JP2016036335A - Gel composition - Google Patents

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JP2016036335A
JP2016036335A JP2015142885A JP2015142885A JP2016036335A JP 2016036335 A JP2016036335 A JP 2016036335A JP 2015142885 A JP2015142885 A JP 2015142885A JP 2015142885 A JP2015142885 A JP 2015142885A JP 2016036335 A JP2016036335 A JP 2016036335A
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gel composition
composition
corn starch
texture
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JP6641753B2 (en
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玄 奥平
Gen Okudaira
玄 奥平
敏行 竹田
Toshiyuki Takeda
敏行 竹田
美由紀 唐木
Miyuki Karaki
美由紀 唐木
佳祐 伊藤
Keisuke Ito
佳祐 伊藤
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Taisho Pharmaceutical Co Ltd
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Abstract

PROBLEM TO BE SOLVED: To provide a gel composition that imparts fruit pulp-like texture and suppresses water separation with time.SOLUTION: The inventors have found that when high amylose corn starch is blended into a gel composition, grated fruit pulp-like texture (grated texture) is given and water separation with time can be suppressed. A gel composition of the present invention contains high amylose corn starch. The gel composition is preferably blended with at least one gelling agent selected from the group consisting of carrageenan, glucomannan, gelatin, agar, gellan gum, xanthan gum, locust bean gum, and pectin. The composition of the present invention is provided as a food or a medicament.SELECTED DRAWING: None

Description

本発明は、ゲル組成物に関し、果肉感を付与し、また、経時的な離水を抑制した組成物に関する。   The present invention relates to a gel composition, and relates to a composition that imparts a flesh feel and suppresses water separation over time.

ゼラチンや寒天、カラギーナン等のゲル化剤を含有するゼリーのような形態は、優れた服用性から嚥下能力が低下した老人、病人用製剤に、着色や風味付けが容易なことから小児向けの製剤に、また、水なしで服用できる利点を活かした携帯用の製剤などに適用できることなどから、近年、食品、サプリメント、医薬品等、幅広い分野で注目されている製剤である。ゼリーの嗜好性を高めるため、果肉などを添加し食感を付与したものが多く知られるが、果肉などを添加せずに果肉感を付与する方法も報告されている(特許文献1)。
一方、ゲル化剤を配合したゲル組成物は、冷蔵もしくは常温保存中に経時的に水を放出する「離水」が生じるため、食感や外観が著しく低下するという課題がある。
このような組成物の離水による品質低下を抑制するために、従来、ゲル化剤の増量や、イオタカラギーナン、ローカストビーンガム等の併用により離水防止効果を発揮することが知られているゲル化剤の併用、保水効果を有するトレハロース等の添加剤の配合等が行われている(特許文献2〜3)。また、ゲル化剤の種類によっては塩の添加なども行われている(特許文献4)。しかしながら、このようないずれの方法によっても離水を十分に抑制することは難しく、ゲル強度が増加し食感が損なわれる等の課題が生じてしまうのが現状である。
Jelly-like forms containing gelatin, agar, carrageenan and other gelling agents are formulated for children, because they are easy to color and flavor into preparations for the elderly and sick who have reduced swallowing ability due to their excellent dosing properties. In addition, since it can be applied to portable preparations that take advantage of the ability to be taken without water, it has recently been attracting attention in a wide range of fields such as foods, supplements, and pharmaceuticals. In order to enhance the palatability of jelly, many are known that have been added with a flesh or the like to impart a texture, but a method of imparting a flesh without adding a flesh or the like has also been reported (Patent Document 1).
On the other hand, a gel composition containing a gelling agent has a problem that the texture and appearance are remarkably reduced because “water separation” occurs in which water is released over time during refrigeration or storage at room temperature.
In order to suppress the quality deterioration due to water separation of such a composition, conventionally, a gelling agent that is known to exert a water separation preventing effect by increasing the amount of the gelling agent or using a combination of iota carrageenan, locust bean gum, etc. Combination of additives such as trehalose having a water retention effect and the like (Patent Documents 2 to 3). Moreover, addition of a salt etc. is also performed depending on the kind of gelatinizer (patent document 4). However, it is difficult to sufficiently suppress water separation by any of these methods, and the current situation is that the gel strength increases and the texture is impaired.

