JP2015187650A - image forming apparatus - Google Patents

image forming apparatus Download PDF

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JP2015187650A
JP2015187650A JP2014064817A JP2014064817A JP2015187650A JP 2015187650 A JP2015187650 A JP 2015187650A JP 2014064817 A JP2014064817 A JP 2014064817A JP 2014064817 A JP2014064817 A JP 2014064817A JP 2015187650 A JP2015187650 A JP 2015187650A
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image
group
forming apparatus
contact point
image forming
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JP6149773B2 (en
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泰岳 松本
Yasutake Matsumoto
泰岳 松本
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Fujifilm Business Innovation Corp
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Fuji Xerox Co Ltd
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Abstract

PROBLEM TO BE SOLVED: To suppress a deterioration in removal performance.SOLUTION: An image forming apparatus includes an image holding body 31 that rotates to hold an image on the lateral face, and a removal member 361 that removes a material attached to the lateral face. The lateral face of the image holding body 31 is formed of a first material, which has a loss tangent of 0.015 or more and 0.035 or less when given a vibration of 0.5 Hz at 28°C. The removal member 361 includes a contact part 3611 that is formed of a second material having a value of 100% modulus of 7 mega Pascal or more and is in contact at a contact point with an area on the lateral face moved to the upper side in the gravity direction, and a support part 3612 that is formed of a third material having a lower hardness than that of the second material and supports the contact part 3611 from the opposite side of the contact point. The normal vector of an opposing face F1 arranged opposite to the upstream side of the contact point in a direction of rotation of the image holding body 31 does not include a component directed to the upper side in the gravity direction.

Description

本発明は、画像形成装置に関する。   The present invention relates to an image forming apparatus.

特許文献1には、HU(ユニバーサル硬さ値)が150N/mm2以上220N/mm2以下であり、かつ、弾性変形率Woが44%以上65%以下である表面を有する電子写真感光体表面に対して脂肪酸金属塩を供給する脂肪酸金属塩供給手段を有し、かつ、クリーニングブレードのゴム硬度が78度以上99度以下となるようにした画像形成装置が記載されている。   Patent Document 1 discloses an electrophotographic photosensitive member surface having a surface with an HU (Universal Hardness Value) of 150 N / mm 2 or more and 220 N / mm 2 or less and an elastic deformation rate Wo of 44% or more and 65% or less. An image forming apparatus having a fatty acid metal salt supply means for supplying a fatty acid metal salt and having a cleaning blade having a rubber hardness of 78 degrees or more and 99 degrees or less is described.

特開2005−164775号公報JP 2005-164775 A

本発明は、除去性能の劣化を抑制することを目的とする。   An object of this invention is to suppress degradation of removal performance.

本発明の請求項1に係る画像形成装置は、回転して側面に像を保持する像保持体と、前記側面に付着した物質を除去する除去部材とを有し、前記像保持体の前記側面は、摂氏28度で0.5ヘルツの振動を与えたときの損失正接が0.015以上、0.035以下の第1材料により形成され、前記除去部材は、前記側面と接触点で接触する接触部と、前記接触点の反対側から当該接触部を支持する支持部とを有し、前記接触部が、100%モジュラスの値が7メガパスカル以上である第2材料で形成され、前記支持部が、前記第2材料よりも硬度が低い第3材料で形成され、前記像保持体の回転方向における前記接触点の上流側に対向する対向面の法線ベクトルが、重力方向の上に向かう成分を含まないことを特徴とする。   An image forming apparatus according to a first aspect of the present invention includes an image carrier that rotates to hold an image on a side surface, and a removal member that removes a substance attached to the side surface, and the side surface of the image carrier. Is formed of a first material having a loss tangent of 0.015 or more and 0.035 or less when a vibration of 0.5 hertz is applied at 28 degrees Celsius, and the removal member contacts the side surface at a contact point. A contact portion and a support portion that supports the contact portion from the opposite side of the contact point, and the contact portion is formed of a second material having a 100% modulus value of 7 megapascals or more. The portion is formed of a third material whose hardness is lower than that of the second material, and the normal vector of the facing surface facing the upstream side of the contact point in the rotation direction of the image carrier is directed upward in the direction of gravity. It is characterized by not containing any components.

本発明の請求項2に係る画像形成装置は、請求項1に記載の態様において、前記接触点は、前記側面のうち重力方向の上に移動している領域にあることを特徴とする。
本発明の請求項3に係る画像形成装置は、請求項1または2に記載の態様において、前記像保持体は、前記側面の前記接触点における法線ベクトルが、重力方向の上に向かう成分を含まないことを特徴とする。
本発明の請求項4に係る画像形成装置は、請求項1から3のいずれか1項に記載の態様において、前記第1材料は、電荷輸送能を有する下記一般式(1)に示すブタジエン構造を有する化合物と、下記一般式(2)で表される繰り返し単位及び下記一般式(3)で表される繰り返し単位を含むポリカーボネート共重合体と、を含むことを特徴とする。

Figure 2015187650
(一般式(1)中、R1、R2、R3、R4、R5、及び、R6は、それぞれ同一であっても異なっていてもよく、水素原子、アルキル基、アルコキシル基、ハロゲン原子、又は、置換若しくは無置換のアリ−ル基を示す。m及びnは0又は1を示す。)
Figure 2015187650
Figure 2015187650
(一般式(2)及び一般式(3)中、R7、R8、R9、及び、R10は、各々独立に、水素原子、ハロゲン原子、炭素数1以上6以下のアルキル基、炭素数5以上7以下のシクロアルキル基、又は、炭素数6以上12以下のアリール基を表す。Xは、フェニレン基、ビフェニレン基、ナフチレン基、直鎖若しくは分岐アルキレン基、又は、シクロアルキレン基を表す。) An image forming apparatus according to a second aspect of the present invention is the image forming apparatus according to the first aspect, wherein the contact point is in a region of the side surface that is moving in the direction of gravity.
According to a third aspect of the present invention, in the image forming apparatus according to the first or second aspect, the image carrier has a component in which a normal vector at the contact point on the side surface is directed upward in the gravity direction. It is not included.
The image forming apparatus according to a fourth aspect of the present invention is the image forming apparatus according to any one of the first to third aspects, wherein the first material has a butadiene structure represented by the following general formula (1) having a charge transporting ability. And a polycarbonate copolymer containing a repeating unit represented by the following general formula (2) and a repeating unit represented by the following general formula (3).
Figure 2015187650
(In the general formula (1), R 1 , R 2 , R 3 , R 4 , R 5 , and R 6 may be the same or different, and each represents a hydrogen atom, an alkyl group, an alkoxyl group, A halogen atom or a substituted or unsubstituted aryl group, and m and n each represents 0 or 1)
Figure 2015187650
Figure 2015187650
(In General Formula (2) and General Formula (3), R 7 , R 8 , R 9 , and R 10 are each independently a hydrogen atom, a halogen atom, an alkyl group having 1 to 6 carbon atoms, carbon A cycloalkyl group having 5 to 7 carbon atoms, or an aryl group having 6 to 12 carbon atoms, X represents a phenylene group, a biphenylene group, a naphthylene group, a linear or branched alkylene group, or a cycloalkylene group. .)

請求項1、4に係る発明によれば、この構成を有しない場合に比べて除去性能の劣化を抑制することができる。
請求項2、3に係る発明によれば、除去された物質が像保持体の側面上に堆積し難くすることができる。
According to the first and fourth aspects of the invention, it is possible to suppress the deterioration of the removal performance as compared with the case where this configuration is not provided.
According to the second and third aspects of the invention, the removed substance can be made difficult to deposit on the side surface of the image carrier.

本発明の一実施形態に係る画像形成装置の全体構成を示す図である。1 is a diagram illustrating an overall configuration of an image forming apparatus according to an embodiment of the present invention. ドラムクリーナの構成を示す図である。It is a figure which shows the structure of a drum cleaner. 図2における領域IIIを拡大した図である。It is the figure which expanded the area | region III in FIG. 像保持体に対する除去部材の配置を説明するための図である。It is a figure for demonstrating arrangement | positioning of the removal member with respect to an image holding body. 変形例におけるドラムクリーナの構成を示す図である。It is a figure which shows the structure of the drum cleaner in a modification. 変形例におけるドラムクリーナの構成を示す図である。It is a figure which shows the structure of the drum cleaner in a modification.

