替組成物又は容器詰飲料を含む。上記の「長期保存」における「長期」とは例えば3日間以上、好ましくは1週間以上、より好ましくは3週間以上の期間を意味し、期間の上限としては1年間以内を好ましく挙げることができる。保存温度は例えば常温あるいは60℃など、1〜70℃の範囲内の温度を挙げることができる。   In the present invention, “a milk substitute composition or a container-packed beverage in which a deterioration odor derived from milk fat due to long-term storage is suppressed” means a milk substitute composition in which all or 90% by weight or more of the fat and oil contained is milk fat or Compared to container-packed beverages, it means a milk substitute composition or container-packed beverage in which deterioration odor derived from milk fat due to long-term storage is suppressed, and preferred embodiments include milk fat and non-fat contained in the added milk raw material Compared to milk replacement compositions or packaged beverages where the total weight (dry weight) of milk solids is greater than the total weight of added vegetable oils and specific amino acids (or specific free amino acids), due to long-term storage The milk substitute composition or the container-packed drink in which the deterioration smell derived from milk fat was suppressed is included. “Long term” in the above “long term storage” means, for example, a period of 3 days or more, preferably 1 week or more, more preferably 3 weeks or more, and the upper limit of the period is preferably within 1 year. Examples of the storage temperature include normal temperature or a temperature within a range of 1 to 70 ° C. such as 60 ° C.

本発明において「牛乳様の自然な味覚及び風味に優れた乳代替組成物又は容器詰飲料」とは、植物油脂と無脂乳固形分(特に脱脂粉乳)からなる従来の乳代替物、又は、該乳代替物を含む容器詰飲料と比較して、新鮮な牛乳本来の自然な味覚及び風味(自然な乳感)に改善された乳代替組成物又は容器詰飲料、すなわち、牛乳様の味覚及び風味(乳感)の自然さが改善された乳代替組成物又は容器詰飲料を意味する。より具体的には、本発明における「牛乳様の自然な味覚及び風味に優れた乳代替組成物又は容器詰飲料」には、アミノ酸等に代えて無脂乳固形分(好ましくは脱脂粉乳)を用いたこと以外は同種、同量の原料(該原料には、同種、同量の植物油脂が必ず含まれる)を用いて同量の乳代替組成物又は容器詰飲料を同じ製法で製造した場合と比較して、新鮮な牛乳本来の自然な味覚及び風味(自然な乳感)に改善された乳代替組成物又は容器詰飲料、すなわち、牛乳様の味覚及び風味(乳感)の自然さが改善された乳代替組成物又は容器詰飲料が含まれる。比較対象となる、無脂乳固形分(好ましくは脱脂粉乳)を用いた乳代替組成物又は容器詰飲料(好ましくは脱脂粉乳)における無脂乳固形分の含量(重量%)としては、植物油脂の含有量(重量%)の0.5倍〜1.5倍の範囲内である乳代替組成物又は容器詰飲料を好適に挙げることができる。なお、乳感の自然さは、後述の実施例1に記載されているように、専門的なパネリストによる官能評価試験などにより評価することができる。その評価基準としては、後述の表7に記載されているように、牛乳の乳感と比較した基準を用いることができ、特に、粉臭や、加熱乳原料に由来する異質な乳感があまり感じられず、牛乳本来の乳感に近いかどうかに着目することができ、好ましくはさらに、飲んだ後に残る乳感の余韻の持続性に着目することができる。   In the present invention, "milk substitute composition or container-packed beverage excellent in milk-like natural taste and flavor" is a conventional milk substitute consisting of vegetable oil and non-fat milk solids (especially skim milk powder), or Compared to the packaged beverage containing the milk replacer, the milk replacer composition or the packaged beverage improved to the natural taste and flavor (natural feeling of milk) of fresh milk, that is, the milk-like taste and It means a milk replacement composition or a packaged beverage with improved flavor (milkiness). More specifically, the “milk substitute composition or container-packed beverage excellent in milk-like natural taste and flavor” in the present invention contains non-fat milk solids (preferably nonfat dry milk) instead of amino acids and the like. When the same amount of milk substitute composition or packaged beverage is produced by the same manufacturing method using the same type and the same amount of raw material (the raw material must contain the same type and the same amount of vegetable oil) Compared with, the milk substitute composition or the container-packed beverage improved to the natural taste and flavor (natural milk feeling) inherent in fresh milk, that is, the natural taste of milk-like taste and flavor (milk feeling). Improved milk replacement compositions or containerized beverages are included. As a comparison object, the non-fat milk solid content (% by weight) in the milk substitute composition or the packaged beverage (preferably nonfat dry milk) using the nonfat milk solid content (preferably nonfat dry milk) is vegetable oil A milk substitute composition or a container-packed beverage that is within a range of 0.5 to 1.5 times the content (% by weight) of can be preferably mentioned. The natural feeling of milk can be evaluated by a sensory evaluation test or the like by a professional panelist as described in Example 1 described later. As the evaluation criteria, as described in Table 7 to be described later, a standard compared with the milk feeling of milk can be used, and in particular, the powdery odor and the extraordinary milk feeling derived from the heated milk raw material are not so much. It can be noticed whether or not it is close to the original milk feeling of milk, and preferably, the persistence of the remnant of the milk feeling remaining after drinking can be noted.

本発明における容器詰飲料の具体例としては、乳風味を有する容器詰飲料を挙げることができ、中でも、コーヒー飲料、紅茶飲料、ココア飲料、果汁入り乳風味飲料、野菜汁入り乳風味飲料等を好ましく挙げることができ、中でも、コーヒー飲料、紅茶飲料、ココア飲料をより好ましく挙げることができる。   Specific examples of the packaged beverage in the present invention include a packaged beverage having a milk flavor, among which a coffee beverage, a tea beverage, a cocoa beverage, a milk flavored beverage with fruit juice, a milk flavored beverage with vegetable juice, and the like. Among them, coffee drinks, tea drinks, and cocoa drinks can be more preferable.

以下に、本発明を実施例によって詳細に説明するが、本発明はこれらの実施例に限定されるものではない。   EXAMPLES The present invention will be described in detail below with reference to examples, but the present invention is not limited to these examples.

[(1)アミノ酸又はその塩の添加による、容器詰乳入りコーヒー飲料の牛乳様の味覚及び風味への影響]
アミノ酸又はその塩(アミノ酸等)を添加することによって、容器詰乳入りコーヒー飲料における牛乳様の味覚及び風味にどのような影響が生じるかを、以下の方法で検討した。
[(1) Effect of addition of amino acids or salts thereof on the taste and flavor of milk-like coffee beverages with packaged milk]
The effect of adding an amino acid or a salt thereof (such as an amino acid) on the milk-like taste and flavor of a coffee beverage containing a packaged milk was examined by the following method.

(1.コーヒー抽出液の調製)
コーヒー豆(L値18、アラビカ種、中細挽き)の10倍量の熱水(98℃)で抽出した後に、冷却してコーヒー抽出液を得た。なお、前述のL値は、色差計(日本電色工業社製)を用いて測定した。
(1. Preparation of coffee extract)
After extraction with hot water (98 ° C.) 10 times the amount of coffee beans (L value 18, Arabica seed, medium fine ground), cooling was performed to obtain a coffee extract. In addition, the above-mentioned L value was measured using the color difference meter (made by Nippon Denshoku Industries Co., Ltd.).

