JP2016020066A - Method for adhering multilayer film materials - Google Patents

Method for adhering multilayer film materials Download PDF

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JP2016020066A
JP2016020066A JP2014145005A JP2014145005A JP2016020066A JP 2016020066 A JP2016020066 A JP 2016020066A JP 2014145005 A JP2014145005 A JP 2014145005A JP 2014145005 A JP2014145005 A JP 2014145005A JP 2016020066 A JP2016020066 A JP 2016020066A
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adhesive
film material
multilayer film
viscosity
material layer
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JP6401952B2 (en
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石田 正利
Masatoshi Ishida
正利 石田
赤井 智幸
Tomoyuki Akai
智幸 赤井
正樹 西村
Masaki Nishimura
正樹 西村
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Taiyo Kogyo Co Ltd
Technology Research Institute of Osaka Prefecture
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Taiyo Kogyo Co Ltd
Technology Research Institute of Osaka Prefecture
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Abstract

PROBLEM TO BE SOLVED: To enable adhesion work to be performed easily, the adhesion work being between two respective portions of a multilayer film material and a corresponding material in order to obtain specified adhesion strength and sealability between the respective portions.SOLUTION: The method for adhering multilayer film materials comprises: superimposing a portion 15a in a surface direction of a multilayer film material 15, comprising a water impermeable film material layer 16 and a pair of nonwoven fabric film material layers 17 bonded to each surface of the water impermeable film material layer 16, on a portion 22a in a surface direction of a corresponding material 22 arranged to correspond to the multilayer film material 15; and adhering the two with an adhesive 21. The adhesive 21 is a two-component reactive-type adhesive in which a main agent and a curing agent initiate a chemical reaction by mixing of the two liquids with viscosity beginning to increase. At the time of adhesion, viscosity of the adhesive 21 immediately after mixing of the two liquids is adjusted to be in a low viscosity region of 150 to 1000 mPa s at an atmospheric temperature of 23°C. The adhesive is adjusted so that its viscosity reaches a high viscosity region of 2500 to 7000 mPa s after passage of the specified period of time of 5 minutes after mixing.SELECTED DRAWING: Figure 1

Description

本発明は、廃棄物処分場や瓦礫の仮置き場に用いられるキャッピングシートなど、外面に不織布製膜材層を有する多層膜材をこれに対応する何らかの対応材に接着させる際の多層膜材接着方法に関するものである。   The present invention relates to a multilayer film material bonding method for bonding a multilayer film material having a non-woven film material layer on the outer surface to a corresponding material corresponding thereto, such as a capping sheet used in a waste disposal site or a debris temporary storage site. It is about.

上記廃棄物処分場には、通常、下記特許文献1に示されるものがある。この公報のものによれば、上記処分場は、地盤に形成され上方に向かって開く凹形状の廃棄物用埋立域と、詳図されていないが、この埋立域の内面に全体的に敷設される遮水シートと、この遮水シートで囲まれた遮水埋立域に投入されてこの遮水埋立域を十分に埋めた廃棄物の上面を全体的に覆うキャッピングシートとを備えている。また、瓦礫の仮置き場等の上面を全体的に覆うキャッピングシートの存在が一般的に知られている。   Some of the above-mentioned waste disposal sites are shown in Patent Document 1 below. According to this publication, the disposal site is formed in the ground and opened in a concave shape for a waste landfill, and although not shown in detail, it is generally laid on the inner surface of this landfill area. And a capping sheet that is thrown into the impermeable landfill area surrounded by the impermeable sheet and covers the entire upper surface of the waste that sufficiently fills the impermeable landfill area. In addition, the existence of a capping sheet that covers the entire upper surface of a debris temporary storage area or the like is generally known.

上記キャッピングシートは、ほぼ水平な方向に向かって互いに並設される複数枚の多層膜材で構成される。これら各多層膜材は、それぞれ水の通過を防止する非通水性膜材層と、水の通過は許容するが、クッション性を有して上記非通水性膜材層を保護するようこの非通水性膜材層の各面に接合される一対の不織布製膜材層とを有している。そして、隣り合う両多層膜材の互いに対向する端縁同士が重ね合わされて接着剤により接着されることにより、上記キャッピングシートが形成されている。   The capping sheet is composed of a plurality of multilayer film materials arranged in parallel in a substantially horizontal direction. Each of these multilayer membrane materials is a non-water-permeable membrane material layer that prevents the passage of water and a non-permeable membrane material layer that allows the passage of water but has a cushioning property to protect the non-water-permeable membrane material layer. It has a pair of nonwoven fabric film material layers joined to each surface of the aqueous film material layer. And the said capping sheet | seat is formed when the mutually opposing edge of both adjacent multilayer film material is piled up, and it adhere | attaches with an adhesive agent.

上記両多層膜材の各端縁部同士の接着剤による接着方法は、これら端縁部同士の重ね合わせ部で互いに対面する各不織布製膜材層の内部にそれぞれ接着剤を浸入させて硬化させるというものである。   The bonding method using the adhesive between the edge portions of the both multilayer film materials is performed by allowing the adhesive to penetrate into the respective nonwoven fabric film material layers facing each other at the overlapping portion of the edge portions. That's it.

上記接着方法によれば、上記両多層膜材の各端縁部同士が上記接着剤により所定の接着強度で接着させられることに加えて、上記重ね合わせ部における各不織布製膜材層は、これに浸入した接着剤により内部空間が埋められてシール材として働くこととなる。よって、上記キャッピングシートにおける上記重ね合わせ部の両外面のうち、一方の外面がわから他方の外面がわに向かって水が透過することは防止される。この結果、上記各多層膜材同士の接着により形成されたキャッピングシートによれば、処分場の外部の雨水などの水が上記遮水埋立域に投入された廃棄物内に無用に流入することが防止される。   According to the bonding method, in addition to the edge portions of the multilayer film materials being bonded to each other with a predetermined adhesive strength by the adhesive, the nonwoven fabric film material layers in the overlapping portion are The internal space is filled with the adhesive that has penetrated into the film and acts as a sealing material. Therefore, it is prevented that water permeates from one outer surface to the other outer surface of both the outer surfaces of the overlapping portion in the capping sheet. As a result, according to the capping sheet formed by adhering the multilayer film materials, water such as rainwater outside the disposal site can flow unnecessarily into the waste thrown into the impermeable landfill area. Is prevented.

特開2011−245745号公報JP 2011-245745 A

ところで、上記した両多層膜材の各端縁部同士の接着剤による接着方法においては、次のような問題点が生じるおそれがある。   By the way, the following problems may occur in the bonding method using the adhesive between the edge portions of both multilayer film materials described above.

即ち、上記接着剤の特性として、接着作業開始時に、接着剤の粘度が既に高い場合や、接着剤の硬化の速度が速い場合には、上記両多層膜材の各端縁部同士の重ね合わせ部で互いに対面する各不織布製膜材層に接着剤を浸入させたとき、上記各不織布製膜材層の内部への接着剤の円滑な浸入が阻害されて、上記非通水性膜材層に到達する前に硬化してしまうおそれがある。そして、この場合には、上記各不織布製膜材層はシール材としての働きができなくなる。   That is, as a characteristic of the adhesive, when the adhesive viscosity is already high at the start of the bonding operation, or when the curing speed of the adhesive is high, the respective edge portions of both the multilayer film materials are overlapped. When the adhesive is infiltrated into each nonwoven fabric film material layer facing each other at the portion, smooth penetration of the adhesive into the inside of each nonwoven fabric film material layer is inhibited, and the non-water-permeable membrane material layer There is a risk of curing before reaching. In this case, each of the nonwoven fabric film material layers cannot function as a sealing material.

一方、上記接着剤の粘度が低い場合や、硬化の速度が遅い場合には、上記各不織布製膜材層に接着剤を浸入させたとき、これら不織布製膜材層の内部への接着剤の浸入範囲が過大となって液だれが生じるおそれがある。そして、この場合には、上記両多層膜材の各端縁部同士の接着強度が不足するおそれが生じると共に、上記各不織布製膜材層はシール材としての働きができなくなる。   On the other hand, when the viscosity of the adhesive is low or when the curing speed is slow, when the adhesive is infiltrated into each of the nonwoven film-forming material layers, There is a risk of dripping due to excessive penetration. In this case, there is a possibility that the adhesive strength between the edge portions of both the multilayer film materials may be insufficient, and each of the nonwoven fabric film material layers cannot function as a sealing material.