1.実施形態
1−1.画像形成装置の全体構成
図1は、本発明の一実施形態に係る画像形成装置1の全体構成を示す図である。
以下、図において、画像形成装置1の各構成の配置を説明するため、各構成が配置される空間をxyz右手系座標空間として表す。図に示す座標記号のうち、白い円の中に黒い円を描いた記号は、紙面奥側から手前側に向かう矢印を表している。空間においてx軸に沿う方向をx軸方向という。また、x軸方向のうち、x成分が増加する方向を+x方向といい、x成分が減少する方向を−x方向という。y、z成分についても、上記の定義に沿ってy軸方向、+y方向、−y方向、z軸方向、+z方向、−z方向を定義する。
1. Embodiment 1-1. 1 is a diagram showing an overall configuration of an image forming apparatus 1 according to an embodiment of the present invention.
Hereinafter, in order to explain the arrangement of each component of the image forming apparatus 1, the space in which each component is arranged is expressed as an xyz right-handed coordinate space. Of the coordinate symbols shown in the figure, a symbol in which a black circle is drawn in a white circle represents an arrow heading from the back side to the near side. A direction along the x-axis in space is referred to as an x-axis direction. Of the x-axis directions, the direction in which the x component increases is referred to as + x direction, and the direction in which the x component decreases is referred to as -x direction. For the y and z components, the y-axis direction, + y direction, -y direction, z-axis direction, + z direction, and -z direction are defined according to the above definition.

図1に示すように、画像形成装置1は、現像部13と、転写部14と、定着部15と、搬送部16とを有している。
搬送部16は、容器と搬送ロールとを有する。容器には媒体としての用紙Pが収容される。容器に収容されている用紙Pは、図示しない制御部の指示により搬送ロールによって1枚ずつ取り出され、用紙搬送路を経由して転写部14へと搬送される。なお、媒体は用紙に限らず、例えば樹脂製のシートなどであってもよい。要するに、媒体は、表面に画像を記録し得るものであればよい。
As illustrated in FIG. 1, the image forming apparatus 1 includes a developing unit 13, a transfer unit 14, a fixing unit 15, and a conveyance unit 16.
The conveyance part 16 has a container and a conveyance roll. The container stores paper P as a medium. The paper P stored in the container is taken out one by one by a transport roll according to an instruction from a control unit (not shown), and is transported to the transfer unit 14 via a paper transport path. The medium is not limited to paper, and may be a resin sheet, for example. In short, the medium may be any medium that can record an image on the surface.

現像部13は、像保持体31と、帯電器32と、露光装置33と、現像装置34と、一次転写ロール35と、ドラムクリーナ36とを有している。像保持体31は、電荷発生層や電荷輸送層を有する感光体ドラムであり、図示しない駆動部により図中の矢線D13の方向に回転させられる。   The developing unit 13 includes an image carrier 31, a charger 32, an exposure device 33, a developing device 34, a primary transfer roll 35, and a drum cleaner 36. The image carrier 31 is a photosensitive drum having a charge generation layer and a charge transport layer, and is rotated in the direction of an arrow D13 in the drawing by a driving unit (not shown).

像保持体31の側面を形成する材料(以下、第1材料という)は、損失正接が0.015以上、0.035以下となるものを用いる。   As a material for forming the side surface of the image carrier 31 (hereinafter referred to as a first material), a material having a loss tangent of 0.015 or more and 0.035 or less is used.

ここで、損失正接(以下、「tanδ」とも表記する)とは、K6394−2007「加硫ゴム及び熱可塑性ゴム−動的性質の求め方」に定める「損失正接」であって、損失弾性係数と貯蔵弾性係数との比である。損失正接は、材料の種類や温度など測定条件により異なる値を示す。tanδの「δ」は、損失角である。ここでは、測定条件を摂氏28度で0.5ヘルツの振動を与えたとき、とした。   Here, the loss tangent (hereinafter also referred to as “tan δ”) is a “loss tangent” defined in K6394-2007 “Vulcanized rubber and thermoplastic rubber—How to obtain dynamic properties”, and has a loss elastic modulus. And the storage elastic modulus. Loss tangent shows different values depending on measurement conditions such as material type and temperature. “δ” of tan δ is a loss angle. Here, the measurement condition is set to be when the vibration of 0.5 hertz is given at 28 degrees Celsius.

具体的には、第1材料として適した材料に、例えば、2,5−ビス(p−ジエチルアミノフェニル)−1,3,4−オキサジアゾール等のオキサジアゾール誘導体、1,3,5−トリフェニル−ピラゾリン、1−[ピリジル−(2)]−3−(p−ジエチルアミノスチリル)−5−(p−ジエチルアミノスチリル)ピラゾリン等のピラゾリン誘導体、トリフェニルアミン、N,N′−ビス(3,4−ジメチルフェニル)ビフェニル−4−アミン、トリ(p−メチルフェニル)アミニル−4−アミン、ジベンジルアニリン等の芳香族第3級アミノ化合物、N,N′−ビス(3−メチルフェニル)−N,N′−ジフェニルベンジジン等の芳香族第3級ジアミノ化合物、3−(4′−ジメチルアミノフェニル)−5,6−ジ−(4′−メトキシフェニル)−1,2,4−トリアジン等の1,2,4−トリアジン誘導体、4−ジエチルアミノベンズアルデヒド−1,1−ジフェニルヒドラゾン等のヒドラゾン誘導体、2−フェニル−4−スチリル−キナゾリン等のキナゾリン誘導体、6−ヒドロキシ−2,3−ジ(p−メトキシフェニル)ベンゾフラン等のベンゾフラン誘導体、p−(2,2−ジフェニルビニル)−N,N−ジフェニルアニリン等のα−スチルベン誘導体、エナミン誘導体、N−エチルカルバゾール等のカルバゾール誘導体、ポリ−N−ビニルカルバゾールおよびその誘導体などの正孔輸送物質、クロラニル、ブロアントラキノン等のキノン系化合物、テトラアノキノジメタン系化合物、2,4,7−トリニトロフルオレノン、2,4,5,7−テトラニトロ−9−フルオレノン等のフルオレノン化合物、キサントン系化合物、チオフェン化合物等の電子輸送物質、および上記した化合物からなる基を主鎖または側鎖に有する重合体などが挙げられる。また、第1材料は、特に電荷輸送能を有する下記一般式(1)に示すブタジエン構造を有する化合物を含むとよい。

Figure 2015187650
Specifically, examples of suitable materials as the first material include oxadiazole derivatives such as 2,5-bis (p-diethylaminophenyl) -1,3,4-oxadiazole, 1,3,5- Pyrazoline derivatives such as triphenyl-pyrazoline, 1- [pyridyl- (2)]-3- (p-diethylaminostyryl) -5- (p-diethylaminostyryl) pyrazoline, triphenylamine, N, N′-bis (3 , 4-dimethylphenyl) biphenyl-4-amine, tri (p-methylphenyl) aminyl-4-amine, aromatic tertiary amino compounds such as dibenzylaniline, N, N′-bis (3-methylphenyl) Aromatic tertiary diamino compounds such as -N, N'-diphenylbenzidine, 3- (4'-dimethylaminophenyl) -5,6-di- (4'-methoxyphene) L) 1,2,4-triazine derivatives such as-1,2,4-triazine, hydrazone derivatives such as 4-diethylaminobenzaldehyde-1,1-diphenylhydrazone, and quinazoline derivatives such as 2-phenyl-4-styryl-quinazoline Benzofuran derivatives such as 6-hydroxy-2,3-di (p-methoxyphenyl) benzofuran, α-stilbene derivatives such as p- (2,2-diphenylvinyl) -N, N-diphenylaniline, enamine derivatives, N -Carbazole derivatives such as ethylcarbazole, hole transport materials such as poly-N-vinylcarbazole and its derivatives, quinone compounds such as chloranil and broanthraquinone, tetraanoquinodimethane compounds, 2,4,7-trinitro Fluorenone, 2,4,5,7-tetranitro-9-fluore Examples thereof include fluorenone compounds such as non, electron transport materials such as xanthone compounds and thiophene compounds, and polymers having a group consisting of the above compounds in the main chain or side chain. In addition, the first material preferably includes a compound having a butadiene structure represented by the following general formula (1) having a charge transporting ability.
Figure 2015187650

この一般式(1)中、R1、R2、R3、R4、R5、及び、R6は、それぞれ同一であっても異なっていてもよく、水素原子、アルキル基、アルコキシル基、ハロゲン原子、又は、置換若しくは無置換のアリ−ル基を示す。m及びnは0又は1を示す。 In this general formula (1), R 1 , R 2 , R 3 , R 4 , R 5 , and R 6 may be the same or different and each represents a hydrogen atom, an alkyl group, an alkoxyl group, A halogen atom or a substituted or unsubstituted aryl group is shown. m and n represent 0 or 1.