(2.植物油脂及びアミノ酸等を添加した容器詰乳入りコーヒー飲料の調製)
植物油脂及びアミノ酸等を添加したコーヒー飲料(植物油脂及びアミノ酸等添加コーヒー飲料)については、下記表1に示す配合にて、上記のコーヒー抽出液、砂糖(グラニュー糖)、乳代替組成物(植物性油脂及びアミノ酸等)、及び水を容器に添加して混合し、植物油脂及びアミノ酸等添加コーヒー飲料用の調合液を調製した。かかるアミノ酸等としては、アスパラギン酸ナトリウム(実施例飲料1)、グリシン(実施例飲料2)、シトルリン(実施例飲料3)、グルタミン酸ナトリウム(比較例飲料1)、又は、アルギニン(比較例飲料2)を用い、合計5種類の調合液を調製した。
(2. Preparation of container-packed milk-containing coffee beverages with added vegetable oils and amino acids)
For coffee beverages (vegetable oils and fats and amino acid-added coffee beverages) added with vegetable oils and fats and amino acids, the above coffee extract, sugar (granulated sugar), milk substitute composition (plant) Oil and fat, amino acids, etc.) and water were added to the container and mixed to prepare a blended liquid for coffee beverages such as vegetable fats and amino acids. Examples of such amino acids include sodium aspartate (Example Beverage 1), glycine (Example Beverage 2), citrulline (Example Beverage 3), sodium glutamate (Comparative Beverage 1), or arginine (Comparative Beverage 2). A total of 5 types of preparation liquids were prepared.

Figure 2016067296
Figure 2016067296

また、本発明の乳代替組成物(植物油脂及びアミノ酸等)ではなく、特許文献4等の従来の乳代替物(植物油脂+無脂乳固形分)を含む容器詰乳入りコーヒー飲料として、比較例飲料3(植物油脂及び無脂乳固形分添加コーヒー飲料)を設定した。かかる比較例飲料3については、下記表2に示す配合にて、上記のコーヒー抽出液、砂糖(グラニュー糖)、従来の乳代替物(植物性油脂及び無脂乳固形分)、及び水を容器に添加して混合し、比較例飲料3用の調合液を調製した。   In addition, as a coffee drink containing a packaged milk containing the conventional milk substitute (vegetable oil and fat + non-fat milk solid content) such as Patent Document 4 instead of the milk substitute composition (vegetable oil and fat and amino acids) of the present invention. Example drink 3 (a vegetable oil and a non-fat milk solid content added coffee drink) was set. About this comparative example drink 3, the above-mentioned coffee extract, sugar (granulated sugar), conventional milk substitutes (vegetable oils and fats and non-fat milk solids), and water are contained in the container shown in Table 2 below. And mixed to prepare a preparation solution for Comparative Example Beverage 3.

Figure 2016067296
Figure 2016067296

上記表1の植物油脂及びアミノ酸等添加コーヒー飲料の配合において、アミノ酸等のみを含まない比較例として、比較例飲料4(植物油脂添加・アミノ酸等不添加コーヒー飲料)を設定した。比較例飲料4(配合は下記表3)については、アミノ酸等を添加しないこと以外は、植物油脂及びアミノ酸等添加コーヒー飲料の場合と同様の方法により、比較例飲料4用の調合液を調製した。   In the blending of the vegetable oils and fats and added coffee beverages such as amino acids in Table 1 above, Comparative Example Beverage 4 (added vegetable oils and fats and other amino acid-free coffee beverages) was set as a comparative example not containing only amino acids and the like. About the comparative example drink 4 (a mixing | blending is following Table 3), except not adding an amino acid etc., the preparation liquid for the comparative example drink 4 was prepared by the method similar to the case of vegetable oil and fat, an amino acid, etc. addition coffee drink. .

Figure 2016067296
Figure 2016067296

また、陽性対照である比較例として、比較例飲料5(牛乳添加コーヒー飲料)を設定した。比較例飲料5については、下記表4に示す配合にて、上記のコーヒー抽出液、砂糖(グラニュー糖)、牛乳、及び水を容器に添加して混合し、比較例飲料5用の調合液を調製した。   Moreover, the comparative example drink 5 (milk addition coffee drink) was set as a comparative example which is a positive control. For Comparative Example Beverage 5, the above-mentioned coffee extract, sugar (granulated sugar), milk, and water were added to the container and mixed in the formulation shown in Table 4 below. Prepared.

Figure 2016067296
Figure 2016067296

また、牛乳も乳代替組成物も添加しない、陰性対照の比較例として、比較例飲料6(牛乳及び乳代替組成物無添加コーヒー飲料)を設定した。比較例飲料6(配合は下記表5)については、牛乳を添加しないこと以外は、比較例飲料5の場合と同様の方法により、比較例飲料6用の調合液を調製した。   Moreover, the comparative example drink 6 (milk and milk substitute composition additive-free coffee drink) was set as a comparative example of a negative control to which neither milk nor a milk substitute composition was added. About the comparative example drink 6 (a mixing | blending is following Table 5), the preparation liquid for the comparative example drink 6 was prepared by the method similar to the case of the comparative example drink 5 except not adding milk.

Figure 2016067296
Figure 2016067296

前述の実施例飲料1〜3用の調合液や、比較例飲料1〜6用の調合液をそれぞれ60℃〜70℃に昇温後、ホモジナイズ処理に供してから、食品衛生法に従い、120℃4分間同等以上の条件(発育しうる微生物を死滅されるのに十分な効力を有する条件)でUHT殺菌を行い、各調合液を無菌環境下でPETボトルにそれぞれ充填した。このようにして、容器詰乳入りコーヒー飲料である実施例飲料1〜3及び比較例飲料1〜6を調製した。   After heating up the preparation liquid for the above-mentioned Example drinks 1-3 and the preparation liquid for the comparative example drinks 1-6 to 60 degreeC-70 degreeC, respectively, after using for a homogenization process, according to the food hygiene law, 120 degreeC UHT sterilization was performed under the same conditions for 4 minutes or more (conditions sufficient for killing the growing microorganisms), and each preparation solution was filled in PET bottles in an aseptic environment. In this way, Example beverages 1 to 3 and Comparative example beverages 1 to 6 which are coffee beverages containing packed milk were prepared.

(3.官能評価試験)
各容器詰乳入りコーヒー飲料について、それぞれ官能評価試験を行った。訓練を受けたパネリストを4人選定し、これらのパネリストに実施例飲料1〜3及び比較例飲料1〜6を提示して、これらの各容器詰乳入りコーヒー飲料における牛乳様の味覚及び風味の程度(乳感)、及び、乳感の自然感(牛乳本来の乳感への近さ)をそれぞれ以下の表6及び表7の評価基準により評価した。
(3. Sensory evaluation test)
A sensory evaluation test was conducted for each of the bottled milk-containing coffee beverages. Four trained panelists were selected, and the example beverages 1 to 3 and comparative beverages 1 to 6 were presented to these panelists, and the milk-like taste and flavor of each of these bottled coffee beverages The degree (milk feeling) and the natural feeling of milk feeling (closeness to the original milk feeling of milk) were evaluated according to the evaluation criteria shown in Tables 6 and 7 below.

