JP2016065165A5 - - Google Patents
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- JP2016065165A5 JP2016065165A5 JP2014195456A JP2014195456A JP2016065165A5 JP 2016065165 A5 JP2016065165 A5 JP 2016065165A5 JP 2014195456 A JP2014195456 A JP 2014195456A JP 2014195456 A JP2014195456 A JP 2014195456A JP 2016065165 A5 JP2016065165 A5 JP 2016065165A5
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- JP
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- parts
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- general formula
- thermoplastic elastomer
- monomer
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- 229920002725 Thermoplastic elastomer Polymers 0.000 claims description 6
- 239000000178 monomer Substances 0.000 claims description 6
- 229920000800 Acrylic rubber Polymers 0.000 claims description 4
- NLHHRLWOUZZQLW-UHFFFAOYSA-N acrylonitrile Chemical group C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 claims description 4
- 238000004519 manufacturing process Methods 0.000 claims description 4
- VOZRXNHHFUQHIL-UHFFFAOYSA-N Glycidyl methacrylate Chemical compound CC(=C)C(=O)OCC1CO1 VOZRXNHHFUQHIL-UHFFFAOYSA-N 0.000 claims description 2
- 239000011203 carbon fibre reinforced carbon Substances 0.000 claims description 2
- 239000011258 core-shell material Substances 0.000 claims description 2
- 238000004132 cross linking Methods 0.000 claims description 2
- 239000000203 mixture Substances 0.000 claims description 2
- 229920000728 polyester Polymers 0.000 claims description 2
- FBCQUCJYYPMKRO-UHFFFAOYSA-N prop-2-enyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OCC=C FBCQUCJYYPMKRO-UHFFFAOYSA-N 0.000 claims description 2
- 229920001169 thermoplastic Polymers 0.000 claims description 2
- 239000004416 thermosoftening plastic Substances 0.000 claims description 2
- 239000003431 cross linking reagent Substances 0.000 claims 1
Description
本発明は以下のものである。
（Ａ）アクリルゴムを１００質量部と、（Ｂ）熱可塑性ポリエステルを１５〜７０質量部含む混合物を、（Ａ）１００質量部に対して０．１〜５質量部の（Ｃ）架橋剤の存在下で動的に架橋して熱可塑性エラストマーを製造する方法であって、
（Ａ）アクリルゴムは、コア−シェル構造を有し、
コア層は、
（ａ−１）一般式（１）及び／又は一般式（２）で表される単量体から選ばれる少なくとも１種を８０〜１００質量部と、
（ａ−２）アクリロニトリル単量体を０〜２０質量部と、
（ａ−３）メタクリル酸アリル単量体を、（ａ−１）と（ａ−２）の合計１００質量部に対して０．１〜２質量部とを含み、
シェル層は、側鎖に炭素−炭素二重結合を有する多官能単量体を含まず、
（ａ−４）一般式（１）及び／又は一般式（２）で表される単量体から選ばれる少なくとも１種を８０〜１００質量部と、
（ａ−５）アクリロニトリル単量体を０〜２０質量部と、
（ａ−６）メタクリル酸グリシジル単量体を、（ａ−４）と（ａ−５）の合計１００質量部に対して０〜５質量部とを含む、熱可塑性エラストマーの製造方法
（式中、ｎは０、１又は３である）
（式中、ｍは０又は１である）
The present invention is as follows .
(A) A mixture containing 100 parts by mass of acrylic rubber and (B) 15 to 70 parts by mass of thermoplastic polyester, (A) A method for producing a thermoplastic elastomer by dynamically crosslinking in the presence of a thermoplastic elastomer,
(A) Acrylic rubber has a core-shell structure,
The core layer is
(A-1) 80 to 100 parts by mass of at least one selected from monomers represented by general formula (1) and / or general formula (2);
(A-2) 0-20 parts by mass of acrylonitrile monomer;
(A-3) The allyl methacrylate monomer includes 0.1 to 2 parts by mass with respect to 100 parts by mass in total of (a-1) and (a-2),
The shell layer does not include a polyfunctional monomer having a carbon-carbon double bond in the side chain,
(A-4) 80 to 100 parts by mass of at least one selected from monomers represented by general formula (1) and / or general formula (2);
(A-5) 0-20 parts by mass of acrylonitrile monomer;
(A-6) A method for producing a thermoplastic elastomer, comprising glycidyl methacrylate monomer in an amount of 0 to 5 parts by mass with respect to a total of 100 parts by mass of (a-4) and (a-5).
