CA2863326A1 - Carbon dioxide sequestration involving two-salt-based thermolytic processes - Google Patents
Carbon dioxide sequestration involving two-salt-based thermolytic processes Download PDFInfo
- Publication number
- CA2863326A1 CA2863326A1 CA2863326A CA2863326A CA2863326A1 CA 2863326 A1 CA2863326 A1 CA 2863326A1 CA 2863326 A CA2863326 A CA 2863326A CA 2863326 A CA2863326 A CA 2863326A CA 2863326 A1 CA2863326 A1 CA 2863326A1
- Authority
- CA
- Canada
- Prior art keywords
- mgc12
- water
- mgcl2
- product
- caco3
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Abandoned
Links
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 title claims abstract description 595
- 238000000034 method Methods 0.000 title claims abstract description 364
- 229910002092 carbon dioxide Inorganic materials 0.000 title claims abstract description 297
- 239000001569 carbon dioxide Substances 0.000 title claims abstract description 57
- 230000008569 process Effects 0.000 title abstract description 282
- 230000009919 sequestration Effects 0.000 title abstract description 19
- 229910001868 water Inorganic materials 0.000 claims abstract description 373
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims abstract description 320
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 179
- VTHJTEIRLNZDEV-UHFFFAOYSA-L magnesium dihydroxide Chemical compound [OH-].[OH-].[Mg+2] VTHJTEIRLNZDEV-UHFFFAOYSA-L 0.000 claims abstract description 163
- 229910001862 magnesium hydroxide Inorganic materials 0.000 claims abstract description 163
- 239000000347 magnesium hydroxide Substances 0.000 claims abstract description 162
- 235000012254 magnesium hydroxide Nutrition 0.000 claims abstract description 162
- 229910000019 calcium carbonate Inorganic materials 0.000 claims abstract description 157
- 229910052500 inorganic mineral Inorganic materials 0.000 claims abstract description 67
- 235000010755 mineral Nutrition 0.000 claims abstract description 67
- 239000011707 mineral Substances 0.000 claims abstract description 67
- 229910052918 calcium silicate Inorganic materials 0.000 claims abstract description 26
- 239000000378 calcium silicate Substances 0.000 claims abstract description 25
- OYACROKNLOSFPA-UHFFFAOYSA-N calcium;dioxido(oxo)silane Chemical compound [Ca+2].[O-][Si]([O-])=O OYACROKNLOSFPA-UHFFFAOYSA-N 0.000 claims abstract description 24
- 235000010216 calcium carbonate Nutrition 0.000 claims abstract description 15
- 229910019440 Mg(OH) Inorganic materials 0.000 claims description 228
- TWRXJAOTZQYOKJ-UHFFFAOYSA-L Magnesium chloride Chemical compound [Mg+2].[Cl-].[Cl-] TWRXJAOTZQYOKJ-UHFFFAOYSA-L 0.000 claims description 198
- 239000003546 flue gas Substances 0.000 claims description 149
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 claims description 148
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 147
- 239000001110 calcium chloride Substances 0.000 claims description 97
- 229910001628 calcium chloride Inorganic materials 0.000 claims description 97
- 229910001629 magnesium chloride Inorganic materials 0.000 claims description 95
- UXVMQQNJUSDDNG-UHFFFAOYSA-L Calcium chloride Chemical compound [Cl-].[Cl-].[Ca+2] UXVMQQNJUSDDNG-UHFFFAOYSA-L 0.000 claims description 92
- 235000011148 calcium chloride Nutrition 0.000 claims description 90
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims description 75
- 229910052882 wollastonite Inorganic materials 0.000 claims description 62
- 239000000203 mixture Substances 0.000 claims description 49
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 claims description 43
- 239000011575 calcium Substances 0.000 claims description 40
- 239000000377 silicon dioxide Substances 0.000 claims description 40
- 239000007787 solid Substances 0.000 claims description 32
- IXCSERBJSXMMFS-UHFFFAOYSA-N hydrogen chloride Substances Cl.Cl IXCSERBJSXMMFS-UHFFFAOYSA-N 0.000 claims description 29
- 229910000041 hydrogen chloride Inorganic materials 0.000 claims description 29
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 28
- 235000012239 silicon dioxide Nutrition 0.000 claims description 26
- -1 manganese silicates Chemical class 0.000 claims description 25
- 229910052637 diopside Inorganic materials 0.000 claims description 24
- NWXHSRDXUJENGJ-UHFFFAOYSA-N calcium;magnesium;dioxido(oxo)silane Chemical compound [Mg+2].[Ca+2].[O-][Si]([O-])=O.[O-][Si]([O-])=O NWXHSRDXUJENGJ-UHFFFAOYSA-N 0.000 claims description 23
