JP2015212448A - Inner surface treatment agent for glove, and production method of glove using the same - Google Patents

Abstract

PROBLEM TO BE SOLVED: To provide a glove capable of achieving detachment ability when the glove is used, solving discomfort caused by factors such as sweat when the glove is worn during work, preventing getting rough of hands, and achieving smooth work ability because of high adhesion of the glove.SOLUTION: The glove has at least one layer of a rubber layer or resin layer, and an inner surface treatment agent for glove is bonded to an inner surface. The inner surface treatment agent has at least, (A) a flavor component, (B) a component for moisturizing which is a liquid state at 40°C, and (C) a powder, therefore discomfort such as odor caused by sweat is dissolved, and high detachment ability during use and a moisturizing effect to a hand are achieved.

Description

  The present invention relates to a glove that is excellent in detachability and moisturizing effect during use and is in close contact with the hand. More particularly, the present invention relates to a glove that realizes smooth workability due to elimination of discomfort caused by factors such as sweating, prevention of rough hand, and the like when wearing gloves during work.

  Currently, disposable gloves and the like are provided for work. The gloves used for the above work are gloves used for indoor and outdoor work such as medical use, accident prevention, housework such as dishwashing, gardening such as gardening, etc. It is often used for the purpose of protecting the product, and the selling price is also low, so it is widely accepted by consumers.

  Conventionally, synthetic rubbers such as acrylonitrile butadiene rubber (hereinafter referred to as “NBR”) and synthetic resins such as polyvinyl chloride are used for the gloves (for example, Patent Documents 1, 3, 4, etc.). This is because the material is extremely stretchable and strong even if it is thin, and because it has high adhesion to the hand, it can be used for fine work using the fingertips.

  However, when using the glove, the glove sticks to the hand due to the high adhesiveness characteristic of the material, which may cause a problem in the detachability when the glove is used. Also, since the above materials are poorly breathable, when working, moisture accumulates inside the gloves due to sweating, etc., and skin diseases such as rough hands and bacteria etc. propagate, so you will feel uncomfortable, such as odors There was a thing.

  Several solutions to the above problem have been introduced (for example, Patent Documents 2, 5 to 12, etc.). However, when using the above gloves, in order to improve the detachability, a lubricant that is an oily substance is directly applied to the inner surface of the glove, or a lubricant is enclosed in advance when the glove is molded. In the method, the detachability at the time of use may be inferior compared with the method of using powder in order to improve the detachability which is the prior art. In addition, since an oily substance is used as a lubricant, there are cases where it is felt uncomfortable due to contamination of the hand with the lubricant.

JP 2004-131885 A JP 2005-23444 A JP 2005-514238 A Japanese translation of PCT publication No. 2006-511637 Special table 2007-511322 gazette JP 2001-20112 A JP 2008-169503 A JP-A-11-229211 JP 2005-133245 A JP-T-2005-504136 Special table 2009-517563 JP 2004-204430 A

  The present invention has been made in view of the above circumstances, and has high detachability when using gloves, elimination of discomfort caused by factors such as sweating when wearing gloves during work, prevention of rough hands, etc., high adhesion It aims at providing the glove which realizes smooth workability by nature.

  As a result of intensive studies to solve the above-mentioned problems, the inventors of the present invention are gloves that adhere powder to the inner surface of the glove and have high detachability during use without impairing the adhesion of the glove. As a result, moisture is retained inside the gloves due to sweating, etc., and bacteria etc. are propagated when performing work. The present inventors have found that a moisturizing effect can be imparted to the hand, leading to the present invention.

In order to solve the above-mentioned problems, the present invention relates to the following [1] to [13], for example.
[1] A glove having at least one rubber layer or a resin layer and having powder attached to the inner surface of the glove, comprising at least the following components (A) to (C): Internal surface treatment agent.
One or more selected from component (A) fragrance component (B) One or more selected from one or more component (C) powders selected from moisturizing components that are liquid at 40 ° C.

[2] The mass ratio of the component (A) to the component (B) is
Component (A) / Component (B) (mass ratio) = 0.1 to 1000
The inner surface treating agent for gloves as described in [1], wherein

[3] Mixture (X) of the component (A) and the component (B)
When the component (C) is impregnated with the component (A), (B) or the mixture (X), the component (A), (B) or the mixture (X) and the component (C) And the mass ratio is
(Component (A), (B) or mixture (X)) / component (C) (mass ratio) = 0.001 to 0.2
The inner surface treating agent for gloves according to [1] or [2], wherein

[4] Glove inner surface treatment agent (M1) comprising the component (A) and the component (C).
Glove inner surface treatment agent (M2) comprising the component (B) and the component (C)
When the mass ratio between the inner surface treatment agent for gloves (M1) and the inner surface treatment agent for gloves (M2) is
Glove inner surface treatment agent (M1) / Glove inner surface treatment agent (M2) (mass ratio) = 0.1 to 1000
The inner surface treating agent for gloves according to any one of [1] to [3], wherein

  [5] The inner surface treatment agent for gloves according to any one of [1] to [4], wherein the viscosity of the components (A), (B) and the mixture (X) is 200 mPa · s or less.