また、第1材料には、例えば、バインダー樹脂(結着樹脂)として公知の樹脂を使用してもよく、電気絶縁性のフィルムとして形成される樹脂を使用してもよい。第1材料に使用されるバインダー樹脂としては、例えば、ポリカーボネート樹脂、ポリエステル樹脂、メタクリル樹脂、アクリル樹脂、ポリ塩化ビニル樹脂、ポリ塩化ビニリデン樹脂、ポリスチレン樹脂、ポリビニルアセテート樹脂、スチレンーブタジエン共重合体、塩化ビニリデンーアクリロニトリル共重合体、塩化ビニル−酢酸ビニル共重合体、塩化ビニル−酢酸ビニル−無水マレイン酸共重合体、シリコーン樹脂、シリコーン−アルキッド樹脂、フェノールーホルムアルデヒド樹脂、スチレンーアルキッド樹脂、ポリーN―カルバゾール、ポリビニルブチラール、ポリビニルフォルマール、ポリスルホン、カゼイン、ゼラチン、ポリビニルアルコール、エチルセルロース、フェノール樹脂、ポリアミド、カルボキシーメチルセルロース、塩化ビニリデン系ポリマーワックス、ポリウレタンなどが挙げられる。また、特に、第1材料は、下記一般式(2)で表される繰り返し単位及び下記一般式(3)で表される繰り返し単位を含むポリカーボネート共重合体を含むとよい。

Figure 2015187650
Figure 2015187650
In addition, as the first material, for example, a known resin may be used as the binder resin (binder resin), or a resin formed as an electrically insulating film may be used. As the binder resin used for the first material, for example, polycarbonate resin, polyester resin, methacrylic resin, acrylic resin, polyvinyl chloride resin, polyvinylidene chloride resin, polystyrene resin, polyvinyl acetate resin, styrene-butadiene copolymer, Vinylidene chloride-acrylonitrile copolymer, vinyl chloride-vinyl acetate copolymer, vinyl chloride-vinyl acetate-maleic anhydride copolymer, silicone resin, silicone-alkyd resin, phenol-formaldehyde resin, styrene-alkyd resin, Poly-N -Carbazole, polyvinyl butyral, polyvinyl formal, polysulfone, casein, gelatin, polyvinyl alcohol, ethyl cellulose, phenol resin, polyamide, carboxymethyl cellulose Vinylidene polymer waxes chloride, polyurethanes, and the like. In particular, the first material may include a polycarbonate copolymer including a repeating unit represented by the following general formula (2) and a repeating unit represented by the following general formula (3).
Figure 2015187650
Figure 2015187650

これらの一般式(2)及び一般式(3)中、R7、R8、R9、及び、R10は、各々独立に、水素原子、ハロゲン原子、炭素数1以上6以下のアルキル基、炭素数5以上7以下のシクロアルキル基、又は、炭素数6以上12以下のアリール基を表す。Xは、フェニレン基、ビフェニレン基、ナフチレン基、直鎖若しくは分岐アルキレン基、又は、シクロアルキレン基を表す。 In these general formulas (2) and (3), R 7 , R 8 , R 9 , and R 10 are each independently a hydrogen atom, a halogen atom, an alkyl group having 1 to 6 carbon atoms, A cycloalkyl group having 5 to 7 carbon atoms or an aryl group having 6 to 12 carbon atoms is represented. X represents a phenylene group, a biphenylene group, a naphthylene group, a linear or branched alkylene group, or a cycloalkylene group.

帯電器32は像保持体31の表面を帯電させる。露光装置33はレーザ発光源やポリゴンミラーなど(いずれも図示せず)を有し、図示しない制御部の制御の下、画像データに応じたレーザ光を、帯電器32により帯電させられた後の像保持体31に向けて照射する。これにより、像保持体31の側面には潜像が保持される。   The charger 32 charges the surface of the image carrier 31. The exposure device 33 includes a laser light source, a polygon mirror, and the like (both not shown), and after the laser light corresponding to the image data is charged by the charger 32 under the control of a control unit (not shown). Irradiation toward the image carrier 31. Thereby, the latent image is held on the side surface of the image holding body 31.

なお、上記の画像データは、画像形成装置1が図示しない通信部を介して外部装置から取得したものであってもよい。外部装置とは、例えば原画像を読み取る読取装置や画像を示すデータを記憶した記憶装置などである。現像装置34は現像剤を像保持体31に供給する。これにより像保持体31には、画像が形成(現像)される。   Note that the image data may be acquired from an external device by the image forming apparatus 1 via a communication unit (not shown). The external device is, for example, a reading device that reads an original image or a storage device that stores data indicating an image. The developing device 34 supplies the developer to the image carrier 31. As a result, an image is formed (developed) on the image carrier 31.

一次転写ロール35は転写部14の中間転写ベルト41が像保持体31と対向する位置において予め定めた電位差を生じさせ、この電位差によって中間転写ベルト41に画像を転写する。ドラムクリーナ36は、画像の転写後に像保持体31の表面に残留している未転写のトナーを取り除き、像保持体31の表面を除電する。   The primary transfer roll 35 generates a predetermined potential difference at a position where the intermediate transfer belt 41 of the transfer unit 14 faces the image carrier 31, and the image is transferred to the intermediate transfer belt 41 by this potential difference. The drum cleaner 36 removes untransferred toner remaining on the surface of the image carrier 31 after the image is transferred, and neutralizes the surface of the image carrier 31.

転写部14は、中間転写ベルト41と、二次転写ロール42と、ベルト搬送ロール43と、バックアップロール44と、ベルトクリーナ49とを有しており、現像部13によって形成された画像を用紙Pに転写する転写部である。中間転写ベルト41は無端のベルト部材であり、ベルト搬送ロール43およびバックアップロール44はこの中間転写ベルト41を張架する。ベルト搬送ロール43およびバックアップロール44の少なくとも1つには駆動部(図示せず)が備えられており、中間転写ベルト41を図1の矢印D14方向に移動させる。なお、駆動部を有しないベルト搬送ロール43またはバックアップロール44は、中間転写ベルト41の移動に伴って回転する。中間転写ベルト41が図1の矢印D14方向に移動して回転することにより、中間転写ベルト41上の画像は、二次転写ロール42とバックアップロール44とに挟まれる領域に移動させられる。   The transfer unit 14 includes an intermediate transfer belt 41, a secondary transfer roll 42, a belt transport roll 43, a backup roll 44, and a belt cleaner 49, and an image formed by the developing unit 13 is transferred to a sheet P It is a transfer part to transfer to. The intermediate transfer belt 41 is an endless belt member, and the belt conveyance roll 43 and the backup roll 44 stretch the intermediate transfer belt 41. At least one of the belt conveyance roll 43 and the backup roll 44 is provided with a drive unit (not shown), and moves the intermediate transfer belt 41 in the direction of arrow D14 in FIG. Note that the belt conveyance roll 43 or the backup roll 44 that does not have a driving unit rotates as the intermediate transfer belt 41 moves. As the intermediate transfer belt 41 moves and rotates in the direction of arrow D14 in FIG. 1, the image on the intermediate transfer belt 41 is moved to a region sandwiched between the secondary transfer roll 42 and the backup roll 44.

二次転写ロール42は、中間転写ベルト41との電位差によって、中間転写ベルト41上の画像を搬送部16から搬送されてきた用紙Pに転写させる。ベルトクリーナ49は、中間転写ベルト41の表面に残留している未転写のトナーを取り除く。そして、転写部14または搬送部16は、画像が転写された用紙Pを定着部15へと搬送する。定着部15は、加熱によって用紙Pに転写された画像を定着させる。   The secondary transfer roll 42 transfers the image on the intermediate transfer belt 41 onto the paper P conveyed from the conveyance unit 16 by a potential difference with the intermediate transfer belt 41. The belt cleaner 49 removes untransferred toner remaining on the surface of the intermediate transfer belt 41. Then, the transfer unit 14 or the conveyance unit 16 conveys the paper P on which the image is transferred to the fixing unit 15. The fixing unit 15 fixes the image transferred onto the paper P by heating.