ハイアミロースコーンスターチは、消化されにくいアミロースを豊富に含むハイアミロースコーンという品種のトウモロコシから作られたコーンスターチであり、オーストラリアにおいて、古典的育種法によって品種改良されたnon―GMOの品種である。一般的にコーンスターチは、アミロースとアミロペクチンから成るが、ハイアミロースコーンスターチはその名の通りアミロース含量が高く、アミロースを50〜90%以上含有する。コーンスターチは水とともに加熱すると水を吸収、膨張して糊状の物質に変化する「糊化」を起こすが、でんぷんの糊化特性はアミロースとアミロペクチンの比率によって大きく異なる。アミロペクチンが豊富に含まれる一般的なコーンスターチやアミロペクチンを100%含有するワキシーコーンスターチは低濃度、低温度でも糊化しやすいため、通常のコーンスターチはブラマンジェ等のゲル状組成物の成型に用いられることがあるが、ハイアミロースコーンスターチにはそのような用途は知られておらず、糊化しづらい特性からフライ食品やクッキー、パン等の食感改良に用いられている。   High amylose corn starch is a corn starch made from a variety of maize called high amylose corn, which is rich in amylose that is difficult to digest, and is a non-GMO variety that has been improved in Australia by classical breeding methods. Corn starch is generally composed of amylose and amylopectin, but high amylose corn starch has a high amylose content as its name suggests, and contains 50 to 90% or more of amylose. Corn starch absorbs water when heated with water and swells to cause “gelatinization” that changes to a paste-like substance. Starch gelatinization properties vary greatly depending on the ratio of amylose and amylopectin. Common corn starch rich in amylopectin and waxy corn starch containing 100% amylopectin are easy to gelatinize at low concentration and low temperature, so normal corn starch may be used for molding gel-like compositions such as bramange However, high amylose corn starch is not known for such use, and is used to improve the texture of fried foods, cookies, breads and the like because it is difficult to gelatinize.

特許第3101524号公報Japanese Patent No. 3101524 特開2008−99640号公報JP 2008-99640 A 特許第4819300号Patent No. 4819300 特開2008−1655号公報JP 2008-1655 A

本発明は、果肉感を付与し、また、経時的な離水を抑制したゲル組成物を提供することを課題とする。   This invention makes it a subject to provide the gel composition which provided the flesh feeling and suppressed water separation with time.

本発明者らは、上記課題を解決するため鋭意研究を重ねた結果、ゲル組成物にハイアミロースコーンスターチを配合すると、すりおろした果肉を入れたような食感(すりおろし感)を付与でき、また、経時的な離水を抑制できることを見出し、本発明を完成した。   As a result of intensive studies to solve the above-mentioned problems, the inventors of the present invention can impart a texture (grated feeling) such as grated pulp when blended with high amylose corn starch in the gel composition, Moreover, it discovered that water separation with time could be suppressed and completed the present invention.