Figure 2016067296
Figure 2016067296

Figure 2016067296
Figure 2016067296

かかる官能評価試験の結果を以下の表8に示す。   The results of this sensory evaluation test are shown in Table 8 below.

Figure 2016067296
Figure 2016067296

表8の結果から分かるように、植物油脂(硬化ヤシ油)に加えてさらに特定のアミノ酸等(アスパラギン酸ナトリウム、グリシン、シトルリン)を添加すると、乳感に優れ、しかも、自然な乳感を備えた飲料が得られることが分かった。また、グリシンやシトルリンを添加した場合(それぞれ実施例2、実施例3)でも、飲んだ後に残る乳感の余韻が持続したが、アスパラギン酸ナトリウムを添加した場合(実施例1)は、グリシンやシトルリンを添加した場合(それぞれ実施例2、実施例3)と比較して、飲んだ後に残る乳感の余韻がより長く持続する点で、牛乳を用いた陽性対照(比較例5)に最も近く、乳感の自然感が特に優れていることも分かった。一方、従来技術のように植物油脂と脱脂粉乳を用いた場合(比較例3)では、乳感は感じられるものの、粉臭や、加熱乳原料に由来する異質な乳感が感じられるなど、牛乳本来の乳感とはやや異質で、乳感の自然感の評価は低かった。
なお、グルタミン酸ナトリウムを添加した場合(比較例1)は、乳感は感じられるものの、実施例1〜3と比較して、うま味、塩味といった異味が強めに感じられ、牛乳本来の乳感とはやや異質であったため、乳感の自然感の評価は低かった。また、アルギニンを添加した場合(比較例2)も、乳感は感じられるものの、実施例1〜3と比較して、強めの苦味、しかもやや金属様の苦味が感じられ、牛乳本来の乳感とはやや異質であったため、乳感の自然感の評価は低かった。
As can be seen from the results in Table 8, when a specific amino acid or the like (sodium aspartate, glycine, citrulline) is added in addition to the vegetable oil (hardened coconut oil), the milk feel is excellent and a natural milk feel is provided. It was found that a good beverage was obtained. In addition, when glycine or citrulline was added (Examples 2 and 3 respectively), the lingering lingering feeling remained after drinking continued, but when sodium aspartate was added (Example 1), glycine and Compared to the case where citrulline was added (Examples 2 and 3 respectively), the lingering lingering feeling remaining after drinking lasted longer than that of the positive control using milk (Comparative Example 5). It was also found that the natural feeling of milk was particularly excellent. On the other hand, when vegetable oil and nonfat dry milk are used as in the prior art (Comparative Example 3), although milky feeling is felt, milky odor and extraordinary milky feeling derived from heated milk ingredients are felt. It was slightly different from the original milk feeling, and the evaluation of the natural feeling of milk feeling was low.
In addition, when sodium glutamate is added (Comparative Example 1), although the milky feeling is felt, compared to Examples 1 to 3, the tastes such as umami and salty taste are felt stronger, and the original milky feeling of milk is Since it was somewhat heterogeneous, the evaluation of the natural feeling of milk was low. Also, when arginine is added (Comparative Example 2), although a milky feeling is felt, compared to Examples 1 to 3, a stronger bitterness and a slightly metallic bitterness are felt, and the original milky feeling of milk. The evaluation of the natural feeling of milk was low.

[(2)アスパラギン酸ナトリウムの添加量等の違いによる、牛乳様の味覚・風味や、異味への影響]
飲料におけるアスパラギン酸ナトリウムの添加量、又は、飲料におけるアスパラギン酸の含有量の違いによって、容器詰乳入りコーヒー飲料における牛乳様の味覚・風味や、異味にどのような影響が生じるかを以下の方法で検討した。
[(2) Effects on the taste and flavor of milk, and off-flavors due to differences in the amount of sodium aspartate added]
The following methods show how the taste and flavor of milk-like taste and taste in coffee beverages containing packaged milk are caused by the difference in the amount of sodium aspartate in the beverage or the content of aspartic acid in the beverage. I examined it.

(2−1)アスパラギン酸ナトリウムの添加量(重量%)の違いによる、牛乳様の味覚・風味や、異味への影響
上記の表1に示す「植物油脂及びアミノ酸等添加コーヒー飲料」の配合において、アミノ酸等としてアスパラギン酸ナトリウムを用い、及び、アミノ酸等の添加量(重量%)を、0.0125〜0.5重量%まで変化させた容器詰乳入りコーヒー飲料(後述の表11参照)を、実施例1に記載の方法でそれぞれ調製した。これらの各飲料について、牛乳様の味覚及び風味(乳感)の程度を以下の表9の評価基準で評価した。さらに、各飲料について、異味(塩味、及び、脂っぽさ)の有無及び程度を以下の表10の評価基準で評価した。
(2-1) Effect on the taste and flavor of milk and taste due to the difference in the amount (% by weight) of sodium aspartate In the blending of “additional coffee drinks such as vegetable oils and amino acids” shown in Table 1 above A coffee beverage containing packed milk in which sodium aspartate is used as an amino acid or the like, and the addition amount (wt%) of the amino acid or the like is changed to 0.0125 to 0.5 wt% (see Table 11 below) Each was prepared by the method described in Example 1. For each of these beverages, the degree of milk-like taste and flavor (milkiness) was evaluated according to the evaluation criteria shown in Table 9 below. Furthermore, about each drink, the presence or absence and degree of off-taste (salt taste and greasy) were evaluated according to the evaluation criteria in Table 10 below.

Figure 2016067296
Figure 2016067296

Figure 2016067296
Figure 2016067296

かかる官能評価試験の結果を以下の表11に示す。   The results of this sensory evaluation test are shown in Table 11 below.

Figure 2016067296
Figure 2016067296

表11の結果から、アスパラギン酸ナトリウムの添加量が高くなるにしたがって、容器詰乳入りコーヒー飲料の乳感が上昇する傾向が明確に示された。また、飲料における硬化ヤシ油添加量(重量%)に対するアスパラギン酸ナトリウムの添加量(重量%)の比率(%)(以下、「植物油脂の添加量に対する、特定のアミノ酸等添加量の重量比率(%)」とも表示する。)が一定程度以上となると、異味である塩味が次第に強くなる傾向も示された。乳感と異味(塩味)の評価結果のバランスの観点から、「植物油脂の添加量に対する、特定のアミノ酸等添加量の重量比率(%)」が約2〜30%の範囲内、好ましくは2.3〜28%の範囲内、より好ましくは約4〜22%の範囲内、さらに好ましくは4.7〜19%の範囲内、より好ましくは9.4〜19%の範囲内、より好ましくは9.4〜18.7%の範囲内が好ましいことが分かった。   From the results of Table 11, it was clearly shown that the milky feeling of the container-filled milk-containing coffee beverage increased as the amount of sodium aspartate added increased. Moreover, the ratio (%) of the addition amount (% by weight) of sodium aspartate to the addition amount (% by weight) of the hardened coconut oil in the beverage (hereinafter referred to as “the weight ratio of the addition amount of a specific amino acid to the addition amount of vegetable oil ( %) ”).)) Was above a certain level, there was also a tendency that the salty taste, which is an odd taste, gradually became stronger. From the viewpoint of balance between evaluation results of milky feeling and off-flavor (salty taste), the “weight ratio (%) of added amount of specific amino acid to added amount of vegetable oil” is within a range of about 2 to 30%, preferably 2 Within the range of 3 to 28%, more preferably within the range of about 4 to 22%, even more preferably within the range of 4.7 to 19%, more preferably within the range of 9.4 to 19%, more preferably It was found that the range of 9.4 to 18.7% is preferable.

