JP2015508332A - 二種類の塩に基づく熱分解プロセスを伴う二酸化炭素の隔離 - Google Patents
二種類の塩に基づく熱分解プロセスを伴う二酸化炭素の隔離 Download PDFInfo
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- JP2015508332A JP2015508332A JP2014552337A JP2014552337A JP2015508332A JP 2015508332 A JP2015508332 A JP 2015508332A JP 2014552337 A JP2014552337 A JP 2014552337A JP 2014552337 A JP2014552337 A JP 2014552337A JP 2015508332 A JP2015508332 A JP 2015508332A
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- 238000000034 method Methods 0.000 title claims abstract description 316
- 230000008569 process Effects 0.000 title claims abstract description 233
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 title claims abstract description 110
- 229910002092 carbon dioxide Inorganic materials 0.000 title claims abstract description 55
- 239000001569 carbon dioxide Substances 0.000 title claims abstract description 54
- 150000003839 salts Chemical class 0.000 title abstract description 58
- 230000009919 sequestration Effects 0.000 title abstract description 13
- 238000000197 pyrolysis Methods 0.000 title abstract 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 184
- 229910001868 water Inorganic materials 0.000 claims abstract description 173
- TWRXJAOTZQYOKJ-UHFFFAOYSA-L Magnesium chloride Chemical compound [Mg+2].[Cl-].[Cl-] TWRXJAOTZQYOKJ-UHFFFAOYSA-L 0.000 claims abstract description 25
- 229910001629 magnesium chloride Inorganic materials 0.000 claims abstract description 10
- 229910001576 calcium mineral Inorganic materials 0.000 claims abstract description 3
- 238000006243 chemical reaction Methods 0.000 claims description 199
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims description 166
- 239000003546 flue gas Substances 0.000 claims description 128
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 claims description 125
- IXCSERBJSXMMFS-UHFFFAOYSA-N hydrogen chloride Substances Cl.Cl IXCSERBJSXMMFS-UHFFFAOYSA-N 0.000 claims description 119
- 229910000041 hydrogen chloride Inorganic materials 0.000 claims description 119
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 70
- 239000011575 calcium Substances 0.000 claims description 64
- 239000000203 mixture Substances 0.000 claims description 64
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- 239000007787 solid Substances 0.000 claims description 35
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- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 claims description 23
- 239000000378 calcium silicate Substances 0.000 claims description 22
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- OYACROKNLOSFPA-UHFFFAOYSA-N calcium;dioxido(oxo)silane Chemical compound [Ca+2].[O-][Si]([O-])=O OYACROKNLOSFPA-UHFFFAOYSA-N 0.000 claims description 22
- 229910052610 inosilicate Inorganic materials 0.000 claims description 20
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- NWXHSRDXUJENGJ-UHFFFAOYSA-N calcium;magnesium;dioxido(oxo)silane Chemical compound [Mg+2].[Ca+2].[O-][Si]([O-])=O.[O-][Si]([O-])=O NWXHSRDXUJENGJ-UHFFFAOYSA-N 0.000 claims description 14
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- ASTZLJPZXLHCSM-UHFFFAOYSA-N dioxido(oxo)silane;manganese(2+) Chemical compound [Mn+2].[O-][Si]([O-])=O ASTZLJPZXLHCSM-UHFFFAOYSA-N 0.000 claims description 3
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- BVKZGUZCCUSVTD-UHFFFAOYSA-M Bicarbonate Chemical compound OC([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-M 0.000 description 28
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- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 12
- WYTGDNHDOZPMIW-RCBQFDQVSA-N alstonine Natural products C1=CC2=C3C=CC=CC3=NC2=C2N1C[C@H]1[C@H](C)OC=C(C(=O)OC)[C@H]1C2 WYTGDNHDOZPMIW-RCBQFDQVSA-N 0.000 description 12
- 150000001875 compounds Chemical class 0.000 description 12
- ZLNQQNXFFQJAID-UHFFFAOYSA-L magnesium carbonate Chemical compound [Mg+2].[O-]C([O-])=O ZLNQQNXFFQJAID-UHFFFAOYSA-L 0.000 description 12
- 239000002244 precipitate Substances 0.000 description 12
- 229910020091 MgCa Inorganic materials 0.000 description 11
- 101100003996 Mus musculus Atrn gene Proteins 0.000 description 11
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 11