- 229910052610 inosilicate Inorganic materials 0.000 claims description 20
- 229910052742 iron Inorganic materials 0.000 claims description 16
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 claims description 15
- 229910052791 calcium Inorganic materials 0.000 claims description 11
- 230000014759 maintenance of location Effects 0.000 claims description 11
- 238000000926 separation method Methods 0.000 claims description 8
- 229910052748 manganese Inorganic materials 0.000 claims description 7
- 239000011572 manganese Substances 0.000 claims description 7
- 229910052889 tremolite Inorganic materials 0.000 claims description 5
- 238000012544 monitoring process Methods 0.000 claims description 4
- JHEFLPGCJCTLDM-UHFFFAOYSA-N iron(2+);silicic acid Chemical group [Fe+2].[Fe+2].O[Si](O)(O)O JHEFLPGCJCTLDM-UHFFFAOYSA-N 0.000 claims description 3
- 229910007270 Si2O6 Inorganic materials 0.000 claims 1
- 235000019738 Limestone Nutrition 0.000 abstract description 14
- 239000006028 limestone Substances 0.000 abstract description 14
- 239000004576 sand Substances 0.000 abstract description 8
- 239000000126 substance Substances 0.000 abstract description 8
- 230000001351 cycling effect Effects 0.000 abstract description 3
- CPLXHLVBOLITMK-UHFFFAOYSA-N Magnesium oxide Chemical compound [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 240
- 238000006243 chemical reaction Methods 0.000 description 196
- 239000000395 magnesium oxide Substances 0.000 description 135
- 238000000354 decomposition reaction Methods 0.000 description 130
- 239000000047 product Substances 0.000 description 100
- 238000004088 simulation Methods 0.000 description 90
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 70
- 229910052681 coesite Inorganic materials 0.000 description 64
- 229910052906 cristobalite Inorganic materials 0.000 description 64
- 229910052682 stishovite Inorganic materials 0.000 description 64
- 229910052905 tridymite Inorganic materials 0.000 description 64
- ZLNQQNXFFQJAID-UHFFFAOYSA-L magnesium carbonate Chemical compound [Mg+2].[O-]C([O-])=O ZLNQQNXFFQJAID-UHFFFAOYSA-L 0.000 description 63
- 229910000021 magnesium carbonate Inorganic materials 0.000 description 63
- 239000001095 magnesium carbonate Substances 0.000 description 61
- 239000011777 magnesium Substances 0.000 description 60
- 235000002639 sodium chloride Nutrition 0.000 description 54
- AXCZMVOFGPJBDE-UHFFFAOYSA-L calcium dihydroxide Chemical compound [OH-].[OH-].[Ca+2] AXCZMVOFGPJBDE-UHFFFAOYSA-L 0.000 description 51
- 239000000920 calcium hydroxide Substances 0.000 description 51
- 229910001861 calcium hydroxide Inorganic materials 0.000 description 51
- 235000011116 calcium hydroxide Nutrition 0.000 description 51
- 150000003839 salts Chemical class 0.000 description 50
- 238000010586 diagram Methods 0.000 description 46
- 239000003245 coal Substances 0.000 description 42
- 229910052634 enstatite Inorganic materials 0.000 description 41
- 239000000243 solution Substances 0.000 description 37
- 239000003345 natural gas Substances 0.000 description 35
- 150000001768 cations Chemical class 0.000 description 32
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 29
- BVKZGUZCCUSVTD-UHFFFAOYSA-M Bicarbonate Chemical compound OC([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-M 0.000 description 27
- BHPQYMZQTOCNFJ-UHFFFAOYSA-N Calcium cation Chemical compound [Ca+2] BHPQYMZQTOCNFJ-UHFFFAOYSA-N 0.000 description 26
- 229910052604 silicate mineral Inorganic materials 0.000 description 26
- 229910001424 calcium ion Inorganic materials 0.000 description 24
- 239000007789 gas Substances 0.000 description 23
- 241000183024 Populus tremula Species 0.000 description 22
- 150000004679 hydroxides Chemical class 0.000 description 22
- 229910052609 olivine Inorganic materials 0.000 description 22
- 239000010450 olivine Substances 0.000 description 22
- KZBUYRJDOAKODT-UHFFFAOYSA-N Chlorine Chemical compound ClCl KZBUYRJDOAKODT-UHFFFAOYSA-N 0.000 description 21
- 150000003841 chloride salts Chemical class 0.000 description 21
- 238000006297 dehydration reaction Methods 0.000 description 21
- 235000012241 calcium silicate Nutrition 0.000 description 19
- 239000000460 chlorine Substances 0.000 description 19
- 239000007788 liquid Substances 0.000 description 19
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 description 18
- 208000005156 Dehydration Diseases 0.000 description 17
- 241000196324 Embryophyta Species 0.000 description 17