すなわち、本発明は、
(1)ハイアミロースコーンスターチを含有することを特徴とするゲル組成物、
(2)ゲル組成物が、食品又は経口医薬品である(1)に記載の組成物、
(3)食品が、ゼリー、グミ、アイスクリーム、プリン、ムース、ババロア、ヨーグルト、水ようかん、杏仁豆腐又はジャムである(2)記載の組成物、
(4)経口医薬品がゼリー剤である(2)に記載の組成物、
(5)カラギーナン、グルコマンナン、ゼラチン、寒天、ジェランガム、キサンタンガム、ローカストビーンガム、ペクチンからなる群から選ばれる少なくとも1種のゲル化剤を含有する(1)〜(4)のいずれかに記載の組成物、
である。
That is, the present invention
(1) A gel composition comprising high amylose corn starch,
(2) The composition according to (1), wherein the gel composition is a food or an oral drug,
(3) The composition according to (2), wherein the food is jelly, gummy, ice cream, pudding, mousse, bavaroa, yogurt, mizuyokan, apricot tofu or jam,
(4) The composition according to (2), wherein the oral drug is a jelly agent,
(5) It contains at least one gelling agent selected from the group consisting of carrageenan, glucomannan, gelatin, agar, gellan gum, xanthan gum, locust bean gum and pectin, according to any one of (1) to (4) Composition,
It is.

本発明により、すりおろした果肉を入れたような特有の果肉感(すりおろし感)を有し、また、離水を抑制したゲル組成物を提供することが可能となった。本発明に係る組成物は、嗜好性が高く、ゲル組成物の本来の食感を損なうことなく、良好な品質を保持することができる。   According to the present invention, it is possible to provide a gel composition that has a peculiar flesh feeling (grated feeling) as if grated flesh is added and that suppresses water separation. The composition according to the present invention has high palatability and can maintain good quality without impairing the original texture of the gel composition.

本発明のハイアミロースコーンスターチの配合量は、発明の効果の点から本発明の組成物全体に対して0.1質量%以上が好ましく、より好ましくは1.0〜15.0質量%である。   The blending amount of the high amylose corn starch of the present invention is preferably 0.1% by mass or more, more preferably 1.0 to 15.0% by mass with respect to the entire composition of the present invention from the viewpoint of the effect of the present invention.

本発明のゲル組成物とは、多量の水分を含むが自重では流されず、形を保っているものであって、ゲル化剤によって調製されたものをいう。好ましい形態としては、ゼリー、グミ、アイスクリーム、プリン、ムース、ババロア、ヨーグルト、水ようかん、杏仁豆腐、ジャムが挙げられ、好ましくはゼリー、グミ、アイスクリーム、プリン、ババロアであり、この中でもゼリーが最も好ましい。   The gel composition of the present invention refers to a gel composition that contains a large amount of water but does not flow under its own weight, maintains its shape, and is prepared with a gelling agent. Preferable forms include jelly, gummy, ice cream, pudding, mousse, bavaroa, yogurt, mizuyokan, apricot tofu, jam, and preferably jelly, gummy, ice cream, pudding, bavaroa, among which jelly is Most preferred.

本発明のゲル組成物は、食品(飲食品、特定保健用食品、栄養機能食品、特別用途食品、機能性食品、健康補助食品(サプリメント)を含む)、外用又は経口用の医薬品、医薬部外品など幅広く利用することができる。   The gel composition of the present invention includes foods (including foods and drinks, foods for specified health use, functional foods for nutrition, special foods, functional foods, health supplements (supplements)), pharmaceuticals for external use or oral use, and quasi drugs. It can be used widely.

本発明のゲル化剤としては、増粘多糖類が好ましい。例えばカラギーナン(ι、λ、κ)、ゼラチン、寒天、カラギーナン、ジェランガム、キサンタンガム、ローカストビーンガム、ペクチン、グルコマンナン等が挙げられるが、発明の効果の点から、ゼラチン、寒天、カラギーナン、グルコマンナンが好ましく、更に好ましくはゼラチン、寒天、カラギーナン、グルコマンナンの中から2種以上を組み合わせて配合するのが好ましい。本発明において、ゲル化剤の含有量は、対象とする組成物の形態、ゲル化剤の種類、含まれる水分含量等によって適宜調製可能であるが、本発明の組成物全体に対し0.1〜5.0質量%が好ましく、より好ましくは0.5〜3.0質量%である。   The gelling agent of the present invention is preferably a thickening polysaccharide. For example, carrageenan (ι, λ, κ), gelatin, agar, carrageenan, gellan gum, xanthan gum, locust bean gum, pectin, glucomannan and the like. More preferably, it is preferable to combine two or more of gelatin, agar, carrageenan and glucomannan in combination. In the present invention, the content of the gelling agent can be appropriately adjusted depending on the form of the target composition, the type of gelling agent, the water content contained, etc., but is 0.1% relative to the total composition of the present invention. -5.0 mass% is preferable, More preferably, it is 0.5-3.0 mass%.