そこで、上記不都合が生じないようにするため、上記接着剤の特性に合わせて、接着作業をより速く進めたり、液だれ防止の作業を追加したりすることが考えられるが、これでは、この接着作業が極めて煩雑になるおそれがある。   Therefore, in order to prevent the above inconvenience, it may be possible to advance the bonding work faster or to add a dripping prevention work in accordance with the characteristics of the adhesive. There is a risk that the operation becomes extremely complicated.

本発明は、上記のような事情に注目してなされたもので、本発明の目的は、外面に不織布製膜材層を有する多層膜材の面方向の一部分を、この多層膜材に対応するよう設けられた対応材の面方向の一部分に重ね合わせて接着剤により接着するに際し、これら多層膜材と対応材との各一部分同士の間に所定の接着強度とシール性とが得られるようにするための上記各一部分同士の接着作業が容易にできるようにすることである。   The present invention has been made paying attention to the above-described circumstances, and an object of the present invention is to correspond to a part of the multilayer film material having a nonwoven fabric film material layer on the outer surface in the surface direction. So that a predetermined adhesive strength and sealability can be obtained between each part of the multilayer film material and the corresponding material when they are overlapped with a portion in the surface direction of the corresponding material and adhered by an adhesive. It is to make it possible to easily perform the bonding operation between the respective parts for the purpose.

請求項1の発明は、非通水性膜材層16とこの非通水性膜材層16の各外面に接合される一対の不織布製膜材層17とを有した多層膜材15の面方向の一部分15aを、この多層膜材15に対応するよう設けられた対応材22の面方向の一部分22aに重ね合わせて接着剤21により接着する際の多層膜材接着方法であって、
上記接着剤21を主剤と硬化剤とによる二液の混合により化学反応が開始されて粘性が上昇し始める二液型反応系接着剤とし、
上記接着に際しての上記二液の混合直後における接着剤21の粘度が、雰囲気温度23℃にて150−1000mPa・sの低粘度域となるようにし、かつ、上記接着剤21が、上記混合直後から5分の所定期間経過後に2500−7000mPa・sの高粘度域となるようにしたことを特徴とする多層膜材接着方法である。
The invention of claim 1 is directed to the surface direction of the multilayer film material 15 having the water impermeable film material layer 16 and a pair of non-woven film material layers 17 bonded to the outer surfaces of the water impermeable film material layer 16. A multilayer film material adhering method in which a portion 15a is overlapped with a portion 22a in a surface direction of a corresponding material 22 provided so as to correspond to the multilayer film material 15 and adhered by an adhesive 21;
The adhesive 21 is a two-component reaction adhesive in which a chemical reaction is started by mixing the two components of the main agent and the curing agent and the viscosity starts to increase,
The viscosity of the adhesive 21 immediately after mixing the two liquids during the bonding is in a low viscosity range of 150 to 1000 mPa · s at an ambient temperature of 23 ° C., and the adhesive 21 is immediately after the mixing. A multilayer film material adhering method characterized by having a high viscosity range of 2500 to 7000 mPa · s after a lapse of a predetermined period of 5 minutes.

請求項2の発明は、雰囲気温度23℃での上記接着剤21の主剤と硬化剤との粘度比率を1.3:1−3:1としたことを特徴とする請求項1に記載の多層膜材接着方法である。   The invention according to claim 2 is characterized in that the viscosity ratio of the main agent and the curing agent of the adhesive 21 at an ambient temperature of 23 ° C. is 1.3: 1-3: 1. This is a film material adhesion method.

請求項3の発明は、上記接着剤21をポリウレタン系としたことを特徴とする請求項2に記載の多層膜材接着方法である。   The invention of claim 3 is the multilayer film material bonding method according to claim 2, wherein the adhesive 21 is made of polyurethane.

請求項4の発明は、上記接着剤21の主剤の主成分をポリオール類とし、硬化剤の主成分をイソシアネート類とし、上記主剤と硬化剤との質量混合比を2.5:1−5:1としたことを特徴とする請求項2に記載の多層膜材接着方法である。   In the invention of claim 4, the main component of the main component of the adhesive 21 is a polyol, the main component of the curing agent is an isocyanate, and the mass mixing ratio of the main component and the curing agent is 2.5: 1-5: The multilayer film material adhering method according to claim 2, wherein the method is 1.

請求項5の発明は、上記多層膜材15と対応材22との各一部分15a,22a同士が互いに重ね合わされた既重ね合わせ部33に対し、その外面から上記接着剤21を上記所定期間内にて塗布するようにしたことを特徴とする請求項1から4のうちいずれか1つに記載の多層膜材接着方法である。   In the invention of claim 5, the adhesive 21 is applied from the outer surface to the already overlapped portion 33 in which the portions 15a and 22a of the multilayer film material 15 and the corresponding material 22 are overlapped with each other within the predetermined period. The multilayer film material adhering method according to any one of claims 1 to 4, wherein the multilayer film material adhering method is applied.

なお、この項において、上記各用語に付記した符号や図面番号は、本発明の技術的範囲を後述の「実施例」の項や図面の内容に限定解釈するものではない。   In addition, in this section, the reference numerals and drawing numbers appended to the above terms are not intended to limit the technical scope of the present invention to the “Example” section and the contents of the drawings described later.

本発明による効果は、次の如くである。   The effects of the present invention are as follows.

請求項1の発明は、非通水性膜材層とこの非通水性膜材層の各外面に接合される一対の不織布製膜材層とを有した多層膜材の面方向の一部分を、この多層膜材に対応するよう設けられた対応材の面方向の一部分に重ね合わせて接着剤により接着する際の多層膜材接着方法であって、
上記接着剤を主剤と硬化剤とによる二液の混合により化学反応が開始されて粘性が上昇し始める二液型反応系接着剤とし、
上記接着に際しての上記二液の混合直後における接着剤の粘度が、雰囲気温度23℃にて150−1000mPa・sの低粘度域となるようにし、かつ、上記接着剤が、上記混合直後から5分の所定期間経過後に2500−7000mPa・sの高粘度域となるようにしており、次の効果が生じる。
In the invention of claim 1, a part in the surface direction of a multilayer film material having a water-impermeable film material layer and a pair of non-woven film material layers bonded to each outer surface of the water-impermeable film material layer, A multilayer film material adhering method when adhering with an adhesive by superimposing on a part of the surface direction of the corresponding material provided to correspond to the multilayer film material,
The above-mentioned adhesive is a two-component reaction type adhesive in which the chemical reaction is started by mixing the two components with the main agent and the curing agent and the viscosity starts to increase,
The viscosity of the adhesive immediately after mixing the two liquids at the time of bonding is in a low viscosity range of 150 to 1000 mPa · s at an ambient temperature of 23 ° C., and the adhesive is 5 minutes after the mixing. After a predetermined period of time, a high viscosity range of 2500 to 7000 mPa · s is obtained, and the following effects are produced.

即ち、上記接着方法により、上記多層膜材と対応材との各一部分同士を接着させる接着作業をする場合には、まず、この接着作業の開始直前に上記二液を混合して接着剤を生成する。そして、上記各一部分同士の重ね合わせ部(重ね合わせた部分と重ね合わせが予定された部分とを含む)における上記多層膜材の不織布製膜材層に上記接着剤を塗布する。   That is, in the case of performing the bonding work for bonding each part of the multilayer film material and the corresponding material by the bonding method, first, the two liquids are mixed to produce an adhesive immediately before the start of the bonding work. To do. And the said adhesive agent is apply | coated to the nonwoven fabric film-forming material layer of the said multilayer film material in the overlapping part (The part which overlapped and the part where superposition | superposition was scheduled) of each said part are included.