  [6] The glove interior according to any one of [1] to [5], wherein the inner surface treatment agent for gloves further contains at least one component selected from component (D) nonionic surfactant. Surface treatment agent.

[7] The mass ratio of the component (A), (B) or mixture (X) to the component (D) is as follows:
(Component (A), (B) or mixture (X)) / component (D) (mass ratio) = 2-100
The inner surface treating agent for gloves according to any one of [1] to [6], wherein

[8] Mixture (Y1) of component (A) and component (D)
Mixture (Y2) of component (B) and component (D)
Mixture (Y3) of the mixture (X) and the component (D)
When the component (C) is impregnated with the mixture (Y1), (Y2) or (Y3), respectively, the mixture (Y1), (Y2) or (Y3) and the component (C) Mass ratio is
(Mixture (Y1), (Y2) or (Y3)) / component (C) (mass ratio) = 0.001 to 0.2
The inner surface treating agent for gloves according to any one of [1] to [7], wherein

[9] Glove inner surface treatment agent (M4) comprising the mixture (Y1) and the component (C).
Glove inner surface treatment agent (M5) comprising the mixture (Y2) and the component (C)
When the mass ratio between the inner surface treatment agent for gloves (M4) and the inner surface treatment agent for gloves (M5) is
Glove inner surface treatment agent (M4) / Glove inner surface treatment agent (M5) (mass ratio) = 0.1 to 1000
The inner surface treating agent for gloves according to any one of [1] to [8], wherein

  [10] The inner surface treating agent for gloves according to any one of [1] to [9], wherein the mixture (Y1), (Y2) and (Y3) have a viscosity of 200 mPa · s or less.

[11] Glove inner surface treatment agent (M3) comprising the mixture (X) and the component (C)
When the mass ratio of the glove inner surface treatment agent ((M1) + (M2)) or (M3) to the glove is
(Inner surface treatment agent for gloves ((M1) + (M2)) or (M3)) / gloves (mass ratio) = 0.005 to 0.075
The inner surface treatment agent for gloves according to any one of [1] to [10], wherein

[12] Glove inner surface treatment agent (M6) comprising the mixture (Y3) and the component (C)
When the glove inner surface treatment agent ((M4) + (M5)) or (M6) and the mass ratio of the glove,
(Glove inner surface treatment agent ((M4) + (M5)) or (M6)) / gloves (mass ratio) = 0.005 to 0.075
The inner surface treating agent for gloves according to any one of [1] to [11], wherein

  [13] When the inner surface treatment agent for glove is attached to the inner surface of the glove, the inner surface treatment agent for glove and the glove are put in a tumbler and stirred to adhere. 12] The method for producing a glove according to any one of the above.

  According to the present invention, high detachability when using gloves, elimination of discomfort caused by factors such as sweating when wearing gloves during work, prevention of rough hands, and smooth workability due to high adhesion are realized. Gloves can be provided.

  Hereinafter, the present invention will be specifically described.

  Although the material of the said glove used for this invention is not specifically limited, In order to respond | correspond to a fine operation | work, since high adhesiveness to a hand is required, it is preferable that it is a synthetic rubber or a synthetic resin.

  The synthetic rubber is not particularly limited, but any one selected from diene synthetic rubber such as NBR, synthetic isoprene, chloroprene rubber, silicone rubber and the like may be used in combination. Among these, diene-based synthetic rubber is preferable from the viewpoint of strength and price, and NBR is more preferable.

  Although the said synthetic resin is not specifically limited, You may use any 1 type selected from a polyvinyl chloride, an acrylic resin, a polyurethane, and polyethylene, or 2 or more types in combination. Among these, from the viewpoint of environmental consideration, acrylic resin, polyurethane, and polyethylene are preferable, and acrylic resin and polyurethane are more preferable.

  The glove used in the present invention may be colored or colorless. Further, it may be transparent or opaque.

  The gloves used in the present invention may be disposable or reusable.

  Although the said component (A) aromatic component used for this invention is not specifically limited, It is oil-soluble or water-soluble.

  Although the said component (A) fragrance | flavor component used for this invention is not specifically limited, A natural product or a synthetic | combination material may be sufficient, and 1 type, or 2 or more types chosen from a natural product and a synthetic | combination may be used. Moreover, if it is a natural product, the thing etc. which extracted the plant etc. with the solvent may be used, and what was squeezed may be used.

  Although the said component (A) fragrance | flavor component used for this invention is not specifically limited, What is generally called a fragrance | flavor may be used, and it is used for foodstuffs, such as a fragrance | flavor used for cosmetics, such as a skin lotion, and a flavor. You may use 1 type, or in combination of 2 or more types, such as a fragrance | flavor, the fragrance | flavor used for miscellaneous goods, such as a room colon, and the fragrance | flavor for detergents used for a softening agent. Among these, cosmetic fragrances, food fragrances, and detergent fragrances are preferable because they are in direct contact with the hand, and cosmetic fragrances and food fragrances are more preferable.

  The component (B) used in the present invention is not particularly limited as the moisturizing component that is liquid at 40 ° C., but is oil-soluble or water-soluble.

  The component (B) moisturizing component that is liquid at 40 ° C. used in the present invention is not particularly limited, but may be a natural product or a synthetic product, and one or two or more types selected from natural products and synthetic products are used in combination. May be.