1−2.ドラムクリーナの構成
図2は、ドラムクリーナ36の構成を示す図である。図2に示すように、ドラムクリーナ36は、ケース360、除去部材361、および保持部材362を有する。ドラムクリーナ36は、他に像保持体31の表面を除電する機構やその表面に潤滑剤を供給する機構などを有していてもよい。
1-2. Configuration of Drum Cleaner FIG. 2 is a diagram illustrating a configuration of the drum cleaner 36. As shown in FIG. 2, the drum cleaner 36 includes a case 360, a removing member 361, and a holding member 362. In addition, the drum cleaner 36 may have a mechanism for discharging the surface of the image carrier 31 or a mechanism for supplying a lubricant to the surface.

ケース360は、像保持体31に対向する側に開口部を有する筐体であり、天井板に固定された保持部材362を有する。保持部材362は、除去部材361の一端を保持し、他端をケース360の開口部から露出させて、決められた圧力(以下、接触圧という)および決められた角度(以下、接触角度という)で像保持体31に対して接触させる。なお、図2に示すように、像保持体31の接触点における接平面と、除去部材361の接触部3611が伸びる方向との角度θが接触角度である。   The case 360 is a housing having an opening on the side facing the image carrier 31 and includes a holding member 362 fixed to the ceiling plate. The holding member 362 holds one end of the removing member 361 and exposes the other end from the opening of the case 360 to determine a predetermined pressure (hereinafter referred to as contact pressure) and a predetermined angle (hereinafter referred to as contact angle). Then, the image holding member 31 is brought into contact. As shown in FIG. 2, the angle θ between the tangential plane at the contact point of the image carrier 31 and the direction in which the contact portion 3611 of the removal member 361 extends is the contact angle.

除去部材361は、いわゆる二層構造のクリーニングブレードであり、接触部3611と支持部3612とを有する。接触部3611は、像保持体31に接触して像保持体31の表面に付着したトナーなどの物質を除去する。支持部3612は、接触部3611が像保持体31に接触する点(以下、接触点という)の反対側から接触部3611を支持する。除去部材361の接触部3611によって掻き落とされた上記の物質はケース360に収容されメンテナンスの際に画像形成装置1から取り除かれる。   The removing member 361 is a so-called two-layer cleaning blade, and includes a contact portion 3611 and a support portion 3612. The contact part 3611 contacts the image carrier 31 and removes substances such as toner adhering to the surface of the image carrier 31. The support part 3612 supports the contact part 3611 from the side opposite to the point where the contact part 3611 contacts the image carrier 31 (hereinafter referred to as a contact point). The substance scraped off by the contact portion 3611 of the removing member 361 is accommodated in the case 360 and removed from the image forming apparatus 1 during maintenance.

なお、図2に示す保持部材362は、除去部材361のうち支持部3612の側を保持しているが、接触部3611の側を保持してもよいし、接触部3611および支持部3612の両方に接触して除去部材361を保持してもよい。   The holding member 362 shown in FIG. 2 holds the support portion 3612 side of the removal member 361, but may hold the contact portion 3611 side, or both the contact portion 3611 and the support portion 3612. The removal member 361 may be held in contact with.

接触部3611および支持部3612の各材料は、以下の規定を満たすものが用いられる。すなわち、接触部3611を構成する材料(以下、第2材料という)は、100%モジュラスの値が7メガパスカル以上になるように調整された材料である。100%モジュラスの値とは、JISのK6251−2010「加硫ゴム及び熱可塑性ゴム−引張特性の求め方」に定める「所定伸び引張応力」であり、試験片に100%の伸びを与えたときの引張力を試験片の初期断面積で除した値である。ここでは、試験温度として25℃を採用する。これにより、第2材料によって構成される接触部3611の摩耗が抑制される。
支持部3612を構成する材料(以下、第3材料という)は、第2材料よりも硬度が低い材料である。
As the materials for the contact portion 3611 and the support portion 3612, those satisfying the following rules are used. That is, the material constituting the contact portion 3611 (hereinafter referred to as the second material) is a material adjusted so that the value of 100% modulus is 7 megapascals or more. The value of 100% modulus is “predetermined tensile stress” defined in JIS K6251-2010 “Vulcanized rubber and thermoplastic rubber-Determination of tensile properties”. When 100% elongation is given to a test piece Is the value obtained by dividing the tensile force by the initial cross-sectional area of the test piece. Here, 25 degreeC is employ | adopted as test temperature. Thereby, wear of contact part 3611 constituted by the 2nd material is controlled.
The material constituting the support portion 3612 (hereinafter referred to as a third material) is a material having a hardness lower than that of the second material.

1−3.除去部材の配置
図3は、図2における領域IIIを拡大した図である。像保持体31は、矢線D13の方向に回転しており、除去部材361の接触部3611は、接触点Cで像保持体31の側面F0に接触している。
除去部材361は、先端に対向面F1を有する。この対向面F1は、像保持体31の回転方向における接触点Cの上流側に対向する面である。
1-3. Arrangement of Removal Member FIG. 3 is an enlarged view of region III in FIG. The image carrier 31 is rotated in the direction of the arrow D13, and the contact portion 3611 of the removing member 361 is in contact with the side surface F0 of the image carrier 31 at the contact point C.
The removal member 361 has a facing surface F1 at the tip. The facing surface F <b> 1 is a surface facing the upstream side of the contact point C in the rotation direction of the image carrier 31.

ここで、接触点Cおよび対向面F1が、以下の2つの条件を満たすように除去部材361の配置が決められる。
(条件a)接触点Cは、像保持体31の側面のうち、重力方向の上(+z方向)に移動している領域にある。すなわち、接触点Cは、像保持体31が昇る側の側面にある。
(条件b)対向面F1の法線ベクトルN1は、重力方向の上(+z方向)に向かう成分を含まない。すなわち、対向面F1は下向きの面である。
Here, the arrangement of the removal member 361 is determined so that the contact point C and the facing surface F1 satisfy the following two conditions.
(Condition a) The contact point C is in an area of the side surface of the image carrier 31 that is moving above the gravity direction (+ z direction). That is, the contact point C is on the side surface on the side where the image carrier 31 rises.
(Condition b) The normal vector N1 of the facing surface F1 does not include a component directed upward in the gravity direction (+ z direction). That is, the facing surface F1 is a downward surface.

図4は、像保持体31に対する除去部材361の配置を説明するための図である。上述した2つの条件により、像保持体31に対して除去部材361が配置される範囲が定まる。条件aにより、接触点Cは、像保持体31が昇る側の側面にあるので、図4に示す領域R1の範囲内にある。条件bにより、対向面F1は下向きの面であるので、図4に示す領域R2の範囲内にある。条件aおよび条件bをいずれも満たすため、除去部材361は、領域R1と領域R2とが重なる領域にある接触点Cと接触する。つまり、図4においては、除去部材361−0から除去部材361−5までが、配置可能な除去部材361である。   FIG. 4 is a diagram for explaining the arrangement of the removing member 361 with respect to the image carrier 31. The range in which the removal member 361 is disposed with respect to the image carrier 31 is determined by the two conditions described above. According to the condition a, the contact point C is on the side surface on the side where the image carrier 31 rises, and thus is within the range of the region R1 shown in FIG. According to the condition b, the facing surface F1 is a downward surface and is within the range of the region R2 shown in FIG. In order to satisfy both the condition a and the condition b, the removing member 361 contacts the contact point C in the region where the region R1 and the region R2 overlap. That is, in FIG. 4, the removal member 361 from the removal member 361-0 to the removal member 361-5 is the disposing member 361 that can be arranged.

