JP2016028816A - Massive treatment agent - Google Patents

Abstract

PROBLEM TO BE SOLVED: To provide a treatment agent for treating excreta and others.SOLUTION: The present invention relates to a massive treatment agent comprising hydrated lime or limestone, water-absorbing polymers, and binders.

Description

  The present invention relates to a treatment agent. More specifically, the present invention relates to a treatment agent used for treatment of manure and the like.

  In general, toilets can be roughly classified into a flush type that allows manure to flow into the sewer together with water, and a flush type that can be stored in a tank. In the case of a flush toilet, manure is flushed with the water into the sewer and processed at the sewage treatment plant. On the other hand, in the case of a draw-up type toilet, manure is drawn from the tank by a vacuum car or the like and is transported to a sewage treatment plant for processing.

  In a sewage treatment plant, sewage containing manure is stored in a septic tank, where organic matter in manure is decomposed and removed by the action of microorganisms such as activated sludge, and then the water is purified through several stages of treatment, Released into the river.

  However, in the event of a long-term blackout or water outage due to a disaster such as an earthquake, the toilet cannot be used, and a large amount of manure accumulates in each household. Malodors continue to emanate from the large amount of manure, and if left untreated, the odor will significantly deteriorate the living environment. Therefore, in general, a method of storing manure in a plastic bag and storing it in a sealed state is generally used. However, since the plastic bag is easily damaged, the manure is leaked due to damage during storage. There is a problem that the odor is emitted from the surroundings. In addition, the manure placed in the plastic bag rots with time and accumulates odor gas, and there is a problem that odor gas leaks from the plastic bag due to the pressure.

  In addition, simple toilets are used at construction sites, event venues, campsites, etc., but in conventional simple toilets, a large amount of feces and urine accumulates during installation, and odors are emitted around. There's a problem.

  Under such circumstances, Patent Document 1 discloses that an acrylic acid monomer aqueous solution having a neutralization rate of 50 mol% or more is subjected to a polymerization reaction, and after adding a hydrophilic polyvalent epoxy compound and a polymerization initiator, light is emitted. Irradiated to repolymerize to form a gel-like solid, and this gel-like solid is dried with hot air, pulverized and selected, and surface treated with a surface cross-linking agent. A polymer is disclosed.

JP 2008-095016 A

  However, when manure is processed using the superabsorbent polymer described in Patent Document 1, there is a problem that the object to be processed rots several days after the processing, and malodor and gas are generated. In addition, the present inventor has recognized that there are problems such as usage that have not been recognized in the past.

  Therefore, in this invention, it aims at suppressing generation | occurrence | production of the malodor and gas of a to-be-processed object, and also solving at least one of the subject on use.

  The above object is solved by providing the following invention.

  (1) A block treatment agent comprising slaked lime or limestone, a water-absorbing polymer, and a binder.

  (2) The block treatment agent according to (1), further comprising an acidic solid substance.

  (3) The block treatment agent according to (1) or (2), wherein the average diameter is 3 to 100 mm.

  (4) The block treatment agent according to any one of (1) to (3), further including at least one additive selected from the group consisting of zeolite, activated carbon, sodium bicarbonate, and a lubricant.

  (5) The block treatment agent according to any one of (1) to (4), which is used for treatment of manure.

  (6) A granular treatment agent obtained by pulverizing the massive treatment agent according to any one of (1) to (5).

  (7) The granular processing agent as described in (6) whose average particle diameter is more than 150 micrometers-less than 3 mm.

  (8) A toilet bowl in which the block treatment agent according to any one of (1) to (5) or the granule treatment agent according to (6) or (7) is arranged in advance.

  (9) In the absence of water, the bulk treatment agent according to any one of (1) to (5) or the granular treatment agent according to (6) or (6) is arranged in advance. A toilet according to (7).

  (10) An absorptive article for manure, which is formed by including the bulk treatment agent according to any one of (1) to (5) or the granular treatment agent according to (6) or (7).

  The present invention has the following effects by the above-described invention.

  (1) The 1st of this invention is a block treatment agent containing slaked lime or limestone, a water absorbing polymer, and a binder. With this configuration, it is possible to easily and efficiently treat a large amount of manure without requiring an operation such as stirring. Moreover, even after processing, the processing object hardly rots, and the generation of malodor and gas can be suppressed. That is, it can also be used for disinfectants, deodorants, bactericides, or sterilizers, leading to prevention of infectious diseases. Moreover, since the processing agent of this invention is solidified, since dust does not dance at the time of use, a handleability improves. In particular, when used in a disaster, fine dust is not generated, it is very excellent in terms of handling properties, and health damage is significantly suppressed. Specifically, a treatment agent with poor handleability tends to adhere to the skin or the like. In that case, there is a high possibility of causing dermatitis or the like while the immunity is reduced due to prolonged life in an evacuation center or the like. However, since the treatment agent of the present invention is solidified, it is possible to significantly suppress the movement of slaked lime or limestone dust, so that it is easy to suppress such a situation. Moreover, even if it considers the use in the sealed vehicle (for example, at the time of traffic congestion), it can be said that the solidified processing agent which suppresses dust is very suitable.

  (2) Moreover, the 1st block treatment agent of this invention can neutralize the ammonia which may generate | occur | produce from a to-be-processed object (for example, stool, urine) by further containing an acidic solid substance. Therefore, malodor can be further suppressed.

(3) Moreover, when the average diameter of the 1st block treatment agent of this invention is 3-100 mm, while a handleability improves, a contact area with a to-be-processed object increases, and reaction with a to-be-processed object Efficiency can be improved.

  (4) Moreover, said effect improves further by the 1st block treatment agent of this invention further containing at least 1 sort (s) of additive selected from the group which consists of a zeolite, activated carbon, baking soda, and a lubrication agent. .

  (5) Moreover, since the 1st block treatment agent of this invention contains slaked lime or limestone, a water absorbing polymer, and a binder, it is especially suitable for the process of excrement.

  (6) The 2nd of this invention is a granular processing agent formed by grind | pulverizing the 1st block processing agent of this invention. With such a configuration, it is possible to easily and efficiently treat urine and the like without requiring an operation such as stirring, and it is possible to suppress the generation of malodor and gas. In addition, in the case of a granular treatment agent, it is not necessary to maintain a solid state for a long time as in the case of a bulk treatment agent, so that the ratio of active ingredients per unit weight can be increased from the viewpoint that the amount of binder can be reduced. .

  (7) Further, when the average particle size of the second granular processing agent of the present invention is more than 150 μm to less than 3 mm, the handling area is improved while the contact area with the object to be processed is increased. The reaction efficiency with the product can be improved.

  (8) A third aspect of the present invention is a toilet bowl in which the first bulk treatment agent of the present invention or the second granular treatment agent of the present invention is arranged in advance. With such a configuration, it is possible to easily and efficiently treat urine and the like without requiring an operation such as stirring, and it is possible to suppress the generation of malodor and gas. In addition, since the toilet bowl of the present invention is preliminarily provided with a treatment agent, after excretion, the user does not need to check his / her own (or care recipient, etc.) feces and urine, and the user can use it comfortably. Can do. On the other hand, after the treatment agent is excreted, it is necessary to sprinkle the treatment agent on manure (or a caregiver or the like), and the user (or caregiver or the like) may become uncomfortable. there were. However, according to the toilet of the present invention, since the treatment agent is arranged in advance, there is an effect that it is sufficient to discard the simple toilet as it is, without requiring confirmation after excretion.

  (9) Further, in the third toilet of the present invention, when the first bulk treatment agent of the present invention or the second granular treatment agent of the present invention is preliminarily disposed in the absence of water, (8 In addition to the effects described in), storage stability as a toilet is also improved.

  (10) A fourth aspect of the present invention is formed by including the block treatment agent according to any one of (1) to (5) or the granule treatment agent according to (6) or (7). It is an absorbent article for manure. With such a configuration, it is possible to easily and efficiently treat urine and the like without requiring an operation such as stirring, and it is possible to suppress the generation of malodor and gas. Further, the first lump treatment agent of the present invention or the second granular treatment agent of the present invention present in the absorbent article has a very excellent deodorizing property and a dry feeling is remarkable. This can greatly reduce the burden on the person who is doing this and for the caregivers.

<First of the present invention>
(1) Bulk treatment agent The first of the present invention is a block treatment agent containing slaked lime or limestone, a water-absorbing polymer, and a binder. As mentioned above, since the processing agent of this invention is solidified by including a binder, it is excellent in handleability. In addition, the component which comprises the 1st block treatment agent of this invention exists in the state mutually bound by the binder.

  The shape of the first lump treatment agent of the present invention (which may be simply referred to as “treatment agent” in the present specification) also includes slaked lime or limestone, a water-absorbing polymer, and a binder. There is no particular limitation as long as it is realized. For example, any shape such as a spherical shape, a cylindrical shape, a middle-high cylindrical shape, and a rectangular parallelepiped shape may be used. However, from the viewpoint of storage stability of the treating agent, a spherical shape, a cylindrical shape, a middle-high columnar shape, and the like are preferable, and from a viewpoint of manufacturing, a cylindrical shape and a middle-high columnar shape are preferable.