上記の場合、二液の混合直後における接着剤の粘度は1000mPa・s以下とされて適度に低くされたため、この接着剤は、接着作業の開始に伴い上記重ね合わせ部における不織布製膜材層の内部に円滑に浸入し始める。そして、この際、この塗布作業と不織布製膜材層の内部への上記接着剤の浸入とを、例えば雰囲気温度23℃で上記5分の所定期間内に完了させれば、上記塗布時と浸入時とに上記接着剤は上記高粘度域に達することが防止されたままで上記低粘度域に保たれることから、この接着剤は上記重ね合わせ部における不織布製膜材層の内部に円滑に浸入し、かつ、上記非通水性膜材層に達するよう上記不織布製膜材層の内部の必要範囲にわたり浸入する。そして、上記接着剤が上記非通水性膜材層に達し、上記5分の所定期間が経過した後は、上記接着剤は高粘度域に達するため、作業面が斜面である場合等での塗布作業でも、必要以上に液だれが生じることは防止される。   In the above case, since the viscosity of the adhesive immediately after the mixing of the two liquids was set to 1000 mPa · s or less and was appropriately lowered, this adhesive was used for the nonwoven fabric film-forming material layer in the overlapping portion with the start of the bonding operation. Begin to penetrate smoothly into the interior. At this time, if the coating operation and the penetration of the adhesive into the nonwoven fabric film material layer are completed within a predetermined period of 5 minutes at an atmospheric temperature of 23 ° C., for example, Since the adhesive is kept in the low viscosity region while preventing it from reaching the high viscosity region, the adhesive smoothly penetrates into the nonwoven fabric film material layer in the overlapping portion. And it penetrates over the necessary range inside the nonwoven fabric film material layer so as to reach the water impermeable film material layer. Then, after the adhesive reaches the water-impermeable membrane material layer and the predetermined period of 5 minutes elapses, the adhesive reaches a high viscosity region, so that the working surface is an inclined surface. Even during work, it is possible to prevent dripping more than necessary.

ここで、上記二液の混合直後における接着剤の粘度が仮に1000mPa・sを越えていたり、上記塗布作業が上記所定期間を越えたりすると、この接着剤は上記重ね合わせ部における不織布製膜材層の内部に円滑に浸入することが阻害されると共に、この不織布製膜材層の内部の全体にわたり浸入することが阻害されるおそれを生じる。そこで、上記したように二液の混合直後における接着剤の粘度を1000mPa・s以下としてある。   Here, if the viscosity of the adhesive immediately after the mixing of the two liquids exceeds 1000 mPa · s, or if the application operation exceeds the predetermined period, the adhesive is formed into a non-woven film-forming material layer in the overlapping portion. As a result, the smooth intrusion into the interior of the nonwoven fabric is hindered and the entire interior of the nonwoven fabric film material layer may be impeded. Therefore, as described above, the viscosity of the adhesive immediately after mixing the two liquids is set to 1000 mPa · s or less.

一方、上記混合直後における接着剤の粘度は150mPa・s以上とされて適度に高くされたため、上記重ね合わせ部における不織布製膜材層の内部に接着剤を浸入させたとき、この接着剤は、上記不織布製膜材層の内部への浸入範囲が過大になることが防止されて、上記重ね合わせ部の不織布製膜材層の内部に滞留させられる。   On the other hand, since the viscosity of the adhesive immediately after the mixing was 150 mPa · s or more and appropriately increased, when the adhesive was infiltrated into the nonwoven fabric film material layer in the overlapping portion, It is prevented that the intrusion range into the inside of the nonwoven fabric film material layer is excessive, and is retained in the nonwoven fabric film material layer of the overlapping portion.

ここで、上記二液の混合直後における接着剤の粘度が仮に 150mPa・s未満であるとすると、この接着剤は、上記重ね合わせ部における不織布製膜材層の内部への接着剤の浸入範囲が過大となって液だれが生じがちとなり、上記重ね合わせ部における不織布製膜材層の内部への滞留が阻害されるおそれを生じる。そこで、上記したように雰囲気温度が23℃での二液の混合直後における接着剤の粘度を150mPa・s以上としてある。   Here, if the viscosity of the adhesive immediately after the mixing of the two liquids is less than 150 mPa · s, this adhesive has a penetration range of the adhesive into the nonwoven fabric film material layer in the overlapping portion. If it becomes excessively large and dripping tends to occur, there is a possibility that the retention in the nonwoven fabric film material layer in the overlapped portion is hindered. Therefore, as described above, the viscosity of the adhesive immediately after mixing the two liquids at an ambient temperature of 23 ° C. is set to 150 mPa · s or more.

そして、少なくとも上記所定期間の経過以前に上記多層膜材と対応材との各一部分同士を面接触させ、この面接触状態のままで上記所定期間を経過させる。すると、上記接着剤は高粘度域に達することから、この接着剤により上記各一部分同士は所定の接着強度で接着させられ、かつ、上記した重ね合わせ部における不織布製膜材層の内部への接着剤の全体的な浸入によりその内部空間が埋められて、上記重ね合わせ部における不織布製膜材層はシール材としての働きができる。   Then, at least before the predetermined period elapses, each part of the multilayer film material and the corresponding material is brought into surface contact with each other, and the predetermined period elapses in the surface contact state. Then, since the adhesive reaches a high viscosity region, the parts are bonded to each other with a predetermined adhesive strength by the adhesive, and are bonded to the inside of the nonwoven fabric film forming material layer in the overlapped portion. The internal space is filled by the entire penetration of the agent, and the nonwoven fabric film-forming material layer in the overlapping portion can serve as a sealing material.

よって、上記多層膜材と対応材との各一部分同士が接着された上記重ね合わせ部の両外面のうち、一方の外面がわから他方の外面がわに向かって水が透過しようとしても、上記非通水性膜材層は勿論のこと、上記したように重ね合わせ部においてシール材として働く不織布製膜材層を上記水が通り抜けることは、より確実に防止される。   Therefore, even if water is about to pass from one outer surface to the other outer surface of both the outer surfaces of the overlapping portion where the multilayer film material and the corresponding material are bonded to each other, As described above, it is possible to more reliably prevent the water from passing through the non-woven membrane material layer that functions as a sealing material in the overlapping portion as well as the water-permeable membrane material layer.

そして、上記した接着剤の粘度調整によれば、接着作業をより速く進めたり、液だれ防止の作業を追加したりしないでも、上記多層膜材と対応材との上記重ね合わせ部における各一部分同士は所定の接着強度で接着されると共に、上記重ね合わせ部における不織布製膜材層はシール材として、より確実に働くことから、これら多層膜材と対応材との各一部分同士の接着作業は容易にできることとなる。   Then, according to the above-described viscosity adjustment of the adhesive, each part in the overlapping portion of the multilayer film material and the corresponding material can be obtained without proceeding the bonding work faster or adding a dripping prevention work. Is bonded with a predetermined adhesive strength, and the non-woven fabric film material layer in the overlapped portion functions more reliably as a seal material, so that it is easy to bond each part of the multilayer film material to the corresponding material. Will be able to.

請求項2の発明は、雰囲気温度23℃での上記接着剤21の主剤と硬化剤との粘度比率を1.3:1−3:1としている。   In the invention of claim 2, the viscosity ratio of the main agent and the curing agent of the adhesive 21 at an ambient temperature of 23 ° C. is set to 1.3: 1-3: 1.

このため、上記二液を混合すれば、その混合直後の接着剤の粘度を前記150−1000mPa・sにすることが、より確実にできる。   For this reason, if the two liquids are mixed, the viscosity of the adhesive immediately after the mixing can be more reliably set to 150 to 1000 mPa · s.

請求項3の発明は、上記接着剤をポリウレタン系としている。   In the invention of claim 3, the adhesive is made of polyurethane.

このため、上記ポリウレタン系の特質により、二液の混合と硬化とを常温ですることができて、この接着剤の取り扱いが容易にできる。よって、その分、上記接着作業が、より容易にできる。   For this reason, the two-component mixing and curing can be performed at room temperature due to the above-mentioned characteristics of the polyurethane system, and the handling of the adhesive can be facilitated. Therefore, the bonding operation can be facilitated accordingly.