- 229910020489 SiO3 Inorganic materials 0.000 description 17
- 230000018044 dehydration Effects 0.000 description 17
- 229910052749 magnesium Inorganic materials 0.000 description 17
- 239000011435 rock Substances 0.000 description 17
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 16
- 239000002994 raw material Substances 0.000 description 16
- 229910020091 MgCa Inorganic materials 0.000 description 15
- 101100003996 Mus musculus Atrn gene Proteins 0.000 description 15
- 238000009385 rock melting Methods 0.000 description 15
- JLVVSXFLKOJNIY-UHFFFAOYSA-N Magnesium ion Chemical group [Mg+2] JLVVSXFLKOJNIY-UHFFFAOYSA-N 0.000 description 14
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 14
- 150000001875 compounds Chemical class 0.000 description 14
- 239000002244 precipitate Substances 0.000 description 14
- 239000011734 sodium Chemical group 0.000 description 14
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical group [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 13
- WYTGDNHDOZPMIW-RCBQFDQVSA-N alstonine Natural products C1=CC2=C3C=CC=CC3=NC2=C2N1C[C@H]1[C@H](C)OC=C(C(=O)OC)[C@H]1C2 WYTGDNHDOZPMIW-RCBQFDQVSA-N 0.000 description 13
- 230000015572 biosynthetic process Effects 0.000 description 13
- 238000004519 manufacturing process Methods 0.000 description 13
- 239000002918 waste heat Substances 0.000 description 13
- ODINCKMPIJJUCX-UHFFFAOYSA-N Calcium oxide Chemical compound [Ca]=O ODINCKMPIJJUCX-UHFFFAOYSA-N 0.000 description 12
- 229910052801 chlorine Inorganic materials 0.000 description 12
- 229910000514 dolomite Inorganic materials 0.000 description 12
- 229910001425 magnesium ion Inorganic materials 0.000 description 12
- 229940091250 magnesium supplement Drugs 0.000 description 12
- 230000009467 reduction Effects 0.000 description 12
- 229920006395 saturated elastomer Polymers 0.000 description 12
- 150000004760 silicates Chemical class 0.000 description 12
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 11
- 229910003110 Mg K Inorganic materials 0.000 description 11
- 238000010521 absorption reaction Methods 0.000 description 11
- 150000005323 carbonate salts Chemical class 0.000 description 11
- 238000004090 dissolution Methods 0.000 description 11
- 150000004687 hexahydrates Chemical class 0.000 description 11
- 235000014380 magnesium carbonate Nutrition 0.000 description 11
- 239000002002 slurry Substances 0.000 description 11
- 229910002794 Si K Inorganic materials 0.000 description 10
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 10
- 229910052760 oxygen Inorganic materials 0.000 description 10
- 239000001301 oxygen Substances 0.000 description 10
- 239000000376 reactant Substances 0.000 description 10
- 238000011084 recovery Methods 0.000 description 10
- 238000002441 X-ray diffraction Methods 0.000 description 9
- 239000010459 dolomite Substances 0.000 description 9
- 239000000463 material Substances 0.000 description 9
- 239000010456 wollastonite Substances 0.000 description 9
- 229910002552 Fe K Inorganic materials 0.000 description 8
- 230000008901 benefit Effects 0.000 description 8
- ZCCIPPOKBCJFDN-UHFFFAOYSA-N calcium nitrate Chemical compound [Ca+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O ZCCIPPOKBCJFDN-UHFFFAOYSA-N 0.000 description 8
- BVKZGUZCCUSVTD-UHFFFAOYSA-N carbonic acid Chemical group OC(O)=O BVKZGUZCCUSVTD-UHFFFAOYSA-N 0.000 description 8
- 150000004649 carbonic acid derivatives Chemical class 0.000 description 8
- 230000000694 effects Effects 0.000 description 8
- 235000017550 sodium carbonate Nutrition 0.000 description 8
- 229910000029 sodium carbonate Inorganic materials 0.000 description 8
- 229910018493 Ni—K Inorganic materials 0.000 description 7
- 229910052799 carbon Inorganic materials 0.000 description 7
- 150000001805 chlorine compounds Chemical class 0.000 description 7
- 239000003034 coal gas Substances 0.000 description 7
- 239000000706 filtrate Substances 0.000 description 7
- 238000001914 filtration Methods 0.000 description 7
- 229910052739 hydrogen Inorganic materials 0.000 description 7
- QWPPOHNGKGFGJK-UHFFFAOYSA-N hypochlorous acid Chemical class ClO QWPPOHNGKGFGJK-UHFFFAOYSA-N 0.000 description 7
- 150000002500 ions Chemical class 0.000 description 7
- 229960002337 magnesium chloride Drugs 0.000 description 7
- 159000000003 magnesium salts Chemical class 0.000 description 7
- 238000012545 processing Methods 0.000 description 7
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 6