  The average diameter of the first block treatment agent of the present invention is preferably 3 to 100 mm. By being in such a range, the above-mentioned problems due to dust can be significantly solved, and the contact area with the object to be processed is increased while improving the handleability, and the reaction efficiency with the object to be processed. It is easy to improve the above-described effects. The average diameter of the 1st block treatment agent of this invention becomes like this. More preferably, it is 6-50 mm, More preferably, it is 7-20 mm. Here, the average diameter of the first bulk treatment agent of the present invention is an average obtained by arbitrarily selecting 50 grain treatment agents, measuring the longest particle diameter for each grain, and arithmetically averaging them. Mean value. Moreover, it is preferable that the average thickness of the 1st block treatment agent of this invention is 1-30 mm. Moreover, the average thickness of the 1st block treatment agent of this invention becomes like this. More preferably, it is 2-15 mm, More preferably, it is 4-10 mm. By being in this range, the above-described effects can be easily achieved. When the average diameter is 7 to 20 mm and the average thickness is 4 to 10 mm, the rate of disintegration increases when contacting with the object to be processed, and also from the viewpoint of manufacturing such a treatment agent. It is easy and particularly preferred. In addition, if the 1st block treatment agent of this invention is a column shape, a middle-high column shape, and a rectangular parallelepiped form, a long axis will become an average diameter. On the other hand, the minor axis is the average thickness. Moreover, although there is no restriction | limiting in particular also in the weight of the 1st block treatment agent of this invention, when the portability and handling property are considered, the weight per grain becomes like this. Preferably it is about 0.05-30g, More preferably Is about 0.2 to 10 g, more preferably about 0.3 to 2 g. Of course, it may be outside this range.

  Hereinafter, the configuration requirements will be described in detail.

[Slaked lime]
Since slaked lime (Ca (OH) ₂ ) that can be contained in the first bulk treatment agent of the present invention is a strong alkali, it has a large bactericidal effect during the excrement treatment (especially stool). In addition, animals and livestock infected by foot-and-mouth disease and bird flu, or dead bodies thereof, food (plants, etc.) that the animals and livestock were eating, livestock houses where the animals or livestock existed or existed, Alternatively, it is effective for sterilizing, sterilizing, disinfecting, and deodorizing soil and roads in the vicinity of the livestock house. This stops fermentation and decomposition of organic matter. Then, it is sterilized, sterilized and disinfected. And the effect which reduces an odor can be acquired. Moreover, since slaked lime mainly adsorb | sucks a sulfide, it can be said that the odor reduction effect by using slaked lime is large also from this point.

  The shape of the slaked lime is not particularly limited, and examples thereof include powdery granules and pellets, but are preferably granular from the viewpoint of effectively dispersing slaked lime with respect to stool. Further, the lower limit of the average particle diameter is not particularly limited, but is not particularly limited, for example, 10 μm or more, more preferably 50 μm or more, and the upper limit is, for example, 1000 μm or less, preferably 500 μm or less, more preferably 300 μm. Hereinafter, it is more preferably 150 μm or less. That is, 10 to 1000 μm is preferable, 50 to 300 μm is preferable, and 100 to 150 μm is preferable.

Within such a range, the production is facilitated and the production cost is reduced, the contact area between the resulting treatment agent and the object to be treated is increased, the reaction efficiency is improved, no lumps are produced during the treatment, and unreacted substances are produced. No longer remains. If necessary, the slaked lime may be used in combination of two or more slaked limes having different average particle sizes. In the present invention, the average particle diameter means an average value obtained by arbitrarily selecting 100 grains, measuring the longest grain diameter for each grain, and arithmetically averaging them. Hereinafter, the “average particle diameter” described in the present specification has the same definition. In order to obtain a desired average particle size, it may be appropriately sieved.

  The slaked lime used in the present invention may be surface-treated with a hydrophobic coating agent. Moreover, the slaked lime used by this invention may synthesize | combine and may use a commercial item.

  When slaked lime is contained in the block treatment agent of the present invention, the content of the slaked lime is about 5 to 90% by mass and 10 to 80% by mass with respect to the total mass (100% by mass; hereinafter the same) of the block treatment agent. %, Or 15 to 70 mass. If it is this range, the effect of odor reduction and the suppression of gas generation | occurrence | production will be acquired more favorably in the case of a to-be-processed object (for example, excrement).

[Limestone]
Limestone (calcium carbonate) that can be contained in the first bulk treatment agent of the present invention is a calcium carbonate represented by the composition formula CaCO ₃ . Since limestone is alkaline, it has the same effect as slaked lime.

  The shape of the limestone is not particularly limited, and examples thereof include powdery granules and pellets. From the viewpoint of effectively dispersing the stool, the limestone is preferably granular. Further, the lower limit of the average particle diameter is not particularly limited, but is not particularly limited, for example, 10 μm or more, more preferably 50 μm or more, and the upper limit is, for example, 1000 μm or less, preferably 500 μm or less, more preferably 300 μm. Hereinafter, it is more preferably 150 μm or less. That is, 10 to 1000 μm is preferable, 50 to 300 μm is preferable, and 100 to 150 μm is preferable. Within such a range, the production can be facilitated and the production cost can be reduced, the contact area between the resulting treatment agent and the object to be treated is increased, and the reaction efficiency may be improved. It does not occur and no unreacted material remains. As needed, the said limestone may be used in combination of 2 or more types of limestone from which average particle diameter differs.

  When the block treatment agent of the present invention contains limestone, the content of the limestone is about 5 to 90% by mass, about 10 to 80% by mass, or 15 to 70% with respect to the total mass of the block treatment agent. It is about mass%. If it is this range, the effect of the odor reduction at the time of processing of a to-be-processed object (for example, manure) and the suppression of gas generation will be acquired more favorably.

  As a method for preparing limestone, a method of purchasing a commercially available product is preferable, and for example, Tankar of Ube Materials, Industrial Tankar of Yoshizawa Lime Industry Co., Ltd. and the like are preferable.

[Water-absorbing polymer (also referred to as water-absorbing agent or polymer water-absorbing agent)]
The water-absorbing polymer (water-absorbing agent) contained in the first block treatment agent of the present invention serves to assist slaked lime or limestone. That is, for example, when only slaked lime or limestone is used as the treatment agent, it may not be able to absorb the moisture of the object to be treated (for example, in manure) and may become a muddy state. When slaked lime gets wet, the slaked lime itself may give off a unique malodor. Further, if the manure remains in a muddy state, the manure may come into contact with the air, and the fermentation and decomposition of the manure may proceed.

Since the 1st block treatment agent of this invention contains a water absorbing polymer (polymer water absorbing agent), it can absorb the water | moisture content in a to-be-processed object, and can solidify. When slaked lime or limestone and water-absorbing polymer are added to the object to be treated, the object to be treated solidifies, and the solidified object is covered with slaked lime or limestone to stop the fermentation and decomposition activities of microorganisms. As a result, the above-described effects can be obtained. Moreover, the addition amount of slaked lime or limestone can be reduced, and the malodor which slaked lime or limestone itself emits can be reduced more. Furthermore, since the water-absorbing polymer swells when it comes into contact with moisture, it serves as a base point for the collapse of the solidified treatment agent.

  The water-absorbing polymer used in the present invention is not particularly limited as long as it does not adversely affect the effects of the present invention, and known substances can be used. Specific examples thereof include, for example, starch-based acrylonitrile graft polymer hydrolyzate, starch-based water-absorbing polymers such as starch-acrylic acid graft polymer, cellulose-acrylonitrile graft polymer, cellulose-styrene sulfonic acid graft copolymer. Cellulose-based water-absorbing polymers such as polymers, polysaccharide-based water-absorbing polymers, protein-based water-absorbing polymers such as collagen, polyvinyl alcohol-based water-absorbing polymers such as polyvinyl alcohol-crosslinked polymers, crosslinked sodium polyacrylate, heavy acrylic acid Acrylic water-absorbing polymer such as a sodium partial polymer salt cross-linked product, sodium acrylate-vinyl alcohol copolymer, maleic anhydride water-absorbing polymer, vinyl pyrrolidone water-absorbing polymer, polyethylene glycol diac Polyether type water-absorbing polymer, such as rate crosslinked polymer and the like, and the like. These water-absorbing polymers may be used alone or in combination of two or more. These water-absorbing polymers may be synthesized or commercially available. Examples of commercially available products include, for example, Aquakeep (registered trademark) SA (manufactured by Sumitomo Seika Co., Ltd.), Aquaric (registered trademark) CA (manufactured by Nippon Shokubai Co., Ltd.), Sunfresh, Aquapearl (Sundia Polymer Co., Ltd.) Product), Hymosub HS-960 (manufactured by Hymo Co., Ltd.) and the like. Among these water-absorbing polymers, Hymosub HS-960 (manufactured by Hymo Co., Ltd.) is more preferable.

  The average particle diameter of the water-absorbing polymer contained in the first bulk treatment agent of the present invention is not particularly limited, but is preferably 50 to 1000 μm, more preferably 80 to 850 μm, and further preferably 100 to 600 μm. It is.

  Among Aqua Keep (registered trademark) SA (manufactured by Sumitomo Seika Co., Ltd.), SA-50II or SA60-S is preferable, and SA60-S is preferable from the viewpoint of water absorption. Further, SA-50II is preferable from the viewpoint of cost. The shape of the water-absorbing polymer is not particularly limited, and examples thereof include a granular shape, a powder shape, a granular shape, and a pellet shape.

  The content of the water-absorbing polymer can be appropriately adjusted depending on the type and shape of the water-absorbing polymer and the amount of water contained in the object to be treated, but is about 1 to 90% by mass with respect to the total mass of the bulk treatment agent. It is preferably about 5 to 50% by mass or about 10 to 48% by mass. If it is this range, the effect of a water-absorbing polymer can be acquired significantly, an unreacted water-absorbing polymer does not remain, and it is advantageous in cost.

[Binder (binder)]
The binder contained in the first block treatment agent of the present invention may be an organic binder described below or an inorganic binder such as baking soda. However, in view of the binding property, preferably, the binder contained in the first block treatment agent of the present invention is at least one selected from the group consisting of a cellulose binder, a polymer binder, and a starch binder. An organic binder is preferable, and in particular, the binder is preferably a cellulose binder.

  The 1st block treatment agent of this invention has the characteristics in components, such as slaked lime or limestone, being solidified. The first block treatment agent of the present invention contains a water-absorbing polymer (water-absorbing agent) in addition to slaked lime or limestone. The water-absorbing polymer (water-absorbing agent) is cushion-like when solidified (at the time of compression). May be difficult to compress and compress.

  However, since the 1st block treatment agent of this invention contains binder (binder), solidification, tablet formation, and granulation become easy. And the 1st block treatment agent of this invention has sufficient intensity | strength by the form that a binder (binder) is contained. In this respect, it is preferable from the viewpoints of transportability and handleability.