接触点Cを像保持体31が昇る側の側面に限定したため、像保持体31の側面に付着しているトナーなどの物質が除去部材361により剥がされたときに、この物質が除去部材361に阻まれて落下し難くなり、除去部材361と像保持体31との間に留まる可能性が低減される。また、対向面F1を下向きの面としたため、剥がされた上記の物質が対向面F1に載り難くなり、除去部材361と像保持体31との間に留まる可能性が低減される。以上説明したとおり、条件aおよび条件bを設けたことによって、像保持体31の側面から剥がされた物質が、除去部材361と像保持体31との間に留まる可能性が低減されるため、除去部材361の摩耗、変形、振動が抑えられる。そして、これらが抑えられるため、除去性能の劣化が低減する。   Since the contact point C is limited to the side surface on the side where the image carrier 31 rises, when a substance such as toner adhering to the side surface of the image carrier 31 is peeled off by the removal member 361, this substance is applied to the removal member 361. It is prevented from falling and is less likely to stay between the removal member 361 and the image carrier 31. Further, since the facing surface F1 is a downward surface, the peeled-off substance is difficult to be placed on the facing surface F1, and the possibility of staying between the removal member 361 and the image carrier 31 is reduced. As described above, the provision of the condition a and the condition b reduces the possibility that the material peeled from the side surface of the image carrier 31 stays between the removal member 361 and the image carrier 31. Wear, deformation, and vibration of the removal member 361 are suppressed. And since these are suppressed, degradation of removal performance reduces.

2.試験例
2−1.試験構成
以下に、試験1から試験11を行った。表1に示すように、試験に用いた各装置は、上述した対向面F1の向き、像保持体31の側面に用いる第1材料、第1材料の損失正接、接触部3611の100%モジュラスの値によってそれぞれ特徴付けられる。
第1材料として、材料M1,M2,M3,M4を用いた。材料M1は、以下に示す手順に従って作成された。
2. Test Example 2-1. Test configuration Tests 1 to 11 were performed below. As shown in Table 1, each apparatus used in the test has the orientation of the facing surface F1, the first material used for the side surface of the image carrier 31, the loss tangent of the first material, and the 100% modulus of the contact portion 3611. Each is characterized by a value.
As the first material, materials M1, M2, M3, and M4 were used. Material M1 was made according to the following procedure.

酸化亜鉛(平均粒子径:70nm、テイカ社製、比表面積値:15m2/g)100質量部をメタノール500質量部と攪拌混合し、シランカップリング剤として、KBM603(信越化学社製)0.75質量部を添加し、2時間攪拌した。その後、メタノールを減圧蒸留にて留去し、120℃で3時間焼き付けを行い、シランカップリング剤表面処理酸化亜鉛粒子を得た。   100 parts by mass of zinc oxide (average particle size: 70 nm, manufactured by Teika, specific surface area value: 15 m 2 / g) is stirred and mixed with 500 parts by mass of methanol, and KBM603 (manufactured by Shin-Etsu Chemical Co., Ltd.) 0.75 is used as a silane coupling agent. Part by mass was added and stirred for 2 hours. Thereafter, methanol was distilled off under reduced pressure, and baking was performed at 120 ° C. for 3 hours to obtain silane coupling agent surface-treated zinc oxide particles.

前記表面処理を施した酸化亜鉛粒子60質量部と、式(4)に示すアントラキノン構造を含む反応性アクセプター物質を1.2質量部と、硬化剤としてブロック化イソシアネート(スミジュール3173、住友バイエルンウレタン社製)13.5質量部と、ブチラール樹脂(BM−1、積水化学社製)15質量部とを、メチルエチルケトン85質量部に溶解した溶液38質量部と、メチルエチルケトン25質量部とを混合し、直径1mmのガラスビーズを用いてサンドミルにて4時間の分散を行い、分散液を得た。得られた分散液に、触媒としてジオクチルスズジラウレート0.005質量部と、シリコーン樹脂粒子(トスパール145、GE東芝シリコーン社製)4.0質量部とを添加し、下引き層形成用塗布液を得た。下引き層形成用塗布液の塗布温度(24℃)における粘度は235mPa・sであった。
この塗布液を、浸漬塗布法にて塗布速度220mm/minで直径30mmのアルミニウム基材上に塗布し、180℃、40分の乾燥硬化を行い厚さ25μmの下引き層を得た。
60 parts by mass of the surface-treated zinc oxide particles, 1.2 parts by mass of a reactive acceptor substance containing an anthraquinone structure represented by formula (4), and blocked isocyanate (Sumidule 3173, Sumitomo Bayern Urethane as a curing agent) 13.5 parts by mass) and 15 parts by mass of butyral resin (BM-1, Sekisui Chemical Co., Ltd.) dissolved in 85 parts by mass of methyl ethyl ketone and 25 parts by mass of methyl ethyl ketone are mixed. Dispersion was performed for 4 hours with a sand mill using glass beads having a diameter of 1 mm to obtain a dispersion. To the obtained dispersion, 0.005 parts by mass of dioctyltin dilaurate and 4.0 parts by mass of silicone resin particles (Tospearl 145, manufactured by GE Toshiba Silicone) are added as a catalyst, and a coating liquid for forming an undercoat layer is added. Obtained. The viscosity of the coating solution for forming the undercoat layer at the coating temperature (24 ° C.) was 235 mPa · s.
This coating solution was applied onto an aluminum substrate having a diameter of 30 mm at a coating speed of 220 mm / min by a dip coating method, followed by drying and curing at 180 ° C. for 40 minutes to obtain an undercoat layer having a thickness of 25 μm.

次に、電荷発生材料として、CuKα特性X線に対するブラッグ角(2θ±0.2゜)の少なくとも7.5゜、9.9゜、12.5゜、16.3゜、18.6゜、25.1゜及び28.3゜に強い回折ピークを有するヒドロキシガリウムフタロシアニン結晶15質量部、塩化ビニル−酢酸ビニル共重合体樹脂(VMCH、日本ユニオンカーバイト社製)10質量部およびn−ブチルアルコール300質量部からなる混合物を、直径1mmのガラスビーズを用いてサンドミルにて4時間分散して電荷発生層形成用塗布液を得た。電荷発生層形成用塗布液の塗布温度(24℃)における粘度は1.8mPa・sであった。この塗布液を前記下引き層上に浸漬塗布法にて塗布速度65mm/minで浸漬塗布し、150℃で10分間乾燥して電荷発生層を得た。   Next, as a charge generation material, at least 7.5 °, 9.9 °, 12.5 °, 16.3 °, 18.6 °, Bragg angle (2θ ± 0.2 °) with respect to CuKα characteristic X-ray, 15 parts by mass of hydroxygallium phthalocyanine crystals having strong diffraction peaks at 25.1 ° and 28.3 °, 10 parts by mass of vinyl chloride-vinyl acetate copolymer resin (VMCH, manufactured by Nippon Union Carbide) and n-butyl alcohol A mixture of 300 parts by mass was dispersed for 4 hours with a sand mill using glass beads having a diameter of 1 mm to obtain a coating solution for forming a charge generation layer. The viscosity at the coating temperature (24 ° C.) of the coating solution for forming a charge generation layer was 1.8 mPa · s. This coating solution was dip-coated on the undercoat layer by a dip coating method at a coating speed of 65 mm / min and dried at 150 ° C. for 10 minutes to obtain a charge generation layer.