請求項4の発明は、上記接着剤21の主剤の主成分をポリオール類とし、硬化剤の主成分をイソシアネート類とし、上記主剤と硬化剤との質量混合比を2.5:1−5:1としている。   In the invention of claim 4, the main component of the main component of the adhesive 21 is a polyol, the main component of the curing agent is an isocyanate, and the mass mixing ratio of the main component and the curing agent is 2.5: 1-5: 1 is assumed.

このため、上記した雰囲気温度23℃での上記接着剤21の主剤と硬化剤との粘度比率を維持しながら、上記した質量混合比とすれば、接着作業時の周辺温度に多少の上下変動があっても、硬化するまでの時間を実使用に耐え得る範囲に維持することが可能となる。   For this reason, if the above-mentioned mass mixing ratio is maintained while maintaining the viscosity ratio between the main agent of the adhesive 21 and the curing agent at the above-described atmospheric temperature of 23 ° C., there is some vertical fluctuation in the ambient temperature during the bonding operation. Even if it exists, it becomes possible to maintain the time until hardening in the range which can endure actual use.

請求項5の発明は、上記多層膜材と対応材との各一部分同士が互いに重ね合わされた既重ね合わせ部に対し、その外面から上記接着剤を上記所定期間内にて塗布するようにしている。。   According to a fifth aspect of the present invention, the adhesive is applied from the outer surface to the already overlapped portion in which the portions of the multilayer film material and the corresponding material are overlapped with each other within the predetermined period. . .

このため、上記所定期間内の接着剤は低粘度域にあるため、この接着剤は、上記各一部分が既重ね合わせ部であるとしても、この既重ね合わせ部における不織布製膜材層の内部に円滑にかつ十分に浸入してその内部空間が埋められる。よって、上記不織布製膜材層はシール材として確実に働くことから、上記既重ね合わせ部における不織布製膜材層を水が透過することは防止される。   For this reason, since the adhesive within the predetermined period is in a low-viscosity region, even if each of the parts is an already overlapped portion, the adhesive is placed inside the nonwoven fabric film forming material layer in the already overlapped portion. The interior space is filled with smooth and sufficient penetration. Therefore, since the said nonwoven fabric film-forming material layer acts reliably as a sealing material, it is prevented that water permeate | transmits the nonwoven fabric film-forming material layer in the said overlapping part.

廃棄物処分場の部分側面断面図である。It is a partial side sectional view of a waste disposal site. 図1の一部についての接着方法を示す図である。It is a figure which shows the adhesion | attachment method about a part of FIG. 接着作業の開始からの接着剤の経時的な粘度の変化を示すグラフ図である。It is a graph which shows the change of the viscosity of the adhesives with time from the start of the bonding operation. 図1の他部についての他の接着方法を示す図である。It is a figure which shows the other adhesion | attachment method about the other part of FIG. 図1の更に他部についての更に他の接着方法を示す図である。It is a figure which shows the further another adhesion | attachment method about the other part of FIG.

本発明の多層膜材接着方法に関し、外面に不織布製膜材層を有する多層膜材の面方向の一部分を、この多層膜材に対応するよう設けられた対応材の面方向の一部分に重ね合わせて接着剤により接着するに際し、これら多層膜材と対応材との各一部分同士の間に所定の接着強度とシール性とが得られるようにするための上記各一部分同士の接着作業が容易にできるようにする、という目的を実現するため、本発明を実施するための形態は、次の如くである。   In the multilayer film material bonding method of the present invention, a part in the surface direction of a multilayer film material having a nonwoven fabric film material layer on the outer surface is superimposed on a part in the surface direction of a corresponding material provided to correspond to the multilayer film material. When adhering with an adhesive, the above-mentioned parts can be easily bonded to each other in order to obtain a predetermined adhesive strength and sealability between the parts of the multilayer film material and the corresponding material. In order to realize the purpose of doing so, the form for carrying out the present invention is as follows.

即ち、多層膜材接着方法は、非通水性膜材層とこの非通水性膜材層の各外面に接合される一対の不織布製膜材層とを有した多層膜材の面方向の一部分を、この多層膜材に対応するよう設けられた対応材の面方向の一部分に重ね合わせて接着剤により接着するものである。   That is, in the multilayer film material bonding method, a part of the multilayer film material having a non-water-permeable film material layer and a pair of non-woven film material layers bonded to each outer surface of the non-water-permeable film material layer in the surface direction is used. In addition, it is overlapped with a part of the surface direction of the corresponding material provided so as to correspond to the multilayer film material, and is adhered by an adhesive.

上記接着剤を主剤と硬化剤とによる二液の混合により化学反応が開始されて粘性が上昇し始める二液型反応系接着剤とする。上記接着に際しての上記二液の混合直後における接着剤の粘度が、雰囲気温度23℃にて150−1000mPa・sの低粘度域となるようにし、かつ、上記接着剤が、上記混合直後から5分の所定期間経過後に2500−7000mPa・sの高粘度域となるようにする。   The above-mentioned adhesive is a two-component reaction adhesive in which a chemical reaction is started by mixing two liquids using a main agent and a curing agent and viscosity starts to increase. The viscosity of the adhesive immediately after mixing the two liquids at the time of bonding is in a low viscosity range of 150 to 1000 mPa · s at an ambient temperature of 23 ° C., and the adhesive is 5 minutes after the mixing. After a predetermined period of time elapses, a high viscosity range of 2500 to 7000 mPa · s is obtained.

本発明をより詳細に説明するために、その実施例を添付の図に従って説明する。   In order to explain the present invention in more detail, an embodiment thereof will be described with reference to the accompanying drawings.

図1において、符号1は、廃棄物2を地盤3内に埋め立て可能にするための廃棄物処分場である。この処分場1は、地盤3に形成され上方に向かって開く凹形状の廃棄物用埋立域6と、この埋立域6の内面に全体的に敷設される遮水シート7と、この遮水シート7で囲まれた遮水埋立域8に投入されてこの遮水埋立域8を埋めた廃棄物2の上面を全体的に覆うキャッピングシート9と、上記廃棄物2から発生するガス10を上記キャッピングシート9の内部から外部に排出可能とするガス抜き具11とを備えている。   In FIG. 1, reference numeral 1 is a waste disposal site for making it possible to landfill waste 2 in the ground 3. The disposal site 1 includes a concave waste landfill area 6 formed on the ground 3 and opened upward, a water shielding sheet 7 laid entirely on the inner surface of the landfill area 6, and the water shielding sheet. 7 is a capping sheet 9 which is put into the impermeable landfill area 8 surrounded by 7 and covers the entire upper surface of the waste 2 filling the impermeable landfill area 8, and the gas 10 generated from the waste 2 is capped. A degassing tool 11 that can be discharged from the inside of the sheet 9 to the outside is provided.

上記遮水シート7は、防水性に優れたポリ塩化ビニル(PVC)等の合成樹脂製のシートであり、この合成樹脂としては、ポリ塩化ビニル(PVC)の他、ポリウレタン(PU)、エチレン・酢酸ビニル共重合体(EVA)、ポリエチレン(PE)等である。なお、上記遮水シート7は、上記合成樹脂製シートの代わりにクロロプレンゴム(CR)、エチレンプロピレンゴム(EPDM)等のゴム製のシートであってもよい。   The water shielding sheet 7 is a sheet made of synthetic resin such as polyvinyl chloride (PVC) having excellent waterproof properties. As this synthetic resin, in addition to polyvinyl chloride (PVC), polyurethane (PU), ethylene Examples thereof include vinyl acetate copolymer (EVA) and polyethylene (PE). The water shielding sheet 7 may be a rubber sheet such as chloroprene rubber (CR) or ethylene propylene rubber (EPDM) instead of the synthetic resin sheet.

上記キャッピングシート9は、ほぼ水平な方向に向かって互いに並設される複数枚の多層膜材15で構成される。これら各多層膜材15は、それぞれ水の通過を防止する非通水性膜材層16と、この非通水性膜材層16の各外面に接合される一対の不織布製膜材層17,17とを有している。   The capping sheet 9 is composed of a plurality of multilayer film materials 15 arranged in parallel to each other in a substantially horizontal direction. Each of these multilayer film materials 15 includes a non-water-permeable film material layer 16 that prevents passage of water, and a pair of non-woven film material layers 17 and 17 that are joined to the respective outer surfaces of the non-water-permeable film material layer 16. have.