  When the moisturizing component that is liquid at 40 ° C. used in the present invention is oil-soluble, it is not particularly limited, but one or more of animal and vegetable oils, mineral oils, ester oils, silicone oils, etc. are used in combination. May be. Among them, due to its high moisturizing properties, squalane, squalene, olive oil, rice germ oil, camellia oil, oil tea oil, argania spinosa kernel oil, jojoba oil, sweet almond oil, liquid paraffin, liquid isoparaffin, ethylhexyl palmitate, isonononyl isononanoate , Isodecyl isononanoate, isotridecyl isononanoate, cetyl ethylhexanoate, glyceryl tri-2-ethylhexanoate, glyceryl tri (caprylic acid / capric acid), dimethicone, dimethiconol, methylphenylpolysiloxane, modified silicone, and cyclic silicone are preferred. , Squalane, olive oil, camellia oil, oil tea oil, argania spinosa kernel oil, jojoba oil, liquid paraffin, liquid isoparaffin, ethylhexyl palmitate, isodecyl isononanoate, Isotridecyl nonanoate, cetyl ethylhexanoate, glyceryl tri-2-ethylhexanoate, glyceryl tri (caprylic acid / capric acid), dimethicone, dimethiconol, methylphenylpolysiloxane, cyclic silicone are preferred, squalane, olive oil, camellia oil, liquid paraffin Most preferred are liquid isoparaffin, isotridecyl isononanoate, dimethicone and methylphenyl polysiloxane.

  When the moisturizing component that is liquid at 40 ° C. used in the present invention is water-soluble, it is not particularly limited, but it may be used alone or in combination of two or more kinds such as plant extracts, polyhydric alcohols or saccharides. good. Among them, because of high moisturizing properties, aloe extract, aloe vera extract, seaweed extract, fruit juice, soybean extract, soymilk fermented extract, honey, royal jelly extract, BG, PG, glycerin, diglycerin, sorbitol solution, erythritol solution, trehalose solution, poly Oxyethylene methyl glucoside is preferred, and aloe extract, aloe vera extract, seaweed extract, fermented soymilk extract, honey, royal jelly extract, BG, PG, glycerin, sorbitol solution, erythritol solution, polyoxyethylene methyl glucoside are preferred, aloe vera extract, Soymilk fermented extract, royal jelly extract, BG, glycerin, and polyoxyethylene methyl glucoside are most preferred.

  Although the said component (C) powder used for this invention is not specifically limited, From a viewpoint of a usability | use_condition, it is preferable that an average particle diameter is 125 micrometers or less. Furthermore, 50 μm or less is preferable, and 15 μm or less is most preferable. When the average particle size of the component (C) powder exceeds 125 μm, when the glove obtained in the present invention is actually worn on the hand, it becomes rough and uncomfortable.

  Here, the average particle size means a particle size at an integrated value of 50% in the particle size distribution obtained by “particle size analysis—laser diffraction / scattering method” shown in JIS Z 8825: 2013.

  The above-mentioned “particle size analysis—laser diffraction / scattering method” is a method for measuring the particle size by utilizing the fact that the light intensity distribution of diffracted and scattered light varies depending on the particle size when laser light is applied to the particle. Yes, the particle size of “integrated value 50%” refers to the particle size at which the particle number reaches 50% of the total particle number when counting the number of particles from the smallest particle size.

  Although the said component (C) powder used for this invention is not specifically limited, Either inorganic powder or organic powder may be sufficient, and it uses it combining 1 type, or 2 or more types chosen from inorganic powder or organic powder. May be.

  When the component (C) powder used in the present invention is an inorganic powder, it is not particularly limited, but from the viewpoint of familiarity with the component (A) and the component (B), kaolin, diatomaceous earth, silica, talc Hectorite, bentonite and montmorillonite are preferred, kaolin, diatomaceous earth, silica and talc are preferred, and diatomaceous earth, silica and talc are most preferred.

  When the component (C) powder used in the present invention is an organic powder, it is not particularly limited. From the viewpoint of familiarity with the component (A) and the component (B), corn starch, synthetic resin, cyclodextrin , Silicone powder, silk powder, cellulose powder, nylon powder, polyethylene powder, polystyrene powder are preferred, corn starch, synthetic resin, silicone powder, silk powder, cellulose powder, nylon powder, polyethylene powder are preferred, corn starch, silicone powder Cellulose powder and polyethylene powder are most preferred.

The mass ratio of the component (A) and the component (B) used in the present invention is not particularly limited, but from the viewpoint of the balance between the aroma component and the moisturizing component (moderate fragrance and high moisturizing), the component (A) The mass ratio of the component (B) to the component (B) is preferably component (A) / component (B) (mass ratio) = 0.1 to 1000, more preferably 0.5 to 500, and most preferably 1 to 100. .
When component (A) / component (B) (mass ratio) is less than 0.1, a sufficient scent cannot be obtained.
Moreover, when a component (A) / component (B) (mass ratio) exceeds 1000, sufficient moisturizing power cannot be obtained.