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 6
- 239000007864 aqueous solution Substances 0.000 description 6
- 235000012255 calcium oxide Nutrition 0.000 description 6
- 239000000292 calcium oxide Substances 0.000 description 6
- 238000005265 energy consumption Methods 0.000 description 6
- 230000036571 hydration Effects 0.000 description 6
- 238000006703 hydration reaction Methods 0.000 description 6
- 239000001257 hydrogen Substances 0.000 description 6
- 239000012535 impurity Substances 0.000 description 6
- 239000000543 intermediate Substances 0.000 description 6
- AMXOYNBUYSYVKV-UHFFFAOYSA-M lithium bromide Chemical compound [Li+].[Br-] AMXOYNBUYSYVKV-UHFFFAOYSA-M 0.000 description 6
- 150000002823 nitrates Chemical class 0.000 description 6
- 238000005457 optimization Methods 0.000 description 6
- 238000001556 precipitation Methods 0.000 description 6
- 238000005979 thermal decomposition reaction Methods 0.000 description 6
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 5
- 238000004458 analytical method Methods 0.000 description 5
- 239000006227 byproduct Substances 0.000 description 5
- 238000009833 condensation Methods 0.000 description 5
- 230000005494 condensation Effects 0.000 description 5
- 238000002474 experimental method Methods 0.000 description 5
- 150000004820 halides Chemical class 0.000 description 5
- 238000011835 investigation Methods 0.000 description 5
- YIXJRHPUWRPCBB-UHFFFAOYSA-N magnesium nitrate Inorganic materials [Mg+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O YIXJRHPUWRPCBB-UHFFFAOYSA-N 0.000 description 5
- HCWCAKKEBCNQJP-UHFFFAOYSA-N magnesium orthosilicate Chemical compound [Mg+2].[Mg+2].[O-][Si]([O-])([O-])[O-] HCWCAKKEBCNQJP-UHFFFAOYSA-N 0.000 description 5
- 239000000391 magnesium silicate Substances 0.000 description 5
- 229910052919 magnesium silicate Inorganic materials 0.000 description 5
- 235000019792 magnesium silicate Nutrition 0.000 description 5
- BBCCCLINBSELLX-UHFFFAOYSA-N magnesium;dihydroxy(oxo)silane Chemical compound [Mg+2].O[Si](O)=O BBCCCLINBSELLX-UHFFFAOYSA-N 0.000 description 5
- 239000011541 reaction mixture Substances 0.000 description 5
- 229910052710 silicon Inorganic materials 0.000 description 5
- 238000012360 testing method Methods 0.000 description 5
- 239000002699 waste material Substances 0.000 description 5
- 229910021532 Calcite Inorganic materials 0.000 description 4
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 description 4
- 229910018666 Mn—K Inorganic materials 0.000 description 4
- 229910002651 NO3 Inorganic materials 0.000 description 4
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 4
- UIIMBOGNXHQVGW-UHFFFAOYSA-M Sodium bicarbonate Chemical compound [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 description 4
- 239000007900 aqueous suspension Substances 0.000 description 4
- 239000003795 chemical substances by application Substances 0.000 description 4
- 150000004683 dihydrates Chemical group 0.000 description 4
- 238000007323 disproportionation reaction Methods 0.000 description 4
- 239000003344 environmental pollutant Substances 0.000 description 4
- 238000010438 heat treatment Methods 0.000 description 4
- 229940050906 magnesium chloride hexahydrate Drugs 0.000 description 4
- 150000002681 magnesium compounds Chemical class 0.000 description 4
- DARFZFVWKREYJJ-UHFFFAOYSA-L magnesium dichloride dihydrate Chemical compound O.O.[Mg+2].[Cl-].[Cl-] DARFZFVWKREYJJ-UHFFFAOYSA-L 0.000 description 4
- DHRRIBDTHFBPNG-UHFFFAOYSA-L magnesium dichloride hexahydrate Chemical compound O.O.O.O.O.O.[Mg+2].[Cl-].[Cl-] DHRRIBDTHFBPNG-UHFFFAOYSA-L 0.000 description 4
- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 description 4
- 231100000647 material safety data sheet Toxicity 0.000 description 4
- 150000005324 oxide salts Chemical class 0.000 description 4
- 231100000719 pollutant Toxicity 0.000 description 4
- 239000010703 silicon Substances 0.000 description 4
- 235000011121 sodium hydroxide Nutrition 0.000 description 4
- 229910002703 Al K Inorganic materials 0.000 description 3
- CWYNVVGOOAEACU-UHFFFAOYSA-N Fe2+ Chemical group [Fe+2] CWYNVVGOOAEACU-UHFFFAOYSA-N 0.000 description 3
- 208000009989 Posterior Leukoencephalopathy Syndrome Diseases 0.000 description 3
- 239000004113 Sepiolite Substances 0.000 description 3
- 239000000654 additive Substances 0.000 description 3
- 230000000996 additive effect Effects 0.000 description 3