  The binder contained in the first block treatment agent of the present invention may be synthesized by a conventionally known method or may be prepared by purchasing a commercial product. As commercially available products, Asahi Kasei Chemicals Co., Ltd. Cerrosa K2, PH-102, TG-101, ST-02, TG-101, Higuchi Trading Company PVPK-15, PVPK-30, PVPK-90 (polyvinylpyrrolidone), KC flocs manufactured by Nippon Paper Chemical Co., Ltd. (W-50S, W-50, W-100 / 100G, W-200 / 200G, W-250, W-300G, W-400G) are preferably used. Among these, Cellosa K2 manufactured by Asahi Kasei Chemicals and KC floc manufactured by Nippon Paper Chemicals, a cellulose-based chemical, are preferable from the viewpoint of bonding strength and disintegration because they are fibrous. In addition, the present inventor has found that KC Flock manufactured by Nippon Paper Chemicals Co., Ltd. and Cerossa K2 manufactured by Asahi Kasei Chemicals Co., Ltd. are very excellent in terms of binding properties. In particular, Cerrosa K2 manufactured by Asahi Kasei Chemicals Co., Ltd. has a granular shape and fine particles, and thus has a high binding force and is extremely excellent in terms of smooth feed from the hopper of the tableting machine. Is heading.

  The average particle diameter of the binder contained in the first bulk treatment agent of the present invention is not particularly limited, but is preferably 1 μm to 100 μm, more preferably 5 μm to 70 μm, and further preferably 20 μm to 60 μm. .

  The content of the binder is about 1 to 80% by mass, about 5 to 70% by mass, about 8 to 65% by mass, or 20 to 60% by mass with respect to the total mass of the first block treatment agent of the present invention. Is about. Within such a range, the powdered slaked lime or limestone and the water-absorbing polymer are made into a lump, which is preferable from the viewpoint of the effect of preventing dust scattering during use. For example, when a cellulosic binder is used as the binder, if the amount of the binder increases, the following effects are obtained. In other words, the binder itself also has water absorption, exhibits a function of assisting the water-absorbing agent serving as a base point of disintegration, and increases the disintegration speed when it comes into contact with the workpiece. In addition, when the amount of the binder is reduced, the cost can be kept low, and as the capacity is reduced, the area in contact with the object to be processed is increased and the reactivity is improved.

[Acid solid material]
The especially preferable form of the 1st block treatment agent of this invention contains an acidic solid substance. When the 1st block treatment agent of this invention contains an acidic solid substance, the ammonia which can be generated from a to-be-processed object (for example, stool, urine) can be neutralized. Therefore, malodor can be further suppressed. As described above, when an acidic solid substance is added, it exists in a state of being bound to each other.

  The acidic solid material that can be used in the present invention is not particularly limited, but is at a temperature of −10 to 60 ° C., preferably 0 to 50 ° C., and a pressure of 0.5 to 1.2 atm, preferably 1 atm. It is preferably an acidic substance that can exist in a solid form. As the acidic solid substance, any conventionally known substance such as an inorganic acid or a salt thereof, an organic acid or a salt thereof can be used. When a liquid acid is employed as the acidic substance, it can be used by impregnating it with talc, cellulose or the like, but a solid acid (solid substance) is preferably used.

The pH of the acidic solid substance is not particularly limited as long as it exhibits acidity, but is preferably 1.5 to less than 7 from the viewpoint of preventing corrosiveness when a human touches the skin. Is more preferable, and 3.5 to 5.5 is more preferable.

  The pH described in the present specification means a value measured using a PH recorder SD card recording system model number PH-SD manufactured by Sato Corporation. If it has pH in such a range, it can neutralize with the basic component (for example, ammonia) etc. which are contained in a to-be-processed object (for example, excrement), and can suppress bad odor efficiently.

  More specifically, the acidic solid substance that can be used in the present invention is acetic acid, citric acid (food additive pH: 2.36), isocitric acid, malic acid (food additive pH: 2.45), tartaric acid. (Food additive pH: 2.28), lactic acid, gluconic acid, succinic acid, glycolic acid, oxalic acid, maleic acid, maleic anhydride, itaconic acid, benzoic acid, hydroxybenzoic acid, nitrilotriacetic acid, carbonic acid, salicylic acid, It consists of fumaric acid, adipic acid, phthalic acid, terephthalic acid, inosinic acid, guanylic acid, glutamic acid, erythorbic acid, sorbic acid, polyglutamic acid, benzenesulfonic acid, toluenesulfonic acid, phytic acid, phosphoric acid, phosphonic acid and boric acid It may be an unneutralized acidic component (first component) (an acidic component not in the form of a salt) selected from the group.

  Also, sodium citrate, sodium benzoate, monosodium fumarate, 5'-sodium inosinate, 5'-sodium guanylate, 5'-disodium guanylate, sodium glutamate, sodium erythorbate, potassium sorbate, phosphoric acid Sodium dihydrogen (food additive (pH: 4.3 to 4.9), industrial (pH: 4.1 to 4.9) (1% solution), sodium hydrogen sulfate, potassium hydrogen sulfate, ammonium hydrogen sulfate, Potassium dihydrogen phosphate (food additive (pH: 4.4 to 4.9), industrial (pH: 4.4 to 4.9) (1% solution), disodium dihydrogen pyrophosphate (food additive) (PH: 3.8 to 4.5), industrial (pH: 3.8 to 4.5) (1% solution)), acidic aluminum tripolyphosphate for industrial use (pH: 2.4 to 2.8) ( 1% dissolved )), Sodium acid hexametaphosphate (acid sodium pyrophosphate (food additive (pH: 3.8 to 4.5) (1% solution)), sodium ultraphosphate (food additive (pH: 1.7 to 1)) .9), industrial (pH: 1.7-1.9) (1% solution), monosodium fumarate (food additive (pH: 3.0-4.0) (1% solution)), sulfuric acid Band industrial use (pH: 3.0 or more) (1% solution)), sulfamic acid, alum industrial use (pH: about 3.5) (12 water salt) and grass charcoal (peat) containing humic acid (humic acid) It may be a neutralized acidic component (salt that exhibits acidity when dissolved in water) (second component) selected from the group consisting of (pH: 3.0 to 6.8).

  Among them, sodium dihydrogen phosphate (pH: 4.3 to 4.9), potassium dihydrogen phosphate (pH: 4.4 to 4.9), disodium dihydrogen pyrophosphate (pH: 3.8 to 4) .5), aluminum aluminum tripolyphosphate (pH: 2.4 to 2.8), monosodium fumarate (pH: 3.0 to 4.0), sodium ultraphosphate (pH: 1.7 to 1.9) ), Acidic sodium hexametaphosphate (pH: 3.8 to 4.5) or grass charcoal (peat) containing humic acid (humic acid) (pH: 3.0 to 6.8), etc. This is particularly preferable from the viewpoint of not reducing the amount.

  In particular, the inclusion of an acidic solid component such as sodium dihydrogen phosphate has the following effects. That is, when the ratio of slaked lime increases in the treatment agent, the alkali concentration increases, and there may be an environment where ammonia is likely to be generated. In such a case, a bad odor derived from ammonia may occur. Therefore, it is particularly preferable to include an acidic solid component such as sodium dihydrogen phosphate for neutralizing ammonia and maintaining the sterilizing ability of slaked lime. Further, the second component such as sodium dihydrogen phosphate is also preferable from the viewpoint that the water absorption capacity of the water absorbing polymer is not deteriorated so much.

  In addition, when the acidic solid material is composed only of the first component, for example, when polyacrylate is used as the water-absorbing polymer, the “salt portion” of the polyacrylate is consumed, which is preferable from the viewpoint of water absorption characteristics. There may not be. However, it is preferable in that the effect of neutralizing ammonia in the object to be treated (for example, urine) is high. On the other hand, when an acidic solid substance consists only of a 2nd component, it is preferable from a viewpoint of a water absorption characteristic. Of course, the effect of neutralizing ammonia in the object to be treated (for example, urine) is also significantly high.

  The specific acidic solid substances listed above may be synthesized by referring to or combining conventionally known methods as appropriate, or may be prepared by purchasing commercially available products. Commercially available products include Daimei Chemical's sulfate band, alum, Iwata Chemical's citric acid, malic acid, tartaric acid, lactic acid, itaconic acid, spicrispolic acid, and Tsuchino Food Industry's phytin. Acid, succinic acid, fumaric acid, maleic anhydride of Nippon Shokubai Co., Ltd., acetic anhydride of Nippon Synthetic Chemical Industry Co., Ltd., gluconic acid of Fuso Chemical Industry Co., Ltd., sulfamic acid, citric acid, malic acid, tartaric acid, Lactic acid, succinic acid, fumaric acid, phytic acid, itaconic acid, monosodium fumarate, benzoic acid from Fushimi Pharmaceutical Co., Ltd., sodium benzoate, oxalic acid from Takasugi Pharmaceutical Co., Ltd., nitric acid, salicylic acid from Maruishi Pharmaceutical, Kirin Kyowa Foods 'inosinic acid, glutamic acid, glutamic acid, Daicel Chemical Industries' sorbic acid, Nippon Chemical Industry's phosphonic acid, Asahi Kasei Chemicals ( ) Adipic acid, Mitsubishi Chemical Corporation terephthalic acid, Nagase ChemteX Corporation nitrilotriacetic acid, Ueno Pharmaceutical's hydroxybenzoic acid, Mitejima Chemical Industries sodium dihydrogen phosphate, potassium dihydrogen phosphate, Disodium dihydrogen pyrophosphate, aluminum acid tripolyphosphate, sodium acid hexametaphosphate, sodium ultraphosphate, Humin Ace by Meikyo Shoji Co., Ltd., Mohumin (registered trademark) by Artrei Co., Ltd., natural humus by Nasu Ryokuchi Co., Ltd. Examples thereof include acid humic acid, Kaoran (registered trademark) (pH = 3.0), Amine (registered trademark) (pH = 6.8), and Amin 1 manufactured by Denki Kagaku Co., Ltd. (Denka Amin Co., Ltd.). Of course, you may purchase a commercial item other than these.