なお、この官能評価試験において用いたコーヒー飲料では、硬化ヤシ油添加量(重量%)は、硬化ヤシ油含有量(重量%)と同視できる。したがって、表11の結果から「植物油脂の添加量に対する、特定のアミノ酸等添加量の重量比率(%)」に関して先に述べたことや好ましい数値範囲は、「植物油脂の含有量に対する、特定のアミノ酸等添加量の重量比率(%)」に関しても当てはまる。   In addition, in the coffee drink used in this sensory evaluation test, hardened palm oil addition amount (weight%) can be regarded with hardened palm oil content (weight%). Therefore, from the results of Table 11, the above-mentioned and preferred numerical ranges regarding “weight ratio (%) of the addition amount of specific amino acids to the addition amount of vegetable oil and fat” are “specific to the content of vegetable oil and fat. This also applies to the “weight ratio (%) of the added amount of amino acids”.

(2−2)アスパラギン酸の含有量の違いによる、牛乳様の味覚・風味や、異味への影響
添加したアスパラギン酸ナトリウム以外に、コーヒー豆や牛乳などにも遊離アスパラギン酸等の遊離アミノ酸がごく微量含まれているとされる。そこで、上記(2−1)において官能評価試験に用いた各飲料における遊離アスパラギン酸(アスパラギン酸の単量体)の含有量(重量%)を測定し、その含有量(重量%)の数値を用いて、乳感や異味との関係を再評価した。具体的には、上記(2−1)の表11におけるアスパラギン酸ナトリウムの添加量(重量%)の数値を、遊離アスパラギン酸の含有量(重量%)の数値で置き換えた。その結果を表12に示す。なお、飲料における遊離アスパラギン酸の含有量の測定は、一般財団法人 日本食品分析センターに委託して行った。
(2-2) Effects on milk-like taste, flavor, and taste due to differences in aspartic acid content In addition to sodium aspartate added, free amino acids such as free aspartic acid are also present in coffee beans and milk. It is said that a trace amount is contained. Therefore, the content (% by weight) of free aspartic acid (aspartic acid monomer) in each beverage used in the sensory evaluation test in (2-1) above is measured, and the value of the content (% by weight) is determined. Used to re-evaluate the relationship with milk feeling and off-taste. Specifically, the numerical value of the added amount (% by weight) of sodium aspartate in Table 11 of (2-1) was replaced with the numerical value of the content (% by weight) of free aspartic acid. The results are shown in Table 12. The measurement of free aspartic acid content in beverages was outsourced to the Japan Food Analysis Center.

Figure 2016067296
Figure 2016067296

表12の結果から、遊離アスパラギン酸の含有量が高くなるにしたがって、容器詰乳入りコーヒー飲料の乳感が上昇する傾向が明確に示された。また、飲料における硬化ヤシ油添加量(重量%)に対する、飲料における遊離アスパラギン酸の含有量(重量%)の重量比率(%)(以下、「植物油脂の添加量に対する、特定の遊離アミノ酸含有量の重量比率(%)」とも表示する。)が一定程度以上となると、異味である塩味が次第に強くなる傾向も示された。乳感と異味(塩味)の評価結果のバランスの観点から、「植物油脂の添加量に対する、特定の遊離アミノ酸含有量の重量比率(%)」が約1.5〜25%の範囲内、好ましくは1.7〜21.1%の範囲内、より好ましくは約3〜16%の範囲内、さらに好ましくは3.5〜14.1%の範囲内、より好ましくは7〜14.1%の範囲内が好適であることが分かった。   From the results in Table 12, it was clearly shown that the milky feeling of the coffee beverage containing the packaged milk increased as the free aspartic acid content increased. In addition, the weight ratio (%) of the content (% by weight) of free aspartic acid in the beverage to the amount (% by weight) of hardened coconut oil added in the beverage (hereinafter referred to as “specific free amino acid content relative to the amount of vegetable oil added) The weight ratio (%) is also indicated as “%”)), and the salty taste, which is an odd taste, gradually increased. From the viewpoint of the balance between the evaluation results of milky feeling and off-flavor (salty taste), the “weight ratio (%) of the specific free amino acid content to the added amount of vegetable oil” is within a range of about 1.5 to 25%, preferably Is in the range of 1.7 to 21.1%, more preferably in the range of about 3 to 16%, still more preferably in the range of 3.5 to 14.1%, more preferably 7-14.1%. Within the range was found to be suitable.

なお、この官能評価試験において用いたコーヒー飲料では、硬化ヤシ油添加量(重量%)は、硬化ヤシ油含有量(重量%)と同視できる。したがって、表12の結果から「植物油脂の添加量に対する、特定の遊離アミノ酸含有量の重量比率(%)」に関して先に述べたことや好ましい数値範囲は、「植物油脂の含有量に対する、特定の遊離アミノ酸含有量の重量比率(%)」に関しても当てはまる。   In addition, in the coffee drink used in this sensory evaluation test, hardened palm oil addition amount (weight%) can be regarded with hardened palm oil content (weight%). Therefore, from the results of Table 12, the above-mentioned and preferred numerical ranges regarding “weight ratio (%) of specific free amino acid content with respect to added amount of vegetable oil” are “specific to the content of vegetable oil”. The same applies to the “weight ratio (%) of free amino acid content”.

[(3)植物油脂添加量の違いによる、牛乳様の味覚・風味や、異味への影響]
飲料中への植物油脂の添加量の違いによって、容器詰乳入りコーヒー飲料における牛乳様の味覚・風味や、異味にどのような影響が生じるかを以下の方法で検討した。
[(3) Effects on the taste and flavor of milk and the taste due to the difference in the amount of vegetable oil added]
The following methods were used to examine the effects of differences in the amount of vegetable oils and fats added to beverages on the taste and flavor of milk and the taste in coffee beverages containing packaged milk.

(3−1)植物油脂添加量の違いによる、牛乳様の味覚・風味や、異味への影響1
上記の表1に示す「植物油脂及びアミノ酸等添加コーヒー飲料」の配合において、アミノ酸等としてアスパラギン酸ナトリウムを用い、及び、アスパラギン酸ナトリウムの添加量を0.15重量%とした上で、植物油脂(硬化ヤシ油)の添加量(重量%)を0〜1.396重量%まで変化させた容器詰乳入りコーヒー飲料(後述の表13参照)を、実施例1に記載の方法でそれぞれ調製した。これらの各飲料について、前述の表9の評価基準で牛乳様の味覚及び風味(乳感)の程度を評価し、さらに、前述の表10の評価基準で異味(塩味、及び、脂っぽさ)の有無及び程度を評価した。かかる官能評価試験の結果を以下の表13に示す。
(3-1) Effect 1 on the taste and flavor of milk and the taste due to the difference in the amount of added vegetable oil
In the blending of the “vegetable oil and fat and amino acid-added coffee drink” shown in Table 1 above, using sodium aspartate as the amino acid and the like, and adding 0.15% by weight of sodium aspartate, vegetable oil and fat Coffee beverages containing packed milk (see Table 13 to be described later) in which the addition amount (% by weight) of (hardened coconut oil) was changed to 0 to 1.396% by weight were prepared by the method described in Example 1, respectively. . For each of these beverages, the degree of milk-like taste and flavor (milkiness) was evaluated according to the evaluation criteria shown in Table 9, and further, the taste (salty taste and greasy) was evaluated according to the evaluation criteria shown in Table 10 above. ) Was evaluated for the presence and extent. The results of this sensory evaluation test are shown in Table 13 below.