- 229910000020 calcium bicarbonate Inorganic materials 0.000 description 3
- 125000005587 carbonate group Chemical group 0.000 description 3
- 239000003054 catalyst Substances 0.000 description 3
- 239000003518 caustics Substances 0.000 description 3
- 238000003889 chemical engineering Methods 0.000 description 3
- 239000003153 chemical reaction reagent Substances 0.000 description 3
- 238000002485 combustion reaction Methods 0.000 description 3
- 238000013461 design Methods 0.000 description 3
- 238000002149 energy-dispersive X-ray emission spectroscopy Methods 0.000 description 3
- 235000013305 food Nutrition 0.000 description 3
- DKAGJZJALZXOOV-UHFFFAOYSA-N hydrate;hydrochloride Chemical class O.Cl DKAGJZJALZXOOV-UHFFFAOYSA-N 0.000 description 3
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N iron oxide Inorganic materials [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 3
- FBDWCTWJJMORIU-UHFFFAOYSA-N magnesium;hexahydrate Chemical compound O.O.O.O.O.O.[Mg] FBDWCTWJJMORIU-UHFFFAOYSA-N 0.000 description 3
- 229910052751 metal Inorganic materials 0.000 description 3
- 239000002184 metal Substances 0.000 description 3
- 229910052698 phosphorus Inorganic materials 0.000 description 3
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- 229910013470 LiC1 Inorganic materials 0.000 description 2
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 description 2
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- RTQCAYKHUMWCEM-UHFFFAOYSA-N [Mg].ClO Chemical compound [Mg].ClO RTQCAYKHUMWCEM-UHFFFAOYSA-N 0.000 description 2
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- AYJRCSIUFZENHW-UHFFFAOYSA-L barium carbonate Chemical compound [Ba+2].[O-]C([O-])=O AYJRCSIUFZENHW-UHFFFAOYSA-L 0.000 description 2
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- FJDQFPXHSGXQBY-UHFFFAOYSA-L caesium carbonate Chemical compound [Cs+].[Cs+].[O-]C([O-])=O FJDQFPXHSGXQBY-UHFFFAOYSA-L 0.000 description 2
- NKWPZUCBCARRDP-UHFFFAOYSA-L calcium bicarbonate Chemical compound [Ca+2].OC([O-])=O.OC([O-])=O NKWPZUCBCARRDP-UHFFFAOYSA-L 0.000 description 2
- 239000004568 cement Substances 0.000 description 2
- 238000005660 chlorination reaction Methods 0.000 description 2
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- 239000005431 greenhouse gas Substances 0.000 description 2
- 230000007062 hydrolysis Effects 0.000 description 2
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- 229910052909 inorganic silicate Inorganic materials 0.000 description 2
- 229910000022 magnesium bicarbonate Inorganic materials 0.000 description 2
- 235000014824 magnesium bicarbonate Nutrition 0.000 description 2
- 238000005259 measurement Methods 0.000 description 2
- 229910001510 metal chloride Inorganic materials 0.000 description 2
- 238000005065 mining Methods 0.000 description 2
- 229910017604 nitric acid Inorganic materials 0.000 description 2
- 239000004033 plastic Substances 0.000 description 2
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- BWHMMNNQKKPAPP-UHFFFAOYSA-L potassium carbonate Chemical compound [K+].[K+].[O-]C([O-])=O BWHMMNNQKKPAPP-UHFFFAOYSA-L 0.000 description 2
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- 238000000746 purification Methods 0.000 description 2
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- 230000008929 regeneration Effects 0.000 description 2
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- 229910052708 sodium Inorganic materials 0.000 description 2
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- 235000017557 sodium bicarbonate Nutrition 0.000 description 2
- JHJLBTNAGRQEKS-UHFFFAOYSA-M sodium bromide Chemical compound [Na+].[Br-] JHJLBTNAGRQEKS-UHFFFAOYSA-M 0.000 description 2
- 239000011780 sodium chloride Substances 0.000 description 2
- 241000894007 species Species 0.000 description 2
- 239000007858 starting material Substances 0.000 description 2
- 235000011149 sulphuric acid Nutrition 0.000 description 2
- 239000010936 titanium Substances 0.000 description 2
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- 239000012808 vapor phase Substances 0.000 description 2
- 239000003643 water by type Substances 0.000 description 2
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 description 1
- 241000206761 Bacillariophyta Species 0.000 description 1
- YKYOUMDCQGMQQO-UHFFFAOYSA-L Cadmium chloride Inorganic materials Cl[Cd]Cl YKYOUMDCQGMQQO-UHFFFAOYSA-L 0.000 description 1
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 1