本発明のゲル組成物中の水の含有量は、20.0〜99.0質量%が好ましく、さらに好ましくは40.0〜99.0質量%であり、最も好ましくは50.0〜99.0質量%である。   The content of water in the gel composition of the present invention is preferably 20.0 to 99.0% by mass, more preferably 40.0 to 99.0% by mass, and most preferably 50.0 to 99.0% by mass. 0% by mass.

本発明の組成物の製造方法は特に限定されないが、例えば以下の方法が挙げられる。
適当な温度に加温した水にゲル化剤を攪拌・溶解し、ハイアミロースコーンスターチと必要に応じて食品や医薬品に汎用される公知の添加剤を混合した後、容器に充填し、冷却すればよい。
Although the manufacturing method of the composition of this invention is not specifically limited, For example, the following method is mentioned.
Stir and dissolve the gelling agent in water heated to an appropriate temperature, mix high amylose corn starch and known additives commonly used in foods and pharmaceuticals as needed, fill into containers, and cool Good.

以下に、実施例、比較例及び試験例を挙げ、本発明を更に詳細に説明する。なお、実施例及び比較例の処方において、数値は全て質量部である。   Hereinafter, the present invention will be described in more detail with reference to Examples, Comparative Examples and Test Examples. In addition, in the prescription of an Example and a comparative example, all numerical values are a mass part.

実施例1〜3
表1(表中の単位は質量部)のとおり秤量したグラニュー糖及びスクラロース、κカラギーナン、ιカラギーナン、グルコマンナン、安息香酸Naを粉末混合し、水に添加した。溶液を加温、攪拌し、添加成分を溶解した。さらに、表1記載のその他の成分を添加し、攪拌した後、容器に充填し、冷蔵庫にて一晩冷却し、ゼリーを得た。
Examples 1-3
Granulated sugar and sucralose, kappa carrageenan, ι carrageenan, ι carrageenan, glucomannan, and sodium benzoate weighed as shown in Table 1 (unit is part by mass) were mixed with powder and added to water. The solution was heated and stirred to dissolve the added components. Furthermore, after adding the other component of Table 1, it stirred, Then, it filled with the container and cooled overnight in the refrigerator, and the jelly was obtained.

実施例4
表1のとおり秤量した水にアセスルファムカリウム、スクラロース、クエン酸、安息香酸Naを加え溶解し、溶液とした。別に、κカラギーナン及びιカラギーナン、グルコマンナンを混合し、この混合物を上記の溶液に加え、加温、攪拌して溶解した。さらに表1記載のその他の成分を添加し、攪拌した後、容器に充填し、冷蔵庫にて一晩冷却し、ゼリーを得た。
Example 4
Acesulfame potassium, sucralose, citric acid, and sodium benzoate were added to water weighed as shown in Table 1 and dissolved to obtain a solution. Separately, kappa carrageenan, iota carrageenan, and glucomannan were mixed, and this mixture was added to the above solution and dissolved by heating and stirring. Furthermore, after adding the other component of Table 1, it stirred, Then, it filled with the container and cooled overnight in the refrigerator, and the jelly was obtained.

比較例1
表1に示した比較例1の処方のゼリーを実施例1〜3と同様の方法で調製した。
Comparative Example 1
A jelly having the formulation of Comparative Example 1 shown in Table 1 was prepared in the same manner as in Examples 1 to 3.