When the component (C) is impregnated with the component (A), (B) or the mixture (X) used in the present invention, the component (A), (B) or the mixture (X) and the component (C) The mass ratio is not particularly limited, but from the viewpoint of uniform adhesion to the inner surface of the glove, (component (A), (B) or mixture (X)) / component (C) (mass ratio) = 0 0.001 to 0.2 are preferred. Furthermore, 0.005-0.15 is preferable and 0.01-0.1 is the most preferable.
When (component (A), (B) or mixture (X)) / component (C) (mass ratio) is less than 0.001, effects such as a moderate fragrance and high moisture retention cannot be obtained.
When (component (A), (B) or mixture (X)) / component (C) (mass ratio) exceeds 0.2, the component (A), (B) or mixture (X) is When impregnating each of the components (C), the powder cannot be processed and is hardened as a powder and is fooled, so that it cannot adhere uniformly to the inner surface of the glove.

  When the component (C) is impregnated with the component (A), (B) or the mixture (X) used in the present invention, there is no particular limitation. However, the components (A) and (B) are different from each other. The component (C) may be selected, or after mixing one or more selected from the component (C), the component (A), (B) or the mixture (X) may be impregnated.

In the above case, the inner surface treatment agent for gloves (M1) in which the component (A) is impregnated in the component (C), and the inner surface treatment for gloves in which the component (B) is impregnated in the component (C). The mass ratio with the agent (M2) is not particularly limited, but the glove inner surface treatment agent (M1) and the glove inner surface from the viewpoint of the balance between the aroma component and the moisturizing component (moderate fragrance and high moisturizing). The mass ratio with the treatment agent (M2) is preferably the inner surface treatment agent for gloves (M1) / the inner surface treatment agent for gloves (M2) (mass ratio) = 0.1 to 1000, and more preferably 0.5 to 500. Is preferable, and 1 to 100 is most preferable.
When the inner surface treatment agent for gloves (M1) / the inner surface treatment agent for gloves (M2) (mass ratio) is less than 0.1, a sufficient scent cannot be obtained.
Further, when the inner surface treatment agent for gloves (M1) / the inner surface treatment agent for gloves (M2) (mass ratio) exceeds 1000, sufficient moisturizing power cannot be obtained.

From the viewpoint of working time when impregnating the component (C), the viscosity of the components (A), (B) and the mixture (X) used in the present invention is determined from the components (A), (B) and the mixture ( The viscosity of X) is preferably 200 mPa · s or less. Furthermore, 150 mPa · s or less is preferable, and 100 mPa · s or less is most preferable.
When the viscosity of the components (A), (B) and the mixture (X) exceeds 200 mPa · s, the working time when impregnating the component (C) becomes very long, and the powder remains solid without being mixed. Get fooled.

  When measuring 200 mL of the measured substance in a 200 mL beaker and adjusting the viscosity to 25 ° C. in a thermostatic bath, the Toki Sangyo Co., Ltd. B-type rotational viscometer (model: TVB-10), rotor: M2, rotating at 30 rpm for 1 minute Use the value after Hereinafter, the viscosity is measured by this method unless otherwise specified.

  You may make the said inner surface treating agent for gloves used for this invention contain 1 or more types chosen from a component (D) nonionic surfactant further. The inner surface treating agent for gloves takes a step of impregnating the component (C) with the component (A), (B) or the mixture (X), but the component (A), (B) or the mixture ( X) may be composed of a plurality of components. At that time, when there is difficulty in compatibility between a plurality of components, it is improved by mixing with at least one selected from the above components (D).

  The component (D) nonionic surfactant used in the present invention is not particularly limited, but is polyoxyethylene (hereinafter referred to as “POE”) alkyl ether, POE hydrogenated castor oil, POE sorbite fatty acid ester, sorbitan fatty acid ester. POE sorbitan fatty acid ester, polyglycerin fatty acid ester, and POE glycerin fatty acid ester are preferable. Furthermore, POE alkyl ether, POE hydrogenated castor oil, POE sorbite fatty acid ester, polyglycerol fatty acid ester, and POE glycerin fatty acid ester are preferable, and POE alkyl ether, POE sorbite fatty acid ester, polyglycerol fatty acid ester, and POE glycerin fatty acid ester are most preferable.

The mass ratio between the component (A), (B) or mixture (X) used in the present invention and one or more selected from the component (D) is not particularly limited, but from the viewpoint of compatibility with each other, It is preferable that (component (A), (B) or mixture (X)) / component (D) (mass ratio) = 2-100. Furthermore, 3-50 are preferable and 5-30 are the most preferable.
When (component (A), (B) or mixture (X)) / component (D) (mass ratio) is less than 2, sufficient fragrance and moisturizing power cannot be obtained.
Further, when (component (A), (B) or mixture (X)) / component (D) (mass ratio) exceeds 100, the compatibility of each of the components (A), (B) or mixture (X) I can't get an improvement.