- 235000008733 Citrus aurantifolia Nutrition 0.000 description 1
- 229910017488 Cu K Inorganic materials 0.000 description 1
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- 208000002064 Dental Plaque Diseases 0.000 description 1
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- PPQREHKVAOVYBT-UHFFFAOYSA-H aluminium carbonate Inorganic materials [Al+3].[Al+3].[O-]C([O-])=O.[O-]C([O-])=O.[O-]C([O-])=O PPQREHKVAOVYBT-UHFFFAOYSA-H 0.000 description 1
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- LVEULQCPJDDSLD-UHFFFAOYSA-L cadmium fluoride Chemical compound F[Cd]F LVEULQCPJDDSLD-UHFFFAOYSA-L 0.000 description 1
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- 238000009792 diffusion process Methods 0.000 description 1
- CTNMMTCXUUFYAP-UHFFFAOYSA-L difluoromanganese Chemical compound F[Mn]F CTNMMTCXUUFYAP-UHFFFAOYSA-L 0.000 description 1
- 238000010494 dissociation reaction Methods 0.000 description 1
- 230000005593 dissociations Effects 0.000 description 1
- 230000035622 drinking Effects 0.000 description 1
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- 230000005611 electricity Effects 0.000 description 1
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- 238000009408 flooring Methods 0.000 description 1
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- 229910052731 fluorine Inorganic materials 0.000 description 1
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- 229910021485 fumed silica Inorganic materials 0.000 description 1
- 239000000499 gel Substances 0.000 description 1
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- 239000010903 husk Substances 0.000 description 1
- 150000004677 hydrates Chemical class 0.000 description 1
- WQYVRQLZKVEZGA-UHFFFAOYSA-N hypochlorite Chemical class Cl[O-] WQYVRQLZKVEZGA-UHFFFAOYSA-N 0.000 description 1
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- 239000012212 insulator Substances 0.000 description 1
- 238000005342 ion exchange Methods 0.000 description 1
- 229910000015 iron(II) carbonate Inorganic materials 0.000 description 1
- FZGIHSNZYGFUGM-UHFFFAOYSA-L iron(ii) fluoride Chemical compound [F-].[F-].[Fe+2] FZGIHSNZYGFUGM-UHFFFAOYSA-L 0.000 description 1
- BVRHQICYSINRIG-UHFFFAOYSA-N iron;magnesium;silicic acid Chemical compound [Mg].[Mg].[Mg].[Fe].O[Si](O)(O)O.O[Si](O)(O)O BVRHQICYSINRIG-UHFFFAOYSA-N 0.000 description 1
- 238000002955 isolation Methods 0.000 description 1
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- 239000004571 lime Substances 0.000 description 1
- 239000006193 liquid solution Substances 0.000 description 1
- 229910052744 lithium Inorganic materials 0.000 description 1
- 229910052808 lithium carbonate Inorganic materials 0.000 description 1
- XGZVUEUWXADBQD-UHFFFAOYSA-L lithium carbonate Chemical compound [Li+].[Li+].[O-]C([O-])=O XGZVUEUWXADBQD-UHFFFAOYSA-L 0.000 description 1
- 229910000032 lithium hydrogen carbonate Inorganic materials 0.000 description 1
- 230000005923 long-lasting effect Effects 0.000 description 1
- 229910001607 magnesium mineral Inorganic materials 0.000 description 1
- FYYHWMGAXLPEAU-OUBTZVSYSA-N magnesium-25 atom Chemical compound [25Mg] FYYHWMGAXLPEAU-OUBTZVSYSA-N 0.000 description 1
- ZEYIGTRJOAQUPJ-UHFFFAOYSA-L magnesium;carbonate;dihydrate Chemical compound O.O.[Mg+2].[O-]C([O-])=O ZEYIGTRJOAQUPJ-UHFFFAOYSA-L 0.000 description 1
- 239000011656 manganese carbonate Substances 0.000 description 1
- 235000006748 manganese carbonate Nutrition 0.000 description 1
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 description 1
- 229910000016 manganese(II) carbonate Inorganic materials 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- 239000000155 melt Substances 0.000 description 1
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 description 1
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- 239000004570 mortar (masonry) Substances 0.000 description 1
- 230000003472 neutralizing effect Effects 0.000 description 1
- FOKWMWSOTUZOPN-UHFFFAOYSA-N octamagnesium;iron(2+);pentasilicate Chemical compound [Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Fe+2].[Fe+2].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-] FOKWMWSOTUZOPN-UHFFFAOYSA-N 0.000 description 1
- 239000013307 optical fiber Substances 0.000 description 1
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- 230000003647 oxidation Effects 0.000 description 1
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- 230000001590 oxidative effect Effects 0.000 description 1