  The amount of the acidic solid substance (if it is a plurality of types, the total mass of the plurality of types) is preferably 10 to 95% by mass, more preferably 13 to 50% by mass with respect to the entire bulk treatment agent (100% by mass). More preferably, it is 14-30 mass%. If it is such a range, the efficiency which acts on components, such as ammonia which can be generated from a to-be-processed object, will go up, and the deodorizing function as a processing agent will improve significantly.

  In addition, the block treatment agent of this invention contains slaked lime or limestone, a water absorbing polymer, and a binder as essential components. The preferred content of these components is as described above. However, when an acidic solid substance is further included, the content of these components is reduced accordingly, so the preferred content of these components is as follows. It is preferable. However, it should be understood that the preferred ranges described below can be the preferred ranges of these “slaked lime or limestone, water-absorbing polymer, and binder” even if they do not contain acidic solid materials. .

Slaked lime or limestone is preferably 5 to 50% by mass, more preferably 10 to 40% by mass, and still more preferably about 15 to 30% by mass with respect to the total mass of the bulk treatment agent. In such a range, the effect of stopping the fermentation and decomposition activities of microorganisms is particularly remarkable. The water-absorbing polymer is preferably 5 to 50% by mass, more preferably 10 to 40% by mass, and further preferably about 20 to 35% by mass with respect to the total mass of the bulk treatment agent. Within such a range, the effect of absorbing water from manure and solidifying in a jelly form, preventing leakage from a plastic bag, which is a simple toilet, and preventing the diffusion of filth is particularly remarkable. Further, the binder is preferably 5 to 50% by mass, more preferably 8 to 45% by mass, and further preferably about 10 to 40% by mass with respect to the total mass of the bulk treatment agent. Within such a range, the powdery slaked lime and the water-absorbing polymer are agglomerated, and the effect of preventing dust scattering during use is particularly remarkable.

  Although there is no restriction | limiting in particular also in the magnitude | size of an acidic solid substance, it is easy to make it into a lump when it is a powder form that an average particle diameter is about 100 nm-about 3 mm, More preferably, it is about 0.01-1 mm. From the viewpoint of supporting the water-absorbing polymer. Of course, it may be out of these ranges depending on the type or in consideration of manufacturing convenience.

  In addition, from the viewpoint of remarkably exhibiting the deodorizing effect, the pH of the object to be treated treated with the first bulk treatment agent of the present invention is preferably controlled to about 5 to 8, more preferably about 6 to 7. It is preferable. By controlling in this way, it becomes easy to control the malodor derived from a basic component (especially ammonia) especially. Examples of the control method include a method of adding an acidic solid substance exhibiting acidity to the first block treatment agent of the present invention.

[Additive]
The other preferable form of the 1st block treatment agent of this invention contains an additive. The additive for the first bulk treating agent of the present invention is preferably at least one selected from the group consisting of zeolite, activated carbon, baking soda and lubricant.

  The amount of the additive is not particularly limited as long as it exhibits the initial effects of the present invention, but is about 0.8 to 30% by mass with respect to the total mass of the first bulk treatment agent of the present invention, 0 About 7 to 20% by mass, or about 0.5 to 18% by mass.

  Hereinafter, the constituent requirements of the additive will be described in detail.

[Zeolite]
The 1st block treatment agent of this invention is good to further contain the additive which is a zeolite. “Zeolite” is a general term for minerals called zeolites, and about 40 kinds of natural zeolites have been discovered. When zeolite is contained, the ammonia component contained in the to-be-processed object (for example, manure) is adsorbed and effective in deodorization and deodorization. By including the zeolite, the pores of the zeolite can take in malodor and suppress the malodor.

  The zeolite of the present invention may be natural or artificial, but is preferably artificial from the viewpoint of availability. Moreover, the zeolite of the present invention is preferably a zeolite called mordenite in which a very small cavity of about 5.5 to 8 mm, which is slightly larger than water and nitrogen molecules, is formed in a tunnel shape.

  When purchasing a commercially available product, Zeolite 2460, Zeolite 60, Zeolite CP, etc., manufactured by New Tohoku Chemical Industry Co., Ltd. are preferable. Among these, zeolite 60 is preferable from the viewpoint of easy feeding to a tableting machine.

  Although there is no restriction | limiting in particular also in the average particle diameter of the zeolite of this invention, About 0.05-1.5 mm is preferable, More preferably, it is about 0.1-1.2 mm.

The zeolite used in the present invention includes SiO ₂ (silicon oxide), Al ₂ O ₃ (aluminum oxide), CaO (calcium oxide), Na ₂ O (sodium oxide), K ₂ O (potassium oxide), Fe ₂ O. ₃ (iron oxide), MgO (magnesium oxide), adhering water (H ₂ O), bound water (H ₂ O), and others are 70.5% by mass, 11.3% by mass, 2.6% by mass, respectively. , 1.6% by mass, 1.3% by mass, 0.7% by mass, 0.1% by mass, 8.0% by mass, 3.9% by mass, of course, but limited to this composition However, it is possible to use those prepared so that each component is about 0.1 to 20% and the total is 100%. In the present invention, for example, zeolite such as K [AlSi ₂ O ₆ ] may be used.

  The amount used in the case of using zeolite can be adjusted as appropriate depending on the type and shape of the zeolite and the components contained in the material to be treated (for example, excrement). More preferably, it is in the range of about 1-50 mass%, 1-30 mass%, or about 2-20 mass%. Within such a range, the effect of suppressing bad odor becomes higher, which is economical in terms of cost.

[Activated carbon]
Activated carbon is preferably added from the viewpoint of suppressing malodor that the slaked lime may emit. Activated carbon also has a function of suppressing bad odor generated during excrement treatment.

  The activated carbon used in the present invention is not particularly limited. Specific examples of the activated carbon include, for example, activated carbon obtained by a known method using, as raw materials, synthetic resin such as charcoal, coke, coconut husk, natural fiber, polyacrylonitrile, rayon, phenol resin, and the like. . These may be used alone or in combination of two or more. Moreover, the activated carbon may be synthesized or a commercially available product may be used. As an example of a commercial item, activated carbon GY alkali use, activated carbon GX acidic use (above, Toyobo Co., Ltd. product), or these mixtures are mentioned, for example.

  Furthermore, it is good also as a slaked lime component and activated carbon component of the processing agent of this invention using the commercial item in which slaked lime and activated carbon are mixed previously, for example, Solvalit (made by Ube Materials Co., Ltd.). Among these activated carbons, sol barit is more preferable from the viewpoint of adsorption of malodorous substances.

  The shape of the activated carbon is not particularly limited, and examples thereof include granule, powder, granule, pellet, macaroni, fiber, and honeycomb.

  The amount of activated carbon used can be adjusted as appropriate depending on the type and shape of the activated carbon and the components contained in the object to be treated (for example, excrement), but is 0. 0% relative to the total mass of the treatment agent. It is about 1-20 mass%, about 0.4-15 mass%, or about 0.3-10 mass%. Within such a range, the effect of suppressing bad odor becomes higher, which is economical in terms of cost.

[Baking soda (sodium bicarbonate)]
Baking soda (sodium bicarbonate) is a component that assists the alkaline components of slaked lime and limestone.

  The average particle size of sodium bicarbonate (sodium bicarbonate) is not particularly limited.

  The amount of sodium bicarbonate used can be adjusted as appropriate depending on the type and shape of sodium bicarbonate and the components contained in the object to be treated (for example, excrement) so as to exert the effect of suppressing malodor.

[lubricant]
The lubricant that can be contained in the first bulk treatment agent of the present invention is used for smooth feeding to the die of the tableting machine, particularly when producing the first bulk treatment agent of the present invention. Is. As a kind of lubricant, a conventionally well-known thing can be selected suitably, or can be used in combination. For example, ester type such as sucrose fatty acid ester, silicon type such as silicon dioxide, calcium stearate, potassium stearate etc. are used, ester type,
Silicon-based calcium stearate is preferred. The content of the lubricant is preferably about 0.5 to 20% by mass or about 0.8 to 17% by mass with respect to the total amount of the first block treatment agent of the present invention. Within such a range, the feed and disintegration of the raw material are enhanced.

[Other additives]
The treatment agent of the present invention may further contain other additives as long as they do not adversely affect the present invention. Examples of such additives include a fragrance, a deodorant, or a deodorant from the viewpoint of odor countermeasures; a hydrophilic organic compound such as alcohol, or a surfactant; from the viewpoint of controlling the water content in manure, Desiccant such as silica gel and anhydrous sodium sulfate; from the viewpoint of sterilization and deodorization; chlorine-containing compounds such as sodium hypochlorite; from the viewpoint of complementing the alkaline conditions during the excrement treatment, from the group 1 elements such as sodium hydroxide A hydroxide etc. are mentioned. These additives may be used alone or in combination of two or more.

  Examples of the fragrances include lemon oil, lemon grass, cinnamon oil, lavender oil, and vetiver.

  Various surfactants can be used as the surfactant, and specific examples thereof include, for example, polyoxyethylene alkyl ether, polyoxyethylene alkyl phenyl ether, polyoxyethylene monofatty acid ester, polyoxyethylene alkyl ester, Nonionic surfactants such as oxyethylene difatty acid ester, polyoxyethylene propylene glycol fatty acid ester, polyethylene sorbitan monofatty acid ester, glycerin monofatty acid ester; alkylbenzene sulfonate, alkyl sulfosuccinate, alkyl sulfate, polyoxyethylene alkyl sulfate Anionic surfactants such as aryl sulfonates; long-chain primary amine salts, dialkyldimethylammonium salts, alkyltrimethylammonium salts, benzylates Ammonium chloride, alkylpyridinium salts, benzalkonium chloride, cationic surfactants such as benzethonium chloride; or alkyldiaminoethylglycine hydrochloride, and amphoteric surfactants such as hydrochloric alkylpolyaminoethylglycine is. Further, a wrapping bag made of a water-soluble resin, a wrapping bag made of water-soluble paper, or a wrapping bag made of a water-degradable nonwoven fabric, which can be used when adding the treatment agent to manure, is also an additive for the treatment agent of the present invention. It can be contained as

  Even if such other additives are included, they are about 0.1 to 10% by mass, or about 1 to 3% by mass with respect to the total amount of the first block treatment agent of the present invention.