Figure 2016067296
Figure 2016067296

表13の結果から、植物油脂の添加量が不十分な量から増加していくにつれて、「植物油脂の添加量に対する、特定のアミノ酸等添加量の重量比率(%)」が低下していき、該重量比率が一定程度以下となると、異味である塩味がなくなると共に、乳感が上昇する傾向が示された。ただし、前述の重量比率が一定程度以下となると、乳感は十分であるものの、異味である脂っぽさが生じる傾向も示された。このような乳感と異味(塩味、脂っぽさ)の評価結果のバランスの観点から、「植物油脂の添加量に対する、特定のアミノ酸等添加量の重量比率(%)」が約10〜30%の範囲内、好ましくは10.7〜28%の範囲内、より好ましくは約11.5〜28%の範囲内、さらに好ましくは12.7〜28%の範囲内が好ましいことが分かった。また、植物油脂である硬化ヤシ油の添加量は、乳感との関係で、約0.35重量%以上であることが好ましく、0.537重量%以上であることがより好ましいことも示された。   From the results of Table 13, as the amount of vegetable oil added increases from an insufficient amount, the “weight ratio (%) of the added amount of a specific amino acid to the amount of vegetable oil added” decreases, When the weight ratio was not more than a certain level, the salty taste, which was an odd taste, disappeared and the milky feeling tended to increase. However, when the above-mentioned weight ratio was below a certain level, the milky feeling was sufficient, but a tendency to produce a greasy fat taste was also shown. From the viewpoint of the balance between the evaluation results of such milk feeling and taste (salt taste, greasy), the “weight ratio (%) of the added amount of a specific amino acid to the added amount of vegetable oil” is about 10 to 30. %, Preferably in the range of 10.7 to 28%, more preferably in the range of about 11.5 to 28%, even more preferably in the range of 12.7 to 28%. It is also shown that the added amount of hydrogenated coconut oil, which is vegetable oil, is preferably about 0.35% by weight or more and more preferably 0.537% by weight or more in relation to milky feeling. It was.

なお、この官能評価試験において用いたコーヒー飲料では、硬化ヤシ油添加量(重量%)は、硬化ヤシ油含有量(重量%)と同視できる。したがって、表13の結果から「植物油脂の添加量に対する、特定のアミノ酸等添加量の重量比率(%)」に関して先に述べたことや好ましい数値範囲は、「植物油脂の含有量に対する、特定のアミノ酸等添加量の重量比率(%)」に関しても当てはまる。   In addition, in the coffee drink used in this sensory evaluation test, hardened palm oil addition amount (weight%) can be regarded with hardened palm oil content (weight%). Therefore, from the results of Table 13, the above-mentioned and preferred numerical ranges regarding “weight ratio (%) of added amount of specific amino acid to added amount of vegetable oil and fat” are “specific to the content of vegetable oil and fat. This also applies to the “weight ratio (%) of the added amount of amino acids”.

(3−2)植物油脂添加量の違いによる、牛乳様の味覚・風味や、異味への影響2
上記(3−1)において官能評価試験に用いた各飲料における遊離アスパラギン酸の含有量(重量%)を測定し、その含有量(重量%)の数値を用いて、乳感や異味(塩味、脂っぽさ)との関係を再評価した。具体的には、上記(3−1)の表13におけるアスパラギン酸ナトリウムの添加量(重量%)の数値を、遊離アスパラギン酸の含有量(重量%)の数値で置き換えた。その結果を表14に示す。なお、飲料における遊離アスパラギン酸の含有量の測定は、一般財団法人 日本食品分析センターに委託して行った。
(3-2) Effect 2 on the taste / flavor of milk and taste due to differences in the amount of vegetable oil / fat added
The content (% by weight) of free aspartic acid in each beverage used in the sensory evaluation test in (3-1) above is measured, and using the numerical value of the content (% by weight), milky feeling and taste (salty, The relationship with greasyness was re-evaluated. Specifically, the numerical value of the added amount (wt%) of sodium aspartate in Table 13 of (3-1) above was replaced with the numerical value of the content (wt%) of free aspartic acid. The results are shown in Table 14. The measurement of free aspartic acid content in beverages was outsourced to the Japan Food Analysis Center.

Figure 2016067296
Figure 2016067296

表14の結果から、植物油脂の添加量が不十分な量から増加していくにつれて、「植物油脂の添加量に対する、特定の遊離アミノ酸含有量の重量比率(%)」が低下していき、該重量比率が一定程度以下となると、異味である塩味がなくなると共に、乳感が上昇する傾向が示された。ただし、前述の重量比率が一定程度以下となると、乳感は十分であるものの、異味である脂っぽさが生じる傾向も示された。このような乳感と異味(塩味、脂っぽさ)の評価結果のバランスの観点から、「植物油脂の添加量に対する、特定の遊離アミノ酸含有量の重量比率(%)」が約7〜23%の範囲内、好ましくは8〜23%の範囲内、より好ましくは約9〜21%の範囲内、さらに好ましくは9.6〜21%の範囲内が好ましいことが分かった。   From the results of Table 14, as the amount of vegetable oil added increases from an insufficient amount, the "weight ratio (%) of the specific free amino acid content to the amount of vegetable oil added" decreases. When the weight ratio was not more than a certain level, the salty taste, which was an odd taste, disappeared and the milky feeling tended to increase. However, when the above-mentioned weight ratio was below a certain level, the milky feeling was sufficient, but a tendency to produce a greasy fat taste was also shown. From the viewpoint of the balance between the evaluation results of such milk feeling and taste (salt taste, greasy), the “weight ratio (%) of the specific free amino acid content to the added amount of vegetable oil” is about 7 to 23. %, Preferably in the range of 8-23%, more preferably in the range of about 9-21%, even more preferably in the range of 9.6-21%.

なお、この官能評価試験において用いたコーヒー飲料では、硬化ヤシ油添加量(重量%)は、硬化ヤシ油含有量(重量%)と同視できる。したがって、表14の結果から「植物油脂の添加量に対する、特定の遊離アミノ酸含有量の重量比率(%)」に関して先に述べたことや好ましい数値範囲は、「植物油脂の含有量に対する、特定の遊離アミノ酸含有量の重量比率(%)」に関しても当てはまる。   In addition, in the coffee drink used in this sensory evaluation test, hardened palm oil addition amount (weight%) can be regarded with hardened palm oil content (weight%). Therefore, from the results shown in Table 14, the above-mentioned and preferred numerical ranges regarding the “weight ratio (%) of the specific free amino acid content with respect to the added amount of the vegetable oil and fat” are “the specific amount relative to the content of the vegetable oil and fat. The same applies to the “weight ratio (%) of free amino acid content”.