上記非通水性膜材層16は、雨水や汚水など水の通過を防止する一方、廃棄物2から発生する各種ガスや水蒸気を透過可能とする通気性を有する多孔質フィルム(孔径:100μm)であり、厚さは0.1mm程度である。上記非通水性膜材層16の材質は、ポリエチレン、ポリプロピレンなどのポリオレフィン樹脂、ポリテトラフルオロエチレン、もしくはポリフッ化ビニリデンなどである。なお、透湿度は、非通水性と通気性とを共に効果的に発揮する上で、1000〜10000g/m・24hrであることが好ましい。 The non-water-permeable membrane material layer 16 is a porous film (pore diameter: 100 μm) having air permeability that allows passage of various gases and water vapor generated from the waste 2 while preventing the passage of water such as rainwater and sewage. Yes, the thickness is about 0.1 mm. The material of the water impermeable membrane material layer 16 is a polyolefin resin such as polyethylene or polypropylene, polytetrafluoroethylene, or polyvinylidene fluoride. The moisture permeability is preferably 1000 to 10000 g / m 2 · 24 hr in order to effectively exhibit both non-water permeability and air permeability.

上記不織布製膜材層17は、通水性、通気性を有する一方、優れたクッション性を有することにより、上記非通水性膜材層16の非通水性、通気性を阻害することなく、何らかの外力に因る非通水性膜材層16の損傷を防止する保護材として働く。上記不織布製膜材層17の繊維は、外筒部(鞘)とこの外筒部に内装される内装部(芯部)とで構成される複合繊維(300g/m)であり、この場合、上記外筒部がポリエチレン(融点125℃)とされ、上記内装部がポリエチレンテレフタレート(融点260℃)などのポリエステルとされて、優れた熱溶着性を有している。なお、上記不織布製膜材層17は、1種の繊維によって構成されるものであってもよく、単相繊維や断面形態等が異なる繊維により構成されるものであってもよい。 The nonwoven fabric membrane material layer 17 has water permeability and air permeability, while having excellent cushioning properties, so that it does not impair the water permeability and air permeability of the water impermeable membrane material layer 16 without any external force. It acts as a protective material for preventing damage to the non-water-permeable membrane material layer 16 due to the above. The fiber of the non-woven fabric film material layer 17 is a composite fiber (300 g / m 2 ) composed of an outer cylinder part (sheath) and an interior part (core part) built in the outer cylinder part. The outer cylinder portion is made of polyethylene (melting point: 125 ° C.), and the interior portion is made of polyester such as polyethylene terephthalate (melting point: 260 ° C.), and has excellent heat weldability. In addition, the said nonwoven fabric film material layer 17 may be comprised by 1 type of fiber, and may be comprised by the fiber from which a single phase fiber, a cross-sectional form, etc. differ.

そして、隣り合う両多層膜材15,15のそれぞれ面方向の一部分15aであって、互いに対向する端縁部同士が上下に重ね合わされて接着剤21により接着されることにより、上記キャッピングシート9が形成される。なお、上記両多層膜材15,15のうち、いずれか一方の多層膜材15は、他方の多層膜材15に対応するよう設けられた対応材22に相当し、上記一方の多層膜材15の一部分15aは、上記対応材22の面方向の一部分22aに相当する。   Then, the capping sheet 9 is a part 15a in the surface direction of each of the adjacent multilayer film materials 15 and 15, and the edge portions facing each other are vertically overlapped and bonded with an adhesive 21. It is formed. One of the multilayer film materials 15 and 15 corresponds to the corresponding material 22 provided so as to correspond to the other multilayer film material 15, and the one multilayer film material 15. The portion 15a corresponds to a portion 22a in the surface direction of the corresponding material 22.

上記接着剤21は、主剤であるA液と、硬化剤であるB液との二液の混合により化学反応が開始されて粘性が上昇し始める二液型反応系接着剤とされる。上記接着剤21の二液はポリウレタン系とされる。具体的には、上記A液の主成分がポリオール類とされ、B液の主成分がイソシアネート類とされる。   The adhesive 21 is a two-component reaction type adhesive in which a chemical reaction is started and viscosity starts to increase by mixing two liquids of a liquid A as a main agent and a liquid B as a curing agent. Two liquids of the adhesive 21 are made of polyurethane. Specifically, the main component of the liquid A is a polyol, and the main component of the liquid B is an isocyanate.

上記A液の粘度はほぼ260mPa・sとされ、B液の粘度はほぼ140mPa・sとされるが、A:Bの粘度比率は1.3:1−3:1であることが好ましい。   The viscosity of the liquid A is approximately 260 mPa · s and the viscosity of the liquid B is approximately 140 mPa · s, but the viscosity ratio of A: B is preferably 1.3: 1-3: 1.

上記両多層膜材15,15(多層膜材15および対応材22)の各一部分15a,15a(一部分15a,22a)同士の接着剤21による接着方法につき説明する。   A method for bonding the parts 15a and 15a (parts 15a and 22a) of the multilayer films 15 and 15 (the multilayer film material 15 and the corresponding material 22) with the adhesive 21 will be described.

図2において、上記接着方法に用いられる接着剤21の二液混合供給装置25は、高圧吐出ポンプ26と、A,Bの各液を個別に充填し、上記吐出ポンプ26のハウジングに着脱可能に取り付けられるカートリッジ式の液タンク27,27と、上記吐出ポンプ26から延出する高圧ホース28の先端に取り付けられ、上記吐出ポンプ26から吐出される二液を混合するスタティックミキサー29と、このスタティックミキサー29の吐出側に取り付けられ、このスタティックミキサー29で混合されて生成された接着剤21を所定断面形状で吐出するノズル30とを備えている。   In FIG. 2, the two-component mixed supply device 25 for the adhesive 21 used in the bonding method is filled with the high-pressure discharge pump 26 and the liquids A and B individually, and is detachable from the housing of the discharge pump 26. The cartridge type liquid tanks 27 and 27 to be attached, the static mixer 29 attached to the tip of the high pressure hose 28 extending from the discharge pump 26, and mixing the two liquids discharged from the discharge pump 26, and the static mixer 29 and a nozzle 30 for discharging the adhesive 21 produced by mixing with the static mixer 29 in a predetermined cross-sectional shape.

上記接着に際しての上記混合供給装置25による二液の混合直後における接着剤21の粘度は、雰囲気温度23℃にて150−1000mPa・sの低粘度域とされる(図3中、3分未満)。また、この接着剤21は、上記混合直後から5分の所定期間経過後に2500−7000mPa・sの高粘度域になるものとされる(図3中、5分経過時)。   The viscosity of the adhesive 21 immediately after the mixing of the two liquids by the mixing and feeding device 25 at the time of bonding is a low viscosity region of 150 to 1000 mPa · s at an ambient temperature of 23 ° C. (less than 3 minutes in FIG. 3). . In addition, the adhesive 21 is in a high viscosity range of 2500 to 7000 mPa · s after a predetermined period of 5 minutes immediately after mixing (when 5 minutes have elapsed in FIG. 3).

図2において、上記両多層膜材15,15(多層膜材15と対応材22と)の各一部分15a,15a(一部分15a,22a)同士を接着させる接着作業をする場合には、まず、この接着作業の開始直前に上記混合供給装置25の作動により上記二液を混合して接着剤21を生成し、この接着剤21を上記ノズル30から吐出させる。そして、上記各一部分15a,15a(一部分15a,22a)同士の重ね合わせ部33における上記両多層膜材15の各不織布製膜材層17,17に上記接着剤21をそれぞれ塗布する。   In FIG. 2, when the bonding work for bonding the parts 15a and 15a (parts 15a and 22a) of the multilayer film materials 15 and 15 (the multilayer film material 15 and the corresponding material 22) is first performed, Immediately before the start of the bonding operation, the two liquids are mixed by the operation of the mixing and feeding device 25 to generate an adhesive 21, and the adhesive 21 is discharged from the nozzle 30. And the said adhesive agent 21 is each apply | coated to each nonwoven fabric film material layer 17 and 17 of the said multilayer film material 15 in the overlapping part 33 of said each part 15a, 15a (part 15a, 22a).