[Production Method of First Bulk Treatment Agent of the Present Invention]
The 1st block treatment agent of this invention can be produced by mixing said composition and compressing so that it may become a desired magnitude | size or weight. At this time, as a mixing method, the respective components may be mixed at a time, or the respective components may be mixed sequentially.

  Hereinafter, the method for producing the first bulk treatment agent of the present invention will be described by dividing it into several preferred embodiments. Of course, it is not limited to the following method.

[Solidification with tabletop manual tableting machine]
In order to solidify with a tabletop manual tableting machine (one pestle and one mortar), first, each ingredient to be solidified is put into the jar with a spoon. At this time, there is no need to consider the difficulty of feeding. Then, a 1st block treatment agent is produced by lowering a lever by manual (hydraulic pressure), applying pressure, and solidifying each component. The advantage of the tabletop manual tableting machine is that it can be solidified even if it is a combination that is difficult to solidify because it is retained and pressure is applied for a considerable time. For example, in the case of using a ridge having a small diameter (diameter 7 mm: upper and lower circular plate type), the smaller the diameter, the higher the pressure applied per area. On the other hand, for example, when using a bowl having a large diameter (diameter 15 mm: upper and lower planographic type), the larger diameter has a smaller pressure per area, which is disadvantageous for those that are hard to solidify. Feeding to will be advantageous and productivity will be improved.

[Continuous tablet press]
In addition, the continuous tableting machine may or may not be a direct tableting machine, but it requires time for pretreatment (for example, granulation step; in the present invention, a dry process is preferred because a water-absorbing polymer is used). It is also preferable to adopt a direct hitting method that improves productivity in that it can be omitted. However, since the slaked lime that can be used as the main component of the present invention has a small particle size, it is preferable to add a lubricant to make it easy to feed such fine powder. On the other hand, when the pretreatment is performed, for example, the present invention is made by tableting a mixture of a binder (binder) mixed with a granulated fine powder by applying a large pressure using a roller compactor. The first block treatment agent may be prepared. In view of mass production, it is preferable to use, for example, a tableting machine (model AP18-SS or the like) manufactured by Hata Plant. The diameter of the mortar at this time is about 13 mm, and the number of uprights is about 18. If such a tableting machine is used, the raw materials are prepared in a desired ratio, mixed, the mixed raw materials are put into the hopper of the tableting machine, and the tableting machine is used for tableting in a rotary manner. Production is possible and preferable.

  Moreover, you may produce the 1st block treatment agent of this invention with a continuous rotary tableting machine. Specifically, each component (for example, slaked lime, activated carbon, water-absorbing polymer, binder, lubricant) is mixed to prepare a mixture, and the mixture is put into a hopper of a continuous tableting machine for tableting. The shape of the ridge may be, for example, an upper and lower circular plate type.

  Thus, there is no restriction | limiting in particular in the method for solidification for producing the 1st block treatment agent of this invention. As described above, tableting, roller compactor, and wet compression (wet the original material to be compressed with water and compression) may be applied in an appropriate combination. In addition, since the 1st block treatment agent of this invention contains a water absorptive polymer, the mixture with additives, such as a stage before mixing a water absorptive polymer, slaked lime, activated carbon, is wet-granulated, and then water absorption A method of mixing with a conductive polymer is also good. Moreover, you may produce the 1st block treatment agent of this invention with a continuous rotary tableting machine. Specifically, each component is mixed to prepare a mixture, and the mixture is put into a hopper of a continuous tableting machine for tableting. The shape of the ridge may be, for example, an upper and lower circular plate type.

[Use of first bulk treatment agent of the present invention]
The application of the first block treatment agent of the present invention is not particularly limited. For example, it can be used to treat manure, organic sludge, animals and plants, livestock, livestock barns or soil. The first lump treatment agent of the present invention exhibits various effects when used as a manure treatment agent, an organic sludge treatment agent, an animal and plant treatment agent, a livestock treatment agent, a livestock treatment agent, or a soil treatment agent. Specifically, since the first lump treatment agent of the present invention is contained in the excrement treatment agent, the treatment agent of the present invention is solidified, so that dust is used when using the treatment agent. Therefore, the handleability is improved. Specifically, manure treatment includes disaster toilets, toilets for traffic jams (toilets used in cars during traffic jams), temporary toilets at construction sites, pet toilets (cat sands and dog toilets), and water washing overseas There are applications in areas without infrastructure. In addition, when the 1st block treatment agent of this invention is used for excrement processing, this excrement includes not only human excrement but animal excrement such as cattle excrement, pig excrement, chicken excrement, etc. Further, the stool may be stool alone, urine alone, or a mixture of stool and urine. In the case of stool alone, it is preferable to contain a lot of water. Also, the treatment of organic sludge can be suitably used for the treatment of contaminated rivers, food residues discharged from restaurants, vomit treatment of infectious patients, blood treatment, and the like.

The treatment of animals, plants, livestock, livestock houses or soils is specifically applicable to the treatment of animals infected with infectious diseases such as foot-and-mouth disease and bird flu, livestock, their feed, livestock, livestock houses or soil. is there. For sterilization of foot-and-mouth disease and avian influenza, powdered slaked lime is usually used. However, since the treatment agent of the present invention is solidified, animal and plant treatment agents, livestock treatment agents, livestock treatment agents or soil treatments are used. Use in disinfectants significantly reduces dust damage, improves handling (handling), does not degrade reactivity, and uses disinfectants, disinfectants, sterilants, and deodorants Can also be used. Usually, slaked lime, limestone, and the like used for disinfection also have granularity, but are generally used in powder form because of poor reactivity. According to the present invention, particles are formed by mixing a water-absorbing polymer (polymer water-absorbing agent) and solidified, and the polymer water-absorbing agent serves as a base point for disintegration due to swelling when in contact with moisture. . Therefore, the reactivity does not decrease even in the case of a lump (in other words, while having the same degree of reactivity as powder), handling becomes very good, and the reactivity does not decrease because it breaks into powder. It is very suitable for foot-and-mouth disease and avian influenza disinfection. In addition, collection is facilitated.

<Second of the present invention>
The second of the present invention is a granular processing agent obtained by pulverizing the first massive processing agent of the present invention. As in the second aspect of the present invention, in the case of a granular treatment agent, it is not necessary to maintain the solid state for a long time as in the case of a bulk treatment agent, so that the unit weight of the bulk treatment agent can be reduced from the viewpoint that the amount of binder can be reduced. The ratio of the active ingredient per hit can be increased.

  Moreover, once it is made into a lump, it is preferable to pulverize it into a granule because the effect of improving the water absorption property continues. The 2nd granular processing agent of this invention consists of grind | pulverizing the 1st block processing agent of this invention once solidified. In the conventional powder state, what is produced through such a process of “temporarily solidifying” is not known. That is, the second granular processing agent of the present invention is different from a conventional powdery processing agent in terms of constitution (presence or absence of binder).

  The method for pulverizing the first block treatment agent of the present invention is not particularly limited, and can be performed, for example, by using a conventionally known atomization apparatus. The finer that can be used is classified into a shear crusher, an impact crusher, and a high-speed rotary crusher, and preferably has one or more of crushing mechanisms such as cutting, shearing, impact, and friction. Can be used. For example, a sizing machine at Hata Iron Works or a table mill at Okada Seiko can be used. Of course, other devices may be used. Alternatively, it may be crushed with a hammer or the like.

  The average particle diameter of the second granular treatment agent of the present invention is preferably more than 150 μm to less than 3 mm, more preferably about 0.05 to 2 mm, and still more preferably about 0.1 to 1 mm per one grain. It is. Within such a range, the handling area is improved, the contact area with the object to be processed is increased, and the reaction efficiency with the object to be processed can be improved.

  The 2nd granular processing agent of this invention can make the quantity of a binder smaller than the 1st block processing agent of this invention as mentioned above. The standard of the amount of the binder is preferably 10% reduction, more preferably 30% reduction, and further preferably 50% reduction to 70% reduction in the case of the first bulk treatment agent of the present invention. What is necessary is just to increase the quantity of slaked lime or limestone, a binder, an acidic solid substance, an additive, etc. in the part which could be reduced, and to make the whole 100 mass%.

<Third invention>
3rd of this invention is a toilet bowl by which the 1st block treatment agent of this invention or the 2nd granule treatment agent of this invention is arrange | positioned previously. Since the 3rd toilet bowl of this invention contains the 1st block treatment agent of this invention, or the 2nd granule treatment agent of this invention, the 1st block treatment agent of this invention, 2nd of this invention. It has the effect of a granular processing agent. Here, in particular, the third toilet of the present invention is very preferable from the viewpoint of handleability when the first block treatment agent of the present invention is included. Of course, it is also preferable that the third toilet of the present invention contains the second granular processing agent of the present invention, and in this case, there is an effect of increasing the surface area and improving the reactivity.

  When the 1st block treatment agent of this invention or the 2nd granule treatment agent of this invention is used for excrement processing, the usage-amount of a 1st block treatment agent is 100 mass parts of to-be-processed objects (for example, excrement). The range is preferably 10 to 200 parts by mass, more preferably 20 to 100 parts by mass, and still more preferably 30 to 60 parts by mass. When the amount of the treatment agent used is less than 10 parts by mass, the contact area between the excreta and slaked lime is reduced, so that the excrement may come into contact with the air and the fermentation and decomposition of the excrement may proceed. On the other hand, when it exceeds 100 mass parts, the residue after a process increases and the waste after a process may increase. In addition, the cost may increase.