次に、4フッ化エチレン樹脂粒子8質量部(平均粒径:0.2μm)と、フッ化アルキル基含有メタクリルコポリマー(重量平均分子量30000)0.01質量部とを、テトラヒドロフラン4質量部、トルエン1質量部とともに20℃の液温に保ち、48時間攪拌混合し、4フッ化エチレン樹脂粒子懸濁液Aを得た。
次に、電荷輸送物質として下記構造式1を示す化合物(一般式(1)において、n=1、m=1、R1、R2、R3、R4、R5、及びR6が全てHのもの、トリス[4−(4,4−ジフェニル−1,3−ブタジエニル)フェニル]アミン)を4質量部、バインダー樹脂として、下記構造式2(一般式(2)において、R7及びR8が全てHのもの)および下記構造式3(一般式(3)において、Xがイソプロピリデン基、R9及びR10が全てCH3のもの)の繰り返し単位からなるポリカーボネート共重合体(粘度平均分子量40000)を6質量部、酸化防止剤として2,6−ジ−t−ブチル−4−メチルフェノールを0.1質量部を混合して、テトラヒドロフラン24質量部及びトルエン11質量部を混合溶解して、混合溶解液Bを得た。なお、構造式3の繰り返し単位からなるポリカーボネート共重合体は、ビスフェノールC型ポリカーボネートである。
Next, 8 parts by mass of tetrafluoroethylene resin particles (average particle size: 0.2 μm) and 0.01 parts by mass of a fluorinated alkyl group-containing methacrylic copolymer (weight average molecular weight 30000), 4 parts by mass of tetrahydrofuran, toluene The mixture was kept at a liquid temperature of 20 ° C. together with 1 part by mass and stirred for 48 hours to obtain a tetrafluoroethylene resin particle suspension A.
Next, a compound having the following structural formula 1 as a charge transport material (in general formula (1), n = 1, m = 1, R 1 , R 2 , R 3 , R 4 , R 5 , and R 6 are all 4 parts by mass of H, tris [4- (4,4-diphenyl-1,3-butadienyl) phenyl] amine) as a binder resin, R 7 and R in the following structural formula 2 (general formula (2)) 8 is a polycarbonate copolymer (viscosity average) composed of repeating units of the following structural formula 3 (in general formula (3), X is an isopropylidene group, R 9 and R 10 are all CH 3 ) 6 parts by mass of molecular weight 40000), 0.1 part by mass of 2,6-di-t-butyl-4-methylphenol as an antioxidant are mixed, and 24 parts by mass of tetrahydrofuran and 11 parts by mass of toluene are mixed and dissolved. Thus, a mixed solution B was obtained. In addition, the polycarbonate copolymer which consists of the repeating unit of Structural formula 3 is a bisphenol C type polycarbonate.

このB液に前記A液を加えて攪拌混合した後、微細な流路を持つ貫通式チャンバーを装着した高圧ホモジナイザー(吉田機械興行株式会社製)を用いて、500kgf/cm2まで昇圧しての分散処理を6回繰り返した液に、フッ素変性シリコーンオイル(商品名:FL−100 信越シリコーン社製)を5ppm添加し、十分に撹拌して電荷輸送層形成用塗布液を得た。この塗布液を電荷発生層上に24μmの厚さで塗布して135℃で25分間乾燥して電荷輸送層を形成し、目的の材料M1を得た。   Dispersion after increasing the pressure to 500 kgf / cm 2 using a high pressure homogenizer (manufactured by Yoshida Kikai Kogyo Co., Ltd.) equipped with a penetrating chamber having a fine flow path after adding the A liquid to the B liquid and stirring and mixing. 5 ppm of fluorine-modified silicone oil (trade name: FL-100 manufactured by Shin-Etsu Silicone Co., Ltd.) was added to the solution obtained by repeating the treatment 6 times, and the mixture was sufficiently stirred to obtain a coating solution for forming a charge transport layer. This coating solution was applied onto the charge generation layer at a thickness of 24 μm and dried at 135 ° C. for 25 minutes to form a charge transport layer, thereby obtaining a target material M1.

Figure 2015187650
Figure 2015187650

Figure 2015187650
Figure 2015187650

材料M2は、上述した手順のうち、バインダー樹脂を構成する物質のうち、構造式3の繰り返し単位からなるポリカーボネート共重合体を、一般式(3)のXをシクロアルキレン基とした構造式の繰り返し単位からなるポリカーボネート共重合体に変更した手順に従って作成された。
材料M3は、上述した手順のうち、バインダー樹脂として構造式2の繰り返し単位を含まず、構造式3の繰り返し単位のみからなるポリカーボネート共重合体(ビスフェノールC型ポリカーボネート)を用いて作成された。
材料M4は、電荷輸送物質として下記構造式4を示す化合物であるN,N´−ビス(3−メチルフェニル)−N,N´−ジフェニルベンジジンを4質量部、バインダー樹脂として下記構造式5を示す化合物であるビスフェノールZ型ポリカーボネート樹脂(粘度平均分子量:40000)を6質量部、それぞれ用いた以外は、上述した手順と共通の手順に従って作成された。
The material M2 is a repeating structural formula in which the polycarbonate copolymer consisting of the repeating unit of the structural formula 3 among the substances constituting the binder resin among the procedures described above is used, and X in the general formula (3) is a cycloalkylene group. It was made according to the procedure changed to a polycarbonate copolymer consisting of units.
The material M3 was prepared by using a polycarbonate copolymer (bisphenol C-type polycarbonate) which does not include the repeating unit of the structural formula 2 but includes only the repeating unit of the structural formula 3 as the binder resin in the above-described procedure.
The material M4 contains 4 parts by mass of N, N′-bis (3-methylphenyl) -N, N′-diphenylbenzidine, which is a compound having the following structural formula 4 as a charge transport material, and the following structural formula 5 as a binder resin. It was prepared in accordance with the same procedure as described above, except that 6 parts by mass of bisphenol Z-type polycarbonate resin (viscosity average molecular weight: 40000), which is the compound shown, was used.

Figure 2015187650
Figure 2015187650

Figure 2015187650
Figure 2015187650

Figure 2015187650
Figure 2015187650

材料M5は、N,N´−ビス(3−メチルフェニル)−N,N´−ジフェニルベンジジンを減量し、ビスフェノールZ型ポリカーボネート樹脂(粘度平均分子量:40000)を増量することによって損失正接が0.015未満となるように調整した以外は、材料M4と共通の手順に従って作成された。   The material M5 has a loss tangent of 0.00 by reducing N, N′-bis (3-methylphenyl) -N, N′-diphenylbenzidine and increasing bisphenol Z-type polycarbonate resin (viscosity average molecular weight: 40000). The material was prepared according to the same procedure as that of the material M4, except that it was adjusted to be less than 015.

2−2.評価方法
各試験例について、画質および摩耗の評価をした。評価は、高いものから順に「優」「良」「困難」「不適」の四段階とし、「優」または「良」と評価されたものを有効な構成と判断した。
2-2. Evaluation Method For each test example, image quality and wear were evaluated. The evaluation was made in four stages of “excellent”, “good”, “difficult”, and “unsuitable” in order from the highest to the lowest, and those evaluated as “excellent” or “good” were judged as effective configurations.

画質の評価は、画像密度1%のランダムチャートを1万枚採取した後、画像密度100%の画像を採取し、直後に像保持体31の側面条に残留したスジの本数を数えることで評価した。スジの本数が0のものを「優」、2本以下のものを「良」、3本以上5本以下のものを「困難」、6本以上のものを「不適」と評価した。   Image quality is evaluated by collecting 10,000 random charts with an image density of 1%, collecting an image with an image density of 100%, and immediately counting the number of streaks remaining on the side stripes of the image carrier 31. did. A case where the number of streaks was 0 was evaluated as “excellent”, a case where it was 2 or less was evaluated as “good”, a case where it was 3 or more and 5 or less was evaluated as “difficult”, and a case where 6 or more were observed as “unsuitable”.

摩耗の評価は、画像密度1%のランダムチャートを1万枚採取した後、接触部3611が摩耗した部分の面積を計測することで評価した。面積が5平方マイクロメートル(μm2)以下のものを「優」、10平方マイクロメートル(μm2)以下のものを「良」、20平方マイクロメートル(μm2)以下のものを「困難」、20平方マイクロメートル(μm2)を超えるものを「不適」と評価した。 The wear was evaluated by measuring the area of the worn portion of the contact portion 3611 after collecting 10,000 random charts having an image density of 1%. “Excellent” if the area is 5 square micrometers (μm 2 ) or less, “Good” if the area is 10 square micrometers (μm 2 ) or less, and “Difficult” if the area is 20 square micrometers (μm 2 ) or less. Those exceeding 20 square micrometers (μm 2 ) were evaluated as “unsuitable”.

2−3.試験結果
表1に示す通り、試験例1から5についての評価は、画質、摩耗ともに「優」または「良」であった。試験例1から5の構成は、いずれも、対向面F1の方向が下向きであり、像保持体31の側面を形成する第1材料が、摂氏28度で0.5ヘルツの振動を与えたときの損失正接が0.015以上、0.035以下であり、接触部3611を構成する第2材料について測定した100%モジュラスの値が7メガパスカル以上であった。
2-3. Test Results As shown in Table 1, the evaluations for Test Examples 1 to 5 were “excellent” or “good” for both image quality and wear. In any of the configurations of Test Examples 1 to 5, the direction of the facing surface F1 is downward, and the first material forming the side surface of the image carrier 31 gives a vibration of 0.5 hertz at 28 degrees Celsius. Loss tangent was 0.015 or more and 0.035 or less, and the value of 100% modulus measured for the second material constituting the contact portion 3611 was 7 megapascals or more.