上記の場合、二液の混合直後における接着剤21の粘度は1000mPa・s以下とされて適度に低くされたため、この接着剤21は、接着作業の開始に伴い上記重ね合わせ部33における不織布製膜材層17の内部に円滑に浸入し始める。そして、この際、この塗布作業と不織布製膜材層17の内部への上記接着剤21の浸入とを、例えば雰囲気温度23℃で上記5分の所定期間内に完了させれば、上記塗布時と浸入時とに上記接着剤21は上記高粘度域に達することが防止されたままで上記低粘度域に保たれることから、この接着剤21は上記重ね合わせ部33における各不織布製膜材層17の内部に円滑に浸入し、かつ、上記非通水性膜材層16に達するよう上記各不織布製膜材層17の内部の必要範囲にわたり浸入する。そして、上記接着剤21が上記非通水性膜材層に達し、上記5分の所定期間が経過した後は、上記接着剤21は高粘度域に達するため、作業面が斜面である場合等での塗布作業でも、必要以上に液だれが生じることは防止される。   In the above case, since the viscosity of the adhesive 21 immediately after mixing the two liquids is set to 1000 mPa · s or less and is appropriately lowered, the adhesive 21 is formed into a nonwoven fabric film in the overlapping portion 33 with the start of the bonding operation. It begins to penetrate smoothly into the material layer 17. At this time, if the coating operation and the penetration of the adhesive 21 into the nonwoven fabric film material layer 17 are completed within a predetermined period of 5 minutes at an ambient temperature of 23 ° C., for example, The adhesive 21 is kept in the low viscosity region while preventing the adhesive 21 from reaching the high viscosity region at the time of intrusion. It smoothly penetrates into the interior of the non-water-permeable membrane material layer 16 and penetrates over the necessary range inside each non-woven membrane material layer 17. And after the said adhesive agent 21 reaches the said water-impermeable membrane material layer and the said 5 minute predetermined period passes, since the said adhesive agent 21 reaches a high-viscosity area, when the work surface is a slope etc. Even in the coating operation, it is possible to prevent dripping of the liquid more than necessary.

ここで、上記二液の混合直後における接着剤21の粘度が仮に1000mPa・sを越えていたり、上記塗布作業が上記所定期間を越えたりすると、この接着剤21は上記重ね合わせ部33における各不織布製膜材層17の内部に円滑に浸入することが阻害されると共に、これら不織布製膜材層17の内部の全体にわたり浸入することが阻害されるおそれを生じる。そこで、上記したように二液の混合直後における接着剤21の粘度を1000mPa・s以下としてある。   Here, if the viscosity of the adhesive 21 immediately after the mixing of the two liquids exceeds 1000 mPa · s, or if the application operation exceeds the predetermined period, the adhesive 21 will be applied to each non-woven fabric in the overlapping portion 33. Intrusion into the inside of the film-forming material layer 17 is hindered, and intrusion over the entire inside of the non-woven film-forming material layer 17 may be hindered. Therefore, as described above, the viscosity of the adhesive 21 immediately after mixing the two liquids is set to 1000 mPa · s or less.

一方、上記混合直後における接着剤21の粘度は150mPa・s以上とされて適度に高くされたため、上記重ね合わせ部33における不織布製膜材層17の内部に接着剤21を浸入させたとき、この接着剤21は、上記不織布製膜材層17の内部への浸入範囲が過大になることが防止されて、上記重ね合わせ部33の不織布製膜材層17の内部に滞留させられる。   On the other hand, since the viscosity of the adhesive 21 immediately after the mixing is set to 150 mPa · s or more and is appropriately high, when the adhesive 21 is infiltrated into the nonwoven fabric film material layer 17 in the overlapping portion 33, The adhesive 21 is prevented from being excessively penetrated into the nonwoven fabric film material layer 17, and is retained in the nonwoven fabric film material layer 17 of the overlapping portion 33.

ここで、上記二液の混合直後における接着剤21の粘度が仮に150mPa・s未満であるとすると、この接着剤21は、上記重ね合わせ部33における不織布製膜材層17の内部への接着剤21の浸入範囲が過大となって液だれが生じがちとなり、上記重ね合わせ部33における不織布製膜材層17の内部への滞留が阻害されるおそれを生じる。そこで、上記したように雰囲気温度23℃での二液の混合直後における接着剤21の粘度を150mPa・s以上としてある。なお、この粘度は200mPa・s以上とすることがより好ましく、このようにすれば、接着作業時の雰囲気温度が高温となった場合における液だれの防止効果をより高めることが可能となる。   Here, assuming that the viscosity of the adhesive 21 immediately after the mixing of the two liquids is less than 150 mPa · s, the adhesive 21 is an adhesive to the inside of the nonwoven fabric film material layer 17 in the overlapping portion 33. The intrusion range of 21 tends to be excessive and dripping tends to occur, and the retention of the nonwoven fabric film material layer 17 in the overlapping portion 33 may be hindered. Therefore, as described above, the viscosity of the adhesive 21 immediately after mixing the two liquids at the atmospheric temperature of 23 ° C. is set to 150 mPa · s or more. The viscosity is more preferably 200 mPa · s or more, and in this way, it is possible to further enhance the effect of preventing dripping when the atmospheric temperature during the bonding operation becomes high.

そして、少なくとも上記所定期間の経過以前に上記両多層膜材15,15(多層膜材15と対応材22と)の各一部分15a,15a(一部分15a,22a)同士を面接触させ、この面接触状態のままで上記所定期間を経過させる。すると、上記接着剤21は高粘度域に達することから、この接着剤21により上記各一部分15a,15a(一部分15a,22a)同士は所定の接着強度で接着させられ、かつ、上記した重ね合わせ部33における不織布製膜材層17の内部への接着剤21の全体的な浸入によりその内部空間が埋められて、上記重ね合わせ部33における不織布製膜材層17はシール材としての働きができる。   Then, at least before the passage of the predetermined period, the parts 15a and 15a (parts 15a and 22a) of the multilayer films 15 and 15 (the multilayer film material 15 and the corresponding material 22) are brought into surface contact with each other, and the surface contact is performed. The predetermined period elapses in the state. Then, since the adhesive 21 reaches a high viscosity region, the parts 21a and 15a (parts 15a and 22a) are bonded to each other with a predetermined adhesive strength by the adhesive 21, and the overlapping portion described above is used. The inner space is filled by the entire penetration of the adhesive 21 into the nonwoven fabric film material layer 17 in 33, and the nonwoven fabric film material layer 17 in the overlapping portion 33 can serve as a sealing material.

よって、上記両多層膜材15,15(多層膜材15と対応材22と)の各一部分15a,15a(一部分15a,22a)同士が接着された上記重ね合わせ部33の両外面のうち、一方の外面がわから他方の外面がわに向かって水が透過しようとしても、上記非通水性膜材層16は勿論のこと、上記したように重ね合わせ部33においてシール材として働く不織布製膜材層17を上記水が通り抜けることは、より確実に防止される。   Therefore, one of the outer surfaces of the overlapping portion 33 where the portions 15a and 15a (the portions 15a and 22a) of the multilayer film materials 15 and 15 (the multilayer film material 15 and the corresponding material 22) are bonded to each other. The non-woven membrane material layer that acts as a sealing material at the overlapping portion 33 as well as the water-impermeable membrane material layer 16 as well as the water-impermeable membrane material layer 16 as described above, even if water is transmitted from the outer surface to the other outer surface. The passage of the water through 17 is more reliably prevented.