  Therefore, when arrange | positioning previously the 1st block treatment agent of this invention or the 2nd granular treatment agent of this invention in the 3rd toilet bowl of this invention, it is preferable to arrange | position by the quantity of said range.

  From the viewpoint of ease of handling and the like, the third toilet of the present invention includes, for example, a sheet having a surface subjected to water-repellent treatment or a bag having an inner surface subjected to water-repellent treatment, etc. It is preferable to arrange one lump treatment agent or the second granular treatment agent of the present invention, and by adding feces and urine to the lump treatment agent, it becomes very easy even when discarded. In addition, feces and urine odors are roughly classified into fecal odor and ammonia odor. Fecal odor is an organic odor, and ammonia odor is an inorganic odor. The ammonia odor is an inorganic odor, and is an odor that hardly diffuses after excretion if a sheet whose surface is water-repellent is bound. However, stool odor tends to leak and diffuse even if the plastic bag is tied up because the gas is generated from the specimen itself, so that the internal pressure in the sheet (for example, plastic bag) whose surface is water repellent is increased. Conventionally known manure treatment agents have a low deodorizing effect, and it has been difficult to suppress manure odor (particularly fecal odor). According to the present invention, there are provided the first bulk treatment agent of the present invention, the second granular treatment agent of the present invention, and the third toilet of the present invention, which does not require an operation such as stirring, and is simple and Since it is possible to treat urine etc. efficiently and sterilize etc., it is possible to suppress the generation of bad odor and gas, for example, the toilet situation in the disaster area can be remarkably improved, It is very suitable in terms of hygiene.

  As mentioned above, since the 1st block treatment agent of this invention is solidified, it can lay in advance in a portable toilet etc. and can urinate or defecate from there. Then, dust such as slaked lime does not rise with the momentum of urination or defecation. Then, since the slaked lime which is a strong alkali having corrosiveness contained therein does not rise, it is preferable from the viewpoint of health without scattering to delicate parts of the human body.

  Moreover, according to the preferable form of the 3rd toilet bowl of this invention, the 1st block treatment agent of this invention or the 2nd granule treatment agent of this invention is previously arrange | positioned in absence of water. That is, since it is a dry type which does not require water, the storage stability as a toilet is also improved. In addition, dust and other problems do not occur, and it is possible to urinate and defecate from a portable toilet that has been laid in advance.

  In addition, since the toilet bowl of the present invention is preliminarily provided with a treatment agent, after excretion, the user does not need to check his / her own (or care recipient, etc.) feces and urine, and the user can use it comfortably. Can do. On the other hand, after the treatment agent is excreted, it is necessary to sprinkle the treatment agent on manure (or a caregiver or the like), and the user (or caregiver or the like) may become uncomfortable. there were. However, according to the toilet bowl of the present invention, since the treatment agent is arranged in advance, there is an effect that it is sufficient to discard the toilet bowl as it is without needing confirmation after excretion.

<Fourth aspect of the present invention>
4th of this invention is an absorbent article formed by including the 1st block treatment agent of this invention, or the 2nd granule treatment agent of this invention. The absorbent article according to the fourth aspect of the present invention is the above-described first bulk treatment agent of the present invention or the second granular treatment agent of the present invention, a liquid-permeable top sheet, and a liquid-impermeable back surface. It is preferable to provide a sheet.

  Although the manufacturing method of the absorbent article concerning this invention is not specifically limited, For example, the 1st block treatment agent of this invention or the 2nd granular treatment agent of this invention is liquid-permeable base material (surface Sheet) and a liquid-impermeable base material (back sheet) and, if necessary, equipped with an elastic member, a diffusion layer, an adhesive tape, etc., absorbent articles such as adult paper diapers, A sanitary napkin may be used.

  The first bulk treatment agent of the present invention or the second granular treatment agent of the present invention can impart a deodorizing function to an absorbent article and exhibits excellent deodorizing performance and absorption characteristics over a long period of time. .

  Specific examples of such absorbent articles include adult paper diapers that have grown significantly in recent years, hygiene materials such as diapers for children, sanitary napkins, so-called incontinence pads, and the like, and are particularly limited thereto. It is not a thing. The first lump treatment agent of the present invention or the second granular treatment agent of the present invention present in the absorbent article has a very excellent deodorizing property and has a remarkable dry feeling. This can greatly reduce the burden on the person and the caregiver.

  The amount of the first bulk treatment agent of the present invention or the second granular treatment agent of the present invention contained in the absorbent article may be appropriately adjusted according to the use. It is preferable to contain 5 to 50 g or 10 to 30 g.

  EXAMPLES Hereinafter, although an Example is given and this invention is demonstrated further in detail, this invention is not restrict | limited at all by the following Example.

Example 1 (Ref: B-4)
Place 0.8 g of the drug substance and 0.2 g of KC Flock (registered trademark), which is a cellulose binder, into the mortar of a tabletop tableting machine (manufactured by Kikusui Seisakusho Co., Ltd.) and apply 40 kN of pressure. Tablets (average diameter: 15 mm, average thickness: 5 mm) were obtained. The scissors used were upper and lower planographic types having a diameter of 15 mm. In addition, sol barit (slaked lime containing 10% by weight of activated carbon, manufactured by Ube Materials Co., Ltd.) 80 parts by weight, and water-absorbing polymer (also referred to as “water absorbing agent”) (product name: Hymosub HS-960 (manufactured by Hymo Co., Ltd.)) The mixture consisting of 20 parts by weight is referred to as “the drug substance”. The same applies hereinafter.

  The obtained tablet of the treatment agent was capable of forming a complete molded product, and had a strength that did not collapse even after one month and did not collapse even when pressed by hand. The handleability was very good.

Example 2 (Ref: B-5)
Treating agent tablets (average diameter: 15 mm, average thickness: 5 mm) as in Example 1 except that the amount of the drug substance is 0.9 g and the amount of KC Flock (registered trademark) is 0.1 g. )

  The obtained tablet of the treatment agent was a molded product with some corners missing, but had a strength that did not collapse even after one month and did not collapse even by hand. The handleability was very good.

Example 3 (Ref: B-8)
0.8 g of the drug substance was prepared and solidified under pressure using a roller compactor (manufactured by Turbo Industry Co., Ltd.) to obtain a granular mixture. This granular mixture and 0.2 g of KC Flock (registered trademark) as a binder are put into a mortar of a tabletop tableting machine (manufactured by Kikusui Seisakusho Co., Ltd.). Average diameter: 15 mm, average thickness: 5 mm). The scissors used were upper and lower planographic types having a diameter of 15 mm.

  The obtained tablet of the treatment agent was capable of forming a complete molded body, and had a strength that did not collapse even after one month and did not collapse even by hand. The handleability was very good.

Example 4 (Ref: B-9)
0.8 g of the drug substance was prepared and solidified under pressure using a tabletop tableting machine (manufactured by Kikusui Seisakusho Co., Ltd.) to obtain a granular material. This granular product is pulverized into a powder using a mortar and pestle, and the obtained powdery drug substance and 0.2 g of KC Flock (registered trademark) as a binder are used as a tabletting tablet machine (Kikusui Seisakusho Co., Ltd.). And a tablet of treatment agent (average diameter: 15 mm, average thickness: 5 mm) was obtained. The scissors used were upper and lower planographic types having a diameter of 15 mm.

  The obtained tablet of the treatment agent was capable of forming a complete molded body, and had a strength that did not collapse even after one month and did not collapse even by hand. The handleability was very good.

(Example 5) (Ref: C-2)
Solvalit (slaked lime containing 10% by weight of activated carbon, manufactured by Ube Materials Co., Ltd.) 0.3 g, water absorbent (Himosub HS-960) 0.3 g, KC Flock (registered trademark) 0.65 g as a binder, and lubricant Ester and silicon (sucrose fatty acid ester DK ester manufacturer name: Daiichi Kogyo Seiyaku Co., Ltd. and fine silicon dioxide silo page 720 manufacturer name: Fuji Silysia Chemical Ltd.) 0.24 g (ester: silicon (weight) Ratio) = 2: 3) is placed in a mortar of a high-speed rotary tableting machine (manufactured by Kikusui Seisakusho Co., Ltd.) and tableted by applying a main pressure of 2t (pressure per one treatment agent). Tablets (average diameter: 15 mm, average thickness: 7 mm) were obtained. The scissors used were upper and lower circular plates with a diameter of 15 mm.

  The obtained tablet of the treatment agent was capable of forming a complete molded body, and had a strength that did not collapse even after one month and did not collapse even by hand. The handleability was very good.

Example 6 (Ref: C-3)
Solvalit (slaked lime containing 5% by weight of activated carbon, manufactured by Ube Materials Co., Ltd.) 0.5 g, water absorbent (Himosub HS-960) 0.3 g, KC Flock (registered trademark) 0.4 g as a binder Were the same as in Example 5 to obtain tablets of the treatment agent (average diameter: 15 mm, average thickness: 5 mm).

  The obtained tablet of the treatment agent was capable of forming a complete molded body, and had a strength that did not collapse even after one month and did not collapse even by hand. The handleability was very good.

(Comparative Example 1) (Ref: A-1)
0.5 g of the drug substance was placed in a mortar of a tabletop tableting machine (manufactured by Kikusui Seisakusho Co., Ltd.) and tableted by applying a pressure of 2 kN to obtain a treating agent tablet. The scissors used were upper and lower planographic types having a diameter of 15 mm.

  The obtained tablet of the treatment agent was a molded product with some corners missing, but completely disintegrated after several days.

(Comparative Example 2) (Ref: A-2)
A treating agent tablet was obtained in the same manner as in Comparative Example 1 except that the pressure was 4 kN.

  The tablet of the obtained treatment agent had a shape as a molded body immediately after molding, but it collapsed after 20 days.