[(4)植物油脂の添加量に対するアミノ酸等添加量等の重量比率(%)は同じ値を維持したまま、植物油脂の添加量及びアミノ酸等添加量等を変化させたことによる、牛乳様の味覚・風味や、異味への影響]
植物油脂添加量に対する特定のアミノ酸等添加量(又は特定の遊離アミノ酸含有量)の重量比率(%)は同じ値を維持したまま、植物油脂の添加量及び特定のアミノ酸等添加量(又は特定の遊離アミノ酸等含有量)を変化させることによって、容器詰乳入りコーヒー飲料における牛乳様の味覚・風味や、異味にどのような影響が生じるかを以下の方法で検討した。
[(4) The weight ratio (%) of the added amount of amino acids, etc. with respect to the added amount of vegetable oils and fats, while maintaining the same value, changed the amount of added vegetable oils and added amino acids, etc. Effect on taste, flavor and off-taste]
While the weight ratio (%) of the specific amino acid addition amount (or specific free amino acid content) to the vegetable fat addition amount is maintained at the same value, the vegetable fat addition amount and the specific amino acid addition amount (or specific By changing the content of free amino acids and the like, the following method was used to examine the effects of milk-like taste and flavor and off-flavors in coffee beverages containing packaged milk.

(4−1)植物油脂の添加量に対する特定のアミノ酸等添加量の重量比率(%)は同じ値を維持したまま、植物油脂の添加量及び特定のアミノ酸等添加量を変化させたことによる、牛乳様の味覚・風味や、異味への影響
上記の表1に示す「植物油脂及びアミノ酸等添加コーヒー飲料」の配合において、アミノ酸等としてアスパラギン酸ナトリウムを用い、及び、アスパラギン酸ナトリウムの添加量と、硬化ヤシ油の添加量を後述の表15のようにした容器詰乳入りコーヒー飲料を、実施例1に記載の方法でそれぞれ調製した。これらの各飲料においては、上記重量比率(%)はいずれも14%である。これらの各飲料について、前述の表9の評価基準で牛乳様の味覚及び風味(乳感)の程度を評価し、さらに、前述の表10の評価基準で異味(塩味、及び、脂っぽさ)の有無及び程度を評価した。かかる官能評価試験の結果を以下の表15に示す。
(4-1) The weight ratio (%) of the addition amount of the specific amino acid to the addition amount of the vegetable oil and fat is the same value, while the addition amount of the vegetable oil and fat and the addition amount of the specific amino acid are changed. Milk-like taste / flavor and influence on off-flavors In the blending of “vegetable oils and fats and amino acid-added coffee beverages” shown in Table 1 above, sodium aspartate is used as the amino acid, and the amount of sodium aspartate added A coffee beverage containing packed milk with the added amount of hardened coconut oil as shown in Table 15 described below was prepared by the method described in Example 1. In each of these beverages, the weight ratio (%) is 14%. For each of these beverages, the degree of milk-like taste and flavor (milkiness) was evaluated according to the evaluation criteria shown in Table 9, and further, the taste (salty taste and greasy) was evaluated according to the evaluation criteria shown in Table 10 above. ) Was evaluated for the presence and extent. The results of this sensory evaluation test are shown in Table 15 below.

Figure 2016067296
Figure 2016067296

表15の結果から、「植物油脂の添加量に対する、特定のアミノ酸等添加量の重量比率(%)」で同じ値(14%)を維持したまま、植物油脂の添加量及び特定のアミノ酸等添加量を不十分な量から増加させていくと、それにつれて乳感が上昇する傾向が示された。ただし、植物油脂の添加量が一定程度以上となると、異味である脂っぽさが生じて増加していく傾向も示された。表15の結果から、植物油脂である硬化ヤシ油の添加量は、乳感及び異味(脂っぽさ)との関係で、約0.35〜2.5重量%(好ましくは約0.358〜2.5重量%)の範囲内であることが好ましく、約0.53〜2.3重量%の範囲内であることがより好ましく、約0.7〜2.2重量%(好ましくは約0.716〜2.15重量%)の範囲内であることがさらに好ましく、約0.7〜2重量%(好ましくは約0.716〜1.79重量%)の範囲内であることがさらにより好ましいことが示された。   From the results of Table 15, the amount of vegetable oil added and the specific amino acid added while maintaining the same value (14%) in the “weight ratio (%) of the amount added of the specific amino acid to the amount added of the vegetable oil” When the amount was increased from an inadequate amount, there was a tendency for the milky feeling to increase accordingly. However, when the addition amount of vegetable oils and fats became more than a certain level, it also showed a tendency to increase due to the occurrence of a greasy taste. From the results of Table 15, the amount of hydrogenated coconut oil, which is a vegetable oil, is about 0.35 to 2.5% by weight (preferably about 0.358, in relation to milky feeling and off-taste (fattyness). -2.5 wt%), preferably about 0.53-2.3 wt%, more preferably about 0.7-2.2 wt% (preferably about 0.716 to 2.15% by weight), more preferably about 0.7 to 2% by weight (preferably about 0.716 to 1.79% by weight). It was shown to be more preferable.

なお、この官能評価試験において用いたコーヒー飲料では、硬化ヤシ油添加量(重量%)は、硬化ヤシ油含有量(重量%)と同視できる。したがって、表15の結果から「植物油脂の添加量に対する、特定のアミノ酸等添加量の重量比率(%)」に関して先に述べたことや、好ましい数値範囲は、「植物油脂の含有量に対する、特定のアミノ酸等添加量の重量比率(%)」に関しても当てはまる。   In addition, in the coffee drink used in this sensory evaluation test, hardened palm oil addition amount (weight%) can be regarded with hardened palm oil content (weight%). Therefore, from the results of Table 15, what has been described above regarding the “weight ratio (%) of the addition amount of a specific amino acid to the addition amount of the vegetable oil and fat” and preferable numerical ranges are “specific to the content of the vegetable oil and fat. This also applies to the “weight ratio (%) of the added amount of amino acids”.

(4−2)植物油脂の添加量に対する特定の遊離アミノ酸含有量の重量比率(%)は同じ値を維持したまま、植物油脂の添加量及び特定の遊離アミノ酸含有量を変化させたことによる、牛乳様の味覚・風味や、異味への影響
上記(4−1)において官能評価試験に用いた各飲料における遊離アスパラギン酸の含有量(重量%)を測定し、その含有量(重量%)の数値を用いて、乳感や異味(塩味、脂っぽさ)との関係を再評価した。具体的には、上記(4−1)の表15におけるアスパラギン酸ナトリウムの添加量(重量%)の数値を、遊離アスパラギン酸の含有量(重量%)の数値で置き換えた。その結果を表16に示す。なお、飲料における遊離アスパラギン酸の含有量の測定は、一般財団法人 日本食品分析センターに委託して行った。
(4-2) The weight ratio (%) of the specific free amino acid content with respect to the added amount of the vegetable oil and fat is the same value, while the added amount of the vegetable oil and the specific free amino acid content is changed. Milk-like taste / flavor and influence on off-flavor The content (% by weight) of free aspartic acid in each beverage used in the sensory evaluation test in (4-1) above was measured. Using numerical values, the relationship with milk feeling and taste (salty taste, greasy) was re-evaluated. Specifically, the numerical value of the added amount (% by weight) of sodium aspartate in Table 15 of (4-1) was replaced with the numerical value of the content (% by weight) of free aspartic acid. The results are shown in Table 16. The measurement of free aspartic acid content in beverages was outsourced to the Japan Food Analysis Center.