この結果、上記したように両多層膜材15,15の各一部分15a,15a同士を重ね合わせ部33で接着させることにより、全体として面積の大きい平坦膜材を形成すれば、この平坦膜材は廃棄物処分場1において特に防水性と通気性とが強く要求されるキャッピングシート9などに有効に適用できる。   As a result, if the flat film material having a large area as a whole is formed by adhering the portions 15a and 15a of the multilayer film materials 15 and 15 to each other at the overlapping portion 33 as described above, the flat film material is In the waste disposal site 1, it can be effectively applied to the capping sheet 9 and the like that are particularly required to be waterproof and breathable.

そして、上記した接着剤21の粘度調整によれば、接着作業をより速く進めたり、液だれ防止の作業を追加したりしないでも、上記重ね合わせ部33における両多層膜材15,15(多層膜材15と対応材22と)の各一部分15a,15a(一部分15a,22a)同士は所定の接着強度で接着されると共に、上記重ね合わせ部33における不織布製膜材層17はシール材として、より確実に働くことから、これら両多層膜材15,15(多層膜材15および対応材22)の各一部分15a,15a(一部分15a,22a)同士の接着作業は容易にできることとなる。   According to the above-described adjustment of the viscosity of the adhesive 21, both the multilayer film materials 15 and 15 (multilayer film) in the overlapping portion 33 can be obtained without proceeding the bonding work faster or adding a dripping prevention work. Each of the portions 15a and 15a (parts 15a and 22a) of the material 15 and the corresponding material 22 is bonded to each other with a predetermined adhesive strength, and the non-woven fabric film material layer 17 in the overlapping portion 33 is used as a sealing material. Since it works reliably, the bonding work between the portions 15a and 15a (the portions 15a and 22a) of both the multilayer film materials 15 and 15 (the multilayer film material 15 and the corresponding material 22) can be easily performed.

なお、上記接着作業に際し、両多層膜材15,15の各一部分15a,15a同士が既に重ね合わされた既重ね合わせ部33において、互いに対面する両不織布製膜材層17,17に接着剤21を塗布する場合には、上記既重ね合わせ部33におけるいずれか一方の不織布製膜材層17、もしくは両方の不織布製膜材層17の面方向での外端縁部の外方から接着剤21を塗布して、この接着剤21の一部もしくは全部を上記各不織布製膜材層17に全体的に浸入させるようにしてもよい。この場合、上記既重ね合わせ部33は、互いに対面する両不織布製膜材層17,17が単に重ね合わされているだけのものであってもよく、互いに対面する両不織布製膜材層17,17の両対向面が上記接着剤21やこれとは異種の各種接着剤、および/もしくは熱溶着などにより既に接合されているものであってもよい。   In addition, in the bonding operation, the adhesive 21 is applied to the two nonwoven fabric film material layers 17 and 17 facing each other in the already overlapped portion 33 in which the portions 15a and 15a of the multilayer film materials 15 and 15 are already overlapped with each other. In the case of applying, the adhesive 21 is applied from the outside of the outer edge portion in the surface direction of one of the nonwoven fabric film material layers 17 in the above-described overlapped portion 33 or both the nonwoven fabric film material layers 17. It may be applied so that a part or all of the adhesive 21 is totally infiltrated into each of the nonwoven fabric film material layers 17. In this case, the overlapped portion 33 may be a structure in which the nonwoven fabric film material layers 17 and 17 facing each other are simply superimposed, and the nonwoven fabric film material layers 17 and 17 facing each other. These opposing surfaces may be already joined by the adhesive 21 or various adhesives different from this and / or heat welding.

また、上記接着剤21の塗布は、手動ガンのハンドル操作で二液を混合させながら行うようにしてもよく、ハケ塗りによるものであってもよい。   Further, the application of the adhesive 21 may be performed while mixing the two liquids by operating the handle of a manual gun, or by brushing.

また、前記したように、雰囲気温度23℃での上記接着剤21の主剤と硬化剤との粘度比率を1.3:1−3:1としている。   Further, as described above, the viscosity ratio between the main agent and the curing agent of the adhesive 21 at an ambient temperature of 23 ° C. is set to 1.3: 1-3: 1.

このため、上記二液を混合すれば、その混合直後の接着剤21の粘度を前記150−1000mPa・sにすることが、より確実にできる。   For this reason, if the two liquids are mixed, the viscosity of the adhesive 21 immediately after the mixing can be more reliably set to 150 to 1000 mPa · s.

また、前記したように、上記接着剤21の二液をポリウレタン系としている。   As described above, the two liquids of the adhesive 21 are made of polyurethane.

このため、上記ポリウレタン系の特質により、二液の混合と硬化とを常温ですることができて、この接着剤21の取り扱いが容易にできる。よって、その分、上記接着作業が、より容易にできる。   For this reason, the two-component mixing and curing can be performed at room temperature due to the above-mentioned characteristics of the polyurethane system, and the adhesive 21 can be easily handled. Therefore, the bonding operation can be facilitated accordingly.

また、前記したように、上記接着剤21の主剤の主成分をポリオール類とし、硬化剤の主成分をイソシアネート類とし、上記主剤と硬化剤との質量混合比を2.5:1−5:1としている。   Further, as described above, the main component of the main component of the adhesive 21 is a polyol, the main component of the curing agent is an isocyanate, and the mass mixing ratio of the main component and the curing agent is 2.5: 1-5: 1 is assumed.

このため、上記した雰囲気温度23℃での上記接着剤21の主剤と硬化剤との粘度比率を維持しながら、上記した質量混合比とすれば、接着作業時の周辺温度に多少の上下変動があっても、硬化するまでの時間を実使用に耐え得る範囲に維持することが可能となる。   For this reason, if the above-mentioned mass mixing ratio is maintained while maintaining the viscosity ratio between the main agent of the adhesive 21 and the curing agent at the above-described atmospheric temperature of 23 ° C., there is some vertical fluctuation in the ambient temperature during the bonding operation. Even if it exists, it becomes possible to maintain the time until hardening in the range which can endure actual use.

また、前記したように、上記多層膜材15と対応材22との各一部分15a,22a同士が互いに重ね合わされた既重ね合わせ部33に対し、その外面から上記接着剤21を上記所定期間内にて塗布するようにしている。   Further, as described above, the adhesive 21 is applied from the outer surface to the overlapped portion 33 in which the portions 15a and 22a of the multilayer film material 15 and the corresponding material 22 are overlapped with each other within the predetermined period. To be applied.

このため、上記所定期間内の接着剤21は低粘度域にあるため、この接着剤21は、上記各一部分15a,22aが既重ね合わせ部33であるとしても、この既重ね合わせ部33における不織布製膜材層17の内部に円滑にかつ十分に浸入してその内部空間が埋められる。よって、上記不織布製膜材層17はシール材として確実に働くことから、上記既重ね合わせ部33における不織布製膜材層17を水が透過することは防止される。   For this reason, since the adhesive 21 within the predetermined period is in a low-viscosity region, the adhesive 21 is a nonwoven fabric in the overlapped portion 33 even though the portions 15a and 22a are the overlapped portions 33. The film forming material layer 17 is smoothly and sufficiently infiltrated to fill the internal space. Therefore, since the said nonwoven fabric film-forming material layer 17 acts reliably as a sealing material, it is prevented that water permeate | transmits the nonwoven fabric film-forming material layer 17 in the said overlapping part 33. FIG.

図4において、前記ガス抜き具11は、上記キャッピングシート9の多層膜材15に形成されたガス抜き開口36と、このガス抜き開口36の開口縁部の外面に締結具37により接合されたフランジ38と、このフランジ38に一端部が結合されるガス抜きパイプ39とを有している。この場合、多層膜材15に形成されたガス抜き開口36の開口縁部が多層膜材15の一部分15aに相当し、上記ガス抜き具11のフランジ38が上記対応材22の一部分22aに相当する。   In FIG. 4, the degassing tool 11 includes a degassing opening 36 formed in the multilayer film material 15 of the capping sheet 9 and a flange joined to the outer surface of the opening edge of the degassing opening 36 by a fastener 37. 38 and a gas vent pipe 39 having one end coupled to the flange 38. In this case, the opening edge portion of the gas vent opening 36 formed in the multilayer film material 15 corresponds to a part 15 a of the multilayer film material 15, and the flange 38 of the gas vent tool 11 corresponds to a part 22 a of the corresponding material 22. .