(Comparative Example 3) (Ref: B-1)
1.0 g of the drug substance was placed in a mortar of a tabletop tableting machine (manufactured by Kikusui Seisakusho Co., Ltd.) and tableted by applying a pressure of 20 kN to obtain a tablet as a treatment agent. The scissors used were upper and lower planographic types having a diameter of 15 mm.

  The resulting treatment tablet disintegrated immediately after molding.

(Comparative Example 4) (Ref: B-2)
A treating agent tablet was obtained in the same manner as in Comparative Example 1, except that the pressure was 40 kN.

  The resulting treatment tablet disintegrated immediately after molding.

<Manure disposal>
・ Sample (sex: male, age: 38-year-old manure)
・ Odor test conditions: temperature 20 ° C, relative humidity 55%
The stool odor (mainly skatole, indole, and sulfide compounds) was subjected to a two-step sensory evaluation.

(Stool odor level)
“1” is equivalent to the stool odor before treatment.

  “0” has almost no stool odor.

  For urine odor (mainly ammonia), evaluation was performed using an ammonia gas detector tube (Kitakawa method) (manufactured by Komyo Chemical Co., Ltd.).

Example 7 (Ref: Experiment No. 2)
50 g of the treatment agent obtained in Example 5 was placed in a container (plastic bag) -like toilet pack in which the inner surface receiving feces and urine has water repellency. 50 g of urine was added on the arranged treatment agent, and then 200 g of stool was added. There was almost no odor when 30 minutes passed after contact (odor level: 0), and there was almost no odor even after 2 weeks (odor level: 0).

Example 8 (Ref: Experiment No. 3)
100 g of the treatment agent obtained in Example 5 was placed in a container (plastic bag) -like toilet pack in which the inner surface receiving feces and urine has water repellency. 50 g of urine was added on the arranged treatment agent, and then 200 g of stool was added. There was almost no odor when 30 minutes passed after contact (odor level: 0), and there was almost no odor even after 2 weeks (odor level: 0).

Example 9 (Ref: Experiment No. 4)
The treatment was performed in the same manner as in Example 8 except that the treatment agent was changed to 75 g. There was almost no odor when 30 minutes passed after contact (odor level: 0), and there was almost no odor even after 2 weeks (odor level: 0).

Example 10 (Ref: C)
A mixture was prepared by mixing the components shown in the following table at a mixing ratio shown in the following table (total 100% by mass) so as to be 50 g. 50 tablets of the bulk treatment agent were prepared by tableting 50 g of this mixture with a tableting machine (HS series) of Fuji Pharmaceutical Co., Ltd., using a 15 mm diameter punch and mortar at a main pressure of 1.5 kN and 30 rpm. (1 g of 1 grain, average diameter: 15 mm, average thickness: 6 mm). The handleability was very good. The hardness of the block treatment agent was 12 kgf. The hardness at this time was measured with a tablet breaking strength measuring instrument (hardness meter) TH-203MP.

  50 g of the treatment agent obtained in Example 10 was placed in a container (plastic bag) -like toilet pack in which the inner surface receiving feces and urine has water repellency. 50 g of urine was added on the arranged treatment agent, and then 200 g of stool was added. There was almost no odor when 30 minutes passed after the treatment (odor level: 0). In addition, a plastic bag of a processed product that had been processed for 24 hours was tied and left for 1 hour, then a small hole was made in the plastic bag, a detector tube was inserted, and gas was measured with a gas detector tube for measuring ammonia. The result was 360 ppm. Thereafter, the plastic bag was opened and left for 2 weeks. The odor was confirmed after standing for 2 weeks, but there was almost no odor (odor level: 0). The particle size distribution of Aquakeep SA50-II is as follows.

Example 11 (Ref: T1)
A mixture was prepared by mixing the components shown in the following table at a mixing ratio shown in the following table (total 100% by mass) so as to be 50 g. 50 tablets of the bulk treatment agent were prepared by tableting 50 g of this mixture with a tableting machine (HS series) of Fuji Pharmaceutical Co., Ltd., using a 15 mm diameter punch and mortar at a main pressure of 1.5 kN and 30 rpm. (1 g of 1 grain, average diameter: 15 mm, average thickness: 6 mm). The feed from the hopper could be done smoothly. Moreover, the handleability was very excellent. The hardness of the block treatment agent was 12 kgf. The hardness at this time was measured with a tablet breaking strength measuring instrument (hardness meter) TH-203MP.

  50 g of the treatment agent obtained in Example 11 was placed in a container (plastic bag) -like toilet pack having an inner surface that receives feces and urine. 50 g of urine was added on the arranged treatment agent, and then 200 g of stool was added.

  There was almost no odor when 30 minutes passed after the treatment (odor level: 0). In addition, a plastic bag of a processed product that had been processed for 24 hours was tied and left for 1 hour, then a small hole was made in the plastic bag, a detector tube was inserted, and gas was measured with a gas detector tube for measuring ammonia. The result was 1 ppm. In this example, since sodium dihydrogen phosphate, which is an acidic solid substance, is contained, the result of the ammonia gas detector tube is very good at 1 ppm while maintaining the action of alkaline slaked lime on the stool. It was a thing. Similar results were obtained in the following examples containing sodium dihydrogen phosphate. The pH of the treated product after 24 hours from the treatment was 6.73. The pH of the present invention was measured using a PH recorder SD card recording system model number PH-SD manufactured by Sato Corporation. Thereafter, the plastic bag was opened and left for 2 weeks. The odor was confirmed after standing for 2 weeks, but there was almost no odor (odor level: 0).

Example 12 (Ref: Experiment (6) -1)
A mixture was prepared by mixing the components shown in the table below at a mixing ratio shown in the table below (total 100% by mass) so as to be 45 g. 45 g of this mixture were tableted with HT-AP18SS-II continuous tableting machine manufactured by Hata Iron Works Co., Ltd., using a 13 mm diameter pestle and mortar, and a tablet pressure of 1.5 kN and 30 rpm to obtain 45 bulk treatment agents. (1 g of 1 grain, average diameter: 13 mm, average thickness: 6 mm). The feed from the hopper could be done smoothly. Moreover, the handleability was very excellent. The hardness of the block treatment agent was 12 kgf. The hardness at this time was measured with a tablet breaking strength measuring instrument (hardness meter) TH-203MP.

  45 g of the treatment agent obtained in Example 12 was placed in a container (plastic bag) -like toilet pack in which the inner surface for receiving excreta has water repellency. 50 g of urine was added on the arranged treatment agent, and then 200 g of stool was added.

  There was almost no odor when 30 minutes passed after the treatment (odor level: 0). In addition, a plastic bag of a processed product that had been processed for 24 hours was tied and left for 1 hour, then a small hole was made in the plastic bag, a detector tube was inserted, and gas was measured with a gas detector tube for measuring ammonia. As a result, it was 0.2 ppm. The pH of the treated product 24 hours after the treatment was 6.8. The pH of the present invention was measured using a PH recorder SD card recording system model number PH-SD manufactured by Sato Corporation. Thereafter, the plastic bag was opened and left for 2 weeks. The odor was confirmed after standing for 2 weeks, but there was almost no odor (odor level: 0).

Example 13 (Ref: Experiment (7) -1)
A mixture was prepared by mixing the components shown in the following table at a mixing ratio shown in the following table (total 100% by mass) so as to be 50 g. 77 g of the bulk processing agent were obtained by tableting 50 g of this mixture with a HT-AP18SS-II continuous tableting machine manufactured by Hata Iron Works Co., Ltd. using a φ13 mm punch and mortar at a main pressure of 6.5 kN and 20 rpm. (About 0.65 g per grain, average diameter: 13 mm, average thickness: 5.5 mm). The feed from the hopper could be done smoothly. Moreover, the handleability was very excellent. The hardness of the block treatment agent was 13 kgf. The hardness at this time was measured with a tablet breaking strength measuring instrument (hardness meter) TH-203MP.

  50 g of the treatment agent obtained in Example 13 was placed in a container (plastic bag) -like toilet pack in which the inner surface for receiving excreta has water repellency. 50 g of urine was added on the arranged treatment agent, and then 200 g of stool was added.

  There was almost no odor when 30 minutes passed after the treatment (odor level: 0). In addition, a plastic bag of a processed product that had been processed for 24 hours was tied and left for 1 hour, then a small hole was made in the plastic bag, a detector tube was inserted, and gas was measured with a gas detector tube for measuring ammonia. As a result, it was 0.1 ppm. The pH of the treated product 24 hours after the treatment was 6.8. The pH of the present invention was measured using a PH recorder SD card recording system model number PH-SD manufactured by Sato Corporation. Thereafter, the plastic bag was opened and left for 2 weeks. The odor was confirmed after standing for 2 weeks, but there was almost no odor (odor level: 0).

Example 14 (Ref: Experiment (7) -2)
A mixture was prepared by mixing the components shown in the following table at a mixing ratio shown in the following table (total 100% by mass) so as to be 50 g. 67 tablets of the bulk treatment agent were obtained by tableting 50 g of this mixture with a HT-AP18SS-II continuous tableting machine manufactured by Hata Iron Works Co., Ltd. using a φ13 mm punch and mortar at a main pressure of 5.58 kN and 20 rpm. (About 0.75 g per grain, average diameter: 13 mm, average thickness: 5 mm). The feed from the hopper could be done smoothly. Moreover, the handleability was very excellent. The hardness of the block treatment agent was 12 kgf. The hardness at this time was measured with a tablet breaking strength measuring instrument (hardness meter) TH-203MP.

  50 g of the treatment agent obtained in Example 14 was placed in a container (plastic bag) -like toilet pack having an inner surface that receives feces and urine. 50 g of urine was added on the arranged treatment agent, and then 200 g of stool was added.