Figure 2016067296
Figure 2016067296

表16の結果から、「植物油脂の添加量に対する、特定の遊離アミノ酸含有量の重量比率(%)」で同じ値(10.5%)を維持したまま、植物油脂の添加量及び特定のアミノ酸含有量を不十分な量から増加させていくと、それにつれて乳感が上昇する傾向が示された。ただし、表15の結果と同様に、植物油脂の添加量が一定程度以上となると、異味である脂っぽさが生じて増加していく傾向も示された。   From the results of Table 16, while adding the same value (10.5%) in the "weight ratio (%) of specific free amino acid content to the added amount of vegetable oil", the added amount of vegetable oil and specific amino acid When the content was increased from an insufficient amount, the milk feeling tended to increase accordingly. However, similar to the results in Table 15, when the amount of vegetable oil added was above a certain level, a tendency to increase the fatiness of a different taste was also shown.

なお、この官能評価試験において用いたコーヒー飲料では、硬化ヤシ油添加量(重量%)は、硬化ヤシ油含有量(重量%)と同視できる。したがって、表16の結果から「植物油脂の添加量に対する、特定の遊離アミノ酸含有量の重量比率(%)」に関して先に述べたことや好ましい数値範囲は、「植物油脂の含有量に対する、特定の遊離アミノ酸含有量の重量比率(%)」に関しても当てはまる。   In addition, in the coffee drink used in this sensory evaluation test, hardened palm oil addition amount (weight%) can be regarded with hardened palm oil content (weight%). Therefore, from the results of Table 16, the above-mentioned and preferred numerical ranges regarding “weight ratio (%) of specific free amino acid content to added amount of vegetable oil” are “specific to the vegetable oil content”. The same applies to the “weight ratio (%) of free amino acid content”.

ところで、「アスパラギン酸ナトリウム」に代えて「アスパラギン酸」を添加した場合や、「アスパラギン酸ナトリウム」に代えて「遊離アスパラギン酸」を含有させた場合も、アスパラギン酸ナトリウムを添加し又は含有させた本願実施例の表11〜表16とほぼ同様の結果が得られると考えられる。アスパラギン酸や遊離アスパラギン酸は、塩味に寄与しているナトリウムを含んでおらず、アスパラギン酸ナトリウムを添加し又は含有させた場合に異味である塩味が生じる濃度に達しても、かかる異味である塩味は生じない蓋然性がきわめて高いからである。したがって、表11〜表16の結果から「植物油脂の添加量に対する、特定のアミノ酸等添加量の重量比率(%)」又は「植物油脂の添加量に対する、特定の遊離アミノ酸含有量の重量比率(%)」に関して先に述べたことや好ましい数値範囲は、「アスパラギン酸ナトリウム」に代えて「アスパラギン酸」を添加した場合や、「アスパラギン酸ナトリウム」に代えて「遊離アスパラギン酸」を含有させた場合にも当てはまる蓋然性がきわめて高い。   By the way, when "aspartic acid" is added instead of "sodium aspartate", or when "free aspartic acid" is contained instead of "sodium aspartate", sodium aspartate is added or contained. It is considered that substantially the same results as in Tables 11 to 16 of the examples of the present application are obtained. Aspartic acid and free aspartic acid do not contain sodium that contributes to salty taste, and even when sodium aspartate is added or contained, the salty taste that has such a strange taste is reached even when the salty taste that is a strange taste is reached. This is because there is a very high probability that no occurrence will occur. Therefore, from the results of Tables 11 to 16, “weight ratio of specific amino acid and the like added to vegetable oil and fat (%)” or “weight ratio of specific free amino acid content to vegetable oil and fat added ( %)), And the preferable numerical range includes “aspartic acid” instead of “sodium aspartate” or “free aspartic acid” instead of “sodium aspartate”. The probability of being true also in cases is very high.

「アスパラギン酸ナトリウム」に代えて「グリシン又はシトルリン」を添加した場合や、「アスパラギン酸ナトリウム」に代えて「遊離グリシン又は遊離シトルリン」を含有させた場合も、アスパラギン酸ナトリウムを添加し又は含有させた本願実施例の表11〜表16とほぼ同様の結果が得られた。これは、グリシンやシトルリンが、乳感の程度に関してアスパラギン酸ナトリウムと同等の評価(◎)を得たこと(表8)、及び、グリシンやシトルリンや遊離グリシンや遊離シトルリンは塩味に寄与しているナトリウムを含んでおらず、アスパラギン酸ナトリウムを添加し又は含有させた場合に異味である塩味が生じる濃度に達しても、かかる異味である塩味は生じないことを考慮すると、ごく自然な結果といえる。したがって、表11〜表16の結果から「植物油脂の添加量に対する、特定のアミノ酸等添加量の重量比率(%)」又は「植物油脂の添加量に対する、特定の遊離アミノ酸含有量の重量比率(%)」に関して先に述べたことや好ましい数値範囲は、「アスパラギン酸ナトリウム」に代えて「グリシン又はシトルリン」を添加した場合や、「アスパラギン酸ナトリウム」に代えて「遊離グリシン又は遊離シトルリン」を含有させた場合にも当てはまる。   When “glycine or citrulline” is added instead of “sodium aspartate”, or when “free glycine or free citrulline” is contained instead of “sodium aspartate”, sodium aspartate is added or contained. The substantially same results as Tables 11 to 16 of the examples of the present application were obtained. This is because glycine and citrulline obtained the same evaluation (◎) as sodium aspartate regarding the degree of milky feeling (Table 8), and glycine, citrulline, free glycine and free citrulline contribute to salty taste. It does not contain sodium, and it can be said that it is a very natural result when considering that the salty taste that is unpleasant taste is not reached even when sodium aspartate is added or contained, even if it reaches a concentration where the taste is unpleasant. . Therefore, from the results of Tables 11 to 16, “weight ratio of specific amino acid and the like added to vegetable oil and fat (%)” or “weight ratio of specific free amino acid content to vegetable oil and fat added ( %)), And the preferred numerical range is that when “glycine or citrulline” is added instead of “sodium aspartate”, or “free glycine or free citrulline” is substituted for “sodium aspartate”. This also applies when it is contained.