A mixture (Y1) of the component (A) and the component (D) used in the present invention, a mixture (Y2) of the component (B) and the component (D), the mixture (X) and the component (D )), The mass ratio of the mixture (Y1), (Y2) or (Y3) and the component (C) is not particularly limited, but the uniform adhesion to the inner surface of the glove is not limited. From the viewpoint, (mixture (Y1), (Y2) or (Y3)) / component (C) (mass ratio) = 0.001 to 0.2 is preferable. Furthermore, 0.005-0.15 is preferable and 0.01-0.1 is the most preferable.
When (mixture (Y1), (Y2) or (Y3)) / component (C) (mass ratio) is less than 0.001, it is not possible to obtain effects such as a moderate fragrance and high moisture retention.
When (mixture (Y1), (Y2) or (Y3)) / component (C) (mass ratio) exceeds 0.2, the mixture (Y1), (Y2) or (Y3) is replaced with the above component ( When impregnating each of C), the powder does not get stuck and remains as a powder and becomes fooled, so that it cannot adhere uniformly to the inner surface of the glove.

From the viewpoint of working time when the component (C) is impregnated, the viscosity of the mixture (Y1), (Y2) and (Y3) used in the present invention is the above mixture (Y1), (Y2) and (Y3). The viscosity is preferably 200 mPa · s or less. Furthermore, 150 mPa · s or less is preferable, and 100 mPa · s or less is most preferable.
When the viscosity of the mixture (Y1), (Y2) and (Y3) exceeds 200 mPa · s, the working time when impregnating the component (C) becomes very long, and it does not get stuck and becomes a powder. become.

When the mixture (X) used in the present invention is the glove inner surface treatment agent (M3) impregnated with the component (C), the glove inner surface treatment agent ((M1) + (M2)) or ( The mass ratio between M3) and the glove is not particularly limited. From the viewpoint of detachability during use, (glove inner surface treatment agent ((M1) + (M2)) or (M3)) / glove (mass) Ratio) = 0.005 to 0.075. Furthermore, 0.0008-0.05 are preferable and 0.001-0.03 are the most preferable.
When the (inner surface treatment agent for gloves ((M1) + (M2)) or (M3)) / gloves (mass ratio) is less than 0.0005, high detachability during use cannot be realized.
Moreover, when the (inner surface treatment agent for gloves ((M1) + (M2)) or (M3)) / gloves (mass ratio) exceeds 0.075, high adhesiveness will be inhibited and it cannot respond to fine work.

Glove inner surface treatment agent (M4) of the mixture (Y1) and the component (C) used in the present invention, Glove inner surface treatment agent (M5) of the mixture (Y2) and the component (C), When the inner surface treatment agent for gloves (M6) of the mixture (Y3) and the component (C) is used, the inner surface treatment agent for gloves ((M4) + (M5)) or (M6) and the gloves The mass ratio is not particularly limited, but from the viewpoint of detachability during use, (glove inner surface treatment agent ((M4) + (M5)) or (M6)) / glove (mass ratio) = 0.0005. ~ 0.075 is preferred. Furthermore, 0.0008-0.05 are preferable and 0.001-0.03 are the most preferable.
When the (inner surface treatment agent for gloves ((M4) + (M5)) or (M6)) / gloves (mass ratio) is less than 0.0005, high detachability during use cannot be realized.
Moreover, when the (inner surface treatment agent for gloves ((M4) + (M5)) or (M6)) / gloves (mass ratio) exceeds 0.075, high adhesiveness will be inhibited and it cannot respond to fine work.

  In addition to the components described above, the components used in the present invention include, for example, fats and oils, waxes, fatty acids, surfactants, antifungal agents, antibacterial agents, vitamins including ascorbic acids, amino acids, hyaluronic acid, ceramides (natural Can be blended as appropriate within a range that does not impair the effects of the present invention.

  Here, the manufacturing process of a glove is demonstrated.

  In the present invention, the glove inner surface treatment agent is adhered to the inner surface of the glove, thereby ensuring improvement in the detachability of the glove. And the method of attaching the inner surface treatment agent for gloves to the inner surface of the glove is not particularly limited, but a method of directly spraying the inner surface treatment agent for gloves. A method in which the inner surface of the glove is immersed in a dispersion of the inner surface treatment agent for gloves, and the inner surface treatment agent for gloves is uniformly adhered, followed by drying. A method of stirring the glove and the inner surface treatment agent for gloves in a tumbler is preferred.

  The tumbler refers to a drum type washing and drying machine that dries while rotating (or cradle movement) with the wind.

  In the present invention, the inner surface treatment agent for gloves (M1) is prepared from (M6), and then a mixture selected from the inner surface treatment agents for gloves (M1) to (M6) is attached to the inner surface of the glove. A process will be taken.

  Therefore, in the manufacturing process of gloves, the method of reducing the step of applying heat to the component (A) fragrance component as much as possible, and attaching the inner surface treatment agent for gloves to the inner surface of the glove from the viewpoint of preventing the fragrance component from changing its odor, A method of stirring the glove and the inner surface treatment agent for the glove in a tumbler is preferable.

  EXAMPLES The present invention will be described in more detail with reference to examples below, but the present invention is not limited to these examples. In addition, the unit of the numerical value which shows content of each component in the following Tables 1-9 shall be the mass% unless there is particular description.

About the average particle diameter of the said component (C) powder Example 1-8 shown in Table 1 was prepared as shown below, and evaluation was performed.