- NDLPOXTZKUMGOV-UHFFFAOYSA-N oxo(oxoferriooxy)iron hydrate Chemical compound O.O=[Fe]O[Fe]=O NDLPOXTZKUMGOV-UHFFFAOYSA-N 0.000 description 1
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- 150000004686 pentahydrates Chemical class 0.000 description 1
- 239000011025 peridot Substances 0.000 description 1
- 229920001084 poly(chloroprene) Polymers 0.000 description 1
- 229910052573 porcelain Inorganic materials 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 235000015320 potassium carbonate Nutrition 0.000 description 1
- 229910000027 potassium carbonate Inorganic materials 0.000 description 1
- 238000010248 power generation Methods 0.000 description 1
- 229910052881 pyroxenoid Inorganic materials 0.000 description 1
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- 229910052706 scandium Inorganic materials 0.000 description 1
- SIXSYDAISGFNSX-UHFFFAOYSA-N scandium atom Chemical compound [Sc] SIXSYDAISGFNSX-UHFFFAOYSA-N 0.000 description 1
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- 238000007086 side reaction Methods 0.000 description 1
- LKZMBDSASOBTPN-UHFFFAOYSA-L silver carbonate Substances [Ag].[O-]C([O-])=O LKZMBDSASOBTPN-UHFFFAOYSA-L 0.000 description 1
- KQTXIZHBFFWWFW-UHFFFAOYSA-L silver(I) carbonate Inorganic materials [Ag]OC(=O)O[Ag] KQTXIZHBFFWWFW-UHFFFAOYSA-L 0.000 description 1
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- 229910000018 strontium carbonate Inorganic materials 0.000 description 1
- LEDMRZGFZIAGGB-UHFFFAOYSA-L strontium carbonate Chemical compound [Sr+2].[O-]C([O-])=O LEDMRZGFZIAGGB-UHFFFAOYSA-L 0.000 description 1
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- FKHIFSZMMVMEQY-UHFFFAOYSA-N talc Chemical compound [Mg+2].[O-][Si]([O-])=O FKHIFSZMMVMEQY-UHFFFAOYSA-N 0.000 description 1
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- 229910052720 vanadium Inorganic materials 0.000 description 1
- GPPXJZIENCGNKB-UHFFFAOYSA-N vanadium Chemical compound [V]#[V] GPPXJZIENCGNKB-UHFFFAOYSA-N 0.000 description 1
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- 235000004416 zinc carbonate Nutrition 0.000 description 1
- 229910000010 zinc carbonate Inorganic materials 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/46—Removing components of defined structure
- B01D53/62—Carbon oxides
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B32/00—Carbon; Compounds thereof
- C01B32/60—Preparation of carbonates or bicarbonates in general
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01F—COMPOUNDS OF THE METALS BERYLLIUM, MAGNESIUM, ALUMINIUM, CALCIUM, STRONTIUM, BARIUM, RADIUM, THORIUM, OR OF THE RARE-EARTH METALS
- C01F11/00—Compounds of calcium, strontium, or barium
- C01F11/18—Carbonates
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01F—COMPOUNDS OF THE METALS BERYLLIUM, MAGNESIUM, ALUMINIUM, CALCIUM, STRONTIUM, BARIUM, RADIUM, THORIUM, OR OF THE RARE-EARTH METALS
- C01F5/00—Compounds of magnesium
- C01F5/24—Magnesium carbonates
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2251/00—Reactants
- B01D2251/40—Alkaline earth metal or magnesium compounds
- B01D2251/402—Alkaline earth metal or magnesium compounds of magnesium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2251/00—Reactants
- B01D2251/40—Alkaline earth metal or magnesium compounds
- B01D2251/404—Alkaline earth metal or magnesium compounds of calcium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2251/00—Reactants
- B01D2251/60—Inorganic bases or salts
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2251/00—Reactants
- B01D2251/60—Inorganic bases or salts
- B01D2251/604—Hydroxides
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2257/00—Components to be removed
- B01D2257/50—Carbon oxides
- B01D2257/504—Carbon dioxide
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02C—CAPTURE, STORAGE, SEQUESTRATION OR DISPOSAL OF GREENHOUSE GASES [GHG]
- Y02C20/00—Capture or disposal of greenhouse gases
- Y02C20/40—Capture or disposal of greenhouse gases of CO2
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/151—Reduction of greenhouse gas [GHG] emissions, e.g. CO2
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Inorganic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Geology (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Biomedical Technology (AREA)
- Analytical Chemistry (AREA)
- Environmental & Geological Engineering (AREA)
- Health & Medical Sciences (AREA)
- Treating Waste Gases (AREA)