比較例2
表1に示した比較例2の処方のゼリーを実施例4と同様の方法で調製した。
Comparative Example 2
A jelly having the formulation of Comparative Example 2 shown in Table 1 was prepared in the same manner as in Example 4.

Figure 2016036335
Figure 2016036335

試験例1:食感の評価
実施例1〜3及び比較例1で調製したゲル組成物をパネル4名にて、評価した。結果、ハイアミロースコーンスターチの入っている実施例1〜3のゲル組成物は、比較例1のハイアミロースコーンスターチの入っていないゲル組成物に比べ、すりおろし感を感じた。
Test Example 1: Evaluation of texture The gel compositions prepared in Examples 1 to 3 and Comparative Example 1 were evaluated by 4 panels. As a result, the gel compositions of Examples 1 to 3 containing high amylose corn starch felt a grated feeling compared to the gel composition of Comparative Example 1 containing no high amylose corn starch.

試験例2:ゲル化剤含有組成物の離水率の評価
(1)方法
実施例4及び比較例2で調製したゲル化剤含有組成物を40℃75%RH条件下で3日間保存した。そのゲル化剤含有組成物を30メッシュの篩の上に3分間静置し、3分後、篩の上に残った組成物の質量を測定し、式1から離水率を計算した。結果を表3に示す。
Test Example 2: Evaluation of water separation rate of gelling agent-containing composition (1) Method The gelling agent-containing composition prepared in Example 4 and Comparative Example 2 was stored at 40 ° C. and 75% RH for 3 days. The gelling agent-containing composition was allowed to stand on a 30-mesh sieve for 3 minutes, and after 3 minutes, the mass of the composition remaining on the sieve was measured. The results are shown in Table 3.

Figure 2016036335
Figure 2016036335

Figure 2016036335
Figure 2016036335

(2)結果
表3より、比較例2の組成物では離水率が高く、ゲル組成物が固くなり、品質が低下していた。 一方、実施例4は、比較例に比べ離水率が低下し、ゲル組成物本来の食感を損なうことなく、良好な品質を保つことが示された。
(2) Results From Table 3, the composition of Comparative Example 2 had a high water separation rate, the gel composition became hard, and the quality was lowered. On the other hand, Example 4 showed that the water separation rate decreased compared with the comparative example, and good quality was maintained without impairing the original texture of the gel composition.

本発明により、特有の果肉感を付与し、また、経時的な離水を抑制したゲル組成物を提供することが可能となった。   According to the present invention, it is possible to provide a gel composition that imparts a unique flesh feel and suppresses water separation over time.

Claims (5)

ハイアミロースコーンスターチを含有することを特徴とするゲル組成物。 A gel composition comprising high amylose corn starch. ゲル組成物が、食品又は経口医薬品である請求項1に記載の組成物。 The composition according to claim 1, wherein the gel composition is a food or an oral medicine. 食品が、ゼリー、グミ、アイスクリーム、プリン、ムース、ババロア、ヨーグルト、水ようかん、杏仁豆腐又はジャムである請求項2に記載の組成物。 The composition according to claim 2, wherein the food is jelly, gummy, ice cream, pudding, mousse, bavaroa, yogurt, mizuyokan, apricot tofu or jam. 経口医薬品がゼリー剤である請求項2に記載の組成物。 The composition according to claim 2, wherein the oral medicine is a jelly. カラギーナン、グルコマンナン、ゼラチン、寒天、ジェランガム、キサンタンガム、ローカストビーンガム、ペクチンからなる群から選ばれる少なくとも1種のゲル化剤を含有する請求項1〜4のいずれかに記載の組成物。 The composition according to any one of claims 1 to 4, comprising at least one gelling agent selected from the group consisting of carrageenan, glucomannan, gelatin, agar, gellan gum, xanthan gum, locust bean gum, and pectin.
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CN109329821A (en) * 2018-10-24 2019-02-15 江西农业大学 One kind i.e. punching or cooking dual-purpose type herbal tea flavor jelly powder and preparation method thereof
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