<Preparation method>
Component (A) and component (B) were mixed in the proportions shown in Table 1 and confirmed to be uniformly dispersed. The mixture (X) is added to a household juicer mixer (Milcer IFM-650D manufactured by Iwatani Corporation, hereinafter referred to as “mixer”) so that the total amount becomes 20 g with respect to the component (C) in the ratio shown in Table 1. It mixed and it confirmed that it was disperse | distributing uniformly. NBR gloves (Tecuroplane NBR-1000 NAT manufactured by Utsunomiya Manufacturing Co., Ltd.) turned inside into a plastic bag (polybag unipack L-4, 480 mm x 340 mm x 0.04 mm, manufactured by Nippon Production Co., Ltd., hereinafter referred to as "polybag") , M size, hereinafter referred to as “NBR gloves”) 10 sheets (mass 55 g) were added, and then an appropriate amount of the inner surface treatment agent for gloves (M3) prepared by impregnating component (C) with mixture (X) was prepared. I put it in. After closing the mouth of the plastic bag and shaking it by hand 20 times, the gloves were taken out and prepared by removing the excess inner surface treatment agent (M3) for gloves while turning over. The mass ratio between the inner surface treatment agent for gloves (M3) adhering to the glove and the glove before adhesion was as shown in Table 1.

<Evaluation>
The sensory evaluation was performed by 10 panelists. The prepared gloves were put on the dominant hand of each paneler and light work was performed for 1 hour. After removing the gloves, each panelist performed a sensory evaluation on “feel when wearing gloves” and calculated an evaluation standard from the average value of the 10 persons. The second decimal place in the average value is rounded off.
<Evaluation point>
5: Good 4: Slightly good 3: Not good 2: Not good 1: Not good <Evaluation criteria>
5: The average value of 10 people is 4.2 or more, 5.0 or less 4: The average value of 10 people is 3.4 or more, less than 4.2 3: The average value of 10 people is 2.6 or more, 3.4 Less than 2: Average value of 10 people is 1.8 or more, less than 2.6 1: Average value of 10 people is 1.0 or more, less than 1.8

Table 1

About (mass ratio of component (A) / component (B)) Examples 9 to 15 and Comparative Examples 1 and 2 shown in Table 2 were prepared as shown below and evaluated.

<Preparation method>
Component (A) and component (B) were mixed in the proportions shown in Table 2 and confirmed to be uniformly dispersed. Ingredients (A), (B) or mixture (X) are mixed in a mixer so that the total amount is 20 g with respect to component (C) at a ratio shown in Table 2. confirmed. Ten NBR gloves turned upside down (mass 55 g) were put into a plastic bag, and then an appropriate amount of the prepared inner surface treatment agent for gloves (M1), (M2) or (M3) was put. After closing the mouth of the plastic bag and shaking 20 times by hand, the gloves were taken out, and the inside surface treatment agent for gloves (M1), (M2) or (M3) was removed while turning over. The mass ratio between the inner surface treatment agent for gloves (M1), (M2) or (M3) attached to the gloves and the gloves before attachment was as shown in Table 2.

<Evaluation>
The sensory evaluation was performed by 10 panelists. The prepared gloves were put on the dominant hand of each paneler and light work was performed for 1 hour. After removing the gloves, each panelist performed sensory evaluation on “comfort by fragrance” and “moisturizing”, and calculated the evaluation criteria from the average value of the 10 persons. The second decimal place in the average value is rounded off.
<Evaluation point>
5: Good 4: Slightly good 3: Not good 2: Not good 1: Not good <Evaluation criteria>
5: The average value of 10 people is 4.2 or more, 5.0 or less 4: The average value of 10 people is 3.4 or more, less than 4.2 3: The average value of 10 people is 2.6 or more, 3.4 Less than 2: Average value of 10 people is 1.8 or more, less than 2.6 1: Average value of 10 people is 1.0 or more, less than 1.8

Table 2

About the above (mass ratio of mixture (X) / component (C)) Examples 16 to 22 shown in Table 3 were prepared as shown below and evaluated.

<Preparation method>
Component (A) and component (B) were mixed in the proportions shown in Table 3 and confirmed to be uniformly dispersed. With respect to the component (C), the mixture (X) was mixed in the mixer so that the total amount was 20 g at the ratio shown in Table 3, and it was confirmed that the mixture was uniformly dispersed. Ten NBR gloves turned upside down (mass 55 g) were put into a plastic bag, and then an appropriate amount of the prepared inner surface treatment agent for gloves (M3) was put. After closing the mouth of the plastic bag and shaking it by hand 20 times, the gloves were taken out and prepared by removing the excess inner surface treatment agent (M3) for gloves while turning over. The mass ratio between the inner surface treatment agent for gloves (M3) adhering to the glove and the glove before adhesion was as shown in Table 3.