(Wherein n is 0, 1 or 3)
(Where m is 0 or 1)
Claims (1)
（Ａ）アクリルゴムは、コア−シェル構造を有し、
コア層は、
（ａ−１）一般式（１）及び／又は一般式（２）で表される単量体から選ばれる少なくとも１種を８０〜１００質量部と、
（ａ−２）アクリロニトリル単量体を０〜２０質量部と、
（ａ−３）メタクリル酸アリル単量体を、（ａ−１）と（ａ−２）の合計１００質量部に対して０．１〜２質量部とを含み、
シェル層は、側鎖に炭素−炭素二重結合を有する多官能単量体を含まず、
（ａ−４）一般式（１）及び／又は一般式（２）で表される単量体から選ばれる少なくとも１種を８０〜１００質量部と、
（ａ−５）アクリロニトリル単量体を０〜２０質量部と、
（ａ−６）メタクリル酸グリシジル単量体を、（ａ−４）と（ａ−５）の合計１００質量部に対して０〜５質量部とを含む、
熱可塑性エラストマーの製造方法。
（式中、ｎは０、１又は３である）
（式中、ｍは０又は１である）
(A) 100 parts by mass of acrylic rubber, (B) a mixture of a thermoplastic polyester containing 15 to 70 parts by weight, of (A) 0.1 to 5 parts by weight per 100 parts by mass of (C) crosslinking agent A method for producing a thermoplastic elastomer by dynamically crosslinking in the presence of a thermoplastic elastomer,
(A) Acrylic rubber has a core-shell structure,
The core layer is
(A-1) 80 to 100 parts by mass of at least one selected from monomers represented by general formula (1) and / or general formula (2);
(A-2) 0-20 parts by mass of acrylonitrile monomer;
(A-3) The allyl methacrylate monomer includes 0.1 to 2 parts by mass with respect to 100 parts by mass in total of (a-1) and (a-2) ,
The shell layer does not include a polyfunctional monomer having a carbon-carbon double bond in the side chain,
(A-4) 80 to 100 parts by mass of at least one selected from monomers represented by general formula (1) and / or general formula (2);
(A-5) 0-20 parts by mass of acrylonitrile monomer;
(A-6) The glycidyl methacrylate monomer contains 0 to 5 parts by mass with respect to a total of 100 parts by mass of (a-4) and (a-5) .
A method for producing a thermoplastic elastomer.
(Wherein n is 0, 1 or 3)
(Where m is 0 or 1)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2014195456A JP6443659B2 (en) | 2014-09-25 | 2014-09-25 | Thermoplastic elastomer |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2014195456A JP6443659B2 (en) | 2014-09-25 | 2014-09-25 | Thermoplastic elastomer |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2016065165A JP2016065165A (en) | 2016-04-28 |
| JP2016065165A5 true JP2016065165A5 (en) | 2017-09-28 |
| JP6443659B2 JP6443659B2 (en) | 2018-12-26 |
Family
ID=55805106
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2014195456A Active JP6443659B2 (en) | 2014-09-25 | 2014-09-25 | Thermoplastic elastomer |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JP6443659B2 (en) |
Family Cites Families (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH07103196B2 (en) * | 1988-10-07 | 1995-11-08 | 武田薬品工業株式会社 | Core shell polymer |
| JPH08231770A (en) * | 1995-02-23 | 1996-09-10 | Nippon Zeon Co Ltd | Thermoplastic elastomer composition |
| WO2005030869A1 (en) * | 2003-09-29 | 2005-04-07 | Zeon Corporation | Thermoplastic elastomer composition and formed article |
| WO2007037526A1 (en) * | 2005-09-30 | 2007-04-05 | Jsr Corporation | Thermoplastic elastomer composition and process for production thereof |
| CN103097457A (en) * | 2010-07-08 | 2013-05-08 | 陶氏环球技术有限责任公司 | Thermoplastic composition, method of producing the same, and articles made therefrom |
-
2014
- 2014-09-25 JP JP2014195456A patent/JP6443659B2/en active Active
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