そして、上記ガス抜き開口36の開口縁部と、これに重ね合わされる上記フランジ38の外縁部との既重ね合わせ部33における不織布製膜材層17に、上記混合供給装置25のノズル30から吐出される接着剤21が塗布される。すると、この接着剤21は上記不織布製膜材層17に浸入して、上記ガス抜き開口36の開口縁部とフランジ38の外縁部とが上記接着剤21により接着される。   And it discharges from the nozzle 30 of the said mixing supply apparatus 25 to the nonwoven fabric film-forming material layer 17 in the already overlapped part 33 of the opening edge part of the said gas vent opening 36, and the outer edge part of the said flange 38 overlapped with this. The adhesive 21 to be applied is applied. Then, the adhesive 21 enters the nonwoven fabric film material layer 17, and the opening edge of the gas vent opening 36 and the outer edge of the flange 38 are bonded together by the adhesive 21.

また、上記キャッピングシート9の多層膜材15には修理のためや損傷などにより生じた開口42が形成されており、この開口42を塞ぐカバー材(パッチ)43が設けられ、このカバー材43は上記多層膜材15と同構成とされている。この場合、上記多層膜材15に形成された開口42の開口縁部が多層膜材15の一部分15aに相当し、上記カバー材43の外縁部が上記対応材22の一部分22aに相当する。   Further, the multilayer film material 15 of the capping sheet 9 is provided with an opening 42 generated for repair or damage, and a cover material (patch) 43 for closing the opening 42 is provided. The multilayer film material 15 has the same configuration. In this case, the opening edge portion of the opening 42 formed in the multilayer film material 15 corresponds to a portion 15 a of the multilayer film material 15, and the outer edge portion of the cover material 43 corresponds to a portion 22 a of the corresponding material 22.

そして、上記開口42の開口縁部と、これに重ね合わされる上記カバー材43の外縁部とが接着剤21により接着される。   Then, the opening edge portion of the opening 42 and the outer edge portion of the cover material 43 superimposed on the opening 42 are bonded by the adhesive 21.

なお、上記カバー材43は、上記遮水シート7と同構成であってもよく、金属板であってもよい。   In addition, the said cover material 43 may be the same structure as the said water shielding sheet 7, and a metal plate may be sufficient as it.

図5において、上記キャッピングシート9を形成するよう少なくとも三枚の多層膜材15が互いに並設されている。これら多層膜材15が互いに対向する端縁部である各一部分15aが三枚重ねの重ね合わせ部33とされる。この場合、この重ね合わせ部33の三枚重ねの上下方向の中央に位置するものが多層膜材15の一部分15aに相当し、他の多層膜材15の一部分15aがそれぞれ上記対応材22の一部分22aに相当することとされる。   In FIG. 5, at least three multilayer films 15 are juxtaposed to form the capping sheet 9. Each part 15a which is an edge part which these multilayer film materials 15 mutually oppose is made into the superposition part 33 of 3 sheets pile. In this case, the one located in the center in the vertical direction of the three overlapping layers of the overlapping portion 33 corresponds to a part 15a of the multilayer film material 15, and a part 15a of the other multilayer film material 15 is a part of the corresponding material 22, respectively. It corresponds to 22a.

そして、上記重ね合わせ部33における各不織布製膜材層17に上記混合供給装置25のノズル30から吐出される接着剤21が塗布される。すると、この接着剤21は上記不織布製膜材層17の内部にそれぞれ浸入して、この重ね合わせ部33の各多層膜材15の一部分15aが上記接着剤21により互いに接着され、かつ、上記各不織布製膜材層17はシール材として働く。   And the adhesive agent 21 discharged from the nozzle 30 of the said mixing supply apparatus 25 is apply | coated to each nonwoven fabric film forming material layer 17 in the said superimposition part 33. FIG. Then, the adhesive 21 penetrates into the nonwoven fabric film material layer 17, and the portions 15 a of the multilayer film materials 15 of the overlapping portion 33 are bonded to each other by the adhesive 21, and The nonwoven fabric film material layer 17 serves as a sealing material.

なお、上記実施例における各部分の構成を、本発明の目的、作用効果に照らして種々組み合せてもよい。   In addition, you may combine the structure of each part in the said Example in light of the objective and effect of this invention.

1 処分場
2 廃棄物
3 地盤
6 埋立域
7 遮水シート
8 遮水埋立域
9 キャッピングシート
10 ガス
11 ガス抜き具
15 多層膜材
15a 一部分
16 非通水性膜材層
17 不織布製膜材層
21 接着剤
22 対応材
22a 一部分
33 重ね合わせ部
DESCRIPTION OF SYMBOLS 1 Disposal site 2 Waste 3 Ground 6 Landfill area 7 Impermeable sheet 8 Impermeable landfill area 9 Capping sheet 10 Gas 11 Degassing tool 15 Multilayer film material 15a Part 16 Non-water-permeable film material layer 17 Nonwoven fabric film material layer 21 Adhesion Agent 22 Corresponding material 22a Part 33 Overlapping part

Claims (5)

非通水性膜材層とこの非通水性膜材層の各外面に接合される一対の不織布製膜材層とを有した多層膜材の面方向の一部分を、この多層膜材に対応するよう設けられた対応材の面方向の一部分に重ね合わせて接着剤により接着する際の多層膜材接着方法であって、
上記接着剤を主剤と硬化剤とによる二液の混合により化学反応が開始されて粘性が上昇し始める二液型反応系接着剤とし、
上記接着に際しての上記二液の混合直後における接着剤の粘度が、雰囲気温度23℃にて150−1000mPa・sの低粘度域となるようにし、かつ、上記接着剤が、上記混合直後から5分の所定期間経過後に2500−7000mPa・sの高粘度域となるようにしたことを特徴とする多層膜材接着方法。
A part in the surface direction of a multilayer film material having a non-water-permeable film material layer and a pair of non-woven film material layers bonded to the respective outer surfaces of the non-water-permeable film material layer corresponds to the multilayer film material. A multilayer film material adhering method for adhering with a part of a surface of a corresponding material provided and adhering with an adhesive,
The above-mentioned adhesive is a two-component reaction type adhesive in which the chemical reaction is started by mixing the two components with the main agent and the curing agent and the viscosity starts to increase,
The viscosity of the adhesive immediately after mixing the two liquids at the time of bonding is in a low viscosity range of 150 to 1000 mPa · s at an ambient temperature of 23 ° C., and the adhesive is 5 minutes after the mixing. A multilayer film material adhering method, wherein a high viscosity range of 2500 to 7000 mPa · s is obtained after a predetermined period of time elapses.
雰囲気温度23℃での上記接着剤の主剤と硬化剤との粘度比率を1.3:1−3:1としたことを特徴とする請求項1に記載の多層膜材接着方法。   2. The multilayer film material bonding method according to claim 1, wherein a viscosity ratio of the main agent and the curing agent of the adhesive at an ambient temperature of 23 ° C. is set to 1.3: 1-3: 1. 上記接着剤をポリウレタン系としたことを特徴とする請求項2に記載の多層膜材接着方法。   The multilayer film material bonding method according to claim 2, wherein the adhesive is made of polyurethane. 上記接着剤の主剤の主成分をポリオール類とし、硬化剤の主成分をイソシアネート類とし、上記主剤と硬化剤との質量混合比を2.5:1−5:1としたことを特徴とする請求項2に記載の多層膜材接着方法。   The main component of the main agent of the adhesive is a polyol, the main component of the curing agent is an isocyanate, and the mass mixing ratio of the main agent and the curing agent is 2.5: 1-5: 1. The multilayer film material adhesion method according to claim 2. 上記多層膜材と対応材との各一部分同士が互いに重ね合わされた既重ね合わせ部に対し、その外面から上記接着剤を上記所定期間内にて塗布するようにしたことを特徴とする請求項1から4のうちいずれか1つに記載の多層膜材接着方法。   2. The adhesive is applied from the outer surface to the already overlapped portion in which each part of the multilayer film material and the corresponding material is overlapped with each other within the predetermined period. 5. The multilayer film material adhesion method according to any one of items 1 to 4.
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