<Evaluation>
The sensory evaluation was performed by 10 panelists. The prepared gloves were put on the dominant hand of each paneler and light work was performed for 1 hour. As for “comfort and moisturizing by scent”, after removing gloves, each panelist performs a sensory evaluation on “comfort by scent” and “moisturizing” respectively. Was calculated. The second decimal place in the average value is rounded off. For “uniformity”, the gloves turned upside down by each panelist were visually evaluated, and the evaluation criteria were calculated from the average value of the 10 persons. The second decimal place in the average value is rounded off.
<Evaluation point>
5: Good 4: Slightly good 3: Neither good 2: Not good 1: Not good <Evaluation criteria for comfort and moisture retention by fragrance>
5: The average value of 10 people is 8.4 or more, 10.0 or less 4: The average value of 10 people is 6.8 or more, less than 8.4 3: The average value of 10 people is 5.2 or more, 6.8 Less than 2: Average value of 10 people is 3.6 or more, less than 5.2 1: Average value of 10 people is 2.0 or more and less than 3.6 <Evaluation criteria for uniformity>
5: The average value of 10 people is 4.2 or more, 5.0 or less 4: The average value of 10 people is 3.4 or more, less than 4.2 3: The average value of 10 people is 2.6 or more, 3.4 Less than 2: Average value of 10 people is 1.8 or more, less than 2.6 1: Average value of 10 people is 1.0 or more, less than 1.8

Table 3

About the above (mass ratio of the inner surface treating agent for gloves (M1) / the inner surface treating agent for gloves (M2)) Examples 23 to 29 shown in Table 4 were prepared and evaluated as shown below.

  The component (A) and the component (C) were mixed by a mixer so that the total was 20 g at the ratio shown in Table 4, and it was confirmed that they were uniformly dispersed. The component (B) and the component (C) were mixed by a mixer so that the total was 20 g at the ratio shown in Table 4, and it was confirmed that they were uniformly dispersed. Ten NBR gloves turned upside down (mass 55 g) were put into a plastic bag, and then, the appropriate amounts of the prepared inner surface treatment agents for gloves (M1) and (M2) were put in a mass ratio shown in Table 4. After closing the mouth of the plastic bag and shaking 20 times by hand, the glove was taken out and prepared by removing the excess inner surface treatment agents (M1) and (M2) for gloves while turning over. The mass ratio between the inner surface treatment agents for gloves (M1) and (M2) attached to the gloves and the gloves before attachment was as shown in Table 4.

<Evaluation>
The sensory evaluation was performed by 10 panelists. The prepared gloves were put on the dominant hand of each paneler and light work was performed for 1 hour. After removing the gloves, each panelist performed sensory evaluation on “comfort by fragrance” and “moisturizing”, and calculated the evaluation criteria from the average value of the 10 persons. The second decimal place in the average value is rounded off.
<Evaluation point>
5: Good 4: Slightly good 3: Not good 2: Not good 1: Not good <Evaluation criteria>
5: The average value of 10 people is 4.2 or more, 5.0 or less 4: The average value of 10 people is 3.4 or more, less than 4.2 3: The average value of 10 people is 2.6 or more, 3.4 Less than 2: Average value of 10 people is 1.8 or more, less than 2.6 1: Average value of 10 people is 1.0 or more, less than 1.8

Table 4

About the viscosity of the said mixture (X) Examples 30-34 shown in Table 5 were prepared as shown below, and evaluation was performed.

<Preparation method>
Component (A) and component (B) were mixed in the proportions shown in Table 5 and confirmed to be uniformly dispersed. To the component (C), the mixture (X) was mixed in the mixer so that the total amount was 20 g at the ratio shown in Table 5.

<Evaluation>
The sensory evaluation was performed by 10 panelists. As for each paneler, “Easy to impregnate the component (C) of the mixture (X)”, it is visually confirmed whether the droplets of the mixture (X) are uniformly impregnated with respect to the component (C) after mixing. Evaluation was performed and the evaluation standard was calculated from the average value of the 10 persons. The second decimal place in the average value is rounded off.
<Evaluation point>
5: Good 4: Slightly good 3: Not good 2: Not good 1: Not good <Evaluation criteria>
5: The average value of 10 people is 4.2 or more, 5.0 or less 4: The average value of 10 people is 3.4 or more, less than 4.2 3: The average value of 10 people is 2.6 or more, 3.4 Less than 2: Average value of 10 people is 1.8 or more, less than 2.6 1: Average value of 10 people is 1.0 or more, less than 1.8

Table 5

About the above (mass ratio of mixture (X) / component (D)) Examples 35 to 39 shown in Table 6 were prepared as shown below and evaluated.

<Preparation method>
Component (A), component (B), and component (D) were mixed in the proportions shown in Table 6 and confirmed to be uniformly dispersed. With respect to the component (C), the mixture (Y3) was mixed with a mixer so that the total was 20 g at the ratio shown in Table 6, and it was confirmed that the mixture was uniformly dispersed. Ten NBR gloves turned upside down (mass 55 g) were put into a plastic bag, and then an appropriate amount of the prepared inner surface treatment agent for gloves (M6) was put. After closing the mouth of the plastic bag and shaking 20 times by hand, the gloves were taken out, and the inside surface treatment agent for gloves (M6) was removed while turning over. The mass ratio between the inner surface treatment agent for gloves (M6) adhering to the gloves and the gloves before adhering was as shown in Table 6.