なお、「アスパラギン酸ナトリウム」に代えて「アスパラギン酸、グリシン及びシトルリンから選択される2種又は3種」を添加した場合や、「アスパラギン酸ナトリウム」に代えて「遊離アスパラギン酸、遊離グリシン及び遊離シトルリンから選択される2種又は3種」を含有させた場合も、アスパラギン酸ナトリウムを添加し又は含有させた本願実施例の表11〜表16とほぼ同様の結果が得られると考えられる。アスパラギン酸、グリシン、シトルリン、遊離アスパラギン酸、遊離グリシン及び遊離シトルリンはいずれも、塩味に寄与しているナトリウムを含んでおらず、これらの合計濃度が、アスパラギン酸ナトリウムを添加し又は含有させた場合に異味である塩味が生じる濃度に達しても、かかる異味である塩味は生じない蓋然性がきわめて高いからである。したがって、表11〜表16の結果から「植物油脂の添加量に対する、特定のアミノ酸等添加量の重量比率(%)」又は「植物油脂の添加量に対する、特定の遊離アミノ酸含有量の重量比率(%)」に関して先に述べたことや好ましい数値範囲は、「アスパラギン酸ナトリウム」に代えて「アスパラギン酸、グリシン及びシトルリンから選択される2種又は3種」を併用して添加した場合や、「アスパラギン酸ナトリウム」に代えて「遊離アスパラギン酸、遊離グリシン及び遊離シトルリンから選択される2種又は3種」を含有させた場合にも当てはまる蓋然性がきわめて高いと考えられる。   In addition, when “two or three kinds selected from aspartic acid, glycine and citrulline” are added instead of “sodium aspartate”, or “free aspartic acid, free glycine and free are replaced with“ sodium aspartate ”. Even when 2 or 3 types selected from citrulline are contained, it is considered that substantially the same results as Tables 11 to 16 in the Examples of the present application to which sodium aspartate was added or contained were obtained. Neither aspartic acid, glycine, citrulline, free aspartic acid, free glycine or free citrulline contains sodium that contributes to saltiness, and the total concentration of these is when sodium aspartate is added or included This is because there is a very high probability that even if the concentration at which salty taste that is unnatural is reached, salty taste that is unnatural is not produced. Therefore, from the results of Tables 11 to 16, “weight ratio of specific amino acid and the like added to vegetable oil and fat (%)” or “weight ratio of specific free amino acid content to vegetable oil and fat added ( %)), And the preferable numerical range is the case where “two or three kinds selected from aspartic acid, glycine and citrulline” are used in combination instead of “sodium aspartate” or “ It is considered that the probability of being applied is extremely high when “two or three kinds selected from free aspartic acid, free glycine and free citrulline” are contained instead of “sodium aspartate”.

本発明は、容器詰飲料又は乳代替組成物の長期保存により発生する乳脂肪由来の劣化臭が抑制されつつ、牛乳様の自然な味覚及び風味に優れた容器詰飲料又は乳代替組成物を提供する。容器詰飲料に関してより詳しくは、容器詰飲料の長期保存により発生する乳脂肪由来の劣化臭を抑制しつつ、牛乳様の自然な味覚及び風味に優れており、しかも、異味(塩味及び脂っぽさ)が抑制された容器詰飲料を提供する。   The present invention provides a packaged beverage or milk substitute composition excellent in milk-like natural taste and flavor while suppressing deterioration odor derived from milk fat generated by long-term storage of the packaged beverage or milk substitute composition To do. More specifically regarding container-packed beverages, it has excellent milk-like natural taste and flavor while suppressing the deterioration odor derived from milk fat caused by long-term storage of container-packed beverages, and it also has a different taste (salt taste and greasy) The present invention provides a packaged beverage in which (a) is suppressed.

Claims (6)

容器詰飲料であって、
(a)植物油脂、及び、(b)遊離アスパラギン酸、遊離グリシン及び遊離シトルリンからなる群から選択される1種又は2種以上の遊離アミノ酸を含有し、
前記飲料における前記植物油脂の含有量が、前記飲料全量に対して0.35重量%以上であり、かつ、
前記飲料における前記植物油脂の含有量に対する、前記飲料における前記遊離アミノ酸の合計含有量の重量比率が、1.5〜25%の範囲内であることを特徴とする、
長期保存による乳脂肪由来の劣化臭が抑制されつつ、牛乳様の自然な味覚及び風味に優れた容器詰飲料。
A packaged beverage,
(A) vegetable oil and fat, and (b) one or more free amino acids selected from the group consisting of free aspartic acid, free glycine and free citrulline,
The content of the vegetable oil in the beverage is 0.35% by weight or more based on the total amount of the beverage, and
The weight ratio of the total content of the free amino acids in the beverage to the content of the vegetable oil in the beverage is in the range of 1.5 to 25%,
A container-packed beverage with excellent milk-like natural taste and flavor while suppressing deterioration odor derived from milk fat due to long-term storage.
飲料における植物油脂の含有量に対する、飲料における遊離アミノ酸の合計含有量の重量比率が、3〜16%の範囲内であることを特徴とする請求項1に記載の容器詰飲料。 The container-packed beverage according to claim 1, wherein the weight ratio of the total content of free amino acids in the beverage to the content of vegetable oil in the beverage is in the range of 3 to 16%. 飲料における植物油脂の含有量が、飲料全量に対して0.35〜2.5重量%の範囲内であることを特徴とする請求項1又は2に記載の容器詰飲料。 The container-packed beverage according to claim 1 or 2, wherein the content of the vegetable oil in the beverage is in the range of 0.35 to 2.5% by weight with respect to the total amount of the beverage. 植物油脂を含有する乳代替組成物において、
アスパラギン酸塩、アスパラギン酸、グリシン、グリシン塩、シトルリン及びシトルリン塩からなる群から選択される1種又は2種以上のアミノ酸又はその塩が添加され、かつ、
前記乳代替組成物における前記植物油脂の添加量に対する、前記乳代替組成物における前記アミノ酸又はその塩の合計添加量の重量比率が、2〜30%の範囲内に調整されたことを特徴とする、長期保存による乳脂肪由来の劣化臭が抑制されつつ、牛乳様の自然な味覚及び風味に優れた乳代替組成物。
In a milk replacement composition containing vegetable oils and fats,
One or more amino acids selected from the group consisting of aspartate, aspartate, glycine, glycine salt, citrulline and citrulline salt or a salt thereof are added; and
The weight ratio of the total addition amount of the amino acid or the salt thereof in the milk substitute composition to the addition amount of the vegetable oil or fat in the milk substitute composition is adjusted within a range of 2 to 30%. A milk substitute composition excellent in milk-like natural taste and flavor while suppressing deterioration odor derived from milk fat due to long-term storage.
容器詰飲料において、
(a)植物油脂、及び、(b)アスパラギン酸塩、アスパラギン酸、グリシン、グリシン塩、シトルリン及びシトルリン塩からなる群から選択される1種又は2種以上のアミノ酸又はその塩が添加され、
前記飲料における前記植物油脂の添加量が、前記飲料全量に対して0.35重量%以上であり、かつ、
前記飲料における前記植物油脂の添加量に対する、前記飲料における前記アミノ酸又はその塩の合計添加量の重量比率が、2〜30%の範囲内に調整されたことを特徴とする、
長期保存による乳脂肪由来の劣化臭が抑制されつつ、牛乳様の自然な味覚及び風味に優れた容器詰飲料。
In packaged beverages,
(A) vegetable oil and fat, and (b) one or more amino acids selected from the group consisting of aspartate, aspartic acid, glycine, glycine salt, citrulline and citrulline salt or salts thereof are added,
The amount of the vegetable oil in the beverage is 0.35% by weight or more based on the total amount of the beverage, and
The weight ratio of the total addition amount of the amino acid or salt thereof in the beverage to the addition amount of the vegetable fat in the beverage is adjusted within a range of 2 to 30%,
A container-packed beverage with excellent milk-like natural taste and flavor while suppressing deterioration odor derived from milk fat due to long-term storage.
容器詰飲料が、容器詰乳飲料又は容器詰乳入り飲料であることを特徴とする請求項1〜3及び5のいずれかに記載の容器詰飲料。 The container-packed drink according to any one of claims 1 to 3, wherein the container-packed drink is a container-packed milk drink or a container-filled milk-containing drink.
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JPS5843755A (en) * 1981-09-08 1983-03-14 T Hasegawa Co Ltd Milky flavor imparting agent and modifier
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Publication number Priority date Publication date Assignee Title
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