  There was almost no odor when 30 minutes passed after the treatment (odor level: 0). In addition, a plastic bag of a processed product that had been processed for 24 hours was tied and left for 1 hour, then a small hole was made in the plastic bag, a detector tube was inserted, and gas was measured with a gas detector tube for measuring ammonia. As a result, it was 0.1 ppm. The pH of the treated product after 24 hours from the treatment was 6.82. The pH of the present invention was measured using a PH recorder SD card recording system model number PH-SD manufactured by Sato Corporation. Thereafter, the plastic bag was opened and left for 2 weeks. The odor was confirmed after standing for 2 weeks, but there was almost no odor (odor level: 0).

Example 15 (Ref: Experiment (7) -6)
A mixture was prepared by mixing the components shown in the following table at a mixing ratio shown in the following table (total 100% by mass) so as to be 50 g. 83 tablets of the bulk treatment agent were obtained by tableting 50 g of this mixture with a HT-AP18SS-II continuous tableting machine manufactured by Hata Iron Works Co., Ltd. using a φ13 mm punch and mortar at 30 rpm at a main pressure of 5.54 kN. (About 0.6 g per grain, average diameter: 13 mm, average thickness: 5.5 mm). The feed from the hopper could be done smoothly. Moreover, the handleability was very excellent. The hardness of the block treatment agent was 8 kgf. The hardness at this time was measured with a tablet breaking strength measuring instrument (hardness meter) TH-203MP.

Example 1 is applied to a toilet pack in the form of a container (plastic bag) having water repellency on the inner surface that receives manure.
50 g of the treating agent obtained in 5 was placed. 50 g of urine was added on the arranged treatment agent, and then 200 g of stool was added.

  There was almost no odor when 30 minutes passed after the treatment (odor level: 0). In addition, a plastic bag of a processed product that had been processed for 24 hours was tied and left for 1 hour, then a small hole was made in the plastic bag, a detector tube was inserted, and gas was measured with a gas detector tube for measuring ammonia. As a result, it was 0.5 ppm. The pH of the treated product that passed 24 hours after the treatment was 6.91. The pH of the present invention was measured using a PH recorder SD card recording system model number PH-SD manufactured by Sato Corporation. Thereafter, the plastic bag was opened and left for 2 weeks. The odor was confirmed after standing for 2 weeks, but there was almost no odor (odor level: 0).

Example 16 (Ref: Experiment (7) -7)
A mixture was prepared by mixing the components shown in the following table at a mixing ratio shown in the following table (total 100% by mass) so as to be 50 g. By pressing 50 g of this mixture with a HT-AP18SS-II continuous tableting machine manufactured by Hata Iron Works Co., Ltd. and using a φ13 mm punch and mortar at a main pressure of 7.5 kN and 20 rpm, 83 bulk treatment agents (About 0.6 g per grain, average diameter: 13 mm, average thickness: 5.5 mm). The feed from the hopper could be done smoothly. Moreover, the handleability was very excellent. The hardness of the block treatment agent was 12 kgf. The hardness at this time was measured with a tablet breaking strength measuring instrument (hardness meter) TH-203MP.

  50 g of the treatment agent obtained in Example 16 was placed in a container (plastic bag) -like toilet pack having an inner surface that receives feces and urine. 50 g of urine was added on the arranged treatment agent, and then 200 g of stool was added.

  There was almost no odor when 30 minutes passed after the treatment (odor level: 0). In addition, a plastic bag of a processed product that had been processed for 24 hours was tied and left for 1 hour, then a small hole was made in the plastic bag, a detector tube was inserted, and gas was measured with a gas detector tube for measuring ammonia. As a result, it was 0.5 ppm. The pH of the treated product after 24 hours from the treatment was 6.95. The pH of the present invention was measured using a PH recorder SD card recording system model number PH-SD manufactured by Sato Corporation. Thereafter, the plastic bag was opened and left for 2 weeks. The odor was confirmed after standing for 2 weeks, but there was almost no odor (odor level: 0).

Example 17 (Ref: FJG-A)
A mixture was prepared by mixing the components shown in the following table at a mixing ratio shown in the following table (total 100% by mass) to 38.5 g. 39 tablets of the bulk treatment agent were obtained by tableting 38.5 g of this mixture with a HT-AP18SS-II continuous tableting machine manufactured by Hata Iron Works Co., Ltd. using a φ13 mm scissors and mortar at 40 rpm and a main pressure of 40 rpm. (About 1 g per grain, average diameter: 13 mm, average thickness: 7 mm). The feed from the hopper could be done smoothly. Moreover, the handleability was very excellent. The hardness of the block treatment agent was 7 kgf. The hardness at this time was measured with a tablet breaking strength measuring instrument (hardness meter) TH-203MP.

  38.5 g of the treatment agent obtained in Example 17 was pulverized by hand with this block treatment agent, and 150 μm or less was selected with a sieve to prepare a granular treatment agent having a size of more than 150 μm. 50 g of urine is added to a container (plastic bag) -like toilet pack whose inner surface that receives excreta has water repellency, 200 g of stool is then added, and 38.5 g of crushed treatment agent is added to 200 g of stool. Sprinkled.

  There was almost no odor when 30 minutes passed after the treatment (odor level: 0). In addition, a plastic bag of a processed product that had been processed for 24 hours was tied and left for 1 hour, then a small hole was made in the plastic bag, a detector tube was inserted, and gas was measured with a gas detector tube for measuring ammonia. As a result, it was 0 ppm (that is, below the detection limit). The pH of the treated product after 24 hours from the treatment was 6.61. The pH of the present invention was measured using a PH recorder SD card recording system model number PH-SD manufactured by Sato Corporation. Thereafter, the plastic bag was opened and left for 2 weeks. The odor was confirmed after standing for 2 weeks, but there was almost no odor (odor level: 0).

(Example 18)
A mixture was prepared by mixing the components shown in the table below at a mixing ratio shown in the table below (total 100% by mass) so as to be 45 g. 45 g of this mixture was tableted with a HT-AP18SS-II continuous tableting machine manufactured by Hata Iron Works Co., Ltd. using a φ13 mm scissors and mortar at a main pressure of 1.5 kN and 30 rpm, to obtain 45 bulk treatment agents. Were prepared (1 g of 1 grain). The feed from the hopper could be done smoothly. Moreover, the handleability was very excellent. The hardness of the block treatment agent was 12 kgf. The hardness at this time was measured with a tablet breaking strength measuring instrument (hardness meter) TH-203MP.

  45 g of the treatment agent obtained in Example 18 was placed in a container (plastic bag) -like toilet pack in which the inner surface for receiving excreta has water repellency. 500 g of urine was added on the arranged treatment agent.

  A plastic bag of a processed product that had been treated for 24 hours was tied and left for 1 hour, then a small hole was made in the plastic bag, a detector tube was inserted, and gas was measured with a gas detector tube for measuring ammonia. As a result, it was 0 ppm. The pH of the treated product after 24 hours from the treatment was 6.6. The pH of the present invention was measured using a PH recorder SD card recording system model number PH-SD manufactured by Sato Corporation.

(Example 19)
A mixture was prepared by mixing the components shown in the following table at a mixing ratio shown in the following table (total 100% by mass) so as to be 50 g. 83 tablets of the bulk treatment agent were obtained by tableting 50 g of this mixture with a HT-AP18SS-II continuous tableting machine manufactured by Hata Iron Works Co., Ltd. using a φ13 mm punch and mortar at 30 rpm at a main pressure of 5.54 kN. Was produced (about 0.6 g per grain). The feed from the hopper could be done smoothly. Moreover, the handleability was very excellent. The hardness of the block treatment agent was 8 kgf. The hardness at this time was measured with a tablet breaking strength measuring instrument (hardness meter) TH-203MP.

  50 g of the treatment agent obtained in Example 19 was placed in a container (plastic bag) -like toilet pack having an inner surface that receives feces and urine. 500 g of urine was added on the arranged treatment agent.

A plastic bag of a processed product that had been treated for 24 hours was tied and left for 1 hour, then a small hole was made in the plastic bag, a detector tube was inserted, and gas was measured with a gas detector tube for measuring ammonia. Result, 0pp
m. The pH of the treated product after 24 hours from the treatment was 6.62. The pH of the present invention was measured using a PH recorder SD card recording system model number PH-SD manufactured by Sato Corporation.

(Comparative Example 5)
50 g of urine was added to a toilet pack in the form of a container (plastic bag) whose inner surface receiving manure has water repellency, and then 300 g of stool was added. Thereafter, 10 g of a water-absorbing polymer (Aquakeep SA-50II manufactured by Sumitomo Seika Co., Ltd.) was added.

  The odor when 30 minutes passed after contact was a strong stool odor (odor level: 1), and even after 2 weeks, there was almost no odor (odor level: 1). A plastic bag of a processed product that had been treated for 24 hours was tied and left for 1 hour, then a small hole was made in the plastic bag, a detector tube was inserted, and gas was measured with a gas detector tube for measuring ammonia. As a result, it was 100 ppm.

Claims (10)

With slaked lime or limestone,
A water-absorbing polymer;
A binder,
A bulk treatment agent comprising:   The block treatment agent according to claim 1, further comprising an acidic solid substance.   The block treatment agent according to claim 1 or 2, having an average diameter of 3 to 100 mm.   The block treatment agent according to any one of claims 1 to 3, further comprising at least one additive selected from the group consisting of zeolite, activated carbon, sodium bicarbonate, and a lubricant.   The block treatment agent according to any one of claims 1 to 4, which is used for manure treatment.   The granular processing agent formed by grind | pulverizing the block processing agent of any one of Claims 1-5.   The granular processing agent of Claim 6 whose average particle diameter is more than 150 micrometers-less than 3 mm.   A toilet bowl in which the block treatment agent according to any one of claims 1 to 5 or the granule treatment agent according to claim 6 or 7 is arranged in advance.   The toilet bowl according to claim 8, wherein the bulk treatment agent according to any one of claims 1 to 5 or the granular treatment agent according to claim 6 or 7 is arranged in advance in the absence of water. .   An absorptive article of excrement formed by including the lump treating agent according to any one of claims 1 to 5 or the granular treating agent according to claim 6 or 7.