<Evaluation>
The sensory evaluation was performed by 10 panelists. The prepared gloves were put on the dominant hand of each paneler and light work was performed for 1 hour. As for “comfort and moisturizing by scent”, after removing gloves, each panelist performs a sensory evaluation on “comfort by scent” and “moisturizing” respectively. Was calculated. The second decimal place in the average value is rounded off. About "compatibility of mixture (X) and component (D)", after mixing, the mixture (Y3) is visually evaluated to determine whether it is uniformly dispersed, and the evaluation standard is determined from the average value of the 10 persons. Calculated. The second decimal place in the average value is rounded off.
<Evaluation point>
5: Good 4: Slightly good 3: Neither good 2: Not good 1: Not good <Evaluation criteria for comfort and moisture retention by fragrance>
5: The average value of 10 people is 8.4 or more, 10.0 or less 4: The average value of 10 people is 6.8 or more, less than 8.4 3: The average value of 10 people is 5.2 or more, 6.8 Less than 2: Average value of 10 people is 3.6 or more, Less than 5.2 1: Average value of 10 people is 2.0 or more and less than 3.6 <Compatibility of mixture (X) and component (D) Evaluation criteria>
5: The average value of 10 people is 4.2 or more, 5.0 or less 4: The average value of 10 people is 3.4 or more, less than 4.2 3: The average value of 10 people is 2.6 or more, 3.4 Less than 2: Average value of 10 people is 1.8 or more, less than 2.6 1: Average value of 10 people is 1.0 or more, less than 1.8

Table 6

About the above (inner surface treatment agent for gloves (M3) / glove mass ratio) Examples 40 to 46 shown in Table 7 were prepared and evaluated as shown below.

<Preparation method>
Component (A) and component (B) were mixed in the proportions shown in Table 7 and confirmed to be uniformly dispersed. With respect to the component (C), the mixture (X) was mixed in the mixer so that the total amount was 20 g at the ratio shown in Table 7, and it was confirmed that the mixture was uniformly dispersed. Ten NBR gloves turned upside down (mass 55 g) were put into a plastic bag, and then an appropriate amount of the prepared inner surface treatment agent for gloves (M3) was put. After closing the mouth of the plastic bag and shaking it by hand 20 times, the gloves were taken out and prepared by removing the excess inner surface treatment agent (M3) for gloves while turning over. Table 7 shows the mass ratio between the inner surface treatment agent for gloves (M3) attached to the gloves and the gloves before attachment.

<Evaluation>
The sensory evaluation was performed by 10 panelists. The prepared gloves were put on the dominant hand of each paneler and light work was performed for 1 hour. After removing the gloves, each panelist performed a sensory evaluation on “detachability (easy to put on and remove gloves)” and “adhesion when wearing gloves”, and the average value of the 10 people Evaluation criteria were calculated from The second decimal place in the average value is rounded off.
<Evaluation point>
5: Good 4: Slightly good 3: Not good 2: Not good 1: Not good <Evaluation criteria>
5: The average value of 10 people is 4.2 or more, 5.0 or less 4: The average value of 10 people is 3.4 or more, less than 4.2 3: The average value of 10 people is 2.6 or more, 3.4 Less than 2: Average value of 10 people is 1.8 or more, less than 2.6 1: Average value of 10 people is 1.0 or more, less than 1.8

Table 7

  From Examples 47 to 53 shown in Table 8 and Table 9, good gloves were obtained.

Table 8

Table 9

In the examples and comparative examples, the following were used.
* 1 FRAGRANCE TJP-M-002050, manufactured by Takasago International Corporation
* 2 Rose water manufactured by Ichimaru Falcos * 3 ORGANIC SWEET ORANGE OIL manufactured by Kobayashi Fragrance
* 4 Lavender oil manufactured by Koei Kogyo Co., Ltd. * 5 Gyunu Flavor G-0841 manufactured by Takasago International Corporation
* 6 Rose extract manufactured by Koei Kogyo Co., Ltd.

The present invention provides a glove that realizes smooth workability with high adhesion, high detachability when using gloves, elimination of discomfort caused by factors such as sweating when hands are worn, prevention of rough hands, etc. The purpose is to provide.

Claims (6)

An inner surface treatment for a glove having at least one rubber layer or resin layer and having powders adhered to the inner surface, wherein the inner surface treatment includes at least the following components (A) to (C): Agent.
One or more selected from component (A) fragrance component (B) One or more selected from one or more component (C) powders selected from moisturizing components that are liquid at 40 ° C. When the mixture (X) of the components (A) and (B) is used, when the component (C) is impregnated with the component (A), (B) or the mixture (X), the component (A) , (B) or the mixture (X) and the component (C) have a mass ratio of
(Component (A), (B) or mixture (X)) / component (C) (mass ratio) = 0.001 to 0.2
The inner surface treating agent for gloves according to claim 1, wherein: The inner surface treating agent for gloves according to claim 1 or 2, wherein the viscosity of the components (A), (B) and the mixture (X) is 200 mPa · s or less. The inner surface treatment agent for gloves according to any one of claims 1 to 3, wherein the inner surface treatment agent for gloves further contains at least one selected from the component (D) nonionic surfactant. The mass ratio of the above inner surface treatment agent for gloves and gloves is
Inner surface treatment agent for gloves / gloves (mass ratio) = 0.005 to 0.075
The inner surface treating agent for gloves according to any one of claims 1 to 4, wherein: 6. The inner surface for a glove according to claim 1, wherein when the inner surface treatment agent for a glove is adhered to the inner surface of the glove, the glove and the inner surface treatment agent for a glove are stirred in a tumbler. A method for producing a glove using a treatment agent.