- Gas Separation By Absorption (AREA)
- Carbon And Carbon Compounds (AREA)
- Physical Or Chemical Processes And Apparatus (AREA)
- Compounds Of Alkaline-Earth Elements, Aluminum Or Rare-Earth Metals (AREA)
- Solid-Sorbent Or Filter-Aiding Compositions (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US201261585597P | 2012-01-11 | 2012-01-11 | |
| US61/585,597 | 2012-01-11 | ||
| PCT/US2013/021264 WO2013106730A1 (en) | 2012-01-11 | 2013-01-11 | Carbon dioxide sequestration involving two-salt-based thermolytic processes |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CA2863326A1 true CA2863326A1 (en) | 2013-07-18 |
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA2863326A Abandoned CA2863326A1 (en) | 2012-01-11 | 2013-01-11 | Carbon dioxide sequestration involving two-salt-based thermolytic processes |
Country Status (23)
| Country | Link |
|---|---|
| US (1) | US20130202516A1 (enExample) |
| EP (1) | EP2809427A4 (enExample) |
| JP (1) | JP2015508332A (enExample) |
| KR (1) | KR20140111034A (enExample) |
| CN (1) | CN104284707A (enExample) |
| AP (1) | AP2014007853A0 (enExample) |
| AR (1) | AR090051A1 (enExample) |
| AU (1) | AU2013203886B2 (enExample) |
| BR (1) | BR112014017019A8 (enExample) |
| CA (1) | CA2863326A1 (enExample) |
| CL (1) | CL2014001842A1 (enExample) |
| CO (1) | CO7020904A2 (enExample) |
| EA (1) | EA201491342A1 (enExample) |
| HK (2) | HK1205976A1 (enExample) |
| IL (1) | IL233577A0 (enExample) |
| IN (1) | IN2014DN05949A (enExample) |
| MX (1) | MX2014008491A (enExample) |
| NZ (1) | NZ628133A (enExample) |
| PE (1) | PE20142384A1 (enExample) |
| PH (1) | PH12014501606A1 (enExample) |
| SG (1) | SG11201404005SA (enExample) |
| TW (1) | TW201335071A (enExample) |
| WO (1) | WO2013106730A1 (enExample) |
Families Citing this family (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CA2937108A1 (en) | 2014-01-17 | 2015-07-23 | Skyonic Corporation | Acid gas removal from a gaseous stream |
| EA201790890A1 (ru) | 2014-10-21 | 2017-10-31 | Скайоник Корпорейшн | Обработка сточных вод до уровня, пригодного для повторного использования в способе удаления co, и система |
| CN116253342A (zh) * | 2015-02-23 | 2023-06-13 | 无碳化工控股有限责任公司 | 利用氢氧化镁进行的二氧化碳封存和氢氧化镁的再生 |
| CN105457461B (zh) * | 2015-12-29 | 2018-04-10 | 原初科技（北京）有限公司 | 一种二氧化碳吸收并矿物化装置及方法 |
| EP3558491A4 (en) | 2016-12-21 | 2020-08-12 | Isca Management Ltd. | ELIMINATION OF GREENHOUSE GASES AND HEAVY METALS FROM AN EMISSIONS STREAM |
| CN107324753B (zh) * | 2017-04-10 | 2020-01-17 | 南京工业大学 | 一种碳酸盐胶凝材料及其制备方法 |
| US11174488B2 (en) | 2017-07-13 | 2021-11-16 | Radici Chimica S.P.A. | Biological methods for modifying cellular carbon flux |
| CN107720800A (zh) | 2017-11-07 | 2018-02-23 | 王麒 | 回收利用二氧化碳的方法以及系统 |
| KR102140915B1 (ko) * | 2018-11-27 | 2020-08-05 | 한국에너지기술연구원 | 이산화탄소의 광물화 반응 장치 및 이산화탄소의 고정화 방법 |
| US11858819B2 (en) | 2021-03-04 | 2024-01-02 | Energy And Environmental Research Center Foundation | Methods of producing a syngas composition |
| US11717802B2 (en) | 2021-03-04 | 2023-08-08 | Energy And Environmental Research Center Foundation | Methods of treating metal carbonate salts |
| AU2023262775A1 (en) * | 2022-04-26 | 2024-10-17 | Inpex Corporation | Processing method and processing apparatus |
| WO2025171399A1 (en) * | 2024-02-09 | 2025-08-14 | Carbonfree Chemicals Holdings, Llc | Co2 capture device using cavitation |
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|---|---|---|---|---|
| US1978403A (en) * | 1932-12-31 | 1934-10-30 | Dow Chemical Co | Process of separating calcium and magnesium chlorides |
| US9359221B2 (en) * | 2010-07-08 | 2016-06-07 | Skyonic Corporation | Carbon dioxide sequestration involving two-salt-based thermolytic processes |
| WO2012122496A1 (en) * | 2011-03-09 | 2012-09-13 | Skyonic Corporation | Carbon dioxide sequestration methods using group 2 silicates and chlor-alkali processes |
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| EP2809427A1 (en) | 2014-12-10 |
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| IL233577A0 (en) | 2014-08-31 |
| TW201335071A (zh) | 2013-09-01 |
| US20130202516A1 (en) | 2013-08-08 |
| WO2013106730A1 (en) | 2013-07-18 |
| AP2014007853A0 (en) | 2014-08-31 |
| AU2013203886B2 (en) | 2015-10-29 |
| KR20140111034A (ko) | 2014-09-17 |
| EP2809427A4 (en) | 2015-08-26 |
| BR112014017019A2 (pt) | 2017-06-13 |
| HK1205039A1 (en) | 2015-12-11 |
| HK1205976A1 (en) | 2015-12-31 |
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