なお、対向面F1の方向が下向きであるとは、対向面F1の法線ベクトルN1が、重力方向の上に向かう成分を含まないこと、すなわち、上述した条件bを満たすことを意味する。そして、表1において対向面F1の方向を下向きとした試験例については、全て上述した条件aを満たすように接触点Cの位置を決定した。   Note that the direction of the facing surface F1 being downward means that the normal vector N1 of the facing surface F1 does not include a component upward in the gravity direction, that is, satisfies the above-described condition b. And about the test example which made the direction of the opposing surface F1 downward in Table 1, the position of the contact point C was determined so that all the conditions a mentioned above might be satisfy | filled.

一方、試験例6の構成は、第2材料について測定した100%モジュラスの値が7メガパスカル未満の「5.0メガパスカル」である。試験例6は、画質、摩耗ともに「不適」と評価された。試験例7の構成は、第1材料の損失正接が0.035を超える「0.040」である。試験例7は、画質、摩耗ともに「困難」と評価された。試験例11の構成は、第1材料の損失正接が0.015未満の「0.013」である。試験例11は、画質について「困難」と評価された。   On the other hand, the configuration of Test Example 6 is “5.0 megapascal” in which the value of 100% modulus measured for the second material is less than 7 megapascals. Test Example 6 was evaluated as “unsuitable” for both image quality and wear. The configuration of Test Example 7 is “0.040” in which the loss tangent of the first material exceeds 0.035. Test Example 7 was evaluated as “difficult” for both image quality and wear. The configuration of Test Example 11 is “0.013” in which the loss tangent of the first material is less than 0.015. Test Example 11 was evaluated as “difficult” in terms of image quality.

試験例8から10の構成は、対向面F1の方向が上向きである。試験例8から10は、試験例8の画質が「良」と評価されたことを除き、画質、摩耗ともに「困難」または「不適」と評価された。

Figure 2015187650
In the configurations of Test Examples 8 to 10, the direction of the facing surface F1 is upward. Test Examples 8 to 10 were evaluated as “difficult” or “unsuitable” for both image quality and wear, except that the image quality of Test Example 8 was evaluated as “good”.
Figure 2015187650

以上の評価結果から、画像形成装置1の構成は、対向面F1が向く方向が下向きであり、像保持体31の側面を形成する第1材料が、摂氏28度で0.5ヘルツの振動を与えたときの損失正接が0.015以上、0.035以下であり、接触部3611を構成する第2材料について測定した100%モジュラスの値が7メガパスカル以上であると、画質の劣化および摩耗が抑えられることがわかった。   From the above evaluation results, the configuration of the image forming apparatus 1 is such that the direction in which the facing surface F1 faces is downward, and the first material forming the side surface of the image holding member 31 vibrates at 0.5 degrees at 28 degrees Celsius. When the loss tangent when given is 0.015 or more and 0.035 or less, and the value of 100% modulus measured for the second material constituting the contact portion 3611 is 7 megapascals or more, image quality deterioration and wear Was found to be suppressed.

3.変形例
以上が実施形態の説明であるが、この実施形態の内容は以下のように変形し得る。また、以下の変形例を組み合わせてもよい。
3−1.変形例1
上述した実施形態において画像形成装置1は、現像部13を1つだけ有していたが、複数の現像部13を有していてもよい。この場合、画像形成装置1は、複数の現像部13のそれぞれに、対応する像保持体31と、帯電器32と、露光装置33と、現像装置34と、一次転写ロール35と、ドラムクリーナ36とを有していればよい。また、複数の現像部13は、それぞれ異なる色のトナー像を形成してもよい。この場合、中間転写ベルト41に異なる色のトナー像が重ねて転写され、用紙Pなどの媒体にカラー画像が形成される。
3. Modification The above is the description of the embodiment, but the contents of this embodiment can be modified as follows. Further, the following modifications may be combined.
3-1. Modification 1
In the embodiment described above, the image forming apparatus 1 has only one developing unit 13, but may have a plurality of developing units 13. In this case, the image forming apparatus 1 includes a corresponding image holding member 31, a charger 32, an exposure device 33, a developing device 34, a primary transfer roll 35, and a drum cleaner 36. As long as it has. The plurality of developing units 13 may form toner images of different colors. In this case, toner images of different colors are transferred onto the intermediate transfer belt 41 and a color image is formed on a medium such as paper P.

3−2.変形例2
上述した実施形態において除去部材361は、ドラムクリーナ36に用いられていたが、ベルトクリーナ49に用いられてもよい。この場合、除去部材361は、像保持体31に代えて中間転写ベルト41に付着した物質を除去すればよい。なお、像保持体31および中間転写ベルト41は、いずれも媒体に形成される像を保持する像保持体の一例である。
3-2. Modification 2
In the embodiment described above, the removing member 361 is used for the drum cleaner 36, but may be used for the belt cleaner 49. In this case, the removing member 361 may remove the substance attached to the intermediate transfer belt 41 instead of the image carrier 31. The image carrier 31 and the intermediate transfer belt 41 are both examples of an image carrier that holds an image formed on a medium.

3−3.変形例3
上述した実施形態において、除去部材361の接触部3611と支持部3612とは、図2に示すように長さが同じであったが、異なる長さや形状であってもよい。
図5は、この変形例におけるドラムクリーナ36の構成を示す図である。図5に示すように、接触部3611は、支持部3612よりも短い部材であってもよい。
3-3. Modification 3
In the embodiment described above, the contact portion 3611 and the support portion 3612 of the removal member 361 have the same length as illustrated in FIG. 2, but may have different lengths and shapes.
FIG. 5 is a diagram showing a configuration of the drum cleaner 36 in this modification. As illustrated in FIG. 5, the contact portion 3611 may be a member shorter than the support portion 3612.

3−4.変形例4
上述した実施形態において、像保持体31の軸方向から見て接触部3611および支持部3612は矩形であったが、これらの形状は矩形に限られず、例えば三角形や扇型であってもよい。図6は、この変形例におけるドラムクリーナ36の構成を示す図である。この場合であっても、条件aおよび条件bを満たすように、除去部材361の配置が定められていればよい。
3-4. Modification 4
In the above-described embodiment, the contact portion 3611 and the support portion 3612 are rectangular as viewed from the axial direction of the image carrier 31, but these shapes are not limited to a rectangle, and may be, for example, a triangle or a fan shape. FIG. 6 is a diagram showing the configuration of the drum cleaner 36 in this modification. Even in this case, it is only necessary that the arrangement of the removing member 361 is determined so as to satisfy the condition a and the condition b.

3−5.変形例5
上述した実施形態において除去部材361は、条件aおよび条件bを満たすように配置されていたが、除去部材361の配置は、条件aを満たさなくてもよい。除去部材361は、少なくとも条件bを満たすように配置されていればよい。すなわち、除去部材361の対向面F1は、下向きの面であればよい。
3-5. Modification 5
In the above-described embodiment, the removal member 361 is arranged so as to satisfy the condition a and the condition b. However, the arrangement of the removal member 361 may not satisfy the condition a. The removal member 361 only needs to be arranged so as to satisfy at least the condition b. That is, the facing surface F1 of the removing member 361 may be a downward surface.