- 229910052801 chlorine Inorganic materials 0.000 description 11
- 239000001095 magnesium carbonate Substances 0.000 description 11
- 235000014380 magnesium carbonate Nutrition 0.000 description 11
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- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 9
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- 230000018044 dehydration Effects 0.000 description 9
- 239000000706 filtrate Substances 0.000 description 9
- VTHJTEIRLNZDEV-UHFFFAOYSA-L magnesium dihydroxide Chemical compound [OH-].[OH-].[Mg+2] VTHJTEIRLNZDEV-UHFFFAOYSA-L 0.000 description 9
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Classifications
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- B01D53/34—Chemical or biological purification of waste gases
- B01D53/46—Removing components of defined structure
- B01D53/62—Carbon oxides
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- C01B32/60—Preparation of carbonates or bicarbonates in general
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- C—CHEMISTRY; METALLURGY
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- C01F5/00—Compounds of magnesium
- C01F5/24—Magnesium carbonates
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- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
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- B01D2251/402—Alkaline earth metal or magnesium compounds of magnesium
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- B—PERFORMING OPERATIONS; TRANSPORTING
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
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- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
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| CA2937108A1 (en) | 2014-01-17 | 2015-07-23 | Skyonic Corporation | Acid gas removal from a gaseous stream |
| EA201790890A1 (ru) | 2014-10-21 | 2017-10-31 | Скайоник Корпорейшн | Обработка сточных вод до уровня, пригодного для повторного использования в способе удаления co, и система |
| CN116253342A (zh) * | 2015-02-23 | 2023-06-13 | 无碳化工控股有限责任公司 | 利用氢氧化镁进行的二氧化碳封存和氢氧化镁的再生 |
| CN105457461B (zh) * | 2015-12-29 | 2018-04-10 | 原初科技（北京）有限公司 | 一种二氧化碳吸收并矿物化装置及方法 |
| EP3558491A4 (en) | 2016-12-21 | 2020-08-12 | Isca Management Ltd. | ELIMINATION OF GREENHOUSE GASES AND HEAVY METALS FROM AN EMISSIONS STREAM |
| CN107324753B (zh) * | 2017-04-10 | 2020-01-17 | 南京工业大学 | 一种碳酸盐胶凝材料及其制备方法 |
| US11174488B2 (en) | 2017-07-13 | 2021-11-16 | Radici Chimica S.P.A. | Biological methods for modifying cellular carbon flux |
| CN107720800A (zh) | 2017-11-07 | 2018-02-23 | 王麒 | 回收利用二氧化碳的方法以及系统 |
| KR102140915B1 (ko) * | 2018-11-27 | 2020-08-05 | 한국에너지기술연구원 | 이산화탄소의 광물화 반응 장치 및 이산화탄소의 고정화 방법 |
| US11858819B2 (en) | 2021-03-04 | 2024-01-02 | Energy And Environmental Research Center Foundation | Methods of producing a syngas composition |
| US11717802B2 (en) | 2021-03-04 | 2023-08-08 | Energy And Environmental Research Center Foundation | Methods of treating metal carbonate salts |
| WO2025171399A1 (en) * | 2024-02-09 | 2025-08-14 | Carbonfree Chemicals Holdings, Llc | Co2 capture device using cavitation |
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| US1978403A (en) * | 1932-12-31 | 1934-10-30 | Dow Chemical Co | Process of separating calcium and magnesium chlorides |
| US9359221B2 (en) * | 2010-07-08 | 2016-06-07 | Skyonic Corporation | Carbon dioxide sequestration involving two-salt-based thermolytic processes |
| WO2012122496A1 (en) * | 2011-03-09 | 2012-09-13 | Skyonic Corporation | Carbon dioxide sequestration methods using group 2 silicates and chlor-alkali processes |
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| CO7020904A2 (es) | 2014-08-11 |
| EP2809427A1 (en) | 2014-12-10 |
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| AR090051A1 (es) | 2014-10-15 |
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| TW201335071A (zh) | 2013-09-01 |
| US20130202516A1 (en) | 2013-08-08 |
| WO2013106730A1 (en) | 2013-07-18 |
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| EP2809427A4 (en) | 2015-08-26 |
| BR112014017019A2 (pt) | 2017-06-13 |
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