3−6.変形例6
上述した実施形態および変形例において除去部材361は、少なくとも条件bを満たすように配置されていたが、さらに以下の条件cを満たすように配置されてもよい。
(条件c)接触点Cにおける像保持体31の側面の法線ベクトルを「法線ベクトルN0」とすると、この法線ベクトルN0は、重力方向の(+z方向)に向かう成分を含まない。すなわち、接触点Cは像保持体31の側面のうち、下半分の範囲内にある。
条件cにより、接触点Cは、像保持体31の下半分の側面にあるので、図4に示す領域R3の範囲内にある。これにより、除去部材361により像保持体31の側面から除去された物質が落下し易くなり、この側面上に堆積し難くなると推測される。
条件a、条件b、および条件cをいずれも満たす場合、除去部材361は、領域R1、領域R2、および領域R3が重なる領域にある接触点Cと接触する。つまり、図4においては、除去部材361−3から除去部材361−5までが、上記の条件を満たす除去部材361である。
3-6. Modification 6
In the embodiment and the modification described above, the removal member 361 is disposed so as to satisfy at least the condition b, but may be disposed so as to satisfy the following condition c.
(Condition c) Assuming that the normal vector of the side surface of the image carrier 31 at the contact point C is “normal vector N0”, the normal vector N0 does not include a component toward the gravity direction (+ z direction). That is, the contact point C is in the lower half of the side surface of the image carrier 31.
According to the condition c, the contact point C is on the side surface of the lower half of the image carrier 31 and is therefore within the range of the region R3 shown in FIG. Accordingly, it is estimated that the material removed from the side surface of the image holding member 31 by the removing member 361 easily falls and is difficult to deposit on the side surface.
When all of the conditions a, b, and c are satisfied, the removing member 361 contacts the contact point C in the region where the region R1, the region R2, and the region R3 overlap. That is, in FIG. 4, the removal member 361 that satisfies the above conditions is from the removal member 361-3 to the removal member 361-5.

1…画像形成装置、13…現像部、14…転写部、15…定着部、16…搬送部、31…像保持体、32…帯電器、33…露光装置、34…現像装置、35…一次転写ロール、36…ドラムクリーナ、360…ケース、361…除去部材、3611…接触部、3612…支持部、362…保持部材、41…中間転写ベルト、42…二次転写ロール、43…ベルト搬送ロール、44…バックアップロール、49…ベルトクリーナ、C…接触点、D13…矢線、F0…側面、F1…対向面、N0…法線ベクトル、N1…法線ベクトル、P…用紙、R1…領域、R2…領域、R3…領域。 DESCRIPTION OF SYMBOLS 1 ... Image forming apparatus, 13 ... Developing part, 14 ... Transfer part, 15 ... Fixing part, 16 ... Conveying part, 31 ... Image carrier, 32 ... Charger, 33 ... Exposure device, 34 ... Developing apparatus, 35 ... Primary Transfer roller, 36 ... drum cleaner, 360 ... case, 361 ... removal member, 3611 ... contact portion, 3612 ... support portion, 362 ... holding member, 41 ... intermediate transfer belt, 42 ... secondary transfer roll, 43 ... belt conveying roll , 44 ... backup roll, 49 ... belt cleaner, C ... contact point, D13 ... arrow line, F0 ... side face, F1 ... opposite face, N0 ... normal vector, N1 ... normal vector, P ... paper, R1 ... area, R2 ... region, R3 ... region.

Claims (4)

回転して側面に像を保持する像保持体と、
前記側面に付着した物質を除去する除去部材と
を有し、
前記像保持体の前記側面は、摂氏28度で0.5ヘルツの振動を与えたときの損失正接が0.015以上、0.035以下の第1材料により形成され、
前記除去部材は、
前記側面と接触点で接触する接触部と、
前記接触点の反対側から当該接触部を支持する支持部とを有し、
前記接触部が、100%モジュラスの値が7メガパスカル以上である第2材料で形成され、
前記支持部が、前記第2材料よりも硬度が低い第3材料で形成され、
前記像保持体の回転方向における前記接触点の上流側に対向する対向面の法線ベクトルが、重力方向の上に向かう成分を含まない
ことを特徴とする画像形成装置。
An image carrier that rotates to hold the image on the side;
A removal member for removing the substance attached to the side surface,
The side surface of the image carrier is formed of a first material having a loss tangent of 0.015 or more and 0.035 or less when a vibration of 0.5 hertz is applied at 28 degrees Celsius,
The removal member is
A contact portion that contacts the side surface at a contact point;
A support portion that supports the contact portion from the opposite side of the contact point;
The contact portion is formed of a second material having a 100% modulus value of 7 megapascals or more;
The support is formed of a third material having a lower hardness than the second material;
The image forming apparatus, wherein the normal vector of the facing surface facing the upstream side of the contact point in the rotation direction of the image holding member does not include a component upward in the gravity direction.
前記接触点は、
前記側面のうち重力方向の上に移動している領域にある
ことを特徴とする請求項1に記載の画像形成装置。
The contact point is
The image forming apparatus according to claim 1, wherein the image forming apparatus is in an area of the side surface that is moving in a gravitational direction.
前記像保持体は、
前記側面の前記接触点における法線ベクトルが、重力方向の上に向かう成分を含まない
ことを特徴とする請求項1または2に記載の画像形成装置。
The image carrier is
The image forming apparatus according to claim 1, wherein the normal vector at the contact point on the side surface does not include a component that moves upward in the direction of gravity.
前記第1材料は、電荷輸送能を有する下記一般式(1)に示すブタジエン構造を有する化合物と、下記一般式(2)で表される繰り返し単位及び下記一般式(3)で表される繰り返し単位を含むポリカーボネート共重合体と、を含む
ことを特徴とする請求項1から3のいずれか1項に記載の画像形成装置。
Figure 2015187650
(一般式(1)中、R1、R2、R3、R4、R5、及び、R6は、それぞれ同一であっても異なっていてもよく、水素原子、アルキル基、アルコキシル基、ハロゲン原子、又は、置換若しくは無置換のアリ−ル基を示す。m及びnは0又は1を示す。)
Figure 2015187650
Figure 2015187650
(一般式(2)及び一般式(3)中、R7、R8、R9、及び、R10は、各々独立に、水素原子、ハロゲン原子、炭素数1以上6以下のアルキル基、炭素数5以上7以下のシクロアルキル基、又は、炭素数6以上12以下のアリール基を表す。Xは、フェニレン基、ビフェニレン基、ナフチレン基、直鎖若しくは分岐アルキレン基、又は、シクロアルキレン基を表す。)
The first material includes a compound having a butadiene structure represented by the following general formula (1) having charge transporting ability, a repeating unit represented by the following general formula (2), and a repeating represented by the following general formula (3). The image forming apparatus according to claim 1, further comprising: a polycarbonate copolymer including units.
Figure 2015187650
(In the general formula (1), R 1 , R 2 , R 3 , R 4 , R 5 , and R 6 may be the same or different, and each represents a hydrogen atom, an alkyl group, an alkoxyl group, A halogen atom or a substituted or unsubstituted aryl group, and m and n each represents 0 or 1)
Figure 2015187650
Figure 2015187650
(In General Formula (2) and General Formula (3), R 7 , R 8 , R 9 , and R 10 are each independently a hydrogen atom, a halogen atom, an alkyl group having 1 to 6 carbon atoms, carbon A cycloalkyl group having 5 to 7 carbon atoms, or an aryl group having 6 to 12 carbon atoms, X represents a phenylene group, a biphenylene group, a naphthylene group, a linear or branched alkylene group, or a cycloalkylene group. .)
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JP2004093864A (en) * 2002-08-30 2004-03-25 Canon Inc Electrophotographic photoreceptor, electrophotographic apparatus, and process cartridge
US20110229233A1 (en) * 2010-03-18 2011-09-22 Ricoh Company, Ltd. Cleaning device, and image forming apparatus, process cartridge, and intermediate transfer unit each including the cleaning device
JP2011197309A (en) * 2010-03-18 2011-10-06 Ricoh Co Ltd Cleaning device, and image forming apparatus, process cartridge, intermediate transfer unit, and recording body conveying unit each including the cleaning device
JP2012047959A (en) * 2010-08-26 2012-03-08 Fuji Xerox Co Ltd Electrophotographic photoreceptor, process cartridge, and image forming apparatus

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2001265186A (en) * 2000-03-15 2001-09-28 Polymatech Co Ltd Cleaning blade
JP2004093864A (en) * 2002-08-30 2004-03-25 Canon Inc Electrophotographic photoreceptor, electrophotographic apparatus, and process cartridge
US20110229233A1 (en) * 2010-03-18 2011-09-22 Ricoh Company, Ltd. Cleaning device, and image forming apparatus, process cartridge, and intermediate transfer unit each including the cleaning device
JP2011197309A (en) * 2010-03-18 2011-10-06 Ricoh Co Ltd Cleaning device, and image forming apparatus, process cartridge, intermediate transfer unit, and recording body conveying unit each including the cleaning device
JP2012047959A (en) * 2010-08-26 2012-03-08 Fuji Xerox Co Ltd Electrophotographic photoreceptor, process cartridge, and image forming apparatus

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